JPH09194338A - Hair cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To prepare a hair cosmetic having excellent hair setting property and hair washing property by combinedly using a water-dispersible acrylic polymer with a water-soluble nonionic activator. SOLUTION: This hair cosmetic contains following (A)-(C) components: (A) a water-dispersible acrylic polymer obtained by copolymerizing 35-74wt.% of a 1-5C alkyl acrylate, 25-65wt.% of a 1-5C alkyl methacrylate and 1-15wt.% of a 3-5C acrylate or its salt and having 0.01-10μm particle diameter, (B) a water-soluble nonionic activator containing a polyalkylene glycol or polyoxyethylene segment and (C) water. Preferably, the cosmetic contains the components A and B in an weight ratio (A/B) of (1/1)-(20/1), more preferably is mixed with a feeling improver (e.g. glyceride) and is prepared to an aerosol cosmetic having pH4-8. As the component (B), a water-soluble polyoxyethylene alkyl ether is exemplified.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a hair cosmetic composition. More specifically, the present invention relates to a hair cosmetic composition which exhibits excellent setting properties when applied to hair and also has excellent hair washability.

[0002]

2. Description of the Related Art Hairsprays containing a film-forming polymer in a non-aqueous ethanol base have been the mainstream of hair sprays used for setting hair, but in recent years, water-based or water-containing hair sprays have been used. Spray is getting attention.

In such a water-based or water-containing hair setting agent, polyvinylpyrrolidone, an acidic vinyl ether polymer, an acidic acrylic polymer, an amphoteric acrylic polymer or a basic acrylic polymer is used as a hair setting component to form a film. It is compounded as a polymer.

However, these film-forming polymers are
When added to a system containing water, there is a problem that the viscosity of the system is increased more than necessary. Therefore, when a water-containing hair setting agent containing such a film-forming polymer is sprayed from a pump spray container or an aerosol container, the size of the hair setting agent particles sprayed from the container is relatively large. As a result, the drying becomes slower, the spray nozzle of the container is clogged, or the spray pattern becomes smaller, resulting in a problem in spray characteristics. As described above, when the film-forming polymer as described above is used, it is difficult to achieve the same performance as that of the non-aqueous aerosol cosmetic composition for hair.

To solve this problem, it has been proposed to use a water-dispersible acrylic polymer having a diameter of 0.1 to 1 μm in place of the above-mentioned film-forming polymer (JP-A-6-207073). . Such a water-dispersible acrylic polymer has a good setting power, and does not cause a significant increase in viscosity even when contained in a system containing water at a relatively high concentration. Therefore, when the hair cosmetic containing the water-dispersible acrylic polymer is sprayed together with a propellant from a pump spray container or an aerosol container, the size of the particles is reduced and the drying property is improved, and the spray nozzle is also used. Will be less likely to be clogged and the spray pattern will not be too small.

[0006]

However, the dry film of the water-dispersible acrylic polymer as described in JP-A-6-207073 has insufficient water solubility, and therefore is difficult to wash off when the hair is washed. The hair washability was insufficient.

The present invention is intended to solve the above-mentioned problems of the prior art, and treats hair with a hair cosmetic containing a water-dispersible acrylic polymer having excellent hair setting properties as a film-forming polymer. In doing so, it is intended to improve the hair washability of the dry film containing the water-dispersible acrylic polymer.

[0008]

The present inventors have achieved the above-mentioned object by using a water-dispersible acrylic polymer in combination with a water-soluble nonionic activator having a water-soluble polyethylene glycol or polyoxyethylene segment. The inventors have found out what can be done and have completed the present invention.

That is, the present invention provides the following component (A):
(B) and (C) (A) (a) alkyl acrylate (wherein the alkyl has 1 to 5 carbon atoms) 35 to 74% by weight,
(B) 25 to 65% by weight of alkyl methacrylate (wherein the alkyl has 1 to 5 carbon atoms), and (c) 1 to 15% by weight of acrylate acid having 3 to 5 carbon atoms or salt thereof.
And a particle size of 0.01-
A hair cosmetic comprising: a water-dispersible acrylic polymer of 10 μm; (B) a water-soluble nonionic activator containing a polyalkylene glycol or a polyoxyethylene segment; and (C) water.

[0010]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.

The hair cosmetic composition of the present invention contains a film-forming water-dispersible acrylic polymer as the component (A).
This water-dispersible acrylic polymer comprises (a) alkyl acrylate, (b) alkyl methacrylate,
(C) A polymer obtained by copolymerizing with an acrylate acid or a salt thereof and having good hair setting properties.

The carbon number of the alkyl group of the alkyl acrylate of the component (a) is 1-5. Specific examples of such an alkyl acrylate include methyl acrylate, ethyl acrylate, propyl acrylate, and butyl acrylate. Of these, ethyl acrylate is preferable.

Further, the alkyl acrylate component (A)
The content therein is 35 to 74% by weight, preferably 40 to 7
It is 0% by weight, more preferably 50 to 60% by weight.

The alkyl group of the alkyl methacrylate of the component (b) has 1 to 5 carbon atoms. Specific examples of such an alkyl methacrylate include methyl methacrylate, ethyl methacrylate, propyl methacrylate,
Butyl methacrylate and the like can be mentioned. Of these, methyl methacrylate is preferable.

The content of the alkyl methacrylate in the component (A) is 25 to 65% by weight, preferably 3%.
It is 0 to 50% by weight, more preferably 30 to 40% by weight.

The acrylate acid of component (c) means an αβ unsaturated carboxylic acid. Examples of such acrylate acids include acrylic acid, methacrylic acid, crotonic acid, itaconic acid and the like. Among them, acrylic acid or methacrylic acid is preferable, and it is particularly preferable to use both in combination. Further, a salt thereof can be used as the acrylate acid of the component (c). Examples of the counter ion of the salt in this case include alkali metal ions such as sodium and potassium, alkaline earth metal ions such as calcium and magnesium, and organic amines such as aminomethyl propanol.

The content of acrylate acid in the component (A) is 1 to 15% by weight, preferably 5 to 15% by weight,
It is more preferably 8 to 12% by weight. In particular, when acrylic acid and methacrylic acid are used in combination as the component (c), it is preferable that the respective amounts be 2 to 10% by weight, provided that the total does not exceed 15% by weight.

By changing the content ratios of the above components (a), (b) and (c), the component (A)
Transition point (Tg) of water-dispersible acrylic polymer
Can be controlled. In this case, if the Tg is too low, the setting force is not sufficient, and if the Tg is too high, the coating becomes hard and the hair becomes stiff when the hair cosmetic is applied. Therefore, the Tg is preferably 0 to 100 ° C. It is preferable to adjust the ratio of each component. Here, Tg can be measured by a differential scanning calorimetry method (DSC method) or the like.

In the hair cosmetic composition of the present invention, the water-dispersible acrylic polymer as the preferred component (A) is
(A) 50-60 wt% of ethyl acrylate, and (b)
30-40% by weight of methyl methacrylate, (c) 2-10% by weight of acrylic acid and 2-10% by weight of methacrylic acid.
(However, the total amount of acrylic acid and methacrylic acid is 15% by weight or less.).

Such components (a), (b) and (c)
The particle size of the water-dispersible acrylic polymer of the component (A) that serves as a copolymerization unit is 0.01 to 10 μm, preferably 0.05 to 5 μm, and more preferably 0.1 to 1 μm.
It is. If the particle size is less than 0.01 μm, the production is difficult, and if it exceeds 10 μm, the dispersion stability is reduced, which is not preferable.

When the water-dispersible acrylic polymer of the component (A) is prepared by emulsion copolymerization as described below, the type and amount of the surfactant used during the polymerization and other factors are used for controlling the particle size. It can be preferably carried out by appropriately adjusting the emulsification conditions.

The water-dispersible acrylic polymer as the component (A) is obtained by adding the components (a), (b) and (c) to the aqueous medium in the presence of a chain transfer agent and a polymerization initiator according to a known emulsion polymerization method. In general, it can be preferably prepared by copolymerizing at a temperature of about 35 to 90 ° C., and usually obtained as an aqueous dispersion. The procedure and conditions of such emulsion copolymerization are well known to those skilled in the art (for example, JP-A-6-207073, paragraphs [0014] to [0].
018]).

The hair cosmetic composition of the present invention comprises, as the component (B), a polyalkylene glycol (preferably C2 to C3).
Water-soluble nonionic activator having a polyalkylene glycol) or a polyoxyethylene segment.
When these polyalkylene glycol or nonionic activator is used together with the water-dispersible acrylic polymer of the component (A) in a hair cosmetic containing water, the component (A)
It can be incorporated into the dry film of the water-dispersible acrylic polymer to improve the washability of the dry film. Moreover, the component (B) plays a role of a plasticizer for the film by appropriately selecting the molecular weight and the chemical structure, and thereby the hair setting force of the water-dispersible acrylic polymer of the component (A) can be complemented. .

Here, as the polyalkylene glycol, if the number average molecular weight is too small, the stickiness increases, and if it is too large, the effect of imparting water solubility decreases.
Preferably 100 to 10,000, more preferably 150
~ 1000 is used. A preferred specific example of such a polyalkylene glycol is polyethylene glycol.

As the water-soluble nonionic activator containing a polyoxyethylene segment (hereinafter abbreviated as POE-containing water-soluble nonionic activator), one which becomes a transparent aqueous solution at 25% at 1% by weight is used. However, you may heat at the time of melt | dissolution. Preferred examples of such a POE-containing water-soluble nonionic activator include polyoxyethylene alkyl ether and polyoxyethylene-modified silicone.

Specific examples of the polyoxyethylene alkyl ether include polyoxyethylene lauryl ether,
Polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene higher alcohol ether,
Polyoxyethylene octyl phenyl ether, polyoxyethylene nonyl phenyl ether, polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan Trioleate, polyoxyethylene sorbite tetraoleate, polyethylene glycol monolaurate, polyethylene glycol monostearate, polyethylene glycol distearate, polyethylene glycol monooleate, polyoxyethylene alkylamine, polyoxyethylene hydrogenated castor oil, etc. be able to.

Specific examples of polyoxyethylene-modified silicones include branched silicones of formula (1), double-ended silicones of formula (2), and single-ended silicones of formula (3). Here, the following equations (1)-
The numbers of l, m and n in (3) can be any combination so that the polyoxyethylene-modified silicone becomes water-soluble.

[0028]

Embedded image The weight ratio of the water-dispersible acrylic polymer as the component (A) to the polyethylene glycol or POE-containing water-soluble nonionic activator as the component (B) is such that if the component (A) is less than the component (B), B) may cause stickiness, and if the amount is too large, the washability of the dry film may be significantly deteriorated. Therefore, 1: 1 to 20: 1, preferably 4: 1.
It is about 10: 1.

The hair cosmetic composition of the present invention contains water as the component (C). As water, ion-exchanged water can be preferably used.

The pH of the hair cosmetic composition of the present invention is preferably adjusted to 4 to 8 by using a known pH adjuster, if necessary. When the pH is lower than 4, irritation to the skin is increased, and there is a concern that stability of the container may be deteriorated. When the pH exceeds 8,
It is not preferable because the dispersibility of the polymer is lowered.

In addition to the components (A), (B) and (C) described above, the hair cosmetic composition of the present invention preferably contains a feel-improving agent in order to improve the feeling of use. Examples of such a texture-improving agent include polyols such as glyceride, dimethylpolysiloxane or an emulsion thereof, silicones such as polyether-modified silicone and alkyl- or alkoxy-modified silicone, and C1 to C24 linear or branched fatty acids. Examples thereof include esters such as C24 linear or branched alkyl esters, hydrocarbons such as squalane and isoparaffin. Also, Japanese Patent Application Laid-Open No.
The organopolysiloxanes described in JP-A No. 76824 or JP-A No. 7-133352 can also be preferably used as the touch improver.

Further, the hair cosmetic composition of the present invention contains various additives, such as an ultraviolet absorber, a moisturizing agent, a surfactant, and a gloss, which are compounded in usual hair cosmetic compositions, within a range that does not impair the effects of the present invention. Appropriate agents, dyes, fragrances and the like can be appropriately added. In particular, for the purpose of adjusting the drying speed and spray pattern of the hair cosmetic, a C2-4 lower alcohol can be blended up to 80% by weight, preferably up to 50% by weight of the hair cosmetic.

The hair cosmetic composition of the present invention is, for example, an aqueous dispersion of component (A) water-dispersible acrylic polymer, component (B) polyethylene glycol or POE-containing water-soluble nonionic activator and component (C). It can be produced by uniformly mixing water by a conventional method.

The hair cosmetic composition of the present invention can be used in various dosage forms. For example, it may be in the form of spray, mist, aerosol, gel, lotion, tonic, blowing agent, cream, post-foaming gel or the like. Particularly, from the viewpoint of operability, it is preferable to use the hair cosmetic of the present invention as an aerosol cosmetic. In this case,
A known pump spray container or an aerosol container is filled with the hair cosmetic, but when the hair container is filled with the hair cosmetic, the C1-5 alkanes,
A liquefied gas such as dimethyl ether or a compressed gas such as air, nitrogen or carbon dioxide is preferably enclosed as a propellant. The aerosol cosmetic composition for hair thus obtained has excellent spray characteristics (spray pattern, atomized particle size, ejection force, etc.).

[0035]

The present invention will be described below in more detail with reference to examples.

Examples 1 to 4 and Comparative Example 1 Hair cosmetics having the formulations shown in Table 1 were prepared by a conventional method.
The pH of the hair cosmetic composition was adjusted using an aqueous sodium hydroxide solution.

[0037]

[Table 1] (wt%) _Component Example Comparative Example 1 2 3 4 1 Component (A) Water-dispersible acrylic polymer * 1 20.0 20.0 20.0 20.0 20.0 Component (B) Polyoxyethylene (EO13) cetyl ether * 2 1.25 − − − − Polyoxyethylene (EO20) Solventane monolaurate * 3 − 0.50 − − − Polyoxyethylene modified silicone * 4 − − 1.25 − − Polyethylene glycol * 5 − − − 0.50 − Ethanol (99.5%) − − − 30.0- Component (C) Ion-exchanged water Balance balance Balance balance Balance pH value of hair cosmetics 7 7 7 7 7

Table Note * 1: Amahold DR25 (25% aqueous solution), manufactured by Amakor * 2: Emulgen 220, manufactured by Kao * 3: Leodol Super TW-L120, manufactured by Kao * 4: SH3746, Toray Dow Corning * 5: PEG300, Sanyo Chemical Industries

(Evaluation) A pump spray container was filled with the obtained hair cosmetic composition to obtain an aerosol cosmetic composition for hair. With respect to this cosmetic, a "washing property test" and a "setting property test" of hair were performed as shown below.

(1) Hair wash test Each cosmetic was sprayed on a glass plate and dried, and water was dripped on the formed dry film, and after 10 seconds, the condition of the film was visually observed according to the following evaluation criteria. evaluated. Table 2 shows the obtained results.

Hair Washability Evaluation Standard Rank Condition ◎: When a film can be removed by rubbing lightly with a finger ○: When a film can be removed by rubbing lightly with a finger several times Δ: When a film cannot be removed without rubbing strongly with a finger ×: If the film cannot be removed by rubbing it with your finger several times

(2) Setting property test A hair bundle having a length of 15 cm and a weight of 2 g is wetted with water to have a diameter of 4 c
After being wound around a glass rod of m and dried at 50 ° C. for 3 hours, the aerosol cosmetic composition was sprayed from a distance of 15 cm. After the hair was dried, it was removed from the glass rod, and the hair bundle was vibrated at 20 ° C. in an atmosphere of 98% RH for 30 minutes. The degree of curl collapse of the hair bundle at that time was observed, the set retention rate was obtained according to the following mathematical formula, and the obtained numerical value was evaluated according to the following evaluation criteria. The results are shown in Table 2.
Shown in

[0043]

## EQU1 ## Set retention rate = {(L ₀ −L ₃₀ ) / (L ₀ −
L _i )} × 100 (wherein L ₀ = length of hair bundle before test L _i = length of hair bundle immediately after detached from glass rod L ₃₀ = length of hair bundle immediately after vibrating for 30 minutes That)

Set property evaluation standard rank Set retention range ⊚: 80% ≤ set retention ≤ 100% ○: 60% ≤ set retention <80% △: 40% ≤ set retention <60% ×: 20% ≤ Set retention rate <40%

[0045]

[Table 2] Examples Comparative examples Evaluation items 1 2 3 4 1 Hair washability ◎ ○ ◎ ○ × Setability ○ ○ ○ ○ ○

From Table 2, the hair cosmetic composition of the present invention showed excellent results in terms of washability and set holding power.

On the other hand, in the hair cosmetic composition of Comparative Example 1, since the component (B) polyethylene glycol or the POE-containing water-soluble nonionic activator was not contained, the dry film of the water-dispersible acrylic polymer was very high. It became difficult to wash off, resulting in insufficient hair washability.

Example 5 An aerosol cosmetic composition for hair was prepared by filling a hair cosmetic composition having the composition shown in Table 3 into an aerosol container. The pH of the hair cosmetic composition was adjusted to pH 7 using an aqueous sodium hydroxide solution.

[0049]

[Table 3] Ingredients% by weight Water-dispersible acrylic polymer * 1 20.00 Polyether-modified silicone * 6 0.5 Glycerin 0.3 Perfume 0.15 Water balance dimethyl ether 35.00

* 1 Same as Table * 6: SH3773C, Toray Dow Corning

The obtained aerosol cosmetics for hair showed excellent results in terms of hair washability and settability similarly to the hair cosmetics of Examples 1 to 4. Also, the treated hair bundle was less stiff.

Example 6 An aerosol cosmetic for hair was manufactured by filling an aerosol container with the hair cosmetic having the composition shown in Table 4. The pH of the hair cosmetic composition was adjusted to pH 7 using an aqueous sodium hydroxide solution.

[0053]

[Table 4] Ingredients% by weight Water-dispersible acrylic polymer * 1 20.00 Polyethylene glycol * 7 1.25 Isopropyl isostearate 0.1 Perfume 0.15 Water balance Ethanol (99.5%) 30.00 Dimethyl ether 40.00

Table Note * 1: Same as Table 1 * 7: Polyethylene glycol 800, manufactured by Sanyo Chemical Industries

The obtained aerosol cosmetics for hair showed excellent results in terms of washability and settability similar to the hair cosmetics of Examples 1 to 4. Also, the treated hair bundle was less stiff.

Example 7 An aerosol cosmetic composition for hair was prepared by filling a hair cosmetic composition having the composition shown in Table 5 into an aerosol container. The pH of the hair cosmetic composition was adjusted to pH 7 using an aqueous sodium hydroxide solution.

[0057]

[Table 5] Ingredients% by weight Water-dispersible acrylic polymer * 1 20.00 Polyvinyl pollydone-vinyl acetate copolymer * 8 0.30 Polyoxyethylene (EO9) lauryl ether * 9 0.30 Organopolysiloxane * 10 0.20 Perfume 0.15 Water balance ethanol (99.5% ) 30.00 Dimethyl ether 40.00

Table Note * 1: Same as Table 1 * 8: PVA / VA 73E (50% ethanol solution), manufactured by BASF * 9: Emulgen 109P, manufactured by Kao * 10: JP-A-7-133352 Polymer of Synthesis Example 3

The obtained aerosol cosmetics for hair showed excellent results in terms of hair washability and settability similarly to the hair cosmetics of Examples 1 to 4. Also, the treated hair bundle was less stiff.

[0060]

EFFECTS OF THE INVENTION The hair cosmetic composition of the present invention has good setting properties and is easy to wash off by washing hair.

Claims (8)

[Claims] 1. The following components (A), (B) and (C) 35 to 74% by weight of (A) (a) alkyl acrylate (wherein the alkyl has 1 to 5 carbon atoms):
(B) 25 to 65% by weight of alkyl methacrylate (wherein the alkyl has 1 to 5 carbon atoms), and (c) 1 to 15% by weight of acrylate acid having 3 to 5 carbon atoms or salt thereof.
And a particle size of 0.01-
A water-dispersible acrylic polymer having a thickness of 10 μm; (B) a water-soluble nonionic activator containing a polyalkylene glycol or a polyoxyethylene segment; (C) a hair cosmetic comprising water. 2. The ratio of component (A) to component (B) is 1:
The hair cosmetic composition according to claim 1, which is 1 to 20: 1. 3. The water-dispersible acrylic polymer as the component (A) comprises 50 to 60% by weight of (a) ethyl acrylate,
(B) 30 to 40% by weight of methyl methacrylate,
(C) 2 to 10% by weight of acrylic acid and 2 to methacrylic acid
The hair cosmetic composition according to claim 1 or 2, which is obtained by copolymerizing with 10% by weight (however, the total amount of acrylic acid and methacrylic acid is 15% by weight or less). 4. The hair cosmetic composition according to claim 1, wherein the component (B) is polyethylene glycol or a water-soluble polyoxyethylene alkyl ether. 5. The hair cosmetic composition according to claim 1, wherein the component (B) is a water-soluble polyoxyethylene-modified silicone. 6. The hair cosmetic composition according to claim 1, which has a pH of 4-8. 7. The hair cosmetic composition according to any one of claims 1 to 6, further comprising a feel-enhancing agent. 8. An aerosol cosmetic for hair, wherein the hair cosmetic according to any one of claims 1 to 7 is filled in an aerosol container together with a propellant.