JPH083774A - Pickling method and pickling device for steel products - Google Patents
Pickling method and pickling device for steel productsInfo
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- JPH083774A JPH083774A JP13605794A JP13605794A JPH083774A JP H083774 A JPH083774 A JP H083774A JP 13605794 A JP13605794 A JP 13605794A JP 13605794 A JP13605794 A JP 13605794A JP H083774 A JPH083774 A JP H083774A
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- Prior art keywords
- pickling
- bath
- acid
- chamber
- treatment
- Prior art date
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- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、鉄基合金、Ｎｉ基合金
などの鋼材の酸洗処理における酸洗液の酸洗能力を維
持、安定化させる方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for maintaining and stabilizing the pickling ability of a pickling solution in a pickling treatment of steel materials such as iron-based alloys and Ni-based alloys.
【０００２】[0002]
【従来の技術】鋼材の熱間加工、熱処理などの高温加熱
によって鋼材の表面に形成された酸化スケールを除去す
るいわゆる脱スケールのために酸洗が行われる。酸洗は
塩酸、硫酸、硝酸、フッ酸等の水溶液に鋼材を浸漬して
鋼材表面の酸化スケール、酸化スケール直下の地金を溶
解して酸化スケールを溶去または剥離させる化学処理で
ある。鋼材の酸洗により、酸洗処理浴中の水素イオンは
酸化スケールおよび地金中の金属原子に電荷を与えるこ
とにより、水素イオン自身は電荷を失ってガス化し系外
に去り酸濃度を減じる。他方金属原子はイオン化して酸
洗処理浴中に溶出し、酸洗処理浴中の金属イオン濃度を
上昇させる。これらの化学反応の速度は酸および金属イ
オン温度に依存性をもつ。2. Description of the Related Art Pickling is performed for so-called descaling, which removes oxide scale formed on the surface of steel products by high-temperature heating such as hot working and heat treatment of steel products. The pickling is a chemical treatment in which a steel material is immersed in an aqueous solution of hydrochloric acid, sulfuric acid, nitric acid, hydrofluoric acid or the like to dissolve the oxide scale on the surface of the steel material and the metal directly under the oxide scale to dissolve or remove the oxide scale. When the steel material is pickled, hydrogen ions in the pickling treatment bath give electric charges to oxide scales and metal atoms in the metal, whereby the hydrogen ions lose their electric charge and are gasified to leave the system to reduce the acid concentration. On the other hand, the metal atoms are ionized and eluted in the pickling bath, increasing the metal ion concentration in the pickling bath. The rate of these chemical reactions depends on the acid and metal ion temperatures.
【０００３】酸洗脱スケールにおいては、地金の溶解に
よる損失をできるだけ少なくして、完全な脱スケールを
安定して行うために酸洗処理浴の温度管理、酸濃度管理
が行われる。また、おもに地金を溶解することにより酸
化スケールを剥離して脱スケールをする硫酸酸洗などに
おいては、特に、酸洗処理浴中の金属イオン濃度が増加
すると急激に脱スケール性が低下するので、酸水溶液中
の金属イオン濃度の管理も行われる。In pickling descaling, temperature control and acid concentration control of the pickling bath are carried out in order to minimize loss due to dissolution of the metal and to perform complete descaling stably. In addition, in sulfuric acid pickling, which mainly removes the oxide scale by dissolving the metal and descales, especially when the metal ion concentration in the pickling treatment bath increases, the descaling property rapidly decreases. The control of the metal ion concentration in the acid aqueous solution is also performed.
【０００４】しかし、酸濃度の測定、金属イオンの定量
分析などは繁雑な操作と多くの労力を要するため、従来
１日当り３回程度の測定分析を行って酸濃度を調整する
に過ぎず、また、酸洗処理浴中の金属イオン除去は行わ
れておらず、ある濃度例えば１００ｇ／リットルになると廃
液し新酸液で新たに浴調整をして酸洗処理を展開する方
法であるため、安定した脱スケール性を得ることは困難
であった。However, since the measurement of the acid concentration and the quantitative analysis of metal ions require complicated operations and much labor, conventionally, the measurement concentration is adjusted only by performing the measurement analysis about three times a day, and However, metal ions are not removed from the pickling bath, and when the concentration reaches a certain level, for example 100 g / l, it is a waste method and a new acid solution is newly added to adjust the pickling process. It was difficult to obtain the descaling property.
【０００５】[0005]
【発明が解決しようとする課題】以上の現状に鑑み、本
発明の目的とするところは、酸洗処理浴中の酸濃度およ
び金属イオン濃度を連続的かつ自動的に調整することに
よって、安定した脱スケール性を経済的に得ることがで
きる鋼材の酸洗方法および酸洗装置を提供することにあ
る。In view of the above circumstances, the object of the present invention is to stabilize the acid concentration and the metal ion concentration in the pickling treatment bath continuously and automatically. It is an object of the present invention to provide a pickling method and a pickling apparatus for a steel material which can economically obtain descaling property.
【０００６】[0006]
【課題を解決するための手段】前記目的を達成するため
の本発明による鋼材の酸洗方法は、（１）酸洗処理浴槽
から連続的に採取される酸洗処理浴サンプルの酸濃度お
よび金属イオン濃度を連続的に測定する工程と、（２）
溶液処理室と、この溶液処理室を挟んで両側に配置さ
れ、カチオン性イオン交換膜によって溶液処理室と区分
された陽極室および陰極室とよりなり、陽極室および陰
極室にはそれぞれ陽極および陰極に印荷される電極を備
える酸回収装置の溶液処理室に、酸洗処理浴槽から連続
的に一定量の酸洗処理浴を導入し、酸洗処理浴を電解分
離し、酸を回収して酸洗処理浴槽へ戻す工程と、（３）
前記金属イオン濃度測定値によって、前記酸回収装置の
陽極および陰極間に流れる電解電流値を自動制御する工
程と、（４）自動分析計の酸濃度測定値によって新酸液
を酸洗処理浴槽へ供給する量を自動制御する工程とを含
むことを特徴とする。[Means for Solving the Problems] A method for pickling steel material according to the present invention for achieving the above object is as follows: (1) Acid concentration and metal content of pickling bath samples continuously taken from a pickling bath. A step of continuously measuring the ion concentration, and (2)
It consists of a solution processing chamber and an anode chamber and a cathode chamber, which are arranged on both sides of the solution processing chamber and are separated from the solution processing chamber by a cationic ion exchange membrane.The anode chamber and the cathode chamber are respectively an anode and a cathode. Into the solution processing chamber of the acid recovery device equipped with the electrode to be loaded into, a fixed amount of pickling treatment bath is continuously introduced from the pickling treatment bath, the pickling treatment bath is electrolytically separated, and the acid is recovered. Returning to the pickling bath, (3)
A step of automatically controlling the electrolytic current value flowing between the anode and the cathode of the acid recovery device by the measured value of the metal ion concentration, and (4) the fresh acid solution to the pickling treatment bath by the measured acid concentration value of the automatic analyzer. And a step of automatically controlling the amount to be supplied.
【０００７】上記に加えて、さらに、本発明による鋼材
の酸洗方法は、好ましくは、（５）酸洗処理浴槽の浴液
面位置を液面計によって連続的に測定する工程と、
（６）前記液面計の測定値によって酸洗処理浴槽の浴液
面位置を自動制御する工程とを含むことを特徴とする。
また、本発明の鋼材の酸洗装置は、（１）酸洗処理浴槽
と、（２）酸洗処理浴槽から連続的に採取される酸洗処
理浴サンプルの酸濃度および金属イオン濃度を連続的に
測定する自動分析計と、（３）前記自動分析計の金属イ
オン濃度測定値によって電解電流値が自動制御される電
解電流制御装置と、（４）酸洗処理浴槽との間に連続的
に一定量の酸洗処理浴を循環する溶液処理室と、この溶
液処理室を挟んで両側に配置され、カチオン性イオン交
換膜によって溶液処理室と区分された陽極室および陰極
室とよりなり、陽極室および陰極室にはそれぞれ陽極お
よび陰極に印荷され、前記電解電流制御装置によって電
解電流が自動制御される電極を備える酸回収装置と、
（５）自動分析計の酸濃度測定値によって、酸洗処理浴
槽へ供給される新酸液の量が自動制御される新酸液供給
装置とを含むことを特徴とする。In addition to the above, the method of pickling steel according to the present invention preferably further comprises (5) a step of continuously measuring the bath liquid level position of the pickling bath with a level gauge.
(6) A step of automatically controlling the bath liquid surface position of the pickling bath according to the measurement value of the liquid level gauge.
Further, the steel pickling apparatus of the present invention is characterized in that (1) pickling bath and (2) pickling bath sample continuously taken from the pickling bath are used to continuously measure the acid concentration and metal ion concentration. Continuously between the automatic analyzer for measurement, (3) the electrolytic current control device in which the electrolytic current value is automatically controlled by the measurement value of the metal ion concentration of the automatic analyzer, and (4) the pickling bath. It consists of a solution treatment chamber that circulates a certain amount of pickling treatment bath, and an anode chamber and a cathode chamber that are arranged on both sides of the solution treatment chamber and are separated from the solution treatment chamber by a cationic ion exchange membrane. In the chamber and the cathode chamber, respectively, an anode and a cathode are loaded, respectively, and an acid recovery device having an electrode whose electrolytic current is automatically controlled by the electrolytic current control device,
(5) A new acid liquid supply device in which the amount of the new acid liquid supplied to the pickling bath is automatically controlled by the acid concentration measurement value of the automatic analyzer.
【０００８】上記に加えて、さらに、本発明の鋼材の酸
洗装置は、好ましくは、（６）酸洗処理浴槽の浴液面位
置を測定する液面計と、（７）前記液面計の測定値によ
って酸洗処理浴槽の浴液面位置が自動制御される新酸液
供給装置とを含むことを特徴とする。In addition to the above, the pickling apparatus for steel according to the present invention preferably further comprises (6) a liquid level gauge for measuring the position of the bath liquid level in the pickling bath, and (7) the liquid level gauge. And a new acid liquid supply device in which the bath liquid surface position of the pickling bath is automatically controlled according to the measured value.
【０００９】[0009]
【実施例】以下、本発明の実施例について説明する。図
１は本発明の鋼材の酸洗処理方法を示す概要図である。
鋼材は酸洗処理浴槽１に張られた酸洗処理浴２に浸漬さ
れて酸洗処理される。酸洗処理浴２としては１０％硫酸
水溶液を主とし、少量の酸洗抑制剤を加えたものを用い
た。酸洗処理浴２は導液管１１とポンプ１２によって濾
過装置１３を経て酸回収装置３の溶液処理室３１に導か
れる。濾過装置１３は酸洗処理浴２中に含まれる未溶解
スケール等の固体夾雑物を除去するためのものである。Embodiments of the present invention will be described below. FIG. 1 is a schematic diagram showing a method of pickling a steel material according to the present invention.
The steel material is immersed in the pickling treatment bath 2 stretched in the pickling treatment bath 1 and subjected to the pickling treatment. As the pickling bath 2, a 10% sulfuric acid aqueous solution was mainly used, to which a small amount of a pickling inhibitor was added. The pickling treatment bath 2 is introduced into the solution treatment chamber 31 of the acid recovery device 3 through the filtration device 13 by the liquid guiding pipe 11 and the pump 12. The filtration device 13 is for removing solid contaminants such as undissolved scale contained in the pickling treatment bath 2.
【００１０】酸回収装置３は溶液処理室３１と、この溶
液処理室３１を挟んで両側に配置され、カチオン性イオ
ン交換膜３４または３５によってそれぞれ溶液処理室３
１と区分された陽極室３２および陰極室３３とよりな
る。陽極室３２および陰極室３３にはそれぞれ陽極電極
３６および陰極電極３７を備える。電解電源３９から陽
極電極３６および陰極電極３７に供給される電流は電解
電流制御装置３８によって制御される。電解電流制御装
置３８は、自動分析計４の金属イオン濃度測定値をもと
に、中央演算処理装置５から与えられる命令によって作
動する。酸回収装置３によって電解処理された再生液は
戻り管１４により酸洗処理浴槽１に戻される。The acid recovery device 3 is disposed on both sides of the solution processing chamber 31 with the solution processing chamber 31 sandwiched therebetween, and the solution processing chamber 3 is provided by the cationic ion exchange membrane 34 or 35, respectively.
The anode chamber 32 and the cathode chamber 33 are separated from each other. The anode chamber 32 and the cathode chamber 33 are provided with an anode electrode 36 and a cathode electrode 37, respectively. The current supplied from the electrolysis power source 39 to the anode electrode 36 and the cathode electrode 37 is controlled by the electrolysis current control device 38. The electrolytic current control device 38 operates based on the metal ion concentration measurement value of the automatic analyzer 4 according to a command given from the central processing unit 5. The regenerant liquid subjected to the electrolytic treatment by the acid recovery device 3 is returned to the pickling treatment bath 1 by the return pipe 14.
【００１１】他方、試料抽出管４１により、酸洗処理浴
槽１から連続的に酸洗処理浴２の分析試料が抽出され、
自動分析計４によって酸濃度および金属イオン濃度が連
続的に測定される。自動分析計４による測定情報は中央
演算処理装置５に送られる。液面計７は酸洗処理浴槽１
内の酸洗処理浴２の液面の位置を計測するためのもの
で、その測定情報は中央演算処理装置５に伝えられる。On the other hand, the sample extraction pipe 41 continuously extracts the analysis sample of the pickling bath 2 from the pickling bath 1.
The acid concentration and the metal ion concentration are continuously measured by the automatic analyzer 4. The measurement information from the automatic analyzer 4 is sent to the central processing unit 5. Liquid level gauge 7 is pickling bath 1
This is for measuring the position of the liquid surface of the pickling treatment bath 2 inside, and the measurement information is transmitted to the central processing unit 5.
【００１２】新酸液槽６は１０％硫酸水溶液を主とし、
少量の酸洗抑制剤を加えた酸洗処理浴の新酸液６１を蓄
えた容器である。新酸液６１は、制御弁６３を備えた新
酸液補給管６２および制御弁６５を備えた新酸液補給管
６４によって酸洗処理浴槽１に導かれる。制御弁６３は
自動分析計４による酸濃度の測定情報を受けた中央演算
処理装置５の命令によって制御される。また、制御弁６
５は液面計の測定情報を受けた中央演算処理装置５の命
令によって制御される。中央演算処理装置５は、自動分
析計４から酸洗処理浴２の酸濃度および金属イオン濃度
の測定値を、また、液面計７から酸洗処理浴槽１内の酸
洗処理浴２の液面位置の測定値を受けて、電解電流制御
装置３８、制御弁６３および制御弁６５の作動を制御す
る。そして、本発明の方法においては、自動分析計４お
よび液面計７から中央演算処理装置５へ連続的に測定値
が送られるように構成されている。The new acid solution tank 6 mainly contains a 10% sulfuric acid aqueous solution,
It is a container that stores a new acid solution 61 of a pickling treatment bath to which a small amount of a pickling inhibitor is added. The fresh acid solution 61 is guided to the pickling bath 1 by a fresh acid solution replenishing pipe 62 having a control valve 63 and a new acid solution replenishing pipe 64 having a control valve 65. The control valve 63 is controlled by a command from the central processing unit 5 which receives the measurement information of the acid concentration by the automatic analyzer 4. In addition, the control valve 6
5 is controlled by an instruction of the central processing unit 5 which receives the measurement information of the liquid level gauge. The central processing unit 5 uses the automatic analyzer 4 to measure the acid concentration and the metal ion concentration of the pickling treatment bath 2, and the liquid level gauge 7 to measure the liquid of the pickling treatment bath 2 in the pickling treatment bath 1. The operation of the electrolytic current control device 38, the control valve 63, and the control valve 65 is controlled by receiving the measurement value of the surface position. In the method of the present invention, the measurement values are continuously sent from the automatic analyzer 4 and the liquid level gauge 7 to the central processing unit 5.
【００１３】すなわち、酸洗処理が進んで酸洗処理浴２
の金属イオン濃度が所定値より高まれば、中央演算処理
装置５は電解電流制御装置３８に電解電流を増すように
命令し、これによって、陰極室３３内の金属イオンは、 Ｍ（ＯＨ）X →（Ｍ，Ｆｅ）Ｏ・Ｆｅ2 Ｏ3 の反応が進行し、結果的に還元が促進されて陰極室３３
内の金属イオン濃度を減じるので、溶液処理室３１内の
金属イオンはカチオン性イオン交換膜３５を浸透して陰
極室３３へ移り、溶液処理室３１内の金属イオン濃度を
減じる結果となる。本実施例の場合には酸洗処理浴２の
金属イオン濃度の所定値は５０±２ｇ／リットルとして実施
した。That is, the pickling treatment advances and the pickling bath 2
If the metal ion concentration of the above is higher than a predetermined value, the central processing unit 5 commands the electrolysis current control device 38 to increase the electrolysis current, whereby the metal ions in the cathode chamber 33 become M (OH) x → The reaction of (M, Fe) O.Fe 2 O 3 proceeds, and as a result, the reduction is promoted and the cathode chamber 33
Since the metal ion concentration in the solution processing chamber 31 is reduced, the metal ions in the solution processing chamber 31 permeate the cationic ion exchange membrane 35 and move to the cathode chamber 33, resulting in a reduction in the metal ion concentration in the solution processing chamber 31. In the case of this example, the predetermined value of the metal ion concentration of the pickling treatment bath 2 was 50 ± 2 g / liter.
【００１４】酸洗処理浴２中の酸分は蒸発するとか鋼材
に付着して酸洗処理浴槽１外へ運び去られるなどして酸
濃度を減じ、あるいは酸洗処理浴槽１内の液量が減じ
る。自動分析計４によって測定された酸濃度測定値が所
定の酸濃度の値を下回れば、中央演算処理装置５は制御
弁６３を開いて新酸液６１を補給させる。また、液面計
７による測定値が液面位置の低下を示したときは、中央
演算処理装置５は制御弁６５を開いて新酸液６１を補給
させる。The acid content in the pickling bath 2 is evaporated or adhered to the steel material and carried away from the pickling bath 1 to reduce the acid concentration, or the amount of liquid in the pickling bath 1 is reduced. Reduce. When the acid concentration measurement value measured by the automatic analyzer 4 is lower than the predetermined acid concentration value, the central processing unit 5 opens the control valve 63 to replenish the fresh acid solution 61. When the measured value by the liquid level gauge 7 indicates a decrease in the liquid surface position, the central processing unit 5 opens the control valve 65 to replenish the fresh acid solution 61.
【００１５】[0015]
【発明の効果】以上説明したように、本発明の鋼材の酸
洗方法および酸洗装置によれば、酸洗処理浴の酸濃度お
よび金属イオン濃度を連続的かつ自動的に測定し、調整
することができるので、安定した脱スケールが可能であ
り、過剰な酸洗処理による地金の損耗を防ぐことがで
き、繁雑な分析操作をなくするなど、品質的にも経済的
にも優れた鋼材の酸洗方法および酸洗装置を提供するこ
とができる。As described above, according to the method and apparatus for pickling steel material of the present invention, the acid concentration and the metal ion concentration of the pickling bath are continuously and automatically measured and adjusted. As a result, stable descaling is possible, the wear of the metal due to excessive pickling treatment can be prevented, and complicated analysis operations are eliminated. It is possible to provide the pickling method and the pickling apparatus.
【図１】本発明の鋼材の酸洗処理方法を示す概要図であ
る。FIG. 1 is a schematic diagram showing a method of pickling a steel material according to the present invention.
１ 酸洗処理浴槽 ３ 酸回収装置 ４ 自動分析計 ５ 中央演算処理装置 ６ 新酸液槽 ７ 液面計 ３１ 溶液処理室 ３４ カチオン性イオン交換膜 ３５ カチオン性イオン交換膜 ３６ 陽極電極 ３７ 陰極電極 ３８ 電解電流制御装置 ６３ 制御弁 ６５ 制御弁 1 Pickling treatment bath 3 Acid recovery device 4 Automatic analyzer 5 Central processing unit 6 New acid solution tank 7 Liquid level gauge 31 Solution processing chamber 34 Cationic ion exchange membrane 35 Cationic ion exchange membrane 36 Anode electrode 37 Cathode electrode 38 Electrolytic current control device 63 control valve 65 control valve
───────────────────────────────────────────────────── フロントページの続き (72)発明者 石橋 忠也 大阪府吹田市朝日ケ丘27−１−1206 ─────────────────────────────────────────────────── ─── Continued Front Page (72) Inventor Tadaya Ishibashi 27-1-1206 Asahigaoka Suita City Osaka Prefecture
Claims (4)
サンプルの酸濃度および金属イオン濃度を連続的に測定
する工程と、 （２）溶液処理室と、この溶液処理室を挟んで両側に配
置され、カチオン性イオン交換膜によって溶液処理室と
区分された陽極室および陰極室とよりなり、陽極室およ
び陰極室にはそれぞれ陽極および陰極に印荷される電極
を備える酸回収装置の溶液処理室に、酸洗処理浴槽から
連続的に一定量の酸洗処理浴を導入し、酸洗処理浴を電
解分離し、酸を回収して酸洗処理浴槽へ戻す工程と、 （３）前記金属イオン濃度測定値によって、前記酸回収
装置の陽極および陰極間に流れる電解電流値を自動制御
する工程と、 （４）自動分析計の酸濃度測定値によって新酸液を酸洗
処理浴槽へ供給する量を自動制御する工程とを含むこと
を特徴とする鋼材の酸洗方法。1. A method of pickling steel material, comprising: (1) continuously measuring the acid concentration and the metal ion concentration of a pickling bath sample continuously taken from the pickling bath; and (2) It consists of a solution processing chamber and an anode chamber and a cathode chamber, which are arranged on both sides of the solution processing chamber and are separated from the solution processing chamber by a cationic ion exchange membrane.The anode chamber and the cathode chamber are respectively an anode and a cathode. Into the solution processing chamber of the acid recovery device equipped with the electrode to be loaded into, a fixed amount of pickling treatment bath is continuously introduced from the pickling treatment bath, the pickling treatment bath is electrolytically separated, and the acid is recovered. Returning to the pickling bath, (3) automatically controlling the electrolytic current value flowing between the anode and the cathode of the acid recovery device by the measured value of the metal ion concentration, (4) the acid concentration of the automatic analyzer Pickling treatment of new acid solution according to measured value Pickling method of the steel which comprises the step of automatically controlling the amount supplied to the tank.
的に測定する工程と、 （２）前記液面計の測定値によって酸洗処理浴槽の浴液
面位置を自動制御する工程とを含むことを特徴とする請
求項１記載の鋼材酸洗方法。2. A method of pickling steel material, comprising: (1) continuously measuring a bath liquid level position of a pickling treatment bath by a level gauge; and (2) pickling by a measurement value of the level gauge. The method for pickling steel material according to claim 1, further comprising the step of automatically controlling the position of the bath surface of the treatment bath.
サンプルの酸濃度および金属イオン濃度を連続的に測定
する自動分析計と、 （３）前記自動分析計の金属イオン濃度測定値によって
電解電流値が自動制御される電解電流制御装置と、 （４）酸洗処理浴槽との間に連続的に一定量の酸洗処理
浴を循環する溶液処理室と、この溶液処理室を挟んで両
側に配置され、カチオン性イオン交換膜によって溶液処
理室と区分された陽極室および陰極室とよりなり、陽極
室および陰極室にはそれぞれ陽極および陰極に印荷さ
れ、前記電解電流制御装置によって電解電流が自動制御
される電極を備える酸回収装置と、 （５）自動分析計の酸濃度測定値によって、酸洗処理浴
槽へ供給される新酸液の量が自動制御される新酸液供給
装置とを含むことを特徴とする鋼材酸洗装置。3. A steel material pickling apparatus comprising: (1) pickling bath and (2) pickling bath sample continuously picked up from the pickling bath to continuously measure acid concentration and metal ion concentration. And (3) an electrolysis current control device in which the electrolysis current value is automatically controlled by the metal ion concentration measurement value of the autoanalyzer, and (4) a pickling bath. It consists of a solution treatment chamber that circulates a certain amount of pickling treatment bath, and an anode chamber and a cathode chamber that are arranged on both sides of the solution treatment chamber and are separated from the solution treatment chamber by a cationic ion exchange membrane. An acid recovery device equipped with electrodes in the chamber and the cathode chamber, respectively, which are loaded on the anode and the cathode, and whose electrolysis current is automatically controlled by the electrolysis current control device; and (5) the acid concentration measured by the automatic analyzer, Supplied to wash bath That the amount of fresh acid solution steel pickling device characterized by including a new acid solution supply device is automatically controlled.
面位置が自動制御される新酸液供給装置とを含むことを
特徴とする請求項３記載の鋼材酸洗装置。4. A steel material pickling apparatus comprising: (1) a liquid level gauge for measuring the position of the bath liquid level in the pickling bath; and (2) a bath liquid in the pickling bath based on the measured value of the liquid level gauge. The steel material pickling device according to claim 3, further comprising a new acid solution supply device whose surface position is automatically controlled.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP06136057A JP3117871B2 (en) | 1994-06-17 | 1994-06-17 | Method and apparatus for pickling steel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP06136057A JP3117871B2 (en) | 1994-06-17 | 1994-06-17 | Method and apparatus for pickling steel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH083774A true JPH083774A (en) | 1996-01-09 |
| JP3117871B2 JP3117871B2 (en) | 2000-12-18 |
Family
ID=15166189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP06136057A Expired - Fee Related JP3117871B2 (en) | 1994-06-17 | 1994-06-17 | Method and apparatus for pickling steel |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3117871B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008081508A1 (en) * | 2006-12-27 | 2008-07-10 | Hirata Corporation | Regeneration apparatus and method of regeneration |
| CN103409766A (en) * | 2013-05-31 | 2013-11-27 | 江苏华阳管业股份有限公司 | Pickling tank |
| CN115522210A (en) * | 2022-01-27 | 2022-12-27 | 山东大业股份有限公司 | Acidity-controllable metal wire pickling tank |
-
1994
- 1994-06-17 JP JP06136057A patent/JP3117871B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008081508A1 (en) * | 2006-12-27 | 2008-07-10 | Hirata Corporation | Regeneration apparatus and method of regeneration |
| CN103409766A (en) * | 2013-05-31 | 2013-11-27 | 江苏华阳管业股份有限公司 | Pickling tank |
| CN115522210A (en) * | 2022-01-27 | 2022-12-27 | 山东大业股份有限公司 | Acidity-controllable metal wire pickling tank |
| CN115522210B (en) * | 2022-01-27 | 2024-02-27 | 山东大业股份有限公司 | Acidity-controllable metal wire pickling tank |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3117871B2 (en) | 2000-12-18 |
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