JPH0892047A - Hair dye composition - Google Patents

Hair dye composition

Info

Publication number
JPH0892047A
JPH0892047A JP21850495A JP21850495A JPH0892047A JP H0892047 A JPH0892047 A JP H0892047A JP 21850495 A JP21850495 A JP 21850495A JP 21850495 A JP21850495 A JP 21850495A JP H0892047 A JPH0892047 A JP H0892047A
Authority
JP
Japan
Prior art keywords
hair dye
dye composition
hair
weight
amino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP21850495A
Other languages
Japanese (ja)
Inventor
Daisuke Misu
大介 三栖
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Publication of JPH0892047A publication Critical patent/JPH0892047A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol

Abstract

PURPOSE: To obtain a hair dye composition excellent in hair dyeing properties and hair conditioning effects, and capable of retaining a hair dyeing effects for a long period. CONSTITUTION: This hair dye composition containing at least one kind of oxidation dye precursor comprises containing (a) 0.1-5wt.% quaternary amonium compound having one or two 8-22C alkyl groups and (b) 0.1-5wt.% N-(8-18)C acylamino acid or its water-soluble salt.

Description

【発明の詳細な説明】Detailed Description of the Invention

【０００１】[0001]

【発明の属する技術分野】本発明は、新規ヘアダイ組成
物に関し、更に詳細には、酸化染料前駆体を含有する組
成物であって、従来のヘアダイ組成物に比べ、染毛効果
が強く、より長期間持続するヘアダイ組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a novel hair dye composition, and more particularly to a composition containing an oxidative dye precursor, which has a stronger hair dyeing effect than conventional hair dye compositions. It relates to a long-lasting hair dye composition.

【０００２】[0002]

【従来の技術】従来のヘアダイ組成物は、通常、酸化さ
れることによってヘアカラー剤を生成する少なくとも一
種の染料前駆体、すなわち少なくとも一種の展色剤と通
常一種のカップリング剤を含有し、任意成分として直接
染料を色合い調節剤として含有するものである。これら
のヘアダイ組成物は、毛髪に適用する前に、希釈した過
酸化水素水溶液と混合される。このような染毛手順の目
的は、出来る限り完全で、強力で長く持続する染毛効果
を達成することである。BACKGROUND OF THE INVENTION Conventional hair dye compositions usually contain at least one dye precursor, i.e., at least one color developing agent and usually one coupling agent, which is oxidized to form a hair coloring agent. It contains a direct dye as an optional component as a tint adjusting agent. These hair dye compositions are mixed with a dilute aqueous hydrogen peroxide solution before being applied to the hair. The purpose of such a hair dyeing procedure is to achieve a hair dyeing effect that is as complete, strong and long lasting as possible.

【０００３】しかしながら、今日市販されている酸化染
料前駆体に基づいて調製されたヘアダイ組成物は、これ
らの点において十分満足できるものではなかった。However, hair dye compositions prepared on the basis of oxidative dye precursors that are commercially available today have not been fully satisfactory in these respects.

【０００４】[0004]

【発明が解決しようとする課題】従って、本発明の目的
は、より高い染毛力と優れた染毛安定性を有する酸化ヘ
アダイ組成物を提供することにある。SUMMARY OF THE INVENTION Therefore, an object of the present invention is to provide an oxidative hair dye composition having higher hair dyeing power and excellent hair dyeing stability.

【０００５】[0005]

【課題を解決するための手段】かかる実情において、本
発明者らは鋭意研究を行った結果、酸化染料前駆体を含
有するヘアダイ組成物に、特定の第４級アンモニウム化
合物とＮ−アシルアミノ酸を組合わせて用いれば、より
高い染毛力を有し、染毛効果が長期間持続し染毛安定性
に優れたヘアダイ組成物が得られることを見出し、本発
明を完成した。Under the circumstances, as a result of intensive studies, the present inventors have found that a hair dye composition containing an oxidative dye precursor contains a specific quaternary ammonium compound and an N-acyl amino acid. It has been found that, when used in combination, a hair dye composition having higher hair dyeing power, long-lasting hair dyeing effect and excellent hair dyeing stability can be obtained, and the present invention has been completed.

【０００６】すなわち、本発明は、少なくとも一種の酸
化染料前駆体を含有するヘアダイ組成物において、 ａ）Ｃ8−Ｃ22アルキル基を一個または二個有する第４
級アンモニウム化合物０．１〜５重量％、および ｂ）Ｎ−Ｃ8−Ｃ18アシルアミノ酸またはその水溶性塩
０．１〜５重量％を含有することを特徴とするヘアダイ
組成物を提供するものである。That is, the present invention provides a hair dye composition containing at least one oxidative dye precursor, which comprises: a) a fourth group having one or two C 8 -C 22 alkyl groups.
Grade ammonium compounds 0.1 to 5 wt%, and b) N-C 8 -C 18 provides a acylamino acid or a hair dye composition characterized by containing a water-soluble salt thereof 0.1 to 5 wt% Is.

【０００７】[0007]

【発明の実施の形態】本発明のヘアダイ組成物は、通常
用いられる酸化染料前駆体を含有するものであり、好ま
しくは少なくとも１種の展色剤および少なくとも１種の
カップリング物質を含有する。BEST MODE FOR CARRYING OUT THE INVENTION The hair dye composition of the present invention contains a commonly used oxidative dye precursor, and preferably contains at least one color developing agent and at least one coupling substance.

【０００８】展色剤としては、この目的を達成するもの
として知られまた用いられている酸化染料前駆体はすべ
て、本発明組成物に用いることができる。かかる展色剤
としては、例えば１，４−ジアミノベンゼン、２，５−
ジアミノトルエン、４−アミノフェノール、２，５−ジ
アミノベンジルアルコール、１−アミノ−４−［ビス
（２−ヒドロキシエチル）−アミノ］ベンゼン、３−メ
チル−４−アミノフェノール、テトラアミノピリミジ
ン、２，５，６−トリアミノ−４−ヒドロキシピリミジ
ン等のトリアミノヒドロキシピリミジン、２，４−ジヒ
ドロキシ−５，６−ジアミノピリミジン、４，６−ジヒ
ドロキシ−２，５−ジアミノピリミジン等のジアミノジ
ヒドロキシピリミジン、２−（２’−ヒドロキシエチル
アミノ）−５−アミノトルエン、およびこれらの塩など
が挙げられる。また、例えば公知の５，６−ジヒドロキ
シインドールおよびその誘導体等の他の展色剤も単独で
あるいは組み合わせて用いることができる。As the color-developing agent, all the oxidative dye precursors known and used for achieving this purpose can be used in the composition of the present invention. Examples of such a color-developing agent include 1,4-diaminobenzene and 2,5-
Diaminotoluene, 4-aminophenol, 2,5-diaminobenzyl alcohol, 1-amino-4- [bis (2-hydroxyethyl) -amino] benzene, 3-methyl-4-aminophenol, tetraaminopyrimidine, 2, Triaminohydroxypyrimidines such as 5,6-triamino-4-hydroxypyrimidine, diaminodihydroxypyrimidines such as 2,4-dihydroxy-5,6-diaminopyrimidine, 4,6-dihydroxy-2,5-diaminopyrimidine, 2- (2′-Hydroxyethylamino) -5-aminotoluene, salts thereof and the like can be mentioned. Further, other color-developing agents such as known 5,6-dihydroxyindole and its derivatives can be used alone or in combination.

【０００９】展色剤の配合量は、過酸化物と混合する前
の組成物全量中に（塩として存在する場合は遊離塩基と
して）、約０．０５〜約５重量％、好ましくは０．１〜
３重量％、更に好ましくは０．２５〜１．５重量％であ
る。The amount of the color-developing agent to be blended is about 0.05 to about 5% by weight, preferably 0.1% by weight, in the total amount of the composition (as a free base when present as a salt) before mixing with the peroxide. 1 to
3% by weight, more preferably 0.25 to 1.5% by weight.

【００１０】カップリング物質は、展色剤対カップリン
グ物質のモル比が約０．５：１〜約２．５：１となる範
囲で用いられるのが好ましく、カップリング物質として
は、例えばレゾルシノール、２−メチルレゾルシノー
ル、４−クロロレゾルシノール、２−アミノフェノー
ル、４−（Ｎ−メチル）アミノフェノール、３−アミノ
フェノール、３−Ｎ，Ｎ−ジメチルアミノフェノール、
４−アミノ−３−メチルフェノール、５−アミノ−２−
メチルフェノール、６−アミノ−３−メチルフェノー
ル、３−アミノ−２−メチルアミノ−６−メトキシピリ
ジン、２−アミノ−３−ヒドロキシピリジン、４−アミ
ノジフェニルアミン、４，４’−ジアミノジフェニルア
ミン、２−ジメチルアミノ−５−アミノピリジン、２，
６−ジアミノピリジン、１，３−ジアミノベンゼン、１
−エトキシ−２，４−ジアミノベンゼン、１−メトキシ
−２−アミノ−４−（２−ヒドロキシエチル）アミノベ
ンゼン、１−アミノ−３−（２’−ヒドロキシエチルア
ミノ）ベンゼン、１−アミノ−３−［ビス（２’−ヒド
ロキシエチル）アミノ］ベンゼン、１，３−ジアミノト
ルエン、α−ナフトール、１，４−ジアミノ−２−クロ
ロベンゼン、４，６−ジクロロレゾルシノール、４−ヒ
ドロキシ−１，２−メチレンジオキシベンゼン、１，５
−ジヒドロキシナフタリン、１，７−ジヒドロキシナフ
タリン、２，７−ジヒドロキシナフタリン、１−ヒドロ
キシナフタリン、４−ヒドロキシー１，２−メチレンジ
オキシベンゼン、２，４−ジアミノ−３−クロロフェノ
ール、１−メトキシ−２−アミノ−４−（２’−ヒドロ
キシエチルアミノ）ベンゼン等が挙げられる。The coupling substance is preferably used in a molar ratio of the color developing agent to the coupling substance of about 0.5: 1 to about 2.5: 1. Examples of the coupling substance include resorcinol. , 2-methylresorcinol, 4-chlororesorcinol, 2-aminophenol, 4- (N-methyl) aminophenol, 3-aminophenol, 3-N, N-dimethylaminophenol,
4-amino-3-methylphenol, 5-amino-2-
Methylphenol, 6-amino-3-methylphenol, 3-amino-2-methylamino-6-methoxypyridine, 2-amino-3-hydroxypyridine, 4-aminodiphenylamine, 4,4'-diaminodiphenylamine, 2- Dimethylamino-5-aminopyridine, 2,
6-diaminopyridine, 1,3-diaminobenzene, 1
-Ethoxy-2,4-diaminobenzene, 1-methoxy-2-amino-4- (2-hydroxyethyl) aminobenzene, 1-amino-3- (2'-hydroxyethylamino) benzene, 1-amino-3 -[Bis (2'-hydroxyethyl) amino] benzene, 1,3-diaminotoluene, α-naphthol, 1,4-diamino-2-chlorobenzene, 4,6-dichlororesorcinol, 4-hydroxy-1,2- Methylenedioxybenzene, 1,5
-Dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 1-hydroxynaphthalene, 4-hydroxy-1,2-methylenedioxybenzene, 2,4-diamino-3-chlorophenol, 1-methoxy- 2-amino-4- (2′-hydroxyethylamino) benzene and the like can be mentioned.

【００１１】特定の色合いを得るために、異なるカップ
リング物質を混合して用いることができ、かかる混合物
としては、例えばレゾルシノールまたは２−メチルレゾ
ルシノールと２−アミノフェノールおよび／または３−
アミノフェノールの混合物、レゾルシノールまたは２−
メチルレゾルシノールと１−メトキシ−２−アミノ−４
−（２’−ヒドロキシエチルアミノ）ベンゼンの混合
物、２−アミノ−３−ヒドロキシピリジンと５−アミノ
−２−メチルフェノールおよび／または１−メトキシ−
２−アミノ−４−（２’−ヒドロキシエチルアミノ）ベ
ンゼンの混合物、１，３−ジアミノベンゼンと１，４−
ジアミノ−２−クロロベンゼンの混合物等が挙げられ
る。Different coupling substances can be used in admixture in order to obtain a particular shade, such mixtures being, for example, resorcinol or 2-methylresorcinol and 2-aminophenol and / or 3-aminophenol.
A mixture of aminophenols, resorcinol or 2-
Methylresorcinol and 1-methoxy-2-amino-4
A mixture of-(2'-hydroxyethylamino) benzene, 2-amino-3-hydroxypyridine and 5-amino-2-methylphenol and / or 1-methoxy-
A mixture of 2-amino-4- (2'-hydroxyethylamino) benzene, 1,3-diaminobenzene and 1,4-
A mixture of diamino-2-chlorobenzene and the like can be mentioned.

【００１２】また、特定の色合いを得るために、通常使
用されている直接染料を少量、好ましくは０．０５〜１
重量％の範囲内で配合することができる。このような直
接染料としては、例えば良く知られたアリアノール(Ari
anor) 染料や、２−アミノ−４，６−ジニトロフェノー
ル、２−アミノ−６−クロロ−４−ニトロフェノール、
２−アミノ−４−ニトロフェノール等のニトロ染料；ヘ
ンナ等の植物染料などを挙げることができる。２−ニト
ロ−ｐ−フェニレンジアミンおよび４−ニトロ−ｏ−フ
ェニレンジアミンは、その毒性のため、任意成分から除
外される。Further, in order to obtain a specific color tone, a small amount of a direct dye which is usually used, preferably 0.05 to 1 is used.
It can be blended within the range of wt%. Such direct dyes include, for example, the well-known
anor) dye, 2-amino-4,6-dinitrophenol, 2-amino-6-chloro-4-nitrophenol,
Examples thereof include nitro dyes such as 2-amino-4-nitrophenol; plant dyes such as henna. 2-Nitro-p-phenylenediamine and 4-nitro-o-phenylenediamine are excluded from the optional ingredients due to their toxicity.

【００１３】最終製品における酸化染料前駆体の配合量
の総量は、過酸化物と混合する前の組成物全量中に好ま
しくは約０．２〜６．０重量％、特に好ましくは約０．
５〜４重量％である。The total amount of the oxidation dye precursor compounded in the final product is preferably about 0.2 to 6.0% by weight, and particularly preferably about 0. 0% by weight based on the total amount of the composition before mixing with the peroxide.
It is 5 to 4% by weight.

【００１４】本発明で用いられるＣ8−Ｃ22アルキル基
を一個または二個有する第４級アンモニウム化合物とし
ては、Ｃ12−Ｃ18アルキル基を有するものが好ましく、
例えばセチルトリメチルアンモニウムクロライド、ジメ
チルジセチルアンモニウムクロライド、トリメチルセチ
ルアンモニウムブロマイド、ステアリルトリメチルアン
モニウムクロライド、ジメチルステアリルベンジルアン
モニウムクロライド、ベンジルテトラデシルジメチルア
ンモニウムクロライド、ジメチル硬化牛脂アンモニウム
クロライド、ラウリルピリジニウムクロライド、ラウリ
ルジメチルベンジルアンモニウムクロライド、ラウリル
トリメチルアンモニウムクロライド、トリス（オリゴオ
キシエチル）アルキルアンモニウムホスフェート、セチ
ルピリジニウムクロライド等が挙げられる。また、ヨー
ロッパ特許出願第４７２１０７号に記載された第４級ア
ンモニウム塩もまた非常に好ましい。基本的には、一般
名称コータニウム（Quaternium）としてＣＴＦＡ化粧料
成分辞典（第４版、１９９１年）に掲載されている全て
の第４級アンモニウム塩化合物を好適に用いることがで
きる。The quaternary ammonium compound having one or two C 8 -C 22 alkyl groups used in the present invention is preferably one having a C 12 -C 18 alkyl group,
For example, cetyl trimethyl ammonium chloride, dimethyl dicetyl ammonium chloride, trimethyl cetyl ammonium bromide, stearyl trimethyl ammonium chloride, dimethyl stearyl benzyl ammonium chloride, benzyl tetradecyl dimethyl ammonium chloride, dimethyl hardened tallow ammonium chloride, lauryl pyridinium chloride, lauryl dimethyl benzyl ammonium chloride. , Lauryltrimethylammonium chloride, tris (oligooxyethyl) alkylammonium phosphate, cetylpyridinium chloride and the like. Also highly preferred are the quaternary ammonium salts described in European Patent Application No. 472107. Basically, all of the quaternary ammonium salt compounds listed in the CTFA Cosmetics Ingredient Dictionary (4th edition, 1991) under the general name Quaternium can be preferably used.

【００１５】これらの第４級アンモニウム塩は、一種ま
たは二種以上を組合わせて用いることができ、過酸化物
と混合する前の組成物全量中に０．１〜５重量％、特に
０．２５〜３重量％、更に０．５〜２．５重量％配合す
るのが好ましい。These quaternary ammonium salts may be used either individually or in combination of two or more, and may be used in an amount of 0.1 to 5% by weight, particularly 0.1% by weight based on the total amount of the composition before mixing with the peroxide. It is preferable to add 25 to 3% by weight, more preferably 0.5 to 2.5% by weight.

【００１６】本発明において用いられるＮ−Ｃ8−Ｃ18
アシルアミノ酸またはその水溶性塩は、長鎖第４級アン
モニウム化合物と同様、公知の物質である。Ｎ−Ｃ8−
Ｃ18アシルアミノ酸としては、例えばＮ−ラウロイルグ
ルタミン酸、Ｎ−ラウロイルサルコシネート、Ｎ−ミリ
ストイルサルコシネート、Ｎ−オレオイルサルコシネー
ト、Ｎ−ラウロイルメチルアラニン、Ｎ−ラウロイルリ
シン、Ｎ−ラウロイルアミノプロピルグリシン等が挙げ
られ、これらの水溶性塩としては、アルカリ金属塩また
はアンモニウム塩が好ましい。これらのうち、Ｎ−ラウ
ロイルグルタミン酸またはその水溶性塩が好ましく、特
にそのアルカリ金属塩、更にナトリウム塩がより好まし
い。N-C 8 -C 18 used in the present invention
The acylamino acid or its water-soluble salt is a known substance like the long-chain quaternary ammonium compound. N-C 8 -
Examples of the C 18 acylamino acid include N-lauroyl glutamic acid, N-lauroyl sarcosinate, N-myristoyl sarcosinate, N-oleoyl sarcosinate, N-lauroyl methylalanine, N-lauroyl lysine and N-lauroyl amino. Examples thereof include propylglycine, and as the water-soluble salts thereof, alkali metal salts or ammonium salts are preferable. Among these, N-lauroyl glutamic acid or its water-soluble salt is preferable, and its alkali metal salt and sodium salt are more preferable.

【００１７】これらのＮ−アシルアミノ酸またはその水
溶性塩は、１種または２種以上を組合わせて用いること
ができ、過酸化物と混合する前の組成物全量中に０．１
〜５重量％、特に０．２５〜２．５重量％、更に０．５
〜１．５重量％配合するのが好ましい。These N-acyl amino acids or water-soluble salts thereof can be used alone or in combination of two or more, and the amount is 0.1
~ 5% by weight, especially 0.25-2.5% by weight, even 0.5
It is preferable to blend the composition in an amount of ˜1.5% by weight.

【００１８】本発明のヘアダイ組成物には、コンディシ
ョニング効果をより一層高めるため、他の成分、例えば
ピロリドンカルボン酸またはその水溶性塩、好ましくは
ナトリウム塩等を配合することができる。かかる成分
は、過酸化物と混合する前の組成物全量中に、約０．１
〜１０重量％、特に０．５〜５重量％、更に１〜３重量
％配合するのが好ましい。In order to further enhance the conditioning effect, the hair dye composition of the present invention may contain other components such as pyrrolidonecarboxylic acid or its water-soluble salt, preferably sodium salt. Such an ingredient is added in an amount of about 0.1 in the total amount of the composition before mixing with the peroxide.
It is preferable to add 10 to 10% by weight, particularly 0.5 to 5% by weight, and further 1 to 3% by weight.

【００１９】本発明のヘアダイ組成物には、更にジメチ
コーンコポリオールを配合することができ、コンディシ
ョニング効果と染毛力をより向上させることができる。
ジメチコーンコポリオールは、過酸化物と混合する前の
組成物全量中に０．１〜１重量％、特に０．２〜０．７
重量％配合するのが好ましい。The hair dye composition of the present invention may further contain dimethicone copolyol to improve the conditioning effect and hair dyeing power.
The dimethicone copolyol is 0.1 to 1% by weight, especially 0.2 to 0.7% by weight in the total amount of the composition before mixing with the peroxide.
It is preferable to add the composition in a weight percentage.

【００２０】これらの物質も公知のものであり、化粧料
に使用される成分として推奨されている。好適なものと
しては、例えば前記ＣＴＦＡ国際化粧料成分辞典（第４
版、１９９１年）第161〜163頁や、ドイツ特許出願第４
２３１６５９号に記載されており、これらの記載は本発
明に援用される。These substances are also known and recommended as components used in cosmetics. Suitable ones include, for example, the CTFA International Cosmetic Ingredient Dictionary (No. 4).
Ed., 1991) pp. 161-163 and German patent application No. 4
231659, which are incorporated herein by reference.

【００２１】本発明のヘアダイ組成物には、更に通常の
ヘアダイ組成物に用いられる成分を、本発明の効果を損
わない範囲において適宜配合することができる。かかる
成分としては、例えば界面活性剤、安定化剤、増粘剤、
非イオン性、カチオン性、両性イオン性またはアニオン
性の天然または合成ポリマー等のコンディショニング成
分などが挙げられ、これらは、例えばK. Schrader 著 "
Grundlagen und Rezepturen der Kosmetika" 第二版
（１９８９年、Huthig Buchverlag 、ハイデルベルグ)
第796-815 頁を始めとする多くの文献に記載されてい
る。これらの文献類をここに明記して援用する。[0021] The hair dye composition of the present invention may further contain components used in ordinary hair dye compositions, as long as the effects of the present invention are not impaired. Examples of such components include a surfactant, a stabilizer, a thickener,
Examples include conditioning components such as nonionic, cationic, zwitterionic or anionic natural or synthetic polymers, which are described, for example, by K. Schrader.
Grundlagen und Rezepturen der Kosmetika "Second Edition (1989, Huthig Buchverlag, Heidelberg)
It is described in many documents including pages 796-815. These documents are specifically incorporated herein by reference.

【００２２】本発明のヘアダイ組成物は、酸化染料前駆
体、すなわち好ましくは展色剤とカップリング物質の混
合物と、第４級アンモニア化合物およびＮ−アシルアミ
ノ酸、更に任意成分を、適切な化粧料用基剤に加えるこ
とにより製造される。基剤としては、クリーム、ゲル、
エマルジョン等が好ましい。The hair dye composition of the present invention comprises an oxidative dye precursor, that is, preferably a mixture of a color-developing agent and a coupling substance, a quaternary ammonia compound and an N-acyl amino acid, and further optional ingredients in a suitable cosmetic composition. It is manufactured by adding it to a base material. As a base, cream, gel,
Emulsion and the like are preferable.

【００２３】本発明のヘアダイ組成物は、弱酸性からア
ルカリ性にかけてのpH範囲であるのが好ましく、すなわ
ち、pH約６〜約１１、特にpH７〜９．５が好ましい。The hair dye composition of the present invention preferably has a pH range from weakly acidic to alkaline, that is, a pH of about 6 to about 11, especially a pH of 7 to 9.5 is preferable.

【００２４】本発明のヘアダイ組成物は、適用直前に過
酸化物、例えばこれと等量の６％過酸化水素水等、と混
合した後に毛髪に塗布し、適用後２０〜４０分間処理し
た後、通常のシャンプーと水で洗い流すことにより使用
される。過酸化水素はそれ自体で用いることができる
が、他の過酸化物、例えば過酸化ホウ素、過酸化尿素、
過酸化メラミン等で置き換えて用いてもよい。しかしな
がら、これらの過酸化物は、使用時まで無水状態に保た
れていなければならないため、用量や操作性の点で複雑
になる。The hair dye composition of the present invention is mixed with a peroxide immediately before application, for example, an equal amount of 6% hydrogen peroxide solution, and then applied to the hair, and after treatment for 20 to 40 minutes. Used by rinsing with ordinary shampoo and water. Hydrogen peroxide can be used by itself, but other peroxides such as boron peroxide, urea peroxide,
It may be replaced with melamine peroxide or the like. However, these peroxides must be kept anhydrous until use, which complicates dose and operability.

【００２５】[0025]

【実施例】以下、実施例により本発明を更に詳しく説明
する。The present invention will be described in more detail with reference to the following examples.

【００２６】実施例１〜４ 表１に示す組成のヘアダイ組成物を常法により製造し
た。Examples 1 to 4 Hair dye compositions having the compositions shown in Table 1 were produced by a conventional method.

【００２７】[0027]

【表１】 [Table 1]

【００２８】実施例１〜４のヘアダイ組成物を６％過酸
化水素溶液と１：１の割合で混合し、ヒトの毛髪に塗布
した。２５〜３０分経過後、毛髪を洗浄し、乾燥した。
その結果、毛髪には非常に表現豊かで強い着色が得ら
れ、その後シャンプーで５回洗髪しても効果が保たれ
た。また、毛髪の感触は軟らかで、櫛通りが良かった。
なお、実施例１〜４によって得られた毛髪の色合いは下
記のとおりであった。The hair dye compositions of Examples 1 to 4 were mixed with a 6% hydrogen peroxide solution in a ratio of 1: 1 and applied to human hair. After 25 to 30 minutes, the hair was washed and dried.
As a result, very expressive and strong coloring was obtained on the hair, and the effect was maintained even after washing the hair 5 times with shampoo. In addition, the hair had a soft feel and combed well.
The shades of the hair obtained in Examples 1 to 4 were as follows.

【００２９】[0029]

【表２】 [Table 2]

【００３０】[0030]

【発明の効果】本発明のヘアダイ組成物は、染毛力に優
れ、染毛効果が長期間持続し、しかもコンディショニン
グ効果に優れ、櫛通りも良好である。EFFECTS OF THE INVENTION The hair dye composition of the present invention has excellent hair dyeing ability, long-lasting hair dyeing effect, excellent conditioning effect, and good combability.

Claims (5)

【特許請求の範囲】[Claims] 【請求項１】 少なくとも一種の酸化染料前駆体を含有
するヘアダイ組成物において、 ａ）Ｃ8−Ｃ22アルキル基を一個または二個有する第４
級アンモニウム化合物０．１〜５重量％、および ｂ）Ｎ−Ｃ8−Ｃ18アシルアミノ酸またはその水溶性塩
０．１〜５重量％を含有することを特徴とするヘアダイ
組成物。1. A hair dye composition comprising at least one oxidative dye precursor, comprising: a) a fourth group having one or two C 8 -C 22 alkyl groups.
Grade ammonium compounds 0.1 to 5 wt%, and b) N-C 8 -C 18 acylamino acid or a hair dye composition characterized by containing a water-soluble salt thereof 0.1 to 5 wt%. 【請求項２】 Ｎ−Ｃ8−Ｃ18アシルアミノ酸としてＮ
−ラウロイルグルタミン酸またはその水溶性塩を０．２
５〜２．５重量％含有する請求項１記載のヘアダイ組成
物。2. N-C 8 -C 18 N as an acylamino acid
Lauroyl glutamic acid or a water-soluble salt thereof in 0.2
The hair dye composition according to claim 1, containing 5 to 2.5% by weight. 【請求項３】 第４級アンモニウム化合物を０．５〜３
重量％含有する請求項１または２記載のヘアダイ組成
物。3. A quaternary ammonium compound is added in an amount of 0.5 to 3
The hair dye composition according to claim 1, wherein the hair dye composition is contained in a weight percentage. 【請求項４】 更に、ピロリドンカルボン酸を０．１〜
１０重量％含有する請求項１〜３のいずれか１項記載の
ヘアダイ組成物。4. Further, the pyrrolidone carboxylic acid is added in an amount of 0.1 to 0.1.
The hair dye composition according to any one of claims 1 to 3, containing 10% by weight. 【請求項５】 更に、ジメチコーンコポリオールを０．
１〜１重量％含有する請求項１〜４のいずれか１項記載
のヘアダイ組成物。5. The dimethicone copolyol is further added in an amount of 0.
The hair dye composition according to any one of claims 1 to 4, which comprises 1 to 1% by weight.
JP21850495A 1994-08-27 1995-08-28 Hair dye composition Pending JPH0892047A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19944430521 DE4430521C1 (en) 1994-08-27 1994-08-27 Hair dye compsn. contg. an oxidisable dye precursor
DE4430521:4 1994-08-27

Publications (1)

Publication Number Publication Date
JPH0892047A true JPH0892047A (en) 1996-04-09

Family

ID=6526759

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Application Number Title Priority Date Filing Date
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Country Status (2)

Country Link
JP (1) JPH0892047A (en)
DE (1) DE4430521C1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013043870A (en) * 2011-08-25 2013-03-04 Dhc Co Hair cosmetic
JP2013530257A (en) * 2010-04-14 2013-07-25 ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド Thickened amino acid surfactant composition and method

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19615145A1 (en) * 1996-04-18 1997-10-23 Henkel Kgaa Process and agent for simultaneous dyeing and care of keratin fibers
DE10009438A1 (en) * 2000-02-29 2001-08-30 Schwarzkopf Gmbh Hans Use of combination of pyrrolidinone carboxylic acid derivative and cationic or amphoteric polymer to improve wash-fastness of dyed fibers, especially human hair
EP2072037A1 (en) * 2007-12-17 2009-06-24 Farmen International Cosmetics Distribution S.p.A Hair dyeing compositions
EP2471504A1 (en) 2010-12-28 2012-07-04 KPSS-Kao Professional Salon Services GmbH Two-part hair colouring composition

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4039063A1 (en) * 1990-12-07 1992-06-11 Wella Ag HAIR CURING IN THE FORM OF A MICROEMULSION
DE4129926C1 (en) * 1991-09-09 1992-07-23 Kao Corporation Gmbh, 4000 Duesseldorf, De
DE4211450A1 (en) * 1992-04-06 1993-10-07 Henkel Kgaa Agent for colouring keratin-contg. fibres, e.g. hair - contg. an aq. carrier, an isatin deriv., and an aminoacid or oligopeptide

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013530257A (en) * 2010-04-14 2013-07-25 ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド Thickened amino acid surfactant composition and method
JP2013043870A (en) * 2011-08-25 2013-03-04 Dhc Co Hair cosmetic

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