JPH09299271A - Wet type cleaning/wiping material - Google Patents
Wet type cleaning/wiping materialInfo
- Publication number
- JPH09299271A JPH09299271A JP12508796A JP12508796A JPH09299271A JP H09299271 A JPH09299271 A JP H09299271A JP 12508796 A JP12508796 A JP 12508796A JP 12508796 A JP12508796 A JP 12508796A JP H09299271 A JPH09299271 A JP H09299271A
- Authority
- JP
- Japan
- Prior art keywords
- cleaning
- perfluoropolyether
- carrier
- wiping
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Body Washing Hand Wipes And Brushes (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、エマルジョン化し
たパーフルオロポリエーテルを不織布等の担体に含浸さ
せてなるウェットティッシュその他の清拭材に関する。
本発明に係る清拭材は、対人用のものであって、頭髪や
身体の清拭に適する。さらに詳しくは、汚れを拭き取っ
た後に臭いや汚れが付きにくく、肌を保護する機能を有
する身体清拭材に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a wet tissue or other cleaning material obtained by impregnating a carrier such as a non-woven fabric with emulsified perfluoropolyether.
The cleaning material according to the present invention is for personal use and is suitable for cleaning hair and body. More specifically, the present invention relates to a body-cleansing material which has a function of protecting the skin from being easily scented or stained after wiping off dirt.
【０００２】[0002]
【従来の技術】従来、ウェットティッシュとしては、不
織布や紙等の水分を保持できるシート材料にプロピレン
グリコール、エチルアルコール、殺菌剤等の水溶液を含
浸させたものが知られている。このウエットティシュ
は、幼児や老人の身体の汚れを拭き取るために使用され
ることがある。2. Description of the Related Art Heretofore, as a wet tissue, there has been known a sheet material such as non-woven fabric or paper impregnated with an aqueous solution of propylene glycol, ethyl alcohol, a germicide or the like. This wet tissue is sometimes used to wipe the dirt of the body of an infant or an elderly person.
【０００３】また、頭髪の汚れを拭き取るためのものと
してドライシャンプーが知られている。ドライシャンプ
ーは、水を使用できない場合に、各種の粉末を毛髪に擦
り付けて、この粉末に汚れを付着させて拭き取ろうとす
るものである。汚れ拭き取り材をミスト状にして頭髪に
吹き付け、頭髪をもんだり、ブラッシングしたりして汚
れをミストに溶解させた後にタオル等で汚れを拭き取る
こともある。この汚れ拭き取り材の成分は、各種粘土鉱
物、デキストリン等の有機粉末、界面活性剤、エタノー
ル、グリコール等であり、これらを不織布に含浸させて
ウェットティッシュにすることも可能である。Further, dry shampoo is known as a device for wiping off dirt on hair. The dry shampoo is one in which, when water cannot be used, various powders are rubbed on the hair to attach dirt to the powder and wipe it off. There is also a case where a stain-wiping material is formed into a mist and sprayed onto the hair, and the hair is brushed or brushed to dissolve the stain in the mist and then the stain is wiped off with a towel or the like. The components of the stain wiper are various clay minerals, organic powders such as dextrin, surfactants, ethanol, glycol and the like, and it is also possible to impregnate these with a non-woven fabric to form a wet tissue.
【０００４】これらのウェットティッシュは、清拭力が
あり、肌に対して安全である他に、拭いた後の肌や頭髪
を汚れや臭いが付着しにくい状態にしたり、さらには肌
を保護したりする機能を有していることが望ましい。清
拭力があり肌を保護する機能を備えたものとしては、種
々のシリコーンを配合した洗浄剤・清拭材に関する特開
昭６４−７９１０８号、同６４−８３０１４号、特開平
７−４１７９４号等の公報に記載された組成物を挙げる
ことができる。ただし、これらの組成物は、汚れや臭い
の付着を防止する機能を有していない。These wet tissues have a cleansing power and are safe for the skin, as well as make the skin and hair after wiping to a state where dirt and odor are not easily attached, and further protect the skin. It is desirable to have the function of As a cleaning agent having a wiping power and a function of protecting the skin, Japanese Patent Laid-Open Nos. 64-79108, 64-83014, and 7-41794 relating to cleaning agents and wiping materials containing various silicones are known. And the like. However, these compositions do not have the function of preventing adhesion of dirt and odor.
【０００５】一方、汚れや臭いが付着しにくくなる清拭
材である特開平４−２０８２１１号公報に開示された
「ふきとり化粧料」には、パーフルオロポリエーテルを
柔軟な担体に含浸させることが記載されている。パーフ
ルオロポリエーテルは、水にも油にも溶解しないから、
この「化粧料」では、パーフルオロポリエーテルそのも
の、または、それのエタノールや流動パラフィン溶液を
担体に含浸させている。On the other hand, in the "wiping cosmetics" disclosed in Japanese Patent Laid-Open No. 4-208211 which is a cleaning material in which dirt and odor are less likely to adhere, a soft carrier may be impregnated with perfluoropolyether. Has been described. Perfluoropolyether is insoluble in water and oil,
In this "cosmetic material", the carrier is impregnated with perfluoropolyether itself or its ethanol or liquid paraffin solution.
【０００６】[0006]
【発明が解決しようとする課題】ところが、肌を清拭す
るためのウエットティシュは、水をベースにした薬液を
使用することが肌に対する刺激を軽微にするうえで好ま
しい。またウエットティシュが水を含んでいれば、パー
フルオロポリエーテルやパラフィン等では拭き取ること
が難しい便等の水溶性の汚れを拭き取ることが可能にな
る。However, for a wet tissue for cleaning the skin, it is preferable to use a water-based drug solution in order to reduce irritation to the skin. Further, if the wet tissue contains water, it becomes possible to wipe off water-soluble stains such as stool which is difficult to wipe off with perfluoropolyether or paraffin.
【０００７】そこで、本発明は、肌に対する刺激が軽微
であり、水溶性の汚れを拭き取ることも可能なパーフル
オロポリエーテルを含む清拭材の提供を課題にしてい
る。[0007] Therefore, an object of the present invention is to provide a cleaning material containing perfluoropolyether which is mildly irritating to the skin and is capable of wiping off water-soluble stains.
【０００８】[0008]
【課題を解決するための手段】前記課題を解決するため
に、本発明は、湿潤タイプの清拭材において、水分を保
持可能な担体にパーフルオロポリエーテルのエマルジョ
ンを含浸させることを特徴にしている。In order to solve the above-mentioned problems, the present invention is characterized in that in a wet type cleaning material, a carrier capable of retaining water is impregnated with an emulsion of perfluoropolyether. There is.
【０００９】[0009]
【発明の実施の形態】本発明に係る湿潤タイプの清拭材
は、パーフルオロポリエーテルのエマルジョンからなる
薬液と、この薬液を含浸させた担体とによって構成され
ている。BEST MODE FOR CARRYING OUT THE INVENTION The wet-type wiping material according to the present invention comprises a chemical solution consisting of an emulsion of perfluoropolyether and a carrier impregnated with the chemical solution.
【００１０】本発明に使用されるパーフルオロポリエー
テルは下記の構造を有し、市販品には商品名フォンブリ
ン（アウジモント社製）、デムナム（ダイキン工業株式
社製）がある。分子量は、５００〜１０，０００程度の
ものが知られており、分子量がこの範囲にあるものは、
どれも使用可能である。もっとも、分子量が小さいと揮
発性が高くなるから、実用上の分子量は１，０００以上
が好ましい。使用量は、不織布や紙等の担体に含浸させ
るための薬液における含有量が、０．０１〜１０重量％
であることが好ましい。使用量が０．０１％未満では充
分な効果が期待できず、１０％を超えると薬液の乾燥に
時間がかかり、清拭後の清涼感が乏しくなる。パーフル
オロポリエーテルを含有する薬液は、担体に対して、担
体重量の１〜５倍量を含浸させることが好ましい。The perfluoropolyether used in the present invention has the following structure, and commercially available products include the product names Fomblin (manufactured by Ausimont) and Demnum (manufactured by Daikin Industries, Ltd.). It is known that the molecular weight is about 500 to 10,000, and the molecular weight in this range is
Any can be used. However, when the molecular weight is small, the volatility becomes high, so that the practical molecular weight is preferably 1,000 or more. The amount used is 0.01 to 10% by weight in the chemical liquid for impregnating into a carrier such as nonwoven fabric or paper.
It is preferred that If the amount used is less than 0.01%, a sufficient effect cannot be expected, and if it exceeds 10%, it takes time to dry the chemical solution, and the refreshing feeling after wiping becomes poor. It is preferable to impregnate the carrier with the chemical solution containing perfluoropolyether in an amount of 1 to 5 times the carrier weight.
【００１１】フォンブリンの構造は、次のとおりであ
る。The structure of fomblin is as follows:
【化１】 デムナムの構造は、次のとおりである。Embedded image The structure of Demnam is as follows.
【化２】Ｆ−（ＣＦ2−ＣＦ2−ＣＦ2−Ｏ）x−ＣＦ2−
ＣＦ3 また、パーフルオロポリエーテルをエマルジョン化した
り、薬液に清拭性能、殺菌性、頭髪に対する帯電防止性
を付与するために配合される界面活性剤は、ノニオン、
カチオン、両性いずれのタイプのものでもよい。ただ
し、肌に対する刺激が弱く、安全性の高いものを選択す
ることが望ましい。Embedded image F- (CF 2 —CF 2 —CF 2 —O) x —CF 2 —
CF 3 In addition, the surfactant blended for emulsifying perfluoropolyether and for imparting a wiping property, a bactericidal property, and an antistatic property to hair to the liquid medicine is nonion,
Both cationic and amphoteric types may be used. However, it is desirable to select one with low irritation to the skin and high safety.
【００１２】薬液には、上記以外の成分も配合すること
ができる。例えば、メタノール、エタノール等のアルコ
ール類や、グリセリン、プロピレングリコール等のグリ
コール類、パラベン類、塩化ベンゼトニウム、塩化セチ
ルピリジウム等の殺菌剤である。これらのほかにも抗炎
症剤、保湿剤、清涼剤、香料等を目的に応じて配合する
ことができる。Components other than the above may be added to the chemical liquid. For example, alcohols such as methanol and ethanol, glycols such as glycerin and propylene glycol, parabens, benzethonium chloride, cetylpyridinium chloride, and other germicides. In addition to these, an anti-inflammatory agent, a moisturizing agent, a refreshing agent, a fragrance and the like can be added according to the purpose.
【００１３】本発明では、水分を保持可能で柔軟な担体
に薬液を含浸させる。かかる担体とは、レーヨン、コッ
トン、パルプ等の水分を保持可能な親水性繊維を５％以
上含む不織布や耐湿潤性ティッシュペーパー等である。In the present invention, a flexible carrier capable of retaining water is impregnated with a chemical solution. Such a carrier is, for example, a non-woven fabric containing 5% or more of hydrophilic fibers capable of retaining water such as rayon, cotton and pulp, and a wet-resistant tissue paper.
【００１４】不織布やティッシュペーパー等の担体に含
浸させる薬液の重量比率は、担体：薬液＝１：１〜１：
５が好ましい。薬液が少なすぎると、清拭材使用時に薬
液が肌へ移行しないから、充分な清拭効果が得られず、
薬液が多すぎると、拭き取った際に薬液が肌や頭髪に残
り清拭材の使用感がよくないうえに、使用後の清涼感が
乏しくなる。The weight ratio of the chemical solution to be impregnated into the carrier such as the nonwoven fabric or the tissue paper is carrier: chemical solution = 1: 1 to 1:
5 is preferred. If the amount of the chemical solution is too small, the chemical solution does not transfer to the skin when using the cleaning material, so a sufficient cleaning effect cannot be obtained.
If the amount of the liquid medicine is too much, the liquid medicine remains on the skin and hair when wiped off, and the feeling of use of the cleaning material is not good, and the feeling of cooling after use is poor.
【００１５】以下に実施例を挙げて本発明に係る清拭材
を説明する。The cleaning material according to the present invention will be described below with reference to examples.
【実施例１】表１に記載の処法に従って、幼児用ウェッ
トティッシュを製造した。表１におけるエマルジョンベ
ースＡおよびシリコーン・スクワランエマルジョンベー
スの調製は、次のとおりである。 （１）パーフルオロポリエーテルのエマルジョンベースＡの調製法 Ａ相 ポリオキシエチレン（１０）ノニルフェノール ５重量％ （エチレンユニット数＝１０） 精製水 １５重量％ Ｂ相 パーフルオロポリエーテル ３０重量％ （アウジモント社製 ＨＣ−Ｒ） Ｃ相 精製水 ５０重量％ Ａ相を均一溶液とした後、撹拌しながらＢ相を徐々に加
えることによって得たゲルにＣ相を加え、低粘度のエマ
ルジョンベースＡを得た。このエマルジョンの粒径は、
２００ｎｍで安定であった。 （２）シリコーン・スクワランエマルジョンベースの調製法 シリコーンオイル（３５０ｃｓ） １０重量％ スクワラン ３５重量％ ショ糖ステアリン酸モノエステル ５重量％ グリセリン １０重量％ 精製水 ３５重量％ シリコーン、スクワラン、ショ糖エステル、グリセリン
をよく撹拌混合し、精製水を徐々に加えて乳化する。Example 1 A wet tissue for infants was manufactured according to the method described in Table 1. The preparation of emulsion base A and silicone squalane emulsion base in Table 1 is as follows. (1) Method for preparing emulsion base A of perfluoropolyether Phase A polyoxyethylene (10) nonylphenol 5% by weight (number of ethylene units = 10) Purified water 15% by weight Phase B perfluoropolyether 30% by weight (Ausimont Corporation) Manufactured by HC-R) Phase C Purified water 50 wt% Phase A was made into a uniform solution, and phase C was added to the gel obtained by gradually adding phase B with stirring to obtain emulsion base A of low viscosity. . The particle size of this emulsion is
It was stable at 200 nm. (2) Preparation method of silicone-squalane emulsion base Silicone oil (350cs) 10% by weight Squalane 35% by weight Sucrose stearic acid monoester 5% by weight Glycerin 10% by weight Purified water 35% by weight Silicone, squalane, sucrose ester, glycerin Is thoroughly mixed with stirring, and purified water is gradually added to emulsify.
【００１６】[0016]
【表１】 実施例１および比較例１のウェットティッシュを２０名
のゼロ才児を対象にして、１ヶ月間、オムツ交換の際に
母親が使用した。各評価項目について母親が５段階評価
した結果の平均値は以下のとおりであった。なお、点数
の基準は、５：非常に満足，４：やや満足，３：どちら
ともいえない，２：やや不満，１：非常に不満、であ
る。[Table 1] The wet tissues of Example 1 and Comparative Example 1 were used by 20 mothers at the time of exchanging diapers for 20 months, for one month. The average values of the five-level evaluation by the mother for each evaluation item were as follows. The criteria for the score are 5: very satisfied, 4: somewhat satisfied, 3: neither can be said, 2: somewhat dissatisfied, 1: very dissatisfied.
【００１７】 実施例１ 比較例１ 汚れの取れ易さ ５ ４ 便の肌への付きにくさ ４ ３ かぶれの治癒効果 ４ ２ 上記の結果より、本発明に係るパーフルオロポリエーテ
ルのエマルジョンを含浸させたウェットティッシュは、
高い清拭力を持ち、清拭後の肌には汚れ（便）が付きに
くく、かぶれの進行を抑制する機能を有するものである
ことがわかる。Example 1 Comparative Example 1 Ease of Stain Removal 5 4 Difficulty Attaching Feces to the Skin 4 3 Healing Effect on Irritation 4 2 From the above results, the perfluoropolyether emulsion of the present invention was impregnated. Wet tissue
It can be seen that it has a high cleaning power, is less likely to get dirt (stool) on the skin after cleaning, and has a function of suppressing the progress of rash.
【００１８】[0018]
【実施例２】表２に記載の処法に従って、頭髪用ウェッ
トティッシュを製造した。表２におけるエマルジョンベ
ースＢの調製は、次のとおりである。Example 2 A wet tissue for hair was manufactured according to the method described in Table 2. The preparation of emulsion base B in Table 2 is as follows.
【００１９】 パーフルオロポリエーテルのエマルジョンベースＢの調整法 Ａ相 パーフルオロポリエーテル ３０重量％ （アウジモント社製 ＨＣ−０４） Ｂ相 ステアリルトリメチルアンモニウムクロライド ５重量％ グリセリン ５重量％ 精製水 １０重量％ Ｃ相 精製水 ５０重量％ Ｂ相をホモミキサーを用いて８０００ｒｐｍで撹拌しな
がら、Ａ相を徐々に加えてエマルジョンを得た。このエ
マルジョンをＣ相で希釈してエマルジョンベースＢを得
た。エマルジョンベースＢの粒径は、２１５ｎｍであり
安定であった。Preparation method of emulsion base B of perfluoropolyether Phase A Perfluoropolyether 30% by weight (HC-04 manufactured by Ausimont) Phase B Stearyltrimethylammonium chloride 5% by weight Glycerin 5% by weight Purified water 10% by weight C Phase 50% by weight of purified water Phase A was gradually added while stirring Phase B using a homomixer at 8000 rpm to obtain an emulsion. This emulsion was diluted with Phase C to obtain Emulsion Base B. The particle size of emulsion base B was 215 nm, which was stable.
【００２０】[0020]
【表２】 実施例２及び比較例２，３のウェットティッシュを使用
して、２０代から３０代の女性２０名が運動後に頭髪を
拭いた。その後頭髪にタバコの煙を吹きかけたときの状
況を５段階で評価した結果の平均値は、以下のとおりで
あった。なお、点数の基準は、５：非常に満足，４：や
や満足，３：どちらともいえない，２：やや不満，１：
非常に不満、である。[Table 2] Using the wet tissues of Example 2 and Comparative Examples 2 and 3, 20 women in their 20s to 30s wiped their hair after exercise. After that, the average value of the results of evaluation of the situation when cigarette smoke was sprayed on the hair in five levels was as follows. In addition, the standard of the score is 5: very satisfied, 4: somewhat satisfied, 3: neither can be said, 2: somewhat dissatisfied, 1:
Very dissatisfied.
【００２１】 実施例２ 比較例２ 比較例３ サッパリ感がある ４ ４ ４ 頭髪への薬液の残り感がない ４ ４ ４ 頭髪のパサ付き感がない ４ ３ ３ 頭髪の汗の臭いが消える ４ ３ ３ 頭髪へのタバコの臭いの 付きにくさ ４ １ ２ 上記結果のように、本発明に係るパーフルオロポリエー
テルのエマルジョンを含浸したウェットティッシュは、
頭髪の清拭に使用した際に、高い清拭力を持ち、拭き取
り後の頭髪は、臭いが付きにくくなるという効果を奏す
る。Example 2 Comparative Example 2 Comparative Example 3 There is a refreshing feeling 4 4 4 There is no feeling of remaining chemical liquid on the hair 4 4 4 No feeling of dryness on the hair 4 3 3 The smell of sweat on the hair disappears 4 3 3 Difficulty in smelling tobacco on hair 4 1 2 As described above, the wet tissue impregnated with the perfluoropolyether emulsion according to the present invention was
When used for cleaning hair, it has a high cleaning power, and has an effect that the hair after being wiped off is less likely to have an odor.
【００２２】[0022]
【実施例３】表３の処方に従って、身体清拭用ウェット
ティッシュを製造した。このウェットティッシュを、２
０人の老人の身体の清拭に１ヶ月間使用し、使用時の状
況を５段階評価した結果の平均値は、以下のとおりであ
った。なお、点数の基準は、５：非常に満足，４：やや
満足，３：どちらともいえない，２：やや不満，１：非
常に不満、である。Example 3 A wet wipe for body cleaning was produced according to the formulation shown in Table 3. 2 this wet tissue
The average value of the results of five-year evaluation of the state of use after using it for one month to clean the body of 0 elderly people was as follows. The criteria for the score are 5: very satisfied, 4: somewhat satisfied, 3: neither can be said, 2: somewhat dissatisfied, 1: very dissatisfied.
【００２３】 実施例３ 比較例４ サッパリ感がある ５ ５ 保湿性がある ４ ３ 床ずれ、かぶれの治癒効果 ４ ２ 上記結果より、本発明に係るパーフルオロポリエーテル
のエマルジョンを含浸させたウエットティッシュは、清
拭後の肌に対して保湿効果があり、かつかぶれの進行を
抑制する効果を奏することがわかる。Example 3 Comparative Example 4 5 A refreshing feeling 5 5 Moisturizing 4 3 Healing effect on bed sores and rashes 4 2 From the above results, the wet tissue impregnated with the perfluoropolyether emulsion according to the present invention is It can be seen that it has a moisturizing effect on the skin after being wiped and has an effect of suppressing the progress of rash.
【００２４】[0024]
【表３】 [Table 3]
【００２５】[0025]
【発明の効果】本発明に係る清拭材は、顕著な清拭効果
を有し、かつ清拭後の肌や頭髪を汚れや臭いが付着しに
くい状態にすることができる。また、床ずれやかぶれの
進行を抑制し、肌を保護する効果を有する。担体に含浸
させる薬液は、水を連続相とするエマルジョンとしてパ
ーフルオロポリエーテルを含有するから、この清拭材
は、水とパーフルオロポリエーテルそれぞれの清拭効果
を兼ね備えることができる。EFFECT OF THE INVENTION The cleaning material according to the present invention has a remarkable cleaning effect and can make the skin and the hair after cleaning less susceptible to dirt and odor. Further, it has the effect of suppressing the development of bedsores and rashes and protecting the skin. Since the chemical liquid with which the carrier is impregnated contains perfluoropolyether as an emulsion having water as a continuous phase, this cleaning material can have both the cleaning effect of water and the cleaning effect of perfluoropolyether.
Claims (5)
オロポリエーテルのエマルジョンを含浸させてなる湿潤
タイプの清拭材。1. A wet-type wiping material obtained by impregnating a perfluoropolyether emulsion into a flexible carrier that can retain water.
ーテルを０．０１〜１０重量％含有している請求項１記
載の清拭材。2. The cleaning material according to claim 1, wherein the emulsion contains 0.01 to 10% by weight of perfluoropolyether.
２記載の清拭材。3. The cleaning material according to claim 1, wherein the carrier is a non-woven fabric.
請求項１〜３のいずれかに記載の清拭材。4. The cleaning material according to claim 1, wherein the cleaning material is a wet tissue.
のである請求項１〜４のいずれかに記載の清拭材。5. The wiping material according to claim 1, wherein the emulsion has water as a continuous phase.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12508796A JP3183823B2 (en) | 1996-05-20 | 1996-05-20 | Wet type cleaning material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12508796A JP3183823B2 (en) | 1996-05-20 | 1996-05-20 | Wet type cleaning material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH09299271A true JPH09299271A (en) | 1997-11-25 |
| JP3183823B2 JP3183823B2 (en) | 2001-07-09 |
Family
ID=14901522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12508796A Expired - Lifetime JP3183823B2 (en) | 1996-05-20 | 1996-05-20 | Wet type cleaning material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3183823B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002363062A (en) * | 2001-06-01 | 2002-12-18 | Kanebo Ltd | Skin wiping agent composition |
| US7235707B2 (en) | 2002-01-24 | 2007-06-26 | Uni-Charm Corporation | Absorbent article for reducing urine odor |
| US9333151B2 (en) | 2011-04-04 | 2016-05-10 | The Procter & Gamble Company | Home care articles and methods |
| US9554978B2 (en) | 2013-06-27 | 2017-01-31 | The Procter & Gamble Company | Personal care articles |
| US9763547B2 (en) | 2011-08-15 | 2017-09-19 | The Procter & Gamble Company | Personal care articles having multi-zone compliant personal care compositions |
-
1996
- 1996-05-20 JP JP12508796A patent/JP3183823B2/en not_active Expired - Lifetime
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002363062A (en) * | 2001-06-01 | 2002-12-18 | Kanebo Ltd | Skin wiping agent composition |
| US7235707B2 (en) | 2002-01-24 | 2007-06-26 | Uni-Charm Corporation | Absorbent article for reducing urine odor |
| US9333151B2 (en) | 2011-04-04 | 2016-05-10 | The Procter & Gamble Company | Home care articles and methods |
| US9592181B2 (en) | 2011-04-04 | 2017-03-14 | The Procter & Gamble Company | Personal care articles and methods |
| US10335351B2 (en) | 2011-04-04 | 2019-07-02 | The Procter & Gamble Company | Personal care articles and methods |
| US10016098B2 (en) | 2011-08-15 | 2018-07-10 | The Procter & Gamble Company | Personal care articles having multiple zones with compliant personal care compositions |
| US9763547B2 (en) | 2011-08-15 | 2017-09-19 | The Procter & Gamble Company | Personal care articles having multi-zone compliant personal care compositions |
| US10070761B2 (en) | 2011-08-15 | 2018-09-11 | The Procter & Gamble Company | Conformable personal care articles |
| US9554978B2 (en) | 2013-06-27 | 2017-01-31 | The Procter & Gamble Company | Personal care articles |
| US9907738B2 (en) | 2013-06-27 | 2018-03-06 | The Procter & Gamble Company | Personal care compositions and articles |
| US9855203B2 (en) | 2013-06-27 | 2018-01-02 | The Procter & Gamble Company | Preserving personal care compositions |
| US10357441B2 (en) | 2013-06-27 | 2019-07-23 | The Procter & Gamble Company | Personal care articles |
| US11090244B2 (en) | 2013-06-27 | 2021-08-17 | The Procter & Gamble Company | Personal care compositions and articles |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3183823B2 (en) | 2001-07-09 |
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