JPH09207230A - Manufacture of lightweight fiberboard - Google Patents

Manufacture of lightweight fiberboard

Info

Publication number
JPH09207230A
JPH09207230A JP8037215A JP3721596A JPH09207230A JP H09207230 A JPH09207230 A JP H09207230A JP 8037215 A JP8037215 A JP 8037215A JP 3721596 A JP3721596 A JP 3721596A JP H09207230 A JPH09207230 A JP H09207230A
Authority
JP
Japan
Prior art keywords
mat
fiber
binder
reactivating
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8037215A
Other languages
Japanese (ja)
Inventor
Koji Murata
功二 村田
Kazuhiro Sato
和博 佐藤
Shoichi Oba
正一 大場
Takeshi Toda
戸田  剛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daiken Trade and Industry Co Ltd
Original Assignee
Daiken Trade and Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daiken Trade and Industry Co Ltd filed Critical Daiken Trade and Industry Co Ltd
Priority to JP8037215A priority Critical patent/JPH09207230A/en
Publication of JPH09207230A publication Critical patent/JPH09207230A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To efficiently manufacture a large strength lightweight fiberboard irrespective of its low specific gravity. SOLUTION: Powdery size being a reactivating binder and water are added to a natural fiber, which are mixed. An inside of the fiber is impregnated with water. A surface of the fiber is dotted with the powdery size, and it is stuck thereto. After molding the mixture in a mat state, the mat state material is treated by heating by supplying heat and water content from its one face in a drying chamber and sucking vapor from the other face. While transpiration of water content in the mat-like material is prevented by this heating, the size stuck to the surface of fiber is activated (melted), and fibers are bonded to each other. Thereafter, a large strength low specific gravity lightweight fiberboard is obtained by drying treatment with only heat.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は軽量の板状体、特に
発泡樹脂板に代わり得る軽量な繊維板の製造方法に関す
るものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a lightweight plate-like body, particularly a lightweight fiberboard which can replace a foamed resin board.

【0002】[0002]

【従来の技術】発泡樹脂板は軽量性、保温性、クッショ
ン性に優れており、この性能を利用して各種の用途に採
用されているが、分解しないために廃棄処理が困難であ
ると共に、焼却時には高温を発するために焼却炉を損傷
させるという問題点がある。一方、廃棄処理が容易な板
状体としては繊維板があり、湿式法と乾式法とのいずれ
かによって製造されるが、湿式法は繊維物質を水中に分
散させると共に結合剤その他の添加剤を添加してスラリ
ーとなし、これを抄造して得られるウエットマットを脱
水したのち加熱、乾燥するものであるから、製造に多く
のエネルギーを要するばかりでなく、この方法では得ら
れる繊維板の比重が0.2 〜0.35であって、軽量性に劣る
ものである。
2. Description of the Related Art Foamed resin plates are excellent in lightness, heat retention and cushioning properties, and are used in various applications by utilizing this performance, but they are difficult to dispose because they do not decompose. There is a problem that the incinerator is damaged due to the high temperature generated during incineration. On the other hand, as a plate-like body that can be easily disposed of, there is a fiber plate, which is manufactured by either a wet method or a dry method.The wet method disperses the fiber substance in water and adds a binder and other additives. Addition to form a slurry, the wet mat obtained by papermaking is dehydrated, then heated and dried, so that not only a lot of energy is required for production, but the specific gravity of the fiber board obtained by this method is It is 0.2 to 0.35, which is inferior in lightness.

【0003】これに対して、乾式法は繊維物質の結合剤
との混合物をフォーマーによってマット状に成形し、こ
のマット状物を加熱することによって結合剤を反応硬化
させて繊維間を結合、固定することにより得られるもの
であるから、有機繊維の場合には成形時の圧力に応じて
比重が0.07〜0.40程度の範囲内で用途に応じた繊維板を
製造することができ、低比重繊維板を得ることができ
る。
In the dry method, on the other hand, a mixture of a fibrous substance and a binder is formed into a mat by a former, and the mat is heated to cure the binder to bond and fix the fibers. Therefore, in the case of an organic fiber, a specific gravity depending on the pressure at the time of molding can produce a fiber board according to the use within a range of about 0.07 to 0.40, and a low specific gravity fiber board. Can be obtained.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、従来の
乾式法では多量の結合剤を要する上に、マット状物が厚
い場合には一面側からの熱を内部にまで均一に伝達する
ことができず、表層部と中層部とでは硬度が異なって保
形性に劣ることになる。このため、結合剤としてフェノ
ールや尿素、メラミンなどの水溶性熱硬化性樹脂を使用
し、繊維物質に該樹脂を混合してマット状に成形し、こ
のマット状物に水蒸気を通過させる方法が開発された
が、この方法によれば、水蒸気の通過によってマット内
部の樹脂まで均一に硬化され、短時間で乾燥処理が行え
るという利点を有する反面、水溶性熱硬化性樹脂の化学
反応によって繊維同士を接着させるものであるから、一
部溶解した樹脂が繊維に吸収されると共に比較的大きな
加圧を必要とし、厚みの大なる低比重繊維板を製造した
場合には強度が劣ることになる。本発明はこのような問
題点を解消し、強度においても優れた性能を発揮する軽
量繊維板の製造方法を提供するものである。
However, in the conventional dry method, a large amount of binder is required, and when the mat-like material is thick, heat from one side cannot be evenly transferred to the inside. However, the surface layer portion and the middle layer portion have different hardnesses, resulting in poor shape retention. For this reason, a method has been developed in which a water-soluble thermosetting resin such as phenol, urea, or melamine is used as a binder, the resin is mixed with a fibrous material to form a mat, and water vapor is passed through the mat. However, according to this method, even though the resin inside the mat is uniformly cured by the passage of water vapor, and the drying treatment can be performed in a short time, on the other hand, the fibers react with each other by the chemical reaction of the water-soluble thermosetting resin. Since the resin is adhered, a part of the dissolved resin is absorbed by the fiber and relatively large pressure is required, and when a low specific gravity fiber board having a large thickness is manufactured, the strength is deteriorated. The present invention solves such problems and provides a method for manufacturing a lightweight fiberboard that exhibits excellent performance in strength.

【0005】[0005]

【課題を解決するための手段】本発明の軽量繊維板の製
造方法は、繊維物質に粉末の再活性化性結合剤と水とを
添加してなる混合物をマット状に成形し、このマットの
一面より熱及び水分を供給する一方、他面より空気を排
出することによってマット内の上記再活性化性結合剤を
活性化させて繊維物質表面に接着させ、次いで熱のみを
供給してマットを乾燥させることを特徴とするものであ
る。
According to the method for producing a lightweight fiberboard of the present invention, a mixture obtained by adding a powder reactivating binder and water to a fibrous material is molded into a mat, and the mat of the mat is formed. Heat and moisture are supplied from one side, while air is discharged from the other side to activate the above-mentioned reactivating binder in the mat to adhere to the surface of the fibrous material, and then only heat is supplied to the mat. It is characterized by being dried.

【0006】[0006]

【発明の実施の形態】軽量繊維板の主成分である繊維物
質としては、木質繊維、綿などの天然繊維を用いるが、
適量の合成繊維を混合させておいてもよい。この繊維物
質に添加する再活性化性結合剤としては、冷水中では不
溶で熱水中で可溶化、即ち活性化(ゲル化)する粉末状
の澱粉またはポリビニールアルコールを用いる。繊維物
質に再活性化性結合剤を添加、混合してマット状物に成
形するに際して清水を適量添加し、繊維物質と再活性化
性結合剤との混合時における繊維物質や再活性化性結合
剤の飛散を防止すると共に繊維物質表面に再活性化性結
合剤を付着させ、さらに、繊維物質内に水分を浸透させ
ておくことにより、爾後における再活性化性結合剤の活
性時において結合剤が繊維物質内へ浸入するのを防止す
る。
BEST MODE FOR CARRYING OUT THE INVENTION Natural fibers such as wood fiber and cotton are used as the fiber substance which is the main component of the lightweight fiberboard.
You may mix an appropriate amount of synthetic fibers. As the reactivating binder to be added to the fibrous substance, powdery starch or polyvinyl alcohol which is insoluble in cold water but solubilizes in hot water, that is, is activated (gelled) is used. When a reactivating binder is added to the fiber material and mixed to form a mat-like material, an appropriate amount of fresh water is added, and the fiber material and the reactivating bond are mixed when the fiber material and the reactivating binder are mixed. By preventing the agent from scattering and attaching a reactivating binder to the surface of the fiber substance, and further allowing water to penetrate into the fiber substance, the binder is activated when the reactivating binder is activated after that. Prevent the ingress of fibrous material.

【0007】このように、繊維物質に粉末の再活性化性
結合剤と清水とを添加、混合し、この混合物をマットフ
ォーマーによってマット状物に成形する。この際、混合
物の量とマット状に圧縮する圧力によって得られる軽量
繊維板の厚みや比重が設定される。なお、マット状物に
成形しても繊維物質に添加、混合している再活性化性結
合剤は繊維物質表面に付着しているが加熱されていない
ために活性化しない。しかしながら、ポリビニールアル
コールの場合は一部溶解が生じている場合もある。従っ
て、繊維物質に再活性化性結合剤を添加、混合する場
合、この結合剤は熱硬化性樹脂とは異なって混合時に殆
ど溶解しないので、マット状物内に万遍なく分散し、繊
維物質に対しては点状に付着した状態となる。
Thus, the powdery reactivating binder and fresh water are added to and mixed with the fibrous material, and the mixture is formed into a mat-like material by a mat former. At this time, the thickness and specific gravity of the lightweight fiberboard obtained by the amount of the mixture and the pressure of compressing the mat are set. Even when formed into a mat-like material, the reactivating binder which is added to and mixed with the fibrous substance is attached to the surface of the fibrous substance but not activated because it is not heated. However, in the case of polyvinyl alcohol, some dissolution may occur. Therefore, when the reactivating binder is added to and mixed with the fibrous substance, unlike the thermosetting resin, the binder hardly dissolves during the mixing, so that the fibrous substance is evenly dispersed in the mat-like material. In contrast, the dots are attached in a dot shape.

【0008】こうして成形されたマット状物は乾燥室内
に搬入され、その一面より熱及び水分を供給する一方、
他面より吸気してマット状物内の空気を排出することに
より加熱処理を施す。なお、熱及び水分の供給手段とし
ては水蒸気の形で行ってもよく、また、熱風と水との噴
霧の形で供給してもよい。この結果、マット状物中の水
分は蒸発することなく温度が上昇し、繊維物質表面に点
状に散在、付着している再活性化性結合剤は繊維物質内
に吸収されることなく該繊維物質表面で溶解して繊維物
質同士を接着させる。また、マット状物の他面からの強
制排気によって熱がマット状物全体に均一に通過、伝達
し、マット状物が表層部と中心部とで接着性に差が生じ
ることなくマット状物の構成する繊維物質全体を均一に
接着させる。
The mat-like material thus molded is carried into the drying chamber and heat and moisture are supplied from one side thereof,
Heat treatment is performed by sucking air from the other surface and discharging the air in the mat-like material. The heat and water may be supplied in the form of water vapor or in the form of spray of hot air and water. As a result, the moisture in the mat-like material rises in temperature without evaporating, and the reactivating binder adhering to the surface of the fibrous material in points is scattered without being absorbed in the fibrous material. It melts on the surface of the substance and bonds the fibrous substances together. Further, the heat is uniformly transmitted and transferred to the entire mat-like material by forced exhaust from the other surface of the mat-like material, and the mat-like material does not have a difference in adhesiveness between the surface layer portion and the central portion. The entire constituent fibrous material is evenly adhered.

【0009】上記のように、繊維物質間を再活性化性結
合剤の活性化によって接着させたのち、次いで、マット
状物に熱風を供給してマット状物に含まれている水分を
蒸散させ、マット状物を乾燥させることによって軽量繊
維板を得るものである。この際、マット状物中の水分は
上記加熱処理によって高温となっているので、容易に蒸
発し、短時間で乾燥させることができる。次に、本発明
の具体的な実施例と比較例とを示す。
After the fibrous substances are bonded to each other by the activation of the reactivating binder as described above, hot air is then supplied to the mat-like material to evaporate the water contained in the mat-like material. A lightweight fiberboard is obtained by drying the mat-like material. At this time, since the water content in the mat-like material is at a high temperature due to the above heat treatment, it can be easily evaporated and dried in a short time. Next, specific examples and comparative examples of the present invention will be described.

【0010】[0010]

【実施例】セルロース系ファイバー1296gにコーンスタ
ーチ291 g、清水786 gを均一に添加、混合し、この混
合物を長さ500mm ×幅500mm ×厚さ30mmのマット状物に
成形したのち、その厚さを保持したまゝ、乾燥室内で1
2=当たり、温度160 ℃の蒸気を450kg/hrの条件でマッ
ト状物の一面に吹き付けながら他面から吸気すると共に
150 ℃の高温空気を0.24m/sの風速でマット内を通気
させ、コーンスターチを糊化させた。コーンスターチの
糊化に要した時間は60sec であり、その後、蒸気の供給
を停止し、高温空気のみを1.6 m/sの風速でもってマ
ット状物に通過させることによりマット状物を乾燥させ
て軽量繊維板を得た。
[Examples] To 1296 g of cellulosic fiber, 291 g of corn starch and 786 g of clear water were uniformly added and mixed, and this mixture was molded into a mat-like material having a length of 500 mm x a width of 500 mm x a thickness of 30 mm, and then the thickness thereof was measured. Keep it 1 in the drying room
m 2 = per unit, while spraying steam with a temperature of 160 ° C on one surface of the mat-like material under the condition of 450 kg / hr, while sucking air from the other surface
Hot air at 150 ° C. was passed through the mat at a wind speed of 0.24 m / s to gelatinize the corn starch. The time required for gelatinization of cornstarch was 60 seconds, after which the steam supply was stopped and only hot air was passed through the mat at a wind speed of 1.6 m / s to dry the mat and reduce the weight. A fiberboard was obtained.

【0011】比較例として、セルロース系ファイバー12
96gに粉末状メラミン・ホルムアルデヒド樹脂(商品名
ニカレジン、日本カーバイト製)285 gと塩化アンモニ
ウム3gを均一に添加、混合した。この混合物を長さ50
0mm ×幅500mm ×厚さ30mmのマット状物に成形したの
ち、その厚さを保持したまゝ、乾燥室内で1m2=当た
り、温度160 ℃の蒸気を450kg/hrの条件でマット状物の
吹き付けながら150 ℃の高温空気を0.14m/sの風速で
通気させることによりマット状物中の上記樹脂を硬化さ
せた。硬化時間は150secであり、その後、蒸気の供給を
停止し、高温空気の風速を1.6 m/sまで上昇させてマ
ット状物を乾燥させることにより軽量繊維板を得た。
As a comparative example, a cellulosic fiber 12
To 96 g, 285 g of powdered melamine-formaldehyde resin (trade name Nikaresin, made by Nippon Carbide) and 3 g of ammonium chloride were uniformly added and mixed. Length 50 of this mixture
After forming into a mat-like material of 0 mm × width 500 mm × thickness 30 mm, while maintaining the thickness, 1 m 2 = per 1 m 2 = in the drying chamber, steam at a temperature of 160 ° C is 450 kg / hr under conditions of 450 kg / hr. The resin in the mat-like material was cured by blowing hot air of 150 ° C. at a wind speed of 0.14 m / s while spraying. The curing time was 150 seconds, after which the supply of steam was stopped, the air velocity of the hot air was increased to 1.6 m / s, and the mat-like material was dried to obtain a lightweight fiberboard.

【0012】上記実施例と比較例の製造条件の相違を表
1に、物性を表2に示す。表2において、平面引張強度
試験は、繊維板の上下に金属製の治具を接着し、下側の
治具を固定して上側を50mm/minの速度で上昇させたとき
の最大破壊強度(応力)を示す。また、曲げ強度は、繊
維板にスパン200mm の3点荷重の曲げ試験を行った時の
曲げヤング率(MOE) と曲げ強さ(MOR) を示す。さらに、
圧縮試験は、繊維板を該繊維板よりも大きな治具で5mm
/minの速度で圧縮した時の圧縮比例限界点と圧縮ヤング
率を求めた。
Table 1 shows the difference in the manufacturing conditions between the above-mentioned Examples and Comparative Examples, and Table 2 shows the physical properties. In Table 2, the plane tensile strength test is the maximum breaking strength when a jig made of metal is adhered to the upper and lower sides of the fiber board, the lower jig is fixed, and the upper side is raised at a speed of 50 mm / min ( Stress). The flexural strength is the flexural Young's modulus (MOE) and flexural strength (MOR) of a fiberboard subjected to a flexural test under a 3-point load with a span of 200 mm. further,
The compression test is performed by using a fiber board with a jig larger than the fiber board,
The compression proportional limit point and the compressive Young's modulus were obtained when compressed at a speed of / min.

【0013】[0013]

【表1】 [Table 1]

【0014】[0014]

【表2】 [Table 2]

【0015】上記表2から明らかなように、本発明実施
例で得られた繊維板は比較例で得られた繊維板に比べて
比重は同等であっても、平面引張強度では約2.7 倍、曲
げヤング率で約5.2 倍、曲げ強度で約2.8 倍、圧縮比例
限界点で約4倍、圧縮ヤング率で約5倍と強度の大きな
繊維板であることは理解できる。これは、上記表1に示
すように、本発明の実施例においては、マット状物の乾
燥前の含水率が比較例に比べて高く且つ結合剤としコー
ンスターチを用いているために、コーンスターチが繊維
表面に付着した状態で繊維内部に殆ど浸入することなく
溶解し、コーンスターチの大部分が繊維同士の接着に作
用したための推測される。
As is clear from Table 2 above, although the fiber boards obtained in the examples of the present invention have the same specific gravity as that of the fiber boards obtained in the comparative examples, the plane tensile strength is about 2.7 times, It can be understood that the fiber board has high strength with a bending Young's modulus of about 5.2 times, bending strength of about 2.8 times, compression proportional limit point of about 4 times, and compression Young's modulus of about 5 times. As shown in Table 1 above, in the examples of the present invention, the moisture content of the mat-like material before drying was higher than that of the comparative example, and since corn starch was used as the binder, the corn starch was a fiber. It is speculated that most of the cornstarch acted on the adhesion of the fibers by dissolving the cornstarch while adhering to the surface and hardly penetrating inside the fibers.

【0016】[0016]

【発明の効果】以上のように本発明の軽量繊維板の製造
方法によれば、繊維物質に粉末の再活性化性結合剤と水
とを添加してなる混合物をマット状に成形し、このマッ
トの一面より熱及び水分を供給する一方、他面より空気
を排出することによってマット内の上記再活性化性結合
剤を活性化させ、次いで熱のみを供給してマットを乾燥
させることを特徴とするものであるから、結合剤として
熱硬化性樹脂ではなく再活性化性結合剤を用いているた
めに、混合段階では結合剤が殆ど粘性(活性化)を生じ
ることなく粉末状態を維持するので、全体に亘って均一
に分散させることができ、その上、繊維物質内に水分を
保有させるので、この水分によって粉末の再活性化性結
合剤が繊維物質内に浸入するのを阻止されて繊維物質の
表面に点在状態に付着させることができるものである。
As described above, according to the method for producing a lightweight fiberboard of the present invention, a mixture formed by adding a powder reactivating binder and water to a fibrous material is molded into a mat, Heat and moisture are supplied from one side of the mat, while air is exhausted from the other side to activate the reactivating binder in the mat, and then only heat is supplied to dry the mat. Therefore, since the reactivating binder is used as the binder instead of the thermosetting resin, the binder maintains a powder state with almost no viscosity (activation) in the mixing step. Therefore, it is possible to disperse the powder evenly throughout and to retain water in the fibrous material, which prevents the powder reactivating binder from penetrating into the fibrous material. Scattered on the surface of the fiber material In which it can be deposited.

【0017】さらに、マット状物に熱及び水分を供給し
て加熱処理を行うので、マット状物中の水分の蒸発を抑
えながら温度を上昇させることができ、従って、繊維物
質表面に点状に散在、付着している再活性化性結合剤が
該繊維物質表面で溶解して繊維物質同士の接着に作用し
て軽量であるにも拘わらず、強度の大きい繊維板を得る
ことができるものである。このように、マット状物中の
水分の蒸発を防ぎつつ温度を上昇させて再活性化性結合
剤をゲル化(活性化)させ、次いで、熱のみを供給して
乾燥させるために、乾燥室内でのマット状物の滞留時間
を大幅に減少させることができ、生産能率を向上させる
ことができるものである。
Furthermore, since heat and water are supplied to the mat-like material to perform the heat treatment, the temperature can be raised while suppressing evaporation of the water in the mat-like material, so that the surface of the fibrous material is dotted. It is possible to obtain a fiberboard having high strength, although the reactivating binder that is scattered and adheres dissolves on the surface of the fibrous substance and acts on the adhesion of the fibrous substances to each other and is lightweight. is there. In this way, the temperature of the mat-like material is prevented from evaporating and the temperature of the matting material is raised to cause the reactivating binder to gel (activate), and then only the heat is supplied to dry the mat. The residence time of the mat-like material can be greatly reduced, and the production efficiency can be improved.

【0018】また、再活性化性結合剤は熱硬化性樹脂の
ように化学反応で接着するのではなく、水酸基の水素結
合で接着するために、大きな加圧を要することなく軽量
な繊維板を容易に製造でき、かつ、ホルムアルデヒドの
ような公害物質も放出しないので、安全に製造し得るも
のである。
Further, since the reactivating binder does not bond by a chemical reaction like a thermosetting resin, but bonds by a hydrogen bond of a hydroxyl group, a lightweight fiberboard is required without requiring a large pressure. Since it can be easily manufactured and does not emit pollutant such as formaldehyde, it can be manufactured safely.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 戸田 剛 大阪市北区中之島2ー3ー18 大建工業株 式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Go Toda 2-3-18 Nakanoshima, Kita-ku, Osaka City Daiken Industry Co., Ltd.

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 繊維物質に粉末の再活性化性結合剤と水
とを添加してなる混合物をマット状に成形し、このマッ
トの一面より熱及び水分を供給する一方、他面より空気
を排出することによってマット内の上記再活性化性結合
剤を活性化させ、次いで熱のみを供給してマットを乾燥
させることを特徴とする軽量繊維板の製造方法。
1. A mixture of a fibrous material and a powdered reactivating binder and water is formed into a mat, and heat and moisture are supplied from one side of the mat while air is supplied from the other side. A method for producing a lightweight fiberboard, which comprises activating the above-mentioned reactivating binder in the mat by discharging, and then supplying only heat to dry the mat.
【請求項2】 繊維物質は木質繊維その他の天然繊維を
主体とするものであることを特徴とする請求項1記載の
軽量繊維板の製造方法。
2. The method for manufacturing a lightweight fiberboard according to claim 1, wherein the fiber material is mainly composed of wood fiber or other natural fiber.
【請求項3】 粉末の再活性化性結合剤は澱粉又はポリ
ビニールアルコールであることを特徴とする請求項1又
は請求項2記載の軽量繊維板の製造方法。
3. The method for producing a lightweight fiberboard according to claim 1, wherein the powder reactivating binder is starch or polyvinyl alcohol.
JP8037215A 1996-01-30 1996-01-30 Manufacture of lightweight fiberboard Pending JPH09207230A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8037215A JPH09207230A (en) 1996-01-30 1996-01-30 Manufacture of lightweight fiberboard

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8037215A JPH09207230A (en) 1996-01-30 1996-01-30 Manufacture of lightweight fiberboard

Publications (1)

Publication Number Publication Date
JPH09207230A true JPH09207230A (en) 1997-08-12

Family

ID=12491373

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8037215A Pending JPH09207230A (en) 1996-01-30 1996-01-30 Manufacture of lightweight fiberboard

Country Status (1)

Country Link
JP (1) JPH09207230A (en)

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