JPH10316544A - Hair shampoo composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain the subject composition having low stimulation, excellent in foam properties, conditioning effects and stability with time by formulating specific two system of anionic surfactants with a specific cationic surfactant in a specified ratio. SOLUTION: This composition is obtained by combining (A) an anionic surfactant of the type of formula I [R<1> is an alkyl, etc.; R<2> is an alkyl, etc.; M<1> is an alkali metal, etc.; one of X and Y is H and the other is SO3 M<2> (M<2> is an alkali metal, etc.)] and (B) an anionic surfactant of the type of an ether-sulfate, an acyl-alkyl-taurate, acyl-isethionate or formula II [R<7> CO is an aliphatic acyl; R<8> is an alkyl, etc.; (m) is 2-15; M<6> is an alkali metal, etc.] with (C) a cationic surfactant of the type of a quaternary ammonium salt, formula III (R<13> is an alkyl, etc.; Y<-> is a halogen, etc.) or an amide quaternary ammonium so that the proportion of the components A+B may be 5-60 wt.%, the weight ratio of the components A/B may be (1/20) to (20/1), and the proportion of the component C may be 0.05-5 wt.%.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

[0001] The present invention relates to a hair shampoo composition. More specifically, the present invention is hypoallergenic, excellent in foaming properties, excellent in foam quality, has an appropriate detergency, has good finger passing during shampooing and rinsing, and has an appropriate slimming feeling in rinsing. The present invention relates to a hair shampoo composition which provides an excellent conditioning effect after drying and has good stability over time.

[0002]

2. Description of the Related Art In recent years, the frequency of shampooing has been increasing irrespective of age and gender due to changes in lifestyle, and the demand for shampooing has also diversified. That is, in terms of performance, it is excellent in foaming properties, has an appropriate detergency, is excellent in use feeling when actually used, and the composition is stable over time, further used And so-called hypoallergenicity, and a hair shampoo composition that satisfies these requirements in total is desired. For example, attempts have been made to use hypoallergenic surfactants to obtain hypoallergenic hair shampoo compositions, and such surfactants include sulfosuccinate-type anionic surfactants. Examples of the composition using a sulfosuccinate-type anionic surfactant include a composition combining an amide ether sulfate-type anionic surfactant (JP-A-2-232298), a water-soluble natural polymer or a natural polymer. Composition comprising a combination of semi-synthetic polymers obtained by chemically modifying polymers (JP-A-2-10589)
No. 5), a composition comprising a combination of a fatty acid salt (Japanese Unexamined Patent Publication No.
No. 163116). Furthermore, in recent hair shampoo compositions, the finish after shampooing is regarded as important, and elements that have been required for rinsing and conditioners have been required for hair shampoo. It has been attempted to incorporate a cationic surfactant into such a hair shampoo composition for the purpose of finishing after washing the hair, and as such a hair shampoo composition, a nonionic surfactant is used. Composition comprising a combination of a quaternary ammonium salt of imidazoline type with a cationic surfactant or a dialkyldipolyoxyethylene hydroxyethylammonium salt type cationic surfactant with a carboxylate type anionic surfactant (JP-A-1-144496), amphoteric surfactants such as betaine-type amphoteric surfactants, monoalkyl-type quaternary ammonium salt-type cationic surfactants, and carboxylate-type anionic surfactants And the like (JP-A-62-288694). However, a hair shampoo composition using a sulfosuccinate ester type anionic surfactant has a problem with stability over time, and the composition thickens or separates, so that a low-irritating surfactant is used. Although it was an agent, its use was limited. In addition, in terms of performance alone, the foaming properties were low, the foam quality was slightly coarse, and a slimy feeling was left after use. On the other hand, for hair shampoo compositions that emphasize the finish after shampooing, those using cationic surfactants are limited in formulation, and when blended in an amount that imparts sufficient flexibility to hair, There are drawbacks in that the foaming properties and the stability over time are reduced, and the irritation is increased.

[0003]

DISCLOSURE OF THE INVENTION The present invention is low-irritant, excellent in foaming properties and foam quality, has a suitable detergency, has good finger passing during shampooing and rinsing, and has a moderate rinsing property. The object of the present invention is to provide a hair shampoo composition which has a slick feeling, has an excellent conditioning effect after drying, and has good stability over time.

[0004]

Means for Solving the Problems The present inventors have conducted intensive studies to solve the above-mentioned problems, and as a result, (A) a sulfosuccinamide type anionic surfactant, (B) an ether sulfate type, Acyl alkyl taurate type, acyl isethionate type or amide ether sulfate type anionic surfactant and (C) quaternary ammonium salt type, isoquinolinium salt type or amide quaternary ammonium type cationic surfactant By combining them in a specific ratio, the above-mentioned drawbacks were solved, and it was found that a hair shampoo composition having an unprecedented characteristic was obtained, and the present invention was completed based on this finding. That is, the present invention provides, as the component (A), a sulfosuccinamide type anionic surfactant represented by the general formula [1]:

Embedded image (Wherein, R ¹ is an alkyl group or alkenyl group having 10 to 22 carbon atoms, R ² is hydrogen, an alkyl group having 1 to 3 carbon atoms or a hydroxyethyl group, and M ¹ is hydrogen, an alkali metal X or Y is one of hydrogen and the other is —SO ₃ M ² , and M ² is hydrogen, an alkali metal, an alkaline earth metal, ammonium or an organic ammonium. The ether sulfate type anionic surfactant represented by the general formula [2] as the component (B) R ³ O (CH ₂ CH ₂ O) n SO ₃ M ³ ... [2] Wherein R ³ is an alkyl group or alkenyl group having 10 to 22 carbon atoms, n is 0 to 15, and M ³ is hydrogen, an alkali metal, an alkaline earth metal, ammonium or organic ammonium. Acylalkyl taurate type anionic surfactant represented by general formula [3]

Embedded image (Wherein, R ⁴ CO is an aliphatic acyl group having 10 to 22 carbon atoms, R ⁵ is an alkyl group having 1 to 3 carbon atoms, M ⁴ is hydrogen, an alkali metal, an alkaline earth metal, Ammonium or organic ammonium), an acyl isethionate-type anionic surfactant represented by the general formula [4] R ⁶ COOCH ₂ CH ₂ SO ₃ M ⁵ ... [4] ⁶ CO is an aliphatic acyl group having 10 to 22 carbon atoms, and M ⁵ is hydrogen, an alkali metal, an alkaline earth metal, ammonium or organic ammonium.) Or an amide represented by the general formula [5] Ether sulfate type anionic surfactant

Embedded image (Where R ⁷ CO is an aliphatic acyl group having 10 to 22 carbon atoms, R ⁸ is hydrogen or an alkyl group having 1 to 3 carbon atoms, m is 2 to 15, and M ⁶ is Hydrogen, an alkali metal, an alkaline earth metal, ammonium or organic ammonium), a quaternary ammonium salt type cationic surfactant represented by the general formula [6] as a component (C),

Embedded image (Where R ⁹ is an alkyl or alkenyl group having 10 to 22 carbon atoms, R ¹⁰ and R ¹¹ are a methyl group, an ethyl group or — (CH ₂ CH ₂ O) pH, and p is 1 to 20, R ¹² is an alkyl group, an alkenyl group or a benzyl group having 1 to 22 carbon atoms, and X ⁻ is a halogen ion or an alkyl sulfate ion having 1 to 2 carbon atoms.) Isoquinolinium salt type cationic surfactant represented

Embedded image (Wherein, R ¹³ is an alkyl group or alkenyl group having 10 to 22 carbon atoms, and Y ⁻ is a halogen ion or an alkyl sulfate ion having 1 to 2 carbon atoms), or the general formula [8]. Amide quaternary ammonium salt type cationic surfactant represented by

Embedded image (Wherein, R ¹⁴ CO is an aliphatic acyl group having 10 to 22 carbon atoms, R ¹⁵ and R ¹⁶ are a methyl group, an ethyl group or — (CH ₂ CH ₂ O) qH, and q is 1 to 20 and R ¹⁷
Is a methyl group, an ethyl group or a benzyl group, and Z ^- is a halogen ion or an alkyl sulfate ion having 1 to 2 carbon atoms. The total content of the components (A) and (B) is 5 to 60% by weight, and the weight ratio of the components (A) and (B) is 1/20 to 20/1. , (C) component content is 0.
0.5 to 5% by weight of a hair shampoo composition.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION The hair shampoo composition of the present invention contains, as a component (A), a sulfosuccinamide type anionic surfactant represented by the general formula [1].

Embedded image In the general formula [1], R ¹ is an alkyl group or an alkenyl group having 10 to 22 carbon atoms, and R ² is hydrogen,
A to 3 alkyl group or a hydroxyethyl group, M ¹
Is hydrogen, an alkali metal, an alkaline earth metal, ammonium or an organic ammonium; one of X and Y is hydrogen and the other is —SO ₃ M ² ; and M ² is hydrogen, an alkali metal, an alkaline earth metal. , Ammonium or organic ammonium. In the general formula [1], examples of the alkyl group or alkenyl group having 10 to 22 carbon atoms represented by R ¹ include a linear or branched decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, Examples thereof include a pentadecyl group, a hexadecyl group, a heptadecyl group, an octadecyl group, an oleyl group, a nonadecyl group, an eicosyl group, a docosyl group, and a mixture of coconut oil alkyl group and tallow alkyl group. R ¹
When the carbon number of the alkyl group or alkenyl group represented by is 9 or less, irritation to hair and skin may be too strong. If the alkyl group or alkenyl group represented by R ¹ has 23 or more carbon atoms, the foaming properties and the temporal stability of the hair shampoo composition may be reduced.

In the general formula [1], examples of the alkyl group having 1 to 3 carbon atoms represented by R ² include a methyl group, an ethyl group, a propyl group and an isopropyl group. In the general formula [1], the number of carbon atoms represented by R ¹ is 10
If the alkyl group represented by R ² has 4 or more carbon atoms in addition to the alkyl group or alkenyl group of No. 22 to No. 22, the foaming properties and the temporal stability of the hair shampoo composition may be reduced. In the general formula [1], examples of the alkali metal represented by M ¹ include lithium, sodium and potassium, and examples of the alkaline earth metal include カ ル シ ウ ム calcium and マ グ ネ シ ウ ム magnesium. Can be mentioned. In the general formula [1], M ¹
In The ammonium or organic ammonium represented, -NH _4, ammonium organic group is one substituent, ammonium organic group has two substituents, organic groups can be exemplified 3-substituted ammonium. Examples of the organic amine that forms such an organic ammonium include, for example,
Aliphatic amines such as methylamine, ethylamine, propylamine, butylamine, hexylamine, and octylamine; alkanolamines such as ethanolamine, diethanolamine, triethanolamine, isopropanolamine, diisopropanolamine, and triisopropanolamine; and aromatics such as aniline Heterocyclic amines such as amine, morpholine, pyridine, pyrrolidine and piperidine can be mentioned.

In the general formula [1], one of X and Y is hydrogen, the other is —SO ₃ M ² ,
² is hydrogen, alkali metal, alkaline earth metal, ammonium or organic ammonium. In the general formula [1], examples of the alkali metal represented by M ² include lithium, sodium, and potassium, and examples of the alkaline earth metal include 例 え ば calcium and 、 magnesium. Can be mentioned.
In the general formula [1], examples of the ammonium or organic ammonium represented by M ² include —NH ₄ , ammonium having one substituted organic group, ammonium having two substituted organic groups, and ammonium having three substituted organic groups. Can be mentioned. Examples of the organic amine forming such an organic ammonium include, for example, methylamine, ethylamine, propylamine, butylamine, hexylamine,
Aliphatic amines such as octylamine, alkanolamines such as ethanolamine, diethanolamine, triethanolamine, isopropanolamine, diisopropanolamine and triisopropanolamine, aromatic amines such as aniline, and heterocycles such as morpholine, pyridine, pyrrolidine and piperidine Examples include formula amines. In the hair shampoo composition of the present invention, the sulfosuccinamide-type anionic surfactant represented by the general formula [1], which is the component (A), may be a single compound, or Two or more compounds can be used in combination.

The hair shampoo composition of the present invention comprises, as a component (B), an ether sulfate type anionic surfactant represented by the general formula [2]: R ³ O (C ₂ H ₄ O) n SO ₃ M ³ ... [2] an acylalkyl taurate type anionic surfactant represented by the general formula [3],

Embedded image Acyl isethionate type anionic surfactant represented by the general formula [4], R ⁶ COOCH ₂ CH ₂ SO ₃ M ⁵ ... [4] or amide ether sulfate type represented by the general formula [5] Anionic surfactants,

Embedded image It contains.

In the ether sulfate type anionic surfactant represented by the general formula [2], R ³ has 1 carbon atom.
0 to 22 alkyl or alkenyl groups, and n is 0
Is to 15, M ³ is hydrogen, an alkali metal, alkaline earth metal, ammonium or organic ammonium. In the general formula [2], the carbon number represented by R ³ is 10 to 22.
Examples of the alkyl group or alkenyl group include, for example, a linear or branched decyl group, an undecyl group, a dodecyl group,
Besides tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, oleyl group, nonadecyl group, eicosyl group, docosyl group and the like, coconut oil alkyl group, tallow alkyl group and the like which are mixtures can be mentioned. . When the carbon number of the alkyl group or alkenyl group represented by R ³ is 9 or less, irritation to hair and skin may be too strong. When the carbon number of the alkyl group or alkenyl group represented by R ³ is 23 or more, the foaming properties and the stability over time of the hair shampoo composition may be reduced. In the general formula [2], n is
It is the average number of moles of oxyethylene groups added, and is 0 to 15. If n exceeds 15, the foaming properties of the hair shampoo composition may be reduced.

In the general formula [2], examples of the alkali metal represented by M ³ include lithium, sodium and potassium, and examples of the alkaline earth metal include 例 え ば calcium, 1 / 2 magnesium and the like. In the general formula [2], M
The ammonium or organic ammonium represented by ^3, -NH _4, ammonium organic group is one substituent, ammonium organic group has two substituents, organic groups can be exemplified 3-substituted ammonium. Examples of the organic amine that forms such an organic ammonium include, for example,
Aliphatic amines such as methylamine, ethylamine, propylamine, butylamine, hexylamine, and octylamine; alkanolamines such as ethanolamine, diethanolamine, triethanolamine, isopropanolamine, diisopropanolamine, and triisopropanolamine; and aromatics such as aniline Heterocyclic amines such as amine, morpholine, pyridine, pyrrolidine and piperidine can be mentioned.

In the acyl alkyl taurate type anionic surfactant represented by the general formula [3], R ⁴ CO is an aliphatic acyl group having 10 to 22 carbon atoms, and R ⁵ is a C 1 to 3 carbon atom. And M ⁴ is hydrogen, an alkali metal, an alkaline earth metal, ammonium or organic ammonium. In formula [3], examples of the aliphatic acyl group having 10 to 22 carbon atoms represented by R ⁴ CO include a caprinoyl group, a lauroyl group, a myristoyl group,
Examples include a palmitoyl group, a stearoyl group, an oleoyl group, and the like, and a mixture of coconut oil fatty acyl group and tallow fatty acid acyl group. When the number of carbon atoms of the aliphatic acyl group represented by R ⁴ CO is 9 or less, the hair shampoo composition may have strong irritation to hair and skin. When the number of carbon atoms of the aliphatic acyl group represented by R ⁴ CO is 23 or more, the foaming property of the hair shampoo composition may be reduced. In the general formula [3], R ⁵
Examples of the alkyl group having 1 to 3 carbon atoms represented by are a methyl group, an ethyl group, a propyl group, and an isopropyl group. In the general formula [3], if the alkyl group represented by R ⁵ has 4 or more carbon atoms in addition to the aliphatic acyl group having 10 to 22 carbon atoms represented by R ⁴ CO, the hair shampoo composition Foaming properties and stability with time may be reduced.

In the general formula [3], examples of the alkali metal represented by M ⁴ include lithium, sodium and potassium, and examples of the alkaline earth metal include カ ル シ ウ ム calcium, 1 / 2 magnesium and the like. In the general formula [3], M
The ammonium or organic ammonium represented by ^4, -NH _4, ammonium organic group is one substituent, ammonium organic group has two substituents, organic groups can be exemplified 3-substituted ammonium. Examples of the organic amine that forms such an organic ammonium include, for example,
Aliphatic amines such as methylamine, ethylamine, propylamine, butylamine, hexylamine, and octylamine; alkanolamines such as ethanolamine, diethanolamine, triethanolamine, isopropanolamine, diisopropanolamine, and triisopropanolamine; and aromatics such as aniline Heterocyclic amines such as amine, morpholine, pyridine, pyrrolidine and piperidine can be mentioned.

In the acyl isethionate type anionic surfactant represented by the general formula [4], R ⁶ CO is an aliphatic acyl group having 10 to 22 carbon atoms, M ⁵ is hydrogen, an alkali metal, Alkaline earth metals, ammonium or organic ammonium. In the general formula [4], R ⁶ CO
Examples of the aliphatic acyl group having 10 to 22 carbon atoms represented by, for example, caprinoyl group, lauroyl group, myristoyl group, palmitoyl group, stearoyl group, oleoyl group and the like, and a coconut oil fatty acid acyl group as a mixture,
Tallow fatty acid acyl groups and the like can be mentioned. R ⁶ C
When the number of carbon atoms of the aliphatic acyl group represented by O is 9 or less, the hair shampoo composition may have strong irritation to hair and skin. If the aliphatic acyl group represented by R ⁶ CO has 23 or more carbon atoms, the foaming properties of the hair shampoo composition may be reduced. In the general formula [4], examples of the alkali metal represented by M ⁵ include lithium, sodium, and potassium.
Examples of the alkaline earth metal include カ ル シ ウ ム calcium, マ グ ネ シ ウ ム magnesium and the like. In the general formula [4], examples of the ammonium or organic ammonium represented by M ⁵ include —NH ₄ , ammonium having one substituted organic group, ammonium having two substituted organic groups, and ammonium having three substituted organic groups. Can be mentioned. Examples of the organic amine that forms such an organic ammonium include, for example, methylamine, ethylamine,
Aliphatic amines such as propylamine, butylamine, hexylamine and octylamine; alkanolamines such as ethanolamine, diethanolamine, triethanolamine, isopropanolamine, diisopropanolamine and triisopropanolamine; aromatic amines such as aniline; morpholine; pyridine And heterocyclic amines such as pyrrolidine and piperidine.

In the amide ether sulfate type anionic surfactant represented by the general formula [5], R ⁷ CO
Is an aliphatic acyl group having 10 to 22 carbon atoms, R ⁸ is hydrogen or an alkyl group having 1 to 3 carbon atoms, and m is 2 to 15
And M ⁶ is hydrogen, an alkali metal, an alkaline earth metal, ammonium or organic ammonium. In the general formula [5], a carbon number of 10 to 22 represented by R ⁷ CO
Examples of the aliphatic acyl group include, for example, a caprinoyl group,
Examples thereof include a lauroyl group, a myristoyl group, a palmitoyl group, a stearoyl group, an oleoyl group, and the like, and a mixture of coconut oil fatty acid acyl group and tallow fatty acid acyl group. When the number of carbon atoms of the aliphatic acyl group represented by R ⁷ CO is 9 or less, the hair and shampoo composition may have strong irritation to hair and skin. When the number of carbon atoms of the aliphatic acyl group represented by R ⁷ CO is 23 or more,
The foamability of the hair shampoo composition may be reduced. In the general formula [5], the number of carbon atoms represented by R ⁸ is 1 to
Examples of the alkyl group 3 include a methyl group, an ethyl group, a propyl group, and an isopropyl group. In the general formula [5], a carbon number of 10 to 22 represented by R ⁷ CO
If the alkyl group represented by R ⁸ has 4 or more carbon atoms in addition to the aliphatic acyl group described above, the foaming properties and the temporal stability of the hair shampoo composition may be reduced.

In the general formula [5], m is the average number of moles of the added oxyethylene group, and is 2 to 15. If m is less than 2, the hair shampoo composition may become more irritating to hair and skin. When m exceeds 15, the foaming properties of the hair shampoo composition may be reduced. In the general formula [5], examples of the alkali metal represented by M ⁶ include lithium, sodium, and potassium, and examples of the alkaline earth metal include:
For example, 1/2 calcium, 1/2 magnesium, etc. can be mentioned. In the general formula [5], as the ammonium or organic ammonium represented by M ⁶ ,
NH ₄ , ammonium having one substituted organic group, ammonium having two substituted organic groups, and ammonium having three substituted organic groups can be given. Examples of the organic amine forming such an organic ammonium include, for example, aliphatic amines such as methylamine, ethylamine, propylamine, butylamine, hexylamine, and octylamine, ethanolamine, diethanolamine, triethanolamine, isopropanolamine, and diisopropanol. Examples thereof include amines, alkanolamines such as triisopropanolamine, aromatic amines such as aniline, and heterocyclic amines such as morpholine, pyridine, pyrrolidine, and piperidine. In the hair shampoo composition of the present invention, the component (B) is an ether sulfate type anionic surfactant represented by the general formula [2], and an acylalkyl taurate type anion represented by the general formula [3]. Surfactants, acyl isethionate-type anionic surfactants represented by the general formula [4], and amide ether sulfate-type anionic surfactants represented by the general formula [5] are one type. The compounds can be used alone, or two or more compounds can be used in combination.

The hair shampoo composition of the present invention comprises, as a component (C), a quaternary ammonium salt type cationic surfactant represented by the general formula [6]:

Embedded image An isoquinolinium salt-type cationic surfactant represented by the general formula [7],

Embedded image Or an amide quaternary ammonium salt type cationic surfactant represented by the general formula [8]:

Embedded image It contains.

In the quaternary ammonium salt type cationic surfactant represented by the general formula [6], R ⁹ has 1 carbon atom.
And R ¹⁰ and R ¹¹ are a methyl group, an ethyl group or — (CH ₂ CH ₂ O) pH
And p is 1 to 20, R ¹² is an alkyl group, alkenyl group or benzyl group having 1 to 22 carbon atoms, and X ⁻ is a halogen ion or an alkyl sulfate ion having 1 to 2 carbon atoms. In the general formula [6], the number of carbon atoms represented by R ⁹ is 1
Examples of the alkyl group or alkenyl group of 0 to 22 include a linear or branched decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, oleyl group, In addition to a nonadecyl group, an eicosyl group, a docosyl group, and the like, a coconut oil alkyl group, a tallow alkyl group, and the like, which are mixtures, can be mentioned. When the carbon number of the alkyl group or alkenyl group represented by R ⁹ is 9 or less, irritation to hair and skin may be too strong. When the alkyl group or alkenyl group represented by R ⁹ has 23 or more carbon atoms, the foaming properties and the stability over time of the hair shampoo composition may be reduced.

In the general formula [6], R ¹⁰ and R ¹¹ are an alkyl group having 3 or more carbon atoms, or-(CH ₂ CH ₂ O)
When the p value of pH exceeds 20, the foaming property of the hair shampoo composition may be reduced, and the feeling in use may be deteriorated.
In the general formula [6], C 1 to C 22 represented by R ¹²
Examples of the alkyl group or alkenyl group include, for example, methyl group, ethyl group, linear or branched propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, Dodecyl group,
Besides tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, oleyl group, nonadecyl group, eicosyl group, docosyl group and the like, coconut oil alkyl group, tallow alkyl group and the like which are mixtures can be mentioned. . When the alkyl group or alkenyl group represented by R ¹² has 23 or more carbon atoms, the foaming properties and the temporal stability of the hair shampoo composition may be reduced. In the general formula [6], X ^- as the alkyl sulfate ion halide ion or a C 1-2 represented by include chlorine ion, a bromine ion, an iodine ion, a methyl sulfate ion, and ethyl sulfate ion .

In the isoquinolinium salt type cationic surfactant represented by the general formula [7], R ¹³ has 10 carbon atoms.
To 22 alkyl groups or alkenyl groups, and Y ^- is a halogen ion or an alkyl sulfate ion having 1 to 2 carbon atoms. In the general formula [7], the number of carbon atoms represented by R ¹³ is 1
Examples of the alkyl group or alkenyl group of 0 to 22 include a linear or branched decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, oleyl group, In addition to a nonadecyl group, an eicosyl group, a docosyl group, and the like, a coconut oil alkyl group, a tallow alkyl group, and the like, which are mixtures, can be mentioned. When the number of carbon atoms of the alkyl group or alkenyl group represented by R ¹³ is 9 or less, irritation to hair and skin may be too strong. When the carbon number of the alkyl group or alkenyl group represented by R ¹³ is 23 or more, the foaming properties and the temporal stability of the hair shampoo composition may be reduced. In the general formula [7], Y ^- halogen ion or carbon atoms 1 represented
Examples of the alkyl sulfate ion (2) include a chlorine ion, a bromine ion, an iodine ion, a methyl sulfate ion, and an ethyl sulfate ion.

In the amide quaternary ammonium salt type cationic surfactant represented by the general formula [8], R ¹⁴ CO
Is an aliphatic acyl group having 10 to 22 carbon atoms, and R ¹⁵ and R ¹⁶ are a methyl group, an ethyl group or — (CH ₂ CH ₂ O) qH
And q is 1 to 20, R ¹⁷ is a methyl group, an ethyl group or a benzyl group, and Z ⁻ is a halogen ion or an alkyl sulfate ion having 1 to 2 carbon atoms. In the general formula [8], examples of the aliphatic acyl group having 10 to 22 carbon atoms represented by R ¹⁴ CO include a caprinoyl group, a lauroyl group, a myristoyl group, a palmitoyl group, a stearoyl group, an oleoyl group, and the like. Furthermore, coconut oil fatty acid acyl groups, tallow fatty acid acyl groups, and the like, which are mixtures, can be mentioned. When the number of carbon atoms of the aliphatic acyl group represented by R ¹⁴ CO is 9 or less, the hair shampoo composition may have strong irritation to hair and skin. When the number of carbon atoms of the aliphatic acyl group represented by R ¹⁴ CO is 23 or more, the foaming properties and the temporal stability of the hair shampoo composition may be reduced. In the general formula [8], R ¹⁵ and R ^{16 each} have 3 carbon atoms.
Or a more alkyl groups, - the value of (CH ₂ CH ₂ O) qH of q is or exceeds 20, the R ¹⁷ is a alkyl group having 3 or more carbon atoms, foaming hair shampoo composition There is a possibility that the feeling of use will deteriorate and the usability will deteriorate. In the general formula [8], a halogen ion represented by Z ⁻ or a carbon number of 1 to 2
Examples of the alkyl sulfate ion include chloride ion, bromine ion, iodine ion, methyl sulfate ion, and ethyl sulfate ion. In the hair shampoo composition of the present invention, the quaternary ammonium salt type cationic surfactant represented by the general formula [6], which is the component (C), and the isoquinolinium salt type cationic surfactant represented by the general formula [7] As the ionic surfactant and the amido quaternary ammonium salt type cationic surfactant represented by the general formula [8], one kind of compound can be used alone, or two or more kinds of compounds can be used. Can be used in combination.

In the hair shampoo composition of the present invention,
The total content of the components (A) and (B) is 5 to 60% by weight, more preferably 10 to 45% by weight. When the total content of the components (A) and (B) is less than 5% by weight,
Poor foaming properties and detergency may result in a poor feeling of use. The sum of the contents of the components (A) and (B) is 60
If the amount is more than 10% by weight, skin irritation is strong, the detergency becomes excessive, a favorable feeling in use cannot be obtained, and the temporal stability of the composition may be reduced. In the hair shampoo composition of the present invention, the weight ratio of the component (A) to the component (B) is 1/2.
0 to 20/1. Less component (A), component (A)
When the weight ratio of the component (B) is less than 1/20, the foaming properties and the stability over time may be reduced. (B) Less component,
When the weight ratio of the component (A) to the component (B) exceeds 20/1, the foaming property is reduced, and a creamy foam may not be obtained. In the hair shampoo composition of the present invention, the content of the component (C) is 0.05 to 5% by weight, more preferably 0.1 to 3% by weight. If the content of the component (C) is less than 0.05% by weight, a sufficient conditioning effect may not be obtained. When the content of the component (C) exceeds 5% by weight, the foaming property and the stability over time are reduced, the irritation is increased, and the feeling in use may be deteriorated.

The hair shampoo composition of the present invention may contain, if necessary, components generally incorporated into the hair shampoo composition, for example, alkyl betaine-type amphoteric surfactant, amidobetaine-type amphoteric surfactant, imidazolinium Amphoteric surfactants such as betaine-type amphoteric surfactants and sulfobetaine-type amphoteric surfactants, higher fatty acid alkanolamide type nonionic surfactants, amine oxide type nonionic surfactants, polyoxyethylene alkyl ether type non-ionic surfactants Nonionic surfactants such as ionic surfactants, foaming agents such as higher fatty acids and higher alcohols, humectants such as polyhydric alcohols such as glycerin, ethylene glycol, propylene glycol and 1,3-butanediol, squalane , Jojoba oil, olive oil, castor oil, lanolin,
Oils such as lecithin, cellulose ether type cationic polymer compounds, cationic polyvinylpyrrolidone derivatives, cationic polyamide derivatives, polydimethyldiallylammonium chloride, copolymers of dimethyldiallylammonium chloride and acrylamide, alkylpolyethyleneimines, etc. Cationic polymer compounds, highly polymerized methylpolysiloxane, silicone derivatives such as dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymer, pearling agents such as ethylene glycol distearate, styrene polymer, sulfur, zinc pyrithione, etc. Anti-dandruff agent, preservative such as p-hydroxybenzoate, sodium benzoate, phenoxyethanol, sodium salicylate, 5-methyl-2-isopropylcyclohexanol, tow Tonic agents such as Rashichinki,
Chelating agents such as ethylenediaminetetraacetate, citric acid, and trisodium nitrilotriacetate, ultraviolet absorbers such as benzophenone derivatives and benzotriazole derivatives, other dyes, and fragrances can be added to such an extent that the effects of the present invention are not impaired.

[0023]

EXAMPLES The present invention will be described in more detail with reference to the following Examples, which should not be construed as limiting the present invention. In the examples and comparative examples, the following compounds were used as component (A), component (B) and component (C). (A) Component Sulfosuccinamide type anionic surfactant A1: In the general formula [1], R ¹ is a dodecyl group, R ² is hydrogen, M
¹ is hydrogen, one of X and Y is hydrogen and the other is -SO ₃
A compound that is Na. Sulfosuccinamide-type anionic surfactant A2: In the general formula [1], R ¹ is a coconut oil alkyl group, R ² is a hydroxyethyl group, M ¹ is hydrogen, one of X and Y is hydrogen and the other is hydrogen. compounds There is -SO ₃ Na. Sulfosuccinamide-type anionic surfactant A3: In the general formula [1], R ¹ is a coconut oil alkyl group, R ² is hydrogen, M ¹ is potassium, one of X and Y is hydrogen and the other is — A compound that is SO ₃ K. Sulfosuccinamide-type anionic surfactant A4: In the general formula [1], R ¹ is a coconut oil alkyl group, R ² is a methyl group, M ¹ is ammonium, one of X and Y is hydrogen and the other is hydrogen. A compound which is —SO ₃ NH ₄ ; Sulfosuccinamide type anionic surfactant A5: In the general formula [1], R ¹ is a lauryl group, R ² is hydrogen, M
¹ triethanolammonium, X with a compound either is the other hydrogen is _{-SO 3 NH (CH 2 CH 2} OH) 3 in Y. Sulfosuccinamide-type anionic surfactant A6: In the general formula [1], R ¹ is a coconut oil alkyl group, R ² is a hydroxyethyl group, M ¹ is potassium, one of X and Y is hydrogen and the other is hydrogen. compounds There is a -SO ₃ K. Sulfosuccinamide-type anionic surfactant A7: In the general formula [1], R ¹ is a dodecyl group, R ² is a hydroxyethyl group, M ¹ is sodium, one of X and Y is hydrogen and the other is — A compound that is SO ₃ Na. Component (B) Ether sulfate type anionic surfactant B1: CH ₃ (CH ₂ ) ₁₁ O (C ₂ H ₄ O) ₃ SO ₃ Na acylalkyl taurate type anionic surfactant B
2: In the general formula [3], a compound in which R ⁴ CO is a coconut oil fatty acid acyl group, R ⁵ is a methyl group, and M ⁴ is sodium. Acyl isethionate type anionic surfactant B3: a compound of the formula [4], wherein R ⁶ CO is a coconut oil fatty acid acyl group and M ⁵ is ammonium. Amide ether sulfate type anionic surfactant B
4: In the general formula [5], a compound in which R ⁷ CO is a coconut oil fatty acid acyl group, R ⁸ is hydrogen, m is 4, and M ⁶ is sodium. Acylalkyl taurate type anionic surfactant B
5: CH ₃ (CH ₂ ) ₁₀ CON (CH ₃ ) CH ₂ CH ₂ SO ₃ Na acyl isethionate type anionic surfactant B6: In the general formula [4], R ⁶ CO is a cocoyl group, and M ⁵ Is triethanolammonium. Amide ether sulfate type anionic surfactant B
7: [CH ₃ (CH ₂ ) ₇ CH = CH (CH ₂ ) ₇ CONH (CH ₂ CH
₂ O) ₄ SO ₃ ] ₂ Mg amide ether sulfate type anionic surfactant B
8: CH ₃ (CH ₂ ) ₁₂ CON (CH ₃ ) (CH ₂ CH ₂ O) ₁₀ SO ₃ N
a Ether sulfate type anionic surfactant B9: a compound of the formula [2], wherein R ³ is a coconut oil alkyl group, n is 3, and M ³ is ammonium. Acylalkyl taurate type anionic surfactant B1
0: In the general formula [3], R ⁴ CO is a cocoyl group, R ⁵
Is a methyl group and M ⁴ is １ ／ magnesium. (C) Component Quaternary ammonium salt type cationic surfactant C1:

Embedded image Isoquinolinium salt type cationic surfactant C2:

Embedded image Amide quaternary ammonium salt type cationic surfactant C
3:

Embedded image Quaternary ammonium salt type cationic surfactant C4:

Embedded image Amide quaternary ammonium salt type cationic surfactant C
5:

Embedded image Quaternary ammonium salt type cationic surfactant C6:

Embedded image Isoquinolinium salt type cationic surfactant C7:

Embedded image Amide quaternary ammonium salt type cationic surfactant C
8:

Embedded image The hair shampoo composition was evaluated by the following method. (1) Skin irritation A closed patch test was performed on the inside of the upper arm for 24 hours using a 0.5% by weight aqueous solution of the hair shampoo composition for each of 10 men and women with healthy skin. evaluate. 0 if no change in skin
The average value of 20 subjects is calculated by setting one point when there is a slight erythema on the skin and one point when two erythema or edema are clearly observed on the skin. In this evaluation, the average value was 0.5.
If it is less than the point, skin irritation is considered to be weak, and the average value is 0.1.
When the score is 5 or more and less than 1.0, the skin irritation is considered to be moderate, and when the average value is 1.0 or more, the skin irritation is strong. (2) Foamability Hair shampoo composition 5 with 20 women as panelists
The foamability when washed with g is evaluated. 2 points if you felt that the foam was good, 1 point if you felt it wasn't very good
The points and the case where foaming is bad are regarded as 0 points, and the average value of 20 persons is obtained. In this evaluation, when the average value is 1.5 points or more, the foaming property is considered to be good, and when the average value is 1.0 points or more and less than 1.5 points, the foaming property is slightly poor, When the average value is less than 1.0 point, it is considered that the foaming property is poor. (3) Creamy property of foam Hair shampoo composition 5 with 20 women as panelists
g on a bath sponge and observe the foam
Evaluate the creaminess of the foam. The average value of 20 people is calculated by setting 2 points when the foam is felt to be fine and creamy, 1 point when the foam is slightly coarse, and 0 when the foam is coarse. In this evaluation, when the average value is 1.5 points or more, the creamy property of the foam is considered to be good, and when the average value is 1.0 points or more and less than 1.5 points, the creamy property of the foam is slightly insufficient. When the average value is less than 1.0 point, it is considered that the foam has poor creamy property. (4) Detergency Using a 1% by weight aqueous solution of the hair shampoo composition,
The artificially stained wool muslin cloth is washed with an rg-O-tometer under the conditions of 40 ° C., 70 rpm, and 10 minutes.
After drying the washed artificially stained cloth, the surface reflectance is measured using a color computer [Suga Test Instruments Co., Ltd., SM-4], and the detergency is calculated from the following equation. Detergency (%) = (A / B) × 100 A: (Reflectance of artificially stained cloth after washing) − (Reflectance of artificially stained cloth before washing) B: (Reflectance of uncontaminated wool muslin) − (Reflectance of artificially stained cloth before cleaning) In this evaluation, when the cleaning power is 60% or more, the cleaning power is determined to be excessive, and when the cleaning power is 25% or more and less than 60%, the cleaning power is determined. Moderate, detergency is 2
If it is less than 5%, the detergency is considered to be weak. (5) Finger washing at the time of hair washing and rinsing Hair shampoo composition 5 with 20 women as panelists
The hair was washed using g, and the finger passing property at the time of washing and rinsing was evaluated. 2 points when the finger felt smooth and the hair did not get caught, 1 point when the hair felt slightly caught, and 0 when the finger felt poor, 2
The average value of 0 persons is calculated. In this evaluation, when the average value is 1.5 points or more, the finger passing property is considered to be good, and when the average value is 0.5 points or more and less than 1.5 points, the finger passing property is considered to be slightly poor, When the average value is less than 0.5 points, it is determined that the finger passing property is poor. (6) Sliminess at the time of rinsing Hair shampoo composition 5 with 20 women as panelists
The slimy feeling at the time of rinsing after washing the hair with g is evaluated. A score of +1 was given if the slimy feeling during rinsing was persistent, 0 was given if the slimy feeling was appropriate, and -1 was given if the slimy feeling was not enough. Find the average value. In this evaluation, the average value was 0.5.
If the score is above the score, the slimy feeling is persistent and the average value is-
If the score is 0.5 or more and less than 0.5, the slimy feeling is considered to be appropriate, and if the average value is less than -0.5, the slimy feeling is insufficient. (7) Conditioning effect after drying A hair shampoo composition 5 with 20 women as panelists
g, wash and rinse, air-dry, and evaluate the conditioning effect by combability. If the hair does not feel squeaky and the comb feels smooth,
The score is 1 when the comb feels a bit on the hair and 0 when the hair is squeezed and the comb feels poor.
The average value of 0 persons is calculated. In this evaluation, when the average value is 1.5 points or more, the conditioning effect is considered to be good. When the average value is 0.5 points or more and less than 1.5 points, the conditioning effect is considered to be slightly poor. 0.
If the score is less than 5, the conditioning effect is considered to be poor. (8) Stability over time The hair shampoo composition is stored for one month under the conditions of -5 ° C, 25 ° C, and 50 ° C, and its appearance is observed. ：: Good stability (transparent dissolution or turbid state at any temperature, no change in appearance). Δ: Slightly poor stability (slightly turbid or colored at any temperature). X: Poor stability (separation and precipitation are observed at any temperature, solidification or remarkable coloring). Of the three samples tested under three different temperature conditions, all were evaluated as good.
If there is, it is evaluated as △. Example 1 Sulfosuccinamide type anionic surfactant A1
Parts by weight, 10 parts by weight of ether sulfate type anionic surfactant B1, 0.5 parts by weight of quaternary ammonium salt type cationic surfactant C1, and 88.5 parts by weight of purified water. A shampoo composition was prepared. This hair shampoo composition was subjected to a skin irritation test for 10 males and 10 females. The average value of the skin irritation was 0.3, and the threshold value of 0.3 was considered to be weak. 5
Was below the point. The average value of the foamability test by 20 female panelists was 1.7 points, indicating that the foamability was good. The average value of the foam creaminess test was 1.6 points, and the foam creaminess was also good. In the cleaning power test using an artificially stained wool muslin cloth, the cleaning power was 28.
3%, which was within the range of 25 to 60%, which is considered to be appropriate detergency. When used by 20 female panelists for shampooing, the average value of finger piercing at the time of shampooing and rinsing was 1.7 points, indicating that finger piercing was good. The average value of the slickness during rinsing was 0.2 point, indicating a moderate and good slickness. The average value of the conditioning effect after air drying was 1.7, and the conditioning effect was also good. The feeling of use as a hair shampoo was generally good. In the aging stability test, -5 ° C, 25 ° C, 5
All the samples stored at 0 ° C. for one month maintained the same state as at the start of the test, and did not change in appearance. Examples 2 to 12 Hair shampoo compositions having the composition shown in Table 1 were prepared, and their performance was evaluated. The results are shown in Table 1.

[0024]

[Table 1]

[0025]

[Table 2]

[0026]

[Table 3]

From the results in Table 1, it can be seen that the hair shampoo compositions of the present invention of Examples 1 to 12 have low skin irritancy, good foaming properties and good creamy properties, and have an appropriate detergency. When used for shampooing, it can be seen that the fingerability during shampooing and rinsing is good, there is an appropriate slimy feeling, an excellent conditioning effect is obtained after drying, and the aging stability is also good. Comparative Example 1 Sulfosuccinamide type anionic surfactant A1
Hair, 10 parts by weight of ether sulfate type anionic surfactant B1, 0.03 part by weight of quaternary ammonium salt type cationic surfactant C1, and 88.97 parts by weight of purified water A shampoo composition was prepared. This hair shampoo composition was subjected to a skin irritation test for 10 males and 10 females. The average value of the skin irritation was 0.3, and the threshold value of 0.3 was considered to be weak.
He was below 5 points. The average value of the foamability test by 20 female panelists was 1.7 points, indicating that the foamability was good. The average value of the foam creaminess test was 1.6 points, and the foam creaminess was also good. In the detergency test using an artificially stained wool muslin cloth, the detergency was 27.
6%, which is within the range of 25 to 60%, which is considered to be appropriate detergency. When used by 20 female panelists for shampooing, the average value of finger piercing at the time of shampooing and rinsing was 0.4 point, and finger piercing was poor. The average value of the slickness during rinsing was 0.2 point, indicating a moderate and good slickness. The average value of the conditioning effect after air drying was 0.4 point, and the conditioning effect was poor.
The feeling of use as a hair shampoo was generally inferior, except for the slimy feeling during rinsing. In the aging stability test,
All the samples stored at -5 ° C, 25 ° C, and 50 ° C for one month maintained the same state as at the start of the test, and did not change in appearance. Comparative Examples 2 to 8 Hair shampoo compositions having the composition shown in Table 2 were prepared, and their performance was evaluated. The results are shown in Table 2.

[0028]

[Table 4]

[0029]

[Table 5]

The hair shampoo composition of Comparative Example 1 comprises (C)
Due to the low content of the components, finger penetration during hair washing and rinsing is poor, and a conditioning effect cannot be obtained. In the hair shampoo composition of Comparative Example 2, the content of the component (C) is too large, so that the skin irritating property is strong, the foaming property and the stability over time are poor, and the slimy feeling upon rinsing is persistent. The hair shampoo composition of Comparative Example 3 has a low foaming property, does not produce a creamy foam, has a low detergency, and is stable over time because the total content of the components (A) and (B) is small. Poor. The hair shampoo composition of Comparative Example 4 has strong skin irritation, excessive detergency, and poor stability over time because the total content of the components (A) and (B) is too large. In the hair shampoo composition of Comparative Example 5, the weight ratio of the component (A) to the component (B) was 1 /
Since it is less than 20, foaming properties and stability over time are poor, and a creamy foam cannot be obtained. In the hair shampoo composition of Comparative Example 6, since the weight ratio of the component (A) to the component (B) exceeds 20/1, the foamability is low and the stability over time is poor. Since the hair shampoo composition of Comparative Example 7 uses lauryl sulfosuccinate disodium salt instead of the component (A), a creamy foam is not obtained, a slimy feeling at the time of rinsing, and stability over time. Is bad. In the hair shampoo composition of Comparative Example 8, since the amount of lauryl sulfosuccinate disodium salt was further increased, foaming, poor stability over time, no creamy foam was obtained, and a strong slimy feeling upon rinsing. Example 13 Sulfosuccinamide-type anionic surfactant A3 was treated with 7
10 parts by weight of an acylalkyl taurate type anionic surfactant B5, 1 part by weight of a quaternary ammonium salt type cationic surfactant C1, 2 parts by weight of coconut oil fatty acid diethanolamide, dimethyl chloride Diallyl ammonium polymer [Merck 100, Mercoat 100]
Parts by weight, 1 part by weight of propylene glycol, 0.2 parts by weight of methyl paraoxybenzoate, 0.2 parts by weight of butyl paraoxybenzoate, 0.1 parts by weight of fragrance and 78.
A hair shampoo composition was prepared by mixing 2 parts by weight. This hair shampoo composition was subjected to a skin irritation test for 10 males and 10 females. The average value of the skin irritation was 0.3, and the threshold value of 0.3 was considered to be weak. He was below 5 points. The average value of the foamability test by 20 female panelists was 1.7 points, indicating that the foamability was good. The average value of the foam creaminess test was 1.
7 points, and the creamy property of the foam was also good. In a detergency test using a wool muslin artificially stained cloth, the detergency is 48.3%, which is 25 to 6 which is considered to be an appropriate detergency.
It was within the range of 0%. When 20 female panelists used the hair for washing, the average value of finger passing during washing and rinsing was 1.8 points, and the finger passing was good. The average value of the slickness during rinsing was 0.2 point, indicating a moderate and good slickness. The average value of the conditioning effect after air drying was 1.7, and the conditioning effect was also good. The feeling of use as a hair shampoo was generally good. In the aging stability test, -5 ° C, 25
All the samples stored for one month at 50 ° C. and 50 ° C. maintained the same state as at the start of the test, and did not change in appearance. Example 14 Sulfosuccinamide type anionic surfactant A4 was prepared using 7
7 parts by weight of an acyl isethionate type anionic surfactant B6, 0.5 parts by weight of an isoquinolinium salt type cationic surfactant C2, 3 parts by weight of betaine myristyldimethylaminoacetate, 2 parts by weight of stearate, cationic modified cellulose ether derivative [Daicel Chemical Industries, Ltd., Gerner QH30
0] and 0.5 parts by weight of methyl paraoxybenzoate.
A pearl hair shampoo composition was prepared by mixing 0.2 parts by weight of butyl paraoxybenzoate, 0.1 part by weight of fragrance, and 79.5 parts by weight of purified water. The hair shampoo composition was subjected to a skin irritation test for 10 men and women, and the average value of the skin irritation was 0.3.
Point, which was below the threshold value of 0.5 point, which is considered to be weak skin irritation. The average value of the foamability test by 20 female panelists was 1.7 points, indicating that the foamability was good. The average value of the foam creaminess test was 1.8 points.
The creamy properties of the foam were also good. In the detergency test using the wool muslin artificially stained cloth, the detergency was 39.4%, which was within the range of 25 to 60%, which was considered to be an appropriate detergency. When used by 20 female panelists for shampooing, the average value of finger piercing at the time of shampooing and rinsing was 1.7 points, indicating that finger piercing was good. The average value of the slickness during rinsing was 0.3 point, indicating a moderate and good slickness. The average conditioning effect after air drying is 1.
It was 7 points and the conditioning effect was also good.
The feeling of use as a hair shampoo was generally good. In the aging stability test, the temperature was 1 at -5 ° C, 25 ° C, and 50 ° C.
All the samples stored for a month maintained the same pearl-like state as before the start of the test, and the appearance did not change. Example 15 Sulfosuccinamide type anionic surfactant A5 was added to 8
6 parts by weight of amide ether sulfate type anionic surfactant B7, 1 part by weight of quaternary ammonium salt type cationic surfactant C4, and 4 parts by weight of coconut oil fatty acid amidopropyldimethylaminoacetate betaine 0.2 parts by weight of a copolymer type cationic polymer compound of dimethyldiallylammonium chloride and acrylamide [Merck Co., Ltd., Mercoat 550], 0.1 part by weight of zinc pyrithione, 0.2 part by weight of methyl parahydroxybenzoate, 0.2 parts by weight of butyl benzoate, 0.5 parts by weight of citric acid, 0.1 parts by weight of fragrance, and 79.7 parts by weight of purified water were blended to prepare a dandruff-free hair shampoo composition. This hair shampoo composition was subjected to a skin irritation test for 10 males and 10 females. The average value of the skin irritation was 0.2, and the threshold value of skin irritation was 0.2.
He was below 5 points. The average value of the foaming test by 20 female panelists was 1.8 points, indicating that the foaming properties were good. The average value of the foam creaminess test was 1.8 points, and the foam creaminess was also good. In the detergency test using the artificially stained wool muslin cloth, the detergency was 38.
4%, which was within the range of 25 to 60%, which is considered to be appropriate detergency. When used by 20 female panelists for shampooing, the average value of finger piercing at the time of shampooing and rinsing was 1.7 points, indicating that finger piercing was good. The average value of the slickness during rinsing was 0.2 point, indicating a moderate and good slickness. The average value of the conditioning effect after air drying was 1.8 points, and the conditioning effect was also good. The feeling of use as a hair shampoo was generally good. In the aging stability test, -5 ° C, 25 ° C, 5
All the samples stored at 0 ° C. for one month maintained the same state as before the start of the test, and did not change in appearance. Example 16 Sulfosuccinamide type anionic surfactant A6 was added to 9
6 parts by weight of an acyl alkyl taurate type anionic surfactant B2, 2 parts by weight of an amide quaternary ammonium salt type cationic surfactant C5, and 3 parts by weight of polyoxyethylene (5 mol) oleyl ether. Parts by weight, 5-methyl-
0.5 parts by weight of 2-isopropylcyclohexanol,
0.2 parts by weight of methyl paraoxybenzoate, 0.2 parts by weight of butyl paraoxybenzoate, 0.5 parts by weight of citric acid, 0.1 parts by weight of fragrance, and 78.5 parts by weight of purified water A tonic hair shampoo composition was prepared. This hair shampoo composition was subjected to a skin irritation test for 10 males and 10 females. The average value of the skin irritation was 0.2, and the threshold value of skin irritation was 0.2. 5
Was below the point. The average value of the foamability test by 20 female panelists was 1.7 points, indicating that the foamability was good. The average value of the foam creaminess test was 1.9 points, and the foam creaminess was also good. In the detergency test using an artificially stained wool muslin cloth, the detergency was 43.
It was 0%, which was within the range of 25 to 60%, which was considered to be an appropriate detergency. When 20 female panelists used the hair for washing, the average value of finger passing during washing and rinsing was 1.8 points, and the finger passing was good. The average value of the slickness during rinsing was 0.2 point, indicating a moderate and good slickness. The average value of the conditioning effect after air drying was 1.7, and the conditioning effect was also good. The feeling of use as a hair shampoo was generally good. In the aging stability test, -5 ° C, 25 ° C, 5
All the samples stored at 0 ° C. for one month maintained the same state as before the start of the test, and did not change in appearance. Example 17 Sulfosuccinamide-type anionic surfactant A7 was added to 7
8 parts by weight of amide ether sulfate type anionic surfactant B8, 0.5 parts by weight of quaternary ammonium salt type cationic surfactant C6, and 0.5 parts by weight of isoquinolinium salt type cationic surfactant C7 1 part by weight, 2 parts by weight of lauryl dimethylamine oxide, 0.5 part by weight of a cationic modified cellulose ether derivative [Daicel Chemical Industries, Ltd., Gerner QH300], 2 parts by weight of ethylene glycol distearate, paraoxybenzoate 0.2 part by weight of methyl acrylate, 0.1 part by weight of butyl parahydroxybenzoate, 0.5 part by weight of citric acid, 0.1 part by weight of fragrance, 78.1 parts by weight of purified water A hair shampoo composition was prepared. About this hair shampoo composition,
When a skin irritation test was conducted on 10 men and women, the average value of the skin irritation was 0.3 point, which was lower than the threshold value of 0.5 point, which is considered to be weak. The average value of the foaming test by 20 female panelists was 1.8 points, indicating that the foaming properties were good. The average value of the foam creaminess test was 1.7 points, and the foam creaminess was also good. In the detergency test using an artificially stained wool muslin cloth, the detergency was 42.5%, which was within the range of 25 to 60%, which was considered to be an appropriate detergency. When used by 20 female panelists for shampooing, the average value of finger piercing at the time of shampooing and rinsing was 1.7 points, indicating that finger piercing was good. The average value of the slickness during rinsing was 0.3 point, indicating a moderate and good slickness. The average value of the conditioning effect after air drying was 1.7, and the conditioning effect was also good. The feeling of use as a hair shampoo was generally good. In the aging stability test, all samples stored at -5 ° C, 25 ° C, and 50 ° C for one month maintain the same pearl-like state as before the start of the test,
No change in appearance occurred. Example 18 Sulfosuccinamide-type anionic surfactant A2 was treated with 1
0 parts by weight, 3 parts by weight of ether sulfate type anionic surfactant B9, 5 parts by weight of acylalkyl taurate type anionic surfactant B10, amide quaternary ammonium salt type cationic surfactant C8 1 part by weight, 0.3 part by weight of a dimethyldiallylammonium chloride polymer [Merck, Mercoat 100], 0.2 part by weight of methyl paraoxybenzoate, and 0.2 part by weight of butyl paraoxybenzoate.
1 part by weight, 0.5 part by weight of citric acid, 0.1 part by weight of fragrance, and 79.8 parts by weight of purified water were blended to prepare a transparent hair shampoo composition. This hair shampoo composition was subjected to a skin irritation test for 10 males and 10 females. The average value of the skin irritation was 0.3, and the threshold value of 0.3 was considered to be weak. He was below 5 points. 2
The average value of the foaming test by 0 female panelists is 1.8
And the foamability was good. The average value of the foam creaminess test was 1.7 points, and the foam creaminess was also good. In a detergency test using an artificially stained wool muslin cloth, the detergency was 45.1%, which was within the range of 25 to 60%, which was considered to be an appropriate detergency. 20
When a named female paneler used the hair for washing, the average value of finger passing during hair washing and rinsing was 1.7 points, indicating that the finger passing was good. Average value of slimy feeling during rinsing is 0.2
It was moderate and had a good slimy feeling. The average value of the conditioning effect after air drying was 1.8 points, and the conditioning effect was also good. The feeling of use as a hair shampoo was generally good. In the aging stability test, all of the samples stored at -5 ° C, 25 ° C, and 50 ° C for one month maintained a transparent dissolved state and did not change in appearance. Table 3 shows the results of Examples 13 to 18.

[0031]

[Table 6]

From the results shown in Table 3, it can be seen that the hair shampoo compositions of the present invention of Examples 13 to 18 have low skin irritation, good foaming properties and good creamy properties, and have an appropriate detergency. When used for shampooing, it can be seen that the fingerability during shampooing and rinsing is good, there is an appropriate slimy feeling, an excellent conditioning effect is obtained after drying, and the aging stability is also good.

[0033]

Industrial Applicability The hair shampoo composition of the present invention is hypoallergenic, excellent in foaming properties and foaming properties, has an appropriate detergency, has good finger passing during shampooing and rinsing, and has good It has an appropriate slimy feeling, provides excellent conditioning effects after drying, and has good stability over time.

Claims (1)

[Claims] 1. A sulfosuccinamide type anionic surfactant represented by the general formula [1] as a component (A): (Wherein, R ¹ is an alkyl group or alkenyl group having 10 to 22 carbon atoms, R ² is hydrogen, an alkyl group having 1 to 3 carbon atoms or a hydroxyethyl group, and M ¹ is hydrogen, an alkali metal X or Y is one of hydrogen and the other is —SO ₃ M ² , and M ² is hydrogen, an alkali metal, an alkaline earth metal, ammonium or an organic ammonium. The ether sulfate type anionic surfactant represented by the general formula [2] as the component (B) R ³ O (CH ₂ CH ₂ O) n SO ₃ M ³ ... [2] Wherein R ³ is an alkyl group or alkenyl group having 10 to 22 carbon atoms, n is 0 to 15, and M ³ is hydrogen, an alkali metal, an alkaline earth metal, ammonium or organic ammonium. Acylalkyl taurate type anionic surfactant represented by general formula [3] (Wherein, R ⁴ CO is an aliphatic acyl group having 10 to 22 carbon atoms, R ⁵ is an alkyl group having 1 to 3 carbon atoms, M ⁴ is hydrogen, an alkali metal, an alkaline earth metal, Ammonium or organic ammonium), an acyl isethionate-type anionic surfactant represented by the general formula [4] R ⁶ COOCH ₂ CH ₂ SO ₃ M ⁵ ... [4] ⁶ CO is an aliphatic acyl group having 10 to 22 carbon atoms, and M ⁵ is hydrogen, an alkali metal, an alkaline earth metal, ammonium or organic ammonium.) Or an amide represented by the general formula [5] Ether sulfate type anionic surfactant (Where R ⁷ CO is an aliphatic acyl group having 10 to 22 carbon atoms, R ⁸ is hydrogen or an alkyl group having 1 to 3 carbon atoms, m is 2 to 15, and M ⁶ is Hydrogen, alkali metal, alkaline earth metal, ammonium or organic ammonium), and a quaternary ammonium salt type cationic surfactant represented by the general formula [6] as the component (C): (Where R ⁹ is an alkyl or alkenyl group having 10 to 22 carbon atoms, R ¹⁰ and R ¹¹ are a methyl group, an ethyl group or — (CH ₂ CH ₂ O) pH, and p is 1 to 20, R ¹² is an alkyl group, an alkenyl group or a benzyl group having 1 to 22 carbon atoms, and X ⁻ is a halogen ion or an alkyl sulfate ion having 1 to 2 carbon atoms.) Isoquinolinium salt type cationic surfactant represented by the following formula: (Wherein, R ¹³ is an alkyl group or alkenyl group having 10 to 22 carbon atoms, and Y ⁻ is a halogen ion or an alkyl sulfate ion having 1 to 2 carbon atoms), or the general formula [8]. Amide quaternary ammonium salt type cationic surfactant represented by the formula: (Wherein, R ¹⁴ CO is an aliphatic acyl group having 10 to 22 carbon atoms, R ¹⁵ and R ¹⁶ are a methyl group, an ethyl group or — (CH ₂ CH ₂ O) qH, and q is 1 to 20 and R ¹⁷
Is a methyl group, an ethyl group or a benzyl group, and Z ^- is a halogen ion or an alkyl sulfate ion having 1 to 2 carbon atoms. The total content of the components (A) and (B) is 5 to 60% by weight, and the weight ratio of the components (A) and (B) is 1/20 to 20/1. , (C) component content is 0.
A hair shampoo composition characterized in that the amount is from 0.5 to 5% by weight.