JPH10328472A - Device for washing fibrous product and its method - Google Patents
Device for washing fibrous product and its methodInfo
- Publication number
- JPH10328472A JPH10328472A JP9142822A JP14282297A JPH10328472A JP H10328472 A JPH10328472 A JP H10328472A JP 9142822 A JP9142822 A JP 9142822A JP 14282297 A JP14282297 A JP 14282297A JP H10328472 A JPH10328472 A JP H10328472A
- Authority
- JP
- Japan
- Prior art keywords
- ultrasonic
- cleaning
- vibration
- cleaned
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000005406 washing Methods 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims description 31
- 239000007788 liquid Substances 0.000 claims abstract description 51
- 239000004094 surface-active agent Substances 0.000 claims abstract description 20
- 102000004190 Enzymes Human genes 0.000 claims abstract description 18
- 108090000790 Enzymes Proteins 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000004140 cleaning Methods 0.000 claims description 145
- 230000001678 irradiating effect Effects 0.000 claims description 17
- 239000004753 textile Substances 0.000 claims description 16
- 230000000694 effects Effects 0.000 abstract description 20
- 239000000835 fiber Substances 0.000 abstract description 16
- -1 for example Substances 0.000 description 13
- 229940088598 enzyme Drugs 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000004744 fabric Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 239000003945 anionic surfactant Substances 0.000 description 8
- 239000002736 nonionic surfactant Substances 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 230000010355 oscillation Effects 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 229910000859 α-Fe Inorganic materials 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- AFINAILKDBCXMX-PBHICJAKSA-N (2s,3r)-2-amino-3-hydroxy-n-(4-octylphenyl)butanamide Chemical compound CCCCCCCCC1=CC=C(NC(=O)[C@@H](N)[C@@H](C)O)C=C1 AFINAILKDBCXMX-PBHICJAKSA-N 0.000 description 3
- 108091005804 Peptidases Proteins 0.000 description 3
- 239000004365 Protease Substances 0.000 description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000004663 powder metallurgy Methods 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 108010059892 Cellulase Proteins 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 229940106157 cellulase Drugs 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229940096992 potassium oleate Drugs 0.000 description 2
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DTJDPHTWZYVDFZ-UHFFFAOYSA-N 1-hydroxyethane-1,1-disulfonic acid Chemical compound OS(=O)(=O)C(O)(C)S(O)(=O)=O DTJDPHTWZYVDFZ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- DKPHLYCEFBDQKM-UHFFFAOYSA-H hexapotassium;1-phosphonato-n,n-bis(phosphonatomethyl)methanamine Chemical compound [K+].[K+].[K+].[K+].[K+].[K+].[O-]P([O-])(=O)CN(CP([O-])([O-])=O)CP([O-])([O-])=O DKPHLYCEFBDQKM-UHFFFAOYSA-H 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、繊維製品の洗浄装
置および洗浄方法に関するものである。The present invention relates to an apparatus and a method for cleaning textile products.
【0002】[0002]
【従来の技術】従来、衣類等の繊維製品における汚れ、
特に、頑固な泥汚れ、シミまたは襟・袖等の油汚れに対
しては、液体または粉末の洗剤(超コン/漂白タイプを
含む)による洗浄液を被洗浄物の汚れ部分に直接塗布し
て該汚れ部分をブラシ等で刷掃(ブラッシング)する洗
浄方法、被洗浄物を洗浄液中において揉み込む手洗い洗
浄方法、または、被洗浄物を洗浄液に浸け置きした後洗
濯機を使用する洗浄方法等が行われていたが、面倒であ
る、手が荒れる、繊維が傷む、あるいは、充分な洗浄効
果が得られない等の不満があった。2. Description of the Related Art Conventionally, stains on textiles such as clothes,
In particular, for stubborn mud stains, stains or oil stains such as collars and sleeves, a cleaning solution using a liquid or powder detergent (including super-con / bleach type) is applied directly to the soiled portion of the object to be cleaned. A cleaning method of brushing the contaminated part with a brush, a hand-washing method of rubbing an object to be cleaned in a cleaning solution, or a cleaning method of using a washing machine after immersing the object in the cleaning solution and the like is performed. However, there were complaints such as troublesomeness, rough hands, damaged fibers, and insufficient cleaning effect.
【0003】また、近年、超音波を利用した超音波洗浄
機として、 特開昭61−249500号公報記載の「超音波染み
抜き方法および装置」 特開昭57−55194号公報記載の「超音波洗濯
機」 実開昭61−184586号公報記載の「超音波洗濯
機」 実開平6−52786号公報記載の「超音波洗濯機」 等が利用されている。In recent years, as an ultrasonic cleaning machine utilizing ultrasonic waves, there has been proposed an "ultrasonic stain removing method and apparatus" described in JP-A-61-249500, and "Ultrasonic washing" described in JP-A-57-55194. "Ultrasonic washing machine" described in Japanese Utility Model Laid-Open No. 61-184586 and "Ultrasonic washing machine" described in Japanese Utility Model Application Laid-Open No. 6-52786 are used.
【0004】の公報に記載された技術では、被洗浄物
に水または洗剤等を滲み込ませた布または紙をシミ部分
に当てて、該シミ部分に超音波染み抜き装置の超音波発
生ヘッドを当接し、被洗浄物の汚れを布または紙に移行
することで洗浄を行っている。また、の公報に記載さ
れた技術では、超音波洗濯機の洗濯槽の底面に、振動子
を取り付け、高周波加振機により生ずるキャビテーショ
ンを利用して洗濯機中に気泡を発生および消滅させるこ
とにより洗浄を行っている。の公報に記載された技術
では、金属製の洗濯槽内に超音波発生装置を配設し、該
洗濯槽の底部に気泡発生装置を設け、該気泡発生装置に
より空気を洗濯槽内に供給し、衣類に用いられている布
地の材料および織りかた、すなわち材料の種類によって
超音波の周波数を切り替えて洗浄を行っている。また、
の公報に記載された技術では、洗濯槽の底部に超音波
振動子を配設し、洗濯槽の上部に殺菌性の電磁波を発生
する電磁波発生手段を配設し、洗濯槽の周囲を覆う電磁
波を遮断する電磁波遮断手段とを有し、被洗浄物の汚れ
の除去と滅菌消毒とを同時に行っている。In the technique described in the above publication, a cloth or paper impregnated with water or a detergent or the like is applied to an object to be cleaned, and the ultrasonic generation head of an ultrasonic stain removing device is applied to the area. The cleaning is performed by contacting and transferring dirt on the object to be cleaned to cloth or paper. According to the technique described in the above publication, a vibrator is attached to the bottom of a washing tub of an ultrasonic washing machine, and bubbles are generated and eliminated in the washing machine using cavitation generated by a high-frequency vibrator. Cleaning is performed. In the technology described in the publication, an ultrasonic generator is disposed in a metal washing tub, a bubble generator is provided at the bottom of the washing tub, and air is supplied into the washing tub by the bubble generator. Cleaning is performed by switching the frequency of ultrasonic waves depending on the material and weaving method of the cloth used for clothing, that is, the type of the material. Also,
In the technology described in the publication, an ultrasonic vibrator is arranged at the bottom of the washing tub, an electromagnetic wave generating means for generating sterilizing electromagnetic waves is arranged at the top of the washing tub, and an electromagnetic wave covering the periphery of the washing tub is provided. And an electromagnetic wave shielding means for shielding the object to be cleaned, and simultaneously removes dirt from the object to be cleaned and sterilizes and disinfects it.
【0005】[0005]
【発明が解決しようとする課題】しかし、の公報に記
載された技術は、被洗浄物の局部的な汚れ(シミ)を布
または紙に移行することが不十分になる可能性があり、
また、〜の公報に記載された技術では、洗濯槽の内
部に被洗浄物を収納した際、被洗浄物が超音波発生装置
等から離れている部分では、洗浄効率が著しく悪く、全
体的に充分な洗浄効果を得ることができなかった。However, according to the technique described in the above publication, there is a possibility that the transfer of local stains (stains) of an object to be washed to a cloth or paper may become insufficient.
Further, according to the techniques described in the above publications, when the object to be washed is stored inside the washing tub, the washing efficiency is extremely poor in a portion where the object to be washed is away from the ultrasonic generator or the like, and A sufficient cleaning effect could not be obtained.
【0006】本発明は、上記の事情に鑑みてなされたも
ので、以下の目的を達成しようとするものである。 (a)洗浄効果の向上を図ること。 (b)繊維に対する影響を低減し、ネクタイ等の高級繊
維に対応した洗浄装置および洗浄方法を提供すること。 (c)洗浄時における繊維への影響を低減すること。 (d)部分洗いにも適用可能な洗浄装置および洗浄方法
を提供すること。 (e)界面活性剤および酵素を含む洗浄液の洗浄力を向
上すること。The present invention has been made in view of the above circumstances, and aims to achieve the following objects. (A) To improve the cleaning effect. (B) To provide a cleaning device and a cleaning method that reduce the influence on the fibers and are compatible with high-grade fibers such as ties. (C) To reduce the effect on fibers during washing. (D) To provide a cleaning apparatus and a cleaning method applicable to partial cleaning. (E) Improving the detergency of a cleaning solution containing a surfactant and an enzyme.
【0007】[0007]
【課題を解決するための手段】洗浄液および被洗浄物を
収容する洗浄容器と、該洗浄液および被洗浄物に振動を
加えるかまたは超音波を照射する加振手段(超音波照射
手段)と、該加振手段(超音波照射手段)の対向位置に
配される振動反射板(超音波反射板)とを具備し、加振
手段(超音波照射手段)の照射面と振動反射板(超音波
反射板)との間に被洗浄物を位置した状態で被洗浄物の
洗浄が行われる。被洗浄物に加える振動が超音波とさ
れ、加振手段が超音波照射手段とされる。洗浄時におけ
る、加振手段(超音波照射手段)の照射面と被洗浄物と
の間隔が1cm以下、好ましくは0.5cm以下に設定
される。加振手段(超音波照射手段)が、振動を加え
る、もしくは振動により超音波を発生する単数または複
数の振動子と、該振動子を振動させるための発振回路と
増幅器と電力計とを具備するものとされて電源に接続さ
れる。振動子としては、圧電セラミック、フェライト等
の磁歪素子、粉末冶金等の超磁歪素子などが選択され
る。振動反射板(超音波反射板)の材質としては、水に
対する音波反射率が60パーセント以上のもの、例え
ば、ガラス、アルミニウム、鋼鉄とされ、好ましくは、
鋼鉄(SUS304)が適用される。加振手段から加え
られる振動は、その周期が、0.1kHz〜10kHz
に、好ましくは0.5kHz〜1kHzの範囲に設定さ
れる。超音波照射手段から照射される超音波は、その周
期が、10kHz〜100kHzに、好ましくは20k
Hz〜60kHzの範囲に設定される。加振手段(超音
波照射手段)から加えられる振動または照射される超音
波は、その出力が20W〜60W、好ましくは30W〜
50Wに設定される。振動子が、洗浄容器に対して一体
に配される技術か、洗浄容器に対して取り外しおよび移
動が可能に配される技術が選択される。被洗浄物が繊維
製等の靴とされ、前記振動子と振動反射板(超音波反射
板)とが靴を内外から挟む状態に洗浄が行われ、ここ
で、振動子が靴の内部に挿入される形状とされ、振動反
射板(超音波反射板)が靴を外側から包み込む形状とさ
れかつ内部に洗浄液を溜める洗浄容器と一体とされる技
術が選択される。洗浄容器の内部に少なくとも2本のロ
ーラが間隔をあけて対向位置に配され、該2本のローラ
の間に加振手段(超音波照射手段)と振動反射板(超音
波反射板)とが対向位置に配され、該加振手段(超音波
照射手段)と振動反射板(超音波反射板)との間に2本
のローラにより被洗浄物が送通されて洗浄が行われ、被
洗浄物が絨毯、カーテン等の長尺物とされて、前記2本
のローラの少なくとも1本には駆動手段が接続される技
術が選択される。洗浄液が、5重量%〜60重量%の範
囲の界面活性剤、または、0.01重量%〜10重量%
の範囲の酵素を少なくとも含むものとされ、界面活性剤
が、α−スルホ脂肪酸エステル塩、α−オレフィンスル
ホン酸塩、ポリオキシエチレン(POE)アルキルエー
テルスルホン酸塩、飽和または不飽和のC12〜C18脂肪
酸石鹸等からなるアニオン界面活性剤、ポリオキシエチ
レン(C3 〜C70)アルキルエーテル、ポリオキシエチ
レンノニルフェニルエーテル等からなるノニオン界面活
性剤から選択された少なくとも1種で5重量%〜60重
量%、好ましくは10重量%〜40重量%とされ、酵素
が、セルラーゼ、ナビナーゼ、リポラーゼ、プロテアー
ゼ等から選ばれた群の少なくとも1種で0.01重量%
〜10重量%、好ましくは0.5重量%〜7重量%とさ
れる。さらに、洗浄液には、リン酸誘導体等のキレート
剤、水酸化ナトリウム等のアルカリ剤、ゼオライト等の
ビルダー、殺菌・抗菌剤、蛍光剤、着色剤および香料等
を配合することも可能である。A cleaning container for accommodating a cleaning liquid and an object to be cleaned, vibrating means (ultrasonic irradiation means) for applying vibration or irradiating ultrasonic waves to the cleaning liquid and the object to be cleaned, and A vibration reflection plate (ultrasonic reflection plate) disposed at a position opposite to the vibration means (ultrasonic irradiation means), and an irradiation surface of the vibration means (ultrasonic irradiation means) and the vibration reflection plate (ultrasonic reflection) The object to be cleaned is cleaned with the object to be cleaned positioned between the plate and the plate). The vibration applied to the object to be cleaned is ultrasonic waves, and the vibration means is ultrasonic wave irradiation means. At the time of cleaning, the distance between the irradiation surface of the vibration means (ultrasonic irradiation means) and the object to be cleaned is set to 1 cm or less, preferably 0.5 cm or less. The vibrating means (ultrasonic irradiation means) includes one or more vibrators for applying vibration or generating ultrasonic waves by vibration, an oscillation circuit for vibrating the vibrator, an amplifier, and a power meter. It is assumed and connected to the power supply. As the vibrator, a magnetostrictive element such as piezoelectric ceramic or ferrite, a giant magnetostrictive element such as powder metallurgy, or the like is selected. As a material of the vibration reflecting plate (ultrasonic reflecting plate), a material having a sound wave reflectance of 60% or more with respect to water, for example, glass, aluminum, or steel is preferable.
Steel (SUS304) is applied. The frequency of the vibration applied from the vibration means is 0.1 kHz to 10 kHz.
Preferably, it is set in the range of 0.5 kHz to 1 kHz. The ultrasonic waves emitted from the ultrasonic irradiation means have a cycle of 10 kHz to 100 kHz, preferably 20 kHz.
Hz to 60 kHz. The output of the vibration or the ultrasonic wave applied from the vibration means (ultrasonic wave irradiation means) is 20 W to 60 W, preferably 30 W to
It is set to 50W. A technique in which the vibrator is arranged integrally with the cleaning container or a technique in which the vibrator is detachably and movably arranged with respect to the cleaning container is selected. The object to be cleaned is a shoe made of fiber or the like, and washing is performed with the vibrator and the vibration reflection plate (ultrasonic reflection plate) sandwiching the shoe from inside and outside, where the vibrator is inserted into the shoe. A technique is adopted in which a vibration reflection plate (ultrasonic reflection plate) wraps the shoe from the outside and is integrated with a cleaning container that stores a cleaning liquid inside. At least two rollers are arranged at an opposing position with an interval inside the cleaning container, and a vibration means (ultrasonic irradiation means) and a vibration reflection plate (ultrasonic reflection plate) are provided between the two rollers. The object to be cleaned is sent by two rollers between the vibrating means (ultrasonic wave irradiating means) and the vibration reflecting plate (ultrasonic reflecting plate), and the cleaning is performed. A technique is adopted in which the object is a long object such as a carpet or a curtain, and a driving means is connected to at least one of the two rollers. The cleaning liquid is a surfactant in the range of 5% to 60% by weight, or 0.01% to 10% by weight.
Wherein the surfactant is an α-sulfofatty acid ester salt, an α-olefin sulfonate, a polyoxyethylene (POE) alkyl ether sulfonate, a saturated or unsaturated C 12 to anionic surfactant comprising a C 18 fatty acid soap, polyoxyethylene (C 3 ~C 70) alkyl ether, 5 wt% of at least one selected from nonionic surfactants consisting of polyoxyethylene nonyl phenyl ether - 60% by weight, preferably 10% by weight to 40% by weight, and the enzyme is 0.01% by weight of at least one selected from the group consisting of cellulase, nabinase, lipolase, protease and the like.
-10% by weight, preferably 0.5% by weight to 7% by weight. Furthermore, a chelating agent such as a phosphoric acid derivative, an alkali agent such as sodium hydroxide, a builder such as zeolite, a bactericidal / antibacterial agent, a fluorescent agent, a coloring agent, a fragrance, and the like can be added to the washing liquid.
【0008】[0008]
【発明の実施の形態】以下、本発明に係る繊維製品の洗
浄装置および洗浄方法の第1実施形態を、図面に基づい
て説明する。図1において、符号Wは洗浄液、Sは被洗
浄物、1は洗浄装置、2は洗浄容器、3は加振手段(超
音波照射手段)、4は振動反射板(超音波反射板)であ
る。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A first embodiment of a textile product cleaning apparatus and a cleaning method according to the present invention will be described below with reference to the drawings. In FIG. 1, reference symbol W denotes a cleaning liquid, S denotes an object to be cleaned, 1 denotes a cleaning device, 2 denotes a cleaning container, 3 denotes a vibration unit (ultrasonic irradiation unit), and 4 denotes a vibration reflection plate (ultrasonic reflection plate). .
【0009】洗浄装置1は、洗浄液Wおよび被洗浄物S
を収容する洗浄容器2と、該洗浄液Wおよび被洗浄物S
に振動を加えるかまたは超音波を照射する加振手段(超
音波照射手段)3と、該加振手段(超音波照射手段)3
の対向位置に配される振動反射板(超音波反射板)4と
を具備し、加振手段(超音波照射手段)3と振動反射板
(超音波反射板)4との間に洗浄液Wおよび被洗浄物S
を位置させた状態で被洗浄物Sの洗浄が行われるものと
される。洗浄容器2は、ポリプロピレン、ABS(アク
リロニトリル・ブタジエン・スチレン)樹脂等のプラス
チック製や、鋼鉄、ステンレス鋼、アルミニウム等、金
属製のものとされ、例えばフッ素樹脂等のコーティング
が施されるステンレス鋼からなるものとされて、該洗浄
容器2の底部21には、図1に示すように、振動反射板
(超音波反射板)4が一体として配される。The cleaning apparatus 1 includes a cleaning liquid W and an object S to be cleaned.
, The washing liquid W and the object to be washed S
Vibrating means (ultrasonic irradiating means) 3 for applying vibration to or irradiating ultrasonic waves to the vibrating means (ultrasonic irradiating means) 3
And a vibration reflection plate (ultrasonic reflection plate) 4 disposed at a position opposite to the above, and a cleaning liquid W and a vibration liquid between the vibration means (ultrasonic irradiation means) 3 and the vibration reflection plate (ultrasonic reflection plate) 4. Cleaning object S
The object S to be cleaned is to be cleaned in a state where is positioned. The cleaning container 2 is made of plastic such as polypropylene or ABS (acrylonitrile / butadiene / styrene) resin, or made of metal such as steel, stainless steel, or aluminum, and is made of, for example, stainless steel coated with a fluorine resin or the like. As shown in FIG. 1, a vibration reflection plate (ultrasonic reflection plate) 4 is integrally disposed on the bottom portion 21 of the cleaning container 2.
【0010】加振手段(超音波照射手段)3は、図1に
示すように、振動を加えるか、または振動により超音波
を発生する単数または複数の振動子31と、該振動子3
1を振動させるための発振回路32と増幅器33と電力
計34とを具備するものとされて、図示しない電源に接
続される。振動子31は、例えばフェライト等の磁歪素
子とされ、図1に示すように、洗浄容器2から取り外し
及び移動可能とされ、平面形状の照射面31aとコイル
31bとを有するものとされる。発振回路32は、図示
しない制御部により、加振手段(超音波照射手段)3か
ら加える振動かまたは照射する超音波の周期を、0.1
kHz〜100kHzの範囲に、好ましくは0.5kH
z〜60kHzの範囲に設定可能とされる。増幅器33
は、図示しない制御部により、加振手段(超音波照射手
段)3から照射する超音波の出力を、20W〜60Wの
範囲に、好ましくは30W〜50Wの範囲に設定可能と
される。As shown in FIG. 1, a vibrating means (ultrasonic wave irradiating means) 3 includes one or more vibrators 31 for applying vibration or generating ultrasonic waves by vibrating;
It is provided with an oscillation circuit 32 for oscillating 1, an amplifier 33, and a power meter 34, and is connected to a power supply (not shown). The vibrator 31 is, for example, a magnetostrictive element such as ferrite, and is detachable and movable from the cleaning container 2 as shown in FIG. 1, and has a planar irradiation surface 31a and a coil 31b. The oscillation circuit 32 sets the cycle of the vibration applied from the vibrating means (ultrasonic wave irradiating means) 3 or the period of the ultrasonic wave to be radiated to 0.1 by a control unit (not shown).
kHz to 100 kHz, preferably 0.5 kHz
It can be set in the range of z to 60 kHz. Amplifier 33
The control unit (not shown) can set the output of the ultrasonic wave irradiated from the vibration means (ultrasonic wave irradiating means) 3 in the range of 20 W to 60 W, preferably in the range of 30 W to 50 W.
【0011】振動反射板(超音波反射板)4の材質とし
ては、水に対する音波反射率が60パーセント以上のも
の、つまり、ガラス、アルミニウム、鋼鉄等から選択さ
れ、例えば反射率88パーセントの鋼鉄製(SUS30
4)とされる。The material of the vibration reflection plate (ultrasonic reflection plate) 4 is selected from those having a sound wave reflectance of 60% or more with respect to water, that is, glass, aluminum, steel, etc. (SUS30
4).
【0012】次に、洗浄容器1において使用される洗浄
液Wについて説明する。洗浄液Wは、5重量%〜60重
量%の範囲内、好ましくは10重量%〜40重量%の範
囲の界面活性剤、およびまたは、0.01重量%〜10
重量%の範囲内、好ましくは0.5重量%〜7重量%の
範囲の酵素を含み、残余が精製水とされる。Next, the cleaning liquid W used in the cleaning container 1 will be described. The cleaning liquid W contains a surfactant in the range of 5% to 60% by weight, preferably 10% to 40% by weight, and / or 0.01% to 10% by weight.
It contains the enzyme in the range of 0.5% by weight, preferably in the range of 0.5% to 7% by weight, with the balance being purified water.
【0013】洗浄液W中の界面活性剤の濃度は、5重量
%〜60重量%の範囲内とされる。5重量%未満では、
特に油汚れなどに対する洗浄効果が不足し、60重量%
を越えると、洗浄液が粘稠となって、汚染物質を膨潤さ
せる効果が減退し、ドロ汚れなどに対する洗浄効果が低
下する。この観点から、界面活性剤がアニオン界面活性
剤とノニオン界面活性剤とからなり、この界面活性剤
が、洗浄液W中に10重量%〜40重量%の範囲内で含
まれていることが更に好ましい。The concentration of the surfactant in the cleaning liquid W is in the range of 5% by weight to 60% by weight. If it is less than 5% by weight,
In particular, the cleaning effect against oil stains is insufficient, and 60% by weight
When the value exceeds the above, the washing liquid becomes viscous, the effect of swelling the contaminants is reduced, and the effect of washing the mud stains is reduced. From this viewpoint, it is more preferable that the surfactant comprises an anionic surfactant and a nonionic surfactant, and the surfactant is contained in the cleaning liquid W in a range of 10% by weight to 40% by weight. .
【0014】アニオン界面活性剤としては、α−スルホ
脂肪酸エステル塩、α−オレフィンスルホン酸塩、ポリ
オキシエチレンアルキルエーテルスルホン酸塩、飽和ま
たは不飽和のC12〜C18脂肪酸石鹸、などが好適に使用
できる。これらは特に水性汚れやドロ汚れに対する洗浄
効果が高い。特にオレイン酸石鹸は、洗浄力が高く、粘
度調整効果があり、環境にも優しいので、アニオン界面
活性剤の少なくとも一部として好適に使用できる。ノニ
オン界面活性剤としては、POE(C3 〜C70)アルキ
ルエーテル、POEノニルフェニルエーテルなどが好適
に使用できる。ノニオン界面活性剤は、一般に油汚れな
どに対する洗浄効果が非常に高い。Preferred examples of the anionic surfactant include α-sulfofatty acid ester salts, α-olefin sulfonates, polyoxyethylene alkyl ether sulfonates, and saturated or unsaturated C 12 -C 18 fatty acid soaps. Can be used. These are particularly effective in cleaning water-based stains and dust stains. In particular, oleic acid soap has a high detergency, has a viscosity adjusting effect, and is environmentally friendly, and thus can be suitably used as at least a part of an anionic surfactant. The nonionic surfactant, POE (C 3 ~C 70) alkyl ether, such as POE nonylphenyl ether can be preferably used. Nonionic surfactants generally have a very high cleaning effect on oil stains and the like.
【0015】前記の界面活性剤としては、アニオン界面
活性剤およびノニオン界面活性剤などから選択された少
なくとも1種とされ、例えば、アニオン界面活性剤とし
ては、α−オレフィンスルホン酸カリウム5重量%、オ
レイン酸カリウム10重量%、ノニオン界面活性剤とし
ては、POE(10)アルキル(C12)エーテル10重
量%が含まれている。酵素は、セルラーゼ、ナビナー
ゼ、リポラーゼ、プロテアーゼ等から選ばれた群の少な
くとも1種とされ、例えば、プロテアーゼ0.5重量%
が含まれている。The above-mentioned surfactant is at least one selected from an anionic surfactant and a nonionic surfactant. For example, as the anionic surfactant, 5% by weight of potassium α-olefin sulfonate, potassium oleate 10 wt%, the nonionic surfactant includes POE (10) alkyl (C 12) ether 10% by weight. The enzyme is at least one selected from the group consisting of cellulase, nabinase, lipolase, protease and the like.
It is included.
【0016】さらに、洗浄液Wには、リン酸誘導体等の
キレート剤、水酸化ナトリウム等のアルカリ剤、ゼオラ
イト等のビルダー、殺菌・抗菌剤、蛍光剤、着色剤およ
び香料等を配合することも可能である。リン酸誘導体の
例としては、1−ヒドロキシエタン−1,1−ジスルホ
ン酸、アミノトリ(メチレンスルホン酸)、エチレンジ
アミンテトラ(メチレンホスホン酸)、オルトリン酸、
メタリン酸、ピロリン酸、ポリリン酸などを挙げること
ができる。The washing liquid W may further contain a chelating agent such as a phosphoric acid derivative, an alkali agent such as sodium hydroxide, a builder such as zeolite, a bactericidal / antibacterial agent, a fluorescent agent, a coloring agent, a fragrance, and the like. It is. Examples of the phosphoric acid derivative include 1-hydroxyethane-1,1-disulfonic acid, aminotri (methylenesulfonic acid), ethylenediaminetetra (methylenephosphonic acid), orthophosphoric acid,
Examples thereof include metaphosphoric acid, pyrophosphoric acid, and polyphosphoric acid.
【0017】被洗浄物Sは、例えば綿製品とされ、それ
以外にも、正絹ネクタイ等の高級繊維製品に適用するこ
とができる。The article S to be cleaned is, for example, a cotton product, and can be applied to other high-quality fiber products such as silk ties.
【0018】以下、このような構成の洗浄装置1におけ
る被洗浄物Sの洗浄方法について説明する。洗浄装置1
においては、洗浄時に、洗浄容器2の底部21付近に被
洗浄物Sが洗浄液Wの中に没水状態に収容され、その上
側に振動子31の照射面31aが同じく洗浄液Wに没水
状態とされる。このとき、加振手段(超音波照射手段)
3の振動子31の照射面31aと振動反射板(超音波反
射板)4との間隔が略2cm以下とされるとともに、振
動子31の照射面31aと被洗浄物Sとの間隔が1cm
以下、好ましくは0.5cm以下、例えば0cmに設定
される。Hereinafter, a method of cleaning the object S to be cleaned in the cleaning apparatus 1 having such a configuration will be described. Cleaning device 1
During cleaning, the object S to be cleaned is housed in the cleaning liquid W in the vicinity of the bottom 21 of the cleaning container 2 in the state of being submerged in the cleaning liquid W, and the irradiation surface 31a of the vibrator 31 is in the state of being submerged in the cleaning liquid W in the upper side. Is done. At this time, vibration means (ultrasonic irradiation means)
The distance between the irradiation surface 31a of the vibrator 31 and the vibration reflection plate (ultrasonic reflection plate) 4 is approximately 2 cm or less, and the distance between the irradiation surface 31a of the vibrator 31 and the object S to be cleaned is 1 cm.
Below, preferably set to 0.5 cm or less, for example, 0 cm.
【0019】次いで、加振手段(超音波照射手段93の
発振回路32により発振された高周波電流を増幅器33
を介して振動子31に供給することにより、振動子31
を振動させて、被洗浄物Sに振動または超音波を例えば
1分程度の照射時間で照射する。このとき、加えられる
音波または照射される超音波の周期が、発振回路32に
より0.1kHz〜100kHzの範囲に、好ましくは
0.5kHz〜50kHzの範囲のうち被洗浄物Sの材
質等の種類により28kHzに設定される。Next, the high-frequency current oscillated by the oscillating circuit 32 of the vibration means
Is supplied to the vibrator 31 through the
Is vibrated, and the object to be cleaned S is irradiated with vibrations or ultrasonic waves for an irradiation time of, for example, about 1 minute. At this time, the period of the applied sound wave or the applied ultrasonic wave is set in the range of 0.1 kHz to 100 kHz by the oscillation circuit 32, preferably in the range of 0.5 kHz to 50 kHz, depending on the kind of the material of the object S to be cleaned. It is set to 28 kHz.
【0020】振動子31から加えられた振動または照射
された超音波は被洗浄物S付近に到達し、キャビテーシ
ョン効果により、洗浄液W中において真空空洞が発生,
消滅する現象が繰り返される。この際の機械的な力によ
り汚れに衝撃を与えて剥離させるとともに、振動または
超音波の伝達によって、洗浄液Wの微少振動が起こり、
被洗浄物Sが振動し付着した汚れを振り切る。上述のよ
うに、汚れの分離除去が行われると同時に、振動子31
から加えられた振動または照射された超音波は、振動子
31の照射面31aと振動反射板(超音波反射板)4と
によって反射されて被洗浄物Sに集中し、あたかも増幅
されるごとく被洗浄物Sの汚れを分離除去する。The vibration applied from the vibrator 31 or the radiated ultrasonic wave reaches the object S to be cleaned, and a vacuum cavity is generated in the cleaning liquid W due to the cavitation effect.
The phenomenon of disappearance is repeated. At this time, the mechanical force exerts an impact on the dirt to separate the dirt, and the vibration or the transmission of the ultrasonic wave causes the micro vibration of the cleaning liquid W,
The cleaning target S vibrates and shakes off the adhered dirt. As described above, at the same time as the dirt is separated and removed, the vibrator 31 is removed.
The ultrasonic waves applied or irradiated by the ultrasonic wave are reflected by the irradiation surface 31a of the vibrator 31 and the vibration reflection plate (ultrasonic reflection plate) 4 and are concentrated on the object S to be cleaned, as if amplified. The dirt of the cleaning object S is separated and removed.
【0021】被洗浄物Sの水没状態とされた洗浄液W
は、アニオン界面活性剤とノニオン界面活性剤とをそれ
ぞそれ好適な濃度で含み、かつ酵素を含んでいるので、
界面活性剤の物理化学的な洗浄効果と、振動または超音
波によるキャビテーション効果および洗浄液Wの振動・
直進流作用による洗浄効果とが相乗効果を示し、被洗浄
物Sの汚れを洗浄することができる。振動または超音波
による洗浄が終了した後に、温水などで濯ぎ洗いすれ
ば、被洗浄物Sは清浄化される。また、振動子31が洗
浄容器2から取り外し及び移動可能とされているので、
部分洗い等に適用することが可能である。The cleaning liquid W in which the object S to be cleaned is submerged.
Contains an anionic surfactant and a nonionic surfactant at suitable concentrations, respectively, and contains an enzyme,
Physicochemical cleaning effect of surfactant, cavitation effect by vibration or ultrasonic wave and vibration of cleaning liquid W
The cleaning effect by the straight flow action shows a synergistic effect, and the dirt on the cleaning target S can be cleaned. After the cleaning by the vibration or the ultrasonic wave is completed, the object to be cleaned S is cleaned by rinsing with warm water or the like. Further, since the vibrator 31 is detachable and movable from the cleaning container 2,
It can be applied to partial washing and the like.
【0022】以下、本発明に係る繊維製品の洗浄装置お
よび洗浄方法の第2実施形態を、図面に基づいて説明す
る。図2において、第1実施形態と異なる箇所は以下の
点である。加振手段(超音波照射手段)3の振動子31
Aが、図1に示すように、圧電セラミックとされて洗浄
容器2の底部21と一体に配される。また、振動反射板
(超音波反射板)4Aが、図1に示すように、例えば洗
浄容器2から取り外しおよび移動可能な平板形状とさ
れ、その面積が、洗浄容器2の底部21の面積より小さ
く設定される。振動反射板(超音波反射板)4Aの材質
としては、例えば前記反射率71パーセントのアルミニ
ウム製とされる。Hereinafter, a second embodiment of the apparatus and method for cleaning textile products according to the present invention will be described with reference to the drawings. In FIG. 2, the points different from the first embodiment are as follows. Vibrator 31 of vibration means (ultrasonic irradiation means) 3
As shown in FIG. 1, A is made of piezoelectric ceramic and is disposed integrally with the bottom 21 of the cleaning container 2. As shown in FIG. 1, the vibration reflection plate (ultrasonic reflection plate) 4 </ b> A has, for example, a flat plate shape that can be removed and moved from the cleaning container 2, and the area thereof is smaller than the area of the bottom 21 of the cleaning container 2. Is set. The material of the vibration reflection plate (ultrasonic reflection plate) 4A is, for example, aluminum having the reflectance of 71%.
【0023】また、洗浄液Wは、界面活性剤のうち、例
えば、アニオン界面活性剤として、α−オレフィンスル
ホン酸カリウム2重量%、オレイン酸カリウム15重量
%、ノニオン界面活性剤として、POE(10)アルキ
ル(C12)エーテル30重量%が含まれ、酵素として、
例えば、プロテアーゼ0.1重量%が含まれている。The washing liquid W contains, for example, 2% by weight of potassium α-olefin sulfonate, 15% by weight of potassium oleate as anionic surfactant, and POE (10) as nonionic surfactant. It contains 30% by weight of alkyl (C 12 ) ether, and as an enzyme,
For example, it contains 0.1% by weight of protease.
【0024】このような構成においては、洗浄時におい
て、洗浄容器2の底部21付近に被洗浄物Sが洗浄液W
の中に没水状態に収容され、その上側に振動反射板(超
音波反射板)4Aが同じく洗浄液Wに没水状態とされ
る。このとき、振動子31Aの照射面31aと振動反射
板(超音波反射板)4Aとの間隔が略2cm以下とされ
るとともに、加振手段(超音波照射手段)3の照射面3
1aと被洗浄物Sの間隔が1cm以下、好ましくは0.
5cm以下、例えば0.5cmに設定される。このと
き、加えられる振動または照射される超音波の周期が、
発振回路32により0.1kHz〜100kHzの範囲
に、好ましくは0.5kHz〜50kHzの範囲のうち
被洗浄物Sの材質等の種類により20kHzに設定され
る。In such a configuration, at the time of cleaning, the object S to be cleaned is placed near the bottom 21 of the cleaning container 2 with the cleaning liquid W.
The vibration reflection plate (ultrasonic reflection plate) 4A is similarly submerged in the cleaning liquid W on the upper side. At this time, the distance between the irradiation surface 31a of the vibrator 31A and the vibration reflection plate (ultrasonic reflection plate) 4A is set to approximately 2 cm or less, and the irradiation surface 3 of the vibration unit (ultrasonic irradiation unit) 3 is set.
1a and the object to be cleaned S are 1 cm or less, preferably 0.1 cm or less.
It is set to 5 cm or less, for example, 0.5 cm. At this time, the cycle of the applied vibration or the applied ultrasonic wave is
The oscillation circuit 32 sets the frequency in the range of 0.1 kHz to 100 kHz, preferably in the range of 0.5 kHz to 50 kHz, to 20 kHz depending on the material and the like of the article S to be cleaned.
【0025】この実施形態においても、第1実施形態と
同様にして被洗浄物Sの洗浄が行われる。Also in this embodiment, the object S is cleaned in the same manner as in the first embodiment.
【0026】以下、本発明に係る繊維製品の洗浄装置お
よび洗浄方法の第3実施形態を、図面に基づいて説明す
る。図3において、第1実施形態と異なる箇所は、被洗
浄物Sが例えば繊維製等の靴とされ、加振手段(超音波
照射手段)3の振動子31Bが、フェライト等の磁歪素
子、または、粉末冶金等の超磁歪素子とされ、かつ、前
記靴Sの内部に挿入可能な形状とされ、振動反射板(超
音波反射板)4Bが、洗浄容器2の側部22と一体とさ
れ、かつ靴Sを外側から包み込むように内部に挿入可能
な形状とされた点である。Hereinafter, a third embodiment of the apparatus and method for cleaning textile products according to the present invention will be described with reference to the drawings. In FIG. 3, a different point from the first embodiment is that the object to be cleaned S is, for example, a shoe made of fiber or the like, and the vibrator 31 </ b> B of the vibrating means (ultrasonic irradiation means) 3 is a magnetostrictive element such as ferrite, or , A giant magnetostrictive element such as powder metallurgy, and a shape that can be inserted into the shoe S, and a vibration reflection plate (ultrasonic reflection plate) 4B is integrated with the side portion 22 of the cleaning container 2, In addition, the shape is such that the shoe S can be inserted inside so as to wrap it from the outside.
【0027】このような構成においては、洗浄時におい
て、洗浄容器2の内部に被洗浄物(靴)Sを洗浄液Wの
中に没水状態に収容して、靴Sの内部に振動子31Bを
同じく洗浄液Wに没水状態とする。このとき、振動子3
1Bの照射面31aと振動反射板(超音波反射板)4B
との間隔が略2cm以下とされるとともに、加振手段
(超音波照射手段)3の照射面31aと被洗浄物Sの間
隔が1cm以下、好ましくは0.5cm以下に設定され
る。In such a configuration, at the time of cleaning, the object to be cleaned (shoes) S is stored in the cleaning liquid W in the washing container 2 in a submerged state, and the vibrator 31B is placed inside the shoes S. Similarly, it is immersed in the cleaning liquid W. At this time, the vibrator 3
1B irradiation surface 31a and vibration reflection plate (ultrasonic reflection plate) 4B
Is set to approximately 2 cm or less, and the interval between the irradiation surface 31a of the vibrating means (ultrasonic irradiation means) 3 and the object to be cleaned S is set to 1 cm or less, preferably 0.5 cm or less.
【0028】この実施形態においては、振動子31Bと
振動反射板(超音波反射板)4Bとが靴Sを内外から挟
む状態として、第1および第2実施形態と同様に、被洗
浄物(靴)Sの洗浄が行われる。In this embodiment, as in the first and second embodiments, the object to be cleaned (the shoe) is sandwiched between the vibrator 31B and the vibration reflection plate (ultrasonic reflection plate) 4B with the shoe S from inside and outside. ) S cleaning is performed.
【0029】以下、本発明に係る繊維製品の洗浄装置お
よび洗浄方法の第4実施形態を、図面に基づいて説明す
る。図4において、第1実施形態と異なる箇所は、洗浄
容器2の内部に少なくとも2本のローラ5,5が間隔を
あけて対向位置に配され、該2本のローラ5,5の間に
加振手段(超音波照射手段)3の振動子31と振動反射
板(超音波反射板)4とが対向位置に配され、前記2本
のローラ5,5にはローラ6,6がそれぞれ接触状態に
配されるとともに、該2本のローラ5の少なくとも1本
には図示しない駆動手段が接続されて、被洗浄物Sが絨
毯、カーテン等の長尺物とされた点である。Hereinafter, a fourth embodiment of an apparatus and method for cleaning textile products according to the present invention will be described with reference to the drawings. In FIG. 4, a different point from the first embodiment is that at least two rollers 5, 5 are arranged at opposing positions with an interval inside the cleaning container 2, and an additional space is provided between the two rollers 5, 5. The vibrator 31 of the vibrating means (ultrasonic wave irradiating means) 3 and the vibration reflecting plate (ultrasonic reflecting plate) 4 are arranged at opposing positions, and the rollers 6, 6 are in contact with the two rollers 5, 5, respectively. And a driving means (not shown) is connected to at least one of the two rollers 5 so that the object S to be cleaned is a long object such as a carpet or a curtain.
【0030】このような構成においては、洗浄時におい
て、洗浄容器2の内部において、ローラ5,5と被洗浄
物(絨毯)Sとを洗浄液Wの中に没水状態として、同じ
く洗浄液Wに没水状態とした振動子31と振動反射板
(超音波反射板)4との間にローラ5,6により被洗浄
物Sが送通される。このとき、加振手段(超音波照射手
段)3の照射面31aと被洗浄物Sの間隔が1cm以
下、好ましくは0.5cm以下に設定される。In such a configuration, at the time of cleaning, the rollers 5, 5 and the object to be cleaned (carpet) S are immersed in the cleaning liquid W inside the cleaning container 2, and are immersed in the cleaning liquid W. The cleaning object S is sent by the rollers 5 and 6 between the vibrator 31 in the water state and the vibration reflection plate (ultrasonic reflection plate) 4. At this time, the distance between the irradiation surface 31a of the vibration means (ultrasonic wave irradiation means) 3 and the object S to be cleaned is set to 1 cm or less, preferably 0.5 cm or less.
【0031】この実施形態においては、ローラ5,6は
図示しない駆動手段により回転駆動され、被洗浄物(絨
毯)Sが、振動子31と振動反射板(超音波反射板)4
との間を所定の速度により移動しつつ、第1および第2
実施形態と同様に、洗浄が行われる。このため、被洗浄
物(絨毯)Sをローラ5,6にセットするだけで洗浄を
行うことができる。In this embodiment, the rollers 5 and 6 are driven to rotate by driving means (not shown), and the object to be cleaned (carpet) S is divided into a vibrator 31 and a vibration reflection plate (ultrasonic reflection plate) 4.
While moving at a predetermined speed between the first and second
Cleaning is performed as in the embodiment. Therefore, cleaning can be performed only by setting the object to be cleaned (carpet) S on the rollers 5 and 6.
【0032】[0032]
【実施例】以下、本発明を実施例および比較例により、
具体的に説明するが、本発明はこれらの実施例のみに限
定されるものではない。 (試験例)図1または図2に示したように、洗浄液の組
成と加振手段(超音波照射手段)の条件と振動反射板
(超音波反射板)の材質とを本発明の範囲内で変化させ
て設定し、被洗浄物(泥汚れの汚垢布)に振動を加える
かまたは超音波を照射し、洗浄力および繊維の傷みにつ
いて評価試験を行った。また、振動反射板(超音波反射
板)をガラスとした実施例3、および、振動反射板(超
音波反射板)をアルミニウムとした実施例4についても
同様に評価試験を行った。The present invention will now be described by way of Examples and Comparative Examples.
Although specifically described, the present invention is not limited to only these examples. (Test Example) As shown in FIG. 1 or FIG. 2, the composition of the cleaning liquid, the condition of the vibrating means (ultrasonic irradiation means), and the material of the vibration reflecting plate (ultrasonic reflecting plate) are within the scope of the present invention. An evaluation test was performed for the cleaning power and the fiber damage by applying vibration or irradiating the object to be cleaned (dirty cloth with mud) with ultrasonic waves. An evaluation test was also performed in the same manner for Example 3 in which the vibration reflection plate (ultrasonic reflection plate) was made of glass and Example 4 in which the vibration reflection plate (ultrasonic reflection plate) was made of aluminum.
【0033】(比較例)前記実施例と同様であるが、洗
浄液が界面活性剤および酵素を含まない比較例1、振動
反射板(超音波反射板)にポリエチレンを用いた比較例
2、加振手段(超音波照射手段)の振動子と被洗浄物と
の距離が2.0cmの比較例3、および洗濯機で10分
間洗浄した比較例4について実施例と同様な評価試験を
行った。(Comparative Example) The same as the above example, but Comparative Example 1 in which the cleaning solution did not contain a surfactant and an enzyme, Comparative Example 2 in which polyethylene was used for the vibration reflection plate (ultrasonic reflection plate), The same evaluation test as that of the example was performed for Comparative Example 3 in which the distance between the vibrator of the means (ultrasonic irradiation means) and the object to be cleaned was 2.0 cm, and Comparative Example 4 in which washing was performed for 10 minutes with a washing machine.
【0034】評価試験は以下のように行った。15gの
赤土と水500mlとを均一に撹拌して、10cm×1
0cmの白色の綿繊維を含浸させた後、乾燥させて表面
の余分な土を払い、泥汚れの汚垢布を調整し被洗浄物と
した。含浸させる前の白色の綿繊維、含浸後の汚垢布、
および洗浄後の汚垢布の白度を色差計(SZ−Σ80,
日本電子工業製)で測定し、次の(式1)により洗浄力
を算出した。 洗浄力(%)=(Y1−Y0)/(X0−Y0)×100 (式1) ただし、 X0 :含浸させる前の白色の綿繊維の白度 Y0 :含浸後の汚垢布の白度 Y1 :洗浄後の汚垢布の白度 である。The evaluation test was performed as follows. 15 g of red clay and 500 ml of water are uniformly stirred, and 10 cm × 1
After impregnated with 0 cm of white cotton fiber, it was dried to remove excess soil on the surface, and a dirty cloth of mud stain was prepared to obtain a cleaning object. White cotton fiber before impregnation, dirty cloth after impregnation,
And the whiteness of the soiled cloth after washing is measured with a color difference meter (SZ- # 80,
The detergency was calculated by the following (Equation 1). Detergency (%) = (Y 1 −Y 0 ) / (X 0 −Y 0 ) × 100 (Equation 1) where X 0 : Whiteness of white cotton fiber before impregnation Y 0 : Soil after impregnation Whiteness of the stained cloth Y 1 : Whiteness of the stained cloth after washing.
【0035】また、繊維の傷みは、洗浄後において目視
により毛羽立ちを確認し、以下のように評価したもので
ある。 ◎:殆どない ○:ない △:ややある ×:かなりある 洗浄液,加振手段(超音波照射手段),および振動反射
板(超音波反射板)の条件と評価結果とを表1および表
2に示す。The damage of the fibers was evaluated by checking the fuzziness visually after washing and evaluating the fuzziness as follows. :: Almost none ○: Not available △: Slightly available ×: Appreciable Available Tables 1 and 2 show the conditions and evaluation results of the cleaning liquid, vibrating means (ultrasonic irradiation means), and vibration reflector (ultrasonic reflector). Show.
【0036】[0036]
【表1】 [Table 1]
【0037】[0037]
【表2】 [Table 2]
【0038】表1ないし表2の評価結果から、洗浄液が
界面活性剤を5重量%〜60重量%、酵素を0.01
重量%〜10重量%の範囲内で含み、洗浄時における、
加振手段(超音波照射手段)の照射面と被洗浄物の間隔
が1cm以下、好ましくは0.5cm以下に設定され、
振動子が、圧電セラミック、フェライト等の磁歪素子、
粉末冶金等の超磁歪素子とされ、振動反射板(超音波反
射板)の材質としては、水に対する音波反射率が60パ
ーセント以上のもの、例えば、ガラス、アルミニウム、
鋼鉄(SUS304)とされ、振動反射板(超音波照射
手段)から加えられる振動または照射される超音波は、
その周期が、0.1kHz〜100kHzに、好ましく
は0.5kHz〜60kHzの範囲に設定され、その出
力が20W〜60W、好ましくは30W〜50Wに設定
される実施例1ないし実施例4の洗浄装置および洗浄方
法は、洗浄力、繊維の傷み度合いの低さのいずれにも優
れており、実用性が高いと判断された。From the evaluation results in Tables 1 and 2, it was found that the cleaning solution contained 5% to 60% by weight of the surfactant and 0.01% of the enzyme.
% In the range of 10% by weight, and at the time of washing,
The distance between the irradiation surface of the vibration means (ultrasonic wave irradiation means) and the object to be cleaned is set to 1 cm or less, preferably 0.5 cm or less,
The vibrator is a magnetostrictive element such as piezoelectric ceramic or ferrite,
It is a giant magnetostrictive element such as powder metallurgy, and the material of the vibration reflection plate (ultrasonic reflection plate) has a sound wave reflectance of 60% or more to water, for example, glass, aluminum,
Vibration or ultrasonic waves applied from a vibration reflection plate (ultrasonic irradiation means), which is made of steel (SUS304),
The cleaning apparatus according to any one of Examples 1 to 4 in which the cycle is set to 0.1 kHz to 100 kHz, preferably 0.5 kHz to 60 kHz, and the output is set to 20 W to 60 W, preferably 30 W to 50 W. The cleaning method was excellent in both detergency and low degree of fiber damage, and was judged to be highly practical.
【0039】表1ないし表2の評価結果から、比較例1
は、洗浄液が界面活性剤および酵素を含まないために洗
浄効果が劣り、比較例2は振動反射板(超音波反射板)
に反射率の低いポリエチレンを用いたため洗浄効果が低
下し、比較例3は加振手段(超音波照射手段)の照射面
と被洗浄物との距離が2.0cmと大きいために洗浄力
が著しく低下しており実用性に乏しく、比較例4は洗濯
機で10分間洗浄しても、汚れが充分落ちない上、繊維
の傷みが生じていると判断された。From the evaluation results in Tables 1 and 2, Comparative Example 1
Is inferior in cleaning effect because the cleaning solution does not contain a surfactant and an enzyme, and Comparative Example 2 is a vibration reflection plate (ultrasonic reflection plate).
The cleaning effect deteriorated because polyethylene having low reflectance was used, and in Comparative Example 3, the distance between the irradiated surface of the vibration means (ultrasonic irradiation means) and the object to be cleaned was as large as 2.0 cm, so that the cleaning power was remarkable. In Comparative Example 4, it was judged that the stain was not sufficiently removed even after washing for 10 minutes in a washing machine, and that the fiber was damaged.
【0040】また、以上の実施例は、必ずしも洗浄容器
を必要とするものではなく、被洗浄物に洗浄剤を含浸
し、該被洗浄物に振動子と振動反射板(超音波反射板)
とを直接接触させることで効率よく洗浄することができ
る。この際、洗浄装置は、例えば、加振手段(超音波照
射手段)の振動子と振動反射板(超音波反射板)とが、
一箇所で回動可能に接続された2本の棒状部材の各先端
部に対向状態に配された構造とすることもできる。本発
明の繊維製品の洗浄装置および洗浄方法によれば、従来
の洗濯機による洗浄等とは格段に優れた洗浄力ならびに
繊維の傷みの低さにより、ネクタイ等の高級繊維製品
や、絨毯等に対しても適用することができる。In the above embodiment, the cleaning container is not necessarily required, and the object to be cleaned is impregnated with the cleaning agent, and the object to be cleaned is vibrated by the vibrator and the vibration reflection plate (ultrasonic reflection plate).
By contacting directly with, cleaning can be performed efficiently. At this time, the cleaning device includes, for example, a vibrator of a vibration unit (ultrasonic irradiation unit) and a vibration reflection plate (ultrasonic reflection plate).
It is also possible to adopt a structure in which the two rod-shaped members rotatably connected at one position are disposed in opposition to the respective distal end portions. According to the textile device cleaning apparatus and method of the present invention, high-grade textile products such as ties, carpets, and the like, due to significantly superior detergency and low fiber damage compared to conventional washing machines. The same can be applied.
【0041】[0041]
【発明の効果】本発明の繊維製品の洗浄装置および洗浄
方法によれば、以下の効果を奏する。 (1)5重量%〜60重量%の範囲の界面活性剤、また
は、0.01重量%〜10重量%の範囲の酵素を少なく
とも含むものとされた洗浄液による洗浄と、加振手段
(超音波照射手段)の照射面と振動反射板(超音波反射
板)との間に被洗浄物が位置されて周波数0.1kHz
〜100kHzの範囲の振動または超音波による洗浄と
の相乗効果により、洗浄効果の向上を図ることができ
る。 (2)加振手段(超音波照射手段)の照射面から、洗浄
液および被洗浄物に1cm以下の至近距離から振動を加
えるかまたは超音波を照射し、かつ、水に対する反射率
60パーセント以上に設定された加振手段(超音波反射
板)により振動または超音波を反射して集中しているた
め、界面活性剤および酵素を含む洗浄液の洗浄力を向上
することができる。 (3)振動または超音波を照射して撹拌することなしに
洗浄を行うため、洗浄時における繊維への影響を低減す
ることができる。 (4)繊維を傷めずに洗浄を行うことができるので、ネ
クタイ等の高級繊維に対応して洗浄を行うことができ
る。 (5)加振手段(超音波照射手段)を洗浄容器から取り
外し可能としたので、部分洗いにも適用することができ
る。According to the apparatus and method for cleaning textile products of the present invention, the following effects can be obtained. (1) Washing with a washing liquid containing at least a surfactant in a range of 5% by weight to 60% by weight or an enzyme in a range of 0.01% by weight to 10% by weight; The object to be cleaned is positioned between the irradiation surface of the irradiation means) and the vibration reflection plate (ultrasonic reflection plate) and has a frequency of 0.1 kHz.
The cleaning effect can be improved by a synergistic effect with cleaning by vibration or ultrasonic waves in the range of 100 kHz to 100 kHz. (2) Vibration or ultrasonic wave is applied to the cleaning liquid and the object to be cleaned from a close distance of 1 cm or less from the irradiation surface of the vibration means (ultrasonic wave irradiation means), and the reflectance to water is 60% or more. Since the vibrating or ultrasonic waves are reflected and concentrated by the set vibrating means (ultrasonic reflecting plate), the cleaning power of the cleaning liquid containing the surfactant and the enzyme can be improved. (3) Since cleaning is performed without stirring by irradiating vibration or ultrasonic waves, the effect on the fibers during cleaning can be reduced. (4) Since cleaning can be performed without damaging the fibers, cleaning can be performed corresponding to high-grade fibers such as ties. (5) Since the vibration means (ultrasonic irradiation means) can be removed from the cleaning container, it can be applied to partial washing.
【図面の簡単な説明】[Brief description of the drawings]
【図1】 本発明に係る繊維製品の洗浄装置および洗浄
方法の第1実施形態を示す正断面図である。FIG. 1 is a front sectional view showing a first embodiment of a cleaning apparatus and a cleaning method for a textile product according to the present invention.
【図2】 本発明に係る繊維製品の洗浄装置および洗浄
方法の第2実施形態を示す正断面図である。FIG. 2 is a front sectional view showing a second embodiment of a cleaning apparatus and a cleaning method for a textile product according to the present invention.
【図3】 本発明に係る繊維製品の洗浄装置および洗浄
方法の第3実施形態を示す正断面図である。FIG. 3 is a front sectional view showing a third embodiment of a cleaning apparatus and a cleaning method for a textile product according to the present invention.
【図4】 本発明に係る繊維製品の洗浄装置および洗浄
方法の第4実施形態を示す正断面図である。FIG. 4 is a front sectional view showing a fourth embodiment of a cleaning apparatus and a cleaning method for textile products according to the present invention.
W…洗浄液 S…被洗浄物 1…洗浄装置 2…洗浄容器 3…加振手段(超音波照射手段) 4…振動反射板(超音波反射板) 4A…振動反射板(超音波反射板) 4B…振動反射板(超音波反射板) 5…ローラ 6…ローラ 21…底部 22…側部 31…振動子 31a…照射面 31b…コイル 31A…振動子 31B…振動子 32…発振回路 33…増幅器 34…電力計 W: Cleaning liquid S: Object to be cleaned 1: Cleaning device 2: Cleaning container 3: Vibration means (ultrasonic irradiation means) 4: Vibration reflection plate (ultrasonic reflection plate) 4A: Vibration reflection plate (ultrasonic reflection plate) 4B ... vibration reflection plate (ultrasonic reflection plate) 5 ... roller 6 ... roller 21 ... bottom part 22 ... side part 31 ... vibrator 31a ... irradiation surface 31b ... coil 31A ... vibrator 31B ... vibrator 32 ... oscillator circuit 33 ... amplifier 34 …Watt meter
Claims (4)
振手段と、該加振手段の対向位置に配される振動反射板
とを具備し、洗浄時に加振手段の照射面と振動反射板と
の間に被洗浄物が位置される洗浄装置であって、加振手
段の照射面と被洗浄物との間隔が1cm以下に設定さ
れ、振動反射板の水に対する音波反射率が、60パーセ
ント以上に設定され、洗浄液が、5重量%〜60重量%
の範囲の界面活性剤、または、0.01重量%〜10重
量%の範囲の酵素を少なくとも含むものとされたことを
特徴とする繊維製品の洗浄装置。1. An oscillating means for applying vibration to a cleaning liquid and an object to be cleaned, and a vibrating reflector disposed at a position facing the vibrating means, wherein an irradiation surface of the vibrating means and a vibrating reflector during cleaning are provided. And the distance between the irradiation surface of the vibrating means and the object to be cleaned is set to 1 cm or less, and the sound reflectance of the vibration reflection plate against water is 60%. The washing liquid is set as described above, and the washing liquid is 5% by weight to 60% by weight.
A cleaning device for textiles, characterized by containing at least a surfactant in the range of 0.01% by weight or an enzyme in the range of 0.01% by weight to 10% by weight.
る超音波照射手段と、該超音波照射手段の対向位置に配
される超音波反射板とを具備し、洗浄時に超音波照射手
段の照射面と超音波反射板との間に被洗浄物が位置され
る洗浄装置であって、超音波照射手段の照射面と被洗浄
物との間隔が1cm以下に設定され、超音波反射板の水
に対する音波反射率が、60パーセント以上に設定さ
れ、洗浄液が、5重量%〜60重量%の範囲の界面活性
剤、または、0.01重量%〜10重量%の範囲の酵素
を少なくとも含むものとされたことを特徴とする繊維製
品の洗浄装置。2. An ultrasonic irradiating means for irradiating an ultrasonic wave to a cleaning liquid and an object to be cleaned, and an ultrasonic reflector disposed at a position opposite to the ultrasonic irradiating means, wherein the ultrasonic irradiating means is used for cleaning. A cleaning device in which an object to be cleaned is positioned between an irradiation surface and an ultrasonic reflecting plate, wherein the distance between the irradiation surface of the ultrasonic irradiation means and the object to be cleaned is set to 1 cm or less, and the ultrasonic reflecting plate The sound wave reflectance to water is set to 60% or more, and the cleaning solution contains at least a surfactant in a range of 5% to 60% by weight or an enzyme in a range of 0.01% to 10% by weight. An apparatus for cleaning textile products.
振動を加えるとともに、該加振手段の対向位置に配され
る振動反射板により振動波を反射させて被洗浄物を洗浄
する際に、加振手段の照射面と振動反射板との間に洗浄
液および被洗浄物を配置し、加振手段の照射面と被洗浄
物との間隔を1cm以下に設定し、振動反射板として、
水に対する音波反射率が60パーセント以上のものを用
い、洗浄液が、5重量%〜60重量%の範囲の界面活性
剤、または、0.01重量%〜10重量%の範囲の酵素
を少なくとも含むものを用いることを特徴とする繊維製
品の洗浄方法。3. When the vibration is applied to the cleaning liquid and the object to be cleaned by the vibration means, and the vibration wave is reflected by the vibration reflection plate disposed at a position facing the vibration means to clean the object to be cleaned. The cleaning liquid and the object to be cleaned are arranged between the irradiation surface of the vibrating means and the vibration reflecting plate, and the distance between the irradiation surface of the vibrating means and the object to be cleaned is set to 1 cm or less.
A solution having a sound wave reflectance of 60% or more with respect to water, and the cleaning solution contains at least a surfactant in a range of 5% to 60% by weight or an enzyme in a range of 0.01% to 10% by weight. CLEANING METHOD OF FIBER PRODUCTS, characterized by using.
により超音波を照射するとともに、該超音波照射手段の
対向位置に配される超音波反射板により超音波を反射さ
せて被洗浄物を洗浄する際に、超音波照射手段の照射面
と超音波反射板との間に洗浄液および被洗浄物を配置
し、超音波照射手段の照射面と被洗浄物との間隔を1c
m以下に設定し、超音波反射板として、水に対する音波
反射率が60パーセント以上のものを用い、洗浄液が、
5重量%〜60重量%の範囲の界面活性剤、または、
0.01重量%〜10重量%の範囲の酵素を少なくとも
含むものを用いることを特徴とする繊維製品の洗浄方
法。4. A cleaning liquid and an object to be cleaned are irradiated with ultrasonic waves by an ultrasonic irradiating means, and the ultrasonic waves are reflected by an ultrasonic reflecting plate arranged at a position facing the ultrasonic irradiating means to clean the object to be cleaned. When cleaning, the cleaning liquid and the object to be cleaned are arranged between the irradiation surface of the ultrasonic irradiation means and the ultrasonic reflecting plate, and the distance between the irradiation surface of the ultrasonic irradiation means and the object to be cleaned is 1c.
m or less, as the ultrasonic reflection plate, using a thing whose sound wave reflectance to water is 60% or more, the cleaning liquid,
A surfactant in the range of 5% to 60% by weight, or
A method for cleaning textiles, comprising using an enzyme containing at least 0.01% by weight to 10% by weight of an enzyme.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9142822A JPH10328472A (en) | 1997-05-30 | 1997-05-30 | Device for washing fibrous product and its method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9142822A JPH10328472A (en) | 1997-05-30 | 1997-05-30 | Device for washing fibrous product and its method |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH10328472A true JPH10328472A (en) | 1998-12-15 |
Family
ID=15324443
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9142822A Withdrawn JPH10328472A (en) | 1997-05-30 | 1997-05-30 | Device for washing fibrous product and its method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH10328472A (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6493289B2 (en) | 2000-04-28 | 2002-12-10 | Kao Corporation | Ultrasonic cleaning apparatus |
JP2007145961A (en) * | 2005-11-25 | 2007-06-14 | Toei Buhin Kk | Sterilizing cleanser and method for removing stains therewith |
CN104088112A (en) * | 2014-07-30 | 2014-10-08 | 祁国祥 | Vibration type washing machine and portable vibration type washing machine |
CN107268227A (en) * | 2017-08-02 | 2017-10-20 | 合肥美的洗衣机有限公司 | Portable Washing Equipment |
JP2018143950A (en) * | 2017-03-03 | 2018-09-20 | 青島海爾洗衣机有限公司QingDao Haier Washing Machine Co.,Ltd. | Ultrasonic cleaning device and washing machine |
WO2018196626A1 (en) * | 2017-04-25 | 2018-11-01 | 青岛海尔洗衣机有限公司 | Portable ultrasonic washing device |
WO2018210115A1 (en) * | 2017-05-15 | 2018-11-22 | 青岛海尔洗衣机有限公司 | Wall-mounted ultrasonic washing device |
CN109137365A (en) * | 2017-06-16 | 2019-01-04 | 青岛海尔洗衣机有限公司 | A kind of informed later |
KR102150376B1 (en) * | 2019-08-27 | 2020-09-01 | (주)대주기계 | Improvement method of textile surface using underwater shock wave |
-
1997
- 1997-05-30 JP JP9142822A patent/JPH10328472A/en not_active Withdrawn
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6493289B2 (en) | 2000-04-28 | 2002-12-10 | Kao Corporation | Ultrasonic cleaning apparatus |
JP2007145961A (en) * | 2005-11-25 | 2007-06-14 | Toei Buhin Kk | Sterilizing cleanser and method for removing stains therewith |
CN104088112A (en) * | 2014-07-30 | 2014-10-08 | 祁国祥 | Vibration type washing machine and portable vibration type washing machine |
JP2018143950A (en) * | 2017-03-03 | 2018-09-20 | 青島海爾洗衣机有限公司QingDao Haier Washing Machine Co.,Ltd. | Ultrasonic cleaning device and washing machine |
WO2018196626A1 (en) * | 2017-04-25 | 2018-11-01 | 青岛海尔洗衣机有限公司 | Portable ultrasonic washing device |
WO2018210115A1 (en) * | 2017-05-15 | 2018-11-22 | 青岛海尔洗衣机有限公司 | Wall-mounted ultrasonic washing device |
CN109137365A (en) * | 2017-06-16 | 2019-01-04 | 青岛海尔洗衣机有限公司 | A kind of informed later |
CN109137365B (en) * | 2017-06-16 | 2021-11-16 | 天津海尔洗涤电器有限公司 | Ultrasonic washing device |
CN107268227A (en) * | 2017-08-02 | 2017-10-20 | 合肥美的洗衣机有限公司 | Portable Washing Equipment |
CN107268227B (en) * | 2017-08-02 | 2019-07-19 | 合肥美的洗衣机有限公司 | Portable Washing Equipment |
KR102150376B1 (en) * | 2019-08-27 | 2020-09-01 | (주)대주기계 | Improvement method of textile surface using underwater shock wave |
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Legal Events
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A300 | Application deemed to be withdrawn because no request for examination was validly filed |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 20040803 |