JPH09165321A - Hair rinse agent composition - Google Patents
Hair rinse agent compositionInfo
- Publication number
- JPH09165321A JPH09165321A JP32909495A JP32909495A JPH09165321A JP H09165321 A JPH09165321 A JP H09165321A JP 32909495 A JP32909495 A JP 32909495A JP 32909495 A JP32909495 A JP 32909495A JP H09165321 A JPH09165321 A JP H09165321A
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- water
- hair
- component
- rinse
- weight
- Prior art date
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Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、毛髪に均一に塗布
することができ、リンス効果が高く、使用感及び効果の
持続性に優れたヘアリンス剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair rinse composition which can be uniformly applied to hair, has a high rinsing effect, and has excellent feeling of use and durability of effect.
【０００２】[0002]
【従来の技術】一般に、ヘアリンス剤組成物は、陽イオ
ン性界面活性剤、油分等を含有するものであり、これら
の成分が毛髪に吸着し、毛髪の表面をなめらかにして、
くし通りをよくし、静電気を防止し、毛髪の表面を保護
する等の機能を発現する。このようなヘアリンス剤組成
物は、洗髪後の毛髪に塗布した後、すすぐことにより使
用されている。2. Description of the Related Art Generally, a hair rinse composition contains a cationic surfactant, an oil component, etc., and these components are adsorbed to the hair to make the surface of the hair smooth,
It has the functions of improving combability, preventing static electricity, and protecting the surface of hair. Such a hair rinse composition is used by applying it to hair after washing and then rinsing.
【０００３】しかしながら、従来のヘアリンス剤組成物
は、毛髪に直接塗布又はのばして使用するものであるた
め、毛髪全体に均一に適用するのは困難であった。特に
長い髪の場合には、より困難であり、手間もかかるとい
う問題がある。また、ヘアリンス剤組成物が均一に塗布
されていない状態ですすぎ流すと、効果が著しく低減し
てしまうという問題もあった。However, since the conventional hair rinse composition is used by directly applying it to the hair or extending it, it is difficult to apply it uniformly to the entire hair. Especially for long hair, there is a problem that it is more difficult and time-consuming. Further, there is a problem that the effect is significantly reduced if the hair rinse composition is rinsed off in a state where it is not uniformly applied.
【０００４】さらに、従来のヘアリンス剤組成物を希釈
して使用しようとした場合には、その性状等から、油分
が浮遊したり、一部の成分が沈殿したりしてしまい、水
等に均一に分散させることは不可能であった。Furthermore, when a conventional hair rinse composition is used by diluting it, oil properties may be suspended or some components may be precipitated due to its properties, etc. Was impossible to disperse.
【０００５】[0005]
【発明が解決しようとする課題】従って、本発明の目的
は、毛髪に均一に塗布することができ、リンス効果が高
く、使用感及びリンス効果の持続性に優れたヘアリンス
剤組成物を提供することにある。Therefore, an object of the present invention is to provide a hair rinse composition which can be uniformly applied to hair, has a high rinsing effect, and is excellent in the feeling of use and the durability of the rinsing effect. Especially.
【０００６】[0006]
【課題を解決するための手段】かかる実情において、本
発明者らは鋭意研究を行った結果、水で希釈したとき
に、リンス成分の９８重量％以上が水相から分離される
ようなヘアリンス剤組成物が、簡便に、毛髪に均一に塗
布することができ、リンス効果が高く、使用感及びリン
ス効果の持続性に優れることを見出し、本発明を完成し
た。Under such circumstances, as a result of intensive studies by the present inventors, a hair rinse agent in which 98% by weight or more of a rinse component is separated from an aqueous phase when diluted with water. The present invention has been completed by finding that the composition can be easily and uniformly applied to hair, has a high rinsing effect, and has excellent feeling in use and durability of the rinsing effect.
【０００７】すなわち、本発明は、陽イオン性界面活性
剤及び高級アルコールをリンス成分として含有する溶液
状のヘアリンス剤組成物であって、これを水で１．８倍
以上に希釈したときに、該リンス成分の９８重量％以上
が水相から分離されることを特徴とするヘアリンス剤組
成物を提供するものである。That is, the present invention is a solution-like hair rinse composition containing a cationic surfactant and a higher alcohol as a rinse component, which is diluted 1.8 times or more with water, A hair rinse composition comprising 98% by weight or more of the rinse component separated from an aqueous phase.
【０００８】[0008]
【発明の実施の形態】本発明のヘアリンス剤組成物は、
リンス成分として陽イオン性界面活性剤及び高級アルコ
ールを含有する溶液状のものである。ここで、溶液状と
は、均一透明溶液をいう。BEST MODE FOR CARRYING OUT THE INVENTION The hair rinse composition of the present invention comprises:
It is a solution containing a cationic surfactant and a higher alcohol as a rinse component. Here, the solution form means a uniform transparent solution.
【０００９】本発明で用いられるリンス成分のうち、陽
イオン性界面活性剤としては、例えば次の一般式
（１）、（２）又は（３）で表わされるものが挙げられ
る。Among the rinse components used in the present invention, examples of the cationic surfactant include those represented by the following general formula (1), (2) or (3).
【００１０】[0010]
【化１】 Embedded image
【００１１】（式中、Ｒ1 は炭素数８〜２２の直鎖又は
分岐鎖のアルキル基又はアルケニル基を示し、Ｒ2 は水
素原子、メチル基、エチル基又は炭素数８〜２２の直鎖
若しくは分岐鎖のアルキル基若しくはアルケニル基を示
し、Ｒ3 及びＲ4 はそれぞれ水素原子、メチル基又はエ
チル基を示し、Ｒ5 は炭素数２〜３のアルキレン基を示
し、Ａはハロゲン原子又は有機アニオン基を示し、ｎは
１〜１０の数を示す）(Wherein R 1 represents a straight chain or branched chain alkyl or alkenyl group having 8 to 22 carbon atoms, and R 2 represents a hydrogen atom, a methyl group, an ethyl group or a straight chain having 8 to 22 carbon atoms. Or a branched alkyl group or alkenyl group, R 3 and R 4 each represent a hydrogen atom, a methyl group or an ethyl group, R 5 represents an alkylene group having 2 to 3 carbon atoms, and A represents a halogen atom or an organic group. Represents an anion group, and n represents a number of 1 to 10)
【００１２】[0012]
【化２】 Embedded image
【００１３】（式中、Ｒ6 は直鎖又は分岐鎖の炭素数７
〜３５のアルキル基又はアルケニル基を示し、Ｒ7 、Ｒ
8 及びＲ9 は同一又は異なって、炭素数１〜４のアルキ
ル基若しくはヒドロキシアルキル基又は水素原子を示
し、Ｂは-CONJ-（Ｊは水素原子又は炭素数１〜３のアル
キル基若しくはヒドロキシアルキル基を示す）、-O- 又
は-COO- を示し、Ｙは水素原子、ヒドロキシル基、炭素
数１〜３６の直鎖若しくは分岐鎖のアルキル基、アルケ
ニル基若しくはヒドロキシアルキル基又は式(In the formula, R 6 is a linear or branched chain having 7 carbon atoms.
An alkyl group or an alkenyl group, R 7 , R
8 and R 9 are the same or different and each represent an alkyl group or a hydroxyalkyl group having 1 to 4 carbon atoms or a hydrogen atom, and B represents -CONJ- (J is a hydrogen atom or an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms) Y represents a hydrogen atom, a hydroxyl group, a linear or branched alkyl group having 1 to 36 carbon atoms, an alkenyl group or a hydroxyalkyl group, or a group represented by the formula:
【００１４】[0014]
【化３】 Embedded image
【００１５】で表わされる基を示し、Ｘは水素原子又は
ヒドロキシル基を示し、ｍは２又は３の数を示し、ｌは
０又は１〜５の整数を示す。ただし、ｌ＝１の場合、Ｘ
は水素原子又はヒドロキシル基を示し、ｌ＝０、２、
３、４、５の場合、Ｘは水素原子を示す、Ａは前記と同
じ）X represents a hydrogen atom or a hydroxyl group, m represents a number of 2 or 3, and 1 represents an integer of 0 or 1 to 5. However, when l = 1, X
Represents a hydrogen atom or a hydroxyl group, and l = 0, 2,
In the case of 3, 4, and 5, X represents a hydrogen atom, and A is the same as described above.
【００１６】これらの陽イオン性界面活性剤のうち、特
にステアリルトリメチルアンモニウムクロライド、セチ
ルトリメチルアンモニウムクロライド、（２−ドデシ
ル）ヘキサデシルトリメチルアンモニウムクロライドが
好ましい。Of these cationic surfactants, stearyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, and (2-dodecyl) hexadecyl trimethyl ammonium chloride are particularly preferable.
【００１７】また、リンス成分のうち、高級アルコール
としては、例えばラウリルアルコール、セチルアルコー
ル、ステアリルアルコール、オレイルアルコール、ラノ
リンアルコール、コレステロール、２−ヘキシルデカノ
ール等が挙げられ、特にセチルアルコール、ステアリル
アルコールが好ましい。Among the rinse components, higher alcohols include, for example, lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, lanolin alcohol, cholesterol, 2-hexyldecanol and the like, with cetyl alcohol and stearyl alcohol being particularly preferred.
【００１８】本発明のヘアリンス剤組成物において、陽
イオン性界面活性剤及び高級アルコールは、全組成中に
合計で１０重量％以上、特に１２〜２５重量％、さらに
１５〜２０重量％配合するのが好ましい。また、陽イオ
ン性界面活性剤と高級アルコールの配合割合は、重量比
で２：１〜１：５、特に１：１〜１：４であるのが好ま
しい。In the hair rinse composition of the present invention, the cationic surfactant and the higher alcohol are added in a total amount of 10% by weight or more, particularly 12 to 25% by weight, and further 15 to 20% by weight in the total composition. Is preferred. Further, the mixing ratio of the cationic surfactant and the higher alcohol is preferably 2: 1 to 1: 5, and particularly preferably 1: 1 to 1: 4 by weight.
【００１９】また、本発明のヘアリンス剤組成物は、水
で１．８倍以上に希釈したときに、リンス成分、すなわ
ち含有されている陽イオン性界面活性剤及び高級アルコ
ールの９８重量％以上が水相から分離されることが必要
である。９８重量％未満しか分離しないのでは、リンス
成分が毛髪へ吸着し難くなる。なお、水で１．８倍に希
釈したときにリンス成分の９８重量％以上が水相から分
離されるヘアリンス剤組成物は、水で１．８倍以上、例
えば１０倍、１００倍、２００倍等に希釈した場合に
も、同様に相分離が起こる。In the hair rinse composition of the present invention, when diluted with water 1.8 times or more, 98% by weight or more of the rinse component, that is, the contained cationic surfactant and higher alcohol is contained. It needs to be separated from the aqueous phase. If less than 98% by weight is separated, it becomes difficult for the rinse component to be adsorbed on the hair. A hair rinse composition in which 98% by weight or more of the rinse component is separated from the aqueous phase when diluted 1.8 times with water is 1.8 times or more with water, for example, 10 times, 100 times, 200 times. Phase separation also occurs when diluted evenly.
【００２０】水で希釈したときに、このような相分離が
生じる本発明のヘアリンス剤組成物としては、例えば
（Ａ）陽イオン性界面活性剤、（Ｂ）高級アルコール、
及び（Ｃ）水に可溶な有機溶剤を含有し、水の含有量が
１５重量％以下であるヘアリンス剤組成物が挙げられ
る。Examples of the hair rinse composition of the present invention in which such phase separation occurs when diluted with water include (A) a cationic surfactant, (B) a higher alcohol,
And (C) a hair rinse composition containing an organic solvent soluble in water and having a water content of 15% by weight or less.
【００２１】ここで用いられる（Ｃ）有機溶剤は、水に
可溶なものであり、例えばエタノール、プロパノール、
プロピレングリコール、エチルカルビトール、ソルビト
ール、グリセリン、１，３−ブタンジオール、３−メチ
ル−１，３−ブタンジオール等が挙げられる。これらの
うち、特に、プロピレングリコール、３−メチル−１，
３−ブタンジオールが好ましい。成分（Ｃ）の有機溶剤
は、全組成中に３０〜９８重量％配合するのが好まし
く、特に５０〜９０重量％、さらに６０〜８５重量％配
合すると、水で希釈したときに相分離が完成に起こるの
で好ましい。The organic solvent (C) used here is one that is soluble in water, such as ethanol, propanol,
Propylene glycol, ethyl carbitol, sorbitol, glycerin, 1,3-butanediol, 3-methyl-1,3-butanediol and the like can be mentioned. Of these, propylene glycol, 3-methyl-1,
3-butanediol is preferred. The organic solvent of the component (C) is preferably added in an amount of 30 to 98% by weight in the total composition, particularly 50 to 90% by weight, and further 60 to 85% by weight, to complete phase separation when diluted with water. It is preferred because it occurs in
【００２２】また、（Ａ）陽イオン性界面活性剤として
は前記と同様のものを全組成中に１〜１５重量％、特に
２〜１２重量％、さらに３〜１０重量％配合するのが好
ましい。（Ｂ）高級アルコールとしても、前記と同様の
ものを全組成中に１〜２０重量％、特に２〜１８重量
％、さらに５〜１５重量％配合するのが好ましい。As the cationic surfactant (A), the same ones as described above are preferably added in an amount of 1 to 15% by weight, particularly 2 to 12% by weight, and further 3 to 10% by weight in the total composition. . As the higher alcohol (B), it is preferable to add the same one as described above to the whole composition in an amount of 1 to 20% by weight, particularly 2 to 18% by weight, and further 5 to 15% by weight.
【００２３】さらに、水の含有量は全組成中に１５重量
％以下であり、好ましくは０．０１〜１０重量％、特に
好ましくは０．１〜５重量％である。１５重量％を超え
るとリンス成分が析出し、分散性が低下するので好まし
くない。Further, the content of water is 15% by weight or less in the whole composition, preferably 0.01 to 10% by weight, particularly preferably 0.1 to 5% by weight. If it exceeds 15% by weight, the rinse component is precipitated and the dispersibility is deteriorated, which is not preferable.
【００２４】本発明のヘアリンス剤組成物には、さらに
水に不溶又は難溶な油性成分を配合することができ、成
分を可溶化することができる。ここで用いられる油性成
分としては、例えば炭素数６〜２２の脂肪酸モノグリセ
ライド、脂肪酸ジグリセライド、モノアルキルグリセリ
ルエーテル、ジアルキルグリセリルエーテル等が挙げら
れる。これらの油性成分を配合する場合は、全組成中に
０．０１〜４０重量％、特に５〜３０重量％配合するの
が好ましい。The hair rinse composition of the present invention may further contain an oily component which is insoluble or sparingly soluble in water to solubilize the component. Examples of the oil component used here include fatty acid monoglycerides having 6 to 22 carbon atoms, fatty acid diglycerides, monoalkyl glyceryl ethers, dialkyl glyceryl ethers, and the like. When these oily components are blended, 0.01 to 40% by weight, especially 5 to 30% by weight is preferably blended in the entire composition.
【００２５】本発明のヘアリンス剤組成物には、前記成
分のほか、通常のヘアリンス剤組成物に用いられる成
分、例えば抗フケ剤、抗菌剤及びビタミン等の薬効剤、
パラベン等の防腐剤、染料、顔料等の着色剤、グリコー
ルエステル等のパール化剤、各種調合香料などを、本発
明の効果を損なわない範囲で適宜配合することができ
る。In the hair rinse composition of the present invention, in addition to the above-mentioned components, components used in a usual hair rinse composition, for example, anti-dandruff agents, antibacterial agents and vitamins and other medicinal agents,
Preservatives such as parabens, coloring agents such as dyes and pigments, pearling agents such as glycol esters, various fragrances, and the like can be appropriately added within a range that does not impair the effects of the present invention.
【００２６】本発明のヘアリンス剤組成物は、通常の方
法により、例えば各成分を混合攪拌することにより製造
することができる。The hair rinse composition of the present invention can be manufactured by a conventional method, for example, by mixing and stirring each component.
【００２７】本発明のヘアリンス剤組成物は、シャンプ
ー後の毛髪に直接塗布して使用することもできるが、湯
又は水で薄め、好ましくは５０〜５００倍程度、特に好
ましくは１００〜２００倍程度に希釈し、これを毛髪に
かけることにより使用するのが好ましい。湯又は水に投
入されると、湯又は水中に均一に分散される。そして各
成分の配合量等を調整することにより、ヘアリンス剤組
成物自体は透明であり、湯又は水中に投入すると白濁
し、かつ油性成分を含有する場合でも、これが水面に浮
かないようにすることができる。The hair rinse composition of the present invention can be used by directly applying it to hair after shampooing, but it is diluted with hot water or water, preferably about 50 to 500 times, particularly preferably about 100 to 200 times. It is preferable to use it by diluting it into hair and applying it to the hair. When poured into hot water or water, it is uniformly dispersed in the hot water or water. And by adjusting the blending amount of each component, etc., the hair rinse composition itself is transparent, becomes cloudy when poured into hot water or water, and even if it contains an oily component, prevent it from floating on the water surface. You can
【００２８】[0028]
【発明の効果】本発明のヘアリンス剤組成物は、リンス
成分を高濃度に配合することができ、高いリンス効果が
得られる。また、湯又は水で希釈して使用するため、簡
便に毛髪に均一に塗布することができ、使用感及びリン
ス効果の持続性に優れたものである。The hair rinse composition of the present invention can contain a rinse component in a high concentration, and a high rinse effect can be obtained. Moreover, since it is diluted with hot water or water, it can be easily and uniformly applied to the hair, and the feeling of use and the durability of the rinse effect are excellent.
【００２９】[0029]
【実施例】次に実施例を挙げて本発明をさらに説明する
が、本発明はこれら実施例に限定されるものではない。The present invention will be further described with reference to the following examples, but the present invention is not limited to these examples.
【００３０】実施例１ 表１及び表２に示す組成のヘアリンス剤組成物を常法に
より製造した。得られたヘアリンス剤組成物について、
水への分散性及びリンス効果を評価した。結果を表１及
び表２に示す。なお、本発明品のヘアリンス剤組成物は
いずれも、水で１．８倍に希釈したときに、リンス成分
の９８重量％以上が水相から分離した。一方、比較品は
分離しなかった。Example 1 Hair rinse compositions having the compositions shown in Tables 1 and 2 were produced by a conventional method. Regarding the obtained hair rinse composition,
The dispersibility in water and the rinse effect were evaluated. The results are shown in Tables 1 and 2. In each of the hair rinse composition of the present invention, 98% by weight or more of the rinse component was separated from the aqueous phase when diluted 1.8 times with water. On the other hand, the comparative product was not separated.
【００３１】（評価方法） （１）水への分散性：ヘアリンス剤組成物５mlを水１ｌ
に添加し（２００倍希釈）、軽く攪拌したときの分散状
態を目視により評価した。分散状態の良好なものを
「○」、不良なものを「×」として示した。(Evaluation method) (1) Dispersibility in water: 5 ml of the hair rinse composition was added to 1 l of water.
(Diluted 200 times), and the state of dispersion when lightly stirred was visually evaluated. A sample having a good dispersion state was shown as “◯”, and a sample having a poor dispersion state was shown as “x”.
【００３２】（２）リンス効果：（１）において調製し
たヘアリンス剤希釈液中に毛髪サンプルを浸し、手でな
じませる過程と、液中から引き上げて流水中ですすぐ過
程におけるなめらかさ及び柔らかさを以下の基準で官能
評価した。 ◎；非常になめらかで柔らかい。 ○；なめらかで柔らかい。 △；あまりなめらかで柔らかくない。 ×；なめらかで柔らかくない。(2) Rinse effect: Smoothness and softness in the process of dipping the hair sample in the hair rinse agent diluted solution prepared in (1) and licking it by hand, and the process of pulling out from the liquid and rinsing in running water The sensory evaluation was performed based on the following criteria. ◎: Very smooth and soft. ○: Smooth and soft. Δ: Not very smooth and soft. ×: Smooth and not soft
【００３３】[0033]
【表１】 [Table 1]
【００３４】[0034]
【表２】 [Table 2]
【００３５】実施例２ 次に示す組成のヘアリンス剤組成物を常法により製造し
た。Example 2 A hair rinse composition having the following composition was produced by a conventional method.
【表３】 （成分） （重量％） セタノール １０ ステアリルトリメチルアンモニウムクロライド ５ プロピレングリコール ２９．７５ カプリル酸モノグリセライド ５ エトキシジグリコール （ジエチレングリコールエチレンエーテル） ４０ エタノール １０ 香料 ０．１５ パラオキシ安息香酸メチル ０．１０(Component) (wt%) Cetanol 10 Stearyltrimethylammonium chloride 5 Propylene glycol 29.75 Caprylic acid monoglyceride 5 Ethoxydiglycol (diethylene glycol ethylene ether) 40 Ethanol 10 Perfume 0.15 Methyl paraoxybenzoate 0.10
【００３６】得られたヘアリンス剤組成物を水で１．８
倍に希釈したところ、リンス成分の９８重量％以上が水
相から分離した。また、得られたヘアリンス剤組成物５
mlを１０００mlの湯に投入したところ、湯は均一に白濁
し、これを毛髪にかけると、髪全体に均一に塗布するこ
とができ、リンス効果が高く、使用感及び効果の持続性
に優れていた。The hair rinse composition thus obtained was diluted with water to give 1.8.
When diluted twice, 98% by weight or more of the rinse component was separated from the aqueous phase. Moreover, the obtained hair rinse composition 5
When 1000 ml of hot water is added, the hot water becomes cloudy evenly, and when this is applied to the hair, it can be applied evenly to the entire hair, the rinse effect is high, and the feeling of use and the durability of the effect are excellent. It was
【００３７】実施例３ 次に示す組成のヘアリンス剤組成物を常法により製造し
た。Example 3 A hair rinse composition having the following composition was produced by a conventional method.
【表４】 （成分） （重量％） セタノール ８ ジステアリルジメチルアンモニウムクロライド ３ セチルトリメチルアンモニウムクロライド ３ プロピレングリコール ４２ カプリル酸モノグリセライド １０ エタノール ３３．７５ 香料 ０．１５ パラオキシ安息香酸メチル ０．１０[Table 4] (Components) (wt%) Cetanol 8 Distearyldimethylammonium chloride 3 Cetyltrimethylammonium chloride 3 Propylene glycol 42 Caprylic acid monoglyceride 10 Ethanol 33.75 Perfume 0.15 Methyl paraoxybenzoate 0.10
【００３８】得られたヘアリンス剤組成物を水で１．８
倍に希釈したところ、リンス成分の９８重量％以上が水
相から分離した。また、得られたヘアリンス剤組成物５
mlを１０００mlの湯に投入したところ、湯は均一に白濁
し、これを毛髪にかけると、髪全体に均一に塗布するこ
とができ、リンス効果が高く、使用感及び効果の持続性
に優れていた。The resulting hair rinse composition was 1.8 with water.
When diluted twice, 98% by weight or more of the rinse component was separated from the aqueous phase. Moreover, the obtained hair rinse composition 5
When 1000 ml of hot water is added, the water becomes cloudy evenly, and when this is applied to the hair, it can be evenly applied to the entire hair, and the rinse effect is high, and the feeling of use and the durability of the effect are excellent. It was
Claims (4)
ルをリンス成分として含有する溶液状のヘアリンス剤組
成物であって、これを水で１．８倍以上に希釈したとき
に、該リンス成分の９８重量％以上が水相から分離され
ることを特徴とするヘアリンス剤組成物。1. A solution-like hair rinse composition containing a cationic surfactant and a higher alcohol as a rinse component, which when the rinse component is diluted 1.8 times or more with water. A hair rinse composition comprising 98% by weight or more separated from an aqueous phase.
級アルコール、及び（Ｃ）水に可溶な有機溶剤を含有
し、水の含有量が１５重量％以下である請求項１記載の
ヘアリンス剤組成物。2. The composition contains (A) a cationic surfactant, (B) a higher alcohol, and (C) a water-soluble organic solvent, and the water content is 15% by weight or less. The hair rinse composition described.
（Ｂ）を１〜２０重量％、成分（Ｃ）を３０〜９８重量
％含有する請求項２記載のヘアリンス剤組成物。3. The hair rinse composition according to claim 2, which contains 1 to 15% by weight of the component (A), 1 to 20% by weight of the component (B), and 30 to 98% by weight of the component (C).
含有する請求項２記載のヘアリンス剤組成物。4. The hair rinse composition according to claim 2, further comprising an oily component insoluble or hardly soluble in water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32909495A JP3502492B2 (en) | 1995-12-18 | 1995-12-18 | Hair rinse composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32909495A JP3502492B2 (en) | 1995-12-18 | 1995-12-18 | Hair rinse composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH09165321A true JPH09165321A (en) | 1997-06-24 |
| JP3502492B2 JP3502492B2 (en) | 2004-03-02 |
Family
ID=18217550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP32909495A Expired - Fee Related JP3502492B2 (en) | 1995-12-18 | 1995-12-18 | Hair rinse composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3502492B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010090219A1 (en) * | 2009-02-03 | 2010-08-12 | 株式会社 資生堂 | Hair conditioner composition and low-energy manufacturing method for the same |
| EP2316414A1 (en) * | 2008-08-08 | 2011-05-04 | Shiseido Company, Ltd. | Hair conditioner composition |
-
1995
- 1995-12-18 JP JP32909495A patent/JP3502492B2/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2316414A1 (en) * | 2008-08-08 | 2011-05-04 | Shiseido Company, Ltd. | Hair conditioner composition |
| EP2316414A4 (en) * | 2008-08-08 | 2011-09-21 | Shiseido Co Ltd | Hair conditioner composition |
| WO2010090219A1 (en) * | 2009-02-03 | 2010-08-12 | 株式会社 資生堂 | Hair conditioner composition and low-energy manufacturing method for the same |
| CN102170854A (en) * | 2009-02-03 | 2011-08-31 | 株式会社资生堂 | Hair conditioner composition and low-energy manufacturing method for the same |
| EP2394632A1 (en) * | 2009-02-03 | 2011-12-14 | Shiseido Co., Ltd. | Hair conditioner composition and low-energy manufacturing method for the same |
| EP2394632A4 (en) * | 2009-02-03 | 2012-08-08 | Shiseido Co Ltd | Hair conditioner composition and low-energy manufacturing method for the same |
| JPWO2010090219A1 (en) * | 2009-02-03 | 2012-08-09 | 株式会社 資生堂 | Hair conditioner composition and low energy production method thereof |
| TWI398264B (en) * | 2009-02-03 | 2013-06-11 | Shiseido Co Ltd | Hair conditioner composition and low energy method for making same |
| US9539444B2 (en) | 2009-02-03 | 2017-01-10 | Shiseido Company, Ltd. | Hair conditioning composition and low energy method of producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3502492B2 (en) | 2004-03-02 |
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