JPH09228299A - Recording sheet - Google Patents

Recording sheet

Info

Publication number
JPH09228299A
JPH09228299A JP8050838A JP5083896A JPH09228299A JP H09228299 A JPH09228299 A JP H09228299A JP 8050838 A JP8050838 A JP 8050838A JP 5083896 A JP5083896 A JP 5083896A JP H09228299 A JPH09228299 A JP H09228299A
Authority
JP
Japan
Prior art keywords
adhesive
pseudo
adhesive composition
fine particles
recording sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8050838A
Other languages
Japanese (ja)
Other versions
JP3565527B2 (en
Inventor
Makoto Hasegawa
真 長谷川
Noriko Kumazawa
納里子 熊澤
Yasuhiro Ichinohe
康裕 一戸
Tsuyoshi Yasuda
強 安田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Paper Industries Co Ltd
Jujo Paper Co Ltd
Original Assignee
Nippon Paper Industries Co Ltd
Jujo Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Paper Industries Co Ltd, Jujo Paper Co Ltd filed Critical Nippon Paper Industries Co Ltd
Priority to JP05083896A priority Critical patent/JP3565527B2/en
Publication of JPH09228299A publication Critical patent/JPH09228299A/en
Application granted granted Critical
Publication of JP3565527B2 publication Critical patent/JP3565527B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Credit Cards Or The Like (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paper (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a recording sheet which can reduce the fluctuation of adhesion in any case that information is printed with any process and manifests always stabilized adhesion with excellent printability. SOLUTION: This recording sheet is prepared by coating at least a part of the surfaces of the substrate material with a pseudo-adherent adhesive composition mainly comprising a thermoplastic adhesive and fine particles and has a pseudo-adhesion of 10-350gf/in and is used for telecommunication and delivery. In this sheet, the layer coated with the adhesive composition is adjusted in its change of the pseudo adhesion within ±30% between before and after printing with a printing machine and/or a printer.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は記録シートに関し、
特に、接着層の疑似接着性が各種の情報印刷方式に対応
することができる上、印刷後の接着力の変動が小さく、
ブロッキングを起こさない、感圧疑似接着性を有する情
報記録シートに関する。
TECHNICAL FIELD The present invention relates to a recording sheet,
In particular, the pseudo-adhesiveness of the adhesive layer can be applied to various information printing methods, and the fluctuation of the adhesive force after printing is small,
The present invention relates to an information recording sheet that does not cause blocking and has a pressure-sensitive pseudo adhesive property.

【0002】[0002]

【従来の技術】従来、疑似接着性を有する層を設けた記
録シートに、隠蔽あるいは秘匿する必要のある各種の情
報等を印刷した後、前記層同士を対向させて加圧し、疑
似接着させることによって、必要な時に再剥離可能な情
報隠蔽シートとすることが行われており、親展ハガキを
中心とする通信媒体として実用化されている。特に最近
では、その疑似接着性とそれを利用した加工方法の容易
さが注目され、配送伝票用紙等の重ね合わせ帳票として
も利用され始めている。
2. Description of the Related Art Conventionally, various kinds of information that need to be concealed or concealed are printed on a recording sheet provided with a layer having a pseudo-adhesive property, and then the layers are opposed to each other and pressed to be pseudo-adhered. Has been used as an information hiding sheet that can be peeled off when necessary, and has been put to practical use as a communication medium centered on confidential postcards. Particularly in recent years, attention has been paid to the pseudo adhesive property and the ease of a processing method using the pseudo adhesive property, and it has begun to be used also as an overlay form such as delivery slip paper.

【0003】通常、これらの感圧疑似接着シートに設け
る疑似接着層には、主としてガラス転移点の低い天然ゴ
ム、或いは、各種のタッキファイアを混合した合成ゴム
が接着剤として含有されている。この場合における疑似
接着剤層の接着力発現の機構は、専ら接着層界面におけ
る高分子接着剤の自己拡散であると考えられていた(接
着の技術、15(2),49-53 頁,1995 年) 。従って、構成材
料である接着剤には自着性あるいは粘着性が求められ
る。
Usually, the pseudo-adhesive layer provided on these pressure-sensitive pseudo-adhesive sheets mainly contains natural rubber having a low glass transition point or synthetic rubber mixed with various tackifiers as an adhesive. In this case, the mechanism of the adhesive force development of the pseudo adhesive layer was considered to be exclusively the self-diffusion of the polymer adhesive at the adhesive layer interface (Adhesion Technology, 15 (2), pp. 49-53, 1995. Year) . Therefore, the adhesive as a constituent material is required to have self-adhesiveness or tackiness.

【0004】しかしながら、上記の疑似接着剤層が設け
られた被塗工シートは、加工時に、例えば、シートを巻
き取った時の接触面、或いは、Z字状に折り畳んだとき
のミシン目やパンチ孔の疑似接着剤層面でブロッキング
が生じ、印刷時あるいは成形時に給紙不能等の事故を生
じるという欠点があった。そこで、ミシン目となる部分
等に、印刷によるマスキング処理(特開平2−2893
93号公報等)や劣化処理を施すことによる改良がなさ
れた(特開平5−116488号公報等)。
However, the coated sheet provided with the pseudo-adhesive layer is, for example, a contact surface when the sheet is rolled up, or a perforation or a punch when the sheet is folded into a Z shape. There is a drawback in that blocking occurs on the surface of the pseudo adhesive layer of the holes, and an accident such as inability to feed paper occurs during printing or molding. Therefore, masking processing by printing is performed on the perforations and the like (Japanese Patent Laid-Open No. 2-2893).
No. 93, etc.) and a deterioration treatment (Japanese Patent Laid-Open No. 5-116488, etc.).

【0005】また、接着剤として、通常の状態では接着
することのない感圧接着剤に、熱可塑性でない微粒子を
充填あるいは緩衝剤として混合してなる接着剤組成物
(特開平1−85794号公報、同1−168779号
公報等)も提案されている。しかしながら、通常の状態
では接着することのない感圧接着剤を用いるため、被塗
工シートを接着させるには、重い荷重下で、長時間かけ
て圧着するか高温をかけることが必要であるので実用的
でない上、高温をかける場合には、非熱可塑性の微小粒
子しか使用することができないという欠点があった。
As an adhesive, an adhesive composition prepared by filling a pressure-sensitive adhesive that does not adhere in a normal state with fine particles that are not thermoplastic or mixing it as a buffer (Japanese Patent Laid-Open No. 1-85794). No. 1-168779, etc.) has also been proposed. However, since a pressure-sensitive adhesive that does not adhere in a normal state is used, it is necessary to perform pressure bonding or high temperature under a heavy load for a long time in order to bond the coated sheet. In addition to being impractical, there is a drawback that only non-thermoplastic fine particles can be used when a high temperature is applied.

【0006】また、近年、疑似接着可能な層上への情報
の記録方法として、例えば、地模様や定型情報をオフセ
ット印刷機等により記録し、個別の可変情報を電子計算
機に連動した、電子写真方式あるいはインクジェット方
式等の高速ノンインパクトプリンターによって印刷する
等、記録方式に任意性が大きくなったことに伴い、疑似
接着性シートを、親展性の高い通信媒体としてのみなら
ず、封書を利用したダイレクトメールに対しても、迅速
に処理できる安価な通信手段として用いるようになっ
た。
Further, in recent years, as a method of recording information on a pseudo-adhesive layer, for example, a ground pattern or a fixed form information is recorded by an offset printing machine or the like, and individual variable information is linked with an electronic computer. With the increased flexibility of recording methods such as printing with high-speed non-impact printers such as inkjet method or inkjet method, the pseudo-adhesive sheet is used not only as a highly confidential communication medium, but also as a direct method using envelopes. Even for email, it has come to be used as an inexpensive communication means that can be processed quickly.

【0007】しかしながら、オフセット印刷等において
はインクの定着に紫外線ランプを利用する一方、高速の
電子写真方式によるノンインパクトプリンティングにお
いては、印刷の定着を、主として160〜220℃程度
の高温加熱方式で行う必要があるので、疑似接着層が紫
外線ランプによって酸化劣化したり、熱によって劣化す
るという問題が生じる。
However, in offset printing or the like, an ultraviolet lamp is used for fixing ink, while in non-impact printing by high-speed electrophotography, fixing of printing is mainly performed by a high temperature heating method of about 160 to 220 ° C. Therefore, there is a problem in that the pseudo adhesive layer is oxidatively deteriorated by an ultraviolet lamp or is deteriorated by heat.

【0008】特に、従来良く用いられる自着性あるいは
粘着性を有する接着剤組成物においては、接着剤とし
て、例えば、天然ゴム、変性天然ゴム、スチレン/ブタ
ジエンゴム、ニトリルゴム、酢酸ビニル系ゴム等を用い
ると共に、前述した被塗工シートの加工時におけるブロ
ッキング等を抑制する目的で、熱可塑性のない微小粒子
を混合したものを基礎として構成するため、紫外線によ
る酸化劣化や熱劣化を受け易い。このように接着剤とし
て機能する樹脂が劣化すると、その粘弾性が乏しくなる
ので、自着性あるいは粘着性の喪失した接着剤組成物に
なる。
Particularly, in the adhesive composition having self-adhesiveness or tackiness which has been often used conventionally, as an adhesive, for example, natural rubber, modified natural rubber, styrene / butadiene rubber, nitrile rubber, vinyl acetate rubber, etc. In addition to the above, the composition is based on a mixture of fine particles having no thermoplasticity for the purpose of suppressing blocking and the like at the time of processing the above-mentioned sheet to be coated, and therefore is susceptible to oxidative deterioration and thermal deterioration by ultraviolet rays. When the resin functioning as an adhesive is deteriorated in this way, its viscoelasticity becomes poor, resulting in an adhesive composition that loses its self-adhesiveness or tackiness.

【0009】従って、前述したような利用形態の多様化
に対応するために種々の記録方法を用いる場合、同じ接
着力に設計された感圧接着性記録シートであっても、オ
フセット印刷機による印刷のみによる利用する場合、電
子写真方式のプリンターあるいはインクジェット方式の
プリンターによる印刷のみによる利用する場合、及び、
これらを組み合わせて利用する場合では、接着剤の劣化
の度合いがそれぞれ異なるため、疑似接着時の記録シー
トの接着力が異なってくる。
Therefore, when various recording methods are used in order to cope with the diversification of the above-mentioned usage forms, even a pressure-sensitive adhesive recording sheet designed to have the same adhesive force is printed by an offset printing machine. When using only with an electrophotographic printer or inkjet printer, and
When these are used in combination, since the degree of deterioration of the adhesive is different, the adhesive strength of the recording sheet at the time of pseudo-adhesion is different.

【0010】そこで、情報の記録方法に関係なく、同一
条件で疑似接着させると、ある時は接着力が低すぎて輸
送中に自然剥離し、又、ある時は接着力が高すぎて再剥
離できず、破れて疑似接着面に記録した情報を読むこと
ができない場合も生じる。従って、利用者が記録シート
を接着する際の加圧条件を、記録シートの記録方法に合
わせて個別に調整し、適度な接着力とするという非常に
煩雑な作業を強いられているのが現状である。
Therefore, irrespective of the information recording method, when pseudo-bonding is performed under the same conditions, the adhesive force is sometimes too low to spontaneously peel during transportation, and sometimes the adhesive force is too high to be re-peeled. In some cases, the information cannot be read and the information recorded on the pseudo adhesive surface cannot be read due to tearing. Therefore, the user is forced to perform a very complicated work of individually adjusting the pressure condition for adhering the recording sheet according to the recording method of the recording sheet to obtain an appropriate adhesive force. Is.

【0011】[0011]

【発明が解決しようとする課題】従って、本発明の目的
は、ブロッキングを起こさない上、印刷適性に優れると
共に、如何なる方法を用いて印刷しても、印刷による接
着力の変動が小さく、常に安定した疑似接着力を有する
記録シートを提供することにある。
SUMMARY OF THE INVENTION Therefore, an object of the present invention is that it does not cause blocking and has excellent printability, and even if it is printed by any method, the fluctuation of the adhesive force due to printing is small and it is always stable. Another object of the present invention is to provide a recording sheet having the above pseudo adhesive force.

【0012】[0012]

【課題を解決するための手段】本発明の上記の目的は、
熱可塑性接着剤と微小粒子を主たる成分として含有する
疑似接着性の接着剤組成物を基材表面の少なくとも一部
に塗布してなる、疑似接着力が10〜350gf/i
n.である、通信用又は配送用の記録シートであって、
前記接着剤組成物を塗布してなる層が、その層上に印刷
機及び/又はプリンターによって印刷がなされた前後に
おいて、疑似接着力の強さの変化量が±30%以内とな
る層であることを特徴とする、感圧疑似接着性の記録シ
ートによって達成された。
SUMMARY OF THE INVENTION The above objects of the present invention are as follows.
The pseudo adhesive strength is 10 to 350 gf / i, which is obtained by applying a pseudo adhesive adhesive composition containing a thermoplastic adhesive and fine particles as main components to at least a part of the substrate surface.
n. Which is a recording sheet for communication or delivery,
The layer formed by applying the adhesive composition is a layer in which the amount of change in the pseudo adhesive strength is within ± 30% before and after printing on the layer with a printing machine and / or a printer. And a pressure-sensitive pseudo-adhesive recording sheet.

【0013】本発明に用いられる基材は、公知のものの
中から適宜選択することができる。その具体例として
は、上質紙、中質紙、合成紙、ポリエチレンフィルム、
ポリエチレンテレフタレートフィルム、フィルム貼合
紙、コート紙、ラミネート紙、及び、金属蒸着紙などが
挙げられる。
The base material used in the present invention can be appropriately selected from known materials. Specific examples thereof include high-quality paper, medium-quality paper, synthetic paper, polyethylene film,
Examples thereof include polyethylene terephthalate film, film-bonded paper, coated paper, laminated paper, and metallized paper.

【0014】本発明における情報印刷前の疑似接着力
(以下単に接着力とする)は、20℃、65%RHの環
境下で十分調湿した後に、同環境下で、2個の金属ロー
ル間を通過させるタイプの加圧機を用い、加圧条件60
kg/cm、10m/分で接着させた後、2時間後のT
剥離試験結果が、剥離速度300mm/分で10〜35
0gf/in.の範囲であると共に、試料に20℃、6
5%RHの環境下で25kgf/cm2 の圧力をかけて
もブロッキングを起こさないことが必要である。
In the present invention, the pseudo adhesive strength (hereinafter simply referred to as adhesive strength) before information printing is performed between two metal rolls under the same environment after sufficiently controlling the humidity in an environment of 20 ° C. and 65% RH. Using a pressurizer of the type that allows
T after 2 hours after bonding at kg / cm and 10 m / min
Peeling test result is 10-35 at peeling speed 300 mm / min
0 gf / in. And the sample at 20 ° C, 6
It is necessary that no blocking occurs even when a pressure of 25 kgf / cm 2 is applied in an environment of 5% RH.

【0015】情報印刷前の接着力が10gf/in.未
満では、印刷後に接着力が低下した場合には、輸送中に
疑似接着面が剥離する危険がある。接着力が350gf
/in.を越えると、印刷後に接着力が増加した場合に
は、記録シートの支持体に紙を使用した場合に、疑似接
着面間の剥離の代わりに紙層間剥離が起こり、情報を得
ることができなくなる。
The adhesive strength before information printing is 10 gf / in. If it is less than the above range, there is a risk that the pseudo adhesive surface may be peeled off during transportation when the adhesive force is reduced after printing. Adhesive force is 350gf
/ In. If the adhesive strength increases after printing, the paper layer peeling will occur instead of peeling between the pseudo-bonding surfaces when paper is used as the support of the recording sheet, making it impossible to obtain information. .

【0016】本発明に用いられる熱可塑性接着剤は、ガ
ラス転移点が−55〜15℃である、アクリル系樹脂、
酢酸ビニル系樹脂、塩化ビニル系樹脂、塩化ビニリデン
系樹脂、あるいはアクリロニトリル−ブタジエン系ゴ
ム、スチレン−ブタジエン系ゴム等の合成ゴムの中から
適宜選択して使用することができる。これらの熱可塑性
接着剤は、単独で用いても2種以上を併用しても良い。
本発明においては、特に、自己架橋型のアクリル系樹脂
を用いることが好ましい。
The thermoplastic adhesive used in the present invention is an acrylic resin having a glass transition point of −55 to 15 ° C.,
A vinyl acetate resin, a vinyl chloride resin, a vinylidene chloride resin, or a synthetic rubber such as acrylonitrile-butadiene rubber or styrene-butadiene rubber can be appropriately selected and used. These thermoplastic adhesives may be used alone or in combination of two or more kinds.
In the present invention, it is particularly preferable to use a self-crosslinking acrylic resin.

【0017】本発明においては、塗工層間に接着力を発
現させるために、表面の微細な凹凸に基づく層間の投錨
効果による機械的な接着機構を用いる。従って、投錨効
果発現の鍵を握る表面の微細な凹凸の形成を、微粒子を
接着剤組成物中に添加することによって調整する。ここ
でいう微粒子は、後述の如く、公知のものの中から適宜
選択することができるが、本発明においては、少なくと
も非熱可塑性の微粒子を含有させることが好ましい。
In the present invention, in order to develop the adhesive force between the coating layers, a mechanical adhesion mechanism by the anchoring effect between the layers based on the fine irregularities on the surface is used. Therefore, the formation of fine irregularities on the surface, which holds the key to the anchoring effect, is adjusted by adding fine particles to the adhesive composition. The fine particles referred to herein can be appropriately selected from known ones as described below, but in the present invention, it is preferable to contain at least non-thermoplastic fine particles.

【0018】本発明において使用する上記微粒子の平均
粒子径は0.5〜4μmの範囲内であることが好まし
い。平均粒子径が、0.5μm未満では十分な接着力が
発現されず、4μmを越えると微粒子が塗工層から剥落
し易くなる等、接着に弊害を及ぼす。また、平均粒子径
とは、通常、1個の粒子の大きさの平均値を示すが、例
えば、シリカのような、微細な粒子が集団を形成し、あ
たかも1個の粒子のような挙動を示す場合には、この集
団(2次粒子)の平均の大きさを意味する。
The average particle size of the fine particles used in the present invention is preferably in the range of 0.5 to 4 μm. If the average particle size is less than 0.5 μm, sufficient adhesive force is not exhibited, and if it exceeds 4 μm, fine particles are easily peeled off from the coating layer, which adversely affects adhesion. In addition, the average particle diameter usually indicates the average value of the size of one particle, but, for example, fine particles such as silica form a group and behave as if they were one particle. When indicated, it means the average size of this population (secondary particles).

【0019】本発明において、印刷機及び/又はプリン
ターによる印刷の前後における接着力の差を±30%以
内に押さえることは、曲面に囲まれた球形、紡錘形、円
盤状、円柱、多角柱、多角錘などの形状を有する、平均
粒子径が8〜25μmの粒子の添加量を調節することに
よって容易に行うことができる。このように、平均粒子
径の異なる適当な微小粒子群を利用し、接着剤塗工層表
面の三次元的構造を制御することによって、塗工層自体
の接着力の微妙なコントロールが可能となると同時に、
印刷適性に優れ、ブロッキングに対する予防効果をも有
する記録シートを製造することができる。
In the present invention, in order to suppress the difference in adhesive force between before and after printing by a printing machine and / or a printer within ± 30%, it is necessary to have a spherical shape surrounded by a curved surface, a spindle shape, a disk shape, a cylinder, a polygonal prism, a polygon. This can be easily performed by adjusting the addition amount of particles having a shape such as a weight and having an average particle diameter of 8 to 25 μm. In this way, it is possible to delicately control the adhesive force of the coating layer itself by controlling the three-dimensional structure of the adhesive coating layer surface by using appropriate fine particle groups having different average particle diameters. at the same time,
It is possible to produce a recording sheet which has excellent printability and also has an effect of preventing blocking.

【0020】本発明における接着剤組成物に用いられる
微小粒子は、シリカ、カオリン、クレー、炭酸カルシウ
ム、水酸化アルミニウム、酸化亜鉛、酸化チタン等、及
び、デンプン粒子、セルロース微粉末、メラミン系樹脂
粒子、尿素系樹脂粒子、スチレン系樹脂粒子、アクリル
系樹脂粒子、再生ナイロン粒子、塩化ビニル、ポリエチ
レン、及び、ポリカーボネートなどの、無機系あるいは
有機系の公知の微小粒子の中から適宜選択して使用する
ことができる。これらの微小粒子は、単独で用いても、
2種以上を併用しても良い。
The fine particles used in the adhesive composition of the present invention include silica, kaolin, clay, calcium carbonate, aluminum hydroxide, zinc oxide, titanium oxide, starch particles, cellulose fine powder, and melamine resin particles. , Urea-based resin particles, styrene-based resin particles, acrylic resin particles, regenerated nylon particles, vinyl chloride, polyethylene, and polycarbonate, etc. are used by appropriately selecting from known inorganic or organic fine particles. be able to. These microparticles can be used alone,
Two or more kinds may be used in combination.

【0021】本発明における、塗工層を形成する接着剤
組成物には、必要に応じ、更に、帯電防止剤、界面活性
剤、消泡剤、分散剤、防腐剤、増粘剤、湿潤剤、紫外線
吸収剤、酸化防止剤、蛍光染料、有色染料、染料定着
剤、媒染剤、及び、インク定着剤等の助剤を添加するこ
ともできる。
In the adhesive composition for forming the coating layer in the present invention, if necessary, an antistatic agent, a surfactant, a defoaming agent, a dispersant, an antiseptic agent, a thickener, and a wetting agent. Further, auxiliary agents such as an ultraviolet absorber, an antioxidant, a fluorescent dye, a colored dye, a dye fixing agent, a mordant, and an ink fixing agent can be added.

【0022】本発明の記録シートにおける接着剤組成物
の塗布量は、通常、2.5〜10g/m2 (乾燥重量)
である。2.5g/m2 未満では、接着性が十分発揮さ
れず、10g/m2 を越えると、接着力が高すぎて再剥
離が困難となり、基材が破損されるおそれがある。又、
基材に対する接着剤組成物の塗布は、エアナイフコータ
ー、ブレードコーター、バーコーター、ロールコータ
ー、カーテンコーター、スクイズコーター、キスコータ
ー、コンマコーター、グラビアコーターなどの公知の塗
布方法により設けることができる。
The coating amount of the adhesive composition in the recording sheet of the present invention is usually 2.5 to 10 g / m 2 (dry weight).
It is. If it is less than 2.5 g / m 2 , the adhesiveness is not sufficiently exhibited, and if it exceeds 10 g / m 2 , the adhesive force is too high and re-peeling becomes difficult and the substrate may be damaged. or,
The adhesive composition can be applied to the substrate by a known application method such as an air knife coater, a blade coater, a bar coater, a roll coater, a curtain coater, a squeeze coater, a kiss coater, a comma coater or a gravure coater.

【0023】[0023]

【発明の実施の形態】本発明の記録シートは、印刷機及
び/又はプリンターによる印刷の前後における接着力の
変化量が±30%以内となる様に、熱可塑性接着剤と微
小粒子等からなる疑似接着剤組成物を調整し、得られた
組成物を公知の方法によって基材表面の少なくとも一部
に塗布することによって容易に得ることができる。
BEST MODE FOR CARRYING OUT THE INVENTION The recording sheet of the present invention comprises a thermoplastic adhesive and fine particles so that the amount of change in adhesive force before and after printing by a printing machine and / or printer is within ± 30%. It can be easily obtained by preparing a pseudo adhesive composition and applying the obtained composition to at least a part of the substrate surface by a known method.

【0024】[0024]

【発明の効果】本発明の記録シートは、如何なる印刷方
法によって情報が記録されても、印刷による接着力の変
動が小さいので、印刷方法に対応させて接着条件を選定
しなくても、常に安定した疑似接着力を得ることがで
き、大量の通信・連絡業務を迅速に、かつ、安定して処
理するのに有用である。
EFFECTS OF THE INVENTION The recording sheet of the present invention has a small fluctuation in the adhesive force due to printing regardless of the printing method used, so that the recording sheet is always stable even if the adhesive conditions are not selected according to the printing method. It is possible to obtain the above pseudo adhesive strength, and it is useful for quickly and stably processing a large amount of communication and contact work.

【0025】[0025]

【実施例】以下、本発明を実施例によって更に詳述する
が、本発明はこれによって限定されるものではない。
又、特に断らない限り、以下に記載する「部」及び
「%」は、それぞれ「重量部」及び「重量%」を意味す
る。
EXAMPLES The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the invention is limited thereto.
Unless otherwise specified, “parts” and “%” described below mean “parts by weight” and “% by weight”, respectively.

【0026】実施例1.接着剤として自己架橋型アクリ
ル樹脂系エマルジョン(QTL8003:日本ゼオン株
式会社製の商品名)100部(乾燥重量)、及び微小粒
子として見かけの平均粒子径1.4μmの合成シリカ
(E220A:日本シリカ工業株式会社製の商品名)7
5部を混ぜ合わせ、目的とする疑似接着剤組成物を得
た。次に、得られた疑似接着剤組成物104.5g/m
2 を、酸性上質紙上に、塗布量が5g/m2 (乾燥重
量)となるように塗布し疑似接着性シート1を得た。
Embodiment 1 FIG. 100 parts (dry weight) of self-crosslinking acrylic resin emulsion (QTL8003: product name of Nippon Zeon Co., Ltd.) as an adhesive, and synthetic silica (E220A: Nippon Silica Industry Co., Ltd.) having an apparent average particle diameter of 1.4 μm as fine particles. (Trade name of product made by corporation) 7
5 parts were mixed to obtain an intended pseudo adhesive composition. Next, the obtained pseudo adhesive composition was 104.5 g / m.
2 was coated on acidic high-quality paper at a coating amount of 5 g / m 2 (dry weight) to obtain a pseudo-adhesive sheet 1.

【0027】実施例2.接着剤として自己架橋型アクリ
ル樹脂系エマルジョン(QTL8003)100部(乾
燥重量)、微小粒子として見かけの平均粒子径1.6μ
mの合成シリカ(E1011:日本シリカ工業株式会社
製の商品名)75部、及び、見かけの平均粒子径が16
μmのアセチル化デンプン60部を混ぜ合わせ、目的と
する疑似接着剤組成物を得た。次に、得られた疑似接着
剤組成物104.5g/m2 を、酸性上質紙上に、塗布
量が5g/m2 (乾燥重量)となるように塗布し疑似接
着性シート2を得た。
Embodiment 2 FIG. Self-crosslinking acrylic resin emulsion (QTL8003) 100 parts (dry weight) as adhesive, apparent average particle size of 1.6μ as fine particles
m of synthetic silica (E1011: trade name of Nippon Silica Industry Co., Ltd.), and an apparent average particle size of 16
60 parts of μm acetylated starch was mixed to obtain a target pseudo adhesive composition. Next, a pseudo adhesive composition 104.5 g / m 2 was obtained, the acidic woodfree paper, coated amount was obtained a pseudo-adhesive sheet 2 was coated to a 5 g / m 2 (dry weight).

【0028】実施例3.接着剤を自己架橋型アクリル樹
脂エマルジョン(AE943:日本合成ゴム株式会社製
の商品名)に変えた他は、実施例2と全く同様にして疑
似接着剤組成物を得た。次に、得られた疑似接着剤組成
物104.5g/m2 を、酸性上質紙上に、塗布量が5
g/m2 (乾燥重量)となるように塗布し疑似接着性シ
ート3を得た。
Embodiment 3 FIG. A pseudo-adhesive composition was obtained in exactly the same manner as in Example 2 except that the adhesive was changed to a self-crosslinking acrylic resin emulsion (AE943: trade name of Nippon Synthetic Rubber Co., Ltd.). Next, 104.5 g / m 2 of the obtained pseudo-adhesive composition was applied onto an acidic high-quality paper at a coating amount of 5
The pseudo-adhesive sheet 3 was obtained by coating so as to have g / m 2 (dry weight).

【0029】実施例4.接着剤として自己架橋型アクリ
ル樹脂系エマルジョン(QTL8004:日本ゼオン株
式会社製の商品名)100部(乾燥重量)、微小粒子と
して見かけの平均粒子径3.7μmの合成シリカ(X−
37B:株式会社トクヤマ製の商品名)95部、及び、
見かけの平均粒子径が16μmのアセチル化デンプン9
0部を混ぜ合わせ、目的とする疑似接着剤組成物を得
た。次に、得られた疑似接着剤組成物104.5g/m
2 を、酸性上質紙上に、塗布量が5g/m2 (乾燥重
量)となるように塗布し疑似接着性シート4を得た。
Embodiment 4 FIG. 100 parts (dry weight) of self-crosslinking acrylic resin emulsion (QTL8004: product name of Nippon Zeon Co., Ltd.) as an adhesive, synthetic silica (X- having an average average particle diameter of 3.7 μm as fine particles).
37B: trade name of Tokuyama Co., Ltd.) 95 parts, and
Acetylated starch 9 having an apparent average particle size of 16 μm
0 parts were mixed to obtain an intended pseudo adhesive composition. Next, the obtained pseudo adhesive composition was 104.5 g / m.
2 was coated on acidic high-quality paper at a coating amount of 5 g / m 2 (dry weight) to obtain a pseudo-adhesive sheet 4.

【0030】比較例1.接着剤として、固形分の変性天
然ゴムラテックス(GS5−50:クォーユー化成株式
会社製の商品名)100部、微小粒子として合成シリカ
(E220A)75部、及び、平均粒子径16μmのア
セチル化デンプン85部を混ぜ合わせ、疑似接着剤組成
物を得た。次に、得られた疑似接着剤組成物104.5
g/m2を、酸性上質紙上に、塗布量が5g/m2 (乾
燥重量)となるように塗布し疑似接着性シート5を得
た。
Comparative Example 1 As an adhesive, 100 parts of a modified natural rubber latex (GS5-50: trade name of Quyu Kasei Co., Ltd.) of solid content, 75 parts of synthetic silica (E220A) as fine particles, and acetylated starch 85 having an average particle diameter of 16 μm 85 The parts were mixed to obtain a pseudo adhesive composition. Next, the obtained pseudo adhesive composition 104.5
g / m 2 was coated on acidic wood free paper so that the coating amount was 5 g / m 2 (dry weight) to obtain a pseudo adhesive sheet 5.

【0031】比較例2.接着剤として親展ハガキ用変性
ラテックス(YV−767:カネボウ・エヌエスシー株
式会社製の商品名)100部、微小粒子として見かけの
平均粒子径2.5μmの合成シリカ50部、及び、見か
けの平均粒子径が14μmのアセチル化デンプン85部
を混ぜ合わせて疑似接着剤組成物を得た。次に、得られ
た疑似接着剤組成物104.5g/m2 を、酸性上質紙
上に、塗布量が5g/m2 (乾燥重量)となるように塗
布し、疑似接着性シート6を得た。
Comparative Example 2 As an adhesive, 100 parts of modified latex for confidential postcards (YV-767: trade name of Kanebo NSC Co., Ltd.), 50 parts of synthetic silica having an apparent average particle diameter of 2.5 μm as fine particles, and apparent average particles. A pseudo adhesive composition was obtained by mixing 85 parts of acetylated starch having a diameter of 14 μm. Next, a pseudo adhesive composition 104.5 g / m 2 was obtained, the acidic woodfree paper, the amount of coating. The coating is 5 g / m 2 (dry weight), to obtain a pseudo-adhesive sheet 6 .

【0032】比較例3.微小粒子としてのシリカの量を
30部、及び、アセチル化デンプンの量を20部に変え
た他は、比較例2と全く同様にして疑似接着剤組成物を
得た。次に、得られた接着剤組成物104.5g/m2
を、酸性上質紙上に、塗布量が5g/m2(乾燥重量)と
なるように塗布し疑似接着性シート7を得た。
Comparative Example 3 A pseudo adhesive composition was obtained in exactly the same manner as Comparative Example 2 except that the amount of silica as fine particles was changed to 30 parts and the amount of acetylated starch was changed to 20 parts. Next, the obtained adhesive composition 104.5 g / m 2
Was coated on an acidic high-quality paper at a coating amount of 5 g / m 2 (dry weight) to obtain a pseudo-adhesive sheet 7.

【0033】比較例4.微小粒子としてのシリカを使わ
ずに、アセチル化デンプンの量を25部に変えた他は、
比較例2と全く同様にして疑似接着剤組成物を得た。次
に、得られた接着剤組成物104.5g/m2 を、酸性
上質紙上に、塗布量が5g/m2 (乾燥重量)となるよ
うに塗布し疑似接着性シート8を得た。
Comparative Example 4 Other than changing the amount of acetylated starch to 25 parts without using silica as fine particles,
A pseudo adhesive composition was obtained in exactly the same manner as in Comparative Example 2. Next, the obtained adhesive composition 104.5 g / m 2, in acidic woodfree paper, coated amount was obtained a pseudo-adhesive sheet 8 was coated to a 5 g / m 2 (dry weight).

【0034】比較例5.微小粒子としてのアセチル化デ
ンプンを使わず、また、シリカの使用量を30部に変え
た他は、比較例2と全く同様にして疑似接着剤組成物を
得た。次に、得られた接着剤組成物104.5g/m2
を、酸性上質紙上に、塗布量が5g/m2(乾燥重量)と
なるように塗布し疑似接着性シート9を得た。
Comparative Example 5 A pseudo adhesive composition was obtained in exactly the same manner as Comparative Example 2 except that acetylated starch as fine particles was not used and the amount of silica used was changed to 30 parts. Next, the obtained adhesive composition 104.5 g / m 2
Was coated on an acidic high-quality paper at a coating amount of 5 g / m 2 (dry weight) to obtain a pseudo-adhesive sheet 9.

【0035】実施例1〜4、及び、比較例1〜5から得
られたシートを用いて、下記のように(1)紫外線照射
処理、及び(2)熱処理した後に、接着力、及びブロッ
キング性を測定し、下記の基準によって評価した結果
は、表1に示した通りである。
Using the sheets obtained from Examples 1 to 4 and Comparative Examples 1 to 5, after the following (1) UV irradiation treatment and (2) heat treatment, the adhesive strength and blocking property were obtained. Is measured and evaluated according to the following criteria. The results are shown in Table 1.

【0036】[0036]

【表1】 [Table 1]

【0037】(1)紫外線照射処理:試料を20℃、6
5%RHの環境下に24時間以上放置した後、3kwの
メタルハライドランプを用いて、試料面上10cmの高
さから、250ミリ秒間、照射処理を行った。 (2)熱処理:試料を20℃、65%RHの環境下に2
4時間以上放置した後、表面温度が約190℃の加熱ロ
ールと給紙ロールの間を、5m/分の速度で、試料面が
加熱ロールに接触するように通過させた。
(1) Ultraviolet irradiation treatment: The sample was treated at 20 ° C. for 6 hours.
After leaving in an environment of 5% RH for 24 hours or more, irradiation treatment was performed for 250 milliseconds from a height of 10 cm above the sample surface using a 3 kw metal halide lamp. (2) Heat treatment: The sample is placed in an environment of 20 ° C and 65% RH for 2
After standing for 4 hours or more, the sample was passed between a heating roll having a surface temperature of about 190 ° C. and a paper feeding roll at a speed of 5 m / min so that the sample surface was in contact with the heating roll.

【0038】接着力:試料を、20℃、65%RHの環
境下に24時間以上放置した後、ローラータイプのプレ
ス機を用いて、線圧60kgf/cm、10m/分の速
度で加圧接着させ、2時間後に、JIS−K6854に
準じてT型剥離試験を行った。尚、評価は、印刷を行う
前の接着強さを1インチ当たりのgfとした。 定着処理後の接着力の変化が、印刷前の接着力の30%以内のもの・・・・○ 定着処理後の接着力の変化が、印刷前の接着力の30%より大きいもの・・×
Adhesive strength: The sample was left in an environment of 20 ° C. and 65% RH for 24 hours or more, and then pressure-bonded at a linear pressure of 60 kgf / cm and a speed of 10 m / min using a roller type press. Then, after 2 hours, a T-type peeling test was performed according to JIS-K6854. In the evaluation, the adhesive strength before printing was gf per inch. Change in adhesive strength after fixing treatment is within 30% of adhesive strength before printing ... ・ ○ Change in adhesive strength after fixing treatment is larger than 30% of adhesive strength before printing.

【0039】ブロッキング試験:100枚重ねた試料
に、20℃、65%RHの環境下で20kgf/cm2
の圧力をかけ、一昼夜放置した後に、手で剥がすことに
より評価した。 ・容易に剥がれるもの・・・・・・・・・・・・・○ ・剥がれにくいもの・・・・・・・・・・・・・・×
Blocking test: 100 sheets of the sample were stacked, and 20 kgf / cm 2 under the environment of 20 ° C. and 65% RH.
The sample was evaluated by peeling it by hand after leaving it under pressure for 24 hours.・ Easy peeling ・ ・ ・ ・ ・ ・ ・ ・ ・ ○ ・ Difficult to peel ・ ・ ・ ・ ×

─────────────────────────────────────────────────────
─────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成8年3月28日[Submission date] March 28, 1996

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0026[Correction target item name] 0026

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0026】実施例1.接着剤として自己架橋型アクリ
ル樹脂系エマルジョン(QTL8003:日本ゼオン株
式会社製の商品名)100部(乾燥重量)、及び微小粒
子として見かけの平均粒子径1.4μmの合成シリカ
(E220A:日本シリカ工業株式会社製の商品名)7
5部を混ぜ合わせ、目的とする疑似接着剤組成物を得
た。次に、得られた疑似接着剤組成物を、坪量が10
4.5g/m 酸性上質紙上に、塗布量が5g/m
(乾燥重量)となるように塗布し疑似接着性シート1を
得た。
Embodiment 1 FIG. 100 parts (dry weight) of self-crosslinking acrylic resin emulsion (QTL8003: product name of Nippon Zeon Co., Ltd.) as an adhesive, and synthetic silica (E220A: Nippon Silica Industry Co., Ltd.) having an apparent average particle diameter of 1.4 μm as fine particles. (Trade name of product made by corporation) 7
5 parts were mixed to obtain an intended pseudo adhesive composition. Next, the obtained pseudo-adhesive composition had a basis weight of 10
The amount of coating is 5 g / m 2 on 4.5 g / m 2 acidic high-quality paper.
It was applied so as to have a (dry weight) to obtain a pseudo adhesive sheet 1.

【手続補正2】[Procedure amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0027[Correction target item name] 0027

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0027】実施例2.接着剤として自己架橋型アクリ
ル樹脂系エマルジョン(QTL8003)100部(乾
燥重量)、微小粒子として見かけの平均粒子径1.6μ
mの合成シリカ(E1011:日本シリカ工業株式会社
製の商品名)75部、及び、見かけの平均粒子径が16
μmのアセチル化デンプン60部を混ぜ合わせ、目的と
する疑似接着剤組成物を得た。次に、得られた疑似接着
剤組成物を、坪量が104.5g/m 酸性上質紙上
に、塗布量が5g/m(乾燥重量)となるように塗布
し疑似接着性シート2を得た。
Embodiment 2 FIG. Self-crosslinking acrylic resin emulsion (QTL8003) 100 parts (dry weight) as adhesive, apparent average particle size of 1.6μ as fine particles
m of synthetic silica (E1011: trade name of Nippon Silica Industry Co., Ltd.), and an apparent average particle size of 16
60 parts of μm acetylated starch was mixed to obtain a target pseudo adhesive composition. Then, the resultant pseudo-adhesive composition, basis weight acidic woodfree paper of 104.5 g / m 2, was coated with the coating amount is 5 g / m 2 (dry weight) Pseudo adhesive sheet 2 Got

【手続補正3】[Procedure 3]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0028[Correction target item name] 0028

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0028】実施例3.接着剤を自己架橋型アクリル樹
脂エマルジョン(AE943:日本合成ゴム株式会社製
の商品名)に変えた他は、実施例2と全く同様にして疑
似接着剤組成物を得た。次に、得られた疑似接着剤組成
を、坪量が104.5g/m 酸性上質紙上に、塗
布量が5g/m(乾燥重量)となるように塗布し疑似
接着性シート3を得た。
Embodiment 3 FIG. A pseudo-adhesive composition was obtained in exactly the same manner as in Example 2 except that the adhesive was changed to a self-crosslinking acrylic resin emulsion (AE943: trade name of Nippon Synthetic Rubber Co., Ltd.). Then, the resultant pseudo-adhesive composition, the acidic quality paper having a basis weight of 104.5 g / m 2, the pseudo-adhesive sheet 3 was coated so that the amount of coating is 5 g / m 2 (dry weight) Got

【手続補正4】[Procedure amendment 4]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0029[Name of item to be corrected] 0029

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0029】実施例4.接着剤として自己架橋型アクリ
ル樹脂系エマルジョン(QTL8004:日本ゼオン株
式会社製の商品名)100部(乾燥重量)、微小粒子と
して見かけの平均粒子径3.7μmの合成シリカ(X−
37B:株式会社トクヤマ製の商品名)95部、及び、
見かけの平均粒子径が16μmのアセチル化デンプン9
0部を混ぜ合わせ、目的とする疑似接着剤組成物を得
た。次に、得られた疑似接着剤組成物を、坪量が10
4.5g/m 酸性上質紙上に、塗布量が5g/m
(乾燥重量)となるように塗布し疑似接着性シート4を
得た。
Embodiment 4 FIG. 100 parts (dry weight) of self-crosslinking acrylic resin emulsion (QTL8004: product name of Nippon Zeon Co., Ltd.) as an adhesive, synthetic silica (X- having an average average particle diameter of 3.7 μm as fine particles).
37B: trade name of Tokuyama Co., Ltd.) 95 parts, and
Acetylated starch 9 having an apparent average particle size of 16 μm
0 parts were mixed to obtain an intended pseudo adhesive composition. Next, the obtained pseudo-adhesive composition had a basis weight of 10
The amount of coating is 5 g / m 2 on 4.5 g / m 2 acidic high-quality paper.
A pseudo adhesive sheet 4 was obtained by coating so as to have a (dry weight).

【手続補正5】[Procedure Amendment 5]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0030[Correction target item name] 0030

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0030】比較例1.接着剤として、固形分の変性天
然ゴムラテックス(GS5−50:クォーユー化成株式
会社製の商品名)100部、微小粒子として合成シリカ
(E220A)75部、及び、平均粒子径16μmのア
セチル化デンプン85部を混ぜ合わせ、疑似接着剤組成
物を得た。次に、得られた疑似接着剤組成物を、坪量が
104.5g/m 酸性上質紙上に、塗布量が5g/
(乾燥重量)となるように塗布し疑似接着性シート
5を得た。
Comparative Example 1 As an adhesive, 100 parts of a modified natural rubber latex (GS5-50: trade name of Quyu Kasei Co., Ltd.) of solid content, 75 parts of synthetic silica (E220A) as fine particles, and acetylated starch 85 having an average particle diameter of 16 μm 85 The parts were mixed to obtain a pseudo adhesive composition. Next, the obtained pseudo-adhesive composition was applied onto an acidic high-quality paper having a basis weight of 104.5 g / m 2 in an application amount of 5 g / m 2.
m 2 to obtain a coating with pseudo-adhesive sheet 5 so that the (dry weight).

【手続補正6】[Procedure correction 6]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0031[Correction target item name] 0031

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0031】比較例2.接着剤として親展ハガキ用変性
ラテックス(YV−767:カネボウ・エヌエスシー株
式会社製の商品名)100部、微小粒子として見かけの
平均粒子径2.5μmの合成シリカ50部、及び、見か
けの平均粒子径が14μmのアセチル化デンプン85部
を混ぜ合わせて疑似接着剤組成物を得た。次に、得られ
た疑似接着剤組成物を、坪量が104.5g/m
性上質紙上に、塗布量が5g/m(乾燥重量)となる
ように塗布し、疑似接着性シート6を得た。
Comparative Example 2 As an adhesive, 100 parts of modified latex for confidential postcards (YV-767: trade name of Kanebo NSC Co., Ltd.), 50 parts of synthetic silica having an apparent average particle diameter of 2.5 μm as fine particles, and apparent average particles. A pseudo adhesive composition was obtained by mixing 85 parts of acetylated starch having a diameter of 14 μm. Then, the resultant pseudo-adhesive composition, basis weight acid <br/> of fine paper of 104.5 g / m 2, was coated with the coating amount is 5 g / m 2 (dry weight) A pseudo adhesive sheet 6 was obtained.

【手続補正7】[Procedure amendment 7]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0032[Name of item to be corrected] 0032

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0032】比較例3.微小粒子としてのシリカの量を
30部、及び、アセチル化デンプンの量を20部に変え
た他は、比較例2と全く同様にして疑似接着剤組成物を
得た。次に、得られた接着剤組成物を、坪量が104.
5g/m 酸性上質紙上に、塗布量が5g/m(乾
燥重量)となるように塗布し疑似接着性シート7を得
た。
Comparative Example 3 A pseudo adhesive composition was obtained in exactly the same manner as Comparative Example 2 except that the amount of silica as fine particles was changed to 30 parts and the amount of acetylated starch was changed to 20 parts. Next, the obtained adhesive composition had a basis weight of 104.
A pseudo-adhesive sheet 7 was obtained by coating 5 g / m 2 of acidic high-quality paper so that the coating amount was 5 g / m 2 (dry weight).

【手続補正8】[Procedure amendment 8]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0033[Correction target item name] 0033

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0033】比較例4.微小粒子としてのシリカを使わ
ずに、アセチル化デンプンの量を25部に変えた他は、
比較例2と全く同様にして疑似接着剤組成物を得た。次
に、得られた接着剤組成物を、坪量が104.5g/m
酸性上質紙上に、塗布量が5g/m(乾燥重量)
となるように塗布し疑似接着性シート8を得た。
Comparative Example 4 Other than changing the amount of acetylated starch to 25 parts without using silica as fine particles,
A pseudo adhesive composition was obtained in exactly the same manner as in Comparative Example 2. Next, the basis weight of the obtained adhesive composition is 104.5 g / m.
5g / m 2 (dry weight) on 2 acidic high-quality paper
To obtain a pseudo adhesive sheet 8.

【手続補正9】[Procedure amendment 9]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0034[Correction target item name] 0034

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0034】比較例5.微小粒子としてのアセチル化デ
ンプンを使わず、また、シリカの使用量を30部に変え
た他は、比較例2と全く同様にして疑似接着剤組成物を
得た。次に、得られた接着剤組成物を、坪量が104.
5g/mの酸性上質紙上に、塗布量が5g/m(乾
燥重量)となるように塗布し疑似接着性シート9を得
た。
Comparative Example 5 A pseudo adhesive composition was obtained in exactly the same manner as Comparative Example 2 except that acetylated starch as fine particles was not used and the amount of silica used was changed to 30 parts. Next, the obtained adhesive composition had a basis weight of 104.
A pseudo-adhesive sheet 9 was obtained by coating 5 g / m 2 of acidic high-quality paper so that the coating amount was 5 g / m 2 (dry weight).

フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C09J 7/02 JKL C09J 7/02 JKL JLE JLE (72)発明者 安田 強 東京都新宿区上落合1丁目30番6号 日本 製紙株式会社商品開発研究所内Continuation of front page (51) Int.Cl. 6 Identification number Office reference number FI Technical display location C09J 7/02 JKL C09J 7/02 JKL JLE JLE (72) Inventor Tsuyoshi Yasuda 1-30 Kamamiochai, Shinjuku-ku, Tokyo No. 6 in the Product Development Laboratory, Nippon Paper Industries Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 熱可塑性接着剤と微小粒子を主たる成分
として含有する疑似接着性の接着剤組成物を基材表面の
少なくとも一部に塗布してなる、疑似接着力が10〜3
50gf/in.である、通信用又は配送用の記録シー
トであって、前記接着剤組成物を塗布してなる層が、そ
の層上に印刷機及び/又はプリンターによって印刷がな
された前後において、疑似接着力の強さの変化量が±3
0%以内となる層であることを特徴とする、感圧疑似接
着性の記録シート。
1. A pseudo adhesive force of 10 to 3 obtained by applying a pseudo adhesive adhesive composition containing a thermoplastic adhesive and fine particles as main components to at least a part of the surface of a substrate.
50 gf / in. Which is a recording sheet for communication or delivery, wherein a layer formed by applying the adhesive composition has a pseudo adhesive force before and after printing on the layer by a printing machine and / or a printer. The amount of change in strength is ± 3
A pressure-sensitive pseudo-adhesive recording sheet having a layer content of 0% or less.
【請求項2】 熱可塑性接着剤のガラス転移点が−55
〜15℃であると共に、微小粒子が同種あるいは異種の
粒子の混合物であって、見かけの平均粒子径が少なくと
も0.5〜4μmであるもの、及び、必要に応じて平均
粒子径が8〜25μmであるものを更に組み合わせてな
るものである、請求項1に記載された記録シート。
2. The glass transition point of the thermoplastic adhesive is -55.
˜15 ° C., the fine particles are a mixture of particles of the same kind or different kinds, and the apparent average particle diameter is at least 0.5 to 4 μm, and, if necessary, the average particle diameter is 8 to 25 μm. The recording sheet according to claim 1, further comprising a combination of the following.
JP05083896A 1996-02-14 1996-02-14 Record sheet Expired - Lifetime JP3565527B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP05083896A JP3565527B2 (en) 1996-02-14 1996-02-14 Record sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP05083896A JP3565527B2 (en) 1996-02-14 1996-02-14 Record sheet

Publications (2)

Publication Number Publication Date
JPH09228299A true JPH09228299A (en) 1997-09-02
JP3565527B2 JP3565527B2 (en) 2004-09-15

Family

ID=12869895

Family Applications (1)

Application Number Title Priority Date Filing Date
JP05083896A Expired - Lifetime JP3565527B2 (en) 1996-02-14 1996-02-14 Record sheet

Country Status (1)

Country Link
JP (1) JP3565527B2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000202974A (en) * 1999-01-19 2000-07-25 Dainippon Printing Co Ltd Laminate
JP2000326470A (en) * 1999-05-19 2000-11-28 Dainippon Printing Co Ltd Laminate and manufacture thereof
JP2001262098A (en) * 2000-03-23 2001-09-26 Toppan Forms Co Ltd Pressure-sensitive adhesive composition having excellent water resistance and information-carrying sheet using the same
JP2001262099A (en) * 2000-03-23 2001-09-26 Toppan Forms Co Ltd Pressure-sensitive adhesive composition having excellent resistance to deterioration and information-carrying sheet using the same
JP2001262102A (en) * 2000-03-23 2001-09-26 Toppan Forms Co Ltd Pressure-sensitive adhesive composition having excellent deterioration resistance and sheet using the same used for carrying information
JP2005153317A (en) * 2003-11-26 2005-06-16 Sato Corp Distribution and transportation slip
JP2021038488A (en) * 2019-09-03 2021-03-11 王子ホールディングス株式会社 Base paper for pseudo-adhesive paper, pseudo-adhesive paper, and delivery slip paper

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000202974A (en) * 1999-01-19 2000-07-25 Dainippon Printing Co Ltd Laminate
JP2000326470A (en) * 1999-05-19 2000-11-28 Dainippon Printing Co Ltd Laminate and manufacture thereof
JP2001262098A (en) * 2000-03-23 2001-09-26 Toppan Forms Co Ltd Pressure-sensitive adhesive composition having excellent water resistance and information-carrying sheet using the same
JP2001262099A (en) * 2000-03-23 2001-09-26 Toppan Forms Co Ltd Pressure-sensitive adhesive composition having excellent resistance to deterioration and information-carrying sheet using the same
JP2001262102A (en) * 2000-03-23 2001-09-26 Toppan Forms Co Ltd Pressure-sensitive adhesive composition having excellent deterioration resistance and sheet using the same used for carrying information
JP2005153317A (en) * 2003-11-26 2005-06-16 Sato Corp Distribution and transportation slip
JP2021038488A (en) * 2019-09-03 2021-03-11 王子ホールディングス株式会社 Base paper for pseudo-adhesive paper, pseudo-adhesive paper, and delivery slip paper

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