JPH10148837A - Liquid crystal display element - Google Patents

Abstract

PROBLEM TO BE SOLVED: To simplify production stages, to obviate the occurrence of flaws on a substrate surface and to make an inter-substrate spacing uniform by joining the outer peripheral parts of the substrates on the side outer than a curable sealing material by fusion joining, etc., thereby temporally stopping the substrates before curing the sealing material. SOLUTION: Gap spacer materials 2 are sprayed by a wet process spraying method on the surface subjected to an orientation treatment of the one substrate 1 of the substrates 1 and 6 which are the resin substrates subjected to the orientation treatments. On the other hand, the sealing material 4 of a one-component type epoxy system is formed on the surface subjected to the orientation treatment of the other substrate 6 by screen printing. The substrate 1 sprayed with the gap spacer materials 2 is superposed on the other substrate and the outer peripheral parts of the sealing material 4 are heated by thermal press bonding terminals while the sealing material is held pressurized to weld and join the substrates 1 and 6. The sealing material 4 is thereafter adhered and cured and the fusion joined parts 5 are cut off. The liquid crystal cell (empty cell) formed in such a manner is set into a reduced pressure chamber, following which the inside of the chamber is evacuated. Nematic liquid crystals are injected from the liquid crystal injection port of the empty cell.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

[0001] The present invention relates to a liquid crystal display device.

[0002]

2. Description of the Related Art In recent years, liquid crystal display elements have been widely used as substitute display elements for cathode-ray tubes or as portable small display elements such as pagers and mobile phones, taking advantage of the advantages of thinness, light weight, and low power consumption. . In order to improve display quality of these display elements, it is important to make the liquid crystal layer uniform between liquid crystal substrates and to have a thinner liquid crystal layer interval. Conventionally,
One-part or two-part epoxy resin is used as a sealant for this type of liquid crystal substrate. Screen printing or dispensing is applied to one side of the substrate, and then superimposed and held on one side of the substrate The sealant was cured by heating while keeping the temperature. However, this method requires a time for curing from several tens of minutes to several hours, and has a problem in process tact. On the other hand, when the substrate material is glass, a method of raising the curing temperature as much as possible and shortening the curing time is generally adopted, but when the substrate material is plastic, there is a limit to increasing the curing temperature. It cannot be an effective means. Furthermore, if the temperature is increased while pressurizing the plastic substrate, if dust enters between the pressure plate and the plastic substrate, traces of the dust remain on the plastic substrate or the pressure plate is transferred to the plastic substrate to increase the yield. It was a cause of lowering. In addition, we studied to switch the material of the sealant to a UV-curable adhesive that can be cured at a low temperature and in seconds, but the adhesive strength, moisture permeability,
At present, there is still a problem in reliability such as liquid crystal resistance (the sealant attacks the liquid crystal), and it has not been adopted yet.

[0003]

SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems, and heat-curs a sealant to maintain uniform distance between liquid crystal substrates without holding a superposed substrate under pressure. It is an object of the present invention to provide a liquid crystal display element having display unevenness eliminated by maintaining the thickness in the order of μm, and a method of manufacturing a liquid crystal display element with improved yield and process tact.

[0004]

According to the present invention, a pair of substrates having an electrode layer provided on at least one of the substrates is laminated on the periphery of the substrate via a curable sealant formed by printing or coating. A liquid crystal display characterized in that a liquid crystal layer is sandwiched between substrates formed by bonding and bonding the outer peripheral portions of the substrate outside the sealant to each other by fusion bonding or the like, and then curing the sealant. The present invention relates to an element and a method for manufacturing the display element.

In the present invention, since the outer peripheral portion of the substrate outside the sealant is bonded by fusion bonding or the like before the curable sealant is cured as described above, the base material is temporarily fixed.
The sealant can be cured without applying pressure, and the sealant can be cured at a higher temperature than when the sealant is cured under pressure. Therefore, not only the manufacturing process of the liquid crystal display element is simplified, but also unlike the conventional case where the curing temperature is increased and pressure is applied, the substrate surface is not damaged and the substrate spacing is uniform.

As a method for bonding the substrates, for example, a heat sealing method in which the substrates are heated and melt-bonded using thermocompression bonding terminals, a method in which the substrates are similarly heated and melt-bonded using ultrasonic waves as a heating means, and a method using chemicals There is a method of melting and joining the substrates to each other. The chemicals used here are
Although an appropriate material is appropriately selected in consideration of the material constituting the base material, an organic solvent such as methylene chloride, methyl ethyl ketone, and tetrahydrofuran is usually preferable from the viewpoint of easy handling and availability.

The substrate is not particularly limited as long as it can be bonded to each other by the above-mentioned fusion bonding means, and examples thereof include polyarylate resin, polycarbonate resin, and polyether sulfone. These substrates are usually formed by forming an alignment film such as a polyimide alignment film, and the alignment film is subjected to an alignment treatment by a rubbing treatment or the like.

[0008] Examples of the thermosetting sealant include thermosetting epoxy resins. In the liquid crystal display element of the present invention, after the liquid crystal layer is sandwiched between the substrates, the above-mentioned fusion bonding of the substrates may be cut.

Examples of the present invention will be described below, but the present invention is not limited to these examples.

Example 1 A 0.1 mm thick polyarylate resin was used as a transparent substrate.
I prepared it. An ITO film was formed as a transparent electrode on this substrate to a thickness of 1000 ° by a sputtering method. This ITO film was patterned into a predetermined shape by photolithography, etched and processed. A polyimide-based aligning agent is dissolved and dispersed in a mixed solvent of γ-butyrolactone / N-methyl-2-pyrrolidine on this surface, formed into a film by flexographic printing, baked at 125 ° C. for 90 minutes, and then rubbed in a certain direction with a rubbing cloth. An orientation treatment was performed. The polyarylate resin substrates subjected to this orientation treatment were designated as substrates 1 and 6 shown in FIG. Next, a gap spacer material 2 on which one substrate 1 was subjected to an orientation treatment was sprayed by a wet spraying method. A spherical polymer resin (particle size: 8.7 μm) was used for the gap material spacer material 2.

On the other hand, a one-component epoxy-based sealant 4 is formed by screen printing on the surface of another substrate 6 which has been subjected to the orientation treatment, and the substrate 1 on which the gap spacer material 2 has been sprayed is superposed and held under pressure. The outer periphery of the sealing agent 4 is heated by a thermocompression bonding terminal while the substrates 1 and 6 are melt-bonded. afterwards,
The sealant 4 is bonded and cured by baking at 120 ° C. for 1 hour, and the melted joint 5 is cut off. After setting the liquid crystal cell (empty cell) thus prepared in a decompression chamber, a few mm
Evacuation is performed to about rr, and a nematic liquid crystal is injected from a liquid crystal injection port (not shown) of the empty cell by utilizing a capillary phenomenon. According to this embodiment, the manufacturing process of the liquid crystal display element is simplified, and the obtained liquid crystal display element has no scratches on the substrate surface and uniform spacing between the substrates, so that there is no color unevenness and the background color is uniform. The image quality was excellent.

Example 2 A liquid crystal display device was prepared in the same manner as in Example 1 except that the substrates 1 and 6 were melt-bonded to each other by using an ultrasonic vibration element on the inner surface of the substrate at the outer peripheral portion of the sealant 4. .

Example 3 A liquid crystal display device was prepared in the same manner as in Example 1 except that the outer periphery of the sealant 4 was melted with methylene chloride and the substrates 1 and 6 were melt-bonded with crimp terminals. .

Example 4 A liquid crystal display device was prepared in the same manner as in Example 1 except that the transparent substrate was changed from a polyarylate resin having a thickness of 0.1 mm to a polycarbonate resin having a thickness of 0.1 mm.

[0015]

[Effect] Since the outer peripheral portion of the substrate is temporarily fixed outside the sealant, the sealant can be hardened without applying pressure, and the sealant can be hardened at a higher temperature than when pressurized. And the substrate can be cured without pressure, so that the substrate is not damaged. For this reason, the substrate spacing is also uniform, and it is easy to produce a liquid crystal display element having a uniform background color without color unevenness.

[Brief description of the drawings]

FIG. 1 is a schematic sectional view of a liquid crystal display device of the present invention.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Substrate 2 Gap spacer material 3 Liquid crystal 4 Sealant 5 Melt joint 6 Substrate

Claims (5)

[Claims] 1. A pair of substrates provided with an electrode layer on at least one of the substrates is superimposed on the periphery of the substrate via a thermosetting sealant, and the pair of substrates is disposed outside the sealant. A liquid crystal display device in which a liquid crystal layer is sandwiched between substrates formed by bonding and then thermosetting the sealant. 2. The liquid crystal display device according to claim 1, wherein the pair of substrates is a plastic substrate. 3. The liquid crystal display device according to claim 1, wherein the bonding of the pair of substrates is performed by hot-melt bonding. 4. The liquid crystal display device according to claim 1, wherein the pair of substrates is bonded by a chemical treatment. 5. A pair of substrates provided with an electrode layer are superimposed on the periphery of the substrate via a sealant, and the pair of substrates is joined outside the sealant, and then the sealant is thermally cured. A method for manufacturing a liquid crystal display element, comprising sandwiching a liquid crystal layer in a substrate gap formed by the above method.