JPH0948962A - Agent that inhibits solidification of liquid - Google Patents
Agent that inhibits solidification of liquidInfo
- Publication number
- JPH0948962A JPH0948962A JP19987595A JP19987595A JPH0948962A JP H0948962 A JPH0948962 A JP H0948962A JP 19987595 A JP19987595 A JP 19987595A JP 19987595 A JP19987595 A JP 19987595A JP H0948962 A JPH0948962 A JP H0948962A
- Authority
- JP
- Japan
- Prior art keywords
- liquid
- liquid composition
- pump
- solidification
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明はポンプ付き容器に充
填されて用いられる液体洗浄料や液体化粧料等の液体組
成物への配合に好適な、ヒドロキシ脂肪酸を有効成分と
する液体の固化抑制剤に関する。TECHNICAL FIELD The present invention relates to a liquid solidification inhibitor containing a hydroxy fatty acid as an active ingredient, which is suitable for blending in a liquid composition such as a liquid detergent or a liquid cosmetic filled in a container equipped with a pump. Regarding
【０００２】[0002]
【従来の技術】近年、ポンプ機構を有する容器の開発に
伴って、液体洗浄料や液体化粧料等の液体組成物が、そ
のようなポンプ付き容器に充填して販売され使用される
ことが多くなってきている。特に、液体洗浄料の分野に
おける普及は著しく、これは、従来の固形石鹸では公共
の場において誰が使用したかわからないものを使うこと
への懸念があったのに対し、液体石鹸等をポンプ容器に
充填して用いることにより、このような懸念が少なくな
ったためであると考えられる。2. Description of the Related Art In recent years, along with the development of containers having a pump mechanism, liquid compositions such as liquid detergents and liquid cosmetics are often filled and sold in such pump-equipped containers. It has become to. Especially, in the field of liquid cleaning agents, the spread is remarkable, and there was a concern about using conventional solid soap in public places where it is not known who used it, while liquid soap etc. is used as a pump container. It is considered that such a concern was alleviated by filling and using.
【０００３】しかしながら、そのような液体洗浄料等の
液体組成物をポンプ容器に充填して用いると、ポンプか
らの吐出口に残存した液体組成物中の揮発成分の揮散等
により、液体組成物が固化し、吐出口を塞ぐことが少な
くなかった。このような現象を防ぐため、吐出口の形状
に残存物の付着量が少なくなるような構造を採用するな
どの検討がなされているが、充分に満足のいくものでは
なかった。一方、このようなポンプ容器への充填に適合
した、固化しにくい液体組成物を開発する試みは、これ
までなされていなかった。However, when such a liquid composition such as a liquid detergent is used by filling it in a pump container, the liquid composition is formed by volatilization of volatile components in the liquid composition remaining at the discharge port from the pump. It often solidifies and blocks the discharge port. In order to prevent such a phenomenon, studies have been made to adopt a structure in which the amount of remaining substances attached to the shape of the discharge port is reduced, but it has not been sufficiently satisfactory. On the other hand, no attempt has been made so far to develop a liquid composition that is suitable for filling such a pump container and hardly solidifies.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、かかる状況
に鑑みてなされたものであり、液体組成物をポンプ付き
容器に充填した場合に、吐出口での固化を抑制する作用
を有する液体の固化抑制剤、及びそれを含有するポンプ
付き容器へ充填して使用するのに適した液体組成物を提
供することを課題とする。DISCLOSURE OF THE INVENTION The present invention has been made in view of the above situation, and when a liquid with a liquid composition is filled in a container with a pump, a liquid having a function of suppressing solidification at a discharge port is provided. An object of the present invention is to provide a solidification inhibitor and a liquid composition suitable for use by filling a container with a pump containing the solidification inhibitor.
【０００５】[0005]
【課題を解決するための手段】本発明者らは、このよう
な状況を踏まえ、ポンプ付き容器に充填する液体組成物
自体についてみた場合に、固化しにくい組成の検討が未
だなされていないことに着目し、種々の化合物につい
て、液体組成物の固化抑制作用を指標にスクリーニング
を重ねた結果、ヒドロキシ脂肪酸及びその塩にそのよう
な作用があることを見いだし、発明を完成した。In view of such a situation, the present inventors have not yet examined the composition which is hard to solidify when the liquid composition itself to be filled in the pump-equipped container is examined. As a result of repeated screening of various compounds using the solidification-inhibiting action of the liquid composition as an index, the inventors have found that hydroxy fatty acids and salts thereof have such actions, and completed the invention.
【０００６】すなわち、本発明は、液体の固化抑制剤に
おいて、ヒドロキシ脂肪酸又はその塩を有効成分とする
ことにより、上記課題を解決するものである。以下、本
発明について詳細に説明する。That is, the present invention solves the above problems by using a hydroxy fatty acid or a salt thereof as an active ingredient in a liquid solidification inhibitor. Hereinafter, the present invention will be described in detail.
【０００７】（１）本発明の固化抑制剤 本発明の固化抑制剤は、ヒドロキシ脂肪酸及び生理的に
許容されるその塩からなる。ヒドロキシ脂肪酸として
は、炭素数１０〜２５のものが好ましく、例えば、１２
−ヒドロキシパルミチン酸、１２−ヒドロキシステアリ
ン酸、リチノレイン酸等が例示できるが、最も好ましい
ものは、１２−ヒドロキシステアリン酸である。これ
は、１２−ヒドロキシステアリン酸が最も入手し易く且
つ安定性にも優れるからである。これらの内からただ一
種を選んで用いても良いし、二種以上を組み合わせて用
いても良い。(1) Solidification Inhibitor of the Present Invention The solidification inhibitor of the present invention comprises a hydroxy fatty acid and a physiologically acceptable salt thereof. The hydroxy fatty acid preferably has 10 to 25 carbon atoms, for example, 12
-Hydroxypalmitic acid, 12-hydroxystearic acid, lithinoleic acid and the like can be exemplified, but 12-hydroxystearic acid is most preferable. This is because 12-hydroxystearic acid is the most available and has excellent stability. One of these may be selected and used, or two or more thereof may be used in combination.
【０００８】これらのヒドロキシ脂肪酸の塩としては、
特段の限定はされないが、例えば、液体洗浄料や液体化
粧料等においては生理的に許容できるものが好ましく、
具体的にはナトリウムやカリウム等のアルカリ金属塩、
カルシウムやマグネシウム等のアルカリ土類金属塩、ア
ンモニウム塩、トリエチルアミンやトリエタノールアミ
ン等の有機アミン塩、リジンやアルギニン等の塩基性ア
ミノ酸塩等を例示することができる。これらの中からた
だ一種を選んで用いても良いし、二種以上を組み合わせ
て用いても良い。As the salts of these hydroxy fatty acids,
Although not particularly limited, for example, in a liquid detergent or liquid cosmetic, a physiologically acceptable one is preferable,
Specifically, alkali metal salts such as sodium and potassium,
Examples thereof include alkaline earth metal salts such as calcium and magnesium, ammonium salts, organic amine salts such as triethylamine and triethanolamine, and basic amino acid salts such as lysine and arginine. One of these may be selected and used, or two or more thereof may be used in combination.
【０００９】（２）本発明の液体組成物 本発明の液体組成物は、前記固化抑制剤を含有した液体
状のものである。ここで液体状とは、通常の生活環境で
想定される温度条件下で流動性を有した状態をいい、粘
度を目安にすれば、２５℃で１５０００ｃｓ以下の粘度
を有する状態をいう。(2) Liquid Composition of the Present Invention The liquid composition of the present invention is a liquid composition containing the solidification inhibitor. Here, the liquid state means a state of having fluidity under a temperature condition assumed in a normal living environment, and a state of having a viscosity of 15,000 cs or less at 25 ° C. when the viscosity is a standard.
【００１０】本発明の液体組成物における固化抑制剤の
好適な含有量は、液体組成物全量に対して０．０１〜１
０重量％、更に好ましくは０．１〜５重量％である。ま
た、本発明の液体組成物が液体洗浄料等の場合であって
前記固化抑制剤以外の脂肪酸が含まれているようなとき
は、その液体組成物に含まれる脂肪酸の総量に対して１
〜２０重量％であることが好ましく、５−１５重量％で
あることが更に好ましい。前記固化抑制剤の配合量がこ
のような範囲であれば、洗浄性等の液体組成物本来の作
用を損なうことなく、ポンプ吐出口での固化・閉塞を十
分に抑制することができる。The preferred content of the solidification inhibitor in the liquid composition of the present invention is 0.01 to 1 based on the total amount of the liquid composition.
It is 0% by weight, more preferably 0.1 to 5% by weight. Further, when the liquid composition of the present invention is a liquid detergent or the like and contains a fatty acid other than the solidification inhibitor, it is 1 with respect to the total amount of fatty acids contained in the liquid composition.
It is preferably -20% by weight, more preferably 5-15% by weight. When the amount of the solidification inhibitor blended is in such a range, solidification / blockage at the pump discharge port can be sufficiently suppressed without impairing the original action of the liquid composition such as the cleaning property.
【００１１】また、本発明の液体組成物は、ポンプ付き
の容器に充填して用いるのに好適な組成物である。ここ
で、ポンプ付き容器とは、ポンプ機能を有した容器一般
をいう。ポンプ機能としては、プッシュ動作によって容
器本体より充填された液体組成物を空気圧などを利用し
て吐出させる機構を有するもの、即ち、吐出ノズルと逆
流防止弁を付したものであればよく、例えば市販のもの
で構わない。又、予め炭酸ガスなどの気体を大気圧より
高い圧力で封入し、プッシュ動作によって、充填した液
体組成物を封入した気体と共に吐出させる構造のもので
もよい。Further, the liquid composition of the present invention is a composition suitable for filling a container with a pump for use. Here, the container with a pump means a general container having a pump function. The pump function may be one having a mechanism for discharging the liquid composition filled from the container body by a push operation using air pressure or the like, that is, as long as it has a discharge nozzle and a backflow prevention valve, for example, commercially available It doesn't matter. Further, it may have a structure in which a gas such as carbon dioxide gas is filled at a pressure higher than atmospheric pressure in advance, and the filled liquid composition is discharged together with the filled gas by a push operation.
【００１２】本発明の液体組成物としては、ハンドソー
プ等の液体石鹸、シャンプー、リンス、ボディシャンプ
ー等の液体洗浄料；化粧水、乳液、リキッドファンデー
ション等の液体化粧料；バスローション等の液体入浴
料；等が挙げられる。Examples of the liquid composition of the present invention include liquid soap such as liquid soap such as hand soap, shampoo, rinse, body shampoo; liquid cosmetic such as lotion, emulsion, liquid foundation; liquid bath such as bath lotion. Fees; and the like.
【００１３】本発明の液体組成物が液体洗浄料である場
合は、前記固化抑制剤以外に、洗浄用の界面活性剤や通
常洗浄料で用いられている任意成分を配合することがで
きる。洗浄用の界面活性剤としては、石鹸やラウリル硫
酸ナトリウムのようなアニオン界面活性剤；アルキルア
マイド類等のような非イオン界面活性剤；塩化ベンザル
コニウムのようなカチオン界面活性剤；アルキルベタイ
ン等の両性界面活性剤；等が挙げられる。又、任意成分
としては、加脂成分としての、スクワランや流動パラフ
ィン等の炭化水素類、ホホバ油やゲイロウ等のエステル
類、牛脂や椰子油等のトリグリセライド類、セタノー
ル、オレイルアルコール等の高級アルコール類、ステア
リン酸、オレイン酸等の脂肪酸、グリセリンや１，３−
ブタンジオール等の多価アルコール類、パラベン等の防
腐剤類、ベンゾフェノンやアミノ安息香酸エステル等の
紫外線吸収剤類、ＢＨＴやトコフェロール等の抗酸化剤
等が例示できる。これらを通常の剤形化の方法、例え
ば、加熱可溶化などで処理すれば、揮発分の散失などに
よって固化をしにくい組成物が得られる。When the liquid composition of the present invention is a liquid detergent, in addition to the above-mentioned solidification inhibitor, a surfactant for washing and optional components usually used in detergents can be added. Examples of detergents for cleaning include anionic surfactants such as soap and sodium lauryl sulfate; nonionic surfactants such as alkyl amides; cationic surfactants such as benzalkonium chloride; alkyl betaines, etc. And amphoteric surfactants; Further, as an optional component, hydrocarbons such as squalane and liquid paraffin, esters such as jojoba oil and gallow, triglycerides such as beef tallow and coconut oil, higher alcohols such as cetanol and oleyl alcohol, as a fatliquoring component. , Fatty acids such as stearic acid and oleic acid, glycerin and 1,3-
Examples thereof include polyhydric alcohols such as butanediol, preservatives such as parabens, ultraviolet absorbers such as benzophenone and aminobenzoate, and antioxidants such as BHT and tocopherol. When these are treated by a usual method of forming a dosage form, for example, solubilization by heating, a composition which is hard to solidify due to dispersion of volatile components can be obtained.
【００１４】本発明の液体組成物が液体化粧料の場合
は、色素類、粉体類、アルブチン等の美白剤等を配合す
ることができる。本発明の液体組成物には、その他に目
的や用途に応じて、任意成分として、香料；ビタミン
Ａ、Ｂ、Ｃ、Ｅ等のビタミン類；等の有効成分を配合す
ることができる。When the liquid composition of the present invention is a liquid cosmetic, a whitening agent such as pigments, powders and arbutin can be added. The liquid composition of the present invention may further contain active ingredients such as fragrances; vitamins such as vitamins A, B, C, E; and the like, as optional components, depending on the purpose and use.
【００１５】[0015]
【発明の実施の形態】以下に、発明の実施の形態を挙げ
て本発明について更に詳細に説明するが、本発明がこれ
らの例のみに限定されないことは言うまでもない。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in more detail with reference to embodiments of the invention, but it goes without saying that the present invention is not limited to these examples.
【００１６】（１）液体組成物及び容器充填洗浄料 下記表１に示した配合成分を秤込み、８０℃で加熱撹拌
溶解し、撹拌冷却して洗浄用の組成物１を得た。更に、
これをポンプ付きの容器に充填し、容器充填洗浄料１を
得た。(1) Liquid Composition and Cleaning Agent for Filling Containers The ingredients shown in Table 1 below were weighed, dissolved by heating with stirring at 80 ° C. and cooled with stirring to obtain a cleaning composition 1. Furthermore,
This was filled in a container with a pump to obtain a container filling cleaning agent 1.
【００１７】[0017]
【表１】 [Table 1]
【００１８】（２）液体組成物及び容器充填洗浄料 表２の配合成分を秤込み、８０℃で加熱撹拌溶解し、撹
拌冷却して洗浄用の液体組成物２を得た。更にこれをポ
ンプ付き容器に充填し容器充填洗浄料２とした。(2) Liquid composition and container-filled cleaning agent The ingredients listed in Table 2 were weighed, heated and stirred at 80 ° C. for dissolution, and cooled with stirring to obtain a cleaning liquid composition 2. Further, this was filled in a container with a pump to obtain a container filling cleaning agent 2.
【００１９】[0019]
【表２】 [Table 2]
【００２０】（３）液体組成物及び容器充填洗浄料 下記表３の配合成分を秤込み、８０℃で加熱撹拌溶解
し、撹拌冷却して洗浄用の液体組成物３を得た。更に、
これをポンプ付きの容器に充填して容器充填洗浄料３と
した。(3) Liquid Composition and Cleaning Agent for Filling Containers The composition components shown in Table 3 below were weighed, dissolved by heating with stirring at 80 ° C. and cooled with stirring to obtain Liquid Composition 3 for cleaning. Furthermore,
This was filled in a container with a pump to obtain a container filling cleaning agent 3.
【００２１】[0021]
【表３】 [Table 3]
【００２２】（４）液体組成物及び容器充填洗浄料 下記表４の配合成分を秤込み、８０℃で加熱撹拌溶解
し、撹拌冷却して洗浄用の液体組成物４を得た。更に、
これをポンプ付きの容器に充填して容器充填洗浄料４と
した。(4) Liquid Composition and Cleaning Agent for Filling Containers The ingredients shown in Table 4 below were weighed, dissolved by heating at 80 ° C. with stirring, and cooled by stirring to obtain Liquid Composition 4 for cleaning. Furthermore,
This was filled in a container equipped with a pump to obtain a container filling cleaning agent 4.
【００２３】[0023]
【表４】 ＜表４＞ （数字は重量％） ────────────────────────────── エチレングリコールモノステアレート ０．５ グリセリン １０ １，３−ブタンジオール １０ トリエタノールアミン ７．５ 2-ウンテ゛シル-1-ハイト゛ロキシエチルイミタ゛ソ゛リンヘ゛タイン ５ ステアリン酸 １ パルミチン酸 ９ １２−ヒドロキシステアリン酸トリエチルアミン ３ メチルパラベン ０．２ 水 ５３．８ ────────────────────────────── [Table 4] <Table 4> (Numbers are% by weight) ────────────────────────────── Ethylene glycol monostearate 0 .5 glycerin 10 1,3-butanediol 10 triethanolamine 7.5 2-undecyl-1-hydoxyethylimidazoline betaine 5 stearic acid 1 palmitic acid 9 12-hydroxystearic acid triethylamine 3 methylparaben 0.2 water 53.8 ─ ─────────────────────────────
【００２４】[0024]
［実施例１］上記発明の実施の形態に記した本発明の液
体組成物１〜４について、強制固化試験を行った。即
ち、シャーレに前記液体組成物を各々１ｇ秤取り、開放
系で室温で１ヶ月放置した後、肉眼で流動性を判定し
た。判定基準は、＋：流動性あり、±：やや固化してい
る、−：固化している、であった。又、本発明の液体組
成物１〜４中の固化抑制剤を水に置き換えたものをそれ
ぞれ比較用組成物１〜４とし、同様に流動性を判定し
た。結果を表５に示す。これより、本発明の液体組成物
は固化しにくいことがわかる。更に、このことから、本
発明の固化抑制剤は固化抑制作用に優れることがわか
る。[Example 1] A forced solidification test was conducted on the liquid compositions 1 to 4 of the present invention described in the embodiment of the present invention. That is, 1 g of each of the above liquid compositions was weighed in a Petri dish, allowed to stand for 1 month at room temperature in an open system, and then visually evaluated for fluidity. The criteria were: +: fluidity, ±: slightly solidified, −: solidified. Further, liquid compositions 1 to 4 of the present invention in which the solidification inhibitor was replaced with water were used as Comparative Compositions 1 to 4, respectively, and the fluidity was similarly determined. Table 5 shows the results. From this, it is understood that the liquid composition of the present invention is hard to solidify. Furthermore, from this, it is understood that the solidification inhibitor of the present invention is excellent in the solidification inhibitory action.
【００２５】[0025]
【表５】 [Table 5]
【００２６】［実施例２］上記発明の実施の形態に記し
た容器充填洗浄料１〜４について、吐出させた後吐出口
の液体組成物を拭き取らずキャップを外したまま、室温
で２週間放置した後の吐出の具合を、＋：良い、±：普
通、−：悪い、の基準で判定した。本発明の液体組成物
の代わりに上記実施例１の比較用組成物１〜４を充填し
た比較用容器充填洗浄料についても同様の試験を行っ
た。結果を表２に示す。これより本発明の化粧料は吐出
の具合が変わらないことがわかる。Example 2 With respect to the container filling cleaning agents 1 to 4 described in the embodiment of the present invention, after discharging, the liquid composition at the discharge port was not wiped off and the cap was removed for 2 weeks at room temperature. The discharge condition after leaving was judged according to the criteria of +: good, ±: normal,-: bad. Similar tests were carried out on the comparative container-filled detergents filled with the comparative compositions 1 to 4 of Example 1 in place of the liquid composition of the present invention. Table 2 shows the results. From this, it can be seen that the cosmetic of the present invention does not change the discharge condition.
【００２７】[0027]
【表６】 [Table 6]
【００２８】［実施例３］上記本発明の洗浄用の液体組
成物１〜４について、各々比較用組成物１〜４との洗浄
能力の比較を専門パネルによって行い、評価した。比較
用組成物より洗浄能力に優れるものには＋を、同等のも
のには±を、劣るものには−を付した。結果を表３に示
す。これより、固化抑制剤を添加したことによる洗浄力
の低下は認められないことがわかった。Example 3 With respect to the cleaning liquid compositions 1 to 4 of the present invention, the cleaning ability was compared with the comparative compositions 1 to 4 by a specialized panel and evaluated. Those having a cleaning ability superior to those of the comparative composition were marked with +, those having an equivalent ability were marked with ±, and those having a poorer cleaning ability were marked with −. The results are shown in Table 3. From this, it was found that the addition of the solidification inhibitor did not impair the detergency.
【００２９】[0029]
【表７】 [Table 7]
【００３０】[0030]
【発明の効果】本発明の固化抑制剤は固化抑制作用に優
れ、これを含有する液体洗浄料等の液体組成物をポンプ
容器に充填した場合は、液体組成物の固化によるノズル
の詰まりがない。The solidification inhibitor of the present invention has an excellent solidification-suppressing action, and when a liquid composition such as a liquid detergent containing the same is filled in a pump container, the nozzle is not clogged due to the solidification of the liquid composition. .
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ１１Ｄ 3/20 Ｃ１１Ｄ 3/20 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI Technical indication C11D 3/20 C11D 3/20
Claims (5)
とする液体の固化抑制剤。1. A liquid solidification inhibitor containing a hydroxy fatty acid or a salt thereof as an active ingredient.
テアリン酸である、請求項１記載の液体の固化抑制剤。2. The liquid solidification inhibitor according to claim 1, wherein the hydroxy fatty acid is 12-hydroxystearic acid.
を含有するポンプ付き容器充填用液体組成物。3. A liquid composition for filling a container with a pump, which contains the liquid solidification inhibitor according to claim 1.
項３記載のポンプ付き容器充填用液体組成物。4. The liquid composition for filling a container with a pump according to claim 3, wherein the liquid composition is a liquid detergent.
項３記載のポンプ付き容器充填用液体組成物。5. The liquid composition for filling a container with a pump according to claim 3, wherein the liquid composition is a liquid cosmetic.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19987595A JP3694069B2 (en) | 1995-08-04 | 1995-08-04 | Liquid solidification inhibitor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19987595A JP3694069B2 (en) | 1995-08-04 | 1995-08-04 | Liquid solidification inhibitor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0948962A true JPH0948962A (en) | 1997-02-18 |
| JP3694069B2 JP3694069B2 (en) | 2005-09-14 |
Family
ID=16415081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19987595A Expired - Lifetime JP3694069B2 (en) | 1995-08-04 | 1995-08-04 | Liquid solidification inhibitor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3694069B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007238457A (en) * | 2006-03-06 | 2007-09-20 | Pola Chem Ind Inc | Cleansing agent in which cleansing agent composition is packed in pump vessel |
| WO2011137664A1 (en) * | 2010-05-07 | 2011-11-10 | Unilever Plc | Skin conditioning compositions containing 12-hydrocystearic acid |
| WO2012061991A1 (en) | 2010-11-11 | 2012-05-18 | Unilever Plc | Leave-on nonsolid skin conditioning compositions containing 12-hydroxystearic acid |
| WO2012080272A2 (en) | 2010-12-15 | 2012-06-21 | Unilever Plc | Leave-on non-solid skin conditioning compositions containing 12-hydroxystearic acid and ethoxylated hydrogenated castor oil |
| WO2012110276A1 (en) | 2011-02-17 | 2012-08-23 | Unilever Plc | Leave -on non- solid skin conditioning composition which has a continuous phase and contains 12 - hydroxystearic acid |
| US9744109B2 (en) | 2012-12-20 | 2017-08-29 | Conopco. Inc. | Eutectic mixtures in personal care compositions |
| JP2019511517A (en) * | 2016-04-13 | 2019-04-25 | ディーエスエム アイピー アセッツ ビー．ブイ．Ｄｓｍ Ｉｐ Ａｓｓｅｔｓ Ｂ．Ｖ． | 10-hydroxystearic acid composition |
| JP2021066792A (en) * | 2019-10-23 | 2021-04-30 | 株式会社 資生堂 | Detergent composition and detergent product |
-
1995
- 1995-08-04 JP JP19987595A patent/JP3694069B2/en not_active Expired - Lifetime
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007238457A (en) * | 2006-03-06 | 2007-09-20 | Pola Chem Ind Inc | Cleansing agent in which cleansing agent composition is packed in pump vessel |
| US9539190B2 (en) | 2010-05-07 | 2017-01-10 | Conopco, Inc. | Skin conditioning compositions containing 12-hydroxystearic acid |
| EP2566439A1 (en) * | 2010-05-07 | 2013-03-13 | Unilever PLC | Skin conditioning compositions containing 12-hydrocystearic acid |
| EP2566439A4 (en) * | 2010-05-07 | 2013-09-25 | Unilever Plc | Skin conditioning compositions containing 12-hydrocystearic acid |
| WO2011137664A1 (en) * | 2010-05-07 | 2011-11-10 | Unilever Plc | Skin conditioning compositions containing 12-hydrocystearic acid |
| EA029536B1 (en) * | 2010-05-07 | 2018-04-30 | Унилевер Н.В. | Skin conditioning compositions containing 12-hydrocystearic acid |
| WO2012061991A1 (en) | 2010-11-11 | 2012-05-18 | Unilever Plc | Leave-on nonsolid skin conditioning compositions containing 12-hydroxystearic acid |
| JP2013542230A (en) * | 2010-11-11 | 2013-11-21 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Leave-on non-solid skin conditioning composition containing 12-hydroxystearic acid |
| WO2012080272A2 (en) | 2010-12-15 | 2012-06-21 | Unilever Plc | Leave-on non-solid skin conditioning compositions containing 12-hydroxystearic acid and ethoxylated hydrogenated castor oil |
| US8613939B2 (en) | 2010-12-15 | 2013-12-24 | Conopco, Inc. | Leave-on nonsolid skin conditioning compositions containing 12-hydroxystearic acid and ethoxylated hydrogenated castor oil |
| WO2012110276A1 (en) | 2011-02-17 | 2012-08-23 | Unilever Plc | Leave -on non- solid skin conditioning composition which has a continuous phase and contains 12 - hydroxystearic acid |
| US9744109B2 (en) | 2012-12-20 | 2017-08-29 | Conopco. Inc. | Eutectic mixtures in personal care compositions |
| JP2019511517A (en) * | 2016-04-13 | 2019-04-25 | ディーエスエム アイピー アセッツ ビー．ブイ．Ｄｓｍ Ｉｐ Ａｓｓｅｔｓ Ｂ．Ｖ． | 10-hydroxystearic acid composition |
| JP2021066792A (en) * | 2019-10-23 | 2021-04-30 | 株式会社 資生堂 | Detergent composition and detergent product |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3694069B2 (en) | 2005-09-14 |
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