JPH09272992A - Method for vertically hanging wet type copper electrolytic starting sheet - Google Patents

Method for vertically hanging wet type copper electrolytic starting sheet

Info

Publication number
JPH09272992A
JPH09272992A JP11118296A JP11118296A JPH09272992A JP H09272992 A JPH09272992 A JP H09272992A JP 11118296 A JP11118296 A JP 11118296A JP 11118296 A JP11118296 A JP 11118296A JP H09272992 A JPH09272992 A JP H09272992A
Authority
JP
Japan
Prior art keywords
seed plate
cathode
copper
weight
electrolytic cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11118296A
Other languages
Japanese (ja)
Inventor
Isao Yoshimura
功 吉村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Metal Mining Co Ltd
Original Assignee
Sumitomo Metal Mining Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Mining Co Ltd filed Critical Sumitomo Metal Mining Co Ltd
Priority to JP11118296A priority Critical patent/JPH09272992A/en
Publication of JPH09272992A publication Critical patent/JPH09272992A/en
Pending legal-status Critical Current

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  • Electrolytic Production Of Metals (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a method for vertically hanging a wet type copper electrolytic starting sheet which is capable of preventing a short-circuit accident caused by contact between an anode and a cathode, is capable of improving packing density of respective electrodes in an electrolytic cell, namely, improving production capacity of products. SOLUTION: In this method for vertically hanging the wet type copper electrolytic starting sheet having sizes of 0.6 to 1.0mm thickness and width × height of 800mm×800mm to 1200mm×1200mm, hanger ribbons 2 made of copper are formed to have sizes in which weight is >=0.75 to <=3.8% of weight of the starting sheet 1, total length is >=320 to <=600mm and width is >=15 to <=100mm so that he starting sheet 1 to be a cathode can be vertically hung down by its own weight. In such a manner, the charging sheet number of anode and cathode in the electrolytic cell at he time of wet type copper electrolyzing can be increased by 8% and time fact means that production capacity per unit electrolytic cell volume is increased by 8%.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、湿式銅電解におい
て用いられる種板の鉛直吊り下げ方法に関するものであ
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for vertically suspending a seed plate used in wet copper electrolysis.

【0002】[0002]

【従来の技術】図2は典型的な湿式銅電解用のカソード
電極全体を示す図である。図において、1は湿式銅電解
用カソードの銅種板、2は銅製種板の吊り手リボン、3
は吊り手リボン2を介して種板を支持する金属クロスビ
ームである。銅の湿式電解において、厚さが0.6〜
1.0mmで、幅×高さが800mm×800mm〜1
200mm×1200mmの寸法を有するカソードとな
る銅種板1と、電解槽内におけるカソード種板1の吊り
手兼通電経路となる銅製吊り手リボン2とは独立して製
造され、電気溶接等の方法により電気的、機械的に両者
を接続する。カソード種板1は、図3のように折り曲げ
られた吊り手リボン2の間に設置されたクロスビーム3
により電解槽内に吊り下げられ、クロスビームを介して
通電される。この時アノードも同時に電解槽に設置さ
れ、アノードの銅成分が直流電界によりカソードに精製
される。
2. Description of the Related Art FIG. 2 is a diagram showing a typical cathode electrode for a typical wet copper electrolysis. In the figure, 1 is a copper seed plate of a cathode for wet copper electrolysis, 2 is a hanging ribbon of a copper seed plate, 3
Is a metal cross beam that supports the seed plate via the hanging ribbon 2. In the wet electrolysis of copper, the thickness is 0.6 to
1.0 mm, width x height 800 mm x 800 mm ~ 1
A copper seed plate 1 serving as a cathode having a size of 200 mm × 1200 mm and a copper hanging hand ribbon 2 serving as a hanging hand and a current-carrying path for the cathode seed plate 1 in an electrolytic cell are manufactured independently, and a method such as electric welding is used. To electrically and mechanically connect both. The cathode seed plate 1 is a cross beam 3 installed between the hanging ribbons 2 folded as shown in FIG.
It is suspended in the electrolytic cell by means of and is energized via the cross beam. At this time, the anode is also installed in the electrolytic cell at the same time, and the copper component of the anode is refined into the cathode by the DC electric field.

【0003】ここで、吊り手リボン2の全長とは、折り
曲げられる前の状態での長さを指し、折り曲げることに
より長さは全長の1/2以下となる。
Here, the total length of the hanging ribbon 2 refers to the length before being bent, and the length becomes half or less of the total length by bending.

【0004】[0004]

【発明が解決しようとする課題】カソードとしての銅種
板と銅製吊り手リボンの接合過程において、例えば銅製
吊り手リボンの部分に通電経路兼種板支持用の金属クロ
スビームを装着するため、図3に示す通り吊り手リボン
2は中央部より2つに折り曲げられる。しかしながら、
この吊り手リボンの折り曲げがクロスビームに対して均
等に行われない場合、図4のように吊り下げされた銅種
板1は、吊り手リボン2の剛性により鉛直に吊り下げに
くく、このため種板を数十枚並べて電解槽への設置が容
易でなくなるばかりか、電解槽内でアノードと接触して
電気的な短絡を生じ電解不能となる場合がある。このた
め、槽内では銅種板の傾きを考慮して、アノード・カソ
ード間隔を予め広くとっておく必要がある。換言すれ
ば、電解槽内の各電極の充填密度、製品の生産能力は、
この間隔を広くとることによって著しく制限されていま
うのである。
In the process of joining a copper seed plate serving as a cathode and a copper lifting ribbon, for example, a metal cross beam for energizing a path and supporting the seed plate is attached to the copper lifting ribbon. As shown in FIG. 3, the hanging ribbon 2 is folded in two from the central portion. However,
When the hanging ribbon is not bent evenly with respect to the cross beam, the copper seed plate 1 hung as shown in FIG. Not only is it difficult to install dozens of plates in an electrolytic cell, but there is a case in which electrolysis is impossible due to an electrical short circuit caused by contact with the anode in the electrolytic cell. For this reason, it is necessary to preliminarily widen the anode-cathode distance in the tank in consideration of the inclination of the copper seed plate. In other words, the packing density of each electrode in the electrolytic cell and the product production capacity are
It is significantly limited by widening this interval.

【0005】本発明の目的は、従来の湿式銅電解用の種
板の吊り下げ方法を改善したものであって、アノードと
カソードとの接触による短絡事故の防止および電解槽内
の各電極の充填密度向上、すなわち製品の生産能力を向
上することができる湿式銅電解種板の鉛直吊り下げ方法
を提供することである。
An object of the present invention is to improve a conventional method for suspending a seed plate for wet copper electrolysis, to prevent a short circuit accident due to contact between an anode and a cathode and to fill each electrode in an electrolytic cell. It is an object of the present invention to provide a method of vertically suspending a wet copper electrolytic seed plate capable of improving the density, that is, improving the production capacity of products.

【0006】[0006]

【課題を解決するための手段】上記課題を改善するため
には、銅種板をいかに鉛直に吊り下げるかを検討するこ
とが肝要となる。そこで本発明者は、吊り手リボンの剛
性に着目し、種々の重量と寸法の吊り手リボンを用いて
種板の鉛直度への影響を調査したところ、特定の重量と
寸法の吊り手リボンを用いると銅種板を鉛直に吊り下げ
られ得ることを見出だして本発明を完成するに至った。
すなわち、本発明は、厚さが0.6〜1.0mmで、幅
×高さが800mm×800mm〜1200mm×12
00mmの寸法を有する湿式銅電解種板の鉛直吊り下げ
方法において、カソードとなる種板が自重により鉛直に
吊り下げられるよう、銅製吊り手リボンを、重量が、種
板重量の0.75%以上で3.8%以下、全長が320
mm以上で600mm以下、幅が25mm以上で100
mm以下の寸法に形成した湿式銅電解用種板の鉛直吊り
下げ方法を特徴とするものである。
[Means for Solving the Problems] In order to solve the above problems, it is important to consider how to vertically hang a copper seed plate. Therefore, the present inventor has focused on the rigidity of the hanging ribbon and investigated the influence on the verticality of the seed plate by using the hanging ribbons of various weights and dimensions. It was found that the copper seed plate can be hung vertically when used, and the present invention has been completed.
That is, the present invention has a thickness of 0.6 to 1.0 mm and a width x height of 800 mm x 800 mm to 1200 mm x 12
In a method of vertically suspending a wet copper electrolytic seed plate having a dimension of 00 mm, a copper handle ribbon is used to have a weight of 0.75% or more of the seed plate weight so that the cathode seed plate can be vertically suspended by its own weight. Less than 3.8%, total length 320
600 mm or less for mm or more, 100 for width of 25 mm or more
The present invention is characterized by a method of vertically suspending a seed plate for wet copper electrolysis formed to have a size of mm or less.

【0007】吊り手リボンの重量が銅種板の自重の3.
8%より大きく、かつ吊り手リボンの長さが320mm
未満、幅が100mmを超えた場合、図4に示すように
種板は鉛直に吊り下げられずらくなり電解槽内でアノー
ドと接触して電気的な短絡を生じ易く、一方吊り手リボ
ンの重量が種板の重量の0.75%未満、かつ吊り手リ
ボンの長さが600mmより長く、幅が25mm未満の
場合には、電解槽への種板の吊り下げ輸送時に銅種板が
激しく揺れて作業上の困難が伴う。また、電解中あるい
は電解終了後のカソード重量に耐えられず吊り手リボン
が破断することがある。
2. The weight of the hanging hand ribbon is the weight of the copper seed plate.
Greater than 8% and the length of the hanging ribbon is 320 mm
If the width is less than 100 mm and the width exceeds 100 mm, the seed plate becomes difficult to be hung vertically as shown in FIG. 4, and it easily contacts with the anode in the electrolytic cell to cause an electrical short circuit. Is less than 0.75% of the weight of the seed plate, and the length of the hanging ribbon is longer than 600 mm and the width is less than 25 mm, the copper seed plate vibrates violently during suspension transportation of the seed plate to the electrolytic cell. Associated with work difficulties. In addition, the weight of the cathode during or after the electrolysis cannot withstand the weight of the cathode, and the hanging ribbon may be broken.

【0008】本発明によると、吊り手リボンの折り曲げ
がクロスビームに対して均等に行われない場合でも、銅
種板の自重により吊り手リボンが曲がって種板の鉛直度
は保たれる。また、吊り手リボンの破断のない強度が得
られる。
According to the present invention, even if the hanging ribbon is not bent evenly with respect to the cross beam, the hanging ribbon is bent by the weight of the copper seed plate and the verticality of the seed plate is maintained. Further, the strength without breaking the hanging ribbon can be obtained.

【0009】[0009]

【発明の実施の形態】本発明で鉛直吊り下げられる対象
となる湿式銅電解用の種板は、厚さが0.6〜1.0m
mで、幅×高さが800mm×800mm〜1200m
m×1200mmの寸法を有するものである。また本発
明に係る該銅種板の吊り手リボンは、その重量が種板の
重量の0.75%以上で3.8%以下であって、かつ吊
り手リボンの長さは320mm以上で600mm以下、
その幅は25mm以上で100mm以下である。
BEST MODE FOR CARRYING OUT THE INVENTION The seed plate for wet copper electrolysis, which is the subject of vertical hanging according to the present invention, has a thickness of 0.6 to 1.0 m.
m, width x height 800 mm x 800 mm to 1200 m
It has a size of m × 1200 mm. The copper seed plate hanging hand ribbon according to the present invention has a weight of 0.75% or more and 3.8% or less of the weight of the seed plate, and a hanging hand ribbon length of 320 mm or more and 600 mm. Less than,
Its width is 25 mm or more and 100 mm or less.

【0010】以下、本発明の吊り手リボンをさらに詳し
く説明すると、本発明の吊り手リボンにおいて、該吊り
手リボンは種々の方法で湿式銅電解用の種板に電気的、
機械的に接合される。そして、金属クロスビームを支点
にして吊り下げられる。この際に、リボンの折り曲げが
クロスビームに対して均等に行われないような場合、ク
ロスビームの真下(鉛直下)に種板は位置しないが、ク
ロスビームを挿入して電解槽への移送のために吊り上げ
た時に種板の自重によりリボンが曲がり、種板は鉛直に
支持されるようになる。したがって、電解槽への設置が
容易となり、従来法によるよりも極めて狭い間隔でアノ
ードとカソードを配置でき、その結果、電解槽内のアノ
ード・カソード充填枚数を増やすことができるのであ
る。
The hanging hand ribbon of the present invention will be described in more detail below. In the hanging hand ribbon of the present invention, the hanging hand ribbon is electrically applied to a seed plate for wet copper electrolysis by various methods.
Mechanically bonded. Then, it is suspended with the metal cross beam as a fulcrum. At this time, if the ribbon is not bent evenly with respect to the cross beam, the seed plate is not located directly below (vertically below) the cross beam, but the cross beam is inserted to transfer it to the electrolytic cell. Therefore, when lifted, the ribbon bends due to the weight of the seed plate, and the seed plate is supported vertically. Therefore, it is easy to install in the electrolytic cell, and the anode and the cathode can be arranged at a much narrower interval than in the conventional method, and as a result, the number of anodes / cathodes filled in the electrolytic cell can be increased.

【0011】[0011]

【実施例】以下、本発明の実施例を図面に基づいて説明
する。図1は本発明の銅カソード全体を表す図であっ
て、1は湿式銅電解用の銅製カソード種板、2は銅種板
の銅製吊り手リボン、3は金属クロスビームである。
Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a diagram showing the entire copper cathode of the present invention, in which 1 is a copper cathode seed plate for wet copper electrolysis, 2 is a copper seed ribbon of a copper seed plate, and 3 is a metal cross beam.

【0012】前記カソード種板1は、吊り手リボン2と
電気的、機械的に接続され、折り曲げられた吊り手リボ
ン2の間に挿入されたクロスビーム3を持って吊り上げ
られ電解槽に向かう。カソード種板1の概寸法は厚さが
0.8mmで、幅×高さが1000mm×1000mm
であり、重さは8kg、吊り手リボン2の寸法は厚さが
0.8mmで、幅×長さが50mm×400mmで、重
さが0.2kgである。カソード種板1がクロスビーム
3を持って吊り上げられてから電解槽に設置されるまで
の間に、本発明の吊り手リボン2が種板1の自重によっ
て曲がり種板1は鉛直に吊り下げられる。
The cathode seed plate 1 is electrically and mechanically connected to the hanging ribbon 2, and is lifted up with the cross beam 3 inserted between the bent hanging ribbons 2 toward the electrolytic cell. The approximate size of the cathode seed plate 1 is 0.8 mm in thickness, and the width x height is 1000 mm x 1000 mm.
And the weight of the hanging ribbon 2 is 0.8 mm, the width × length is 50 mm × 400 mm, and the weight is 0.2 kg. Between the time when the cathode seed plate 1 is lifted by the cross beam 3 and the time when the cathode seed plate 1 is installed in the electrolytic cell, the hanging ribbon 2 of the present invention is bent by the weight of the seed plate 1 and the seed plate 1 is hung vertically. .

【0013】このように本発明に係る吊り手リボン2を
用いて前記種板1を鉛直に吊り下げる方法を採用したこ
とにより、従来法に比べて格段に狭い間隔でアノードと
カソードを配置できるようになり、寸法2600mm×
1300mmの電解槽に対するカソード・アノード充填
枚数は8%増加することができた。
As described above, by adopting the method of vertically hanging the seed plate 1 by using the lifting ribbon 2 according to the present invention, the anode and the cathode can be arranged at a much narrower interval as compared with the conventional method. And the dimensions are 2600 mm x
The number of filled cathode / anode for the 1300 mm electrolytic cell could be increased by 8%.

【0014】[0014]

【発明の効果】以上述べた通り、本発明によると、湿式
銅電解時のアノード・カソードの電解槽内の充填枚数を
8%増加させることができ、このことは単位電解槽容量
当たりの生産能力が8%向上したことを意味する。
As described above, according to the present invention, the number of anodes / cathodes filled in the electrolytic cell during wet copper electrolysis can be increased by 8%, which means that the production capacity per unit electrolytic cell capacity is increased. Means an 8% improvement.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の電解用カソード種板を示す図で(a)
は正面図、(b)は側面図である。
FIG. 1 is a view showing a cathode seed plate for electrolysis of the present invention (a).
Is a front view, and (b) is a side view.

【図2】従来の典型的電解用カソード種板の正面図であ
る。
FIG. 2 is a front view of a conventional typical cathode seed plate for electrolysis.

【図3】図2の吊り手リボンの折り曲げ状態を説明する
側面図である。
FIG. 3 is a side view illustrating a folded state of the hanging ribbon of FIG.

【図4】従来の典型的電解用カソード種板の吊り下げ時
の姿を示す側面図である。
FIG. 4 is a side view showing a state in which a conventional typical cathode seed plate for electrolysis is suspended.

【符号の説明】[Explanation of symbols]

1 カソード種板 2 吊り手リボン 3 金属クロスビーム 1 Cathode seed plate 2 Lifter ribbon 3 Metal cross beam

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 厚さが0.6〜1.0mmで、幅×高さ
が800mm×800mm〜1200mm×1200m
mの寸法を有する湿式銅電解種板の鉛直吊り下げ方法に
おいて、カソードとなる種板が自重により鉛直に吊り下
げられるよう、銅製吊り手リボンを、重量が、種板重量
の0.75%以上で3.8%以下、全長が320mm以
上で600mm以下、幅が25mm以上で100mm以
下の寸法に形成したことを特徴とする湿式銅電解用種板
の鉛直吊り下げ方法。
1. The thickness is 0.6 to 1.0 mm, and the width × height is 800 mm × 800 mm to 1200 mm × 1200 m.
In a method of vertically suspending a wet copper electrolytic seed plate having a size of m, the weight of the copper handle ribbon is 0.75% or more of the weight of the seed plate so that the seed plate serving as the cathode can be vertically suspended by its own weight. The method for vertically suspending a seed plate for wet copper electrolysis is characterized in that the size is 3.8% or less, the total length is 320 mm or more and 600 mm or less, and the width is 25 mm or more and 100 mm or less.
JP11118296A 1996-04-08 1996-04-08 Method for vertically hanging wet type copper electrolytic starting sheet Pending JPH09272992A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11118296A JPH09272992A (en) 1996-04-08 1996-04-08 Method for vertically hanging wet type copper electrolytic starting sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11118296A JPH09272992A (en) 1996-04-08 1996-04-08 Method for vertically hanging wet type copper electrolytic starting sheet

Publications (1)

Publication Number Publication Date
JPH09272992A true JPH09272992A (en) 1997-10-21

Family

ID=14554580

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11118296A Pending JPH09272992A (en) 1996-04-08 1996-04-08 Method for vertically hanging wet type copper electrolytic starting sheet

Country Status (1)

Country Link
JP (1) JPH09272992A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017145464A (en) * 2016-02-18 2017-08-24 住友金属鉱山株式会社 Manufacturing method of cathode for electrolytic refining

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017145464A (en) * 2016-02-18 2017-08-24 住友金属鉱山株式会社 Manufacturing method of cathode for electrolytic refining

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