JPH1046495A - Coated paper for printing and its production - Google Patents

Coated paper for printing and its production

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Publication number
JPH1046495A
JPH1046495A JP8212174A JP21217496A JPH1046495A JP H1046495 A JPH1046495 A JP H1046495A JP 8212174 A JP8212174 A JP 8212174A JP 21217496 A JP21217496 A JP 21217496A JP H1046495 A JPH1046495 A JP H1046495A
Authority
JP
Japan
Prior art keywords
pulp
paper
enzyme
printing
coated paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8212174A
Other languages
Japanese (ja)
Inventor
Yosuke Uchida
洋介 内田
Tetsuya Hirabayashi
哲也 平林
Makoto Iwasaki
誠 岩崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
New Oji Paper Co Ltd
Original Assignee
Oji Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oji Paper Co Ltd filed Critical Oji Paper Co Ltd
Priority to JP8212174A priority Critical patent/JPH1046495A/en
Publication of JPH1046495A publication Critical patent/JPH1046495A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To obtain a coated paper for printing, excellent in dimensional stability and blister resistance, comprising a specific wt.% based on the whole pulp amount of a pulp which is treated with an enzyme having xylan decomposing activity but not filter paper decomposing activity and then bleached by a multi- stage method. SOLUTION: A pulp comprising 60-100wt.% based on the absolute dry weight of the whole pulp of a bleached pulp which is obtained by treating a pulp with an enzyme having xylan decomposing activity but not filter paper decomposing activity and bleaching the treated pulp by a multi-stage method is made into a base paper by using a gap former paper machine. The base paper is coated with a coating solution consisting essentially of a pigment such as ground calcium carbonate or kaolin and an adhesive such as a styrene/butadiene copolymer latex by a blade coater, etc., to give the objective coated paper for printing.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、印刷用塗被紙およ
びその製造方法に関する。更に詳しく述べれば、本発明
は寸法安定性が高く、かつ耐ブリスター性に優れた印刷
用塗被紙を高速で製造する方法に関する。
[0001] The present invention relates to a coated paper for printing and a method for producing the same. More specifically, the present invention relates to a method for producing a coated printing paper having high dimensional stability and excellent blister resistance at high speed.

【0002】[0002]

【従来の技術】近年、出版、広告、宣伝等の媒体として
の印刷物の重要性が再認識され、その基体となる印刷用
塗被紙の需要が増えてきている。その一方で、印刷物の
ビジュアル化やカラー化のために印刷用塗被紙に対する
品質面での要求も年々高くなってきている。このような
状況に対応するためには、印刷用塗被紙の高速抄紙化と
高品質化の双方を実現化することが求められるが、印刷
用塗被紙の抄造においてはこの二つの要求を両立するこ
とは困難であるとされてきた。
2. Description of the Related Art In recent years, the importance of printed matter as a medium for publishing, advertising, advertising, and the like has been re-recognized, and the demand for coated printing paper as a base material has been increasing. On the other hand, quality requirements for coated paper for printing for visualization and colorization of printed matter are increasing year by year. In order to cope with such a situation, it is necessary to realize both high-speed papermaking and high quality printing coated paper, but these two requirements are met in papermaking of printing coated paper. Compatibility has been considered difficult.

【0003】抄紙速度の高速化に伴って、抄紙機の脱水
能力が強化され、このような抄紙機で原紙を製造した場
合には原紙中の微細繊維が表層に偏在し、原紙の層間強
度が弱くなる傾向にある。これを基紙として印刷用塗被
紙を製造した場合には、印刷時において「ブリスター」
と呼ばれる塗工層が膨れ上がる印刷不良を起こしやすく
なり、重大な欠陥製品となる場合がある。一般に、この
種の問題を解決するために、原紙の抄紙工程において紙
力増強剤、とりわけカチオン化澱粉を添加、あるいは増
添して原紙の層間強度を改善する方法が用いられる。し
かしながら、このような紙力増強剤の添加量を多くして
内添した場合には、原紙の層間強度は向上するものの、
透気性が低下するために、場合によってはブリスターが
逆に起こりやすくなるといった問題があった。
[0003] As the papermaking speed is increased, the dewatering ability of the papermaking machine is enhanced. When the basepaper is manufactured by such a papermaking machine, the fine fibers in the base paper are unevenly distributed on the surface layer, and the interlayer strength of the base paper is reduced. It tends to be weak. When printing coated paper is manufactured using this as a base paper, "blister"
, The coating layer is liable to cause a printing failure in which the coating layer swells, which may be a serious defective product. Generally, in order to solve this kind of problem, a method of improving or improving the interlayer strength of a base paper by adding or adding a paper strength enhancer, particularly a cationized starch, in a papermaking process of the base paper is used. However, when the addition amount of such a paper strength enhancer is added internally, although the interlayer strength of the base paper is improved,
There is a problem that blisters are liable to occur in some cases due to a decrease in air permeability.

【0004】また、紙力増強剤を外添しようとした場合
には、前記のように原紙表層に微細繊維が局在化するた
めに原紙内部まで紙力増強剤が浸透せず、この方法もブ
リスターの防止には有効な手段とはならなかった。一
方、パルプの叩解度を上げてパルプの繊維間結合力を高
めることによって原紙の層間強度を向上させた場合に
は、対ブリスター性は向上するものの、原紙の寸法安定
性が悪化し、また、パルプろ水度の低下により操業性も
悪化するという問題点があった。
[0004] Further, when the paper strength enhancer is externally added, since the fine fibers are localized in the surface layer of the base paper as described above, the paper strength enhancer does not penetrate into the base paper. It was not an effective measure to prevent blisters. On the other hand, when the interlaminar strength of the base paper is improved by increasing the degree of pulp beating to increase the fiber-to-fiber bonding strength, the blister resistance is improved, but the dimensional stability of the base paper is deteriorated. There was a problem that the operability deteriorated due to the decrease in pulp freeness.

【0005】近年、酵素をリグノセルロース材料及びリ
グノセルロースを加工して得られる繊維に作用させてそ
れらを改質する技術が多数提案されてきている。例え
ば、特公平2−20756号公報、特開平1−9249
0号公報、特公平3−4672号公報、特開平6−16
6978号公報、特開平6−316899号公報、特開
平7−279078号公報、特開平7−331588号
公報等に開示されているような、叩解性の改良やパルプ
繊維の改質等を目的として、叩解前のパルプ繊維にセル
ラーゼを添加する方法、特開平2−6681号公報、特
開平2−229291号公報、特開平3−124891
号公報等に開示されているようなワイヤー上でのろ水性
を改善するため、叩解して薬品を添加後の紙料にセルラ
ーゼやヘミセルラーゼ等の酵素を添加する方法等があ
る。また、特開平2−264087号公報、特開平2−
293486号公報、特開平6−101185号公報、
特開平6−207390号公報等に開示されているよう
に、漂白前にパルプ繊維をセルラーゼやヘミセルラーゼ
等の酵素で処理することにより、漂白性を改善する方法
も知られている。特開平8−49187号公報には、パ
ルプを酵素処理することにより、オフセット印刷用塗工
紙の耐ブリスター性と耐折れ割れ性が改善されることが
開示されている。
In recent years, many techniques have been proposed for modifying enzymes by acting on lignocellulosic materials and fibers obtained by processing lignocellulose. For example, Japanese Patent Publication No. 2-20756, JP-A-1-9249.
No. 0, Japanese Patent Publication No. 3-4672, Japanese Patent Laid-Open No. 6-16
6978, JP-A-6-316899, JP-A-7-279078, JP-A-7-331588 and the like for the purpose of improving beating properties and modifying pulp fibers. A method of adding cellulase to pulp fibers before beating, JP-A-2-6681, JP-A-2-229291, JP-A-3-1244891.
In order to improve the drainage on a wire as disclosed in Japanese Patent Application Laid-Open Publication No. H10-163, there is a method in which an enzyme such as cellulase or hemicellulase is added to the stock after beating and adding a chemical. In addition, Japanese Patent Application Laid-Open Nos.
293486, JP-A-6-101185,
As disclosed in JP-A-6-207390 and the like, a method of improving bleachability by treating pulp fibers with an enzyme such as cellulase or hemicellulase before bleaching is also known. JP-A-8-49187 discloses that the pulp is treated with an enzyme to improve the blister resistance and the break resistance of the coated paper for offset printing.

【0006】[0006]

【発明が解決しようとする課題】本発明者らは、耐ブリ
スター性に優れ、かつ寸法安定性に優れた印刷用塗被紙
を高速で製造する方法についてパルプの酵素処理を種々
検討を重ねたところ、パルプ処理に用いる酵素の種類に
よっては、オフセット印刷用塗工紙の寸法安定性を悪化
させるという問題があることを見出した。そこで本発明
者らはさらに詳細にパルプの酵素処理について検討した
ところ、ろ紙分解活性を有さない酵素でパルプを処理す
ることにより、原紙の寸法安定性に悪影響を及ぼすこと
なく、耐ブリスター性を改善できることを見出した。さ
らに、多段漂白前のパルプをろ紙分解活性を有さずキシ
ラン分解活性を有する酵素で処理し、次いで多段漂白す
れば、目的の白色度まで漂白するのに要する漂白薬品を
低減できるので、漂白工程でのパルプ繊維の損傷を最低
限に抑制することができ、その結果、原紙の寸法安定性
が向上することを見い出し、本発明に至った。本発明の
目的は、ろ紙分解活性を有さず、キシラン分解活性を有
する酵素で処理し、次いで多段漂白した漂白パルプを原
紙に使用することにより、耐ブリスター性に優れ、かつ
寸法安定性に優れた印刷用塗被紙を高速で製造すること
にある。
DISCLOSURE OF THE INVENTION The present inventors have conducted various studies on pulp enzymatic treatment for a method for producing a printing coated paper excellent in blister resistance and dimensional stability at high speed. However, it has been found that there is a problem that the dimensional stability of the coated paper for offset printing is deteriorated depending on the type of the enzyme used for the pulp treatment. Therefore, the present inventors examined the enzyme treatment of pulp in more detail.By treating the pulp with an enzyme having no filter paper decomposing activity, the blister resistance was improved without adversely affecting the dimensional stability of the base paper. I found that it can be improved. Further, if the pulp before multi-stage bleaching is treated with an enzyme having xylan-decomposing activity without filter paper-decomposing activity and then multi-stage bleaching, the bleaching chemicals required for bleaching to the desired whiteness can be reduced. It has been found that the damage of the pulp fiber can be suppressed to a minimum, and as a result, the dimensional stability of the base paper is improved, leading to the present invention. It is an object of the present invention to provide blister resistance and dimensional stability by using a bleached pulp that has no filter paper decomposing activity and is treated with an enzyme having xylan decomposing activity and then multi-bleached for base paper. To produce coated printing paper at high speed.

【0007】[0007]

【課題を解決するための手段】本発明の第一は、原紙に
顔料と接着剤を主成分とする塗工層を設ける印刷用塗被
紙において、原紙を構成するパルプとして、ろ紙分解活
性を有さず、キシラン分解活性を有する酵素による処理
を施し、次いで多段漂白した漂白パルプを少なくとも一
種類使用することを特徴とする印刷用塗被紙およびその
製造方法である。
SUMMARY OF THE INVENTION The first aspect of the present invention is to provide a coated paper for printing in which a base paper is provided with a coating layer containing a pigment and an adhesive as a main component. A coated paper for printing, characterized by using at least one kind of bleached pulp which has not been subjected to a treatment with an enzyme having xylan-decomposing activity and then is multi-bleached.

【0008】本発明の第二は、原紙を構成するパルプと
して、前記漂白パルプを原紙を構成する全パルプの絶乾
重量あたり60〜100重量%含有させることを特徴と
する請求項1記載の印刷用塗被紙およびその製造方法で
ある。本発明の第三は、ギャップフォーマー抄紙機を用
いて、原紙を抄造することを特徴とする請求項1および
請求項2記載の印刷用塗被紙およびその製造方法であ
る。
A second aspect of the present invention is the printing method according to claim 1, wherein the bleached pulp is contained in the pulp constituting the base paper in an amount of 60 to 100% by weight based on the absolute dry weight of all the pulp constituting the base paper. Coated paper and a method for producing the same. A third aspect of the present invention is a coated paper for printing according to claims 1 and 2, wherein the base paper is made using a gap former paper machine, and a method for producing the same.

【0009】[0009]

【発明の実施の形態】本発明に使用されるパルプの原料
としては、広葉樹材、針葉樹材、或いは非木材から選ぶ
ことができるが、印刷用塗被紙の原紙には良好な地合が
望まれるため、繊維長が短く、かつ繊維幅の小さなパル
プが得られる広葉樹材が好ましく使用される。
BEST MODE FOR CARRYING OUT THE INVENTION The raw material of the pulp used in the present invention can be selected from hardwood, softwood, and non-wood, but a good formation is desired for the base paper of the coated paper for printing. Therefore, hardwoods that can obtain pulp having a short fiber length and a small fiber width are preferably used.

【0010】本発明に使用されるパルプの蒸解法として
は、クラフト蒸解、サルファイト蒸解、ポリサルファイ
ド蒸解、ソーダ蒸解等の公知の蒸解法を使用することが
できるが、パルプ品質、エネルギー効率等を考慮した場
合には、クラフト蒸解およびポリサルファイド蒸解が好
適に用いられる。蒸解液の硫化度は5〜75%、好まし
くは5〜50%であり、有効アルカリ添加率は絶乾木材
重量当たり5〜30重量%、好ましくは10〜25重量
%の範囲である。
As the pulp cooking method used in the present invention, known cooking methods such as kraft cooking, sulfite cooking, polysulfide cooking, and soda cooking can be used, but pulp quality, energy efficiency and the like are taken into consideration. If so, kraft cooking and polysulfide cooking are preferably used. The degree of sulfidation of the cooking liquor is 5 to 75%, preferably 5 to 50%, and the effective alkali addition rate is in the range of 5 to 30% by weight, preferably 10 to 25% by weight, based on the weight of the dried wood.

【0011】蒸解に際して、使用する蒸解液に蒸解助剤
として、公知の環状ケト化合物、例えばベンゾキノン、
ナフトキノン、アントラキノン、アントロン、フェナン
トロキノン及び前記キノン系化合物のアルキル、アミノ
等の核置換体、或いは前記キノン系化合物の還元型であ
るアントラヒドロキノンのようなヒドロキノン系化合
物、更にはディールスアルダー法によるアントラキノン
合成法の中間体として得られる安定な化合物である9,
10−ジケトヒドロアントラセン化合物等から選ばれた
1種或いは2種以上を添加することもできる。その場合
の添加率は木材チップ絶乾重量当たり0.001〜1.
0重量%である。
In the cooking, a known cyclic keto compound such as benzoquinone,
Naphthoquinone, anthraquinone, anthrone, phenanthroquinone and alkyl-substituted products such as alkyl and amino of the quinone-based compound, or hydroquinone-based compounds such as anthrahydroquinone which is a reduced form of the quinone-based compound, and further anthraquinone by the Diels-Alder method A stable compound obtained as an intermediate in the synthesis method,
One or more selected from 10-diketohydroanthracene compounds and the like can be added. In this case, the addition rate is 0.001-1.
0% by weight.

【0012】公知の蒸解法により得られた未晒パルプ
は、洗浄、粗選及び精選工程を経て、多段漂白を行う前
に、ろ紙分解活性を有さずキシラン分解活性を有する酵
素で処理される。しかしながら、酵素の至適pH、至適
温度を考慮した場合には、未晒パルプを酸素脱リグニン
した後に酵素処理を行うのが好適である。本発明に使用
される酵素は、ろ紙分解活性が悪く、キシラン分解活性
を有する酵素である。ろ紙分解活性を有さず、キシラン
分解活性を有する酵素であれば、マンナン、ペクチナン
等の分解活性を有していても特に問題はない。しかしな
がら、ろ紙分解活性を有する場合には、原紙の寸法安定
性が悪化する場合があるため、適さない。
The unbleached pulp obtained by the known digestion method is subjected to washing, roughing and fine-selection steps, and before being subjected to multi-stage bleaching, treated with an enzyme having no filter paper-decomposing activity and having xylan-decomposing activity. . However, in consideration of the optimum pH and the optimum temperature of the enzyme, it is preferable to carry out the enzyme treatment after the unbleached pulp is subjected to oxygen delignification. The enzyme used in the present invention is an enzyme having poor filter paper decomposition activity and having xylan decomposition activity. As long as the enzyme does not have the filter paper decomposing activity and has the xylan decomposing activity, there is no particular problem even if it has the decomposing activity of mannan, pectinan and the like. However, if the filter paper has a filter paper decomposing activity, the dimensional stability of the base paper may be deteriorated, which is not suitable.

【0013】ろ紙分解活性が無く、キシラン分解活性を
有する酵素でパルプを処理した場合には、パルプの表面
或いはパルプ繊維中に遍在するキシランが選択的に分解
され、パルプはセルロース骨格を保持したまま多孔性と
なるので、このようなパルプを原紙に用いた場合には、
紙力増強剤の浸透性が改善されて原紙の層間強度が向上
すると同時に、原紙の透気性も向上するため、耐ブリス
ター性は改善されるものと思われる。一方、酵素処理に
よりパルプの主要骨格であるセルロースはほとんど作用
を受けないので、原紙の寸法安定性は維持される。
When pulp is treated with an enzyme having no xylan-decomposing activity without filter paper-decomposing activity, xylan ubiquitously present on the pulp surface or in pulp fibers is selectively decomposed, and the pulp retains a cellulose skeleton. Since it becomes porous as it is, when such pulp is used for base paper,
It is thought that the blister resistance is improved because the permeability of the paper strength enhancer is improved and the interlayer strength of the base paper is improved, and the air permeability of the base paper is also improved. On the other hand, cellulose, which is the main skeleton of pulp, is hardly affected by the enzyme treatment, and thus the dimensional stability of the base paper is maintained.

【0014】本発明に用いられる酵素は、これを生産す
る微生物、菌体、バクテリア等を培養することによって
採取される。更に、これらの変異株、或いは酵素の生産
を増大させるために遺伝子工学によって製造された菌
株、即ち組替え体菌株から採取しても良い。又、前記酵
素は培養液中に生産されたままのものでも良く、その濃
縮混合物、或いはその乾燥調製物のいずれから製造され
た物であっても良い。前記酵素は、キシラン分解活性と
して、0.1〜10U/絶乾パルプg、好ましくは0.
5〜5U/絶乾パルプgの範囲でパルプに対し添加され
る。ここに、1Uとは、酵素をキシランに作用させた場
合に、1分間に1μモルのキシロースを生成する酵素量
のことをいう。酵素の添加量がキシラン分解活性として
0.1U/絶乾パルプg未満では、パルプからのキシラ
ンの溶出が不十分なため効果が不十分であり、10U/
絶乾パルプgを超えた場合には、酵素処理工程でのパル
プの歩留まりが低下し、コスト高となるため経済的では
ない。
The enzyme used in the present invention is collected by culturing microorganisms, cells, bacteria, and the like that produce the enzyme. Furthermore, these mutants or strains produced by genetic engineering to increase the production of enzymes, ie, recombinant strains, may be collected. Further, the enzyme may be as produced in a culture solution, or may be a concentrated mixture thereof, or a product prepared from a dried preparation thereof. The enzyme has a xylan-decomposing activity of 0.1 to 10 U / g of absolutely dried pulp, preferably 0.1 to 10 U / g.
It is added to the pulp in the range of 5 to 5 U / g of absolutely dry pulp. Here, 1 U means the amount of enzyme that produces 1 μmol xylose per minute when the enzyme is allowed to act on xylan. When the amount of the enzyme added is less than 0.1 U / g of absolutely dried pulp as xylan-decomposing activity, the effect is insufficient due to insufficient elution of xylan from the pulp.
If the absolute pulp exceeds g, the yield of the pulp in the enzyme treatment step is reduced, and the cost is increased, which is not economical.

【0015】酵素処理は、パルプ濃度が1〜20重量
%、好ましくは2〜15重量%の範囲で行われる。パル
プ濃度が1重量%未満では、処理に大容量の設備を要す
るので適さない。パルプ濃度が20重量%を超えると、
パルプと酵素を均一に混合し難くなるので酵素処理の効
果が十分得られない。酵素と含水状態のパルプとの均一
な混合は、低濃度ミキサー、中濃度ミキサー、スタティ
ックミキサー、高濃度ミキサー等の中ら処理時のパルプ
濃度に応じて適宜選択され行われる。
The enzyme treatment is carried out at a pulp concentration of 1 to 20% by weight, preferably 2 to 15% by weight. If the pulp concentration is less than 1% by weight, the treatment requires a large-capacity facility and is not suitable. When the pulp concentration exceeds 20% by weight,
Since it is difficult to mix the pulp and the enzyme uniformly, the effect of the enzyme treatment cannot be sufficiently obtained. The uniform mixing of the enzyme and the pulp in the water-containing state is appropriately selected and performed depending on the pulp concentration during the middle treatment such as a low-concentration mixer, a medium-concentration mixer, a static mixer, or a high-concentration mixer.

【0016】パルプを酵素で処理する時の温度は30〜
80℃、好ましくは40〜60℃の範囲である。温度が
30℃未満では、酵素のキシラン分解活性が低下し処理
効果が不十分となる上、そのような低い温度を得ること
は、蒸解後、あるいは酸素脱リグニン後の高い温度のパ
ルプを冷却しなければならず、しかもその後の多段漂白
の最初の漂白段の温度にまで加熱する必要があり、エネ
ルギーを無駄にすることになり得策ではない。一方、温
度が80℃を超えて高くなると、通常の酵素の場合に
は、酵素自体が変性し、不活性になるので適さない。
The temperature at which the pulp is treated with the enzyme is 30 to
80 ° C, preferably in the range of 40-60 ° C. If the temperature is lower than 30 ° C., the xylan decomposition activity of the enzyme is reduced and the treatment effect is insufficient, and such a low temperature is obtained by cooling the high temperature pulp after digestion or after oxygen delignification. It must be heated to the temperature of the first bleaching stage of the subsequent multi-stage bleaching, which wastes energy and is not a viable option. On the other hand, if the temperature is higher than 80 ° C., it is not suitable for a normal enzyme because the enzyme itself is denatured and becomes inactive.

【0017】処理時のパルプ液或いはパルプに含まれる
溶液のpHは3〜10、好ましくは5〜9の範囲であ
る。pHの調整が必要な場合は、任意の酸性溶液又はア
ルカリ性溶液を添加して調整する。前記のpH調整用に
用いられる溶液は、多段漂白工程で発生する活性塩素を
含まない排水を利用できることはいうまでもない。ま
た、パルプスラリーに二酸化炭素等の排ガスを吹き込む
ことによってpHを調整することもできる。処理時間は
10分間以上、好ましくは30〜180分間であるが、
時間については特に限定されない。前記酵素処理は、前
記したように、蒸解後、あるいは酸素脱リグニン工程に
次いで洗浄した後に行われる。しかしながら、この酵素
処理は、次いで行われる多段漂白の途中、或いは多段漂
白の最終段で、本発明の目的を損なわない範囲で複数回
繰り返し行っても良い。
The pH of the pulp solution or the solution contained in the pulp during the treatment is in the range of 3 to 10, preferably 5 to 9. When the pH needs to be adjusted, the pH is adjusted by adding an arbitrary acidic solution or alkaline solution. It goes without saying that the solution used for adjusting the pH can use wastewater containing no active chlorine generated in the multi-stage bleaching step. The pH can also be adjusted by blowing exhaust gas such as carbon dioxide into the pulp slurry. The processing time is 10 minutes or more, preferably 30 to 180 minutes.
The time is not particularly limited. As described above, the enzyme treatment is performed after cooking or after washing after the oxygen delignification step. However, this enzymatic treatment may be repeated a plurality of times during the subsequent multi-stage bleaching or at the final stage of the multi-stage bleaching without impairing the object of the present invention.

【0018】本発明で用いられる多段漂白工程は、塩素
(C)、苛性ソーダ(E)、次亜塩素酸塩(H)、二酸
化塩素(D)、酸素(O)、過酸化水素(P)、オゾン
(Z)、有機過酸等の公知の漂白薬品を用いる公知の漂
白シーケンス、例えばC−E−H−D、C/D−Eo−
H−D、D−Eop−D、D−E−D等が適宜組み合わ
せて使用されるが、本発明の効果は多段漂白工程におけ
る漂白薬品の組み合わせには特に影響を受けないので、
特に限定するものではない。
The multi-stage bleaching step used in the present invention comprises chlorine (C), caustic soda (E), hypochlorite (H), chlorine dioxide (D), oxygen (O), hydrogen peroxide (P), A known bleaching sequence using a known bleaching chemical such as ozone (Z), organic peracid, etc., for example, CEHD, C / D-Eo-
HD, D-Eop-D, DED, etc. are used in appropriate combination, but the effects of the present invention are not particularly affected by the combination of bleaching chemicals in the multi-stage bleaching step.
There is no particular limitation.

【0019】本発明の目的を活性するためには、以上に
記載したような処理を施されたパルプが塗被紙を構成す
る全パルプの少なくとも60重量%以上を占める必要が
ある。60重量%未満の場合には、パルプ繊維としての
改質効果の発現が不十分となり、十分な効果が得られな
い。原紙を構成する他のパルプとしては、本発明に記載
の処理を施されていない晒クラフトパルプ、機械パル
プ、脱墨パルプ等が挙げられ、本発明の効果を損なわな
い範囲で適宜組み合わせて使用される。
In order to activate the object of the present invention, it is necessary that the pulp treated as described above accounts for at least 60% by weight or more of the total pulp constituting the coated paper. If the amount is less than 60% by weight, the pulp fiber will not have sufficient modifying effect, and will not have sufficient effect. Other pulp constituting the base paper includes bleached kraft pulp, mechanical pulp, deinked pulp, etc., which have not been subjected to the treatment described in the present invention, and are used in an appropriate combination as long as the effects of the present invention are not impaired. You.

【0020】前記酵素処理されたパルプは単独で或いは
他のパルプと混合されて、シングルディスクレフィナ
ー、ダブルディスクレフィナー、ビーター等の叩解機に
より叩解されて用いられる。印刷用塗被紙の品質、強
度、あるいは製造時の操業性を考慮した場合には、カナ
ダ標準ろ水度で示される値が550〜300mlの範囲
になるように叩解して前記酵素処理されたパルプを用い
るのが好適である。
The enzyme-treated pulp is used alone or mixed with other pulp and beaten by a beater such as a single disc refiner, a double disc refiner, or a beater. In consideration of the quality, strength, or operability of the coated paper for printing, the enzyme treatment was performed by beating so that the value indicated by the Canadian standard freeness was in the range of 550 to 300 ml. It is preferred to use pulp.

【0021】前記酵素処理され、叩解されたパルプは公
知の抄紙機にて抄紙されるが、その抄紙条件は特に規定
されるものではない。しかしながら、高速抄紙を考慮し
た場合には、ギャップフォーマーを有する抄紙機が好適
に用いられる。また、タルク、カオリン、重質炭酸カル
シウム、軽質炭酸カルシウム等の填料の他に、一般に使
用される各種のアニオン性、ノニオン性、カチオン性あ
るいは両性の歩留まり向上剤、ろ水性向上剤、紙力増強
剤や内添サイズ剤等の抄紙用内添助剤が必要に応じて使
用される。さらに、染料、蛍光増白剤、pH調整剤、消
泡剤、ピッチコントロール剤、スライムコントロール剤
等も必要に応じて添加される。
The pulp treated with the enzyme and beaten is subjected to papermaking by a known papermaking machine, but the papermaking conditions are not particularly limited. However, in consideration of high speed papermaking, a paper machine having a gap former is preferably used. In addition to fillers such as talc, kaolin, heavy calcium carbonate, and light calcium carbonate, various commonly used anionic, nonionic, cationic or amphoteric retention improvers, drainage improvers, and paper strength enhancement An internal additive for papermaking, such as an agent or an internal sizing agent, is used as needed. Further, a dye, a fluorescent whitening agent, a pH adjuster, an antifoaming agent, a pitch control agent, a slime control agent and the like are added as required.

【0022】こうして得られた原紙に、各種サイズプレ
ス或いはロールコーターで澱粉等の天然接着剤やPVA
等の合成接着剤を用いてサイズ処理を行うことは勿論可
能であるが、製造速度の高速化を考慮した場合には、フ
ィルムメタリングタイプのサイズプレス装置を用いて糊
の固形濃度を高くしてサイズプレス処理を行う方法が好
適に用いられる。また、ロールコーター、ブレードコー
ター等で予備塗工を行うことはもちろん可能である。
The base paper thus obtained is applied to a natural adhesive such as starch or PVA by various size presses or roll coaters.
It is of course possible to perform sizing using a synthetic adhesive such as, but in consideration of speeding up the production speed, use a film metaling type size press to increase the solid concentration of the glue. A method of performing a size press process is preferably used. In addition, it is of course possible to perform preliminary coating with a roll coater, a blade coater, or the like.

【0023】本発明で使用される塗被組成物の主成分の
一つである顔料としては、例えばクレー、カオリン、水
酸化アルミニウム、炭酸カルシウム、二酸化チタン、硫
酸バリウム、酸化亜鉛、サチンホワイト、硫酸カルシウ
ム、タルク、プラスチックピグメント等の通常の汎用顔
料の内の一種以上を任意に選択し配合することができ
る。
Examples of the pigment which is one of the main components of the coating composition used in the present invention include clay, kaolin, aluminum hydroxide, calcium carbonate, titanium dioxide, barium sulfate, zinc oxide, satin white, and sulfuric acid. One or more of common general-purpose pigments such as calcium, talc and plastic pigment can be arbitrarily selected and blended.

【0024】また、接着剤としては、例えばスチレン−
ブタジエン共重合体、メチルメタアクリレート−ブタジ
エン共重合体等の共役ジエン系共重合体ラテックス、ア
クリル酸エステルおよび/またはメタクリル酸エステル
の重合体または共重合体等のアクリル系重合体ラテック
ス、エチレン−酢酸ビニル共重合体等のビニル系重合体
ラテックス、あるいはこれらの各種重合体ラテックス、
カルボキシル基等の官能基含有単量体で変性したアルカ
リ部分溶解性あるいはアルカリ非溶解性の重合体ラテッ
クスを用いることができる。
As the adhesive, for example, styrene-
Conjugated diene copolymer latex such as butadiene copolymer, methyl methacrylate-butadiene copolymer, acrylic polymer latex such as acrylate and / or methacrylate polymer or copolymer, ethylene-acetic acid Vinyl-based polymer latex such as vinyl copolymer, or these various polymer latexes,
An alkali partially soluble or alkali insoluble polymer latex modified with a functional group-containing monomer such as a carboxyl group can be used.

【0025】また、合成接着剤と併用する水溶性接着剤
としては、例えばカチオン化澱粉、酸化澱粉、酵素変性
澱粉、熱化学変性澱粉、エーテル化澱粉、エステル化澱
粉、冷水可溶澱粉等の澱粉類、カルボキシメチルセルロ
ース、ヒドロキシメチルセルロース等のセルロース類、
ポリビニルアルコール、オレフィン−無水マレイン酸樹
脂などの水溶性合成接着剤等、任意に選択し使用するこ
とができる。これらの顔料および接着剤には、分散剤、
耐水化剤、流動性変性化剤、着色剤、蛍光増白剤等の各
種添加剤を必要に応じて添加することができる。
Examples of the water-soluble adhesive used in combination with the synthetic adhesive include starch such as cationized starch, oxidized starch, enzyme-modified starch, thermochemically-modified starch, etherified starch, esterified starch, and cold-water-soluble starch. , Carboxymethylcellulose, celluloses such as hydroxymethylcellulose,
Water-soluble synthetic adhesives such as polyvinyl alcohol and olefin-maleic anhydride resin can be arbitrarily selected and used. These pigments and adhesives include dispersants,
Various additives such as a waterproofing agent, a fluidity modifying agent, a coloring agent, and a fluorescent whitening agent can be added as needed.

【0026】塗被層の塗工は、一般の塗被紙の製造に用
いられる塗工装置、例えばブレードコーター、エアーナ
イフコーター、ロールコーター、リバースロールコータ
ー、バーコーター、カーテンコーター、ダイスロットコ
ーター、グラビアコーター、チャンブレックスコータ
ー、サイズプレスコーター等の塗工装置を設けたオンマ
シンあるいはオフマシンコーターによって、基紙上に片
面か両面に一層あるいは多層に塗工される。その際の塗
被組成物の固形濃度は、一般に40〜75重量%程度で
あるが、操業性を考慮すると45〜70重量%の範囲が
好ましい。また、カレンダー仕上げの方法は、グロスあ
るいはマットカレンダーとして、例えばスーパーカレン
ダー、グロスカレンダー、ソフトコンパクトカレンダー
等の金属またはドラムと弾性ロールよりなる各種カレン
ダーが、オンマシンまたはオフマシンで任意に選択し使
用できる。
The coating of the coating layer is performed by using a coating apparatus used in the production of general coated paper, for example, a blade coater, an air knife coater, a roll coater, a reverse roll coater, a bar coater, a curtain coater, a die slot coater, One- or two-sided coating is performed on one or both sides of the base paper by an on-machine or off-machine coater provided with a coating device such as a gravure coater, a Chambers coater, or a size press coater. The solid concentration of the coating composition at that time is generally about 40 to 75% by weight, but preferably 45 to 70% by weight in consideration of operability. In addition, the calendering method may be any of a variety of calenders such as a super calender, a gloss calender, a soft compact calender, or a metal or a drum and an elastic roll. .

【0027】[0027]

【実施例】以下に実施例を挙げて本発明をより具体的に
説明するが、本発明はこれらにより限定されるものでは
ない。以下の実施例及び比較例中の%は、特に断らない
限り重量%を示す。 実施例1 (パルプの製造)国内産広葉樹チップ70%、ユーカリ
材30%からなる混合広葉樹チップを原料として、クラ
フト蒸解によりカッパー価20.1、パルプ粘度41.
0cpsの未晒パルプを得た。次いで、酸素脱リグニン
を行い、カッパー価9.6、パルプ粘度:25.1cp
sの酸素脱リグニン処理パルプを得た。酸素脱リグニン
処理後のパルプをディフュージョンウォッシャー1段と
ドラムウォッシャー1段で洗浄し、洗浄後のパルプ濃度
を10%に調整した後、希硫酸を加えてpH8.0に調
整し、次いでろ紙分解活性を有さずキシラン分解活性を
有する酵素(商品名:パルプザイムHC、ノボノルディ
スク社製)を2U/絶乾パルプg添加した後、60℃で
90分処理した。更に、この酵素処理後のパルプをC−
E−H−Dの漂白シーケンスで表1に示した条件で多段
漂白を行い、洗浄し、ハンター白色度85.2%の広葉
樹晒クラフトパルプを製造して高濃度貯蔵タンクへ貯蔵
した。
The present invention will be described more specifically with reference to the following examples, but the present invention is not limited to these examples. % In the following Examples and Comparative Examples indicates% by weight unless otherwise specified. Example 1 (Manufacture of pulp) A mixed hardwood chip composed of 70% of domestic hardwood chips and 30% of eucalyptus wood was used as a raw material to obtain a kappa number of 20.1 and a pulp viscosity of 41.
An unbleached pulp of 0 cps was obtained. Next, oxygen delignification was performed to obtain a kappa number of 9.6 and a pulp viscosity of 25.1 cp.
s of oxygen delignified pulp was obtained. The pulp after the oxygen delignification treatment is washed with one stage of a diffusion washer and one stage of a drum washer, the pulp concentration after the washing is adjusted to 10%, and the pH is adjusted to 8.0 by adding dilute sulfuric acid. After adding 2 U / g of absolutely dry pulp having no xylan-decomposing activity (trade name: Pulpzyme HC, manufactured by Novo Nordisk), the mixture was treated at 60 ° C. for 90 minutes. Further, the pulp after the enzyme treatment is C-
In the EHD bleaching sequence, multi-stage bleaching was performed under the conditions shown in Table 1, washed, and hardwood bleached kraft pulp having a Hunter brightness of 85.2% was produced and stored in a high concentration storage tank.

【0028】[0028]

【表1】 [Table 1]

【0029】(塗被用原紙の製造)前記広葉樹晒クラフ
トパルプ100%からなる濃度4%のパルプスラリーを
ダブルディスクリファイナーを用いてカナダ標準ろ水度
が500mlとなるように叩解した。叩解後のパルプス
ラリーに、填料としてタルクを紙灰分が9%になるよう
に添加し、更に内添サイズ剤としてロジンサイズ剤(商
品名:サイズバインE、荒川化学社製)0.7%及び硫
酸アルミニウム2%を絶乾パルプ重量当たり添加し紙料
を調成し、この紙料を用いて長網抄紙機にて速度110
0m/分で抄紙し、更に2本ロールサイズプレス装置
で、5%濃度の酸化澱粉(商品名:エースA、王子コー
ンスターチ社製)液を2g/m2 塗布、乾燥し、米坪量
55g/m2 の印刷塗被紙用原紙を製造した。
(Production of base paper for coating) A pulp slurry having a concentration of 4% composed of 100% bleached hardwood kraft pulp was beaten using a double disc refiner to a Canadian standard freeness of 500 ml. Talc was added as a filler to the beaten pulp slurry so that the paper ash content was 9%, and a rosin sizing agent (trade name: Size Vine E, manufactured by Arakawa Chemical Co.) was added as an internal sizing agent. A paper stock was prepared by adding 2% of aluminum sulfate to the weight of the absolutely dried pulp, and the stock was used to prepare a paper stock at a speed of 110 mm.
The paper was made at 0 m / min, and 2 g / m 2 of a 5% -concentrated oxidized starch (trade name: Ace A, manufactured by Oji Cornstarch Co., Ltd.) was applied and dried using a two-roll size press, and dried. and producing printed coated paper base paper for the m 2.

【0030】(塗被液の調製)重質炭酸カルシウム(商
品名:FMT−90/ファイマテック社製)25%とカ
オリン(商品名:アマゾン88/CADAM社製)75
%からなる顔料をコーレス分散機を用いて分散し、固形
分濃度72%の顔料スラリーを得た。このスラリーにス
チレン−ブタジエン共重合体ラテックス(商品名:SN
307、住友ダウ社製)を顔料重量当たり固形分で10
%、酸化澱粉(商品名:エースA、王子コーンスターチ
社製)を固形分で4%、その他の助剤を添加分散して固
形分濃度58%の塗被液を調製した。
(Preparation of coating liquid) 25% of heavy calcium carbonate (trade name: FMT-90 / manufactured by FIMATECH) and kaolin (trade name: Amazon 88 / manufactured by CADAM) 75
% Of the pigment was dispersed using a CORES disperser to obtain a pigment slurry having a solid content of 72%. A styrene-butadiene copolymer latex (trade name: SN)
307, manufactured by Sumitomo Dow) in solid content per pigment weight of 10
%, Oxidized starch (trade name: Ace A, manufactured by Oji Cornstarch Co., Ltd.) at a solid content of 4%, and other auxiliaries were added and dispersed to prepare a coating solution having a solid content concentration of 58%.

【0031】(塗被紙の製造)前記の印刷塗被紙用原紙
に前記の塗被液を用いて、片面18g/m2 となるよう
にブレードコーターで両面塗被を行った。得られた塗被
紙を金属すーる6本とコットンロール6本からなるオフ
マシーンスーパーカレンダーにニップ圧200kg/c
mで通紙し、王研式平滑度が表1100秒、裏1120
秒のオフセット印刷用塗被紙を製造した。
(Manufacture of Coated Paper) Both sides of the base paper for printing coated paper were coated with the above coating liquid using a blade coater so as to have a surface of 18 g / m 2 . A nip pressure of 200 kg / c was applied to an off-machine super calender comprising six coated metal sheets and six cotton rolls.
m, the Oken-type smoothness is 1100 seconds in the front and 1120 seconds in the back
A second coated paper for offset printing was produced.

【0032】品質評価するため、下記の試験方法を用
い、得られた酵素処理広葉樹晒クラフトパルプの単繊維
強度とオフセット印刷用塗被紙の水分伸縮率、及び耐ブ
リスター性を測定し、評価した。その結果を表4に示
す。
In order to evaluate the quality, the following test method was used to measure and evaluate the single fiber strength of the obtained enzyme-treated hardwood bleached kraft pulp, the moisture expansion / contraction ratio of the coated paper for offset printing, and the blister resistance. . Table 4 shows the results.

【0033】(1)単繊維強度の測定 TAPPI標準 T231cm−85に準拠し、パルプ
繊維のゼロスバン裂断長を測定し、単繊維強度の指標と
した。 (2)水分伸縮率の測定 相対湿度65%の条件下で幅30mmの塗被紙サンプル
をつかみ、間隔100mmで固定した後、5gの荷重下
で相対湿度を65%→20%→80%→65%に変化さ
せ、これを3回繰り返し、その時の寸法変化と水分含有
量の変化を測定し、測定値から寸法変化率と水分変化率
を算出し、下記(1)式から水分伸縮率を求めた。な
お、寸法変化は差動トランス変位計(商品名:MDE−
2、新光電子社製)を用いて0.01mmの精度で、水
分変化は電子天秤を用いて0.001gの精度で測定し
た。 水分伸縮率=寸法変化率(%)/水分変化率(%) ・・・・(1)
(1) Measurement of Single Fiber Strength In accordance with TAPPI standard T231cm-85, the zero-subban breaking length of pulp fibers was measured and used as an index of single fiber strength. (2) Measurement of moisture expansion / contraction ratio A coated paper sample having a width of 30 mm was gripped under the condition of a relative humidity of 65%, fixed at an interval of 100 mm, and the relative humidity was changed from 65% to 20% to 80% under a load of 5 g. 65%, this was repeated three times, the dimensional change and the change in water content at that time were measured, the dimensional change rate and the water change rate were calculated from the measured values, and the moisture expansion / contraction rate was calculated from the following equation (1). I asked. The dimensional change is measured by a differential transformer displacement meter (trade name: MDE-
2, manufactured by Shinko Electronics Co., Ltd.) with an accuracy of 0.01 mm, and the change in moisture was measured with an electronic balance with an accuracy of 0.001 g. Moisture expansion / contraction rate = dimensional change rate (%) / moisture change rate (%) (1)

【0034】(3)耐ブリスター性の測定 RI印刷機(明製作所製)でオフセット輪転印刷用イン
キ1mlを展開し、塗被紙サンプルの両面に印刷する。
印刷したサンプルを加温したシリコーンオイルに漬け、
発生するブリスターの様子を目視で観察し、次の評価基
準で評価した。 評価基準 ◎・・・ブリスターの発生が殆ど見られない。 〇・・・極めて軽度のブリスターの発生が見られるが、
実用的に問題とならない。 △・・・ブリスターの発生が見られ、実用的に使用でき
ない。 ×・・・ひどいブリスターの発生が見られ、実用的に使
用できない。
(3) Blister Resistance Measurement 1 ml of the ink for rotary offset printing is developed with an RI printing machine (manufactured by Meiji Seisakusho) and printed on both sides of a coated paper sample.
Soak the printed sample in heated silicone oil,
The appearance of the generated blisters was visually observed and evaluated according to the following evaluation criteria. Evaluation criteria ・ ・ ・: Almost no blistering was observed. 〇: Extremely mild blistering is observed,
Not a problem in practice. Δ: Blisters are observed and cannot be used practically. X: Severe blister generation was observed, and it could not be used practically.

【0035】実施例2 酵素の添加量をパルプグラム重量当たり0.5Uのキシ
ラン分解活性が作用するように変え、漂白条件を表2の
ように変えた以外は実施例1と同様の操作を行った。得
られた酵素処理広葉樹晒クラフトパルプの単繊維強度と
オフセット印刷用塗被紙の水分伸縮率、及び耐ブリスタ
ー性を測定した結果を表4に示す。
Example 2 The same operation as in Example 1 was carried out except that the amount of the enzyme added was changed so that the xylan-decomposing activity of 0.5 U per gram of pulp worked, and the bleaching conditions were changed as shown in Table 2. Was. Table 4 shows the results of measuring the single fiber strength of the obtained enzyme-treated hardwood bleached kraft pulp, the moisture expansion / contraction ratio of the coated paper for offset printing, and the blister resistance.

【0036】[0036]

【表2】 [Table 2]

【0037】比較例1 酵素処理を行わず、漂白条件を表3のように変えた以外
は実施例1と同様の操作を行った。得られた酵素処理広
葉樹晒クラフトパルプの単繊維強度とオフセット印刷用
塗被紙の水分伸縮率、及び耐ブリスター性を測定した結
果を表4に示す。
Comparative Example 1 The same operation as in Example 1 was performed except that the enzyme treatment was not performed and the bleaching conditions were changed as shown in Table 3. Table 4 shows the results of measuring the single fiber strength of the obtained enzyme-treated hardwood bleached kraft pulp, the moisture expansion / contraction ratio of the coated paper for offset printing, and the blister resistance.

【0038】[0038]

【表3】 [Table 3]

【0039】比較例2 酵素をろ紙分解活性を有する酵素(商品名:セルライザ
ー、長瀬生化学社製)に変えた以外は実施例1と同様の
操作を行った。得られた酵素処理広葉樹晒クラフトパル
プの単繊維強度とオフセット印刷用塗被紙の水分伸縮
率、及び耐ブリスター性を測定した結果を表4に示す。
Comparative Example 2 The same operation as in Example 1 was performed, except that the enzyme was replaced with an enzyme having a filter paper decomposing activity (trade name: Cellulizer, manufactured by Nagase Biochemical Co., Ltd.). Table 4 shows the results of measuring the single fiber strength of the obtained enzyme-treated hardwood bleached kraft pulp, the moisture expansion / contraction ratio of the coated paper for offset printing, and the blister resistance.

【0040】実施例3 ギャップフォーマーを有する抄紙機にて速度1300m
/分で抄紙した以外は実施例1と同様の操作を行った。
得られた酵素処理広葉樹晒クラフトパルプの単繊維強度
とオフセット印刷用塗被紙の水分伸縮率、及び耐ブリス
ター性を測定した結果を表4に示す。
Example 3 Speed 1300 m on a paper machine having a gap former
The same operation as in Example 1 was performed except that papermaking was performed at / min.
Table 4 shows the results of measuring the single fiber strength of the obtained enzyme-treated hardwood bleached kraft pulp, the moisture expansion / contraction ratio of the coated paper for offset printing, and the blister resistance.

【0041】比較例3 ギャップフォーマーを有する抄紙機にて速度1300m
/分で抄紙した以外は比較例1と同様の操作を行った。
得られた酵素処理広葉樹晒クラフトパルプの単繊維強度
とオフセット印刷用塗被紙の水分伸縮率、及び耐ブリス
ター性を測定した結果を表4に示す。
Comparative Example 3 Speed 1300 m on a paper machine having a gap former
The same operation as in Comparative Example 1 was performed except that papermaking was performed at / min.
Table 4 shows the results of measuring the single fiber strength of the obtained enzyme-treated hardwood bleached kraft pulp, the moisture expansion / contraction ratio of the coated paper for offset printing, and the blister resistance.

【0042】実施例4 実施例1で製造された酵素処理した広葉樹晒クラフトパ
ルプ65%と比較例1で製造された酵素未処理の広葉樹
晒クラフトパルプ35%との混合物を配合した紙料を原
紙の製造に使用したこと以外は、実施例1と同様の操作
を行った。得られたオフセット印刷用塗被紙の水分伸縮
率、及び耐ブリスター性の測定結果を表4に示す。
Example 4 A paper stock containing a mixture of 65% of the enzyme-treated bleached hardwood kraft pulp prepared in Example 1 and 35% of the enzyme-untreated hardwood bleached kraft pulp prepared in Comparative Example 1 was used as base paper. The same operation as in Example 1 was performed except that the product was used for the production of Table 4 shows the measurement results of the moisture expansion and contraction rate and the blister resistance of the obtained coated paper for offset printing.

【0043】比較例4 実施例1で製造された酵素処理した広葉樹晒クラフトパ
ルプ45%と比較例1で製造された酵素未処理の広葉樹
晒クラフトパルプ55%との混合物を配合した紙料を原
紙の製造に使用したこと以外は、実施例1と同様の操作
を行った。得られたオフセット印刷用塗被紙の水分伸縮
率、及び耐ブリスター性の測定結果を表4に示す。
COMPARATIVE EXAMPLE 4 A stock containing a mixture of 45% of the enzyme-treated bleached hardwood kraft pulp prepared in Example 1 and 55% of the enzyme-untreated hardwood bleached kraft pulp prepared in Comparative Example 1 was used as base paper. The same operation as in Example 1 was performed except that the product was used for the production of Table 4 shows the measurement results of the moisture expansion and contraction rate and the blister resistance of the obtained coated paper for offset printing.

【0044】[0044]

【表4】 [Table 4]

【0045】[0045]

【発明の効果】表4から明かなように、漂白前のパルプ
をろ紙分解活性を有せず、キシラン分解活性を有する酵
素で処理し、次いで多段漂白した漂白パルプを少なくと
も一種使用することにより、寸法安定性が高く、かつ耐
ブリスター性に優れた印刷用塗被紙を高速で製造できる
ことがわかる。
As is clear from Table 4, the pulp before bleaching is treated with an enzyme having xylan-decomposing activity without filter paper-decomposing activity and then using at least one bleached pulp obtained by multi-stage bleaching. It can be seen that coated printing paper having high dimensional stability and excellent blister resistance can be manufactured at high speed.

─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成8年8月23日[Submission date] August 23, 1996

【手続補正2】[Procedure amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0019[Correction target item name] 0019

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0019】本発明の目的を達成するためには、以上に
記載したような処理を施されたパルプが塗被紙を構成す
る全パルプの少なくとも60重量%以上を占める必要が
ある。60重量%未満の場合には、パルプ繊維としての
改質効果の発現が不十分となり、十分な効果が得られな
い。原紙を構成する他のパルプとしては、本発明に記載
の処理を施されていない晒クラフトパルプ、機械パル
プ、脱墨パルプ等が挙げられ、本発明の効果を損なわな
い範囲で適宜組み合わせて使用される。
In order to achieve the object of the present invention, it is necessary that the pulp treated as described above accounts for at least 60% by weight or more of the total pulp constituting the coated paper. If the amount is less than 60% by weight, the pulp fiber will not have sufficient modifying effect, and will not have sufficient effect. Other pulp constituting the base paper includes bleached kraft pulp, mechanical pulp, deinked pulp, etc., which have not been subjected to the treatment described in the present invention, and are used in an appropriate combination as long as the effects of the present invention are not impaired. You.

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 原紙に顔料と接着剤を主成分とする塗工
層を設けた印刷用塗被紙において、原紙を構成するパル
プとして、ろ紙分解活性を有さず、キシラン分解活性を
有する酵素による処理を施し、次いで多段漂白した漂白
パルプを少なくとも一種使用することを特徴とする印刷
用塗被紙。
In a coated paper for printing having a base paper provided with a coating layer mainly composed of a pigment and an adhesive, the pulp constituting the base paper has no filter paper decomposing activity and has xylan decomposing activity. A coated paper for printing, characterized by using at least one bleached pulp which has been subjected to the following treatment and then multi-bleached.
【請求項2】 原紙を構成するパルプとして、原紙を構
成する全パルプの絶乾重量あたり前記漂白パルプを60
〜100重量%含有させることを特徴とする請求項1記
載の印刷用塗被紙。
2. The bleached pulp is used as the pulp constituting the base paper in an amount of 60% per the absolute dry weight of all the pulp constituting the base paper.
The coated paper for printing according to claim 1, wherein the content of the coated paper is from 100 to 100% by weight.
【請求項3】 ギャップフォーマー抄紙機を用いて、原
紙を抄造することを特徴とする請求項1又は請求項2記
載の印刷用塗被紙の製造方法。
3. The method for producing a coated paper for printing according to claim 1, wherein the base paper is formed using a gap former paper machine.
JP8212174A 1996-07-24 1996-07-24 Coated paper for printing and its production Pending JPH1046495A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8212174A JPH1046495A (en) 1996-07-24 1996-07-24 Coated paper for printing and its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8212174A JPH1046495A (en) 1996-07-24 1996-07-24 Coated paper for printing and its production

Publications (1)

Publication Number Publication Date
JPH1046495A true JPH1046495A (en) 1998-02-17

Family

ID=16618139

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8212174A Pending JPH1046495A (en) 1996-07-24 1996-07-24 Coated paper for printing and its production

Country Status (1)

Country Link
JP (1) JPH1046495A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100528500B1 (en) * 1998-12-31 2006-01-27 한솔제지주식회사 Inkjet Hanji Compositions and Manufacturing Methods Thereof
JP2008095220A (en) * 2006-10-10 2008-04-24 Oji Paper Co Ltd Coated paper for printing
CN107207628A (en) * 2015-01-26 2017-09-26 日本制纸株式会社 The manufacture method of material containing xylan
EP3399100A4 (en) * 2015-12-29 2019-08-14 Fibria Celulose S.A. Method for producing cellulose pulp, cellulose pulp and use thereof, paper

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JPH04507268A (en) * 1989-08-14 1992-12-17 ジェネンコア インターナショナル ヨーロッパ オイ Improvement of oxygen bleaching of pulp
JPH06128891A (en) * 1992-10-15 1994-05-10 Honshu Paper Co Ltd Production of paper and paper board
JPH06158575A (en) * 1992-11-17 1994-06-07 Mitsubishi Paper Mills Ltd Production of paper
JPH06166978A (en) * 1992-09-22 1994-06-14 Honshu Paper Co Ltd Production of bleached hemp pulp
JPH06220786A (en) * 1993-01-25 1994-08-09 Hokuetsu Paper Mills Ltd Method for bleaching pulp
JPH06222502A (en) * 1993-01-28 1994-08-12 New Oji Paper Co Ltd Base material for photographic printing paper
JPH06280179A (en) * 1993-03-26 1994-10-04 New Oji Paper Co Ltd Production of paper
JPH06280178A (en) * 1991-06-01 1994-10-04 Nippon Kamiparupu Kenkyusho:Kk Bleach acceleration composition, its production and treatment of paper and pulp using the composition
JPH06287898A (en) * 1992-03-16 1994-10-11 Nippon Paper Ind Co Ltd Production of base paper for laminated board
JPH06322696A (en) * 1993-05-13 1994-11-22 Nippon Paper Ind Co Ltd Paper for domestic use and its production
JPH07173785A (en) * 1993-12-20 1995-07-11 Mitsubishi Paper Mills Ltd Method for bleaching chemical pulp with peroxide or ozone
JPH0849187A (en) * 1994-08-05 1996-02-20 New Oji Paper Co Ltd Coated paper for offset printing
JPH08206030A (en) * 1995-02-02 1996-08-13 New Oji Paper Co Ltd Tissue
JPH09291490A (en) * 1996-02-29 1997-11-11 Oji Paper Co Ltd Pulp, paper and coated paper

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Publication number Priority date Publication date Assignee Title
JPH04507268A (en) * 1989-08-14 1992-12-17 ジェネンコア インターナショナル ヨーロッパ オイ Improvement of oxygen bleaching of pulp
JPH03228685A (en) * 1989-11-13 1991-10-09 Nippon Kamiparupu Kenkyusho:Kk Defibration composition, production thereof and treatment of paper or pulp using same composition
JPH06280178A (en) * 1991-06-01 1994-10-04 Nippon Kamiparupu Kenkyusho:Kk Bleach acceleration composition, its production and treatment of paper and pulp using the composition
JPH06287898A (en) * 1992-03-16 1994-10-11 Nippon Paper Ind Co Ltd Production of base paper for laminated board
JPH06166978A (en) * 1992-09-22 1994-06-14 Honshu Paper Co Ltd Production of bleached hemp pulp
JPH06128891A (en) * 1992-10-15 1994-05-10 Honshu Paper Co Ltd Production of paper and paper board
JPH06158575A (en) * 1992-11-17 1994-06-07 Mitsubishi Paper Mills Ltd Production of paper
JPH06220786A (en) * 1993-01-25 1994-08-09 Hokuetsu Paper Mills Ltd Method for bleaching pulp
JPH06222502A (en) * 1993-01-28 1994-08-12 New Oji Paper Co Ltd Base material for photographic printing paper
JPH06280179A (en) * 1993-03-26 1994-10-04 New Oji Paper Co Ltd Production of paper
JPH06322696A (en) * 1993-05-13 1994-11-22 Nippon Paper Ind Co Ltd Paper for domestic use and its production
JPH07173785A (en) * 1993-12-20 1995-07-11 Mitsubishi Paper Mills Ltd Method for bleaching chemical pulp with peroxide or ozone
JPH0849187A (en) * 1994-08-05 1996-02-20 New Oji Paper Co Ltd Coated paper for offset printing
JPH08206030A (en) * 1995-02-02 1996-08-13 New Oji Paper Co Ltd Tissue
JPH09291490A (en) * 1996-02-29 1997-11-11 Oji Paper Co Ltd Pulp, paper and coated paper

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100528500B1 (en) * 1998-12-31 2006-01-27 한솔제지주식회사 Inkjet Hanji Compositions and Manufacturing Methods Thereof
JP2008095220A (en) * 2006-10-10 2008-04-24 Oji Paper Co Ltd Coated paper for printing
CN107207628A (en) * 2015-01-26 2017-09-26 日本制纸株式会社 The manufacture method of material containing xylan
EP3252083A4 (en) * 2015-01-26 2018-09-05 Nippon Paper Industries Co., Ltd. Method for producing xylan-containing material
US10316108B2 (en) 2015-01-26 2019-06-11 Nippon Paper Industries Co., Ltd. Method for producing xylan-containing material
CN107207628B (en) * 2015-01-26 2020-02-21 日本制纸株式会社 Method for producing xylan-containing material
EP3399100A4 (en) * 2015-12-29 2019-08-14 Fibria Celulose S.A. Method for producing cellulose pulp, cellulose pulp and use thereof, paper

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