JPH1065A - Coating material for fried food and fried food using the coating material and frozen food of fried food for re-heating with microwave oven by using the same - Google Patents

Coating material for fried food and fried food using the coating material and frozen food of fried food for re-heating with microwave oven by using the same

Info

Publication number
JPH1065A
JPH1065A JP8155547A JP15554796A JPH1065A JP H1065 A JPH1065 A JP H1065A JP 8155547 A JP8155547 A JP 8155547A JP 15554796 A JP15554796 A JP 15554796A JP H1065 A JPH1065 A JP H1065A
Authority
JP
Japan
Prior art keywords
chitosan
fried
fried food
bread
flour
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8155547A
Other languages
Japanese (ja)
Inventor
Kunimitsu Asakura
国満 朝倉
Noriko Hamada
紀子 浜田
Takeshi Okago
健 尾籠
Hiroshi Hirahara
弘志 平原
Yasutaka Kumano
康孝 熊野
Masahatsu Saka
真初 坂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nichiro Corp
Original Assignee
Nichiro Corp
Nichiro Gyogyo Kaisha Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nichiro Corp, Nichiro Gyogyo Kaisha Ltd filed Critical Nichiro Corp
Priority to JP8155547A priority Critical patent/JPH1065A/en
Publication of JPH1065A publication Critical patent/JPH1065A/en
Pending legal-status Critical Current

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  • Grain Derivatives (AREA)
  • Meat, Egg Or Seafood Products (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a coating material for fried foods fixed so that fine particles of chitosan are mixed therein and a fried food using the coating material so as to favorably keep crispy feeling of coating even when time is passed for a long time after frying. SOLUTION: This coating material for fried foods is obtained by applying a composition consisting essentially of wheat floor to the outer periphery of fine particles of chitosan, subjecting the coated composition to heat treatment or adding 0.1-3.0 pts.wt. fine particles of chitosan to 100 pts.wt. grain floor consisting essentially of wheat floor, mixing and kneading the mixture with water and a yeast or an expanding agent, baking the resultant bread dough and pulverizing the baked bread to afford chitosan-containing bread crumb. This fried food is obtained by applying the coating material for fried foods to the surface of the fried food.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、キトサンの微粒子が混
在するよう固定化した揚げ物用衣材とこれを使用した揚
げ物に関し、油ちょう後、長時間経過しても衣のクリス
ピー感が良好に維持できるようにしたものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fried food garment material in which fine particles of chitosan are immobilized and a fried food material using the same, and the crispness of the garment can be improved even after a long time after frying. It is something that can be maintained.

【0002】[0002]

【従来の技術】近年は、低温流通システム(コールドチ
ェーン)の発達と普及、外食産業におけるセントラルキ
ッチンシステムの発達と普及、デリカ食品の普及、電子
レンジ対応食品の普及などに伴い、調理済加工食品、半
調理済加工食品、これらの冷凍食品、チルド食品、半調
理済業務用食品が市場に多種多様に出回るようになっ
た。これらの食品は、調理加工後に流通の場におかれる
など、調理してから長時間が経過した後に食される環境
にある。一般に食品は、新鮮な材料を調理した直後に食
するのが美味しいとされており、時間が経過するにした
がって美味しさが低下するものである。フライ、天ぷ
ら、コロッケ、トンカツなど、衣付揚げ物もその例外で
はない。当該衣付揚げ物の美味しさは、中種を衣で被覆
して中種のエキスと香りを保存することと、衣の香ばし
さとそのクリスピー感にある。しかし、時間が経過する
と、酸化や油焼けなどを起こしたり、水分や油がしみ出
すなどして、品質が劣化し、クリスピー感が劣化するの
が普通である。特に、近年電子レンジで再加熱して食べ
ることができる電子レンジ対応の調理済冷凍食品におい
ては、その再加熱過程や冷凍過程で中種から表面に水分
が浸出し易く、湿り気を帯びて衣のクリスピー感が著し
く失われる欠点がある。
2. Description of the Related Art In recent years, with the development and spread of low-temperature distribution systems (cold chains), the development and spread of central kitchen systems in the restaurant industry, the spread of delicatessen foods, and the spread of microwaveable foods, cooked processed foods have been developed. A wide variety of semi-cooked processed foods, these frozen foods, chilled foods and semi-cooked commercial foods have come to market. These foods are in an environment where they are eaten after a long time has passed since cooking, such as being placed in a distribution place after cooking. Generally, it is considered that food is delicious immediately after cooking fresh ingredients, and the taste decreases as time passes. Fried foods such as fries, tempura, croquettes, and tonkatsu are no exception. The deliciousness of the fried food is that the medium seeds are covered with clothes to preserve the extract and aroma of the medium seeds, and the fragrance of the clothes and its crispy feeling. However, over time, the quality is deteriorated and the crispy feeling is usually deteriorated due to oxidation, burning of oil, etc., or oozing out of water or oil. In particular, in the case of cooked frozen foods compatible with microwave ovens, which can be reheated and eaten in recent years, it is easy for water to leach from the sponge to the surface during the reheating process and the freezing process, and the moisturized clothes There is a disadvantage that the crispy feeling is remarkably lost.

【0003】このような衣を付けて油で揚げている油ち
ょう済冷凍食品の技術課題である衣のクリスピー感を保
持するために、多方面で研究開発がおこなわれている。
例えば、具に増粘剤や粘性を呈する蛋白質をまぶして膨
潤する(特開平3−39053号)、衣層を熱風乾燥す
る(特開平4−12150号)、衣および追種を半揚げ
状態にして冷凍する(特開平5−49412号)、乳化
剤と油脂を添加する(特開昭63−276452号)、
レシチン又は/及びモノグリセリン脂肪酸エステルを含
有するバター液を付着する(特開平1−281041
号)、精白したもろこし粉を含有する(特公平1−62
31号)、食用繊維素材を微粉砕し、造粒したものが添
加する(特公平6−4013号)などである。しかし、
これらはそれなりに効果があるが、満足すべきものには
なっていない。
[0003] In order to maintain the crispy feeling of clothes, which is a technical problem of fried frozen foods fried in oil with such clothes, research and development are being carried out in various fields.
For example, the ingredients are covered with a thickener or a viscous protein to swell (JP-A-3-39053), the garment layer is dried with hot air (JP-A-4-12150), and the garments and seeds are half-fried. And the mixture is frozen (JP-A-5-49412), and an emulsifier and a fat are added (JP-A-63-276452).
A butter solution containing lecithin and / or monoglycerin fatty acid ester is adhered thereto (Japanese Patent Laid-Open No. 1-281041).
No.), contains polished sorghum flour (Japanese Patent Publication No. 1-62)
No. 31), and edible fiber materials are finely pulverized and granulated and added (Japanese Patent Publication No. 6-4013). But,
These are effective, but not satisfactory.

【0004】[0004]

【発明が解決しようとする課題】本発明者も、フライな
どの、衣を付けて油で揚げ物とする冷凍食品、特に電子
レンジ再加熱用フライ類の技術課題であるクリスピー感
を長時間保持するための研究を鋭意行った。その結果、
「クラムの中心に微粒子のキトサンを配し、その外周
に、小麦粉等を主体とする組成物をコ−ティングし、さ
らに加熱処理を施した揚げ物用衣材は、これを中種の表
面に付着して油ちょうすると、そのままでも冷凍しても
長時間経過しても衣のクリスピー感を保持することがで
きる。また特に電子レンジによる再加熱をしてもクリス
ピー感を維持し、澱粉の老化による食感や風味が良好と
なること。」という技術的知見を見出した。発明者ら
は、このような新たに見出した技術的知見に基づいて本
発明をしたものである。
The inventor of the present invention also keeps the crispy feeling, which is a technical problem of frozen foods, such as fried foods, which are fried with a batter and fried in oil, especially fries for reheating microwave ovens. I did research for it. as a result,
"A fine chitosan is placed at the center of the crumb, and a composition mainly composed of flour is coated on the outer periphery of the crumb. The fry makes it possible to maintain the crispy feeling of the garment even as it is, frozen or for a long time. The texture and flavor are good. " The inventors have made the present invention based on such newly found technical knowledge.

【0005】[0005]

【問題を解決しようとする手段】特許を受けようとする
第1発明は、キトサンの微粒子の外周に、小麦粉等を主
体とする組成物をコーティングし、加熱処理を施してな
る揚げ物用衣材である。
Means for Solving the Problems A first invention to be patented is a fried food garment obtained by coating the outer periphery of chitosan fine particles with a composition mainly composed of flour and the like and subjecting the composition to heat treatment. is there.

【0006】本発明で用いるキトサンとは、動物におい
ては主として節足動物たるエビやカニの甲殻の構成成分
としてあるキチン、即ちN−アセチル−D−グルコミサ
ンが多数結合した多糖類のアセチル基を取り除いたもの
である。キトサンは、セルロース様の構造を持つ食物繊
維であり、血中のコレステロール改善作用、整腸作用、
血圧調整作用などの生理作用を有する。そして、キトサ
ンは、水、アルカリ性水溶液、有機溶媒には不要である
が、希酸(塩酸、硝酸など)や有機酸(酢酸、乳酸、蟻
酸、アスコルビン酸、リンゴ酸など)水溶液に溶解し、
クエン酸、酒石酸などの多価有機水溶液には高温で溶解
し、低温でゲル化する性質を有している。また、このキ
トサンの有機酸水溶液は、抗菌性があるので保存料とし
て利用でき、増粘安定剤、粉末乾燥成分の流動性の改
良、嵩の増加、テクスチャー改善などの用途もある。
The term chitosan used in the present invention refers to chitin, which is a constituent of arthropod shrimp and crab shells, ie, removes the acetyl group of a polysaccharide to which a large number of N-acetyl-D-glucomisans are bound. It is a thing. Chitosan is a dietary fiber with a cellulose-like structure, which improves blood cholesterol, regulates intestines,
It has physiological effects such as blood pressure regulation. Chitosan is unnecessary in water, alkaline aqueous solutions and organic solvents, but is dissolved in dilute acid (hydrochloric acid, nitric acid, etc.) or organic acid (acetic acid, lactic acid, formic acid, ascorbic acid, malic acid, etc.) aqueous solution,
It has the property of dissolving at high temperatures and gelling at low temperatures in polyvalent organic aqueous solutions such as citric acid and tartaric acid. The aqueous solution of chitosan in organic acid can be used as a preservative because of its antibacterial properties, and also has applications such as thickening stabilizers, improvement in fluidity of powder dry components, increase in bulk, and improvement in texture.

【0007】キトサン微粒子の周囲に配する小麦粉等を
主体とする組成物は、その本来の組成に応じて調整す
る。その際、調整した組成物をキトサン微粒子の周囲に
配するに際し、塗布等の処理を行なった後に焼成しても
よいし、組成物の中に、キトサンの微粒子を均一に分散
させ、焼成した後、破砕するようにしてもよい。クラム
素材をパン粉により組成物を製造する場合には、パン生
地の仕込み方法には直捏法と中種法があり、焼成方法に
は焙焼式と電極式があり、また、焼成直後の高温多湿の
パンをある程度老化させる方法には常温放置、冷蔵除
湿、強制除湿のそれぞれの方法がある。本発明に用いら
れる組成物はクラムの素材としては、パン粉の他にクラ
ッカ−粉、天かすなどが考えられる。
[0007] The composition mainly composed of flour and the like disposed around the chitosan fine particles is adjusted according to its original composition. At that time, when disposing the adjusted composition around the chitosan fine particles, it may be baked after performing a treatment such as coating, or in the composition, the chitosan fine particles are uniformly dispersed and fired. May be crushed. In the case of producing a composition from bread crumbs using a crumb material, there are a direct kneading method and a sponge method as a method of preparing bread dough, and a baking method includes a roasting method and an electrode method. There are various methods of aging the bread to a certain degree, such as standing at room temperature, refrigerated dehumidification, and forced dehumidification. In the composition used in the present invention, as a raw material of the crumb, cracker powder, heaven cake and the like can be considered in addition to bread crumbs.

【0008】このようにキトサン微粒子の外周に、小麦
粉等を主体とする組成物をコーティングし、加熱処理を
施すことにより、キトサンの凝集作用により、クラム中
の蛋白質が凝集し、焼成に際しておこるクロスリンクを
密にし、クラム自身の物理的構造を強化するとともに、
耐水性を付与し、クラムの中心まで水が浸透することを
阻害する。また、澱粉の老化も抑えられることにより、
当該クラムは電子レンジなどで再加熱しても、油ちょう
時のクリスピー感のある食感を維持することが可能とな
った。すなわち、これを用いて作られた油ちょう食品
は、電子レンジ等で加熱してもその衣の食感が非常に好
ましいものとなることが判明した。
[0008] As described above, by coating a composition mainly composed of flour or the like on the outer periphery of the chitosan fine particles and subjecting the composition to heat treatment, the protein in the crumb aggregates due to the aggregation effect of chitosan, and crosslinks occur during firing. And strengthen Crumb's own physical structure,
Provides water resistance and inhibits water from penetrating to the center of the crumb. Also, by suppressing the aging of starch,
Even if the crumb was reheated in a microwave oven or the like, it became possible to maintain a crispy texture during frying. In other words, it has been found that the oil fried food made using this has a very good texture when worn in a microwave oven or the like.

【0009】特許を受けようとする第2発明は、小麦粉
を主体とした殻粉100(重量部)にキトサンの微粒子
を0.1〜3.0(重量部)を混入したものに、水と、
イースト菌または膨化剤を混入して練り上げた生地でパ
ンを焼成したうえ、これを粉砕してキトサン入りパン粉
にしたことを特徴とする揚げ物用衣材である。
[0009] The second invention to be patented is a mixture of husk flour 100 (parts by weight) containing chitosan microparticles in an amount of 0.1 to 3.0 (parts by weight), water and water. ,
A fried clothing material characterized by baking bread with dough kneaded with yeast or a leavening agent, and crushing the bread into chitosan-containing bread crumbs.

【0010】この発明は上記第1の発明における揚げ物
用衣材の配合割合を特定すると共に、混練したパン生地
を焼成して粉砕することにより揚げ物用衣材とした発明
である。キトサン微粒子の配合割合が小麦粉等を主体と
する組成物に対して0.1%以下であるとキトサンの性
質としての凝集作用に充分な効果が得られなくなる。ま
た、3.0%以上であると、グルテン形成に障害をきた
し、パン焼成が不良となる問題を有している。なお、品
質効果や経済的な実現性等の点から0.3〜0.5%程
度であることが望ましい。ここで用いるキトサンの粘度
は、0.5%の酢酸に0.5%のキトサンを溶解して3
88Poisとし、35メッシュパスで、425μm 以下の
粒度であり、キトサンの外観は、白色〜淡黄色の微粒子
として用いる。
[0010] This invention is an invention in which the mixing ratio of the fried food material in the first invention is specified, and the kneaded dough is baked and pulverized to obtain a fried food material. If the mixing ratio of the chitosan fine particles is 0.1% or less with respect to the composition mainly composed of flour or the like, a sufficient effect on the coagulation action as the property of chitosan cannot be obtained. Further, when the content is 3.0% or more, there is a problem in that gluten formation is hindered and baking is poor. In addition, it is desirable to be about 0.3 to 0.5% from the viewpoint of quality effect, economic feasibility, and the like. The viscosity of chitosan used here is 3% by dissolving 0.5% of chitosan in 0.5% of acetic acid.
The particle size is 88 Pois, the particle size is 425 μm or less in a 35 mesh pass, and the appearance of chitosan is used as white to pale yellow fine particles.

【0011】特許を受けようとする第3発明は、キトサ
ンの微粒子の外周に、小麦粉を主体とする組成物をコー
ティングし、加熱処理を施してなる揚げ物用衣材を、揚
げ物表面に被覆してなる揚げ物である。
[0011] In the third invention to be patented, the outer periphery of chitosan fine particles is coated with a composition mainly composed of wheat flour, and the fried food material obtained by heat treatment is coated on the surface of the fried food. It is fried food.

【0012】この発明は前記第1の発明による揚げ物用
衣材を用いて揚げ物表面に被覆してなる揚げ物の発明で
ある。本発明においては、揚げ物表面が揚げ物用衣材で
被覆されているために、キトサンの凝集作用により、ク
ラム中の蛋白質が凝集し、クラム自身の物理的構造を強
化するとともに、耐水性を付与し、クラムの中心まで水
が浸透することを阻害する効果を有する。また、クラム
中の澱粉の老化も抑えらることにより、当該クラムは電
子レンジなどで再加熱しても、油ちょう時のクリスピー
感のある食感を維持することが可能となる。
[0012] The present invention is an invention of a fried food in which the surface of the fried food is covered with the fry clothing material according to the first invention. In the present invention, since the fried food surface is covered with fried food clothing, the protein in the crumb is aggregated by the aggregation action of chitosan, strengthening the physical structure of the crumb itself and imparting water resistance. Has the effect of inhibiting the penetration of water to the center of the crumb. Also, by suppressing the aging of the starch in the crumb, the crumb can maintain a crispy texture during frying even if it is reheated in a microwave oven or the like.

【0013】特許を受けようとする第4発明は、小麦粉
を主体とした殻粉100(重量部)にキトサンの微粒子
を0.1〜3.0(重量部)を混入したものに、水と、
イースト菌または膨化剤を混入して練り上げた生地でパ
ンを焼成したうえ、これを粉砕してキトサン入りパン粉
にした揚げ物用衣材を、揚げ物表面に被覆したことを特
徴とする揚げ物である。この発明は前記第2の発明によ
る揚げ物用衣材を用いて揚げ物表面に被覆してなる揚げ
物の発明である。
[0013] A fourth invention to be patented is a mixture of husk flour 100 (parts by weight) composed mainly of wheat flour and 0.1 to 3.0 (parts by weight) of fine chitosan particles mixed with water. ,
A fried food characterized by baking bread with kneaded dough mixed with yeast or a leavening agent, and then covering the fried food material with a batter of chitosan-containing bread crumbs. This invention is an invention of a deep-fried food in which the surface of the deep-fried food is covered with the fried clothing according to the second invention.

【0014】特許を受けようとする第5発明は、キトサ
ンの微粒子の外周に、小麦粉を主体とする組成物をコ−
ティングし、加熱処理を施してなる揚げ物用衣材を、揚
げ物表面に被覆してなる衣の内側および/または外側に
付着させたうえ油ちょうし、その後冷凍したことを特徴
とする電子レンジ再加熱用揚げ物の冷凍食品である。
A fifth invention to be patented is that a composition mainly composed of flour is coated on the outer periphery of chitosan fine particles.
For heating a microwave oven, wherein the fried food garment which has been subjected to heat treatment is attached to the inside and / or outside of the garment coated on the surface of the fried food, fried, and then frozen. It is fried frozen food.

【0015】この発明は前記第1発明の揚げ物用衣材を
用いて揚げ物表面に被覆してなるもので、衣の内側およ
び/または外側に付着させたうえ油ちょうし、その後冷
凍した電子レンジ再加熱用揚げ物の冷凍食品としたもの
である。
According to the present invention, the fried food material of the first invention is coated on the surface of the fried food, and is adhered to the inside and / or the outside of the batter, fried, and then frozen and reheated in a microwave oven. It is fried frozen food.

【0016】特許を受けようとする第6発明は、小麦粉
を主体とした殻粉100(重量部)にキトサンの微粒子
を0.1〜3.0(重量部)を混入したものに、水と、
イースト菌または膨化剤を混入して練り上げた生地でパ
ンを焼成したうえ、これを粉砕してキトサン入りパン粉
にした揚げ物用衣材を、揚げ物表面に被覆してなる衣の
内側および/または外側に付着させたうえ油ちょうし、
その後冷凍したことを特徴とする電子レンジ再加熱用揚
げ物の冷凍食品である。
[0016] The sixth invention to be patented is a mixture of husk flour 100 (parts by weight) containing chitosan microparticles in an amount of 0.1 to 3.0 (parts by weight), water and water. ,
Bread is baked with dough mixed with yeast or leavening agent and then crushed into chitosan-containing breadcrumbs for fried food on the inside and / or outside of the garment coated on the surface of the fried food. Let it be oiled,
It is a frozen food of fried food for microwave reheating, characterized by being frozen thereafter.

【0017】この発明は前記第2発明で特定した配合割
合の揚げ物用衣材をパン粉にした揚げ物用衣材を用いて
揚げ物表面に被覆してなるもので、衣の内側および/ま
たは外側に付着させたうえ油ちょうし、その後冷凍した
電子レンジ再加熱用揚げ物の冷凍食品としたものであ
る。
This invention comprises a fried food material having the blending ratio specified in the second invention coated on the surface of the fried food using a fried food material made into a bread crumb, and adheres to the inside and / or outside of the batter. It was made into fried food after being fried and then fried for microwave reheating.

【0018】ここで、電子レンジ再加熱用揚げ物の冷凍
食品というのは、製造段階で中種に揚げ物用衣材を被覆
した上、油ちょうする段階まで調理加工し、この油ちょ
う済の衣付食品を凍結して流通させ、消費者には喫食直
前にオーブントースターや電子レンジ等で加熱するだけ
で喫食させる方式の食品である。冷凍食品としては、農
産加工品、畜産加工品、水産加工品等の各種フライ類の
他に、各種コロッケ類、各種カツ類、各種てんぷら類等
を含むものである。
[0018] Here, the frozen food of the fried food for reheating the microwave oven is defined by coating the middle-aged food for the deep-fried food at the manufacturing stage, cooking and processing until the frying stage, It is a food of the type in which food is frozen and distributed, and is consumed by the consumer just by heating it with an oven toaster or a microwave oven immediately before eating. Frozen foods include various fries such as processed agricultural products, processed livestock products, and processed marine products, as well as various croquettes, various cutlets, and various tempura.

【0019】キトサンの有機酸水溶液は、抗菌性を有す
るので保存料として利用できる他に、増粘安定剤、粉末
乾燥成分の流動性の改良、嵩の増加、テクスチャー改善
などの用途がある。このような性質を有するキトサンの
微粒子の外周に、小麦粉を主体とする組成物をコーティ
ングし、加熱処理を施してなる揚げ物用衣材を、揚げ物
表面に被覆して用いることにより、キトサンの凝集作用
により、クラム中の蛋白質が凝集し、焼成に際しておこ
るクロスリンクを密にし、クラム自身の物理的構造を強
化するとともに、耐水性を付与し、クラムの中心まで水
が浸透することを阻害する効果を有すると共に、クラム
中の澱粉の老化も抑えらることにより、当該クラムは電
子レンジなどで再加熱しても、油ちょう時のクリスピー
感のある食感を維持することが可能となる。すなわち、
これを用いて作られた油ちょう食品は、電子レンジ等で
加熱してもその衣の食感が非常に好ましいものとなるこ
とが判明した。
The organic acid aqueous solution of chitosan has antibacterial properties and can be used as a preservative. In addition, it has applications such as a thickening stabilizer, improvement of fluidity of powder dry component, increase of bulk and improvement of texture. By coating a composition mainly composed of flour on the outer periphery of fine particles of chitosan having such properties, and using a food material for fried food obtained by applying a heat treatment to the surface of the fried food, the aggregation effect of chitosan is obtained. As a result, the protein in the crumb aggregates, making the crosslinks that occur during baking dense, strengthening the physical structure of the crumb itself, imparting water resistance, and inhibiting water from penetrating to the center of the crumb. Having crumbs also suppresses the aging of the starch in the crumbs, so that the crumbs can maintain a crispy texture when fried even if they are reheated in a microwave oven or the like. That is,
It has been found that the fried food made using this has a very good texture even when heated in a microwave oven or the like.

【0020】[0020]

【実施例】以下、本発明を実施例に基づいて詳細に説明
する。 <実施例1>揚げ物用衣材の実施例としてまず、組成物
をコーティングする微粒子のキトサンの原料として油ガ
ニ脚殻由来のキトサンを用意した。このキトサンは水分
が4.2%、灰分が0.3%、蛋白質が0.02%、脱
アセチル化度が85.9%のもので、外観上は淡黄色が
かった白色である。0.5%酢酸に本キトサンを0.5
%溶解した時の粘度は388Poisとなった。このキトサ
ンを粉砕機で粉砕し、微粒化した。その粒度は、35メ
ッシュパスのふるいを通過する、425μm 以下になる
ように調整した。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described in detail based on embodiments. <Example 1> First, as an example of a fry clothing material, chitosan derived from oil crab leg shells was prepared as a raw material of fine chitosan coated with the composition. This chitosan has a water content of 4.2%, an ash content of 0.3%, a protein of 0.02% and a degree of deacetylation of 85.9%, and has a pale yellowish white appearance. 0.5% acetic acid to 0.5% chitosan
The viscosity at% dissolution was 388 Pois. This chitosan was pulverized with a pulverizer and atomized. The particle size was adjusted to be 425 μm or less, which passes through a sieve of a 35 mesh pass.

【0021】<実験例2>揚げ物用衣材の実施例とし
て、小麦粉などを主体とする組成物であるパン粉を製造
した。 試料1(本発明品) 10Kgの小麦粉に対し、実施例
1のキトサン微粒子40gを加え、さらにイ−スト菌、
膨化剤、食塩、砂糖などを加えて混練し、生地温度が約
30度になるまで5分間ミキシングを行い、約1時間発
酵させた後、180℃で50分間オプン加熱を行ってパ
ンとなし、さらに粉砕してなるパン粉。 試料2(対照品) 10Kgの小麦粉にイ−スト菌、膨化
剤、食塩、砂糖などを加えて混練し、生地温度が約30
度になるまで5分間ミキシングを行い、約1時間発酵さ
せた後、180℃で50分間オ−プン加熱を行いパンと
なし、さらに粉砕してなるパン粉。 試料3(比較例1) 10Kgの小麦粉に実施例1のキト
サン微粒子8gを加え、さらにイ−スト菌、膨化剤、食
塩、砂糖などを加えて混練し、生地温度が約30度にな
るまで5分間ミキシングを行い、約1時間発酵させた
後、180℃で50分間オ−プン加熱を行ってパンとな
し、さらに粉砕してなるパン粉。 試料4(比較例2) 10Kgの小麦粉に実施例1のキ
トサン微粒子400gを加え、さらにイ−スト菌、膨化
剤、食塩、砂糖などを加えて混練し、生地温度が約30
度になるまで5分間ミキシングを行い、約1時間発酵さ
せた後、180℃で50分間オ−プン加熱を行ってパン
となし、さらに粉砕してなるパン粉。ここで、試料1お
よび試料3で得られたパンは、対照品である試料2のパ
ンと大きな差は見られなかった。しかし試料4のパン
は、それ自身のふくらみが悪くまたもろいもので、パン
粉にする際の破砕で粒子が小さくなってしまい、本件揚
げ物用衣材としてのパン粉に向かないことが判明した。
なお、パンの焼成法については、電極法と焙焼法がある
が、パン粉の製造に際して両者に顕著な差は認められな
かった。
<Experimental Example 2> As an example of a fried food material, bread crumbs, which is a composition mainly composed of flour, were produced. Sample 1 (product of the present invention) To 10 kg of flour, 40 g of the chitosan fine particles of Example 1 were added.
Add a leavening agent, salt, sugar, etc., knead, mix for 5 minutes until the dough temperature is about 30 degrees, ferment for about 1 hour, and then heat it at 180 ° C for 50 minutes to make bread, Bread crumbs that are further crushed. Sample 2 (control) 10 kg of flour was mixed with yeast, swelling agent, salt, sugar, etc., and kneaded.
After mixing for 5 minutes until fermentation, fermenting for about 1 hour, open heating at 180 ° C. for 50 minutes to make bread, and further crushed bread crumbs. Sample 3 (Comparative Example 1) To 10 kg of flour, 8 g of the chitosan microparticles of Example 1 was added, and yeast yeast, a leavening agent, salt, sugar and the like were further added and kneaded. After mixing for 1 minute and fermenting for about 1 hour, bread heating is carried out at 180 ° C. for 50 minutes to form a bread, and further crushed. Sample 4 (Comparative Example 2) 400 g of the chitosan fine particles of Example 1 were added to 10 kg of flour, and yeast, a leavening agent, salt, sugar and the like were further added and kneaded.
After mixing for 5 minutes until fermentation, fermenting for about 1 hour, open heating at 180 ° C. for 50 minutes to make bread, and further crushed bread crumbs. Here, the bread obtained in the sample 1 and the sample 3 did not show a significant difference from the bread of the control sample 2. However, it was found that the bread of Sample 4 itself had poor swelling and was brittle, and its particles were reduced by crushing when making the bread crumbs, so that it was not suitable for the bread crumbs used as the fried food batter.
The bread baking method includes an electrode method and a roasting method, but no remarkable difference was observed between the two methods in the production of bread crumbs.

【0022】<実験例3>実施例2にて作成したパン粉
を用いて、白身魚を中種とする白身魚フライを製造する
実験を行った。 試験区1 実験例2で製造した試食用パン粉を中種表面
に付着させた後、バッタリングし、さらに従来のパン粉
を外側にブレッダリングしたのち、180℃3分間油ち
ょうして冷凍した冷凍白身魚フライ。 試験区2 実験例2で製造した試食用パン粉をバッタリ
ングした中種の表面に付着させた後、180℃3分間油
ちょうして冷凍した冷凍白身魚フライ。 試験区3 実験例2で製造した試食用パン粉を中種表面
に付着させた後、バッタリングし、さらに試食用パン粉
を外側にブレッダリングしたのち、180℃3分間油ち
ょうして冷凍した冷凍白身魚フライ。ここで白身魚フラ
イの中種は約60g、油ちょう後のフライ重量は約10
0gとなるように調整した。
<Experimental Example 3> Using the bread crumbs prepared in Example 2, an experiment was conducted to produce a white fish fry using white fish as an intermediate species. Test Zone 1 Frozen white fish, which was prepared by attaching the bread crumbs for tasting produced in Experimental Example 2 to the surface of the sponge seeds, followed by battering, and further breading the conventional bread crumbs to the outside, then frying at 180 ° C. for 3 minutes and freezing. fly. Test Section 2 Frozen white fish fried frozen after baking the breadcrumbs for tasting produced in Experimental Example 2 on the surface of the battered medium seeds and frying at 180 ° C. for 3 minutes. Test Section 3 After attaching the crumbs for tasting produced in Experimental Example 2 to the surface of the sponge seeds, battering, and further breading the crumbs for tasting to the outside, then frozen at 180 ° C. for 3 minutes and frozen, frozen white fish fly. Here, the middle type of white fish fry is about 60 g, and the weight of fried fish after frying is about 10
It was adjusted to be 0 g.

【0023】官能検査の結果 出来上がった白身魚フライは、凍結後、1週間および2
ケ月後に取り出し、電子レンジで加熱処理した後、官能
検査に共した。官能検査の評価は、クリスピ−感、歯切
れの良さ等の好ましい食感について20人のパネラ−に
より10点法で採点したものの平均とした。
The results of the sensory test were as follows.
After a month, the sample was taken out, heated in a microwave oven, and subjected to a sensory test. The evaluation of the sensory test was an average of scores obtained by scoring the preferred texture such as crispness and crispness by a panel of 20 persons using a 10-point scale.

【0024】 [0024]

【0025】この結果から、本発明の揚げ物用衣材は、
フライトして好ましい食感即ちクリスピ−感、歯切れの
良さが好評であり、優れていること、また長期保存に耐
えることが判った。また、充分な添加料を入れなかった
試料3では、製造直後は多少の効果は示すものの、長期
の保存に耐えうるほどの効果は有さないことが判った。
試料4は、パン粉自体の性状が劣っていたこともあり効
果が無かった。これらの効果は、クラム自身への水の浸
透が阻害されていると同時に、キトサンの外周に組成物
がコ−ティングされている揚げ物用衣材であるために、
加熱時に水分の発散が促進されるためと思われる。した
がって、本発名品に係る揚げ物用衣材は、衣の内側およ
び外側のいずれにおいてもキトサンが有する効果を有効
に発揮されることが確認された。
From these results, it can be seen that the fried clothing of the present invention
The preferred texture, crispness, and crispness upon flight were well received and proved to be excellent and to withstand long-term storage. Further, it was found that Sample 3, which did not contain a sufficient additive, exhibited some effect immediately after production, but did not have an effect enough to withstand long-term storage.
Sample 4 was ineffective because the properties of the crumb itself were inferior. These effects are due to the fact that the penetration of water into the crumb itself is impeded, and at the same time the composition is coated on the outer periphery of chitosan for fried food garments,
It is considered that the divergence of water is promoted during heating. Therefore, it was confirmed that the fried clothing material according to the present invention effectively exerts the effect of chitosan on both inside and outside of the clothing.

【0026】[0026]

【発明の効果】第1発明は、揚げ物用衣材としてキトサ
ンの微粒子の外周に、小麦粉等を主体とする組成物をコ
−ティングし、加熱処理を施してなる点が技術的特徴で
ある。
The first invention has a technical feature in that a composition mainly composed of flour or the like is coated on the outer periphery of chitosan fine particles as a clothing material for deep-fried foods and subjected to a heat treatment.

【0027】第2発明は、小麦粉を主体とした殻粉10
0(重量部)にキトサンの微粒子を0.1〜3.0(重
量部)を混入したものに、水と、イースト菌または膨化
剤を混入して練り上げた生地でパンを焼成したうえ、こ
れを粉砕してキトサン入りパン粉にした揚げ物用衣材で
ある点が技術的特徴である。
The second invention relates to a shell powder 10 mainly composed of flour.
0 (parts by weight) and 0.1 to 3.0 (parts by weight) of fine particles of chitosan mixed with water, yeast or a leavening agent, and the bread is baked with a dough kneaded. It is a technical feature that it is a garment for fried food that has been crushed into breadcrumbs containing chitosan.

【0028】第3発明は、キトサンの微粒子の外周に、
小麦粉を主体とする組成物をコ−ティングし、加熱処理
を施してなる揚げ物用衣材を、揚げ物表面に被覆してな
る揚げ物である。
According to a third aspect of the present invention, the outer periphery of chitosan fine particles is
It is a fried food obtained by coating a composition for a fried food, which is obtained by coating a composition mainly composed of flour and subjecting the composition to heat treatment.

【0029】第4発明は、小麦粉を主体とした殻粉10
0(重量部)にキトサンの微粒子を0.1〜3.0(重
量部)を混入したものに、水と、イースト菌または膨化
剤を混入して練り上げた生地でパンを焼成したうえ、こ
れを粉砕してキトサン入りパン粉にした揚げ物用衣材
を、揚げ物表面に被覆したことを特徴とする揚げ物であ
る。
The fourth invention is a husk powder 10 mainly composed of flour.
0 (parts by weight) and 0.1 to 3.0 (parts by weight) of fine particles of chitosan mixed with water, yeast or a leavening agent, and the bread is baked with a dough kneaded. A fried food, characterized in that the fried food batter, which has been pulverized into chitosan-containing breadcrumbs, is coated on the surface of the fried food.

【0030】第5発明は、キトサンの微粒子の外周に、
小麦粉を主体とする組成物をコ−ティングし、加熱処理
を施してなる揚げ物用衣材を、揚げ物表面に被覆してな
る衣の内側および/または外側に付着させたうえ油ちょ
うし、その後冷凍したことを特徴とする電子レンジ再加
熱用揚げ物の冷凍食品である。
The fifth invention is directed to a method in which chitosan fine particles
A composition mainly composed of flour is coated, and a fried food material obtained by performing a heat treatment is adhered to the inside and / or outside of a fried food surface-coated batter, fried, and then frozen. It is a frozen food of fried food for reheating a microwave oven.

【0031】第6発明は、小麦粉を主体とした殻粉10
0(重量部)にキトサンの微粒子を0.1〜3.0(重
量部)を混入したものに、水と、イースト菌または膨化
剤を混入して練り上げた生地でパンを焼成したうえ、こ
れを粉砕してキトサン入りパン粉にした揚げ物用衣材
を、揚げ物表面に被覆してなる衣の内側および/または
外側に付着させたうえ油ちょうし、その後冷凍したこと
を特徴とする電子レンジ再加熱用揚げ物の冷凍食品であ
る。
The sixth invention relates to a shell powder 10 mainly composed of wheat flour.
0 (parts by weight) and 0.1 to 3.0 (parts by weight) of fine particles of chitosan mixed with water, yeast or a leavening agent, and the bread is baked with a dough kneaded. A fried food material for reheating a microwave oven, wherein the fried food material crushed into chitosan-containing bread crumbs is adhered to the inside and / or outside of a batter coated on the surface of the fried food, fried, and then frozen. Is frozen food.

【0032】本願発明は、このような性質を有するキト
サンの微粒子の外周に、小麦粉を主体とする組成物をコ
ーティングし、加熱処理を施してなる揚げ物用衣材を、
揚げ物表面に被覆して用いることにより、キトサンの凝
集作用により、クラム中の蛋白質が凝集し、焼成に際し
ておこるクロスリンクを密にし、クラム自身の物理的構
造を強化するとともに、耐水性を付与し、クラムの中心
まで水が浸透することを阻害する効果を有すると共に、
クラム中の澱粉の老化も抑えらることにより、当該クラ
ムは電子レンジなどで再加熱しても、油ちょう時のクリ
スピー感のある食感を維持するものとなる。そして、揚
げ物用衣材を用いて作られた油ちょう食品は、電子レン
ジ等で加熱してもその衣の食感が非常に好ましいものと
なるものである。
According to the present invention, a coating material for fried food obtained by coating a composition mainly composed of flour on the outer periphery of fine particles of chitosan having such properties and subjecting the composition to heat treatment,
By coating and using on the fried food surface, the protein in the crumb aggregates due to the aggregation action of chitosan, making the crosslinks that occur during firing dense, strengthening the physical structure of the crumb itself, and imparting water resistance, While having the effect of inhibiting water from penetrating to the center of the crumb,
By suppressing the aging of the starch in the crumb, the crumb maintains a crispy texture during frying even when reheated in a microwave oven or the like. The fried food made using the fried food clothing material has a very good texture even when heated in a microwave oven or the like.

フロントページの続き (72)発明者 平原 弘志 神奈川県横須賀市久里浜7丁目36番5号 株式会社ニチロ中央研究所内 (72)発明者 熊野 康孝 神奈川県横須賀市久里浜7丁目36番5号 株式会社ニチロ中央研究所内 (72)発明者 坂 真初 神奈川県横須賀市久里浜7丁目36番5号 株式会社ニチロ中央研究所内Continued on the front page (72) Inventor Hiroshi Hirahara 7-36-5 Kurihama, Yokosuka City, Kanagawa Prefecture Inside Nichiro Central Research Laboratory Co., Ltd. (72) Inventor Yasutaka Kumano 7-36-5 Kurihama, Yokosuka City, Kanagawa Prefecture Nichiro Central Co., Ltd. Inside the laboratory (72) Inventor Masaki Saka 7-36-5 Kurihama, Yokosuka City, Kanagawa Prefecture Nichiro Central Research Laboratory Co., Ltd.

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 キトサンの微粒子の外周に、小麦粉等を
主体とする組成物をコーティングし、加熱処理を施して
なる揚げ物用衣材。
1. A fried food clothing material obtained by coating the outer periphery of fine particles of chitosan with a composition mainly composed of flour or the like and subjecting the composition to a heat treatment.
【請求項2】 小麦粉を主体とした殻粉100(重量
部)にキトサンの微粒子を0.1〜3.0(重量部)を
混入したものに、水と、イースト菌または膨化剤を混入
して練り上げた生地でパンを焼成したうえ、これを粉砕
してキトサン入りパン粉にしたことを特徴とする揚げ物
用衣材。
2. A mixture of chitosan fine particles of 0.1 to 3.0 (parts by weight) mixed with husk flour 100 (parts by weight) mainly composed of flour, and water, yeast or a leavening agent mixed therein. Baking bread with the kneaded dough and crushing the bread into chitosan-containing bread crumbs, a fried clothing material.
【請求項3】キトサンの微粒子の外周に、小麦粉を主体
とする組成物をコーティングし、加熱処理を施してなる
揚げ物用衣材を、揚げ物表面に被覆してなる揚げ物。
3. A fried food obtained by coating the outer periphery of chitosan microparticles with a composition mainly composed of flour and subjecting the fried food clothing material to heat treatment to cover the surface of the fried food.
【請求項4】 小麦粉を主体とした殻粉100(重量
部)にキトサンの微粒子を0.1〜3.0(重量部)を
混入したものに、水と、イースト菌または膨化剤を混入
して練り上げた生地でパンを焼成したうえ、これを粉砕
してキトサン入りパン粉にした揚げ物用衣材を、揚げ物
表面に被覆したことを特徴とする揚げ物。
4. A mixture of husk flour (mainly flour) 100 (parts by weight) and chitosan microparticles (0.1 to 3.0 parts by weight) mixed with water, yeast or a leavening agent. A fried food characterized by baking bread with the kneaded dough and then coating the fried food surface with a fried food batter obtained by pulverizing the bread into chitosan-containing bread crumbs.
【請求項5】 キトサンの微粒子の外周に、小麦粉を主
体とする組成物をコーティングし、加熱処理を施してな
る揚げ物用衣材を、揚げ物表面に被覆してなる衣の内側
および/または外側に付着させたうえ油ちょうし、その
後冷凍したことを特徴とする電子レンジ再加熱用揚げ物
の冷凍食品。
5. The outer periphery of chitosan microparticles is coated with a composition mainly composed of flour, and a heat-treated fry clothing material is coated on the surface of the fried food inside and / or outside. Fried frozen food for microwave reheating, characterized by being attached, fried, and then frozen.
【請求項6】 小麦粉を主体とした殻粉100(重量
部)にキトサンの微粒子を0.1〜3.0(重量部)を
混入したものに、水と、イースト菌または膨化剤を混入
して練り上げた生地でパンを焼成したうえ、これを粉砕
してキトサン入りパン粉にした揚げ物用衣材を、揚げ物
表面に被覆してなる衣の内側および/または外側に付着
させたうえ油ちょうし、その後冷凍したことを特徴とす
る電子レンジ再加熱用揚げ物の冷凍食品。
6. A mixture of chitosan fine particles of 0.1 to 3.0 (parts by weight) in a flour 100 (parts by weight) mainly composed of wheat flour, and water, yeast or a leavening agent mixed therein. The bread is baked with the kneaded dough, and the baked bread is then crushed into chitosan-containing breadcrumbs. The baked bread is then applied to the inside and / or outside of the baked batter, and then fried, and then frozen. Fried frozen foods for reheating microwave ovens, characterized in that:
JP8155547A 1996-06-17 1996-06-17 Coating material for fried food and fried food using the coating material and frozen food of fried food for re-heating with microwave oven by using the same Pending JPH1065A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8155547A JPH1065A (en) 1996-06-17 1996-06-17 Coating material for fried food and fried food using the coating material and frozen food of fried food for re-heating with microwave oven by using the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8155547A JPH1065A (en) 1996-06-17 1996-06-17 Coating material for fried food and fried food using the coating material and frozen food of fried food for re-heating with microwave oven by using the same

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JPH1065A true JPH1065A (en) 1998-01-06

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JP8155547A Pending JPH1065A (en) 1996-06-17 1996-06-17 Coating material for fried food and fried food using the coating material and frozen food of fried food for re-heating with microwave oven by using the same

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000028503A (en) * 1998-10-31 2000-05-25 박규홍 Fries powder for fried chicken
DE10054450A1 (en) * 2000-09-06 2002-03-28 Guillermo Pasch Alonso Modification of cereal products, such as flour to make them more suitable for a wide range of foods and animal feeds, is by interaction with chitosan
CN115152975A (en) * 2022-06-28 2022-10-11 东北农业大学 Method for reducing oil content in fried food by chitosan edible coating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000028503A (en) * 1998-10-31 2000-05-25 박규홍 Fries powder for fried chicken
DE10054450A1 (en) * 2000-09-06 2002-03-28 Guillermo Pasch Alonso Modification of cereal products, such as flour to make them more suitable for a wide range of foods and animal feeds, is by interaction with chitosan
CN115152975A (en) * 2022-06-28 2022-10-11 东北农业大学 Method for reducing oil content in fried food by chitosan edible coating

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