JPH0977673A - Production of aqueous calcium solution - Google Patents
Production of aqueous calcium solutionInfo
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- JPH0977673A JPH0977673A JP7257214A JP25721495A JPH0977673A JP H0977673 A JPH0977673 A JP H0977673A JP 7257214 A JP7257214 A JP 7257214A JP 25721495 A JP25721495 A JP 25721495A JP H0977673 A JPH0977673 A JP H0977673A
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- Prior art keywords
- calcium
- acid
- aqueous solution
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
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- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
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Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、カルシウム水溶液
の製造方法に関する。さらに詳しくは炭酸カルシウム、
炭酸水素カルシウム、貝類の殻、サンゴ等のカルシウム
源を有機酸で溶解するに際し、ろ過助剤を添加すること
を特徴とするカルシウム水溶液の製造方法に関する。TECHNICAL FIELD The present invention relates to a method for producing an aqueous calcium solution. More specifically, calcium carbonate,
The present invention relates to a method for producing an aqueous calcium solution, which comprises adding a filter aid when a calcium source such as calcium hydrogen carbonate, shellfish and coral is dissolved with an organic acid.
【０００２】[0002]
【従来の技術】近年、カルシウムは、健康増強、カルシ
ウム補給、カルシウム欠損の改善などを目的として食
品、健康食品、飲料、菓子類、医薬品などに広く利用さ
れている。そのカルシウム源としては炭酸カルシウム、
炭酸水素カルシウム、貝類の殻、サンゴ等が用いられて
おり、カルシウムを液状で摂取するためには、種々のカ
ルシウム源を有機酸によって溶解して用いられている。2. Description of the Related Art In recent years, calcium has been widely used in foods, health foods, beverages, confectionery, pharmaceuticals, etc. for the purpose of enhancing health, supplementing calcium, improving calcium deficiency and the like. As its calcium source, calcium carbonate,
Calcium hydrogen carbonate, shellfish, coral and the like are used, and in order to ingest calcium in a liquid state, various calcium sources are dissolved in organic acids and used.
【０００３】[0003]
【発明が解決しようとする課題】炭酸カルシウム、炭酸
水素カルシウム、貝類の殻、サンゴ等のカルシウム源を
有機酸で溶解する場合、大量の炭酸ガスが発生し、それ
によって大量の気泡が容器内に充満するため、カルシウ
ム源あるいは有機酸の添加量を調節しながら徐々に溶解
せざるをえず、カルシウム源が完全に溶解するまでに長
時間を要するという欠点があった。従って、気泡を大量
に発生させずカルシウム源の溶解時間を短縮する方法が
望まれていた。When a calcium source such as calcium carbonate, calcium hydrogen carbonate, shellfish and coral is dissolved with an organic acid, a large amount of carbon dioxide gas is generated, which causes a large amount of bubbles in the container. Since it is full, it has to be gradually dissolved while adjusting the amount of the calcium source or the organic acid added, and there is a drawback that it takes a long time until the calcium source is completely dissolved. Therefore, a method for shortening the dissolution time of the calcium source without generating a large amount of bubbles has been desired.
【０００４】[0004]
【課題を解決するための手段】本発明は、上記の欠点、
課題を解決するためのものである。即ち、本発明は、炭
酸カルシウム、炭酸水素カルシウム、貝類の殻、サンゴ
等のカルシウム源を有機酸に溶解するに際し、ろ過助剤
を添加することにより、気泡を大量に発生させずカルシ
ウム源の溶解時間を大幅に短縮する方法を提供する。The present invention is based on the above-mentioned drawbacks,
It is for solving problems. That is, the present invention, when dissolving a calcium source such as calcium carbonate, calcium hydrogen carbonate, shellfish, coral, etc. in an organic acid, by adding a filter aid, the calcium source is dissolved without generating a large amount of bubbles. Provides a way to save time significantly.
【０００５】本発明に使用されるろ過助剤としてはセル
ロース、ケイソウ土、パーライト、活性炭、粉末木炭が
用いられ、その中でもセルロース、ケイソウ土が好まし
く、平均長さ４０〜３００μmのセルロース、平均粒径
２〜１２μmのケイソウ土が特に好ましい。例えば、セ
ルロースとしてはファイブラルセルＢＨ−１００（米国
セライト社製）、ダイアセル−１５０（セルロース−フ
ルストッフ−ファブリック社製）、ソルカ−フロックＢ
Ｗ−４０（ブラウン社製）が、ケイソウ土としてはセラ
イトＳＳＣ、Ｃ−５１２、Ｃ−５０５（ジョンズ−マン
ビレ−インターナショナル−コーポレーション社製）、
ダイカライト スーパーエイド（グレフコ社製）が挙げ
られる。ろ過助剤の添加量はカルシウム源に対し５〜５
０W/W％が好ましく、特に７．５〜３０W/W％が好まし
い。これらのろ過助剤を１種又は２種以上使用するが、
１種又は２種が好ましい。Cellulose, diatomaceous earth, perlite, activated carbon, and powdered charcoal are used as the filter aid used in the present invention. Among them, cellulose and diatomaceous earth are preferable, and cellulose having an average length of 40 to 300 μm and an average particle diameter are used. Particularly preferred is diatomaceous earth of 2 to 12 μm. For example, as the cellulose, Fibrarcell BH-100 (manufactured by Celite, USA), Diacel-150 (manufactured by Cellulose-Full Stuff-Fabric), Solker-Flock B
W-40 (manufactured by Brown Co.) is used as diatomaceous earth as Celite SSC, C-512, C-505 (manufactured by Johns-Mambire International-Corporation),
Daika Light Super Aid (made by GLEFUCO) is mentioned. The amount of the filter aid added is 5 to 5 with respect to the calcium source.
0 W / W% is preferable, and 7.5 to 30 W / W% is particularly preferable. One or more of these filter aids are used,
1 type or 2 types are preferable.
【０００６】本発明に用いられるカルシウム源である炭
酸カルシウム、炭酸水素カルシウムは特に制限はなく市
販のものでよく、貝類の殻は例えばボレイ末であり、サ
ンゴは予め粉砕し６０〜１００メッシュの篩で篩過した
ものが好ましい。The calcium source used in the present invention, calcium carbonate and calcium hydrogen carbonate, are not particularly limited and may be commercially available. The shells of shellfish are, for example, boley powder, and corals are crushed in advance and sieved to 60-100 mesh. It is preferably sieved with.
【０００７】本発明に用いられる有機酸は、乳酸、酢
酸、氷酢酸、リンゴ酸、クエン酸、マレイン酸又はフマ
ル酸を１種又は２以上使用することが好ましい。有機酸
の添加量はカルシウム源を溶解させるために必要な量で
あればよい。The organic acid used in the present invention is preferably one or more of lactic acid, acetic acid, glacial acetic acid, malic acid, citric acid, maleic acid or fumaric acid. The amount of the organic acid added may be any amount required to dissolve the calcium source.
【０００８】処理温度は、特に限定されないが、高温で
あるほど溶解時間が短縮されるため、溶解時間を考慮し
た場合５０〜９０℃が好ましい。カルシウム源又は有機
酸の添加速度は、タンク上面から気泡が溢れ出ないよう
に調節する。The treatment temperature is not particularly limited, but the higher the temperature is, the shorter the dissolution time is. Therefore, in consideration of the dissolution time, 50 to 90 ° C. is preferable. The rate of addition of the calcium source or the organic acid is adjusted so that air bubbles do not overflow from the upper surface of the tank.
【０００９】[0009]
【発明の実施の形態】本発明のカルシウム水溶液は、例
えば、炭酸カルシウム、炭酸水素カルシウム、貝類の
殻、サンゴ等のカルシウム源及びろ過助剤を精製水に加
え、攪拌しながら炭酸ガスの気泡が容器から溢れ出さな
い速度で乳酸、酢酸、氷酢酸、リンゴ酸、クエン酸、マ
レイン酸、フマル酸等の有機酸の水溶液を添加し、カル
シウム源が完全に溶解するまで攪拌し、次いでろ過する
ことにより製造する。BEST MODE FOR CARRYING OUT THE INVENTION The calcium aqueous solution of the present invention comprises, for example, calcium sources such as calcium carbonate, calcium hydrogen carbonate, shellfish and coral, and a filter aid added to purified water. Add an aqueous solution of an organic acid such as lactic acid, acetic acid, glacial acetic acid, malic acid, citric acid, maleic acid, fumaric acid, etc. at a speed that does not overflow the container, stir until the calcium source is completely dissolved, and then filter. Manufactured by.
【００１０】こうして得られたカルシウム水溶液は、慣
用の添加剤、賦形剤、防腐剤等を必要に応じて適宜使用
することにより食品、健康食品、飲料、医薬品などに調
製することができる。The thus obtained aqueous calcium solution can be prepared into foods, health foods, beverages, pharmaceuticals and the like by appropriately using conventional additives, excipients, preservatives and the like as needed.
【００１１】[0011]
【実施例】次に、実施例をあげて本発明を説明するが、
これらに限定されるものではない。The present invention will be described below with reference to examples.
It is not limited to these.
【００１２】実施例１ 内径６０cm、高さ９０cmのステンレス製タンクに、精製
水１３０Ｌを添加し、攪拌しながら炭酸カルシウム１４
kg及び２kgのファイブラルセルＢＨ−１００を順次加
え、９０℃にて、タンク上面から気泡が溢れ出さない速
度で３０W/V％酢酸水溶液を７０Ｌ及び６０W/V％クエン
酸水溶液を８．３Ｌ順次添加し、炭酸カルシウムが完全
に溶解したところでろ過し、２．７W/V％のカルシウム
水溶液を製造した。Example 1 130 L of purified water was added to a stainless steel tank having an inner diameter of 60 cm and a height of 90 cm, and calcium carbonate 14 was added with stirring.
kg and 2 kg of Fibral Cell BH-100 are sequentially added, and 30 L / 60% aqueous solution of 30 W / V% acetic acid and 8.3 L of 60 W / V% citric acid aqueous solution are sequentially added at 90 ° C. at a speed at which bubbles do not overflow from the upper surface of the tank. When added, the calcium carbonate was completely dissolved and filtered to produce a 2.7 W / V% calcium aqueous solution.
【００１３】実施例２ 内径１００cm、高さ１５０cmのステンレス製タンクに、
精製水６５０Ｌを添加し、攪拌しながら、粉砕して１０
０メッシュの篩で篩過したボレイ末７０kg及び１０kgの
ダイアセル−１５０を順次加え、７０℃にて、タンク上
面から気泡が溢れ出さない速度で５０W/V％乳酸水溶液
３６０Ｌを添加し、ボレイ末が完全に溶解したところで
ろ過し、２．８W/V％のカルシウム水溶液を製造した。Example 2 In a stainless steel tank having an inner diameter of 100 cm and a height of 150 cm,
Add 650 L of purified water, crush and stir 10
Add 70 kg of boley powder and 10 kg of DIACEL-150 sieved through a 0 mesh sieve in sequence, add 360 W of 50 W / V% lactic acid aqueous solution at 70 ° C. at a speed at which bubbles do not overflow from the upper surface of the tank, and volley powder is removed. When completely dissolved, it was filtered to produce a 2.8 W / V% calcium aqueous solution.
【００１４】実施例３ 内径１３０cm、高さ１９５cmのステンレス製タンクに、
精製水１３００Ｌを添加し、攪拌しながら、粉砕して１
００メッシュの篩で篩過したサンゴ１４０kg及び２０kg
のセライトＣ−５０５を順次加え、５０℃にて、タンク
上面から気泡が溢れ出さない速度で５０W/V％乳酸水溶
液５００Ｌ及び６０W/V％クエン酸水溶液８３Ｌを順次
添加し、サンゴが完全に溶解したところでろ過し、３W/
V％のカルシウム水溶液を製造した。Example 3 In a stainless steel tank having an inner diameter of 130 cm and a height of 195 cm,
Add 1300 L of purified water, crush and stir 1
140kg and 20kg of coral sieving with 00 mesh sieve
Celite C-505 is sequentially added, and at 50 ° C, 500 L of 50 W / V% lactic acid aqueous solution and 83 L of 60 W / V% citric acid aqueous solution are sequentially added at a speed at which bubbles do not overflow from the tank upper surface, and the coral is completely dissolved. When filtered, filter 3W /
An aqueous V% calcium solution was prepared.
【００１５】実施例４ 内径１３０cm、高さ１９５cmのステンレス製タンクに、
精製水６５０Ｌを添加し、攪拌しながら、粉砕して１０
０メッシュの篩で篩過したボレイ末１４０kg、５kgのダ
イアセル−１５０及び５kgのセライトＣ−５０５を順次
加え、９０℃にて、タンク上面から気泡が溢れ出さない
速度で氷酢酸２１０Ｌ及び６０W/V％マレイン酸水溶液
８３Ｌを順次添加し、サンゴが完全に溶解したところで
ろ過し、５．９W/V％のカルシウム水溶液を製造した。Example 4 In a stainless steel tank having an inner diameter of 130 cm and a height of 195 cm,
Add 650 L of purified water, crush and stir 10
Boreh powder 140 kg, 5 kg Diacel-150 and 5 kg Celite C-505, which have been sieved through a 0 mesh sieve, are sequentially added, and 210 L and 60 W / V of glacial acetic acid at 90 ° C at a speed at which bubbles do not overflow from the upper surface of the tank. % Maleic acid aqueous solution (83 L) was sequentially added, and when the coral was completely dissolved, it was filtered to produce a 5.9 W / V% calcium aqueous solution.
【００１６】実施例５ 内径１００cm、高さ１５０cmのステンレス製タンクに、
精製水６５０Ｌを添加し、攪拌しながら、炭酸カルシウ
ム７０kg、２．５kgのファイブラルセルＢＨ−１００及
び２．５kgのダイアセル−１５０を順次加え、７０℃に
て、タンク上面から気泡が溢れ出さない速度で５０W/V
％乳酸水溶液２５０Ｌ及び６０W/V％リンゴ酸水溶液４
２Ｌを順次添加し、炭酸カルシウムが完全に溶解したと
ころでろ過し、３W/V％のカルシウム水溶液を製造し
た。Example 5 In a stainless steel tank having an inner diameter of 100 cm and a height of 150 cm,
650 L of purified water was added, and 70 kg of calcium carbonate, 2.5 kg of Fibral cell BH-100 and 2.5 kg of DIACEL-150 were sequentially added while stirring, and air bubbles did not overflow from the upper surface of the tank at 70 ° C. 50W / V at speed
% Lactic acid aqueous solution 250 L and 60 W / V% Malic acid aqueous solution 4
2 L were sequentially added, and when the calcium carbonate was completely dissolved, it was filtered to produce a 3 W / V% calcium aqueous solution.
【００１７】実施例６ 内径１００cm、高さ１５０cmのステンレス製タンクに、
精製水６５０Ｌを添加し、攪拌しながら、粉砕して１０
０メッシュの篩で篩過したサンゴ７０kg、１０kgのファ
イブラルセルＢＨ−１００及び１０kgのセライトＣ−５
０５を順次加え、５０℃にて、タンク上面から気泡が溢
れ出さない速度で５０W/V％乳酸水溶液２５０Ｌ及び６
０W/V％フマル酸水溶液４２Ｌを順次添加し、サンゴが
完全に溶解したところでろ過し、３W/V％のカルシウム
水溶液を製造した。Example 6 In a stainless steel tank having an inner diameter of 100 cm and a height of 150 cm,
Add 650 L of purified water, crush and stir 10
70 kg of coral, 10 kg of Fibral Cell BH-100 and 10 kg of Celite C-5 which have been sieved through a 0 mesh sieve.
05 was sequentially added, and at 50 ° C., 250 L of 50 W / V% lactic acid aqueous solution and 6 at a speed at which bubbles did not overflow from the upper surface of the tank.
42 L of 0 W / V% fumaric acid aqueous solution was sequentially added, and when the coral was completely dissolved, it was filtered to produce a 3 W / V% calcium aqueous solution.
【００１８】実施例７ 内径１００cm、高さ１５０cmのステンレス製タンクに、
精製水６５０Ｌを添加し、攪拌しながら、粉砕して１０
０メッシュの篩で篩過したボレイ末７０kg、粉末木炭５
kg及び活性炭５kgを順次加え、９０℃にて、タンク上面
から気泡が溢れ出さない速度で３０W/V％酢酸水溶液３
５０Ｌ及び６０W/V％リンゴ酸水溶液４２Ｌを順次添加
し、ボレイ末が完全に溶解したところでろ過し、２．７
W/V％のカルシウム水溶液を製造した。Example 7 In a stainless steel tank having an inner diameter of 100 cm and a height of 150 cm,
Add 650 L of purified water, crush and stir 10
70 kg of boley powder sieving with 0 mesh sieve, powdered charcoal 5
kg and activated carbon 5 kg are added in sequence, and at 90 ° C, 30 W / V% acetic acid aqueous solution at a speed that prevents bubbles from overflowing from the top surface of the tank 3
50 L and 42 W of 60 W / V% malic acid aqueous solution were sequentially added, and when the boll powder was completely dissolved, it was filtered to 2.7.
An aqueous W / V% calcium solution was prepared.
【００１９】次に、上述の各実施例に対応する公知の方
法を比較例として示す。 比較例１ 内径６０cm、高さ９０cmのステンレス製タンクに、精製
水１３０Ｌを添加し、攪拌しながら炭酸カルシウム１４
kgを順次加え、９０℃にて、タンク上面から気泡が溢れ
出さない速度で３０W/V％酢酸水溶液７０Ｌ及び６０W/V
％クエン酸水溶液８．３Ｌを順次添加し、炭酸カルシウ
ムが完全に溶解したところでろ過し、２．７W/V％のカ
ルシウム水溶液を製造した。Next, a known method corresponding to each of the above-mentioned embodiments will be shown as a comparative example. Comparative Example 1 130 L of purified water was added to a stainless steel tank having an inner diameter of 60 cm and a height of 90 cm, and calcium carbonate 14 was added with stirring.
kg sequentially, and at 90 ° C, 70 L and 60 W / V of 30 W / V% acetic acid aqueous solution at a speed at which bubbles do not overflow from the top surface of the tank.
% 8.3 L citric acid aqueous solution was added successively, and when the calcium carbonate was completely dissolved, it was filtered to produce a 2.7 W / V% calcium aqueous solution.
【００２０】比較例２ 内径１００cm、高さ１５０cmのステンレス製タンクに、
精製水６５０Ｌを添加し、攪拌しながら、粉砕して１０
０メッシュの篩で篩過したボレイ末７０kgを順次加え、
７０℃にて、タンク上面から気泡が溢れ出さない速度で
５０W/V％乳酸水溶液３６０Ｌを添加し、ボレイ末が完
全に溶解したところでろ過し、２．８W/V％のカルシウ
ム水溶液を製造した。Comparative Example 2 In a stainless steel tank having an inner diameter of 100 cm and a height of 150 cm,
Add 650 L of purified water, crush and stir 10
Add 70kg of volley powder sieved with 0 mesh sieve,
At 70 ° C., 360 L of a 50 W / V% lactic acid aqueous solution was added at a rate at which bubbles did not overflow from the upper surface of the tank, and when the boley powder was completely dissolved, it was filtered to produce a 2.8 W / V% calcium aqueous solution.
【００２１】比較例３ 内径１３０cm、高さ１９５cmのステンレス製タンクに、
精製水１３００Ｌを添加し、攪拌しながら、粉砕して１
００メッシュの篩で篩過したサンゴ１４０kgを順次加
え、５０℃にて、タンク上面から気泡が溢れ出さない速
度で５０W/V％乳酸水溶液５００Ｌ及び６０W/V％クエン
酸水溶液８３Ｌを順次添加し、サンゴが完全に溶解した
ところでろ過し、３W/V％のカルシウム水溶液を製造し
た。Comparative Example 3 In a stainless steel tank having an inner diameter of 130 cm and a height of 195 cm,
Add 1300 L of purified water, crush and stir 1
140 kg of coral that has been sieved with a 00 mesh sieve are sequentially added, and at 50 ° C., 500 L of 50 W / V% lactic acid aqueous solution and 83 L of 60 W / V% citric acid aqueous solution are sequentially added at a rate at which bubbles do not overflow from the tank upper surface, When the coral was completely dissolved, it was filtered to produce a 3 W / V% calcium aqueous solution.
【００２２】比較例４ 内径１３０cm、高さ１９５cmのステンレス製タンクに、
精製水６５０Ｌを添加し、攪拌しながら、粉砕して１０
０メッシュの篩で篩過したボレイ末１４０kgを順次加
え、９０℃にて、タンク上面から気泡が溢れ出さない速
度で氷酢酸２１０Ｌ及び６０W/V％マレイン酸水溶液８
３Ｌを順次添加し、サンゴが完全に溶解したところでろ
過し、５．９W/V％のカルシウム水溶液を製造した。Comparative Example 4 In a stainless steel tank having an inner diameter of 130 cm and a height of 195 cm,
Add 650 L of purified water, crush and stir 10
Add 140kg of volley powder sieving with a 0 mesh sieve, and add 210L of glacial acetic acid and 60W / V% maleic acid aqueous solution at 90 ° C at a speed that does not cause bubbles to overflow from the top of the tank.
3 L was sequentially added, and when the coral was completely dissolved, it was filtered to produce a 5.9 W / V% calcium aqueous solution.
【００２３】比較例５ 内径１００cm、高さ１５０cmのステンレス製タンクに、
精製水６５０Ｌを添加し、攪拌しながら、炭酸カルシウ
ム７０kgを順次加え、７０℃にて、タンク上面から気泡
が溢れ出さない速度で５０W/V％乳酸水溶液２５０Ｌ及
び６０W/V％リンゴ酸水溶液４２Ｌを順次添加し、炭酸
カルシウムが完全に溶解したところでろ過し、３W/V％
のカルシウム水溶液を製造した。Comparative Example 5 In a stainless steel tank having an inner diameter of 100 cm and a height of 150 cm,
650 L of purified water was added, 70 kg of calcium carbonate was sequentially added with stirring, and 250 L of 50 W / V% lactic acid aqueous solution and 60 W / V% malic acid aqueous solution were added at 70 ° C. at a speed at which bubbles did not overflow from the tank upper surface. Sequentially add, filter when completely dissolved calcium carbonate, 3W / V%
An aqueous calcium solution was prepared.
【００２４】比較例６ 内径１００cm、高さ１５０cmのステンレス製タンクに、
精製水６５０Ｌを添加し、攪拌しながら、粉砕して１０
０メッシュの篩で篩過したサンゴ７０kgを順次加え、５
０℃にて、タンク上面から気泡が溢れ出さない速度で５
０W/V％乳酸水溶液２５０Ｌ及び６０W/V％フマル酸水溶
液４２Ｌを順次添加し、サンゴが完全に溶解したところ
でろ過し、３W/V％のカルシウム水溶液を製造した。Comparative Example 6 In a stainless steel tank having an inner diameter of 100 cm and a height of 150 cm,
Add 650 L of purified water, crush and stir 10
Add 70 kg of coral that has been sieved through a 0 mesh sieve in order
At 0 ° C, 5 at a speed that prevents bubbles from overflowing from the top of the tank
250 L of 0 W / V% lactic acid aqueous solution and 42 L of 60 W / V% fumaric acid aqueous solution were sequentially added, and when the coral was completely dissolved, it was filtered to produce a 3 W / V% calcium aqueous solution.
【００２５】比較例７ 内径１００cm、高さ１５０cmのステンレス製タンクに、
精製水６５０Ｌを添加し、攪拌しながら、粉砕して１０
０メッシュの篩で篩過したボレイ末７０kgを加え、９０
℃にて、タンク上面から気泡が溢れ出さない速度で３０
W/V％酢酸水溶液３５０Ｌ及び６０W/V％リンゴ酸水溶液
４２Ｌを順次添加し、ボレイ末が完全に溶解したところ
でろ過し、２．７W/V％のカルシウム水溶液を製造し
た。Comparative Example 7 In a stainless steel tank having an inner diameter of 100 cm and a height of 150 cm,
Add 650 L of purified water, crush and stir 10
Add 70 kg of boley powder screened with 0 mesh sieve,
30 ° C at a speed that prevents bubbles from overflowing from the top of the tank
A W / V% acetic acid aqueous solution (350 L) and a 60 W / V% malic acid aqueous solution (42 L) were sequentially added, and when the boley powder was completely dissolved, the mixture was filtered to produce a 2.7 W / V% calcium aqueous solution.
【００２６】次に、実施例で得られたカルシウム水溶液
をカルシウム飲料とする製造方法の一例を参考例として
示す。 参考例 実施例１で得られたカルシウム水溶液を精製水で２２０
Ｌとし、これに精製白糖８５kg及び還元麦芽糖水飴（７
５％）３５kgを添加し、攪拌溶解後、精製水で７００Ｌ
とした。この液をガラス瓶に充填し、アルミキャップで
施栓したあと殺菌してカルシウム飲料を製造した。Next, an example of a method of producing the calcium aqueous solution obtained from the examples as a calcium beverage will be shown as a reference example. Reference Example The aqueous calcium solution obtained in Example 1 was purified with purified water 220
L and 85 kg of refined white sugar and reduced maltose starch syrup (7
5%) 35 kg was added, dissolved with stirring, and then 700 L with purified water
And A glass bottle was filled with this solution, and the bottle was capped with an aluminum cap and then sterilized to produce a calcium beverage.
【００２７】[0027]
【発明の効果】有機酸の添加を開始してからカルシウム
源が完全に溶解するまでの時間を測定した。結果を表１
に示す。EFFECT OF THE INVENTION The time from the start of the addition of the organic acid to the complete dissolution of the calcium source was measured. Table 1 shows the results
Shown in
【００２８】[0028]
【表１】 [Table 1]
【００２９】表１から明らかなように、本発明方法は公
知の方法である比較例と比べカルシウム源の溶解時間が
大幅に短縮された。 整理番号ＰＺ０１５９ 化学式等を記載した書面 明細書As is apparent from Table 1, the dissolution time of the calcium source was significantly shortened in the method of the present invention as compared with the known method of Comparative Example. Document number with the reference number PZ0159 chemical formula
【表１】 上記のカルシウム源を有機酸に溶解するに際し、セルロ
ース、ケイソウ土、パーフライト、活性炭、粉末木炭な
どのろ過助剤を添加することにより、気泡を大量に発生
させずカルシウム源の溶解時間を大幅に短縮した。[Table 1] When dissolving the above calcium source in an organic acid, by adding a filter aid such as cellulose, diatomaceous earth, perflite, activated carbon, and powdered charcoal, the dissolution time of the calcium source is greatly increased without generating a large amount of bubbles. Shortened.
Claims (3)
類の殻又はサンゴを有機酸で溶解する方法において、ろ
過助剤を添加することを特徴とするカルシウム水溶液の
製造方法。1. A method for producing an aqueous calcium solution, which comprises adding a filter aid in a method of dissolving calcium carbonate, calcium hydrogen carbonate, shellfish or coral with an organic acid.
ライト、活性炭又は粉末木炭の１種又は２種以上である
請求項１記載のカルシウム水溶液の製造方法。2. The method for producing an aqueous calcium solution according to claim 1, wherein the filter aid is one or more of cellulose, diatomaceous earth, perlite, activated carbon and powdered charcoal.
クエン酸、マレイン酸又はフマル酸の１種又は２種以上
である請求項１又は２記載のカルシウム水溶液の製造方
法。3. The organic acid is lactic acid, acetic acid, glacial acetic acid, malic acid,
The method for producing an aqueous calcium solution according to claim 1 or 2, which is one kind or two or more kinds of citric acid, maleic acid or fumaric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25721495A JP3985272B2 (en) | 1995-09-11 | 1995-09-11 | Method for producing aqueous calcium solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25721495A JP3985272B2 (en) | 1995-09-11 | 1995-09-11 | Method for producing aqueous calcium solution |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0977673A true JPH0977673A (en) | 1997-03-25 |
| JP3985272B2 JP3985272B2 (en) | 2007-10-03 |
Family
ID=17303256
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25721495A Expired - Fee Related JP3985272B2 (en) | 1995-09-11 | 1995-09-11 | Method for producing aqueous calcium solution |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3985272B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0949294A1 (en) * | 1996-12-24 | 1999-10-13 | Asahi Kasei Kogyo Kabushiki Kaisha | Aqueous suspension composition and water-dispersible dry composition |
| JP2008222458A (en) * | 2007-03-08 | 2008-09-25 | Hiroshima Industrial Promotion Organization | Method of preparing calcium ion water, and cement hardened body and method of manufacturing the same |
| JP2012012276A (en) * | 2010-07-05 | 2012-01-19 | Kinki Univ | Method for producing cement hardened body |
-
1995
- 1995-09-11 JP JP25721495A patent/JP3985272B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0949294A1 (en) * | 1996-12-24 | 1999-10-13 | Asahi Kasei Kogyo Kabushiki Kaisha | Aqueous suspension composition and water-dispersible dry composition |
| EP0949294A4 (en) * | 1996-12-24 | 2000-03-29 | Asahi Chemical Ind | Aqueous suspension composition and water-dispersible dry composition |
| JP2008222458A (en) * | 2007-03-08 | 2008-09-25 | Hiroshima Industrial Promotion Organization | Method of preparing calcium ion water, and cement hardened body and method of manufacturing the same |
| JP2012012276A (en) * | 2010-07-05 | 2012-01-19 | Kinki Univ | Method for producing cement hardened body |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3985272B2 (en) | 2007-10-03 |
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