JPH10299903A - Ring gland packing and manufacture thereof - Google Patents

Ring gland packing and manufacture thereof

Info

Publication number
JPH10299903A
JPH10299903A JP11872497A JP11872497A JPH10299903A JP H10299903 A JPH10299903 A JP H10299903A JP 11872497 A JP11872497 A JP 11872497A JP 11872497 A JP11872497 A JP 11872497A JP H10299903 A JPH10299903 A JP H10299903A
Authority
JP
Japan
Prior art keywords
fluororesin
gland packing
tape
ring
tapes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11872497A
Other languages
Japanese (ja)
Inventor
Katsumi Watanabe
勝美 渡辺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nichias Corp
Original Assignee
Nichias Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nichias Corp filed Critical Nichias Corp
Priority to JP11872497A priority Critical patent/JPH10299903A/en
Publication of JPH10299903A publication Critical patent/JPH10299903A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To effectively prevent permeating leakage from between the layers of expansion graphite packing formed by a tape molding system by arranging expansion graphite and fluororesin alternately in spiral or concentric circle shape. SOLUTION: At the time of manufacturing a ring gland packing 3 used to prevent fluid leakage from a valve stem or the like, expansion graphite tapes 1 and fluororesin tapes 2 are overlapped in the state of the tips of the fluororesin tapes 2 being folded, and wound to an inner die of a molding die and then spirally wound and put in an outer die of the molding die for pressing to obtain the required ring gland packing 3. The fluororesin tapes 2 are therefore filled between the layers of the expansion graphite tapes 1 so as to eliminate leakage from between the layers. The ring gland packing with the face 2b of the fluororesin tape 2 exposed to the inner peripheral surface has the effect of reducing required torque at the time of rotating a shaft by the low sliding property of fluororesin.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、バルブ等の機器の
スタフィングボックス内に装填し、バルブステムからの
流体の漏れを防止する等の用途に使用されるリング状グ
ランドパッキンの改良に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improvement in a ring-shaped gland packing which is loaded into a stuffing box of a device such as a valve and used for preventing leakage of fluid from a valve stem.

【0002】[0002]

【従来の技術】従来、バルブステムあるいは回転軸(以
下、軸と称する)からの漏れを防止するために使用する
パッキンとしては、石綿繊維やカーボン繊維等の耐熱繊
維を八編み、袋編みあるいは格子編み等に編組し、潤滑
剤などを含浸させるか表面処理を行った、いわゆる編組
パッキンが多く使用されていた。かかるパッキンは耐熱
性・耐薬品性・耐摩耗性等が優れているために現在でも
広く使用されているが、近時、環境問題に対する意識の
高まり等から微少な漏れも問題とされるようになり、シ
ール性の高い膨張黒鉛を主原料として用いるパッキン
(以下、膨張黒鉛系パッキンと称する)が使用されるよ
うになってきた。
2. Description of the Related Art Conventionally, as a packing used to prevent leakage from a valve stem or a rotating shaft (hereinafter referred to as a shaft), heat-resistant fibers such as asbestos fiber and carbon fiber are knitted, sack-knitted or latticed. A so-called braided packing which is braided into a braid or the like and impregnated with a lubricant or the like or subjected to a surface treatment has been often used. Such packings are still widely used today because of their excellent heat resistance, chemical resistance, wear resistance, etc., but recently, small leaks have become a problem due to increased awareness of environmental issues. Thus, packing using expanded graphite having high sealing properties as a main material (hereinafter referred to as expanded graphite-based packing) has been used.

【0003】前記膨張黒鉛系パッキンには種々のタイプ
があるが、最も一般的なものはテープモールド式といわ
れ、膨張黒鉛製シートを所定の幅にスリットして得たテ
ープ状素材を成形用金型内に渦巻き状または同心円状に
配置した後、これを縦方向に加圧成形して得られたリン
グ状グランドパッキンである。
[0003] There are various types of the expanded graphite-based packing, and the most common type is called a tape mold type, and a tape-shaped material obtained by slitting an expanded graphite sheet into a predetermined width is used for forming metal. This is a ring-shaped gland packing obtained by spirally or concentrically arranging in a mold, and then press-molding this vertically.

【0004】また、別の成形方法としてはラミネート式
といわれ、膨張黒鉛製シートをリング状に打ち抜いたリ
ング状素材を成形用金型内に所定枚数積層し、これを縦
方向に加圧成形する方法があり、その他にこれらを組み
合わせた方法など数多くのものが知られている。
Another molding method is called a lamination method, in which a predetermined number of ring-shaped materials obtained by punching an expanded graphite sheet into a ring shape are laminated in a molding die, and this is press-formed in the longitudinal direction. There are methods, and many other methods are known, such as a method combining these methods.

【0005】[0005]

【発明が解決しようとする課題】ところが、従来の膨張
黒鉛系パッキンのうちテープモールド式により成形され
たリング状グランドパッキンでは、図5に示すように膨
張黒鉛製テープ1間に形成される微少な隙間(層間)か
ら流体fの浸透漏れが発生するという欠点があり、ラミ
ネート式により成形されたリング状グランドパッキンで
は、図6に示すようにパッキンに締め付け荷重を与えた
ときの径方向への圧力(側圧)が少ない上に、パッキン
自体の径方向への変形が小さく軸に対する密着力が弱い
ため、グランドパッキンと軸との間に微少な隙間が発生
することが避けられず、いずれも完全に流体をシールす
るまでには至っていない。
However, among the conventional expanded graphite-based packings, the ring-shaped gland packing formed by the tape mold method has a small size formed between the expanded graphite tapes 1 as shown in FIG. There is a disadvantage that leakage of the fluid f occurs from a gap (layer), and in a ring-shaped gland packing formed by a lamination method, as shown in FIG. 6, the pressure in the radial direction when a tightening load is applied to the packing. (Side pressure) is small, and the packing itself is less deformed in the radial direction and the adhesion to the shaft is weak. Therefore, it is unavoidable that a small gap is generated between the gland packing and the shaft. The fluid has not yet been sealed.

【0006】本発明の目的は、以上の問題点に鑑みてな
されたもので、テープモールド式により成形される膨張
黒鉛系パッキンの層間からの浸透漏れを有効に防止で
き、しかも製造が容易で安価に製造できるリング状グラ
ンドパッキンを提供することにある。
An object of the present invention has been made in view of the above problems, and it is possible to effectively prevent the leakage of the expanded graphite-based packing formed by the tape molding method from between the layers, and it is easy and inexpensive to manufacture. The present invention is to provide a ring-shaped gland packing which can be manufactured at a time.

【0007】[0007]

【課題を解決するための手段】上記目的を達成するため
請求項1の発明のリング状グランドパッキンは、膨張黒
鉛とフッ素樹脂が交互に渦巻き状または同心円状に配置
されていることを要旨としている。
According to a first aspect of the present invention, there is provided a ring-shaped gland packing in which expanded graphite and fluororesin are alternately arranged in a spiral or concentric manner. .

【0008】請求項2の発明は、請求項1の発明におい
て、フッ素樹脂製テープの幅が膨張黒鉛製テープの幅よ
りも狭いことを要旨とする。
[0008] The invention of claim 2 is the gist of the invention of claim 1, wherein the width of the fluororesin tape is smaller than the width of the expanded graphite tape.

【0009】請求項3の発明は、請求項1または2の発
明において、リング状グランドパッキンの内周面に前記
フッ素樹脂の面が出ていることを要旨とする。
According to a third aspect of the present invention, in the first or second aspect, the surface of the fluororesin is exposed on the inner peripheral surface of the ring-shaped gland packing.

【0010】請求項4の発明のリング状グランドパッキ
ンの製造方法は、膨張黒鉛製テープとフッ素樹脂製テー
プを渦巻き状または同心円状に配置した後、これを成形
用金型内に入れ縦方向に加圧成形することを要旨とす
る。
According to a fourth aspect of the present invention, there is provided a method of manufacturing a ring-shaped gland packing, comprising disposing spirally or concentrically a tape made of expanded graphite and a tape made of a fluororesin, placing the tape in a molding die and extending the tape vertically. The gist is to perform pressure molding.

【0011】[0011]

【発明の実施の形態】本発明の実施の形態としては、例
えば図3に示すように、厚さ0.38mm、幅16mm
の膨張黒鉛製テープ1と厚さ0.1mm、幅13mmの
フッ素樹脂製テープ2をフッ素樹脂製テープ2の先端を
折り返すようにして重ね合わせ、これを成形用金型の内
型に巻き付けた後渦巻き状に巻回して成形用金型の外型
内に入れ加圧成形した図1に示すようなリング状グラン
ドパッキンである。また図4に示すように、厚さ0.3
8mm、幅16mmの膨張黒鉛製テープ1とこれより幅
の狭いフッ素樹脂製テープ2を、先端約100mmが膨
張黒鉛製テープ1となるように重ね合わせ、これを同様
に渦巻き状に巻回した後、成形用金型で縦方向に加圧成
形した図2に示すようなリング状グランドパッキンであ
る。
DESCRIPTION OF THE PREFERRED EMBODIMENTS As an embodiment of the present invention, for example, as shown in FIG.
The expanded graphite tape 1 and a fluororesin tape 2 having a thickness of 0.1 mm and a width of 13 mm are overlapped with each other so that the tip of the fluororesin tape 2 is folded back, and this is wound around an inner die of a molding die. This is a ring-shaped gland packing as shown in FIG. 1 which is spirally wound, placed in an outer mold of a molding die, and pressure molded. Also, as shown in FIG.
An expanded graphite tape 1 having a width of 8 mm and a width of 16 mm and a fluororesin tape 2 having a narrower width are superimposed such that the leading end of the tape 1 becomes an expanded graphite tape 1, and the spirally wound tape is similarly wound. And a ring-shaped gland packing as shown in FIG.

【0012】本発明者らは、テープモールド式により成
形された膨張黒鉛製リング状グランドパッキンの膨張黒
鉛製テープ間に形成される微少な隙間(層間)を減らす
ために鋭意検討を行ない、まずはじめに膨張黒鉛製リン
グ状グランドパッキンの成形密度を大きくすることを検
討したが、膨張黒鉛製リング状グランドパッキンの上限
密度と思われる2.0g/cm3まで大きくしても、完
全に流体をシールするまでには至らなかった。
The present inventors have made intensive studies to reduce the minute gaps (interlayers) formed between the expanded graphite tapes of the expanded graphite ring-shaped gland packing formed by the tape molding method. We considered increasing the molding density of the expanded graphite ring-shaped gland packing. However, even if it was increased to 2.0 g / cm 3, which is considered to be the upper limit density of the expanded graphite ring-shaped gland packing, the fluid was completely sealed. Did not reach.

【0013】次に、膨張黒鉛製シートの表面にあらかじ
め液状のシール材を塗布してから従来のテープモールド
式により膨張黒鉛製リング状グランドパッキンを成形し
てみたが、加圧成形の圧力により塗布したシール材が層
間からはみ出し、外観が悪くなるという問題が発生し
た。
Next, a liquid sealing material was applied to the surface of the expanded graphite sheet in advance, and then a ring-shaped gland packing made of expanded graphite was formed by a conventional tape molding method. The sealing material protrudes from between the layers, causing a problem of poor appearance.

【0014】そこで本発明者らはさらに検討を行ない、
膨張黒鉛製テープにフッ素樹脂製テープを重ね合わせ、
これを渦巻き状に巻回した後、成形用金型で縦方向に加
圧成形してリング状グランドパッキンを成形したとこ
ろ、膨張黒鉛製テープの層間にフッ素樹脂製テープが充
填され、層間からの漏れがほとんどなくなることが判っ
た。また、図1のように内周面にフッ素樹脂製テープの
面2bが出るものは、フッ素樹脂の低摺動性により軸を
回転させる時に必要なトルクが小さくなるという効果も
あることが判った。
Therefore, the present inventors conducted further studies,
Overlay the fluoroplastic tape on the expanded graphite tape,
After this was spirally wound, a ring-shaped gland packing was formed by press-molding in a vertical direction with a molding die, and a fluororesin tape was filled between the layers of the expanded graphite tape. It was found that there was almost no leakage. In addition, it has been found that the one in which the surface 2b of the fluororesin tape is exposed on the inner peripheral surface as shown in FIG. 1 also has the effect of reducing the torque required when rotating the shaft due to the low sliding property of the fluororesin. .

【0015】[0015]

【実施例】以下、実施例により本発明を具体的に説明す
るが、本発明はこの実施例に限定されるものではない。 [実施例1] 厚さ0.38mm、幅16mmの膨張黒
鉛製テープに厚さ0.1mm、幅13mmの未焼成四フ
ッ化エチレン樹脂製テープ(ニチアス(株)製ナフロン
シールテープ)を図3に示すように未焼成四フッ化エチ
レン樹脂製テープの先端約10mmを折り返すようにし
て重ね合わせ、これを成形用金型の内型に巻き付けた後
渦巻き状に巻回して、成形用金型の外型内に入れ、縦方
向に加圧成形した図1に示すようなリング状(内径26
mm、外径42mm、高さ8mm)のグランドパッキン
を得た。 [実施例2] 実施例1の未焼成四フッ化エチレン樹脂
製テープの代わりに厚さ0.1mm、幅13mmの黒鉛
入り四フッ化エチレン樹脂製テープ(ゴアテックス
(株)製GFO)を用い、実施例1と同様に成形してリ
ング状(内径26mm、外径42mm、高さ8mm)の
グランドパッキンを得た。 [実施例3] 厚さ0.38mm、幅16mmの膨張黒
鉛製テープに厚さ0.1mm、幅13mmの未焼成四フ
ッ化エチレン樹脂製テープ(ニチアス(株)製ナフロン
シールテープ)を図4に示すように、先端約100mm
が膨張黒鉛製テープ1となるように重ね合わせ、これを
実施例1と同様に成形して図2に示すようなリング状
(内径26mm、外径42mm、高さ8mm)のグラン
ドパッキンを得た。 [比較例1] 厚さ0.38mm、幅16mmの膨張黒
鉛製テープを渦巻き状に巻回した後、成形用金型で縦方
向に加圧成形してリング状(内径26mm、外径42m
m、高さ8mm)のグランドパッキンを得た。
EXAMPLES The present invention will be described below in detail with reference to examples, but the present invention is not limited to these examples. Example 1 An expanded graphite tape having a thickness of 0.38 mm and a width of 16 mm and a tape made of unfired ethylene tetrafluoride resin having a thickness of 0.1 mm and a width of 13 mm (Naflon seal tape manufactured by Nichias Co., Ltd.) are shown in FIG. As shown in the figure, about 10 mm of the tip of the unfired tetrafluoroethylene resin tape is folded back and overlapped, wound around the inner mold of the molding die, and then spirally wound to form a molding die. A ring shape (inner diameter 26) as shown in FIG.
mm, outer diameter 42 mm, height 8 mm). [Example 2] Instead of the unfired ethylene tetrafluoride resin tape of Example 1, a graphite tetrafluoride ethylene resin tape (GFO manufactured by Gore-Tex Corp.) having a thickness of 0.1 mm and a width of 13 mm was used. In the same manner as in Example 1, a ring-shaped (inner diameter 26 mm, outer diameter 42 mm, height 8 mm) gland packing was obtained. Example 3 A tape made of expanded graphite tape having a thickness of 0.1 mm and a width of 13 mm (Naflon seal tape manufactured by Nichias Co., Ltd.) was applied to an expanded graphite tape having a thickness of 0.38 mm and a width of 16 mm. As shown in the figure, the tip is about 100mm
Are superimposed to form an expanded graphite tape 1 and molded in the same manner as in Example 1 to obtain a ring-shaped (inner diameter 26 mm, outer diameter 42 mm, height 8 mm) gland packing as shown in FIG. . [Comparative Example 1] An expanded graphite tape having a thickness of 0.38 mm and a width of 16 mm was spirally wound, and then formed into a ring shape (inner diameter: 26 mm, outer diameter: 42 m) by pressing in a vertical direction with a molding die.
m, height 8 mm).

【0016】上記実施例1〜3及び比較例1のリング状
グランドパッキンPを図7に示す出願人規格の試験機4
(ステム径26mm、スタフィングボックス内径42m
m、スタフィングボックス深さ150mm)にそれぞれ
4リング装着して面圧300kgf/cm2で締め付け、この
試験機4を常温にて7日間、さらに260℃で16時間
加熱した後、常温まで放冷するサイクルを7日間行い、
21kgf/cm2のヘリウムガスHを負荷したときの漏洩量
を測定した。常温時及び加熱サイクル時における7日間
の平均の漏洩量を表1に示す。なお、図7において、5
は軸、6はパッキン押さえ、7は締め付けボルト、8は
ランタンリング、9はガス加圧口、10はガス出口であ
る。
The ring-shaped gland packings P of Examples 1 to 3 and Comparative Example 1 are applied to a tester 4 of the applicant's standard shown in FIG.
(Stem diameter 26 mm, stuffing box inner diameter 42 m
m, stuffing box depth 150 mm), and tightened with a surface pressure of 300 kgf / cm 2. The tester 4 was heated at room temperature for 7 days and further at 260 ° C. for 16 hours, and then allowed to cool to room temperature Cycle for 7 days,
The amount of leakage when helium gas H of 21 kgf / cm 2 was loaded was measured. Table 1 shows the average amount of leakage for 7 days at normal temperature and during the heating cycle. In FIG. 7, 5
Is a shaft, 6 is a packing holder, 7 is a fastening bolt, 8 is a lantern ring, 9 is a gas pressurizing port, and 10 is a gas outlet.

【0017】[0017]

【表1】 [Table 1]

【0018】表1に示す如く、本発明による実施例1〜
3で得られたリング状グランドパッキンは、比較例1の
膨張黒鉛製リング状グランドパッキンに比べて常温時及
び加熱後の漏れが著しく減少していることが確認され
た。なお、今回の実施例はいずれも表面処理剤等を使わ
ずに使用しているが、使用目的に応じてはリング成形前
後に通常パッキンに用いられるタービン油等の鉱油系潤
滑剤、シリコンオイル、フッ素オイル、パラフィンワッ
クス等の潤滑剤や二硫化モリブデン、窒化ホウ素等の固
体潤滑剤を処理しても差し支えない。
As shown in Table 1, Examples 1 to 3 according to the present invention were used.
It was confirmed that the ring-shaped gland packing obtained in No. 3 had significantly less leakage at room temperature and after heating than the ring gland packing made of expanded graphite of Comparative Example 1. In addition, although all of the examples in this example are used without using a surface treatment agent or the like, depending on the purpose of use, mineral oil-based lubricants such as turbine oil or the like normally used for packing before and after ring molding, silicon oil, Lubricants such as fluorine oil and paraffin wax and solid lubricants such as molybdenum disulfide and boron nitride may be treated.

【0019】[0019]

【発明の効果】以上述べたように、本発明によるリング
状グランドパッキンは、従来の膨張黒鉛製リング状グラ
ンドパッキンと比較して、フッ素樹脂により膨張黒鉛製
シートの層間に生じる微少な隙間から生じる漏れがな
く、極めて良好なシール性を保持していることは明らか
である。
As described above, the ring-shaped gland packing according to the present invention is formed by minute gaps generated between layers of the expanded graphite sheet due to the fluororesin, as compared with the conventional expanded gland-made ring gland packing. Clearly, there is no leakage and very good sealability is maintained.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明のリング状グランドパッキンの一実施例
の断面斜視図である。
FIG. 1 is a sectional perspective view of one embodiment of a ring-shaped gland packing of the present invention.

【図2】本発明のリング状グランドパッキンの他の実施
例の断面斜視図である。
FIG. 2 is a sectional perspective view of another embodiment of the ring-shaped gland packing of the present invention.

【図3】本発明のリング状グランドパッキンの一実施例
の製造初期の状態を示す概略図である。
FIG. 3 is a schematic diagram showing an initial state of manufacture of an embodiment of the ring-shaped gland packing of the present invention.

【図4】本発明のリング状グランドパッキンの他の実施
例の製造初期の状態を示す概略図である。
FIG. 4 is a schematic view showing an initial state of manufacture of another embodiment of the ring-shaped gland packing of the present invention.

【図5】従来の膨張黒鉛製リング状グランドパッキンの
断面斜視図である。
FIG. 5 is a sectional perspective view of a conventional expanded graphite ring-shaped gland packing.

【図6】従来の他の膨張黒鉛製リング状グランドパッキ
ンの断面斜視図である。
FIG. 6 is a sectional perspective view of another conventional expanded graphite ring gland packing.

【図7】試験機の断面図である。FIG. 7 is a cross-sectional view of the testing machine.

【符号の説明】[Explanation of symbols]

1 膨張黒鉛製テープ 2 フッ素樹脂製テープ 2a 折り返し部 2b 内周面 3 リング状グランドパッキン f 流体 H ヘリウムガス P 供試用グランドパッキン 4 試験機本体 5 軸 6 パッキン押さえ 7 締め付けボルト 8 ランタンリング 9 ガス加圧口 10 ガス出口 DESCRIPTION OF SYMBOLS 1 Expansive graphite tape 2 Fluororesin tape 2a Folded part 2b Inner peripheral surface 3 Ring-shaped gland packing f Fluid H Helium gas P Test gland packing 4 Test machine main body 5 Shaft 6 Packing holder 7 Tightening bolt 8 Lantern ring 9 Gas supply Pressure port 10 Gas outlet

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 膨張黒鉛とフッ素樹脂が交互に渦巻き状
または同心円状に配置されていることを特徴とするリン
グ状グランドパッキン。
1. A ring-shaped gland packing in which expanded graphite and fluororesin are alternately arranged in a spiral or concentric manner.
【請求項2】 フッ素樹脂製テープの幅が膨張黒鉛製テ
ープの幅よりも狭いことを特徴とする請求項1記載のリ
ング状グランドパッキン。
2. The ring-shaped gland packing according to claim 1, wherein the width of the fluororesin tape is smaller than the width of the expanded graphite tape.
【請求項3】 リング状グランドパッキンの内周面に前
記フッ素樹脂の面が出ていることを特徴とする請求項1
または2記載のリング状グランドパッキン。
3. The fluororesin surface is exposed on the inner peripheral surface of the ring-shaped gland packing.
Or the ring-shaped gland packing of 2.
【請求項4】 膨張黒鉛製テープとフッ素樹脂製テープ
を渦巻き状または同心円状に配置した後、これを成形用
金型内に入れ縦方向に加圧成形することを特徴とするリ
ング状グランドパッキンの製造方法。
4. A ring-shaped gland packing characterized in that an expandable graphite tape and a fluororesin tape are spirally or concentrically arranged, and then placed in a molding die and pressure-formed in the vertical direction. Manufacturing method.
JP11872497A 1997-04-22 1997-04-22 Ring gland packing and manufacture thereof Pending JPH10299903A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11872497A JPH10299903A (en) 1997-04-22 1997-04-22 Ring gland packing and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11872497A JPH10299903A (en) 1997-04-22 1997-04-22 Ring gland packing and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH10299903A true JPH10299903A (en) 1998-11-13

Family

ID=14743521

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11872497A Pending JPH10299903A (en) 1997-04-22 1997-04-22 Ring gland packing and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH10299903A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014083786A (en) * 2012-10-25 2014-05-12 Lignyte Co Ltd Graphite sheet composite material and method for producing the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014083786A (en) * 2012-10-25 2014-05-12 Lignyte Co Ltd Graphite sheet composite material and method for producing the same

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