JPH10115988A - Conductive member and its manufacture, and image forming device using it - Google Patents

Conductive member and its manufacture, and image forming device using it

Info

Publication number
JPH10115988A
JPH10115988A JP17521397A JP17521397A JPH10115988A JP H10115988 A JPH10115988 A JP H10115988A JP 17521397 A JP17521397 A JP 17521397A JP 17521397 A JP17521397 A JP 17521397A JP H10115988 A JPH10115988 A JP H10115988A
Authority
JP
Japan
Prior art keywords
conductive member
image forming
electric resistance
conductive
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP17521397A
Other languages
Japanese (ja)
Inventor
Tadashi Nakajima
正 中島
Hiroko Maeda
裕子 前田
Manabu Yakushiji
薬師寺  学
Takahiro Kawagoe
隆博 川越
Kanji Inoue
完治 井上
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Priority to JP17521397A priority Critical patent/JPH10115988A/en
Publication of JPH10115988A publication Critical patent/JPH10115988A/en
Pending legal-status Critical Current

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  • Conductive Materials (AREA)
  • Dry Development In Electrophotography (AREA)
  • Electrostatic Charge, Transfer And Separation In Electrography (AREA)
  • Rolls And Other Rotary Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a conductive member in which the increase of electric resistance by continuous energizing is small, and between the varying width of the electric resistance at the time of a low temperature and a low humidity and that at the time of a high temperature and a high humidity is small, and which is suitably used as a developing member and an electrifying member for electrophotographic processing. SOLUTION: The electric resistance with measuring voltage of 1000V under the conditions of temperature 15 deg.C and relative humidity 10% is equal to or below ten times of the electric resistance with measuring voltage 1000V under the conditions of temperature 32.5 deg.C and relative humidity 85%, and also the electric resistance with measuring voltage 1000V under the conditions of temperature 15 deg.C and relative humidity 10% after continuously energizing by electric power 10mW is made equal to or below three times of the electric resistance with measuring voltage 1000V under the same conditions as before continuous energizing.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、帯電防止機能を有
する包装部材、帯電防止機能を有する衝撃吸収部材、特
に電子写真プロセスなどで使用される現像部材や転写部
材として好適に使用される導電性部材及びその製造方
法、並びに該導電性部材を用いた画像形成装置に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a packaging member having an antistatic function, a shock absorbing member having an antistatic function, and in particular, to a conductive member suitably used as a developing member or a transfer member used in an electrophotographic process or the like. The present invention relates to a member, a manufacturing method thereof, and an image forming apparatus using the conductive member.

【0002】[0002]

【従来の技術及び発明が解決しようとする課題】近年、
電子写真技術の進歩にともなってレーザプリンターや乾
式複写機などの画像形成装置に用いられる導電性部材の
性能に対する要求も厳しくなっており、とりわけ現像,
転写等のプロセスに用いにれる弾性ローラの性能が注目
されている。
2. Description of the Related Art In recent years,
With the advance of electrophotographic technology, the demands on the performance of conductive members used in image forming apparatuses such as laser printers and dry copying machines have become strict.
Attention has been paid to the performance of elastic rollers used in processes such as transfer.

【0003】従来、このような用途に用いられる導電性
部材は、金属又は金属酸化物の粉末や、ウィスカー,カ
ーボンブラックなどの導電性フィラーを混入して所定の
抵抗値に調整したゴムやウレタンなどからなる高分子エ
ラストマー材料や高分子フォーム材料により形成されて
いた。これらの導電性部材を電子写真プロセスにおける
現像部材や転写部材として用いる場合に要求される性能
は、1×104〜1×1012Ωcm程度の中抵抗領域で
所定の電気抵抗を有しているだけにとどまらず、低温低
湿時と高温高湿時とで電気抵抗の変動幅が小さく、かつ
連続して通電した際の電気抵抗の変動幅が少ないことで
ある。
Conventionally, conductive members used in such applications include powders of metals or metal oxides, and rubber or urethane adjusted to a predetermined resistance value by mixing a conductive filler such as whisker or carbon black. Formed of a polymer elastomer material or a polymer foam material. The performance required when these conductive members are used as a developing member or a transfer member in an electrophotographic process has a predetermined electric resistance in a medium resistance region of about 1 × 10 4 to 1 × 10 12 Ωcm. Not only that, the fluctuation width of the electric resistance between low temperature and low humidity and the high temperature and high humidity is small, and the fluctuation width of the electric resistance when energized continuously is small.

【0004】ところが、金属や金属酸化物の粉末、又は
ウィスカーやアセチレンブラック,ケッチェンブラック
等の導電性カーボンブラックなどの導電性フィラーを混
入することにより所定の抵抗値に調整した高分子エラス
トマーや高分子フォーム等からなる導電性部材は、製造
時の電気抵抗に位置ばらつきが大きく、特にカーボンブ
ラックを用いた導電性部材には、通常、連続通電により
電気抵抗が徐々に増大するという欠点がある。
However, a high molecular elastomer or a high molecular elastomer which is adjusted to a predetermined resistance value by mixing a metal or metal oxide powder, or a conductive filler such as whisker, conductive carbon black such as acetylene black or Ketjen black, or the like is used. A conductive member made of a molecular foam or the like has a large positional variation in electric resistance at the time of manufacturing. In particular, a conductive member using carbon black has a drawback that the electric resistance usually gradually increases by continuous energization.

【0005】また、導電性部材を得る別の手段として、
過塩素酸リチウム,過塩素酸ナトリウム,過塩素酸カル
シウムなどの無機イオン物質、陽イオン性界面活性剤、
両性イオン界面活性剤、過塩素酸テトラエチルアンモニ
ウム,過塩素酸テトラブチルアンモニウム,ホウフッ化
テトラブチルアンモニウム等の4級アンモニウム塩など
の有機イオン物質よりなる導電剤及び/又は親水性のポ
リエーテルやポリエステル等の帯電防止剤を混入して所
定の抵抗値に調整したゴムやウレタンなどからなる高分
子エラストマーや高分子フォーム材料を用いる方法もあ
る。
Further, as another means for obtaining a conductive member,
Inorganic ionic substances such as lithium perchlorate, sodium perchlorate and calcium perchlorate, cationic surfactants,
Zwitterionic surfactants, conductive agents composed of organic ionic substances such as quaternary ammonium salts such as tetraethylammonium perchlorate, tetrabutylammonium perchlorate and tetrabutylammonium borofluoride, and / or hydrophilic polyethers and polyesters There is also a method of using a polymer elastomer or a polymer foam material made of rubber, urethane, or the like, which is adjusted to a predetermined resistance value by mixing an antistatic agent.

【0006】しかしながら、このような物質を混入する
ことにより所定の抵抗値に調整した高分子エラストマー
や高分子フォーム材料などで形成した導電性部材は、低
温低湿時と高温高湿時とで電気抵抗の変動幅が大きいと
いう欠点がある。
However, a conductive member formed of a polymer elastomer or a polymer foam material adjusted to a predetermined resistance value by mixing such a substance has an electric resistance between low temperature and low humidity and high temperature and high humidity. There is a disadvantage that the range of fluctuation of is large.

【0007】本発明は、上記事情に鑑みなされたもの
で、連続通電による電気抵抗の増大が小さく、かつ低温
低湿時と高温高湿時とでの電気抵抗の変動幅も小さく、
更に電気抵抗の位置ばらつきが小さく、電子写真プロセ
スにおける現像部材や転写部材として好適に使用される
導電性部材、その製造方法、及び該導電性部材を用いた
画像形成装置を提供することを目的とする。
The present invention has been made in view of the above circumstances, and the increase in electric resistance due to continuous energization is small, and the fluctuation range of electric resistance between low temperature and low humidity and high temperature and high humidity is small.
Further, it is an object of the present invention to provide a conductive member which has a small variation in electric resistance and is preferably used as a developing member or a transfer member in an electrophotographic process, a method for manufacturing the same, and an image forming apparatus using the conductive member. I do.

【0008】[0008]

【課題を解決するための手段及び発明の実施の形態】本
発明者は、上記目的を達成するため鋭意検討を行った結
果、温度15℃,相対湿度10%の条件下における測定
電圧1000Vでの電気抵抗が、温度32.5℃,相対
湿度85%の条件下における測定電圧1000Vでの電
気抵抗の10倍以下であり、かつ電力10mWで連続通
電した後の温度15℃,相対湿度10%の条件下におけ
る測定電圧1000Vでの電気抵抗が、連続通電前の同
条件下における測定電圧1000Vでの電気抵抗の3倍
以下である導電性部材であれば、電子写真プロセスにお
ける現像部材や転写部材として用いた場合でも、十分満
足し得る性能を使用環境の変動や連続通電にかかわらず
確実に発揮し得ることを見い出した。そして、本発明者
は検討を進めた結果、導電性の高分子エラストマーや高
分子フォーム材料などで所望形状の導電性部材を成形し
た後、これを熱処理することによって、このような優れ
た性能を有する導電性部材が得られることを見い出し、
本発明を完成したものである。
Means for Solving the Problems and Embodiments of the Invention As a result of diligent studies to achieve the above object, the present inventor has found that a measurement voltage of 1000 V at a temperature of 15 ° C. and a relative humidity of 10% is obtained. The electric resistance is 10 times or less of the electric resistance at a measurement voltage of 1000 V under the conditions of a temperature of 32.5 ° C. and a relative humidity of 85%, and at a temperature of 15 ° C. and a relative humidity of 10% after continuous energization with a power of 10 mW. A conductive member whose electrical resistance at a measurement voltage of 1000 V under the condition is three times or less the electrical resistance at a measurement voltage of 1000 V under the same condition before continuous energization is used as a developing member or a transfer member in an electrophotographic process. It has been found that even when used, sufficiently satisfactory performance can be surely exerted irrespective of changes in the use environment or continuous energization. As a result of studying the present inventor, after forming a conductive member of a desired shape with a conductive polymer elastomer or a polymer foam material and the like, and performing a heat treatment on the conductive member, such excellent performance is obtained. Have found that a conductive member having
The present invention has been completed.

【0009】従って、本発明は、温度15℃,相対湿度
10%の条件下における測定電圧1000Vでの電気抵
抗が、温度32.5℃,相対湿度85%の条件下におけ
る測定電圧1000Vでの電気抵抗の10倍以下であ
り、かつ電力10mWで連続通電した後の温度15℃,
相対湿度10%の条件下における測定電圧1000Vで
の電気抵抗が、連続通電前の同条件下における測定電圧
1000Vでの電気抵抗の3倍以下であることを特徴と
する導電性部材、及び、所望形状の導電性部材を成形し
た後、これを熱処理することを特徴とする導電性部材の
製造方法を提供する。
Therefore, according to the present invention, the electric resistance at a measurement voltage of 1000 V under the conditions of a temperature of 15 ° C. and a relative humidity of 10% is an electric resistance at a measurement voltage of 1000 V under a condition of a temperature of 32.5 ° C. and a relative humidity of 85%. A temperature of 15 ° C. after continuous energization at a power of 10 mW which is 10 times or less of the resistance,
A conductive member having an electrical resistance at a measurement voltage of 1000 V under a condition of a relative humidity of 10% that is three times or less than an electrical resistance at a measurement voltage of 1000 V under the same condition before continuous energization; A method for manufacturing a conductive member, comprising: forming a conductive member having a shape; and heat-treating the formed conductive member.

【0010】ここで、熱処理によって、上述のような連
続通電による電気抵抗の増大が小さく、かつ低温低湿時
と高温高湿時とでの電気抵抗の変動幅も小さく、更に電
気抵抗の位置ばらつきも小さい導電性部材が得られる理
由は、必ずしも明かではないが、以下のように考えるこ
とができる。即ち、本発明の効果は、特に制限されるも
のではないが、ガスブラック、オイルファーネスブラッ
ク、サーマルブラック、インクブラック、導電性ブラッ
ク等のカーボンブラックなどからなる導電性フィラーを
混入して導電性を調整した場合に特に顕著であり、この
ことから見るに、カーボンブラック等の導電性フィラー
によって成形時に形成された導電パスを導電性高分子材
料に応力が加わっていない状態で加熱することにより、
導電性フィラーを高分子の熱運動で安定化,再配置する
ことができ、これにより導電性部材の特性が向上するも
のと考えられる。
[0010] Here, the increase in electric resistance due to the continuous energization as described above due to the heat treatment is small, and the fluctuation range of electric resistance between low temperature and low humidity and high temperature and high humidity is small. The reason why a small conductive member can be obtained is not necessarily clear, but can be considered as follows. That is, the effect of the present invention is not particularly limited, but the conductivity is mixed by mixing a conductive filler such as carbon black such as gas black, oil furnace black, thermal black, ink black, and conductive black. It is particularly remarkable when adjusted, and from this it can be seen that by heating the conductive path formed at the time of molding with a conductive filler such as carbon black in a state where stress is not applied to the conductive polymer material,
It is considered that the conductive filler can be stabilized and rearranged by the thermal motion of the polymer, thereby improving the properties of the conductive member.

【0011】また、本発明の導電性部材は、電子写真プ
ロセスに従って画像形成を行う画像形成装置に用いられ
る現像機構部の現像部材や転写機構部の転写部材として
好適に用いられるものであり、具体的には、現像部材の
表面に現像剤を担持して該現像剤の薄層を形成し、この
状態で現像部材を画像形成体に接触又は近接させて画像
形成体表面に上記現像剤を供給することにより、該画像
形成体表面に可視画像を形成する現像機構を具備した画
像形成装置における上記現像部材や、転写部材に近接又
は接触させて記録媒体を帯電させ、画像形成体表面に形
成された可視画像を前記記録媒体に転写する転写機構を
具備した画像形成装置における上記転写部材として特に
好ましく用いられ、この場合、高品質な画像を使用環境
等に影響されることなく確実に得ることができ、その効
果が顕著である。
Further, the conductive member of the present invention is suitably used as a developing member of a developing mechanism used in an image forming apparatus for forming an image in accordance with an electrophotographic process and a transfer member of a transfer mechanism. Specifically, the developer is carried on the surface of the developing member to form a thin layer of the developer, and in this state, the developing member is brought into contact with or close to the image forming body to supply the developer to the surface of the image forming body. By doing so, the developing member in the image forming apparatus provided with a developing mechanism for forming a visible image on the surface of the image forming body, or the recording medium is charged by approaching or in contact with the transfer member to form the recording medium on the surface of the image forming body. It is particularly preferably used as the transfer member in an image forming apparatus provided with a transfer mechanism for transferring a visible image onto the recording medium. In this case, a high-quality image is affected by the use environment and the like. Without it is possible to reliably obtain the effect is remarkable.

【0012】従って、本発明は、現像部材の表面に現像
剤を担持して該現像剤の薄層を形成し、この状態で現像
部材を画像形成体に接触又は近接させて、画像形成体表
面に上記現像剤を供給することにより、該画像形成体表
面に可視画像を形成する現像機構を具備した画像形成装
置において、前記現像部材が上記本発明の導電性部材で
あることを特徴とする画像形成装置、及び、転写部材に
近接又は接触させて記録媒体を帯電させ、画像形成体表
面に形成された可視画像を前記記録媒体に転写する転写
機構を具備した画像形成装置において、前記転写部材が
上記本発明の導電性部材であることを特徴とする画像形
成装置を提供する。
Accordingly, the present invention provides a method for forming a thin layer of a developer by carrying the developer on the surface of the developing member, and bringing the developing member into contact with or in proximity to the image forming body in this state, An image forming apparatus having a developing mechanism for forming a visible image on the surface of the image forming body by supplying the developer to the image forming apparatus, wherein the developing member is the conductive member of the present invention. A forming device, and an image forming apparatus having a transfer mechanism for charging a recording medium in proximity to or in contact with a transfer member and transferring a visible image formed on the surface of an image forming body to the recording medium, wherein the transfer member is An image forming apparatus characterized by being the conductive member of the present invention is provided.

【0013】以下、本発明につき更に詳しく説明する。
本発明の導電性部材を形成する導電性材料は、部材の用
途等に応じて適宜選定され、特に制限されるものではな
いが、通常はゴムやウレタン樹脂に導電剤を添加して導
電性を調整した高分子エラストマーや高分子フォーム材
料が用いられ、これらを用途に応じて所望の形状に成形
することにより、本発明の導電性部材が得られるもので
ある。
Hereinafter, the present invention will be described in more detail.
The conductive material forming the conductive member of the present invention is appropriately selected according to the use of the member and the like, and is not particularly limited. However, usually, a conductive agent is added to rubber or urethane resin to increase the conductivity. An adjusted polymer elastomer or polymer foam material is used, and the conductive member of the present invention can be obtained by molding these into a desired shape according to the application.

【0014】まず、材料としてゴムを用いる場合には、
例えば天然ゴム(NR)、ブタジエンゴム(BR)、ス
チレンブタジエンゴム(SBR)、イソプレンゴム(I
R)、エチレンプロピレンゴム(EPM,EPDM)、
ニトリルゴム(NBR)等のゴムに導電剤、硫黄や過酸
化物等の架橋剤、老化防止剤、架橋反応促進剤等を混合
した後、この混合物を所望の形状が型取りされた金型内
に注入・射出成形する方法、又はこの混合物を押し出し
成形する方法等の公知の成形方法を使用して加熱硬化さ
せることにより、所望形状の導電性部材を得る方法が好
ましく用いられるが、必要に応じて得られた導電性部材
の表面を研磨・切削加工することもできる。
First, when rubber is used as a material,
For example, natural rubber (NR), butadiene rubber (BR), styrene butadiene rubber (SBR), isoprene rubber (I
R), ethylene propylene rubber (EPM, EPDM),
A rubber such as nitrile rubber (NBR) is mixed with a conductive agent, a cross-linking agent such as sulfur or peroxide, an antioxidant, a cross-linking reaction accelerator, and the like, and the mixture is placed in a mold having a desired shape. A method of obtaining a conductive member having a desired shape by heating and curing using a known molding method such as a method of injection / injection molding into a mixture or a method of extruding the mixture is preferably used. The surface of the conductive member thus obtained can be polished and cut.

【0015】また、材料としてウレタンを用いる場合に
は、例えばポリエーテルポリオール、ポリエステルポリ
オール、ポリブタジエンポリオール、ポリイソプレンポ
リオール、グリセリンにポリエチレンオキサイドやポリ
プロピレンオキサイドを付加重合したポリオール、ポリ
エチレングリコール、プロパンジオール、ブタンジオー
ル等のポリオール成分と、トリレンジイソシアネート
(TDI)、ジフェニルメタンジイソシアネート(MD
I)粗製ジフェニルメタンジイソシアネート(クルード
MDI)、イソホロンジイソシアネート等のポリイソシ
アネート成分とからなるウレタンに導電剤、架橋反応触
媒、整泡剤等を混合した後、この混合物を所望の形状が
型取りされた金型内に注入・射出する方法、又はこの混
合物を押し出し成形する方法等の公知の成形方法を使用
して加熱硬化させることにより、所望形状の導電性部材
を得る方法が好ましく用いられるが、必要に応じて得ら
れた導電性部材の表面を研磨・研削加工することもでき
る。なお、ポリオール成分を予めイソシアネートにより
プレポリマー化しておくこともできる。
When urethane is used as a material, for example, polyether polyol, polyester polyol, polybutadiene polyol, polyisoprene polyol, polyol obtained by addition-polymerizing polyethylene oxide or polypropylene oxide to glycerin, polyethylene glycol, propanediol, butanediol Polyol components such as tolylene diisocyanate (TDI), diphenylmethane diisocyanate (MD
I) After mixing a conductive agent, a crosslinking reaction catalyst, a foam stabilizer and the like with urethane comprising a polyisocyanate component such as crude diphenylmethane diisocyanate (crude MDI) and isophorone diisocyanate, the mixture is molded into a gold having a desired shape. A method of obtaining a conductive member having a desired shape by heating and curing using a known molding method such as a method of injecting and injecting the mixture into a mold or a method of extruding the mixture is preferably used. The surface of the conductive member obtained accordingly can also be polished and ground. Incidentally, the polyol component may be prepolymerized with isocyanate in advance.

【0016】なお、用途等によっては導電性部材を低硬
度化する等の目的で、これらの材料を発泡体とすること
も好ましい。材料の発泡方法は、特に限定されず、材料
がゴムの場合には発泡剤による方法が好ましく、一方、
材料がウレタンの場合には発泡剤による方法又は機械的
な撹拌により気泡を混入する方法が好ましく採用され
る。
In some applications, these materials are preferably made into foams for the purpose of lowering the hardness of the conductive member. The method of foaming the material is not particularly limited, and when the material is rubber, a method using a foaming agent is preferable.
When the material is urethane, a method using a foaming agent or a method of mixing air bubbles by mechanical stirring is preferably adopted.

【0017】ここで、本発明の導電性部材に用いられる
導電剤としては、例えば、ケッチェンブラック,電化ブ
ラック等のガスブラック、SFR級,GPF級,FEF
級,HAF級,ISAF級,SAF級等のオイルファー
ネスブラック、FT級,MT級,旭サーマル等のサーマ
ルブラック、三菱化学#25,#33,#44,#4
5,#52,#95,CF9等のインクブラック、三菱
化学#3050,#3250等の導電性ブラック、デグ
ザックPrintex 150 T 等のチャンネルブ
ラック、コロンビアンRaven 780 等の疑似ラ
ンプブラックやランプブラック、酸化スズ,酸化亜鉛,
酸化チタン等の金属酸化物や酸化スズ,酸化亜鉛,酸化
チタン等に導電性処理を施した表面処理金属酸化物、同
フレークや同ウィスカー等の金属からなる導電性フィラ
ーなどが挙げられる。これら導電剤の添加量はゴム又は
ウレタン等の主材料100重量に対して0.01〜50
重量部であることが好ましく、特に中抵抗領域で安定に
抵抗を制御する観点からDBP吸油量が30〜125m
l/100g(ミディアムストラクチャー)のカーボン
ブラックを0.5〜10重量部程度添加することが好ま
しい。
Here, as the conductive agent used for the conductive member of the present invention, for example, gas black such as Ketjen black, electrified black, SFR grade, GPF grade, FEF
Furnace, HAF, ISAF, SAF, etc. oil furnace black, FT, MT, Asahi Thermal and other thermal blacks, Mitsubishi Chemical # 25, # 33, # 44, # 4
5, # 52, # 95, ink black such as CF9, etc., conductive black such as Mitsubishi Chemical # 3050 and # 3250, channel black such as Degusz Printex 150 T, pseudo lamp black or lamp black such as Columbian Raven 780, and oxidation. Tin, zinc oxide,
Examples include a metal oxide such as titanium oxide, a surface-treated metal oxide obtained by subjecting tin oxide, zinc oxide, titanium oxide, and the like to a conductive treatment, and a conductive filler made of a metal such as the flake and the whisker. The amount of the conductive agent to be added is 0.01 to 50 with respect to 100 weight of a main material such as rubber or urethane.
In particular, the DBP oil absorption is preferably from 30 to 125 m from the viewpoint of controlling the resistance stably in the medium resistance region.
It is preferable to add about 1 to 100 parts by weight of 1/100 g (medium structure) carbon black.

【0018】その他の導電剤としては、例えばテトラシ
アノエチレン及び/又はその誘導体,テトラシアノキノ
ジメタン及び/又はその誘導体,ベンゾキノン及び/又
はその誘導体,クロルアニル及び/又はその誘導体,ア
ントラキノン及び/又はその誘導体アントラセン及び/
又はその誘導体,ジクロロジシアノベンゾキノン及び/
又はその誘導体,フェロセン及び/又はその誘導体,フ
タロシアニン及び/又はその誘導体,テトラチアフルバ
レン及び/又はその誘導体等の電荷移動物質、過塩素酸
リチウム,過塩素酸ナトリウム,過塩素酸カルシウム等
の無機イオン物質、ラウリルトリメチルアンモニウムク
ロライド,ステアリルトリメチルアンモニウムクロライ
ド,オクタデシル・トリメチルアンモニウムクロライ
ド,変性脂肪酸,ジメトル・エチルアンモニウムエトサ
ルフェート等の陽イオン性界面活性剤、ラウリルベタイ
ン,ステアリルベタイン,ジメチル・アルキルラウリル
ベタイン等の両性イオン界面活性剤、過塩素酸テトラエ
チルアンモニウム,過塩素酸テトラブチルアンモニウ
ム,ほうふっ化テトラブチルアンモニウム等の4級アン
モニウム塩などの有機イオン物質からなる導電剤、親水
性のポリエーテルやポリエステルなどの帯電防止剤など
が挙げられ、これら導電剤の添加量はゴム又はウレタン
等の主材料100重量部に対して0.001〜5重量部
であることが好ましい。
Other conductive agents include, for example, tetracyanoethylene and / or its derivative, tetracyanoquinodimethane and / or its derivative, benzoquinone and / or its derivative, chloranil and / or its derivative, anthraquinone and / or its derivative Derivatives anthracene and / or
Or a derivative thereof, dichlorodicyanobenzoquinone and / or
Or a charge transfer substance such as a derivative thereof, ferrocene and / or a derivative thereof, phthalocyanine and / or a derivative thereof, tetrathiafulvalene and / or a derivative thereof, and an inorganic ion such as lithium perchlorate, sodium perchlorate, and calcium perchlorate. Substances, cationic surfactants such as lauryltrimethylammonium chloride, stearyltrimethylammonium chloride, octadecyltrimethylammonium chloride, modified fatty acids, dimethyl-ethylammonium ethosulfate, amphoteric such as laurylbetaine, stearylbetaine, dimethylalkyllaurylbetaine Organic surfactants such as ionic surfactants and quaternary ammonium salts such as tetraethylammonium perchlorate, tetrabutylammonium perchlorate and tetrabutylammonium borofluoride And a conductive agent composed of an ON material, an antistatic agent such as a hydrophilic polyether or polyester, and the amount of the conductive agent to be added is 0.001 to 5 parts by weight based on 100 parts by weight of a main material such as rubber or urethane. Part.

【0019】これら導電剤の添加による抵抗値の調整
は、特に制限されるものではないが、電子写真プロセス
に用いられる現像部材や転写部材とする場合には、通
常、部材の電気抵抗が1×104〜1×1012Ωcm程
度の中抵抗領域となるように調整することができる。な
お、上記導電剤は、1種類を単独で用いても2種以上を
混合して用いてもよい。
The adjustment of the resistance value by the addition of these conductive agents is not particularly limited. However, when a developing member or a transfer member used in an electrophotographic process is used, the electric resistance of the member is usually 1 ×. It can be adjusted so as to have a medium resistance region of about 10 4 to 1 × 10 12 Ωcm. The conductive agent may be used alone or in combination of two or more.

【0020】本発明の導電性部材は、上述のように、温
度15℃,相対湿度10%の条件下における測定電圧1
000Vでの電気抵抗が、温度32.5℃,相対湿度8
5%の条件下における測定電圧1000Vでの電気抵抗
の10倍以下で、かつ電力10mWで連続通電した後の
温度15℃,相対湿度10%の条件下における測定電圧
1000Vでの電気抵抗が、連続通電前の同条件下にお
ける測定電圧1000Vでの電気抵抗の3倍以下となる
ようにしたものである。なお、温度15℃,相対湿度1
0%の条件下における測定電圧1000Vでの電気抵抗
は、特に制限されるものではないが、上記温度32.5
℃,相対湿度85%の条件下における測定電圧1000
Vでの電気抵抗の1/100以上,10倍以下であるこ
とが好ましく、また上記連続通電による通電時間は、特
に制限されないが通常150時間程度とすることができ
る。このような特性は、上記の導電性材料を用いて所望
の形状に成形した部材を熱処理することにより得ること
ができる。
As described above, the conductive member of the present invention has a measurement voltage of 1 at a temperature of 15 ° C. and a relative humidity of 10%.
The electrical resistance at 000 V is 32.5 ° C and the relative humidity is 8
The electric resistance at a measurement voltage of 1000 V under a condition of a temperature of 15 ° C. and a relative humidity of 10% after continuous energization at a power of 10 mW is 10 times or less the electric resistance at a measurement voltage of 1000 V under a condition of 5%. The electric resistance at the measurement voltage of 1000 V under the same conditions before energization is three times or less. The temperature was 15 ° C and the relative humidity was 1
The electrical resistance at a measurement voltage of 1000 V under the condition of 0% is not particularly limited.
Measured voltage 1000 under the conditions of ° C and 85% relative humidity
It is preferable that the electric resistance at V is 1/100 or more and 10 times or less, and the energization time by the continuous energization is not particularly limited, but can be usually about 150 hours. Such characteristics can be obtained by heat-treating a member formed into a desired shape using the above-described conductive material.

【0021】この熱処理を行う場合の条件は、上記特性
が得られる条件であればよく、導電性部材の材料や形態
(形状や大きさ等)などに応じて適宜設定され、特に制
限されるものではないが、通常は80〜200℃、特に
90〜140℃の温度で1分〜72時間、特に15分〜
8時間処理する条件が好ましい。この場合、熱処理温度
が80℃未満であると熱処理による効果が得られない場
合があり、一方200℃を超えると、ローラ表面がべと
ついて感光体等を汚染するものとなってしまう場合があ
る。なお、加熱手段としては、乾熱オーブン、スチー
ム、温水浴等の公知の手段を用いることができる。ま
た、この熱処理は、導電性部材を金型より取り出した状
態で、研磨・切削加工後に行われる。
The conditions for performing this heat treatment may be conditions under which the above characteristics can be obtained, and are appropriately set according to the material and form (shape, size, etc.) of the conductive member, and are particularly limited. However, it is usually at a temperature of 80 to 200 ° C., particularly 90 to 140 ° C., for 1 minute to 72 hours, particularly 15 minutes to
Conditions for treating for 8 hours are preferred. In this case, if the heat treatment temperature is lower than 80 ° C., the effect of the heat treatment may not be obtained. On the other hand, if the heat treatment temperature is higher than 200 ° C., the surface of the roller may become sticky and contaminate the photoreceptor and the like. . In addition, as a heating means, a known means such as a dry heat oven, steam, or a hot water bath can be used. This heat treatment is performed after polishing and cutting in a state where the conductive member is removed from the mold.

【0022】この熱処理工程では、成形工程において成
形材料の金型へ注入・射出或いは押し出しを行った時の
温度又は研磨・切削加工時の応力の非一様性によって発
生する電気抵抗の位置ばらつきと応力を低減することが
でき、具体的には、ローラ状の導電性部材の場合、電圧
1000V,温度15℃,相対湿度10%の条件で、1
cm幅の銅板を用いて長手方向で等間隔に6点、周方向
で90度毎に4方向の合計24点における電気抵抗を評
価したとき、電気抵抗の最低値と最高値との差を10以
内とすることができる。
In this heat treatment step, the position variation of the electric resistance caused by the non-uniformity of the temperature at the time of injecting / injecting or extruding the molding material into the mold in the molding step or the stress at the time of the polishing / cutting processing, The stress can be reduced. Specifically, in the case of a roller-shaped conductive member, a voltage of 1000 V, a temperature of 15 ° C., and a relative humidity of 10% are used.
When the electrical resistance was evaluated at a total of 24 points in 6 directions at equal intervals in the longitudinal direction and at every 90 degrees in the circumferential direction using a copper plate having a width of 10 cm, a difference between the minimum value and the maximum value of the electrical resistance was 10%. Within.

【0023】また、後述する実施例でも明らかなよう
に、電気抵抗の電圧依存性も改善することができ、具体
的には、温度25℃,相対湿度55%の環境で、電圧5
00Vで測定した電気抵抗が1000Vで測定した電気
抵抗の2.5倍以下となるようにすることができる。
Further, as will be apparent from the embodiment described later, the voltage dependence of the electric resistance can be improved. Specifically, in an environment of a temperature of 25 ° C. and a relative humidity of 55%, a voltage of 5% is used.
The electrical resistance measured at 00V can be 2.5 times or less the electrical resistance measured at 1000V.

【0024】なお、この熱処理は、加熱により分子運動
を活性化し、カーボンブラック等の導電性フィラーを再
配置・安定化する観点から上述したカーボン等の導電性
フィラーを含むゴム又はウレタン等の高分子材料からな
る導電性部材に対して行うことが好ましい。更に、独立
気泡を含むゴム又はウレタンの発泡体では、気泡の膨張
・収縮による応力緩和が好影響を与えることとなる。
In this heat treatment, from the viewpoint of activating molecular motion by heating and rearranging and stabilizing the conductive filler such as carbon black, the above-described rubber or urethane or other polymer containing the conductive filler such as carbon is used. It is preferable to perform the process on a conductive member made of a material. Furthermore, in the case of a rubber or urethane foam containing closed cells, stress relaxation due to expansion and contraction of the cells has a favorable effect.

【0025】本発明の導電性部材の形態は、用途,目的
等に応じて適宜選定されるものであり、特に制限される
ものではないが、電子写真プロセス等による画像形成装
置の現像機構で使用される現像部材や転写機構で使用さ
れる転写部材とする場合には、通常、芯金を中心に配置
したローラ形状とすることが好ましい。また、本発明の
導電性部材は、このような画像形成装置の現像機構で使
用される現像部材や転写機構で使用される転写部材とし
て好適に使用されるものである。この場合、画像形成装
置としては、例えば、図1に示したように、帯電ローラ
で一様に帯電させた感光体(画像形成体)表面に光学系
からレーザービームを露光して静電潜像を形成し、この
感光体表面に現像部材(図では、ローラ状)を備えた現
像機構部から現像剤を供給して、上記静電潜像を可視画
像化し、更にこの可視画像を転写ローラ(図では、ロー
ラ状)を備えた転写機構部で普通紙等の記録媒体に転写
する画像形成装置を例示することができる。そして、本
発明の導電性部材は、このような画像形成装置におい
て、現像部材の表面に現像剤を担持して該現像剤の薄層
を形成し、この状態で現像部材を画像形成体に接触又は
近接させて画像形成体表面に上記現像剤を供給すること
により、該画像形成体表面に可視画像を形成する現像機
構部の現像部材や、転写部材に近接又は接触させて記録
媒体を帯電させ、画像形成体表面に形成された可視画像
を前記記録媒体に転写する転写機構部の転写部材として
好適に使用されるものである。なお、図1では、画像形
成体として表面に静電潜像を保持する感光体を用いた例
を示したが、画像形成体は感光体等の潜像保持体に限定
されるものではなく、表面に現像剤を供給して直接現像
剤による画像を形成するものであってもよい。
The form of the conductive member of the present invention is appropriately selected depending on the use and purpose, and is not particularly limited, but is used in a developing mechanism of an image forming apparatus by an electrophotographic process or the like. When the developing member is used as a developing member or a transfer member used in a transfer mechanism, it is usually preferable to use a roller shape having a cored bar as a center. Further, the conductive member of the present invention is suitably used as a developing member used in a developing mechanism of such an image forming apparatus or a transfer member used in a transfer mechanism. In this case, as shown in FIG. 1, for example, as shown in FIG. 1, the surface of a photosensitive member (image forming member) uniformly charged by a charging roller is exposed to a laser beam from an optical system to form an electrostatic latent image. Is formed, a developer is supplied from a developing mechanism provided with a developing member (in the figure, a roller shape) on the surface of the photoreceptor, the electrostatic latent image is visualized, and the visible image is further transferred to a transfer roller ( In the drawing, an image forming apparatus that transfers to a recording medium such as plain paper by a transfer mechanism unit having a roller shape can be exemplified. In such an image forming apparatus, the conductive member of the present invention supports the developer on the surface of the developing member to form a thin layer of the developer, and in this state, the developing member contacts the image forming body. Alternatively, by supplying the developer to the surface of the image forming body in close proximity to the developing member of the developing mechanism for forming a visible image on the surface of the image forming body, or by bringing the recording medium close to or in contact with the transfer member, the recording medium is charged. It is suitably used as a transfer member of a transfer mechanism for transferring a visible image formed on the surface of an image forming body to the recording medium. Although FIG. 1 shows an example in which a photoconductor holding an electrostatic latent image on the surface is used as an image forming body, the image forming body is not limited to a latent image holding body such as a photoconductor, A developer may be supplied to the surface to directly form an image with the developer.

【0026】本発明の帯電部材を用いた画像形成装置の
現像機構及び転写機構は、通電時の抵抗上昇がほとんど
なく長寿命であり、また従来から用いられているイオン
導電剤によって導電性を付与した部材を用いた現像機構
及び転写機構と比較して高温高湿時と低温低湿時とで電
気抵抗の変動が少なく、電源の容量を小さくすることが
できるものである。
The developing mechanism and the transfer mechanism of the image forming apparatus using the charging member of the present invention have a long life with almost no increase in resistance when energized, and have been given conductivity by a conventionally used ionic conductive agent. Compared with the developing mechanism and the transfer mechanism using the above-described members, the change in electric resistance between high temperature and high humidity and low temperature and low humidity is small, and the capacity of the power supply can be reduced.

【0027】[0027]

【実施例】以下、実施例,比較例を示し、本発明をより
具体的に説明するが、本発明は下記実施例に限定される
ものではない。[実施例1]グリセリンにプロピレンオ
キサイドとエチレンオキサイドをランダムに付加し、そ
のエチレンオキサイド・ユニットの含有率が12%、分
子量3500であるポリエーテルポリオール100重量
部、1,4−ブタンジオール6.05重量部、トリレン
ジイソシアネート22重量部、反応性シリコーン系界面
活性剤4重量部、ジブチルチンジラウレート0.01重
量部、窒素吸着量により測定した比表面積60m2/g
でDBP吸油量63ml/100gのカーボンブラック
6重量部をミキサーで混合し、その混合物を直径6mm
の金属製シャフトを中心に配設したモールドに注型し、
100℃で5時間キュアーしてから研磨し、直径16.
7mmで長さ215mmのウレタンフォーム転写ローラ
を作成した。次いで、この転写ローラを100℃で2時
間乾熱オーブンで熱処理した。
The present invention will be described in more detail with reference to examples and comparative examples, but the present invention is not limited to the following examples. Example 1 Propylene oxide and ethylene oxide were randomly added to glycerin, and the content of the ethylene oxide unit was 12%, the polyether polyol having a molecular weight of 3500 was 100 parts by weight, and 1,4-butanediol 6.05. Parts by weight, 22 parts by weight of tolylene diisocyanate, 4 parts by weight of a reactive silicone surfactant, 0.01 parts by weight of dibutyltin dilaurate, and a specific surface area of 60 m 2 / g measured by nitrogen adsorption.
, 6 parts by weight of carbon black having a DBP oil absorption of 63 ml / 100 g were mixed by a mixer, and the mixture was 6 mm in diameter.
Cast into a mold arranged around a metal shaft of
After curing at 100 ° C. for 5 hours, polishing is performed.
A urethane foam transfer roller having a length of 7 mm and a length of 215 mm was prepared. Next, this transfer roller was heat-treated at 100 ° C. for 2 hours in a dry heat oven.

【0028】得られたローラを厚さ2mmの銅板上に載
せ、ローラ両端部に各々500gの荷重をかけて上記銅
板上に圧接しながら、1000Vの電圧を印加して芯金
と銅板との間の電気抵抗を測定した。その結果、25℃
/55%(温度/湿度、以下同様)環境下での電気抵抗
が6.6×107Ω、32.5℃/85%環境下での電
気抵抗が1.5×108Ω、15℃/10%環境下での
電気抵抗が2.0×107Ωであった。
The obtained roller was placed on a copper plate having a thickness of 2 mm, and a load of 500 g was applied to both ends of the roller while pressing against the copper plate while applying a voltage of 1000 V to apply a voltage of 1000 V between the core metal and the copper plate. Was measured for electrical resistance. As a result, 25 ° C
/ 55% (temperature / humidity, the same applies hereinafter), the electric resistance in an environment of 6.6 × 10 7 Ω, 32.5 ° C./85% in an environment of 1.5 × 10 8 Ω, 15 ° C. The electric resistance under a / 10% environment was 2.0 × 10 7 Ω.

【0029】このローラを転写ローラとして図1に示し
た画像形成装置に組み込み、15℃/10%でグレース
ケール、黒ベタ、白ベタ画像を印刷したところ、いずれ
も良好な画像が得られた。
This roller was incorporated in the image forming apparatus shown in FIG. 1 as a transfer roller, and when a gray scale, a solid black, and a solid white image were printed at 15 ° C./10%, good images were obtained.

【0030】[実施例2]研磨後の加熱処理温度を12
0℃としたこと以外は、実施例1と同様にして転写ロー
ラを作成した。得られたローラにつき実施例1と同様に
電気抵抗を測定したところ、25℃/55%環境下での
電気抵抗が1.3×108Ω、32.5℃/85%環境
下での電気抵抗が2.3×108Ω、15℃/10%環
境下での電気抵抗が4.2×107Ωであった。
Example 2 The temperature of the heat treatment after polishing was 12
A transfer roller was prepared in the same manner as in Example 1 except that the temperature was set to 0 ° C. When the electric resistance of the obtained roller was measured in the same manner as in Example 1, the electric resistance under a 25 ° C./55% environment was 1.3 × 10 8 Ω, and the electric resistance under a 32.5 ° C./85% environment. The resistance was 2.3 × 10 8 Ω, and the electric resistance under a 15 ° C./10% environment was 4.2 × 10 7 Ω.

【0031】このローラを転写ローラとして図1に示し
た画像形成装置に組み込み、15℃/10%でグレース
ケール、黒ベタ、白ベタ画像を印刷したところ、いずれ
も良好な画像が得られた。
This roller was incorporated in the image forming apparatus shown in FIG. 1 as a transfer roller, and when a gray scale, a solid black, and a solid white image were printed at 15 ° C./10%, good images were obtained in all cases.

【0032】[比較例1]カーボンブラックの配合量を
2.5重量部とし、研磨後の加熱処理を行わなかったこ
と以外は実施例1と同様に転写ローラを作成した。得ら
れたローラにつき実施例1と同様に電気抵抗を測定した
ところ、25℃/55%環境下での電気抵抗が8.5×
107Ω、32.5℃/85%環境下での電気抵抗が
8.0×107Ω、15℃/10%環境下での電気抵抗
が5.7×107Ωであった。
Comparative Example 1 A transfer roller was prepared in the same manner as in Example 1 except that the blending amount of carbon black was 2.5 parts by weight and the heat treatment after polishing was not performed. When the electric resistance of the obtained roller was measured in the same manner as in Example 1, the electric resistance under a 25 ° C./55% environment was 8.5 ×.
The electric resistance in a 10 7 Ω, 32.5 ° C./85% environment was 8.0 × 10 7 Ω, and the electric resistance in a 15 ° C./10% environment was 5.7 × 10 7 Ω.

【0033】このローラを転写ローラとして図1に示し
た画像形成装置に組み込み、15℃/10%でグレース
ケール、黒ベタ、白ベタ画像を印刷したところ、黒ベタ
画像の両端部で転写不良が発生した。
This roller was incorporated into the image forming apparatus shown in FIG. 1 as a transfer roller, and when a gray scale, black solid, or white solid image was printed at 15 ° C./10%, a transfer failure occurred at both ends of the black solid image. Occurred.

【0034】[比較例2]研磨後の加熱処理温度を22
0℃としたこと以外は、実施例1と同様にして転写ロー
ラを作成した。この転写ローラは表面がべとついて感光
体を汚染するものであった。
Comparative Example 2 The heat treatment temperature after polishing was 22
A transfer roller was prepared in the same manner as in Example 1 except that the temperature was set to 0 ° C. The transfer roller had a sticky surface and contaminated the photoreceptor.

【0035】転写ローラの評価上記実施例1,2及び比
較例1の転写ローラにつき、以下の項目による評価を行
った。結果を表1に示す。(1)連続通電図1の画像形
成装置の感光体をアルミ素管に変更し、温度/湿度が2
5℃/55%の環境下で、通電電力10mWで150時
間連続して回転させた後、温度/湿度が15℃/10%
の環境下に48時間放置し、同環境下で厚さ2mmの銅
板上に載せ、ローラ両端部を各々500gの力で圧接し
ながら1000Vの電圧を印加して芯金と銅板との間の
電気抵抗を測定し、この電気抵抗値を連続通電前の同環
境下での電気抵抗値で割り算した値で評価した。(2)
電気抵抗の環境依存性上述した各例の32.5℃/85
%での電気抵抗値を15℃/10%での電気抵抗値で割
り算した値で評価した。(3)電気抵抗の位置ばらつき
電圧1000V、温度15℃、相対湿度10%の条件
で、1cm幅の銅板で長手方向に等間隔に6点、周方向
で90度毎に4方向の24点で電気抵抗を測定し、最大
抵抗値と最小抵抗値との差で評価した。(4)電気抵抗
の電圧依存性温度25℃、相対湿度55%の環境下で、
電圧500Vで測定した電気抵抗を同環境下、電圧10
00Vで測定した電気抵抗で割り算した値で評価した。
Evaluation of Transfer Roller The transfer rollers of Examples 1 and 2 and Comparative Example 1 were evaluated by the following items. Table 1 shows the results. (1) Continuous energization The photosensitive member of the image forming apparatus shown in FIG.
After rotating continuously for 150 hours at an electric power of 10 mW in an environment of 5 ° C./55%, the temperature / humidity becomes 15 ° C./10%
Under the same environment for 48 hours, placed on a copper plate having a thickness of 2 mm in the same environment, and applying a voltage of 1000 V while pressing both ends of the roller with a force of 500 g each to apply electricity between the metal core and the copper plate. The resistance was measured and evaluated by a value obtained by dividing the electric resistance by the electric resistance under the same environment before continuous energization. (2)
Environment dependence of electric resistance 32.5 ° C./85 in each of the above examples
% Was divided by the electric resistance at 15 ° C./10%. (3) Positional variation of electrical resistance Under the conditions of a voltage of 1000 V, a temperature of 15 ° C., and a relative humidity of 10%, a copper plate having a width of 1 cm is provided at six points at equal intervals in the longitudinal direction and at 24 points in four directions at every 90 degrees in the circumferential direction. The electric resistance was measured and evaluated by the difference between the maximum resistance value and the minimum resistance value. (4) Voltage dependence of electric resistance Under an environment of a temperature of 25 ° C. and a relative humidity of 55%,
Under the same environment, the electric resistance measured at a voltage of 500 V was changed to a voltage of 10
The evaluation was made by dividing the value by the electric resistance measured at 00V.

【0036】[0036]

【表1】 [Table 1]

【0037】[0037]

【発明の効果】以上説明したように、本発明によれば、
電気抵抗の位置ばらつきが小さく、かつ電気抵抗の印加
電圧依存性が少なく、また低温低湿時と高温高湿時とで
電気抵抗の変動幅が小さく、しかも連続通電した後であ
っても電気抵抗の変動幅が小さい導電性部材が得られ
る。また、この導電性部材を画像形成装置の現像,転写
等のプロセスに利用することにより、良好な画像を長期
に亘って確実に得ることができる。
As described above, according to the present invention,
The variation in the position of the electric resistance is small, the dependence of the electric resistance on the applied voltage is small, and the fluctuation range of the electric resistance between low temperature and low humidity and high temperature and high humidity is small. A conductive member having a small fluctuation range can be obtained. In addition, by using this conductive member for processes such as development and transfer of the image forming apparatus, a good image can be reliably obtained over a long period of time.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の導電性部材が装着される画像形成装置
の一例を示す模式図である。
FIG. 1 is a schematic diagram illustrating an example of an image forming apparatus to which a conductive member of the present invention is mounted.

フロントページの続き (51)Int.Cl.6 識別記号 FI F16C 13/00 F16C 13/00 A G03G 15/08 501 G03G 15/08 501D H01B 1/24 H01B 1/24 Z // B29K 75:00 Continued on the front page (51) Int.Cl. 6 Identification code FI F16C 13/00 F16C 13/00 A G03G 15/08 501 G03G 15/08 501D H01B 1/24 H01B 1/24 Z // B29K 75:00

Claims (12)

【特許請求の範囲】[Claims] 【請求項1】 温度15℃,相対湿度10%の条件下に
おける測定電圧1000Vでの電気抵抗が、温度32.
5℃,相対湿度85%の条件下における測定電圧100
0Vでの電気抵抗の10倍以下であり、かつ電力10m
Wで連続通電した後の温度15℃,相対湿度10%の条
件下における測定電圧1000Vでの電気抵抗が、連続
通電前の同条件下における測定電圧1000Vでの電気
抵抗の3倍以下であることを特徴とする導電性部材。
An electric resistance at a measurement voltage of 1000 V under a condition of a temperature of 15 ° C. and a relative humidity of 10% is a temperature of 32.
Measurement voltage 100 under conditions of 5 ° C and 85% relative humidity
It is 10 times or less the electric resistance at 0 V and the power is 10 m
The electric resistance at a measurement voltage of 1000 V under a condition of a temperature of 15 ° C. and a relative humidity of 10% after continuous energization at W is not more than three times the electric resistance at a measurement voltage of 1000 V under the same conditions before the continuous energization. A conductive member characterized by the above-mentioned.
【請求項2】 ウレタンフォームにより形成されたもの
である請求項1記載の導電性部材。
2. The conductive member according to claim 1, wherein the conductive member is formed of urethane foam.
【請求項3】 導電性フィラーを添加した材料により形
成されたものである請求項1又は2記載の導電性部材。
3. The conductive member according to claim 1, wherein the conductive member is formed of a material to which a conductive filler is added.
【請求項4】 導電性フィラーがカーボンブラックであ
る請求項3記載の導電性部材。
4. The conductive member according to claim 3, wherein the conductive filler is carbon black.
【請求項5】 電子写真プロセスなどに用いられる弾性
ローラである請求項1〜4のいずれか1項に記載の導電
性部材。
5. The conductive member according to claim 1, which is an elastic roller used in an electrophotographic process or the like.
【請求項6】 所望形状の導電性部材を成形した後、こ
れを熱処理することを特徴とする導電性部材の製造方
法。
6. A method for manufacturing a conductive member, comprising forming a conductive member having a desired shape, and heat-treating the formed conductive member.
【請求項7】 熱処理の条件が、温度80〜200℃,
処理時間1分〜72時間である請求項6記載の導電性部
材の製造方法。
7. The heat treatment is performed at a temperature of 80 to 200 ° C.
The method for producing a conductive member according to claim 6, wherein the treatment time is 1 minute to 72 hours.
【請求項8】 導電性部材が、ウレタンフォームで形成
されたものである請求項6又は7記載の導電性部材の製
造方法。
8. The method for producing a conductive member according to claim 6, wherein the conductive member is formed of urethane foam.
【請求項9】 導電性部材が、導電性フィラーを添加し
た材料により形成されたものである請求項6〜8のいず
れか1項に記載の導電性部材の製造方法。
9. The method for producing a conductive member according to claim 6, wherein the conductive member is formed of a material to which a conductive filler is added.
【請求項10】 導電性フィラーがカーボンブラックで
ある請求項9記載の導電性部材の製造方法。
10. The method for producing a conductive member according to claim 9, wherein the conductive filler is carbon black.
【請求項11】 現像部材の表面に現像剤を担持して該
現像剤の薄層を形成し、この状態で現像部材を画像形成
体に接触又は近接させて、画像形成体表面に上記現像剤
を供給することにより、該画像形成体表面に可視画像を
形成する現像機構を具備した画像形成装置において、前
記現像部材が請求項1〜5のいずれか1項に記載の導電
性部材であることを特徴とする画像形成装置。
11. A developer is carried on the surface of a developing member to form a thin layer of the developer. In this state, the developing member is brought into contact with or close to the image forming body, and the developer is applied to the surface of the image forming body. The developing member is a conductive member according to any one of claims 1 to 5 in an image forming apparatus provided with a developing mechanism for forming a visible image on the surface of the image forming body by supplying the developing member. An image forming apparatus comprising:
【請求項12】 転写部材に近接又は接触させて記録媒
体を帯電させ、画像形成体表面に形成された可視画像を
前記記録媒体に転写する転写機構を具備した画像形成装
置において、前記転写部材が請求項1〜5のいずれか1
項に記載の導電性部材であることを特徴とする画像形成
装置。
12. An image forming apparatus comprising: a transfer mechanism for charging a recording medium in proximity to or in contact with a transfer member and transferring a visible image formed on the surface of an image forming body to the recording medium; Any one of claims 1 to 5
An image forming apparatus comprising the conductive member according to any one of the above items.
JP17521397A 1996-06-17 1997-06-16 Conductive member and its manufacture, and image forming device using it Pending JPH10115988A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17521397A JPH10115988A (en) 1996-06-17 1997-06-16 Conductive member and its manufacture, and image forming device using it

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP15577096 1996-06-17
JP8-155770 1996-06-17
JP17521397A JPH10115988A (en) 1996-06-17 1997-06-16 Conductive member and its manufacture, and image forming device using it

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2001245287A Division JP3608616B2 (en) 1996-06-17 2001-08-13 Method for manufacturing conductive member

Publications (1)

Publication Number Publication Date
JPH10115988A true JPH10115988A (en) 1998-05-06

Family

ID=26483692

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17521397A Pending JPH10115988A (en) 1996-06-17 1997-06-16 Conductive member and its manufacture, and image forming device using it

Country Status (1)

Country Link
JP (1) JPH10115988A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002311682A (en) * 2001-04-11 2002-10-23 Kanegafuchi Chem Ind Co Ltd Semiconductive roller for electrophotographic device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002311682A (en) * 2001-04-11 2002-10-23 Kanegafuchi Chem Ind Co Ltd Semiconductive roller for electrophotographic device

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