JPH0891882A - Pane for fire protection and crime prevention - Google Patents

Pane for fire protection and crime prevention

Info

Publication number
JPH0891882A
JPH0891882A JP6221804A JP22180494A JPH0891882A JP H0891882 A JPH0891882 A JP H0891882A JP 6221804 A JP6221804 A JP 6221804A JP 22180494 A JP22180494 A JP 22180494A JP H0891882 A JPH0891882 A JP H0891882A
Authority
JP
Japan
Prior art keywords
glass
plate
frit
fire
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6221804A
Other languages
Japanese (ja)
Inventor
Toshikazu Kondo
敏和 近藤
Nobuyuki Yamamoto
信行 山本
Tetsuo Kawahara
哲郎 河原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Sheet Glass Co Ltd
Original Assignee
Nippon Sheet Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Sheet Glass Co Ltd filed Critical Nippon Sheet Glass Co Ltd
Priority to JP6221804A priority Critical patent/JPH0891882A/en
Publication of JPH0891882A publication Critical patent/JPH0891882A/en
Pending legal-status Critical Current

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  • Special Wing (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

PURPOSE: To provide a pane having fire protection performance and crime prevention performance in combination by interposing a metallic sheet between two or more of glass sheets and adhering the glass sheet surface facing the front surface thereof by the frit, thereby forming an integral structure. CONSTITUTION: The metallic sheet 4 having through-parts 3 of a circular, elliptic or polygonal shape and having a thickness of 0.1 to 1.0mm is formed. The respective through-parts 3 have a diameter of 3 to 20mm when converted in area to a circle. The through-parts 3 have a linear expansion coefft. of 70 to 130×10<-7> / deg.C at 30 to 350 deg.C. The frit 5 which is an amorphous material having a sealing temp. of 400 to 750 deg.C or an amorphous material having a sealing temp. of <=750 deg.C and having a coefft. of linear expansion of 80 to 120×10<-7> / deg.C at 30 to 350 deg.C is mixed with a vehicle and is thinly applied on both surfaces of the metallic sheet formed in the manner described above. The coating is then dried. Next, the metallic sheet 4 is held between the glass sheet 1 having a soda lime silicate glass compsn. and the glass sheet 2 and the frit mixed with the vehicle is applied on the outer peripheries of the glass sheets 1 and 2 and the glass sheets are heat treated on a flat rack plate at 450 to 630 deg.C.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は防火性能を有するととも
に、衝撃等による貫通孔生成が困難で犯罪者の侵入抑止
効果が高い防火・防犯ガラスに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fire / security glass which has a fire-proof property and is difficult to generate a through hole due to an impact or the like and has a high effect of suppressing the intrusion of a criminal.

【0002】[0002]

【従来の技術】火災時に延焼を防止できる防火性能を持
つガラス板としては、金属網入りガラス板が最も良く知
られている。近年、金属網入りガラス板に代わって、熱
膨張係数が小さくかつ軟化温度の高い透明結晶化ガラス
あるいは強化したほう珪酸ガラスを使用する例も見られ
る。しかし、これらはいずれも充分な耐衝撃性および耐
貫通性を持たず、犯罪者侵入の抑制効果が十分ではな
い。
2. Description of the Related Art A glass plate with a metal mesh is most well known as a glass plate having a fireproof property capable of preventing the spread of fire in the event of a fire. In recent years, examples of using transparent crystallized glass having a small coefficient of thermal expansion and a high softening temperature or reinforced borosilicate glass have been seen in place of the glass plate with metal mesh. However, none of these have sufficient impact resistance and penetration resistance, and the effect of suppressing the intrusion of criminals is not sufficient.

【0003】一方、耐衝撃性と耐貫通性を有し、防犯性
能を持つガラス板としては合わせガラスが知られてい
る。更に性能を向上させるため強化ガラスを使用した強
化合わせガラスも知られている。また、中間膜の間に透
孔性を有する金属製板材を入れた防犯窓用合わせガラス
も考案されている(実開平2−140938)。これら
はいずれも有機性の合わせ用中間膜を使用しているた
め、火災時の高温状態には有害ガスが発生する危険があ
るとともにその形状を保持できず防火性能が弱い。
On the other hand, laminated glass is known as a glass plate having impact resistance and penetration resistance and having crime prevention performance. A tempered laminated glass using a tempered glass for further improving the performance is also known. In addition, a laminated glass for crime prevention window, in which a metal plate material having a porosity is inserted between the intermediate films, has also been devised (Actual Kaihei 2-140938). Since all of these use an organic interlayer film for matching, there is a risk that harmful gas will be generated in a high temperature state at the time of a fire, and the shape cannot be maintained, so that the fire prevention performance is weak.

【0004】2枚のガラス板の間の空隙に透かし部をも
つ金属を挟んだ考案もある(実開昭56−14673
4)。更に1枚のガラス板に打ち抜き孔のある金属薄板
を接着した透光面材がある(実開昭63−11632
6)。これら二つの考案いずれも充分な防火性能は期待
できない。
There is also a device in which a metal having a watermark is sandwiched in a space between two glass plates (Actual No. 56-14673).
4). Further, there is a light-transmitting surface material in which a thin metal plate having a punched hole is adhered to one glass plate (Shokai Sho 63-11632).
6). Neither of these two devices can be expected to have sufficient fire protection.

【0005】また、耐熱性の低膨張透明結晶化ガラスと
普通のソーダ石灰ガラス、あるいは低膨張ほう珪酸ガラ
スの間にPET膜を挟み、接着した合わせガラスが防火
・安全ガラス板として開示されている(特開平6−48
786)。これも膜厚が薄くて防犯性の点では不十分で
ある。
A laminated glass in which a PET film is sandwiched between heat-resistant low-expansion transparent crystallized glass and ordinary soda-lime glass or low-expansion borosilicate glass is disclosed as a fire and safety glass plate. (JP-A-6-48
786). This is also inadequate in terms of crime prevention because of its thin film thickness.

【0006】透かし部のある金属薄板を2枚のガラス板
で挟んで、誘導加熱により金属薄板とガラス板を融着す
る考案がある(特開平6−56485)。この方法は金
属薄板が急に加熱されるため、ガラス板に亀裂が入りや
すい欠点がある。
There is a device in which a thin metal plate having a watermark is sandwiched between two glass plates and the thin metal plate and the glass plate are fused by induction heating (Japanese Patent Laid-Open No. 6-56485). This method has a drawback in that the glass sheet is likely to be cracked because the thin metal plate is rapidly heated.

【0007】更に、網入りガラスの表面に伝導性のパタ
ーンを形成し、ガラスが破損すると導通しなくなること
を利用して警報を出すなどの工夫をした防火・防犯ガラ
スもあるが、誤警報の恐れもあり、また意図的な犯罪者
の侵入を阻止できない。
[0007] Further, there is a fire / security glass that has been devised such that an electrically conductive pattern is formed on the surface of the meshed glass and an alarm is issued by utilizing the fact that if the glass is broken, it will not conduct electricity. There are fears and it is impossible to prevent the intrusion of intentional criminals.

【0008】[0008]

【発明が解決しようとする課題】最近、高層集合住宅の
入り口ドアーなどに防火性と防犯性を併せ持つ透光性材
料が要求されている。合わせガラスの場合には有機性の
中間膜を使用する必要があり、この中間膜は一般に可燃
性のため、甲種あるいは乙種防火戸としての機能は期待
しがたい。燃えにくい有機薄膜もあるが非常に高価で接
着性などに問題がある。一方、防火性能を重視すれば、
金属網入りガラス板に見られるように、意図的な犯罪者
の侵入を抑止出来るほどの耐衝撃性と耐貫通性を持たせ
ることができない。
Recently, there has been a demand for a translucent material having both fireproof property and crime prevention property for entrance doors of high-rise apartment houses. In the case of laminated glass, it is necessary to use an organic interlayer film, and since this interlayer film is generally flammable, it is difficult to expect its function as a Class A or Class B fire door. There are some organic thin films that are difficult to burn, but they are very expensive and have problems with adhesion. On the other hand, if fire protection is important,
As can be seen in the glass plate with metal mesh, it cannot be provided with impact resistance and penetration resistance enough to prevent the intentional intrusion of criminals.

【0009】本発明の目的は火炎などを遮断する防火性
能を持ち、通常時には耐衝撃性に優れ、貫通孔の出来に
くい防犯性能を併せもつ透光性ガラス板窓を提供するこ
とにある。
An object of the present invention is to provide a translucent glass plate window having fireproof performance for blocking flames and the like, excellent shock resistance in normal times, and crime prevention performance in which a through hole is hardly formed.

【0010】[0010]

【課題を解決するための手段】本発明者らは上記の目的
を達成すべく、研究を重ねた結果、中間膜などの有機性
材料を使用することなく防火性と防犯性を兼ね備えた透
光性ガラス板窓の構造を見いだした。すなわち、本発明
は、少なくとも2枚のガラス板の間に、透かし部を有す
る金属薄板を介在させ、かつ前記金属薄板の表面とそれ
に対向するガラス板表面をフリットにより接着して一体
化構造としたことを特徴とする防火・防犯用窓ガラスで
ある。
Means for Solving the Problems The inventors of the present invention have conducted extensive studies to achieve the above-mentioned object, and as a result, have achieved a light-transmitting property having both fire and crime prevention properties without using an organic material such as an interlayer film. I found the structure of the glass window. That is, according to the present invention, a metal thin plate having a watermark portion is interposed between at least two glass plates, and the surface of the metal thin plate and the glass plate surface opposite thereto are bonded by a frit to form an integrated structure. It is a characteristic fire and crime prevention window glass.

【0011】本発明による防火・防犯用窓ガラスは、2
枚または3枚以上のガラス板の間に所定厚みの少なくと
も1枚の金属薄板を挟んで接着した一体化構造になって
いる。前記金属薄板は互いに隔てられた複数の透かし部
分をもっている。この透かし部分は窓ガラスに透光性を
もたせる。そして金属薄板の表面とそれに対向するガラ
ス板表面はフリットにより接着されている。このフリッ
トとしては、ガラス同士、金属同士、あるいは金属とガ
ラスを接着および封着する無機材料として広く電子部品
などに使用されているものを使用することができる。フ
リットをビークルと呼ぶ有機溶剤と混合して金属薄板の
両面に塗布し、これをガラス板の間に挟んで、フリット
の融着温度で加熱すれば金属薄板とガラス板が一体化し
た防火・防犯ガラスが得られる。
The window glass for fire / crime prevention according to the present invention is 2
It has an integrated structure in which at least one thin metal plate having a predetermined thickness is sandwiched and adhered between one or three or more glass plates. The metal sheet has a plurality of watermark portions separated from each other. This watermark makes the window glass transparent. The surface of the thin metal plate and the surface of the glass plate facing it are adhered by a frit. As the frit, it is possible to use one widely used in electronic parts and the like as an inorganic material for adhering and sealing glass to glass, metal to metal, or metal and glass. The frit is mixed with an organic solvent called a vehicle, applied on both sides of a thin metal plate, sandwiched between glass plates, and heated at the frit fusion temperature to create a fire and crime prevention glass in which the thin metal plate and the glass plate are integrated. can get.

【0012】本発明において、ガラス板、フリットおよ
び金属薄板の熱膨張率の差を所定の範囲内になるように
選ぶことにより、ガラス板と金属薄板が熱処理の冷却過
程であるいは使用中に外れたりすることが防止され、接
着後に大きな歪が残ってガラス板が割れ易くなるのを防
止することができる。通常、ガラス板として使用される
ソーダ・ライムシリケート組成のガラスの熱膨張率は、
30〜350℃で約85×10-7/℃である。金属薄板
とガラス板の熱膨張率差は、出来る限り小さい方が熱応
力の発生による破損の危険が少なくて好ましい。ガラス
板と金属薄板の間に存在させるフリットとして適当な熱
膨張率を有するものを選ぶことにより、発生する熱応力
は緩和されるため、金属薄板として熱膨張率が70〜1
30×10-7/℃(30〜350℃)の範囲のものを使
用して一体化構造を維持することができる。このときフ
リットの熱膨張率は80〜120×10-7/℃(30〜
350℃)であれば、一体化構造が維持できるともに、
ガラスが破損することもない。このような熱膨張率範囲
にある金属薄板の材質としては例えば、Sylvani
a#4( 42Niー6Cr-Fe)、SUS410(1
3Cr-Fe)、SUS430(18Cr-Fe)、Ca
rpenter52(50NiーFe)などがある。
In the present invention, by selecting the difference in the coefficient of thermal expansion of the glass plate, the frit and the metal thin plate within a predetermined range, the glass plate and the metal thin plate may come off during the cooling process of the heat treatment or during use. It is possible to prevent the glass plate from being cracked easily due to a large strain remaining after the bonding. Usually, the coefficient of thermal expansion of the glass of soda lime silicate composition used as a glass plate,
It is about 85 × 10 −7 / ° C. at 30 to 350 ° C. It is preferable that the difference in the coefficient of thermal expansion between the thin metal plate and the glass plate is as small as possible because the risk of damage due to the generation of thermal stress is small. By selecting a frit having an appropriate coefficient of thermal expansion between the glass plate and the metal thin plate, the generated thermal stress is relieved. Therefore, the coefficient of thermal expansion of the metal thin plate is 70 to 1
The integrated structure can be maintained by using a material in the range of 30 × 10 −7 / ° C. (30 to 350 ° C.). At this time, the coefficient of thermal expansion of the frit is 80 to 120 × 10 −7 / ° C. (30 to
If the temperature is 350 ° C), the integrated structure can be maintained and
The glass will not break. As a material of the thin metal plate in such a thermal expansion coefficient range, for example, Sylvani
a # 4 (42Ni-6Cr-Fe), SUS410 (1
3Cr-Fe), SUS430 (18Cr-Fe), Ca
rpenter 52 (50Ni-Fe) and the like.

【0013】本発明では、フリットを塗布した金属薄板
をガラス板の間に挟んで加熱処理を行う温度は、ガラス
板の軟化点(約750℃)より低いので、ガラス板表面
の平滑性に影響することが無く、金属薄板の透かし部に
対向するガラス板部分は軟化変形せず表面の平滑性は損
なわれない。従って、このガラス板部分を通して光は直
進するので透光性だけでなく透視性も維持できる。フリ
ットとしては、400〜750℃の封着温度を有する非
晶質フリットまたは750℃以下の封着温度を有する結
晶質フリットが好ましい。400℃未満の非晶質フリッ
トでは、火災発生時フリットが軟化して一体化構造が維
持できなくなり防火性能が低下する。750℃より高温
側になると前述のごとくガラス板が軟化して透視性が悪
化する。
In the present invention, the temperature at which the heat treatment is performed by sandwiching the frit-coated thin metal plate between the glass plates is lower than the softening point (about 750 ° C.) of the glass plate, so that the smoothness of the glass plate surface is affected. The glass plate portion facing the watermark of the metal thin plate is not softened and deformed and the surface smoothness is not impaired. Therefore, since the light travels straight through the glass plate portion, not only the translucency but also the transparency can be maintained. As the frit, an amorphous frit having a sealing temperature of 400 to 750 ° C. or a crystalline frit having a sealing temperature of 750 ° C. or lower is preferable. If the amorphous frit is less than 400 ° C., the frit is softened when a fire occurs, the integrated structure cannot be maintained, and the fire prevention performance is deteriorated. When the temperature is higher than 750 ° C, the glass plate is softened as described above and the transparency is deteriorated.

【0014】フリットには熱処理、接着後もガラス状態
を保持している非晶質系と結晶化する結晶質系があり、
いずれも使用可能だが、火災発生時のことを考えると一
般的には軟化しにくい結晶質系が有利である。更に廃棄
された場合の環境対策やリサイクル性を考えると、鉛や
カドミウムなどの有害物を含まないフリットが望まし
い。例えば珪素、ほう素、アルカリ金属およびアルカリ
土類金属の各酸化物からなるガラスと有害物を含まない
フィラー、例えばコージライト、ジルコンなど、からな
るフリットが望ましい。フリットに各種無機系着色剤を
含有するなどして着色することも可能である。
There are two types of frit, an amorphous system which retains a glass state after heat treatment and adhesion and a crystalline system which crystallizes.
Although any of them can be used, a crystalline system that is difficult to soften is generally advantageous in view of a fire. Further, considering the environmental measures and the recyclability when discarded, a frit containing no harmful substances such as lead and cadmium is desirable. For example, a frit made of glass made of oxides of silicon, boron, alkali metal and alkaline earth metal and a filler containing no harmful substances such as cordierite and zircon is desirable. It is also possible to color the frit by including various inorganic colorants.

【0015】本発明において、金属薄板の端部をガラス
の端部より2〜10mm程度、引っ込めておいて金属薄
板に接当しないガラス板の全周端部にもフリットを塗布
してガラス端部同士を接着すれば、金属薄板が完全にガ
ラス板中に閉じこめられるため、雨水の侵入などによる
金属薄板が錆びるのを防止することができる。なお、金
属薄板の透かし部に対向するガラス板部分は軟化変形せ
ず、金属薄板の透かし部の両側の2枚のガラス板部分の
間は空間が生じている。
In the present invention, the frit is applied to the entire peripheral edge of the glass sheet which is retracted from the edge of the glass by about 2 to 10 mm from the edge of the glass and does not contact the metal sheet. If the metal thin plates are adhered to each other, the metal thin plates can be completely enclosed in the glass plate, so that the metal thin plates can be prevented from rusting due to intrusion of rainwater. The glass plate portion facing the watermark portion of the metal thin plate is not softened and deformed, and a space is created between the two glass plate portions on both sides of the watermark portion of the metal thin plate.

【0016】ガラス板の間に入れる金属薄板の厚みは
0.1〜1.0mmが好ましい。0.1mm未満では耐
衝撃性および耐貫通性向上に効果が少なく犯罪者の侵入
を抑制できず、1.0mm以上では一体化構造窓ガラス
が重くなりすぎる欠点がある。更に好ましくは0.3〜
1.0mmである。0.3mm以上であれば、後述する
耐貫通性試験で10分以上の性能が得られ、防犯性能と
して申し分ない。
The thickness of the thin metal plate inserted between the glass plates is preferably 0.1 to 1.0 mm. If it is less than 0.1 mm, the effect of improving impact resistance and penetration resistance is small, and invasion of criminals cannot be suppressed. If it is 1.0 mm or more, the window glass having an integrated structure becomes too heavy. More preferably 0.3-
It is 1.0 mm. If it is 0.3 mm or more, a performance of 10 minutes or more can be obtained in a penetration resistance test described later, which is satisfactory as crime prevention performance.

【0017】金属透かし部の形状は、円形、楕円形ある
いは多角形でそれぞれその直径、または円に面積換算し
た場合の直径が、3〜20mmの範囲が望ましい。3m
m未満では透光性が充分でなく、20mmを越えると耐
貫通性と防火性に問題がある。より好ましい直径の範囲
は6〜15mmである。この範囲にあれば、耐貫通性を
確保した上で透視性も良くなる。金属透かし部の開口率
は20〜70%が好ましい。20%未満では透光性が充
分でなく、70%を越えると耐貫通性と防火性が低下す
る。通常は、ほぼ等しい寸法の複数の透かし部を規則的
に金属薄板にパンチング等により設ける。
The shape of the metal watermark is preferably circular, elliptical or polygonal, and the diameter when converted to a circle is preferably in the range of 3 to 20 mm. 3m
If it is less than m, the translucency is not sufficient, and if it exceeds 20 mm, there are problems in penetration resistance and fire resistance. A more preferable diameter range is 6 to 15 mm. Within this range, transparency is improved while ensuring penetration resistance. The aperture ratio of the metal watermark is preferably 20 to 70%. If it is less than 20%, the translucency is not sufficient, and if it exceeds 70%, the penetration resistance and fire resistance are deteriorated. Usually, a plurality of watermark portions having substantially the same size are regularly provided on a thin metal plate by punching or the like.

【0018】3枚以上のガラス板の隣り合ったガラス板
の間にそれぞれ金属薄板を透かし部を合わせて接着すれ
ば、透光性を確保した上で防火性能と耐衝撃性能は飛躍
的に向上する。
If a thin metal plate is adhered between adjacent glass plates of three or more glass plates together with a watermark portion, the fireproof performance and the impact resistance performance are dramatically improved while ensuring the light-transmitting property.

【0019】使用するガラス板は、透明ガラス以外に熱
線や紫外線あるいは可視域の特定波長を吸収、反射する
ガラス板でも良い。さらには型ガラス板や金属線あるい
は金属網入りガラス板でも良い。
The glass plate to be used may be a glass plate which absorbs and reflects heat rays, ultraviolet rays or specific wavelengths in the visible range, in addition to transparent glass. Further, it may be a shaped glass plate, a metal wire or a metal mesh-containing glass plate.

【0020】以上、金属薄板とガラス板をフリットによ
り接着する一体化構造(フリット法)について説明した
が、フリットを用いずに、金属薄板をガラス板の間に挟
んでガラス板を軟化点以上に加熱することで一体化構造
にすることもできる。(以下単に融着法と呼ぶ)
The integrated structure (frit method) for adhering a thin metal plate and a glass plate with a frit has been described above. However, without using a frit, the thin metal plate is sandwiched between the glass plates to heat the glass plate to a softening point or higher. By doing so, an integrated structure can be obtained. (Hereinafter referred to simply as fusion method)

【0021】融着法ではガラス板に金属薄板を挟み、ガ
ラス板と金属薄板、およびガラス板同士が互いに融着す
る温度まで加熱し、有機系材料はもちろんフリットなど
の無機系封着剤を使用することなくガラス板と金属薄板
を一体化する。なお、加熱炉は天然ガスや重油などの化
石燃料を用いるか、ニクロム線など電気抵抗体により、
ガラス板全体を加熱し、局部加熱によりガラス板に亀裂
が入らないようにする。融着法の場合には軟化点以上で
の熱処理となるため、ガラス板表面の平滑性は悪化する
ので透視性はよくないが透光性は充分である。なお一体
化処理した後、ガラス板の表面を研磨すれば透視性は良
くなる。
In the fusion method, a thin metal plate is sandwiched between glass plates and heated to a temperature at which the glass plate and the thin metal plates and the glass plates are fused to each other, and an inorganic sealing agent such as frit is used as well as an organic material. The glass plate and the thin metal plate are integrated without doing. In addition, the heating furnace uses fossil fuel such as natural gas or heavy oil, or by an electric resistor such as Nichrome wire,
The entire glass plate is heated so that the glass plate is not cracked by local heating. In the case of the fusion method, since the heat treatment is performed at a softening point or higher, the smoothness of the surface of the glass plate is deteriorated, and thus the transparency is not good, but the transparency is sufficient. The transparency is improved by polishing the surface of the glass plate after the integration process.

【0022】金属薄板の寸法をガラス板の寸法よりもや
や小さくして金属薄板の端部をガラス板端部より5mm
程度、引っ込めておき、金属薄板の端部よりも突出した
ガラス板の全周端部を融着すれば、金属薄板が完全にガ
ラス板中に閉じこめられるため金属薄板が錆びることも
ないので好ましい。しかし金属薄板の端部をガラス板端
部よりあまり大きく引っ込めると、金属薄板の透かし部
における両ガラス板の間に空気が残りやすい。空気が残
らないようにするためガラス板の中央部分から次第に周
辺部分へと融着が進行するように、ガラス板の中央部分
が周辺部分よりも先に高温度になるようなガラス板の温
度分布とするなどの必要がある。この点でも誘導加熱に
よる急熱は好ましくない。融着法の場合には使用可能な
金属薄板の熱膨張率の範囲は上述のように80〜120
×10-7/℃(30〜350℃)である。80×10-7
/℃未満あるいは120×10-7/℃より大きいと上述
のようにガラス板が割れたり、接着が外れたりする。金
属薄板の厚み、金属透かし部の形状、大きさ、金属透か
し部の開口率等については、前述のフリットを使用する
場合と同様である。
The size of the thin metal plate is made slightly smaller than that of the glass plate so that the end of the thin metal plate is 5 mm from the end of the glass plate.
It is preferable that the thin metal plate is completely retracted and the entire peripheral end portion of the glass plate protruding from the end portion of the thin metal plate is fused so that the thin metal plate is completely enclosed in the glass plate and the thin metal plate does not rust. However, if the end of the thin metal plate is retracted much more than the end of the glass plate, air tends to remain between the two glass plates in the open part of the thin metal plate. The temperature distribution of the glass plate such that the central part of the glass plate has a higher temperature than the peripheral part so that the fusion gradually progresses from the central part of the glass plate to the peripheral part to prevent air from remaining. And so on. Also in this respect, rapid heating by induction heating is not preferable. In the case of the fusion method, the range of the coefficient of thermal expansion of the metal sheet that can be used is 80 to 120 as described above.
× 10 −7 / ° C. (30 to 350 ° C.). 80 x 10 -7
If the temperature is lower than / ° C or higher than 120 × 10 -7 / ° C, the glass plate may be cracked or the adhesion may be broken as described above. The thickness of the thin metal plate, the shape and size of the metal watermark portion, the aperture ratio of the metal watermark portion, and the like are the same as in the case of using the frit described above.

【0023】[0023]

【作用】本発明により、ガラス板と透かし部を有する金
属薄板を一体化構造とした窓ガラスは火災発生時、金属
薄板とガラス板がフリットを介してあるいは直接、強固
に接着しているため、ガラス片が脱落、貫通孔を形成す
ることなく火炎や煙の通過を金属網入りガラス板と同様
に所定の時間阻止し、火災拡大を防ぐ効果がある。熱伝
導の良い金属薄板を挟んでいるため、火炎などで加熱さ
れた窓ガラス中央の高温部と周辺の低温部の温度差が抑
制されて、端部から発生した亀裂の進展を普通の金属網
入りの防火ガラスよりも妨げる効果がある。
According to the present invention, the window glass in which the glass plate and the metal thin plate having the watermark portion are integrally structured has a strong adhesion between the metal thin plate and the glass plate via the frit or directly when a fire occurs. Similar to the glass plate with metal mesh, passage of flames and smoke is blocked for a predetermined time without the glass pieces falling off and forming a through hole, and it is effective in preventing the spread of fire. Since a thin metal plate with good thermal conductivity is sandwiched, the temperature difference between the high temperature part in the center of the window glass and the low temperature part in the surroundings, which is heated by flames, is suppressed, and the development of cracks generated from the edge part is prevented by ordinary metal mesh. It is more effective than the fire protection glass that contains it.

【0024】さらに通常時においては透かし部を有する
金属薄板がガラス板と一体化した構造のため変形しがた
く耐衝撃性能および耐貫通性能に優れ、犯罪者が故意に
本発明の窓ガラスを破損して、侵入を図っても容易には
侵入させないことで優れた防犯性能がある。そして透か
し部の大きさや開口率を調節することで適当な透光性あ
るいは透視性が得られる。
Further, in a normal state, since the thin metal plate having a watermark is integrated with the glass plate, it is hard to be deformed and has excellent impact resistance and penetration resistance, and a criminal intentionally damages the window glass of the present invention. Then, even if an attempt is made to invade, it has excellent crime prevention performance because it is not easily intruded. Then, by adjusting the size and aperture ratio of the watermark portion, an appropriate translucency or transparency can be obtained.

【0025】[0025]

【実施例】表1は実施例(1〜4は本発明におけるフリ
ット法、5〜6は本発明における融着法)と比較例の構
成と性能を示すものである。表1の実施例1〜4の一部
断面図を図1に示す。ガラス板1とガラス板2の間に透
かし部3を有する金属薄板4がフリット5を介して接着
され一体化構造の窓ガラスになっている。図2はその一
部平面図である。図3は実施例5〜6の一部断面図であ
る。ガラス板1とガラス板2が透かし部3を有する金属
薄板4とフリットを介することなく融着し、一体化構造
の窓ガラスになっている。
EXAMPLES Table 1 shows the configurations and performances of Examples (1 to 4 are frit methods in the present invention, 5 to 6 are fusion methods in the present invention) and Comparative Examples. A partial sectional view of Examples 1 to 4 in Table 1 is shown in FIG. A thin metal plate 4 having a watermark 3 between the glass plate 1 and the glass plate 2 is adhered via a frit 5 to form an integrated window glass. FIG. 2 is a partial plan view thereof. FIG. 3 is a partial cross-sectional view of Examples 5-6. The glass plate 1 and the glass plate 2 are fused with the metal thin plate 4 having the watermark portion 3 without the interposition of the frit to form a window glass having an integrated structure.

【0026】実施例および比較例における各サンプルは
以下の方法によって作製した。まずフリット法について
説明する。6〜15mmの開口直径(換算径)の透かし
部、25〜82%の開口率、および95〜180×10
-7/℃(30〜350℃)の熱膨張率を有する厚み0.
05〜0.8mm、59cm角の金属薄板を用意する。
非晶質のフリット(組成系; Bi2O3−B2O3−Zn
O、PbO−B2O3−SiO2、およびSIO2−B2O3
−R2O)あるいは結晶質のフリット(組成系;PbO
−B2O3−ZnO)をビークル(ニトロセルロース2%
混合の酢酸イソアミル)と混合し、上記金属薄板の両面
に薄く塗布して乾燥させる。つぎに厚みが3mmまたは
6.8mmで60cm角のソーダ石灰珪酸塩系組成のガ
ラス板2枚の間にこの金属薄板をその端部がガラス板全
周の端部より0.5cm引っ込む状態で挟み、金属薄板
のないガラス板外周部にもビークルと混合したフリット
を金属薄板を挟み込む前にあらかじめ塗布する。その
後、サンプルを平らな棚板の上に置いて抵抗式電気炉で
450〜630℃の温度で約30分熱処理して、一体化
構造の窓ガラスが得られる。
Each sample in the examples and comparative examples was prepared by the following method. First, the frit method will be described. Watermark portion having an opening diameter (converted diameter) of 6 to 15 mm, an opening ratio of 25 to 82%, and 95 to 180 × 10
Thickness having a coefficient of thermal expansion of −7 / ° C. (30 to 350 ° C.).
A metal thin plate of 05 to 0.8 mm and 59 cm square is prepared.
Amorphous frit (composition system; Bi2O3-B2O3-Zn)
O, PbO-B2O3-SiO2, and SIO2-B2O3
-R2O) or crystalline frit (composition system; PbO)
-B2O3-ZnO) vehicle (nitrocellulose 2%
Mixed with a mixed isoamyl acetate), thinly coated on both surfaces of the above metal thin plate, and dried. Next, sandwich this thin metal plate between two glass plates having a thickness of 3 mm or 6.8 mm and a 60 cm square soda-lime silicate composition, with its end part retracted by 0.5 cm from the end part of the entire circumference of the glass plate. The frit mixed with the vehicle is also applied to the outer peripheral portion of the glass plate without the metal sheet before the metal sheet is sandwiched. Then, the sample is placed on a flat shelf and heat-treated in a resistance electric furnace at a temperature of 450 to 630 ° C. for about 30 minutes to obtain a window glass having an integrated structure.

【0027】つぎに融着法について説明する。60cm
角のガラス板2枚の間に透かし部を有する59cm角の
金属薄板をその端部がガラス板端部より0.5cm引っ
込む状態で挟み、平らな棚板の上に置いて抵抗式電気炉
で730〜770℃の温度で約45分熱処理して、一体
化構造の窓ガラスが得られる。加熱炉は急熱される誘導
加熱方式は亀裂発生の点で好ましくなく、上記の抵抗式
電気炉の代わりにガスや重油などの化石燃料を使用する
炉でも良い。
Next, the fusion method will be described. 60 cm
A 59 cm square metal thin plate having a watermark between two square glass plates is sandwiched with its edge retracted 0.5 cm from the edge of the glass plate and placed on a flat shelf plate with a resistance electric furnace. Heat treatment is performed at a temperature of 730 to 770 ° C. for about 45 minutes to obtain a window glass having an integrated structure. The induction heating method in which the heating furnace is rapidly heated is not preferable in terms of crack generation, and a furnace using fossil fuel such as gas or heavy oil may be used instead of the resistance type electric furnace.

【0028】実施例および比較例の評価は次のようにし
て行った。一体化構造はフリット法、あるいは融着法に
より製作された各サンプルにおいて、ガラス板と金属薄
板の接着が外れていたり、ガラス板が割れたりしたもの
は×、ガラス板の割れもなく一体化しているものを○と
した。
The evaluation of Examples and Comparative Examples was carried out as follows. As for the integrated structure, in each sample manufactured by the frit method or the fusion method, if the glass plate and the thin metal plate are not adhered or the glass plate is cracked, it is ×, and the glass plate is integrated without cracking. Those that were present were marked as ○.

【0029】防火性能は箱型電気炉の片面にサンプルを
取付け、炉内ガラス面近くに温度計を設置し、乙種防火
戸試験の昇温曲線により加熱したあと、ガラスが脱落し
たり、貫通孔のあるものは×、ガラスに亀裂はあるが脱
落のないものは○とした。
The fireproof performance was determined by mounting the sample on one side of a box-type electric furnace, setting a thermometer near the glass surface inside the furnace, and heating it according to the temperature rising curve of the fire extinguisher door test, and then dropping the glass or the through hole. If there was a crack, the glass was cracked but not dropped.

【0030】防犯性能はつぎのようにして耐衝撃性およ
び耐貫通性を評価した。耐衝撃性はJISR3205
(合わせガラス)のショットバッグ試験(3類)に準拠
して評価し、適合したものを○とした。耐貫通性は空き
巣の手口に倣い、サッシにはめたサンプルにマイナスの
ドライバーで孔をこじ開けて広げ、クレセント錠のロッ
クを外すまでの時間を測定して3分未満を×、3分以上
かかったものを○、10分以上かかったものを◎とし
た。
As for the crime prevention performance, impact resistance and penetration resistance were evaluated as follows. Impact resistance is JIS R3205
(Laminated glass) was evaluated according to the shot bag test (Category 3), and the one that conformed was evaluated as ◯. Penetration resistance is similar to that of a burrow, and it took less than 3 minutes x 3 minutes or more to measure the time it took to open the sample in the sash with a flathead screwdriver to open the hole and unlock the crescent lock. The sample was rated as ◯ and the sample that took 10 minutes or more was rated as ◎.

【0031】実施例1〜4のフリット法、5〜6の融着
法による各サンプルともガラス板と金属薄板が一体化し
ていて、所定の防火性能および防犯性能を示す。
In each of the samples of the frit method of Examples 1 to 4 and the fusion method of 5 to 6, the glass plate and the thin metal plate are integrated, and the predetermined fireproof performance and crime prevention performance are exhibited.

【0032】比較例1は金属薄板の熱膨張率が大きすぎ
て、ガラス板と接着できず、一体化構造にならない。比
較例2は金属薄板の開口率が大きすぎて、比較例3は金
属薄板の厚みが薄すぎてともに耐貫通性が不足し、所定
の防犯性能を満足しない。比較例4は融着温度が低すぎ
て、一体化しない。比較例5は市販のクロス型金属網入
りガラス板の例で防火性能はあるが、防犯性能はない。
乙種防火戸試験を実施すると金属網入りガラス板の亀裂
は周辺部から中央部まで進展しているが、本発明による
実施例はフリット法、融着法に関わらず、周辺部の亀裂
は中央部まで進展せず、より長時間あるいはより高温度
などの過酷な火災状況に対応しうるものと考えられる。
図4のaおよびbはそれぞれ実施例1と比較例5につい
ての乙種防火戸試験後のサンプルの亀裂状態を示し、比
較例5では亀裂が窓ガラス中央部まで達しており防火性
能が不足しているが、実施例1では亀裂は窓ガラス周辺
部に留まっており、防火性能が優れている。
In Comparative Example 1, the coefficient of thermal expansion of the thin metal plate was too large to bond it to the glass plate, resulting in no integrated structure. In Comparative Example 2, the aperture ratio of the metal thin plate is too large, and in Comparative Example 3, the metal thin plate is too thin and the penetration resistance is insufficient, and the predetermined crime prevention performance is not satisfied. In Comparative Example 4, the fusion temperature is too low to be integrated. Comparative Example 5 is an example of a commercially available cloth-type metal mesh-containing glass plate, which has fireproof performance but not crime prevention performance.
Although the cracks of the glass plate with metal mesh have progressed from the peripheral portion to the central portion when the Class B fire door test is carried out, the examples according to the present invention show that the cracks in the peripheral portion are the central portion regardless of the frit method and the fusion method. It is thought that it will be possible to cope with severe fire conditions such as longer time or higher temperature without progressing to the above.
4A and 4B show cracked states of the samples after Example B fire door tests for Example 1 and Comparative Example 5, respectively. In Comparative Example 5, the crack reached the center of the window glass and the fireproof performance was insufficient. However, in Example 1, the crack remains in the peripheral portion of the window glass, and the fire prevention performance is excellent.

【0033】[0033]

【表1】 表1 =================================== 実施例 1 2 3 4 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ガラス板 透明3mm 透明5mm 透明3mm 透明3mm 2枚 2枚 熱線反射3mm 2枚 金属薄板 材質 SUS430 Sylvania#4 SUS430 SUS430 厚み mm 0.4 0.2 0.6 0.8 熱膨張率 10-7/℃ 110 95 110 110 (30〜350℃) 開口径mm 6 6 15 3 (換算径) 開口率% 40 51 68 25 フリット 非晶質系 結晶系 非晶質系 非晶質系 PbO-B2O3-SiO2 PbO-B2O3-ZnO B2O3-SiO2-ZnO B2O3-Bi2O3-ZnO -R2O -R2O 封着温度℃ 500 450 630 550 熱膨張率 10-7/℃ 110 92 95 85 (30〜350℃) 融着温度 ℃ − − − − 一体化構造 ○ ○ ○ ○ 防火性能 ○ ○ ○ ○ 防犯性能 耐衝撃性能 ○ ○ ○ ○ 耐貫通性能 ◎ ○ ◎ ◎ ===================================[Table 1] Table 1 ===================================== Example 1 2 3 4 --- −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Glass plate Transparent 3 mm Transparent 5 mm Transparent 3 mm Transparent 3 mm 2 sheets 2 sheets Heat ray reflection 3 mm 2 Sheet metal sheet Material SUS430 Sylvania # 4 SUS430 SUS430 Thickness mm 0.4 0.2 0.2 0.6 0.8 Coefficient of thermal expansion 10 −7 / ° C. 110 95 110 110 (30 to 350 ° C.) Opening diameter mm 6 6 15 3 ( Converted diameter) Aperture ratio% 40 51 68 25 Frit Amorphous system Crystal system Amorphous system Amorphous system PbO-B 2 O 3 -SiO 2 PbO-B 2 O 3 -ZnO B 2 O 3 -SiO 2- ZnO B 2 O 3 -Bi 2 O 3 -ZnO -R 2 O -R 2 O Sealing temperature ℃ 500 450 630 550 Coefficient of thermal expansion 10 -7 / ℃ 110 92 95 85 (30-350 ℃) Fusion temperature ℃ − − − − Integrated structure ○ ○ ○ ○ Fireproof performance ○ ○ ○ ○ Crime prevention performance Impact resistance performance ○ ○ ○ ○ Penetration resistance performance ◎ ○ ◎ ◎ ================ ===================

【0034】 表1(つづき) =================================== 実施例 比較例 5 6 1 2 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ガラス板 透明3mm 透明3mm 1枚 透明3mm 透明3mm 2枚 金属線入り6mm1枚 2枚 2枚 金属薄板 材質 Carpenter52 SUS430 SUS304 SUS430 厚み mm 0.2 0.4 0.4 0.3 熱膨張率 10-7/℃ 95 110 180 110 (30〜350℃) 開口径mm 8 6 6 15 (換算径) 開口率% 34 61 53 82 フリット − − − − 封着温度℃ − − − − 熱膨張率 10-7/℃ − − − − (30〜350℃) 融着温度 ℃ 760 770 770 760 一体化構造 ○ ○ × ○ 防火性能 ○ ○ 評価せず ○ 防犯性能 耐衝撃性能 ○ ○ 評価せず ○ 耐貫通性能 ○ ◎ 評価せず × ===================================Table 1 (continued) ===================================== Example Comparative Example 5 6 1 2 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Glass plate Transparent 3 mm Transparent 3 mm 1 sheet Transparent 3 mm Transparent 3 mm 2 sheets 6mm with metal wire 1 2 2 2 Metal thin plate Material Carpenter52 SUS430 SUS304 SUS430 Thickness mm 0.2 0.4 0.4 0.4 0.3 Coefficient of thermal expansion 10 −7 / ° C. 95 110 180 110 (30 to 350 ° C.) Opening diameter mm 8 6 6 15 (converted diameter) Opening ratio% 34 61 53 53 82 Frit − − − − Sealing temperature ℃ − − − − Coefficient of thermal expansion 10 −7 / ° C. − − − − (30 to 350 ° C.) Fusion temperature ℃ 760 770 770 760 Integrated structure ○ ○ × ○ Fire prevention performance ○ ○ Not evaluated ○ Prevention Performance Impact resistance performance ○ ○ Not evaluated ○ Penetration resistance ○ ◎ Not evaluated × ================================ ====

【0035】 表1(つづき) =================================== 比較例 3 4 5 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ガラス板 透明3mm 透明3mm クロス網入り6.8mm 2枚 2枚 1枚 金属薄板 − 材質 SUS430 SUS430 メッキ軟鋼線 厚み mm 0.05 0.4 熱膨張率 10-7/℃ 110 110 (30〜350℃) 開口径mm 6 6 (換算径) 開口率% 60 48 フリット 結晶系 − − 封着温度℃ 500 − − 熱膨張率 10-7/℃ 92 − − (30〜350℃) 融着温度 ℃ − 730 − 一体化構造 ○ × ○ 防火性能 ○ 評価せず ○ 防犯性能 耐衝撃性能 ○ 評価せず ○ 耐貫通性能 × 評価せず × ================================Table 1 (continued) ===================================== Comparative Example 3 4 5 −− −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Glass plate Transparent 3 mm Transparent 3 mm Cloth with mesh 6.8 mm 2 sheets 2 sheets 1 Sheet Metal thin plate-Material SUS430 SUS430 Plated mild steel wire Thickness mm 0.05 0.4 Thermal expansion coefficient 10 -7 / ° C 110 110 (30 to 350 ° C) Opening diameter mm 6 6 (converted diameter) Opening rate% 60 48 Frit crystal System − − Sealing temperature ℃ 500 − − Coefficient of thermal expansion 10 −7 / ° C. 92 − − (30 to 350 ° C.) Fusing temperature ℃ − 730 − Integrated structure ○ × ○ Fire prevention performance ○ Not evaluated ○ Crime prevention performance Impact performance ○ Not evaluated ○ Penetration resistance × Not evaluated × ====================== ============

【0036】[0036]

【発明の効果】本発明による防火・防犯窓ガラスは火災
時にはガラスが脱落することなく火炎を所定の時間、遮
断して延焼を防止する防火性能を示し、かつ通常時には
犯罪者が意図的に破損しようとしても耐貫通性を有する
ため容易にはその侵入を許さないことで優れた防犯性能
も示す。また適当な透光性あるいは透視性が得られる。
INDUSTRIAL APPLICABILITY The fire / security window glass according to the present invention exhibits fire-preventing performance of preventing the spread of fire by blocking the flame for a predetermined time without the glass falling off in the event of a fire, and is normally damaged intentionally by a criminal. Even if an attempt is made, since it has penetration resistance, it does not easily permit its entry, and thus exhibits excellent crime prevention performance. In addition, appropriate translucency or transparency can be obtained.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の1実施例の一部断面図。FIG. 1 is a partial sectional view of an embodiment of the present invention.

【図2】図1の実施例の一部平面図。FIG. 2 is a partial plan view of the embodiment shown in FIG.

【図3】本発明における他の実施例の一部断面図。FIG. 3 is a partial cross-sectional view of another embodiment of the present invention.

【図4】本発明の実施例の防火試験後の亀裂状態を示す
平面図。
FIG. 4 is a plan view showing a crack state after a fireproof test of an example of the present invention.

【符号の説明】[Explanation of symbols]

1;ガラス板 2;ガラス板 3;金属薄板の透かし部 4;金属薄板 5;フリット 11;ガラス板 12;ガラス板 13;金属薄板の透かし部 14;金属薄板 DESCRIPTION OF SYMBOLS 1; Glass plate 2; Glass plate 3; Watermark part of metal thin plate 4; Metal thin plate 5; Frit 11; Glass plate 12; Glass plate 13; Watermark part of metal thin plate 14; Metal thin plate

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 少なくとも2枚のガラス板の間に、透か
し部を有する金属薄板を介在させ、かつ前記金属薄板の
表面とそれに対向するガラス板表面をフリットにより接
着して一体化構造としたことを特徴とする防火・防犯用
窓ガラス。
1. A metal thin plate having a watermark is interposed between at least two glass plates, and the surface of the metal thin plate and the glass plate surface opposite thereto are bonded by a frit to form an integrated structure. Fire and crime prevention window glass.
【請求項2】 前記ガラス板がソーダライムシリケート
ガラス組成を有し、かつ前記金属薄板が0.1〜1.0
mmの厚みと、30〜350℃において70〜130×
10-7/℃の線膨張係数を有する請求項1記載の防火・
防犯用窓ガラス。
2. The glass plate has a soda lime silicate glass composition, and the thin metal plate is 0.1 to 1.0.
mm thickness, 70-130x at 30-350 ° C
The fire protection according to claim 1, which has a linear expansion coefficient of 10 -7 / ° C.
Security window glass.
【請求項3】 前記金属薄板は円形、楕円形または多角
形の形状の複数個の透かし部を有し、透かし部のそれぞ
れは円に面積換算したときに3〜20mmの直径を有
し、かつ前記金属薄板が20〜70%の開口率を有する
請求項1または2記載の防火・防犯用窓ガラス。
3. The thin metal plate has a plurality of watermarks each having a circular, elliptical or polygonal shape, each watermark having a diameter of 3 to 20 mm when converted into a circle, and The fire / security window glass according to claim 1 or 2, wherein the thin metal plate has an aperture ratio of 20 to 70%.
【請求項4】 前記フリットは400〜750℃の封着
温度を有する非晶質フリットまたは750℃以下の封着
温度を有する結晶質フリットである請求項1記載の防火
・防犯用窓ガラス。
4. The fire / security window glass according to claim 1, wherein the frit is an amorphous frit having a sealing temperature of 400 to 750 ° C. or a crystalline frit having a sealing temperature of 750 ° C. or lower.
【請求項5】 前記フリットが30〜350℃において
80〜120×10-7/℃の線膨張係数を有する請求項
2記載の防火・防犯用窓ガラス。
5. The fire / security window glass according to claim 2, wherein the frit has a linear expansion coefficient of 80 to 120 × 10 −7 / ° C. at 30 to 350 ° C.
【請求項6】 ソーダライムシリケートガラス組成を有
する少なくとも2枚のガラス板の間に、透かし部を有す
る金属薄板を介在させ、かつ前記金属薄板と前記ガラス
板を融着して一体化構造としてなり、前記金属薄板が
0.1〜1.0mmの厚みと、30〜350℃において
80〜120×10-7/℃の線膨張係数と、円形、楕円
形または多角形の形状の複数個の透かし部とを有してお
り、前記透かし部のそれぞれは円に面積換算したときに
3〜20mmの直径を有し、かつ前記金属薄板が20〜
70%の開口率を有する防火・防犯用窓ガラス。
6. A metal thin plate having a watermark portion is interposed between at least two glass plates having a soda lime silicate glass composition, and the metal thin plate and the glass plate are fused to form an integrated structure, The thin metal plate has a thickness of 0.1 to 1.0 mm, a linear expansion coefficient of 80 to 120 × 10 −7 / ° C. at 30 to 350 ° C., and a plurality of watermark portions having a circular, elliptical or polygonal shape. Each of the watermark portions has a diameter of 3 to 20 mm when converted into a circle, and the thin metal plate has a diameter of 20 to 20 mm.
Fire and crime prevention window glass with an aperture ratio of 70%.
JP6221804A 1994-09-16 1994-09-16 Pane for fire protection and crime prevention Pending JPH0891882A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6221804A JPH0891882A (en) 1994-09-16 1994-09-16 Pane for fire protection and crime prevention

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6221804A JPH0891882A (en) 1994-09-16 1994-09-16 Pane for fire protection and crime prevention

Publications (1)

Publication Number Publication Date
JPH0891882A true JPH0891882A (en) 1996-04-09

Family

ID=16772463

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6221804A Pending JPH0891882A (en) 1994-09-16 1994-09-16 Pane for fire protection and crime prevention

Country Status (1)

Country Link
JP (1) JPH0891882A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005082617A1 (en) 2004-03-02 2005-09-09 Mitsubishi Plastics, Inc. Multilayer resin film and laminated glass

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005082617A1 (en) 2004-03-02 2005-09-09 Mitsubishi Plastics, Inc. Multilayer resin film and laminated glass

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