JPH09280719A - Refrigerator with freezer - Google Patents

Refrigerator with freezer

Info

Publication number
JPH09280719A
JPH09280719A JP8914996A JP8914996A JPH09280719A JP H09280719 A JPH09280719 A JP H09280719A JP 8914996 A JP8914996 A JP 8914996A JP 8914996 A JP8914996 A JP 8914996A JP H09280719 A JPH09280719 A JP H09280719A
Authority
JP
Japan
Prior art keywords
humidity
moisture
storage
refrigerator
freezer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8914996A
Other languages
Japanese (ja)
Inventor
Akiko Enotsu
明子 榎津
Mayumi Kaji
まゆみ 鍛冶
Kuninari Araki
邦成 荒木
Shoichi Kitahata
正一 北畠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP8914996A priority Critical patent/JPH09280719A/en
Publication of JPH09280719A publication Critical patent/JPH09280719A/en
Pending legal-status Critical Current

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  • Cold Air Circulating Systems And Constructional Details In Refrigerators (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a refrigerator with a freezer provided with a high humidity storage chamber, wherein the temperature and humidity in the chamber are controlled to a condition which is suitable for the preservation of food by making use of a radiation-cooling effect of a favorable heat conductive member and a humidity control effect of a humidity absorbing and dissipating member. SOLUTION: In a high humidity storage chamber which adopts an indirect refrigerating system by arranging a vessel cover 13 on a storage vessel D, an opening is formed in a portion thereof. A humidity control member C is replaceably mounted in the opening and such a humidity control member C is made of a hydrophobic film which includes a humidity absorbing and dissipating fiber being compression-molded in a plate-like shape and having minute pores and a plate-like hydrophilic resin. The storage vessel D is made of a member having a favorable thermal conductivity such as a metal plate or a synthetic resin mold which is produced by kneading and molding powdery metal or master batched powdery metal and accordingly is given a favorable thermal conductivity. It may be possible to replaceably mount a vessel which is made of a material having a favorable thermal conductivity within a conventional storage vessel.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は冷凍冷蔵庫に係り、
特に、食品の保存に適した温度,湿度に調整する機能を
持つ貯蔵室を備えた冷凍冷蔵庫に関する。
TECHNICAL FIELD The present invention relates to a refrigerator and a refrigerator,
In particular, the present invention relates to a refrigerator / freezer having a storage room having a function of adjusting temperature and humidity suitable for storing food.

【0002】[0002]

【従来の技術】食品の鮮度保持で、貯蔵温度および湿度
は最も重要な要素であり、貯蔵環境を各食品に応じた温
度,湿度に調整されれば、長期間新鮮さを保持すること
が可能となる。しかし、不特定且つ他品種の食品が保存
される家庭用の冷凍冷蔵庫では、各食品に応じた温湿度
に詳細に調節することは不可能であり、また、低価格化
が望まれる市場の状況で、複雑且つ高コストな装置を備
えた製品は適さない。そこで、従来より家庭用の冷凍冷
蔵庫でも、冷凍室や冷蔵室に加えて、チルド室や野菜室
等の様に大まかな食品の種類毎に、それぞれ適した温度
に保存できる貯蔵室が備えられるようになった。しか
し、貯蔵室内の温度は、扉開閉や冷凍機の除霜等に伴っ
て上昇したり、数個所設置された冷気吹出口による局所
的な冷却では温度分布の不均一性が発生する等、適正な
温度に調整されにくかった。これらに起因する温度変動
は生鮮食品、特に貯蔵中も生命活動を営んでいる青果物
にとっては大きなストレスとなり、呼吸作用を増進させ
水分蒸散を促す等、鮮度低下の要因となる。また、直接
冷却式の貯蔵室では、乾燥した冷気が食品表面に当た
り、乾燥の促進,変色等の鮮度劣化を引き起こすため、
貯蔵容器にカバー等を配し、間接的に冷却することによ
り従来より内部の湿度を高めた貯蔵室も多く見られるよ
うになった。以下、図面に従ってこれら代表的な食品保
存機能について説明する。
2. Description of the Related Art Storage temperature and humidity are the most important factors for maintaining the freshness of foods, and if the storage environment is adjusted to the temperature and humidity according to each food, the freshness can be maintained for a long time. Becomes However, in home-use refrigerator-freezers that store foods of unspecified and other varieties, it is not possible to finely adjust the temperature and humidity according to each food, and the market situation where lower prices are desired Therefore, a product having a complicated and expensive device is not suitable. Therefore, even in the conventional refrigerators and freezers for home use, in addition to the freezing room and the refrigerating room, a storage room capable of storing at a suitable temperature for each rough food type such as a chilled room and a vegetable room is provided. Became. However, the temperature inside the storage room rises due to the opening and closing of the doors, defrosting of the refrigerator, etc., and local cooling by several cold air outlets causes uneven temperature distribution. It was difficult to adjust to a proper temperature. The temperature fluctuation caused by these causes great stress for fresh foods, in particular, fruits and vegetables that are still carrying out vital activities during storage, and promotes respiratory action and promotes water evaporation, which causes a decrease in freshness. In a direct-cooled storage room, dry cold air hits the food surface, which accelerates drying and deteriorates freshness such as discoloration.
By placing a cover or the like on the storage container and indirectly cooling the storage container, it has become possible to see many storage chambers in which the internal humidity is higher than in the past. Hereinafter, these typical food storage functions will be described with reference to the drawings.

【0003】図12は間接冷却方式によって、食品の種類
に応じた氷温貯蔵温度に冷却制御できる複数の区画室を
有する貯蔵庫の断面図である。貯蔵庫の内箱24の内部は
上下三室に区画されており、それぞれにアルミニウム等
の良熱伝導部材で構成された前面開口のケース25,26,
27が組み込まれ、各ケース25,26,27の内部には区画室
28,29,30が形成されている。各ケースにはそれぞれ連
通しない冷気通路31,32,33が設けられ、これらは断熱
箱体背部に上下方向にわたって設けられたダクト部材34
とケースの背面側にて連通しており、ダクト部材34から
冷気が吐出口35,36,37を介して冷気通路31,32,33内
に流入する。また、冷気通路内には吐出口を開閉する冷
気制御手段として電磁ダンパ38,39,40を配し、区画室
28,29,30内には温度検出装置41,42,43を設置して内
部の温度を制御している。温度はそれぞれの食品の種類
に対応する氷温貯蔵温度に制御され、また間接冷却方式
により高湿度を保持して、食品の保存性を高めている。
FIG. 12 is a cross-sectional view of a storage having a plurality of compartments which can be cooled and controlled to an ice temperature storage temperature according to the type of food by an indirect cooling system. The inside of the inner box 24 of the storage is divided into upper and lower three chambers, and cases 25, 26 with front openings each made of a good heat conducting member such as aluminum are provided.
27 is built in, and each compartment 25, 26, 27 has a compartment inside
28, 29, 30 are formed. Each case is provided with cold air passages 31, 32, and 33 that do not communicate with each other, and these are duct members 34 provided on the back of the heat insulating box body in the vertical direction.
And the cool air flows from the duct member 34 into the cool air passages 31, 32, 33 through the discharge ports 35, 36, 37. In addition, electromagnetic dampers 38, 39, 40 are provided as cold air control means for opening and closing the discharge port in the cold air passage,
Temperature detectors 41, 42 and 43 are installed in 28, 29 and 30 to control the internal temperature. The temperature is controlled to the ice temperature storage temperature corresponding to each type of food, and the indirect cooling system keeps high humidity to improve the storability of food.

【0004】一方、図13は貯蔵室内の湿度を調整する機
能を持つ、高湿チルド室の断面図である。44は貯蔵容器
であり、45は食品の水分蒸散を抑制するために設置され
た容器カバーであり、46は容器カバー内側に付着する結
露水を処理するために設けた調湿シートである。また47
は食品間で生ずる臭移りを処理するために設けた脱臭フ
ィルタであり、これらの機構により食品をラップ等の包
装なしで保存することが出来る。
On the other hand, FIG. 13 is a sectional view of a high-humidity chilled chamber having a function of adjusting the humidity in the storage chamber. Reference numeral 44 is a storage container, 45 is a container cover installed to suppress water evaporation of food, and 46 is a humidity control sheet provided to treat condensed water adhering to the inside of the container cover. Again 47
Is a deodorizing filter provided for treating odor transfer generated between foods, and these mechanisms allow foods to be stored without wrapping.

【0005】なお、この種の冷凍冷蔵庫に関連する技術
例は、例えば、図12に関しては特開平7−198242
号公報、図13に関しては特開平6−213556号公報
が挙げられる。
A technical example related to this type of refrigerator-freezer is disclosed in, for example, Japanese Unexamined Patent Publication No. 7-198242 in FIG.
Japanese Patent Application Laid-Open No. 6-213556 can be cited for the publication and FIG.

【0006】[0006]

【発明が解決しようとする課題】上記従来の調整機構で
は、以下のような問題があった。すなわち、図12を用い
て従来の問題点を説明する。貯蔵庫の内箱24の内部を上
下三つに区画して、それぞれにアルミニウム等の良熱伝
導部材で構成した前面開口のケース25,26,27を組み込
み、各ケース内部に形成した区画室28,29,30を、ケー
ス周囲にそれぞれ独立した冷気通路を配して間接冷却を
行うことにより、温度変化の幅を小さくし、且つ高湿度
の状態を維持できる機構であるが、ケース内は負荷自身
の水分蒸散を利用して高湿度化しているため、負荷少量
時にはケース内の水分が不足して湿度が低下する一方、
負荷多量時には湿度過多となり、余分な水分は天井面等
に結露して負荷の表面に滴下し、腐敗を招く可能性があ
る。また、貯蔵室の外側にアルミニウム等の良熱伝導部
材で形成したケースを配することにより、温度変動幅を
小さくすることができるが、冷気吐出口近くの温度が低
下して内部の温度分布は必ずしも均一にはならない。温
度分布が均一化されないと、貯蔵室の密閉性を高めて高
湿度化しても内部で対流が生じ、この空気の移動によっ
て負荷食品の水分蒸散が促進される等、食品の鮮度を低
下させる要因にもなる。また、ケース毎に冷気通路を配
し、冷気吐出口を開閉する冷気制御手段と温度検出装置
を備えることにより、各食品に応じたより精密な温度制
が可能となるが、不特定且つ他品種の食品が収納される
家庭用の冷凍冷蔵庫では、各々の食品に対応する温度制
御は困難であり、また複雑且つ高コストな制御機構は製
品の高価格化をもたらすため、より簡便で安価な構成が
望まれる。
The above-mentioned conventional adjusting mechanism has the following problems. That is, conventional problems will be described with reference to FIG. The inner box 24 of the storage compartment is divided into three upper and lower parts, and cases 25, 26, 27 having front openings made of a good heat conductive material such as aluminum are incorporated into each compartment, and compartments 28 formed inside each case. Independent cooling air passages are installed around the cases 29 and 30 for indirect cooling, which reduces the range of temperature change and maintains a high humidity condition. Since the humidity is increased by using the moisture evaporation of the, the moisture in the case is insufficient and the humidity decreases when the load is small,
When the load is large, the humidity becomes excessive, and excess water may condense on the ceiling surface and drop on the surface of the load, causing spoilage. Also, by arranging a case made of a good heat conductive material such as aluminum outside the storage chamber, the temperature fluctuation range can be reduced, but the temperature near the cool air discharge port decreases and the internal temperature distribution becomes Not necessarily uniform. If the temperature distribution is not uniform, internal convection will occur even if the storage chamber is highly airtight and the humidity is high, and this movement of air accelerates the evaporation of water from the food load, which is a factor that reduces the freshness of the food. It also becomes. Also, by providing a cool air passage for each case and providing a cool air control means for opening and closing the cool air discharge port and a temperature detecting device, more precise temperature control according to each food is possible, but unspecified and of other types In a home-use refrigerator / freezer in which food is stored, it is difficult to control the temperature corresponding to each food, and a complicated and high-cost control mechanism leads to high prices of products, so a simpler and cheaper configuration is required. desired.

【0007】一方、図13は貯蔵容器44に食品が水分蒸散
により乾燥劣化をするのを防ぐ容器カバー45を設置して
室内の湿度を保つ、間接冷却方式を採用している。容器
カバー45の上面には特に温度の低い冷気が通過して局部
的に冷却されるため、貯蔵室内の水蒸気が容器カバー45
の下面に凝縮して結露水となり付着するが、これを処理
するために容器カバー45の冷気通過面の一部に開口部を
設け、親水性処理を施した樹脂を多孔質状に板状成形し
て吸水性を付与した調湿シート46を設置している。調湿
シート46は結露した水分を吸水し、飽和すると保持して
いた水分を貯蔵室内に蒸散して湿度をコントロールす
る。しかし、負荷少量時には貯蔵室内側よりも、乾燥し
た冷気が通過する貯蔵室外側に水分が蒸散し、室内側を
適正な湿度に保つことが困難である。
On the other hand, FIG. 13 employs an indirect cooling system in which a storage container 44 is provided with a container cover 45 for preventing the food from being dried and deteriorated due to evaporation of water to keep indoor humidity. Particularly, cold air having a low temperature passes through the upper surface of the container cover 45 and is locally cooled.
Condensate as dew condensation water on the bottom surface of the container and attach to it, but in order to treat this, an opening is provided in a part of the cold air passage surface of the container cover 45, and the resin that has been subjected to the hydrophilic treatment is formed into a porous plate shape. A moisture conditioning sheet 46 having water absorption property is installed. The humidity control sheet 46 absorbs the condensed moisture, and when saturated, the retained moisture is evaporated into the storage chamber to control the humidity. However, when the load is small, the water evaporates to the outside of the storage chamber through which the dry cold air passes, rather than to the inside of the storage chamber, and it is difficult to maintain an appropriate humidity inside the storage chamber.

【0008】本発明の目的は、温度変動,温度分布の不
均一性を解消し、負荷量に伴う湿度変動を抑制して、貯
蔵室内を食品の保存に適した温湿度に調整する機能を備
え、鮮度保持性を高めた冷凍冷蔵庫を提供することにあ
る。
An object of the present invention is to eliminate the temperature fluctuation and the non-uniformity of the temperature distribution, suppress the humidity fluctuation associated with the load amount, and have a function of adjusting the temperature and humidity in the storage chamber to a temperature and humidity suitable for storing food. , It is to provide a freezer-refrigerator with improved freshness retention.

【0009】[0009]

【課題を解決するための手段】本発明は、貯蔵室全体あ
るいはその一部を良熱伝導部材で形成し、特に貯蔵容器
と容器カバーからなる間接冷却方式の高湿貯蔵室では、
内部に調湿部材を設置することにより、貯蔵室内を食品
の保存に適した温湿度に調整し、鮮度保持性を高めた。
すなわち、貯蔵容器もしくは容器カバーを金属素材、あ
るいは金属粉末を練り込んで良熱伝導性を付与したプラ
スチック材等、良熱伝導部材で形成することにより、良
熱伝導部材の輻射冷却効果で、扉開閉や除霜に伴う温度
変動や貯蔵室内の温度分布の不均一性を解消し、負荷の
品温を一定化して食品に与える温度ストレスを軽減し、
また板状に圧縮成形して剛性を付与した吸放湿性繊維を
貯蔵室の内側に設置することによって、負荷多量時、あ
るいは扉開閉により外部の暖気が低温の貯蔵室内に流入
する等、室内湿度が必要以上に上昇した場合には、余分
な水蒸気を吸湿することによって結露の発生を防ぎ、貯
蔵室内が一定湿度以上のときには内部に水分を保持し、
負荷少量時、あるいは水分含有量の少ない食品が負荷と
して収納される等、室内湿度が低下した場合には、保持
していた水分を蒸散させて室内を食品の保存に適した湿
度に調整するものである。また、この吸放湿性繊維の片
面には微小な細孔を有する疎水性フィルムを貼着して、
吸放湿性繊維に吸水,保持された水分が貯蔵室外側に過
剰に蒸散するのを防ぎ、またその上部に一定の空間を設
けて板状の親水性樹脂を設置することにより、余分な水
分を貯蔵室外に排出する機構とした。このメカニズムの
詳細を説明する。板状の親水性樹脂を、吸放湿性繊維が
保持可能な水分量をオーバーすると吸湿,吸水により膨
張して接触するような位置に配し、吸放湿性繊維が板状
親水性樹脂に接触すると内部の水分が疎水性フィルムの
細孔を介して親水性樹脂に吸水され、これが親水性樹脂
上面を通過する冷気に蒸散することにより、余分な水分
が室外に排出される。また親水性樹脂は、ポリエチレン
等の樹脂の表面を親水性の素材でコーティングして多孔
質状に成形したものであり、表面に水滴が接触すると毛
細管現象を生じて内部に浸透し、吸水可能な容量を超え
ると水分を低湿側に蒸散させる性質を持つ。したがっ
て、貯蔵室の一部に開口部を設け、吸放湿性繊維をフィ
ルム側が室外に面するように設置し、その上部に一定の
空間を設けて板状の親水性樹脂を配することにより、吸
放湿性繊維の吸水量が保持可能な容量以下の場合には、
室内側に水分を蒸散させて内部の湿度を調整し、吸放湿
性繊維の吸水量が保持可能な容量を超えた場合には膨張
した吸放湿性繊維が親水性樹脂に接触し、内部の水分を
疎水性フィルムの細孔を介して親水性樹脂に吸水させ、
上面を通過する冷気に蒸散させるため、調湿部材で吸水
しきれない水分が負荷等に滴下することなく、食品の保
存に適した環境を創出できる。更に、親水性樹脂表面を
抗菌剤で処理し、吸放湿性繊維を抗菌剤で表面処理する
あるいは吸放湿性繊維に抗菌剤を練り込むことにより、
安全性,衛生性をより向上することができる。このよう
に、貯蔵室に上述の機構を配することにより、簡便且つ
安価な構成で食品の保存に最適な温湿度環境が創出でき
る。
According to the present invention, the whole or a part of the storage chamber is formed of a good heat conducting member, and particularly in a high humidity storage chamber of an indirect cooling type comprising a storage container and a container cover,
By installing a humidity control member inside, the temperature and humidity inside the storage room were adjusted to be suitable for food preservation, and the freshness retention was enhanced.
That is, by forming the storage container or the container cover with a good heat conducting member such as a metal material or a plastic material in which metal powder is kneaded to impart good heat conducting property, the radiation cooling effect of the good heat conducting member allows the door to be closed. Eliminates temperature fluctuations due to opening and closing and defrosting and non-uniformity of temperature distribution in the storage room, stabilizes the product temperature of the load and reduces temperature stress on food,
In addition, by installing moisture absorbing / releasing fibers that have been compressed into a plate shape and added rigidity to the inside of the storage room, the indoor humidity such as when the load is large or the outside warm air flows into the low temperature storage room due to the opening and closing of the door, etc. If the temperature rises more than necessary, the condensation of moisture is prevented by absorbing excess water vapor, and when the storage room has a certain humidity or higher, it retains moisture inside,
When the indoor humidity drops, such as when the load is small or when food with a low water content is stored as a load, the retained water is evaporated to adjust the room to a humidity suitable for storing food. Is. Also, a hydrophobic film having fine pores is attached to one surface of the moisture absorptive and desorptive fiber,
Moisture-absorbing and desorbing fibers prevent water from being excessively evaporated to the outside of the storage chamber, and by installing a plate-like hydrophilic resin with a certain space above it, excess water can be removed. A mechanism was adopted for discharging to the outside of the storage room. The details of this mechanism will be described. The plate-shaped hydrophilic resin is placed at a position where it expands and contacts due to moisture absorption and water absorption when the amount of water that the moisture-absorbing and desorbing fiber can hold exceeds, and when the moisture-absorbing and desorbing fiber contacts the plate-shaped hydrophilic resin. The water content inside is absorbed by the hydrophilic resin through the pores of the hydrophobic film, and this water is evaporated to cool air passing through the upper surface of the hydrophilic resin, whereby excess water is discharged to the outside of the room. The hydrophilic resin is a resin formed by coating the surface of a resin such as polyethylene with a hydrophilic material to form a porous material. When a water droplet comes into contact with the surface, it causes a capillary phenomenon to penetrate into the interior and absorb water. When it exceeds the capacity, it has the property of evaporating water to the low humidity side. Therefore, by providing an opening in a part of the storage chamber, the moisture-absorbing and desorbing fiber is installed so that the film side faces the outside of the room, and by arranging a plate-shaped hydrophilic resin with a certain space provided above it, When the water absorption of the moisture absorptive and desorptive fiber is less than the capacity that can be retained,
When moisture is evaporated to the indoor side and the internal humidity is adjusted, if the water absorption capacity of the moisture absorptive and desorptive fibers exceeds the capacity that can be maintained, the expanded moisture absorptive and desorptive fibers come into contact with the hydrophilic resin and the internal moisture Makes the hydrophilic resin absorb water through the pores of the hydrophobic film,
Since the cool air that passes through the upper surface is evaporated, moisture that cannot be absorbed by the humidity control member does not drip into the load, and an environment suitable for storing food can be created. Furthermore, by treating the surface of the hydrophilic resin with an antibacterial agent and surface-treating the moisture absorbing / releasing fiber with the antibacterial agent, or by kneading the antibacterial agent into the moisture absorbing / releasing fiber,
Safety and hygiene can be further improved. As described above, by arranging the above-mentioned mechanism in the storage room, it is possible to create a temperature and humidity environment most suitable for the preservation of food with a simple and inexpensive structure.

【0010】[0010]

【発明の実施の形態】以下本発明の一実施例を図面に基
づき説明する。
BEST MODE FOR CARRYING OUT THE INVENTION An embodiment of the present invention will be described below with reference to the drawings.

【0011】〈実施例1〉図1は貯蔵容器に容器カバー
を配して密閉性を高め、間接冷却方式を採ることにより
内部の湿度を高める高湿貯蔵室を備えた冷凍冷蔵庫の断
面図である。図中、1は冷凍冷蔵庫、2は冷凍室、4は
冷蔵室、3は冷凍室扉、5は冷蔵室扉である。6は冷気
循環用のファンであり、7はファンを駆動するモータ、
8はエバポレータである。Aは高湿チルド室、Bは高湿
野菜室、9はチルド室Aの扉、10は野菜室Bの扉であ
り、11はコンプレッサである。
<Embodiment 1> FIG. 1 is a sectional view of a freezer-refrigerator provided with a high-humidity storage chamber in which a container cover is arranged in a storage container to enhance the airtightness and an internal cooling system is used to increase the internal humidity. is there. In the figure, 1 is a refrigerator / freezer, 2 is a freezer compartment, 4 is a refrigerator compartment, 3 is a refrigerator compartment door, and 5 is a refrigerator compartment door. 6 is a fan for circulating cold air, 7 is a motor for driving the fan,
8 is an evaporator. A is a high humidity chilled room, B is a high humidity vegetable room, 9 is a door of the chilled room A, 10 is a door of the vegetable room B, and 11 is a compressor.

【0012】図2は、図1の高湿チルド室Aの断面図で
ある。12は貯蔵室の密閉性を高め、間接冷却するために
配した容器カバーであり、C部は高湿チルド室A内に設
置した調湿部材である。調湿部材Cは、容器カバー12の
一部に配した開口部にリブを設け、着脱自在に設置され
ているが、貯蔵室内の如何なる部分に同様な構成で設置
しても良い。また、Dは良熱伝導部材からなる貯蔵容器
である。
FIG. 2 is a sectional view of the high humidity chilled chamber A of FIG. Reference numeral 12 is a container cover arranged to enhance the airtightness of the storage chamber and indirectly cool the storage chamber, and C is a humidity control member installed in the high humidity chilled chamber A. The humidity control member C is detachably installed by providing a rib in an opening provided in a part of the container cover 12, but it may be installed in any portion in the storage chamber with a similar configuration. Further, D is a storage container made of a good heat conducting member.

【0013】図3は、図1の高湿野菜室Bの断面図であ
る。13は貯蔵室の密閉性を高め、間接冷却するために配
した容器カバーであり、C部は高湿野菜室B内に設置し
た調湿部材である。C部は図2と同様、貯蔵室内の如何
なる部分に開口部及びリブを設けて設置しても良い。ま
た、Dは良熱伝導部材からなる貯蔵容器である。
FIG. 3 is a sectional view of the high humidity vegetable compartment B of FIG. Reference numeral 13 is a container cover arranged to enhance the airtightness of the storage compartment and indirectly cool it, and C is a humidity control member installed in the high humidity vegetable compartment B. Similar to FIG. 2, the portion C may be installed by providing an opening and a rib at any portion in the storage chamber. Further, D is a storage container made of a good heat conducting member.

【0014】図4は図2,図3における調湿部材Cの断
面図である。14は調湿部材Cの基材となる吸放湿性繊維
であり、量産における組立て性,取り扱い性等を考慮し
て、これを板状に圧縮成形することにより剛性を付与し
ている。この吸放湿性繊維14に使用する素材としては、
架橋ポリアクリル酸ソーダや酢酸ビニル系の共重合ケン
化物からなる吸放湿性樹脂を繊維化したもの等が挙げら
れる。貯蔵室内部に吸放湿性繊維14を設置することによ
り、負荷多量時、あるいは扉開閉により外部の暖気が低
温の貯蔵室内に流入した場合等には、室内の余分な水分
を吸湿することによって結露の発生を防ぎ、貯蔵室内が
一定湿度以上のときには内部に水分を保持し、負荷少量
時、あるいは水分含有量の少ない食品が負荷として収納
される等、室内湿度が低下した場合には、保持した水分
を蒸散させて室内を食品の保存に適した湿度に調整する
ことができる。更に吸放湿性繊維14の内部に保持した水
分を貯蔵室外側に蒸散するのを防ぐために、微小な細孔
を有するポリエチレンあるいはポリビニルアルコール
等、疎水性の樹脂からなるフィルム15を貼着し、更にそ
の上部に一定の空間を設けて、表面を親水処理したポリ
エチレン等の樹脂からなる親水性樹脂板16を設置して、
調湿部材Cを構成している。この調湿機能の詳細を説明
する。図4(a)は調湿部材Cの初期状態を示してお
り、吸放湿性繊維14が吸水し膨張すると図4(b)のよ
うに親水性樹脂16に接触して、余分な水分が疎水性フィ
ルム15の細孔を介して親水性樹脂16に吸水され、親水性
樹脂16の表面を通過する冷気に蒸散する。上述のような
機構で調湿部材C内部の水分が調整されるため、吸水し
きれない水分が負荷等に滴下するのを防ぐことができ
る。更に、親水性樹脂16表面を抗菌剤で処理し、吸放湿
性繊維14を抗菌剤で表面処理するあるいは繊維に抗菌剤
を練り込むことにより、安全衛生性がより向上される。
FIG. 4 is a sectional view of the humidity control member C shown in FIGS. Reference numeral 14 denotes a moisture absorbing / releasing fiber which is a base material of the humidity control member C, and the rigidity is imparted by compression-molding the fiber into a plate shape in consideration of the assembling property and the handling property in mass production. As the material used for the moisture absorptive and desorptive fiber 14,
Examples include fibers of a hygroscopic resin made of a crosslinked sodium polyacrylate or a saponified vinyl acetate copolymer. By installing the moisture absorbing / releasing fiber 14 inside the storage chamber, when a large amount of load is applied or when outside warm air flows into the low temperature storage chamber due to opening and closing of the door, dew condensation occurs by absorbing excess moisture in the room. It keeps moisture inside the storage room when the humidity is above a certain level, and keeps it when the room humidity drops, such as when the load is small or food with a low water content is stored as a load. It is possible to evaporate water to adjust the humidity in the room to a level suitable for storing food. Furthermore, in order to prevent the moisture retained inside the moisture absorptive and desorptive fiber 14 from being evaporated to the outside of the storage chamber, a film 15 made of a hydrophobic resin such as polyethylene or polyvinyl alcohol having fine pores is attached, and A certain space is provided above it, and a hydrophilic resin plate 16 made of a resin such as polyethylene whose surface is hydrophilically treated is installed,
The humidity control member C is configured. The details of the humidity control function will be described. FIG. 4A shows the initial state of the humidity control member C. When the moisture absorptive and desorptive fiber 14 absorbs water and expands, it comes into contact with the hydrophilic resin 16 as shown in FIG. The hydrophilic resin 16 absorbs water through the pores of the hydrophilic film 15 and evaporates cold air passing through the surface of the hydrophilic resin 16. Since the moisture inside the humidity control member C is adjusted by the mechanism as described above, it is possible to prevent the moisture that cannot be absorbed completely from dripping on the load or the like. Further, the surface of the hydrophilic resin 16 is treated with an antibacterial agent, the moisture absorbing / releasing fiber 14 is surface treated with an antibacterial agent, or the antibacterial agent is kneaded into the fiber, whereby safety and hygiene is further improved.

【0015】図5は調湿部材Cを構成する、片面に疎水
性フィルム15を貼着した吸放湿性繊維14の斜視図であ
る。疎水性フィルム15には微細孔17が配されているが、
吸放湿性繊維14内部に保持した水分を室外側に過剰に放
湿させないよう、微細孔17の直径は10〜100μm程度に
設定するのが適当である。
FIG. 5 is a perspective view of the moisture absorptive and desorptive fiber 14 which constitutes the humidity control member C and has a hydrophobic film 15 attached to one surface thereof. Microscopic holes 17 are arranged in the hydrophobic film 15,
It is appropriate that the diameter of the fine holes 17 is set to about 10 to 100 μm so that the moisture retained inside the moisture absorptive and desorptive fiber 14 is not excessively discharged to the outside of the room.

【0016】図6は、図2,図3に記載の貯蔵容器Dの
断面図である。18はアルマイト,ステンレス等の良熱伝
導部材で形成した貯蔵容器であり、良熱伝導部材による
輻射冷却効果で貯蔵室内の温度変動を抑え、温度分布を
均一化して負荷する食品の品温を一定に保つことがで
き、また内部温度の不均一性により生じる室内空気の対
流等、負荷の水分蒸散を促進する要因を排除することが
できる。更に、上述の調湿部材Cによる湿度調整の効果
も相俟って、食品の保存性が著しく向上する。
FIG. 6 is a sectional view of the storage container D shown in FIGS. 18 is a storage container made of a good heat conducting material such as alumite, stainless steel, etc., which suppresses temperature fluctuations in the storage chamber by the radiation cooling effect of the good heat conducting material, makes the temperature distribution uniform, and keeps the temperature of the food product loaded constant. In addition, it is possible to eliminate the factors that promote moisture evaporation of the load, such as convection of indoor air caused by the nonuniformity of the internal temperature. In addition, the effect of the humidity adjustment by the humidity control member C is also combined, and the storability of food is significantly improved.

【0017】図7は、図6記載のアルマイト,ステンレ
ス等の良熱伝導部材で形成した貯蔵容器18を設置する代
わりに、19に示す金属粉末、あるいはこれをマスターバ
ッチ化したものをポリプロピレン,ABS樹脂等の合成
樹脂20に練り込むことにより、良熱導性を付与した貯蔵
容器の断面図である。図6のようにアルマイト,ステン
レス等の金属素材を使用した場合と比較して、低コス
ト、且つ軽量に容器を形成することができ、取り扱い性
等の向上を図ることができる。
In FIG. 7, instead of installing the storage container 18 formed of a good heat conductive material such as alumite or stainless steel as shown in FIG. 6, metal powder 19 or a masterbatch of this powder is polypropylene or ABS. FIG. 3 is a cross-sectional view of a storage container having good heat conductivity by being kneaded into a synthetic resin 20 such as a resin. Compared with the case where a metal material such as alumite or stainless steel is used as shown in FIG. 6, the container can be formed at low cost and light weight, and the handleability and the like can be improved.

【0018】図8は、図6,図7記載の熱良導部材で形
成した貯蔵容器を使用する代わりに、ポリプロピレン,
ABS樹脂等の合成樹脂20からなる貯蔵容器本体の内側
に、アルマイト,ステンレス等の良熱伝導部材で形成し
た良熱伝導性容器21を着脱自在に設置したものである。
良熱伝導性容器21は必ずしも図8に示したような五面体
である必要はなく、五面以下の容器を用いても良い。ま
た良熱伝導性容器21は、貯蔵室からの出し入れがしやす
いトレー形状にすることにより、清掃性,収納性等のユ
ーザーの取扱性を向上することができる。
FIG. 8 shows polypropylene instead of the storage container formed of the heat conducting member shown in FIGS.
A good heat conductive container 21 formed of a good heat conductive member such as alumite or stainless steel is detachably installed inside a storage container body made of a synthetic resin 20 such as ABS resin.
The good heat conductive container 21 does not necessarily have to be a pentahedron as shown in FIG. 8, and a container having five or less faces may be used. Further, the good thermal conductive container 21 has a tray shape that can be easily taken in and out from the storage chamber, so that the user's handleability such as cleanability and storability can be improved.

【0019】図9は、図2,図3に記載の容器カバー1
2,13の代わりに、良熱伝導部材で形成した容器カバー2
2を設置した貯蔵室の断面図である。良熱伝導部材で形
成した容器カバー22にも図2,図3に記載の容器カバー
12,13と同様に一部の開口部とリブを設け、調湿部材C
を着脱自在に設置することにより、同等の鮮度保持効果
が得られる。
FIG. 9 shows the container cover 1 shown in FIGS.
Container cover 2 made of good heat conductive material instead of 2 and 13
FIG. 3 is a sectional view of a storage room in which 2 is installed. The container cover 22 made of a good heat conductive material is also used for the container cover 22 shown in FIGS.
Similar to 12 and 13, some openings and ribs are provided, and the humidity control member C
The same freshness-retaining effect can be obtained by detachably installing.

【0020】図10は、図3に記載の高湿野菜室Bと比較
例として従来の野菜室に、水分蒸散により鮮度が低下し
やすい青果物を収納して行った保存試験の結果を示した
ものである。供試品の代表例として、アスパラガス,ブ
ロッコリーを14日間貯蔵した際の水分減少率の推移を表
すグラフをそれぞれ図10(a),図10(b)に示す。い
ずれの図でも実験1は本実施例、実験2は比較例を示
す。
FIG. 10 shows the results of a preservation test conducted by storing fruits and vegetables whose freshness is likely to decrease due to moisture evaporation in a high humidity vegetable compartment B shown in FIG. 3 and a conventional vegetable compartment as a comparative example. Is. As a typical example of the sample, asparagus and broccoli are shown in FIGS. 10 (a) and 10 (b), respectively, which are graphs showing changes in water reduction rate when stored for 14 days. In both figures, Experiment 1 shows the present Example and Experiment 2 shows the Comparative Example.

【0021】図10に図示のように、アスパラガス,ブロ
ッコリーともに、水分減少率は1/5以下に抑えられ、
新鮮さを保つことができる。
As shown in FIG. 10, the water loss rate of both asparagus and broccoli was suppressed to 1/5 or less,
You can keep it fresh.

【0022】〈実施例2〉図11は、直接冷却方式の貯蔵
室内壁を良熱伝導部材で構成した冷凍冷蔵庫の断面図で
ある。貯蔵室内部を高湿度化する機構は備えていない
が、貯蔵室内壁23を良熱伝導部材で構成することによ
り、内部の温度変動を抑制し、温度分布を均一化して、
温度ストレスによる食品の劣化を防ぎ、保存性を高める
ことが可能となる。
<Embodiment 2> FIG. 11 is a sectional view of a freezer-refrigerator in which the inner wall of the storage chamber of the direct cooling system is formed of a good heat conducting member. Although there is no mechanism for increasing the humidity inside the storage chamber, by configuring the storage chamber inner wall 23 with a good heat conducting member, the internal temperature fluctuation is suppressed and the temperature distribution is made uniform.
It is possible to prevent the food from deteriorating due to temperature stress and to improve the shelf life.

【0023】[0023]

【発明の効果】本発明によれば、貯蔵室、特に貯蔵容器
と容器カバーから構成され、密閉性を高めた高湿貯蔵室
の貯蔵容器を良熱伝導部材で形成することにより、良熱
伝導部材の輻射冷却効果で扉開閉や除霜に伴う温度変動
を抑え、貯蔵室内の温度分布を均一化することにより、
食品に与える温度ストレスを軽減して食品の保存性を高
めるばかりでなく、内部温度の不均一性により生じる空
気の移動により、負荷の水分蒸散を促進する現象を防ぐ
こともできる。更に吸放湿性の繊維を板状に成形した材
料を貯蔵室内に設置することにより、負荷多量時、ある
いは扉開閉により外部の暖気が低温の貯蔵室内に流入し
た場合等には、室内の余分な水分を吸湿することによっ
て結露の発生を防ぎ、貯蔵室内が一定湿度以上のときに
は内部に水分を保持し、負荷少量時等、室内湿度が低下
する場合には、保持していた水分を蒸散して室内を食品
の保存に適した湿度に調整することができる。また、吸
放湿性繊維の片面に微小な細孔を有する疎水性フィルム
を貼着し、その上部に一定の空間を設けて板状の親水性
樹脂を設置し、吸放湿性繊維が保持可能な吸水量を超え
ると吸湿,吸水により膨張して親水性樹脂に接触し、余
分な水分を疎水性フィルムの細孔を介して親水性樹脂に
吸水させ、親水性樹脂上面を通過する冷気に蒸散させる
ことにより、吸水しきれない水分が負荷等に滴下するの
を防ぐことができる。更に、これら構成部材に抗菌処理
を施すことにより、安全性,衛生性がより向上される。
上記のような簡便且つ安価な構成で、食品保存に適した
温湿度環境を創出することができ、その結果、負荷食品
の水分減少率は従来の約1/5以下に抑えられ、更に安
全衛生面も配慮したことにより、長期にわたる保存が可
能となり、鮮度保持性が著しく高められる。
According to the present invention, good heat conduction is achieved by forming a storage chamber, particularly a storage container of a high humidity storage chamber which is composed of a storage container and a container cover, and which has an improved airtightness, with a good heat conduction member. By suppressing the temperature fluctuations due to door opening and closing and defrosting by the radiation cooling effect of the members, and by making the temperature distribution in the storage room uniform,
Not only can the temperature stress on the food be reduced to improve the storability of the food, but it is also possible to prevent the phenomenon of promoting moisture evaporation of the load due to the movement of air caused by the nonuniformity of the internal temperature. Furthermore, by installing a material formed by absorbing and desorbing fibers into a plate shape in the storage room, it is possible to prevent excess space in the room when a large amount of load is applied or when outside warm air flows into the low temperature storage room due to opening and closing of the door. It prevents the occurrence of dew condensation by absorbing moisture, retains moisture inside the storage chamber when the humidity is above a certain level, and evaporates the retained moisture when the indoor humidity decreases, such as when the load is small. The humidity inside the room can be adjusted to be suitable for food storage. In addition, a hydrophobic film having fine pores is attached to one surface of the moisture absorptive and desorptive fiber, and a plate-like hydrophilic resin is provided with a certain space above it to allow the moisture absorptive and desorptive fiber to be held. When it exceeds the water absorption amount, it swells due to moisture absorption and water absorption and comes into contact with the hydrophilic resin, causing excess water to be absorbed by the hydrophilic resin through the pores of the hydrophobic film and dissipating cool air passing through the upper surface of the hydrophilic resin. As a result, it is possible to prevent water that cannot be absorbed completely from dripping on the load or the like. Further, by applying an antibacterial treatment to these constituent members, safety and hygiene are further improved.
With the above-mentioned simple and inexpensive structure, it is possible to create a temperature and humidity environment suitable for food storage, and as a result, the moisture reduction rate of loaded foods can be suppressed to about 1/5 or less of the conventional one, and health and safety are further improved. With consideration given to the aspect, it can be stored for a long period of time, and the freshness-keeping property is remarkably improved.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例となる高湿貯蔵室を設置した
冷凍冷蔵庫の断面図。
FIG. 1 is a cross-sectional view of a refrigerator having a high-humidity storage chamber according to an embodiment of the present invention.

【図2】同じく良熱伝導部材から構成される貯蔵容器と
調湿部材を備えた高湿チルド室の断面図。
FIG. 2 is a sectional view of a high-humidity chilled chamber including a storage container and a humidity control member, which are also made of a good heat conductive member.

【図3】同じく良熱導部材から構成される貯蔵容器と調
湿部材を備えた高湿野菜室の断面図。
FIG. 3 is a cross-sectional view of a high-humidity vegetable compartment equipped with a storage container and a humidity control member which are also made of a good heat conducting member.

【図4】同じく板状に圧縮成形した吸放湿性繊維と微細
孔を有する疎水性フィルム、板状親水性樹脂から構成さ
れる調湿部材の断面図。
FIG. 4 is a cross-sectional view of a humidity control member which is also composed of a moisture absorbing / releasing fiber compression-molded into a plate shape, a hydrophobic film having fine pores, and a plate-like hydrophilic resin.

【図5】同じく調湿部材を構成する片面に微細孔を有す
る疎水性フィルムを貼着した吸放湿性繊維の斜視図。
FIG. 5 is a perspective view of a moisture absorptive and desorptive fiber having a hydrophobic film having fine pores attached to one side thereof which also constitutes the humidity control member.

【図6】同じく金属等の良熱伝導部材で形成した貯蔵容
器の断面図。
FIG. 6 is a sectional view of a storage container which is also formed of a good heat conducting member such as metal.

【図7】同じく金属粉末あるいはこれをマスターバッチ
化して合成樹脂に練り込むことにより良熱伝導性を付与
した合成樹脂等の部材で形成する貯蔵容器の断面図。
FIG. 7 is a cross-sectional view of a storage container formed of a metal powder or a member such as a synthetic resin to which good heat conductivity is imparted by kneading the metal powder into a master batch and kneading the same into a synthetic resin.

【図8】同じく合成樹脂で形成された貯蔵容器に金属等
の良熱伝導部材で形成された容器を着脱自在に設置した
貯蔵容器の断面図。
FIG. 8 is a sectional view of a storage container in which a container formed of a good heat conductive member such as metal is detachably installed in the storage container also formed of synthetic resin.

【図9】同じく良熱伝導部材で形成した貯蔵容器カバー
を設置した高湿貯蔵室の断面図。
FIG. 9 is a cross-sectional view of a high-humidity storage chamber in which a storage container cover also formed of a good heat conductive member is installed.

【図10】同じく本実施例の高湿貯蔵室による鮮度保持効
果確認のため実施した保存試験における、食品の水分減
少率を示す特性図。
FIG. 10 is a characteristic diagram showing a moisture reduction rate of food in a storage test carried out to confirm the freshness-retaining effect of the high-humidity storage chamber of this example.

【図11】同じく内壁に良熱伝導部材を配した直接冷却方
式の貯蔵室を具備する他の実施例となる冷凍冷蔵庫の断
面図。
FIG. 11 is a cross-sectional view of a freezer-refrigerator according to another embodiment including a storage chamber of a direct cooling system in which a good heat conducting member is arranged on the inner wall.

【図12】従来の冷却制御貯蔵庫の断面図。FIG. 12 is a sectional view of a conventional cooling control storage.

【図13】従来の高湿チルド室例を示す断面図。FIG. 13 is a cross-sectional view showing an example of a conventional high humidity chilled chamber.

【符号の説明】[Explanation of symbols]

10…野菜室扉、11…コンプレッサ、12…チルド容器カバ
ー、13…野菜容器カバー。
10 ... Vegetable compartment door, 11 ... Compressor, 12 ... Chilled container cover, 13 ... Vegetable container cover.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 北畠 正一 栃木県下都賀郡大平町大字富田800番地株 式会社日立製作所冷熱事業部内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Shoichi Kitahata 800 Tomita, Ohira-machi, Shimotsuga-gun, Tochigi Prefecture Hitachi Co., Ltd.

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】貯蔵容器にカバーを配して密閉性を上げ、
間接冷却方式により内部の湿度を高めた貯蔵室におい
て、上記貯蔵容器及びカバーの全体、あるいはその一部
に良熱伝導部材を用い、室内の温度変動抑制,温度分布
均一化を図り、上記貯蔵室の内部に吸放湿性を有する調
湿部材を設置することにより、室内の湿度を調整するこ
とを特徴とする冷凍冷蔵庫。
1. A cover is placed on a storage container to improve the airtightness,
In a storage room whose internal humidity is increased by an indirect cooling method, a good heat conducting member is used for the entire or part of the storage container and cover to suppress temperature fluctuations in the room and to make the temperature distribution uniform. A refrigerator / freezer characterized in that a humidity control member having a moisture absorbing / releasing property is installed inside to adjust the indoor humidity.
【請求項2】上記貯蔵容器、上記カバーの材料として、
金属材料を使用するか、あるいはこれら金属素材を粉末
状にする、もしくは粉末状のものをマスターバッチ化し
て練り込むことにより、良熱伝導性を付与した合成樹脂
を使用して成る請求項1に記載の冷凍冷蔵庫。
2. The material of the storage container and the cover,
A synthetic resin having good thermal conductivity, which is obtained by using a metal material, or by powdering these metal materials, or masterbatching the powdery material into a kneaded mixture and kneading the metal material into a powder. The refrigerator-freezer described.
【請求項3】上記貯蔵容器、上記カバーの全体あるいは
一部に良熱伝導部材を使用する代わりに、上記貯蔵容器
の内部に、良熱伝導部材から成る一ないし五面の容器を
着脱自在に配設して成る請求項1に記載の冷凍冷蔵庫。
3. Instead of using a good heat conducting member for the whole or a part of the storage container and the cover, a container having one to five faces made of a good heat conducting member can be detachably attached to the inside of the storage container. The freezer-refrigerator according to claim 1, which is provided.
【請求項4】上記調湿部材として、周囲の湿度に応じて
吸湿,放湿する性質を有する繊維を板状に圧縮成形する
ことにより剛性を付した材料を使用して成る請求項2ま
たは3に記載の冷凍冷蔵庫。
4. A material having rigidity obtained by compression-molding a fiber having a property of absorbing and releasing moisture according to ambient humidity into a plate shape as the humidity control member. The refrigerator-freezer described in.
【請求項5】上記吸放湿性繊維の上面に10〜100μmの
細孔を有する疎水性のフィルムを貼着し、更にその上部
に、板状の親水性樹脂を吸放湿性繊維が保持可能な水分
量をオーバーすると吸湿,吸水により膨張して接触する
よう、一定の空間を設けて設置し、上記吸放湿性繊維内
の水分を上記疎水性フィルムの細孔を介して板状親水性
樹脂に吸水させ、これを上記板状親水性樹脂の上面を通
過する冷気に蒸散させることによって、余分な水分を室
外に排出する機構を備えた請求項4に記載の冷凍冷蔵
庫。
5. A hygroscopic fiber having a plate-like hydrophilic resin can be held on a hydrophobic film having pores of 10 to 100 μm attached on the upper surface of the hygroscopic fiber. It is installed with a certain space so that it expands and contacts due to moisture absorption and water absorption when the amount of water exceeds, and the moisture in the moisture absorptive and desorptive fiber is transferred to the plate-like hydrophilic resin through the pores of the hydrophobic film. The refrigerator-freezer according to claim 4, further comprising a mechanism for absorbing excess water and evaporating the cold air passing through the upper surface of the plate-like hydrophilic resin to discharge excess water to the outside of the room.
【請求項6】間接冷却して成る貯蔵室のほか、直接冷却
方式の上記貯蔵室の内壁の全体、あるいは一部に上記良
熱伝導部材を使用することにより、温度変動抑制,温度
分布の均一化を図ったことを特徴とする冷凍冷蔵庫。
6. In addition to a storage chamber formed by indirect cooling, by using the good heat conducting member on the whole or a part of the inner wall of the direct cooling type storage chamber, temperature fluctuation suppression and uniform temperature distribution can be achieved. A freezer-refrigerator characterized by being made into a product.
JP8914996A 1996-04-11 1996-04-11 Refrigerator with freezer Pending JPH09280719A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8914996A JPH09280719A (en) 1996-04-11 1996-04-11 Refrigerator with freezer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8914996A JPH09280719A (en) 1996-04-11 1996-04-11 Refrigerator with freezer

Publications (1)

Publication Number Publication Date
JPH09280719A true JPH09280719A (en) 1997-10-31

Family

ID=13962816

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8914996A Pending JPH09280719A (en) 1996-04-11 1996-04-11 Refrigerator with freezer

Country Status (1)

Country Link
JP (1) JPH09280719A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010038524A (en) * 2008-03-14 2010-02-18 Panasonic Corp Refrigerator
JP2011017472A (en) * 2009-07-08 2011-01-27 Hitachi Appliances Inc Refrigerator
JP2017032257A (en) * 2015-08-06 2017-02-09 日立アプライアンス株式会社 refrigerator
JP2017032258A (en) * 2015-08-06 2017-02-09 日立アプライアンス株式会社 refrigerator
CN106440637A (en) * 2015-08-06 2017-02-22 日立空调·家用电器株式会社 Refrigerator
JP2017160421A (en) * 2016-03-02 2017-09-14 三洋化成工業株式会社 Moisture feed material
CN109373671A (en) * 2018-11-05 2019-02-22 青岛海尔股份有限公司 Refrigerator
WO2023112904A1 (en) * 2021-12-17 2023-06-22 シャープ株式会社 Freshness retaining sheet and cooling box
JP2023093814A (en) * 2021-12-23 2023-07-05 東芝ライフスタイル株式会社 Storage container for refrigerator, and refrigerator

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010038524A (en) * 2008-03-14 2010-02-18 Panasonic Corp Refrigerator
JP2011017472A (en) * 2009-07-08 2011-01-27 Hitachi Appliances Inc Refrigerator
JP2017032257A (en) * 2015-08-06 2017-02-09 日立アプライアンス株式会社 refrigerator
JP2017032258A (en) * 2015-08-06 2017-02-09 日立アプライアンス株式会社 refrigerator
CN106440637A (en) * 2015-08-06 2017-02-22 日立空调·家用电器株式会社 Refrigerator
JP2017160421A (en) * 2016-03-02 2017-09-14 三洋化成工業株式会社 Moisture feed material
CN109373671A (en) * 2018-11-05 2019-02-22 青岛海尔股份有限公司 Refrigerator
WO2023112904A1 (en) * 2021-12-17 2023-06-22 シャープ株式会社 Freshness retaining sheet and cooling box
JP2023093814A (en) * 2021-12-23 2023-07-05 東芝ライフスタイル株式会社 Storage container for refrigerator, and refrigerator

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