JPH1046059A - High workability stainless steel sheet having antibacterial action - Google Patents

High workability stainless steel sheet having antibacterial action

Info

Publication number
JPH1046059A
JPH1046059A JP8208639A JP20863996A JPH1046059A JP H1046059 A JPH1046059 A JP H1046059A JP 8208639 A JP8208639 A JP 8208639A JP 20863996 A JP20863996 A JP 20863996A JP H1046059 A JPH1046059 A JP H1046059A
Authority
JP
Japan
Prior art keywords
stainless steel
steel sheet
antibacterial
antibacterial action
high workability
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8208639A
Other languages
Japanese (ja)
Inventor
Takehisa Mizunuma
武久 水沼
Masaaki Hashimoto
政哲 橋本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP8208639A priority Critical patent/JPH1046059A/en
Publication of JPH1046059A publication Critical patent/JPH1046059A/en
Pending legal-status Critical Current

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  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain the subject stainless steel sheets suitable for materials of an electric washer, a cloth drier, etc., having a antibacterial action by coating with a resin layer containing antibacterial, agent, containing a lubricant. SOLUTION: The stainless steel sheet to be used in a circumstance where saprophytic bacteria is more apt to generate, is obtained by coating with the resin layer containing the lubricants such as polyethylene wax, polypropylene wax, etc., and antibacterial agents based on an organic carboxylic acid, pyrimidine derivatives, thiazoles, imidazole derivatives, biguanides, etc., in 1-20μm of dry thickness.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、雑菌の発生し易い
環境で使用される電機洗濯機、衣類乾燥機等のように、
雑菌の発生が好ましくない場所に使用される機器用材と
して好適に用いられる抗菌性および高加工性を有するス
テンレス鋼板に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electric washing machine, a clothes dryer and the like used in an environment where various germs are likely to occur.
The present invention relates to a stainless steel sheet having antibacterial properties and high workability, which is suitably used as a material for equipment used in places where the occurrence of various bacteria is not preferred.

【0002】[0002]

【従来の技術】ステンレス鋼板は、家電製品等の幅広い
分野で使用されているが、使用する場所によっては、ス
テンレス製の商品に抗菌性が要求される。また、これら
の製品は、製造上プレス加工を受けることが多く、加工
性も要求される。ステンレス製品に抗菌性を持たせる従
来の技術としては、金属銀または銀を含有する物質をガ
ラス原料と溶融してガラスフリットとし、このガラスフ
リットの粉末をステンレス製品の表面に積層するステン
レス製品の抗菌処理方法(特開平7−228982号公
報〕がある。
2. Description of the Related Art Stainless steel sheets are used in a wide range of fields such as home appliances, but depending on the place where they are used, stainless steel products are required to have antibacterial properties. In addition, these products are often subjected to press working in manufacturing, and workability is also required. The conventional technology for imparting antimicrobial properties to stainless steel products is to melt metallic silver or a substance containing silver with a glass raw material to form a glass frit, and then apply the glass frit powder to the surface of the stainless steel product. There is a processing method (JP-A-7-228982).

【0003】また、加工性を改善する手段として、ステ
ンレス鋼板に潤滑油を塗布するか、あるいは、軟質塩化
ビニール製のフィルムを貼る等が行なわれている。ま
た、これに代わるものとして、ステンレス鋼板表面に塩
化ビニール系の樹脂に潤滑剤を含有させ、加工性を改善
したステンレス鋼板(特開平7−195614号公報)
がある。
[0003] As means for improving workability, lubricating oil has been applied to a stainless steel plate, or a film made of soft vinyl chloride has been applied. As an alternative to this, a stainless steel plate having improved workability by adding a lubricant to a vinyl chloride resin on the surface of the stainless steel plate (Japanese Patent Application Laid-Open No. 7-195614).
There is.

【0004】しかし、特開平7−228982号公報に
開示されているステンレス製品の抗菌処理方法は、抗菌
性は有すると考えられるものの、潤滑性が劣り、高加工
性用途には適さない。また、加工性改善のための軟質塩
化ビニール製のフィルムは、プレス後のビニールの廃却
処理問題および人手によるビニール剥ぎ取りの作業の実
施でコスト高になる等、種々の問題を有する。また潤滑
油の使用は、プレス加工時の飛散のため、作業環境を悪
化する上、加工後、脱脂が必要である等の問題がある。
また、特開平7−228982号公報記載の発明では、
加工性の改善と共に、軟質塩化ビニール製フィルムや潤
滑油が有する問題点の改善は期待できるものの、抗菌性
は有していない。
[0004] However, the antibacterial treatment method for stainless steel products disclosed in Japanese Patent Application Laid-Open No. 7-228982 is considered to have antibacterial properties, but is inferior in lubricity and is not suitable for high workability applications. Further, a film made of soft vinyl chloride for improving processability has various problems, such as a problem of disposal of vinyl after pressing and an increase in cost due to manual peeling of vinyl. In addition, the use of lubricating oil deteriorates the working environment due to scattering at the time of press working, and also has a problem that degreasing is required after working.
In the invention described in JP-A-7-228982,
Although the improvement of the processability can be expected to solve the problems of the soft vinyl chloride film and the lubricating oil, it does not have antibacterial properties.

【0005】[0005]

【発明が解決しようとする課題】そこで、本発明は、抗
菌性と高加工性を有するステンレス鋼板を提供するもの
である。本発明者らは、従来の技術の問題点を解決する
ため、鋭意研究を重ねた結果、特に、有機系抗菌剤を塗
装樹脂に適当量複合することによって、抗菌性と高加工
性を有するステンレス鋼板の製造が可能であることを見
出したものである。すなわち、本発明によれば、ステン
レス鋼板の少なくとも、片方の表面上に、通常用いられ
ているチアベンダゾールおよびビグアナイト系等の有機
系の抗菌剤を、アクリル系あるいはエポキシ系等の塗装
樹脂に含有させ、抗菌性と高加工性に優れたステンレス
鋼板を提供するものである。有機系の抗菌剤の含有量
は、例えば、塗装樹脂100重量部当たり0.5〜10
重量で良い。また、樹脂皮膜厚さは、乾燥膜厚として、
1〜20μm程度で良い。
SUMMARY OF THE INVENTION Accordingly, the present invention provides a stainless steel sheet having antibacterial properties and high workability. The present inventors have conducted intensive studies to solve the problems of the conventional technology, and as a result, in particular, by combining an appropriate amount of an organic antibacterial agent with a coating resin, a stainless steel having antibacterial properties and high workability. It has been found that a steel sheet can be manufactured. That is, according to the present invention, at least on one surface of the stainless steel sheet, a commonly used organic antibacterial agent such as thiabendazole and biguanite is contained in a coating resin such as acrylic or epoxy, It is intended to provide a stainless steel sheet having excellent antibacterial properties and high workability. The content of the organic antibacterial agent is, for example, 0.5 to 10 per 100 parts by weight of the coating resin.
Good with weight. In addition, the resin film thickness, as a dry film thickness,
It may be about 1 to 20 μm.

【0006】[0006]

【課題を解決するための手段】本発明は、基板として用
いるステンレス鋼板は、プレス加工が施されるステンレ
ス冷延鋼板であり、その表面は、冷延のまま、あるいは
酸洗まま、光輝焼鈍仕上等の状態で使用されるものであ
る。また、ステンレス鋼板表面に形成される塗装樹脂に
複合させる抗菌剤の含有量は、例えば、塗装樹脂100
重量部当たり0.5〜10重量部を添加する。
According to the present invention, a stainless steel sheet used as a substrate is a cold-rolled stainless steel sheet which is subjected to press working, and the surface of which is cold-rolled or pickled and has a bright annealing finish. And so on. The content of the antibacterial agent to be combined with the coating resin formed on the surface of the stainless steel plate is, for example, 100% of the coating resin.
Add 0.5 to 10 parts by weight per part by weight.

【0007】さらに、潤滑皮膜は通常用いられている潤
滑剤で良い。潤滑剤としては、例えば、ポリエチレンワ
ックス、ポリプロピレンワックス等がある。また、有機
系の抗菌剤は公知のもので良く、例えば、有機カルボン
酸系、ピリジン誘導体系、チアゾール系、イミダゾール
系、ビグアナイト系で良い。
Further, the lubricating film may be a commonly used lubricant. Examples of the lubricant include polyethylene wax and polypropylene wax. The organic antibacterial agent may be a known one, for example, an organic carboxylic acid type, a pyridine derivative type, a thiazole type, an imidazole type, or a biguanite type.

【0008】[0008]

【発明の実施の形態】以下に本発明を実施例に基づき説
明する。SUS304鋼板(1mm厚,2B仕上材)の両
面に、表1に示す樹脂処理条件で塗布し、乾燥後約20
0℃で焼き付けした。以上のようにして作製した樹脂処
理鋼板について、加工性、抗菌性の各評価試験を下記試
験要領で実施した。 (1)加工性試験 塗油なしで、エリクセン円筒絞り試験機を用いて、ポン
チ径50mm、ポンチ肩R;5mmの条件で試験を行い、限
界絞り比(LDR)により評価した。 (2)抗菌性試験 試験片の表面に、105 個/mlの大腸菌液および黄色ブ
ドウ球菌液1mlのせて、24時間経過後の生存菌数を測
定し、その評価を○:生存菌検出されず、×:抗菌効果
なし、として示した。表1から明らかのように、本発明
のステンレス鋼板は、何れも加工性、抗菌性共に優れた
特性を示す。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below based on embodiments. Apply to both surfaces of SUS304 steel plate (1mm thickness, 2B finishing material) under the resin treatment conditions shown in Table 1, and after drying about 20
Bake at 0 ° C. Each evaluation test of workability and antibacterial property of the resin-treated steel sheet produced as described above was performed according to the following test procedure. (1) Workability test Using an Erichsen cylindrical drawing tester without oiling, a test was performed under the conditions of a punch diameter of 50 mm and a punch shoulder R; 5 mm, and the limit drawing ratio (LDR) was evaluated. (2) on the surface of the antimicrobial test specimen, 10 5 cells / ml and placed coli solution and Staphylococcus aureus solution 1ml of, measuring the number of surviving bacteria after 24 hours, the evaluation ○: detected survivors And x: No antibacterial effect. As is clear from Table 1, all of the stainless steel sheets of the present invention exhibit excellent workability and antibacterial properties.

【0009】[0009]

【表1】 [Table 1]

【0010】本発明例1〜8は、何れも抗菌性を有する
と共に、良好な加工性を有している。比較例1〜4は、
加工性は良好であるが、抗菌剤無添加のため、抗菌性は
ない。
Examples 1 to 8 of the present invention all have antibacterial properties and good workability. Comparative Examples 1 to 4
Although the processability is good, there is no antibacterial property because no antibacterial agent is added.

【0011】[0011]

【発明の効果】以上述べたように、本発明ステンレス鋼
板は、潤滑剤を含む塗装樹脂に抗菌剤を適量含有させ
た、樹脂層を被覆することによって、抗菌性と加工性を
持たせると共に、軟質ビニールあるいは潤滑油を使用し
ないため、良好な環境で作業ができる。しかも、抗菌
性、加工性も良好であるため、産業上極めて有効な発明
である。
As described above, the stainless steel sheet of the present invention has antibacterial properties and workability by coating a resin layer containing an appropriate amount of an antibacterial agent in a coating resin containing a lubricant. Since no soft vinyl or lubricating oil is used, work can be performed in a favorable environment. In addition, the antibacterial property and the processability are good, so that the invention is industrially extremely effective.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 潤滑剤と抗菌剤を含有する樹脂皮膜が形
成されていることを特徴とする抗菌性を有する高加工性
潤滑ステンレス鋼板。
1. A highly workable lubricated stainless steel sheet having antibacterial properties, wherein a resin film containing a lubricant and an antibacterial agent is formed.
JP8208639A 1996-08-07 1996-08-07 High workability stainless steel sheet having antibacterial action Pending JPH1046059A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8208639A JPH1046059A (en) 1996-08-07 1996-08-07 High workability stainless steel sheet having antibacterial action

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8208639A JPH1046059A (en) 1996-08-07 1996-08-07 High workability stainless steel sheet having antibacterial action

Publications (1)

Publication Number Publication Date
JPH1046059A true JPH1046059A (en) 1998-02-17

Family

ID=16559578

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8208639A Pending JPH1046059A (en) 1996-08-07 1996-08-07 High workability stainless steel sheet having antibacterial action

Country Status (1)

Country Link
JP (1) JPH1046059A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003048401A1 (en) * 2001-12-06 2003-06-12 Nippon Steel Corporation Ferritic stainless steel sheet excellent in press formability and workability and method for production thereof
JP2006231690A (en) * 2005-02-24 2006-09-07 Jfe Galvanizing & Coating Co Ltd Insect-proofing steel sheet and its manufacturing method
CN112981079A (en) * 2021-02-03 2021-06-18 上海华杰生态环境工程有限公司 Antibacterial stainless steel for door lock and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003048401A1 (en) * 2001-12-06 2003-06-12 Nippon Steel Corporation Ferritic stainless steel sheet excellent in press formability and workability and method for production thereof
US7341637B2 (en) 2001-12-06 2008-03-11 Nippon Steel & Sumikin Stainless Steel Corporation Ferritic stainless steel sheet excellent in press formability and workability and method for production thereof
JP2006231690A (en) * 2005-02-24 2006-09-07 Jfe Galvanizing & Coating Co Ltd Insect-proofing steel sheet and its manufacturing method
CN112981079A (en) * 2021-02-03 2021-06-18 上海华杰生态环境工程有限公司 Antibacterial stainless steel for door lock and preparation method thereof

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