JPH0854826A - Label - Google Patents
LabelInfo
- Publication number
- JPH0854826A JPH0854826A JP6188007A JP18800794A JPH0854826A JP H0854826 A JPH0854826 A JP H0854826A JP 6188007 A JP6188007 A JP 6188007A JP 18800794 A JP18800794 A JP 18800794A JP H0854826 A JPH0854826 A JP H0854826A
- Authority
- JP
- Japan
- Prior art keywords
- label
- container
- refractive index
- layer
- base material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010410 layer Substances 0.000 claims abstract description 32
- 239000000463 material Substances 0.000 claims abstract description 16
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 15
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 claims abstract description 13
- 239000002184 metal Substances 0.000 claims abstract description 13
- 238000000465 moulding Methods 0.000 claims abstract description 12
- 239000012790 adhesive layer Substances 0.000 claims abstract description 8
- 238000007639 printing Methods 0.000 claims abstract description 7
- 230000003746 surface roughness Effects 0.000 claims description 12
- 239000011253 protective coating Substances 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 6
- 238000007740 vapor deposition Methods 0.000 abstract description 16
- 229920001577 copolymer Polymers 0.000 abstract description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- 229920001038 ethylene copolymer Polymers 0.000 description 5
- 239000002932 luster Substances 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 230000008961 swelling Effects 0.000 description 4
- 230000037303 wrinkles Effects 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 229920005604 random copolymer Polymers 0.000 description 3
- 238000003851 corona treatment Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- QLZJUIZVJLSNDD-UHFFFAOYSA-N 2-(2-methylidenebutanoyloxy)ethyl 2-methylidenebutanoate Chemical compound CCC(=C)C(=O)OCCOC(=O)C(=C)CC QLZJUIZVJLSNDD-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、例えば、ポリエチレ
ン、ポリプロピレン等のプラスチック製中空容器などの
成形時に金型内で同時に該容器に貼着されるプロピレン
系重合体より構成されたラベルに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a label made of a propylene-based polymer which is simultaneously attached to a container such as a hollow container made of plastic such as polyethylene or polypropylene in a mold at the time of molding.
【０００２】[0002]
【従来の技術】近代、コスト的にプラスチック製中空容
器などを成形する際、金型内で同時に該容器に貼着され
るラベルが使用されることが多くなったが、シャンプー
やリンス、化粧品等の容器には、金属光沢を有する美麗
なラベルが好んで使用されるため、前記ラベルにおいて
も、アルミニウム等の金属を蒸着させるようになった。2. Description of the Related Art In modern times, when molding a plastic hollow container or the like, a label attached to the container at the same time is often used in a mold, but shampoo, conditioner, cosmetics, etc. Since a beautiful label having a metallic luster is preferably used for the container, a metal such as aluminum is vapor-deposited also in the label.
【０００３】[0003]
【発明が解決しようとする課題】ところが、前記従来の
金属蒸着を有するラベルでは、成形の際の貼着時に、該
蒸着による金属光沢が失われて白化する問題が生じ、充
分な金属光沢が得られないものであった。However, in the case of the conventional label having metal vapor deposition, there is a problem that the metal gloss is lost due to the vapor deposition and whitening occurs at the time of sticking at the time of molding, and a sufficient metal gloss is obtained. I couldn't do it.
【０００４】本発明は、上記のような問題点を解決する
ためになされたもので、容器などの成形時に金型内で同
時に該容器に貼着されるプロピレン系重合体より構成さ
れ、且つ金属蒸着が施されてなるラベルであって、成形
の際の貼着時に、該蒸着による金属光沢が失われて白化
することがないラベルを提供することを課題とする。The present invention has been made to solve the above problems, and is composed of a propylene-based polymer which is simultaneously adhered to a container in a mold during molding of the container and the like, and is made of metal. An object of the present invention is to provide a label which is vapor-deposited and which is not whitened due to loss of metallic luster due to the vapor deposition during sticking during molding.
【０００５】[0005]
【課題を解決するための手段】本発明は、上記課題を解
決するために、次の技術的手段を講じる。The present invention takes the following technical means in order to solve the above problems.
【０００６】即ち、容器B の成形時に金型内で同時に接
着剤層8 を介して該容器B に貼着されるラベルA であっ
て、プロピレン系重合体より構成されるラベル基材3
と、該ラベル基材3 の裏面側に設けられた印刷層4 とか
らなり、且つ該印刷層4 に金属蒸着が施されたラベルA
において、前記ラベル基材3 は、前記容器B 対して上下
方向(Y) の屈折率が１．５１３〜１．５２０であり、且
つ該容器B に対して左右方向(X) の屈折率が１．４９３
〜１．５００であることを特徴とするものである。That is, when the container B is molded, the label A is attached to the container B via the adhesive layer 8 at the same time in the mold, and the label base material 3 is composed of a propylene-based polymer.
And a print layer 4 provided on the back side of the label base material 3, and the print layer 4 is provided with a metal vapor deposited label A.
In the above, the label base material 3 has a refractive index of 1.513 to 1.520 in the up-down direction (Y) with respect to the container B, and has a refractive index of 1 in the left-right direction (X) with respect to the container B. .493
It is characterized by being ˜1.500.
【０００７】[0007]
【作用】本発明のラベル基材3 と印刷層4 とからなるラ
ベルA は、容器B の成形時に金型内で同時に貼着するも
のであるが、該ラベルA のラベル基材3 は、前記容器B
対して上下方向(Y) の屈折率が１．５１３〜１．５２０
であり、且つ該容器B に対して左右方向(X) の屈折率が
１．４９３〜１．５００であるように構成されているの
で、たとえ、前記印刷層4 に金属蒸着を施しても、蒸着
面が白濁して金属光沢が失われることも、また、該ラベ
ルA に皺，膨れ，曲がり, 弛み等を生じることもなくな
る。The label A consisting of the label base material 3 and the printing layer 4 of the present invention is attached at the same time in the mold during the molding of the container B. Container B
On the other hand, the refractive index in the vertical direction (Y) is 1.513 to 1.520.
And the refractive index in the left-right direction (X) with respect to the container B is 1.493 to 1.500, even if the printed layer 4 is metal-deposited, Neither the vapor-deposited surface becomes cloudy and the metallic luster is lost, nor does the label A wrinkle, swell, bend, loosen, or the like.
【０００８】また、前記ラベルA で、容器B に貼着され
る側2 の平均表面粗さ(Ra ) を０．２〜２．０μｍとし
たものにおいては、該ラベルA の裏面7 側がかなり粗面
化しているので、容器B と該ラベルA との隙間9 から空
気が抜けやすくなり、気泡を抱き込むことがなくなる。
従って、容器B への貼着性が非常に良くなり、ラベルA
の膨れを防止すると共に、該容器B の変形や割れ、ひび
などの発生を抑制することができる。Further, in the case of the label A having the average surface roughness (R a ) of the side 2 adhered to the container B of 0.2 to 2.0 μm, the back surface 7 side of the label A is considerably Since the surface is roughened, air easily escapes from the gap 9 between the container B and the label A, and air bubbles are not held.
Therefore, the adhesiveness to the container B is very good, and the label A
It is possible to prevent the container B from swelling and to prevent the container B from being deformed, cracked, or cracked.
【０００９】更に、前記ラベルA の表面2 側に保護用コ
ーティング層5 が設けられたものにおいては、該ラベル
A に擦り傷等の微細な傷が付くことを充分防止できる。Further, in the case where the protective coating layer 5 is provided on the surface 2 side of the label A, the label is
Sufficiently prevent scratches and other fine scratches on A.
【００１０】[0010]
【実施例】本発明のラベルA はプロピレン系重合体より
構成され、図１で示すように、プラスチック製等の中空
状の容器B の成形時に、金型内で同時に該容器B の表面
1に外嵌貼着され、該容器B の表面1 とラベルの表面2
が略面一に設けられる、所謂インモールドラベルであっ
て、特に該ラベルA に金属蒸着が施されたものである。EXAMPLE The label A of the present invention is composed of a propylene-based polymer, and as shown in FIG. 1, at the time of molding a hollow container B made of plastic or the like, the surface of the container B is simultaneously in the mold.
The outer surface of the container B is attached to the outer surface of the container B and the surface of the label 2
Is a so-called in-mold label that is provided substantially flush with the label A, and in particular, the label A is metal-deposited.
【００１１】前記ラベルA は、容器B に対して上下方向
（以下、単にＹという。）の屈折率が１．５１３〜１．
５２０、好ましくは１．５１４〜１．５１９であると共
に、該容器B に対して左右方向（以下、単にＸとい
う。）の屈折率が１．４９３〜１．５００、好ましくは
１．４９４〜１．４９９であるラベル基材3 と、該基材
3の裏面側に設けられた印刷層4 とから構成されている
と共に、該ラベル基材3 の表面側、即ちラベルA の表面
2 には傷防止のための保護用コーティング層5 が設けら
れ、また前記印刷層4 にはアルミニウム等の金属が蒸着
された蒸着層6 が設けられ、更に、該蒸着層6 の表面、
即ち、ラベルA の裏面7 側には容器B との貼着を施すた
めに接着剤層8 が設けられている。The label A has a refractive index in the vertical direction (hereinafter simply referred to as Y) of 1.513 to 1.
520, preferably 1.514 to 1.519, and having a refractive index of 1.493 to 1.500, preferably 1.494 to 1, in the left-right direction (hereinafter simply referred to as X) with respect to the container B. Label base material 3 which is .499 and the base material
3 and a print layer 4 provided on the back side of the label base 3, and the front side of the label base material 3, that is, the front side of the label A.
2 is provided with a protective coating layer 5 for preventing scratches, the printed layer 4 is provided with a vapor deposition layer 6 on which a metal such as aluminum is vapor deposited, and the surface of the vapor deposition layer 6 is further provided.
That is, the adhesive layer 8 is provided on the back surface 7 side of the label A for sticking to the container B.
【００１２】上記Ｙ及びＸの屈折率とは、空気中におけ
る光の速度と前記ラベルA のラベル基材3 中における光
の通過速度との比を求めたもので、入射角の正弦と屈折
角の正弦の比で表される。The Y and X refractive indexes are obtained by calculating the ratio of the speed of light in air to the speed of light passing through the label base material 3 of the label A. The sine of the incident angle and the refractive angle It is expressed as the ratio of the sine of.
【００１３】前記屈折率の値が上記範囲より低いと、該
ラベルA を容器B に貼着後、前記蒸着層6 が白濁して美
麗性が消失するし、また、逆に前記屈折率の値が上記範
囲より高くなると、容器B に貼着される際、該ラベルA
自体に、皺が入ったり、歪みが出たりして容器B に貼着
後の外観が劣化する。When the value of the refractive index is lower than the above range, after the label A is attached to the container B, the vapor-deposited layer 6 becomes cloudy and the beauty is lost, and conversely, the value of the refractive index is Is higher than the above range, when the label A is attached to the container B,
Wrinkles and distortions appear on the product itself, and the appearance after sticking to the container B deteriorates.
【００１４】前記ラベル基材3 として使用されるプロピ
レン系重合体としては、結晶性を有するポリプロピレ
ン、プロピレン・エチレン共重合体、プロピレン・ブテ
ン-1共重合体、或いはプロピレン・エチレン・ブテン-1
共重合体など、プロピレンを主成分とする結晶性重合体
が挙げられるが、これらの中で、本発明に係るラベルの
素材として最も好ましいものは、プロピレン・エチレン
・ランダム共重合体であり、特に、エチレン含有量２〜
５重量％のものである。Examples of the propylene-based polymer used as the label substrate 3 include crystalline polypropylene, propylene / ethylene copolymer, propylene / butene-1 copolymer, or propylene / ethylene / butene-1.
Examples of the copolymer include a crystalline polymer containing propylene as a main component. Among these, the most preferable material for the label according to the present invention is propylene / ethylene / random copolymer, and particularly , Ethylene content 2
5% by weight.
【００１５】本発明に係るラベルA は、図２に示すよう
に、容器B に貼着される側2 の平均表面粗さ（以下、単
にＲa という。）が０．２〜２．０μｍ、好ましくは
０．５〜１．５μｍの範囲内のものであり、且つその最
大表面粗さ（以下、単にＲmaxという。) が４〜２０μ
ｍ、好ましくは５〜１５μｍの範囲内のものである。Labels A according to the [0015] present invention, as shown in FIG. 2, the average surface roughness of the side 2 that is attached to the container B (hereinafter, simply referred to as R a.) Is 0.2 to 2.0 [mu] m, It is preferably in the range of 0.5 to 1.5 μm, and its maximum surface roughness (hereinafter, simply referred to as R max ) is 4 to 20 μm.
m, preferably in the range of 5 to 15 μm.
【００１６】尚、前記Ｒa が上記範囲より小さいと、容
器B とラベルA の間9 に気泡が残りやすくなり、外観不
良となることが多く、また、そのために、前記容器B と
ラベルA との密着性も悪くなる。また、逆に前記Ｒa が
上記範囲を越えると、容器B が衝撃のため割れる確率が
高くなり、この傾向は、容器B が薄肉化されることに伴
って顕著となる。If R a is smaller than the above range, air bubbles are likely to remain in the space 9 between the container B and the label A, often resulting in poor appearance. Also has poor adhesion. On the other hand, if the above R a exceeds the above range, the probability that the container B will crack due to impact increases, and this tendency becomes remarkable as the container B becomes thinner.
【００１７】更に、前記Ｒmax は、前記容器B の薄肉化
に左右され、該Ｒmax が上記範囲より 大きくなると、
薄肉化された容器においては、容器B とラベルA との間
隙9から該容器B が割れたり、ひびが入ったりする確率
が高くなる。Further, the R max depends on the thinning of the container B, and when the R max becomes larger than the above range,
In a thinned container, there is a high probability that the container B will crack or crack from the gap 9 between the container B and the label A.
【００１８】ただし、前記保護用コーティング層5 の表
面、即ち、ラベルA の表面2 のＲa’及びＲmax ’は小
さい方が良く、具体的には、前記貼着される側、即ち、
ラベルA の表面7 のＲa 及びＲmax の半分以下であるこ
とが望ましい。However, it is better that R a 'and R max ' of the surface of the protective coating layer 5, that is, the surface 2 of the label A, is smaller, and specifically, the adhered side, that is,
It is preferably less than half of R a and R max of the surface 7 of the label A.
【００１９】これは、前記ラベルA においては、表面2
側が目視される側であり、該ラベルA 及び容器B の外観
価値を上げるため、光沢や艶がある方が良いからであ
る。In the label A, this is the surface 2
This is because the side is the side to be viewed, and in order to enhance the appearance value of the label A and the container B, it is better to have gloss or gloss.
【００２０】次に、前記ラベルA の製造方法について、
具体的に、前記ラベル基材3 に結晶性プロピレン・エチ
レン・ランダム共重合体を用いた場合の実施例を挙げ、
詳述する。Next, with respect to the manufacturing method of the label A,
Specifically, an example of using a crystalline propylene / ethylene / random copolymer for the label substrate 3 will be given.
Detailed description.
【００２１】先ず、結晶性プロピレン・エチレン・ラン
ダム共重合体（エチレン含有量４．０重量％，メルトフ
ローインデックス３．０ｇ／１０ｍｉｎ）に、公知の酸
化防止剤、有機スリップ剤、無機アンチブロッキング剤
を微量づつ含有させたものよりなるペレットを用意し、
該ペレットを押出機に供給して、約２５０°Ｃの温度に
て溶融押出する。First, a crystalline propylene / ethylene / random copolymer (ethylene content 4.0% by weight, melt flow index 3.0 g / 10 min) is added to a known antioxidant, organic slip agent, inorganic antiblocking agent. Prepare a pellet consisting of a small amount of
The pellets are fed to an extruder and melt extruded at a temperature of about 250 ° C.
【００２２】次に、前記押出機から押出された溶融ペレ
ットＴ型ダイスから流出し、溶融シートを成形する。Next, the molten pellets are extruded from the extruder and flow out from the T-type die to form a molten sheet.
【００２３】次に、この溶融シートを、表面温度約２０
°Ｃの冷却ドラムに巻き付けて冷却固化し、厚さ約３０
０μｍの未延伸シートを成形する。Next, the surface temperature of the molten sheet is about 20.
Approximately 30 ℃
An unstretched sheet of 0 μm is formed.
【００２４】次に、前記未延伸シートを約８５〜９５°
Ｃに予熱した後、赤外線ヒーターにて加熱しつつ、長手
方向に３．０〜４．０倍の延伸倍率で延伸し、一旦５０
°Ｃの冷却ロールに巻き付けて冷却して、一軸配向シー
トとし、次に再度１００〜１１０°Ｃに加熱して、幅方
向に１．０〜１．２倍延伸する。Next, the unstretched sheet is heated to about 85 to 95 °.
After preheating to C, while heating with an infrared heater, it is stretched in the longitudinal direction at a stretch ratio of 3.0 to 4.0 times, and once stretched to 50
A uniaxially oriented sheet is wound around a chill roll of ° C and cooled to obtain a uniaxially oriented sheet, which is then heated again to 100 to 110 ° C and stretched 1.0 to 1.2 times in the width direction.
【００２５】次に、前記延伸シートを１１０〜１４０°
Ｃに加熱して、１５秒間緊張熱固定し、常温となるまで
冷却した後に、該シートの片面にコロナ放電処理を施
し、該表面の濡れ張力を約５０ダイン／ｃｍまで上昇さ
せ、巻き取り、フィルムを成形する。Next, the stretched sheet is heated to 110 to 140 °.
After heating to C, tension heat fixing for 15 seconds, and cooling to room temperature, one side of the sheet is subjected to corona discharge treatment, the wetting tension of the surface is increased to about 50 dynes / cm, and winding is performed. Form the film.
【００２６】次に、前記フィルムを所定幅にスリットし
て、製品ロールの形状とした後、該フィルムをグラビア
印刷機にかけて、前記コロナ放電処理を施した側の表面
に、例えば２〜６色からなる印刷を施し、文字、絵柄、
各種デザイン等を印刷して、印刷層4 を設け、更に、そ
の上面に、アルミニウムを約０．０５μm の厚さに真空
蒸着し、蒸着層6 を設ける。Next, after slitting the film to a predetermined width to form a product roll, the film is subjected to a gravure printing machine and the surface on the side subjected to the corona discharge treatment is, for example, from 2 to 6 colors. Is printed, characters, patterns,
A print layer 4 is provided by printing various designs, and aluminum is vacuum-deposited to a thickness of about 0.05 μm on the upper surface of the print layer 4 to provide a vapor deposition layer 6.
【００２７】この際、前記印刷層4 における絵柄など
は、クリアな部分10（インキが付いていない部分）が存
在するため、その部分10においてはラベルA の表面2 側
から蒸着層6 を目視することができる。At this time, since the pattern on the printed layer 4 has a clear portion 10 (a portion without ink), the vapor deposition layer 6 is visually observed from the surface 2 side of the label A in the portion 10. be able to.
【００２８】尚、前記フィルム表面と蒸着層6 間の接着
性を向上させるために、該蒸着の前に、印刷などによっ
て透明なアンダーコート層を設けても良い。In order to improve the adhesion between the film surface and the vapor deposition layer 6, a transparent undercoat layer may be provided by printing or the like before the vapor deposition.
【００２９】次に、前記蒸着層6 の上面にエチレン・エ
チルアクリレートを主剤とする接着剤を塗布し、接着剤
層8 を設ける。Next, an adhesive containing ethylene ethyl acrylate as a main component is applied to the upper surface of the vapor deposition layer 6 to form an adhesive layer 8.
【００３０】前記接着剤層8 の中には、粒径１〜１０μ
m のシリカ粒子を各種比率で添加して、容器B に貼着さ
れる側、即ちラベルA の裏面7 の平均表面粗さ(Ra ) を
０．２０〜２．００μｍに調整する。The adhesive layer 8 has a particle size of 1 to 10 μm.
The silica particles of m 3 are added at various ratios to adjust the average surface roughness (R a ) of the side adhered to the container B, that is, the back surface 7 of the label A, to 0.20 to 2.00 μm.
【００３１】次に、前記フィルムの表面、つまりラベル
基材3 の上面に透明なインキ等を塗布し、保護用コーテ
ィング層5 を設ける。また、該保護用コーティング層5
中に帯電防止剤を含有させることによって、ラベルの
埃、汚れ等を防止することも可能となる。Next, a transparent ink or the like is applied to the surface of the film, that is, the upper surface of the label substrate 3 to form a protective coating layer 5. In addition, the protective coating layer 5
By incorporating an antistatic agent therein, it is possible to prevent dust, dirt, etc. on the label.
【００３２】前記のように成形された印刷処理済みのフ
ィルムを、ラベル用打抜機にかけて、該フィルムの一軸
配向の方向を容器B に貼着する際の上下方向の長さに適
合させ、該フィルムのＹの長さを略１０５ｍｍ、Ｘの長
さを略６０ｍｍの寸法にて適宜打抜き、長方形状のラベ
ルA を得る。The print-processed film formed as described above is subjected to a label punching machine so that the direction of the uniaxial orientation of the film is adjusted to the vertical length when the film is attached to the container B, and the film is processed. A rectangular label A is obtained by appropriately punching the Y length of about 105 mm and the X length of about 60 mm.
【００３３】以上のように製造されたラベルA の前記ラ
ベル基材3 は、前記Ｙ方向の屈折率が１．５１３〜１．
５２０であり、且つＸ方向の屈折率が１．４９３〜１．
５００を有するものとなる。The label base material 3 of the label A manufactured as described above has a refractive index in the Y direction of 1.513 to 1.
520, and the refractive index in the X direction is 1.493 to 1.
Will have 500.
【００３４】前記ラベルA の複数枚をマカジンに収納
し、ここから１枚づつ吸着カップで取り出し、中空容器
成型金型に移送させる。尚、前記ラベルA の裏面7 の平
均表面粗さ(Ra ) を０．２０〜２．００μｍに調整して
いるため、取り出し時に、２枚取りがなされるなどの支
障は生じない。A plurality of the above-mentioned labels A are housed in a makagin, taken out one by one with a suction cup, and transferred to a hollow container molding die. Incidentally, since the average surface roughness (R a ) of the back surface 7 of the label A is adjusted to 0.20 to 2.00 μm, there is no problem such as taking two sheets at the time of taking out.
【００３５】次に、プロピレン・エチレン共重合体パリ
ソン（樹脂温度約２１０°Ｃ）をブロー成形して、金型
内で前記ラベルA の接着剤層8 をボトル容器B の表面1
に接着させる。Next, the propylene / ethylene copolymer parison (resin temperature of about 210 ° C.) is blow-molded, and the adhesive layer 8 of the label A is placed on the surface 1 of the bottle container B in the mold.
To adhere to.
【００３６】上述のようにして製造されたラベル及び、
従来の屈折率の異なるラベルを用いて、図３に示すよう
に、前記中空容器B に貼着したまま、長時間に渡って、
その外観を評価してみた。その結果を下記表１に示す。A label manufactured as described above, and
As shown in FIG. 3, using conventional labels having different refractive indexes, while sticking to the hollow container B, for a long time,
I evaluated its appearance. The results are shown in Table 1 below.
【００３７】[0037]
【表１】 [Table 1]
【００３８】尚、目視評価は、○を良好, △をやや不
良, ×を不良として３段評価したものである。The visual evaluation is a three-level evaluation in which ◯ is good, Δ is slightly bad, and X is bad.
【００３９】前記実験の結果、本発明に係る実施例１〜
実施例３におけるラベルでは、皺、ひきつれ、膨れ、密
着性不良、気泡の混入、容器B の変形などはなく、良好
な状態を保持することができることがわかった。As a result of the above experiment, Examples 1 to 1 according to the present invention
It was found that the label in Example 3 can maintain a good condition without wrinkles, tightness, swelling, poor adhesion, inclusion of bubbles, and deformation of the container B.
【００４０】尚、上記製造の際に必要とされる、本発明
におけるラベルの屈折率、表面粗さ等の特性値の測定法
については下記測定法を用いてなされるものである。The measuring method of the characteristic values such as the refractive index and the surface roughness of the label in the present invention, which is required in the above-mentioned manufacturing, is carried out by the following measuring method.
【００４１】＜屈折率＞アッベ屈折計を用い、ＪＩＳ
Ｋ ７１０５に準じて測定する。<Refractive index> Using an Abbe refractometer, JIS
Measure according to K 7105.
【００４２】＜表面粗さ＞ＪＩＳ Ｂ ０６０１に基づ
く平均表面粗さ（Ｒa ) と最大表面粗さ（Ｒmax）の測
定法にて測定する。<Surface Roughness> The average surface roughness (R a ) and the maximum surface roughness (R max ) are measured according to JIS B 0601.
【００４３】この際、カットオフは０．８０ｍｍ、測定
長さは４．５ｍｍとし、ラベルの表面をランダムに５ヵ
所測定し、その５ヵ所の各々のＲa ，Ｒmax を単純に算
術平均して、その表面の表面粗さとする。At this time, the cutoff was 0.80 mm, the measurement length was 4.5 mm, the surface of the label was randomly measured at 5 points, and R a and R max at each of the 5 points were simply arithmetically averaged. The surface roughness of the surface.
【００４４】＜メルト・フロー・インデックス＞ＡＳＴ
Ｍ Ｄ １２３８の条件Ｌにて測定する。<Melt Flow Index> AST
It is measured under the condition L of MD 1238.
【００４５】＜エチレン含有量＞赤外線スペクトルで、
７２０ｃｍ-1と、９００ｃｍ-1の吸光度比（Ａ７２０／
Ａ９００）から換算する。<Ethylene content> In the infrared spectrum,
Absorbance ratio between 720 cm -1 and 900 cm -1 (A720 /
A900).
【００４６】[0046]
【発明の効果】叙上のように、本発明に係るラベルのラ
ベル基材は、容器対して上下方向(Y)の屈折率が１．５
１３〜１．５２０であり、且つ該容器に対して左右方向
(X) の屈折率が１．４９３〜１．５００であるように構
成されているので、たとえ、前記印刷層に金属蒸着を施
しても、蒸着面が白濁して金属光沢が失われることも、
また、該ラベルに皺，膨れ，曲がり, 弛み等を生じるこ
ともなくなる。As described above, the label base material of the label according to the present invention has a refractive index of 1.5 relative to the container in the vertical direction (Y).
13 to 1.520 and in the left-right direction with respect to the container
Since the refractive index of (X) is configured to be 1.493 to 1.500, even if the printed layer is subjected to metal vapor deposition, the vapor deposition surface may become cloudy and lose the metallic luster. ,
In addition, wrinkles, swelling, bending, slack and the like do not occur on the label.
【００４７】また、前記ラベルで、容器に貼着される側
の平均表面粗さ(Ra ) を０． ２〜２．０μｍとしたも
のにおいては、該ラベルの裏面側がかなり粗面化してい
るので、容器と該ラベルとの隙間から空気が抜けやすく
なり、気泡を抱き込むことがなくなる。従って、容器へ
の貼着性が非常に良くなり、ラベルの膨れを防止すると
共に、該容器の変形や割れ、ひびなどの発生を抑制する
ことができる。Further, in the above label, the average surface roughness (R a ) on the side attached to the container is 0. In the case of 2 to 2.0 μm, since the back surface side of the label is considerably roughened, it is easy for air to escape from the gap between the container and the label, and it is possible to prevent inclusion of air bubbles. Therefore, the sticking property to the container becomes very good, the swelling of the label can be prevented, and the deformation, cracks, cracks and the like of the container can be suppressed.
【００４８】更に、前記ラベルの表面側に保護用コーテ
ィング層が設けられたものにおいては、該ラベルに擦り
傷等の微細な傷が付くことを充分防止できる。Further, in the case where the protective coating layer is provided on the surface side of the label, it is possible to sufficiently prevent the label from being scratched or fine scratched.
【図１】本発明のラベルを貼着した容器を示す断面図。FIG. 1 is a cross-sectional view showing a container to which a label of the present invention is attached.
【図２】同、要部拡大断面図。FIG. 2 is an enlarged sectional view of the same.
【図３】同、ラベルを貼着した容器を示す斜視図。FIG. 3 is a perspective view showing a container to which the label is attached.
１ 容器の表面 ２ ラベルの表面 ３ ラベル基材 ４ 印刷層 ５ 保護用コーティング層 ６ 蒸着層 ７ ラベルの裏面 ８ 接着剤層 ９ 容器とラベルの隙間 Ａ ラベル Ｂ 容器 Ｘ 容器対して左右方向 Ｙ 容器対して上下方向 1 surface of the container 2 surface of the label 3 label base material 4 printing layer 5 protective coating layer 6 vapor deposition layer 7 back surface of the label 8 adhesive layer 9 gap between the container and the label A label B container X left and right direction to the container Y container to the container Up and down
フロントページの続き (72)発明者 原田 寛 大阪市鶴見区今津北５−３−18 冨士シ− ル工業株式会社内Front page continued (72) Inventor Hiroshi Harada 5-3-18 Imazukita, Tsurumi-ku, Osaka City Fuji Seal Industry Co., Ltd.
Claims (3)
剤層(8) を介して該容器(B) に貼着されるラベル(A) で
あって、プロピレン系重合体より構成されるラベル基材
(3) と、該ラベル基材(3) の裏面側に設けられた印刷層
(4) とからなり、且つ該印刷層(4) に金属蒸着が施され
たラベル(A) において、前記ラベル基材(3) は、前記容
器(B) 対して上下方向(Y) の屈折率が１．５１３〜１．
５２０であり、且つ該容器(B) に対して左右方向(X) の
屈折率が１．４９３〜１．５００であることを特徴とす
るラベル。1. A label (A) which is adhered to the container (B) at the same time in the mold via the adhesive layer (8) at the time of molding the container (B), and is composed of a propylene-based polymer. Label base material
(3) and a printing layer provided on the back side of the label substrate (3)
(4) and in the label (A) in which the printed layer (4) is vapor-deposited with metal, the label substrate (3) is bent in the vertical direction (Y) with respect to the container (B). The rate is 1.513-1.
A label having a refractive index of 520 and a refractive index of 1.493 to 1.500 in the left-right direction (X) with respect to the container (B).
着される側の平均表面粗さ(Ra ) が０．２０〜２．００
μｍである請求項１記載のラベル。2. In the label (A), the average surface roughness (R a ) on the side attached to the container (B) is 0.20 to 2.00.
The label according to claim 1, wherein the label is μm.
用コーティング層(5)が設けられてなる請求項１又は２
記載のラベル。3. The protective coating layer (5) is provided on the surface side of the label substrate (3).
Label as described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6188007A JP2759426B2 (en) | 1994-08-10 | 1994-08-10 | label |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6188007A JP2759426B2 (en) | 1994-08-10 | 1994-08-10 | label |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0854826A true JPH0854826A (en) | 1996-02-27 |
| JP2759426B2 JP2759426B2 (en) | 1998-05-28 |
Family
ID=16216018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6188007A Expired - Fee Related JP2759426B2 (en) | 1994-08-10 | 1994-08-10 | label |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2759426B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005531686A (en) * | 2002-06-26 | 2005-10-20 | エーブリー デニソン コーポレイション | Oriented film containing a polypropylene / olefin elastomer mixture |
-
1994
- 1994-08-10 JP JP6188007A patent/JP2759426B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005531686A (en) * | 2002-06-26 | 2005-10-20 | エーブリー デニソン コーポレイション | Oriented film containing a polypropylene / olefin elastomer mixture |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2759426B2 (en) | 1998-05-28 |
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