JPH09187243A - Process for keeping freshness of bean curd - Google Patents

Process for keeping freshness of bean curd

Info

Publication number
JPH09187243A
JPH09187243A JP8004387A JP438796A JPH09187243A JP H09187243 A JPH09187243 A JP H09187243A JP 8004387 A JP8004387 A JP 8004387A JP 438796 A JP438796 A JP 438796A JP H09187243 A JPH09187243 A JP H09187243A
Authority
JP
Japan
Prior art keywords
water
tofu
anode
bean curd
container
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8004387A
Other languages
Japanese (ja)
Inventor
Izumi Tanaka
いずみ 田中
Yukari Mizutani
由加里 水谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NIPPON INTEC KK
Original Assignee
NIPPON INTEC KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NIPPON INTEC KK filed Critical NIPPON INTEC KK
Priority to JP8004387A priority Critical patent/JPH09187243A/en
Publication of JPH09187243A publication Critical patent/JPH09187243A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To extend the retention time of the freshness of bean curd by a safe process. SOLUTION: In an electrolysis tank having an anode chamber and a cathode chamber partitioned by a diaphragm having ion permeability, an aqueous solution of an alkali chloride compound is electrolyzed to produce an anode water having an oxidation-reduction potential of 1000-1200mV and pH of 2.0-3.0 in the anode chamber. Bean curd is placed in an adequate container, and the anode water is poured into the container in such an amount that the bean curd is dipped in the water. The opening of the container is covered with a food packaging film, etc., to intercept the inner materials from the outer atmosphere, and the container is allowed to stand. The proliferation of microorganisms on the surface of the bean curd is suppressed by the anode water, and the suppressing effect lasts for several days because of the interception from the outer atmosphere. Since the anode water is converted into water, the anode water is harmless.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、豆腐の味、外観等
を損なわずに保持できる豆腐の品質保持方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for maintaining quality of tofu that can be retained without impairing the taste, appearance, etc. of tofu.

【0002】[0002]

【従来の技術】豆腐は栄養価が高く、日々の食生活にお
いて欠かすことのできない食品の一つであるが、原料大
豆が微細化される過程で細胞膜が破壊され、蛋白質が雑
菌の増殖に適する大きさに細断され、水の存在で上記雑
菌が急速に繁殖する。このためいわゆる日持ちがよくな
いことが欠点である。豆腐は、製造日において販売、購
入され、食されるのが通常であるが、翌日まで保存する
場合、小売店及び家庭のいずれにおいても一般的に冷蔵
保存される。しかし、この冷蔵保存もせいぜい2、3日
程度が限度であり、特に腐敗の進行が速い夏季において
は、その程度の保存さえも困難であるのが実情である。
2. Description of the Related Art Tofu is one of the foods that is indispensable in daily eating habits because it has a high nutritional value, but the cell membrane is destroyed in the process of miniaturizing the raw soybean, and the protein is suitable for the growth of various bacteria Shredded into small pieces, the above bacteria rapidly propagate in the presence of water. Therefore, the so-called poor shelf life is a drawback. Tofu is usually sold, purchased, and eaten on the date of manufacture, but when it is stored until the next day, it is generally refrigerated at both retail stores and homes. However, this refrigerated storage is limited to a few days at the most, and it is the actual situation that even such storage is difficult especially in the summer when the progress of decay is fast.

【0003】したがって、小売店においては、売れ残
り、品質が劣化した豆腐はもちろんのこと、例え品質の
劣化がない場合でも製造日翌日や翌々日の製品は売れ行
きが落ちる傾向があり、販売されないまま廃棄処分せざ
るを得ない。一方、消費者においても何らかの理由で購
入後一、二日食さなかったような場合、安全を考えてや
はり廃棄せざるを得ない。安全性確保のためとはいえ、
いずれの場合も不経済であり、かつ農業資源を無駄にす
ることにもなる。これらの問題は、全国的、更に、近年
豆腐が国際的に食されるようなったことを考慮して全世
界的な視野にまで拡大して検討してみれば、とうてい無
視できる程度のものではない。
Therefore, in retail stores, not only tofu that has remained unsold and deteriorated in quality, but even if there is no deterioration in quality, the products on the next day or the day after the second day of manufacture tend to lose sales, and are discarded without being sold. I have to do it. On the other hand, even if the consumer does not eat one or two days after purchase for some reason, he / she must discard it for safety. For safety reasons,
In either case, it is uneconomical and wastes agricultural resources. These problems are almost negligible if we consider the fact that tofu is eaten nationwide and internationally in recent years, and expanded to a global perspective. Absent.

【0004】[0004]

【発明が解決しようとする課題】豆腐の鮮度保持期間を
延長する方法の一つとして、防腐剤の添加、増量が考え
られる。しかし、添加物による発癌性の問題やアレルギ
ー症の問題が知られるようになっており、添加物を全く
含まないか或いはできるだけ含まないような自然食品の
適用が求められている現在においては、安易な防腐剤の
使用は望ましくない。
As one of the methods for extending the freshness retention period of tofu, it is possible to add a preservative and increase the amount thereof. However, the problems of carcinogenicity and allergic diseases caused by additives have become known, and it is now easy to apply natural foods containing no or no additives as much as possible. The use of different preservatives is undesirable.

【0005】そこで本発明は、防腐剤等の添加物を使用
せずに、できるだけ長期間、豆腐の味、外観等の鮮度及
び安全性を損なわずに保持できる豆腐の鮮度保持方法を
提供することを目的とするものである。
Therefore, the present invention provides a method for keeping freshness of tofu which can be retained for a long period of time without using additives such as preservatives without impairing the freshness such as taste and appearance of tofu and safety. The purpose is.

【0006】[0006]

【課題を解決するための手段】前述の課題を解決するた
めに本発明に係る豆腐の鮮度保持方法は、請求項1に記
載するように、塩化アルカリ化合物の水溶液をイオン透
過性隔膜により分離された陽極室及び陰極室を有する電
解槽中で電気分解するものにおいて、上記陽極室におい
て生成して得られる陽極水(以下、「酸化電位水」とい
う)に、豆腐を浸漬し外部雰囲気と遮断した状態で保存
することを特徴とするものである。
In order to solve the above-mentioned problems, the method of keeping freshness of tofu according to the present invention comprises, as described in claim 1, an aqueous solution of an alkali chloride compound separated by an ion-permeable membrane. In an electrolyzer having an anode chamber and a cathode chamber, the tofu is immersed in the anode water (hereinafter referred to as “oxidation potential water”) produced in the anode chamber and isolated from the external atmosphere. It is characterized by saving in a state.

【0007】また、前述の課題を解決するために本発明
に係る豆腐の鮮度保持方法は、請求項2に記載するよう
に、酸化電位水が、酸化還元電位が1000〜1200
mVで、かつpHが2.0〜3.0のものであることを
特徴とするものである。
Further, in order to solve the above-mentioned problems, the method of keeping freshness of tofu according to the present invention is, as described in claim 2, the oxidation potential water and the oxidation reduction potential of 1000 to 1200.
It is characterized by having a mV and a pH of 2.0 to 3.0.

【0008】[0008]

【発明の実施の態様】本発明の豆腐の鮮度保持方法にお
いては、酸化電位水により豆腐を処理するが、この酸化
電位水は、塩化アルカリ化合物の水溶液を電気分解して
得られるものであり、例えば、特開平6−246265
号公報記載の方法により、製造することができる。次
に、その一例を図1を参照しながら説明する。図1は、
酸化電位水を得るための電解槽の概略断面図である。
BEST MODE FOR CARRYING OUT THE INVENTION In the method for maintaining freshness of tofu according to the present invention, tofu is treated with oxidizing potential water, which is obtained by electrolyzing an aqueous solution of an alkali chloride compound. For example, JP-A-6-246265
It can be manufactured by the method described in the publication. Next, an example thereof will be described with reference to FIG. FIG.
It is a schematic sectional drawing of the electrolytic cell for obtaining oxidation potential water.

【0009】まず、電解槽10の供給口20から塩化ア
ルカリ化合物の水溶液、例えば、塩化ナトリウム水溶液
を、陽極18が設置された陽極室と、陰極16が設置さ
れた陰極室に供給する。両室はイオン透過性の隔膜14
により分離されている。次に、電極から通電を開始し、
電気分解をなす。その結果、電解水、即ち、陰極室には
陰極水が生成し、陽極室には酸化電位水(陽極水)が生
成する。そして、陽極室内部の生成水を取り出すことに
より、本発明で用いる酸化電位水を得ることができる。
8は酸化還元電位を測るORP計であり、9はpH計で
ある。また、22は陰極室側の吐出口である。なお、塩
化アルカリ化合物としては塩化ナトリウムのほかにも、
塩化カリウム、塩素酸カリウム、塩素酸ナトリウム等を
用いることができる。なお、図において、供給口20か
ら塩化アルカリ化合物が連続的に流入する連続式電解槽
として示されているが、供給口20の前段にバルブを設
けて断続的に給水する所謂バッチ式電解槽としてもよ
い。
First, an aqueous solution of an alkali chloride compound, for example, an aqueous solution of sodium chloride, is supplied from the supply port 20 of the electrolytic cell 10 to the anode chamber in which the anode 18 is installed and the cathode chamber in which the cathode 16 is installed. Both chambers are ion-permeable diaphragm 14
Are separated by Next, start energizing from the electrodes,
Make electrolysis. As a result, electrolyzed water, that is, cathode water is generated in the cathode chamber and oxidation potential water (anode water) is generated in the anode chamber. Then, by extracting the generated water inside the anode chamber, the oxidation potential water used in the present invention can be obtained.
Reference numeral 8 is an ORP meter for measuring the redox potential, and 9 is a pH meter. Reference numeral 22 is a discharge port on the cathode chamber side. In addition to sodium chloride as an alkali chloride compound,
Potassium chloride, potassium chlorate, sodium chlorate, etc. can be used. In the figure, the continuous electrolytic cell in which the alkali chloride compound continuously flows in from the supply port 20 is shown, but as a so-called batch type electrolytic cell in which a valve is provided in front of the supply port 20 to intermittently supply water. Good.

【0010】図1に示すような電解槽10を用い、本発
明で用いる酸化還元電位が1000〜1200mVでか
つpHが2.0〜3.0の酸化電位水を得るには、原水
に塩化ナトリウムを混入して3〜10%塩化ナトリウム
水溶液とし、この混合液を原水に継続的に一定量を供給
するもの、即ち、一定濃度に保持された電解質を含む水
溶液を供給口20を介して時間当り定量を電解槽12内
に供給する。このとき、該水溶液の電導度の増加に伴っ
て通電量が増加し、強い電解が行われる。この電解で得
られた酸化電位水は吐水口24から吐水するが、これは
ORP計8やpH計9で計測され所望値の吐水が使用に
供される。なお、電解槽10に流れる電流は原水の性
質、塩化アルカリ化合物の混入量や電解槽10の形状等
によって変わるが、これらは図示しない制御回路によっ
て適宜制御される。
In order to obtain oxidation potential water having an oxidation-reduction potential of 1000 to 1200 mV and a pH of 2.0 to 3.0 using the electrolytic cell 10 as shown in FIG. 1, sodium chloride is added to raw water. 3 to 10% sodium chloride aqueous solution is mixed with the mixture, and a constant amount of this mixed solution is continuously supplied to the raw water, that is, an aqueous solution containing an electrolyte maintained at a constant concentration is supplied per hour via the supply port 20. A fixed amount is supplied into the electrolytic cell 12. At this time, the energization amount increases as the electric conductivity of the aqueous solution increases, and strong electrolysis is performed. The oxidation potential water obtained by this electrolysis is discharged from the water discharge port 24, and this is measured by the ORP meter 8 or the pH meter 9 and the desired value of water discharge is used. The current flowing through the electrolytic cell 10 varies depending on the nature of the raw water, the amount of the alkali chloride compound mixed in, the shape of the electrolytic cell 10, etc., but these are appropriately controlled by a control circuit (not shown).

【0011】このようにして得られた酸化電位水は、微
生物の繁殖を抑制する効果が優れているため、酸化還元
電位が約1000〜1200mVで、かつpHが2.0
〜3.0程度のものが好ましい。
The oxidation-potential water thus obtained has an excellent effect of suppressing the growth of microorganisms, and therefore has an oxidation-reduction potential of about 1000 to 1200 mV and a pH of 2.0.
It is preferably about 3.0.

【0012】酸化電位水による豆腐の処理は、外部雰囲
気と遮断した状態で豆腐の全部又は一部を酸化電位水中
に浸漬することによりなされる。この処理方法として
は、例えば、次の方法を適用することができる。まず、
適当な容器中に豆腐を入れ、次に、豆腐が好ましくは完
全に浸漬する量の酸化電位水を注入する。もちろん、こ
の作業は逆でも差し支えない。また、このとき、容器か
ら溢れる程度の酸化電位水を注入し、容器内に空間がな
くなるようにすることが好ましい。その後、前記容器の
開口部分を、蓋、食品包装用フィルム等の通気性のない
もので密閉して外部雰囲気と遮断し、放置する。この放
置は、通常は室温下で放置すればよく、必要に応じて冷
蔵庫内等の低温下で放置してもよい。なお、食品包装用
フィルムとしてポリエチレンやポリピロピレンフィルム
等が使用できるが、好ましくはポリビニリデンフィルム
が望ましい。
The treatment of tofu with oxidation potential water is carried out by immersing all or part of the tofu in oxidation potential water while being shielded from the external atmosphere. As the processing method, for example, the following method can be applied. First,
The tofu is placed in a suitable container and then the oxidizing potential water is poured in an amount such that the tofu is preferably completely immersed. Of course, this procedure can be reversed. Further, at this time, it is preferable to inject the oxidizing potential water to the extent that it overflows from the container so that there is no space in the container. After that, the opening of the container is sealed with a non-breathable material such as a lid and a food packaging film to shield it from the external atmosphere, and then allowed to stand. This may be left at room temperature, and may be left at a low temperature such as in a refrigerator, if necessary. A polyethylene or polypropylene film can be used as the food packaging film, but a polyvinylidene film is preferable.

【0013】[0013]

【実施例】以下、実施例により本発明を更に詳しく説明
するが、本発明はこれらに限定されるものではない。
EXAMPLES The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the present invention is limited thereto.

【0014】製造例1 図1に示すような電解槽10により、酸化電位水を製造
した。なお、塩化アルカリ化合物の水溶液として、水道
水100リットルに対して10%食塩水1リットルを加
えて混合したものを用いた。また、電気分解は、6V、
30Aの通電条件で行った。この方法により、酸化還元
電位が1150mVで、pHが2.6の酸化電位水を得
た。
Production Example 1 Oxidizing potential water was produced by the electrolytic cell 10 as shown in FIG. The aqueous solution of the alkali chloride compound was a mixture of 100 liters of tap water and 1 liter of 10% saline. Also, electrolysis is 6V,
It carried out on the energization conditions of 30A. By this method, oxidation potential water having a redox potential of 1150 mV and a pH of 2.6 was obtained.

【0015】実施例1及び比較例1〜3 市販の木綿豆腐(凝固剤として塩化マグネシウムを、消
泡剤として界面活性剤を使用)4丁を、4つの1リット
ルの容器に一つずつ入れ、それぞれ図1の酸化電位水、
100ppm次亜塩素酸ナトリウム水溶液(比較例1)
又は水道水(比較例2)を、豆腐が完全に浸漬され、容
器の縁近くになるまで注入した。また、残りの一つの容
器には何も注入しなかった(比較例3)。その後、容器
の口を市販の食品包装用フィルム(ポリビニリデンラミ
ネートポリエチレン)で完全に覆い、容器の内部を外部
雰囲気から遮断した。その状態で25℃で7日間、室内
で放置し、経日変化を観察した。
Example 1 and Comparative Examples 1 to 3 Four commercially available cotton tofu (using magnesium chloride as a coagulant and a surfactant as a defoaming agent) were placed in four 1-liter containers, one by one, The oxidation potential water of Fig. 1, respectively
100 ppm aqueous sodium hypochlorite solution (Comparative Example 1)
Alternatively, tap water (Comparative Example 2) was poured until the tofu was completely immersed and near the edge of the container. Moreover, nothing was injected into the remaining one container (Comparative Example 3). Then, the mouth of the container was completely covered with a commercially available film for food packaging (polyvinylidene laminated polyethylene), and the inside of the container was shielded from the external atmosphere. In that state, it was left indoors at 25 ° C. for 7 days, and the change with time was observed.

【0016】その結果、7日間経過後においても、実施
例1の豆腐には、外観上の変化はまったく見られず、実
際に7人の食品パネラーが試食したところ、味にも変化
がないことが確認された。比較例3の豆腐は、約1日経
過後において外観上明らかに腐敗が確認された。比較例
1の豆腐は、約1日経過後において水に濁りが確認さ
れ、約5日経過後において豆腐が浮上してきた。比較例
2の豆腐は、外観上の変化は見られなかったが、ガスの
発生により、食品包装用フィルムの膨張が観察された。
As a result, no change in appearance was observed in the tofu of Example 1 even after 7 days, and when tasted by seven food panelists, no change in taste was observed. Was confirmed. The tofu of Comparative Example 3 was apparently spoiled after about 1 day. The tofu of Comparative Example 1 was confirmed to be turbid in water after a lapse of about 1 day, and the tofu surfaced after a lapse of about 5 days. The tofu of Comparative Example 2 showed no change in appearance, but swelling of the food packaging film was observed due to the generation of gas.

【0017】本発明で用いる酸化電位水は蛋白質と反応
して失活する性質を有しているので、実施例1において
は、酸化電位水は豆腐と接触後に失活し、単なる水とな
っているため、まったく無害である。その一方、酸化電
位水が豆腐と接触した際、表面に付着している微生物の
増殖は抑制され、その後は密閉状態で保持されているの
で、抑制効果は引き続き保持されることになる。このた
め、実施例1は比較例1〜3と比べて、優れた結果が得
られたものである。
Oxidizing potential water used in the present invention has the property of deactivating by reacting with proteins. Therefore, in Example 1, the oxidizing potential water is deactivated after contact with tofu and becomes mere water. Therefore, it is completely harmless. On the other hand, when the oxidation potential water comes into contact with tofu, the growth of microorganisms attached to the surface is suppressed, and thereafter, the microorganisms are kept in a sealed state, so that the inhibitory effect is continuously retained. Therefore, in Example 1, excellent results were obtained as compared with Comparative Examples 1 to 3.

【0018】[0018]

【発明の効果】本発明の豆腐の鮮度保持方法によれば、
簡単な方法で、豆腐の品質を数日から1週間程度保持す
ることができる。また、本発明で用いる酸化電位水は豆
腐と接触後に単なる水に変化するため無害である。本発
明の豆腐の鮮度保持方法により、販売日及び購入日から
の販売可能及び消費可能な期間を従来よりもある程度長
く確保できるため、小売店及び消費者ともにその恩恵を
受けることができ、価格低下や農業資源の有効利用に資
することができる。
According to the method for maintaining freshness of tofu of the present invention,
With a simple method, the quality of tofu can be maintained for several days to a week. Further, the oxidation potential water used in the present invention is harmless because it changes to simple water after contact with tofu. With the method of maintaining freshness of tofu according to the present invention, it is possible to secure a sale date and a period from the purchase date that can be sold and can be consumed to a certain extent longer than before. And contribute to effective use of agricultural resources.

【図面の簡単な説明】[Brief description of the drawings]

【図1】酸化電位水の製造方法を説明するための概略断
面図である。
FIG. 1 is a schematic cross-sectional view for explaining a method for producing oxidation potential water.

【符号の説明】[Explanation of symbols]

8 ORP計 9 pH計 10 電解槽 14 イオン透過性隔膜 16 陰極 18 陽極 20 供給口 22 吐出口 24 吐出口 8 ORP meter 9 pH meter 10 Electrolyzer 14 Ion permeable diaphragm 16 Cathode 18 Anode 20 Supply port 22 Discharge port 24 Discharge port

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 塩化アルカリ化合物の水溶液をイオン透
過性隔膜により分離された陽極室及び陰極室を有する電
解槽中で電気分解し、上記陽極室において生成して得ら
れる陽極水に、豆腐を浸漬し外部雰囲気と遮断した状態
で保存することを特徴とする豆腐の鮮度保持方法。
1. A tofu is dipped in an anode water obtained by electrolyzing an aqueous solution of an alkali chloride compound in an electrolytic cell having an anode chamber and a cathode chamber separated by an ion-permeable diaphragm. A freshness-preserving method for tofu, which is characterized by storing in a state of being shielded from the external atmosphere.
【請求項2】 前記陽極水が、酸化還元電位が1000
〜1200mVで、かつpHが2.0〜3.0のもので
あることを特徴とする請求項1記載の豆腐の鮮度保持方
法。
2. The redox potential of the anode water is 1000.
The method for keeping freshness of tofu according to claim 1, wherein the method is to 1200 mV and pH is 2.0 to 3.0.
JP8004387A 1996-01-12 1996-01-12 Process for keeping freshness of bean curd Pending JPH09187243A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8004387A JPH09187243A (en) 1996-01-12 1996-01-12 Process for keeping freshness of bean curd

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8004387A JPH09187243A (en) 1996-01-12 1996-01-12 Process for keeping freshness of bean curd

Publications (1)

Publication Number Publication Date
JPH09187243A true JPH09187243A (en) 1997-07-22

Family

ID=11582957

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8004387A Pending JPH09187243A (en) 1996-01-12 1996-01-12 Process for keeping freshness of bean curd

Country Status (1)

Country Link
JP (1) JPH09187243A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013042757A (en) * 2012-02-16 2013-03-04 Yoshiharu Ota Apparatus for manufacturing food raw material and processed food

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013042757A (en) * 2012-02-16 2013-03-04 Yoshiharu Ota Apparatus for manufacturing food raw material and processed food

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