JPH0837019A - Combined system of ozonizer and fuel cell - Google Patents

Combined system of ozonizer and fuel cell

Info

Publication number
JPH0837019A
JPH0837019A JP3124883A JP12488391A JPH0837019A JP H0837019 A JPH0837019 A JP H0837019A JP 3124883 A JP3124883 A JP 3124883A JP 12488391 A JP12488391 A JP 12488391A JP H0837019 A JPH0837019 A JP H0837019A
Authority
JP
Japan
Prior art keywords
fuel cell
gas
oxygen
ozone generator
ozone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3124883A
Other languages
Japanese (ja)
Inventor
Hirohito Kawahara
大人 川原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taimei Kinzoku Kogyo Co Ltd
Original Assignee
Taimei Kinzoku Kogyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taimei Kinzoku Kogyo Co Ltd filed Critical Taimei Kinzoku Kogyo Co Ltd
Priority to JP3124883A priority Critical patent/JPH0837019A/en
Publication of JPH0837019A publication Critical patent/JPH0837019A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Oxygen, Ozone, And Oxides In General (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Fuel Cell (AREA)

Abstract

PURPOSE:To save the energy and resources to a great extent by using a hydrogen gas and oxygen gas which an ozonizer produces subsidiarily, as a reaction gas for a fuel cell. CONSTITUTION:A mixture gas 5 of oxygen and ozone generated from the anode 3 of an electrolytic ozonizer 1 is passed through a substance 6 consuming ozone, and a mixture gas 7 is formed of oxygen and used ozone. The mixture gas 7 is dehumidified by a dehumidifier 9, and the ozone is turned by an ozone reducing device 10 into ordinary oxygen so that only oxygen gas is contained, and this is supplied to a fuel cell 14. The hydrogen gas 4 generated by the cathoed 2 is supplied to the fuel cell 14. The oxygen gas and hydrogen gas are used as a reaction gas for the fuel cell 14. Thus oxygen and hydrogen which the ozonizer 1 produces subsidiarily can be used with no wastefulness. It is practicable to save external power supply to a great extent by sending the DC current 29 generated by the fuel cell 14 to this ozonizer 1.

Description

【発明の詳細な説明】Detailed Description of the Invention

【産業上の利用分野】本発明は、各種の消毒、滅菌或い
は水の浄化、野菜、肉等の生鮮食料品或いは各種の加工
食品の腐敗または変質の防止、脱臭、脱色等の種々の目
的に有効に使用できるオゾンを発生するためのオゾン発
生器と、燃料のもっている化学エネルギーを連続的に、
直接、電気エネルギーに変換する燃料電池との組合せシ
ステムに関するものである。
BACKGROUND OF THE INVENTION The present invention has various purposes such as various disinfection, sterilization or purification of water, prevention of decay or deterioration of fresh foods such as vegetables and meat or various processed foods, deodorization and decolorization. Ozone generator for generating ozone that can be effectively used and chemical energy of fuel are continuously supplied,
The present invention relates to a combined system with a fuel cell that directly converts electric energy.

【従来の技術】オゾン発生器としては、1万ボルト程度
の高電圧を与えて生ずる無声放電の中に、乾燥した酸素
または空気を通過させることによって酸素の一部をオゾ
ンに変化させるオゾン発生器が一般に使用されている。
しかし、高濃度のオゾンの製造を主目的としたものとし
ては、電解式オゾン発生器を使用するのが好ましい。電
解式オゾン発生器は、純水の電気分解によって陰極から
水素ガスを発生し、陽極からオゾンと酸素の混合ガスを
発生する。従来、この水素ガスは燃焼させて水分にし、
酸素ガスは大気中に放散させる等の方法で処理されてい
る。また、燃料電池には種々の種類のものがあるが、か
せいカリを電解液として、純水素および純酸素を用いる
燃料電池が、高い効率を期待できるものと考えられてい
る。
2. Description of the Related Art As an ozone generator, an ozone generator for converting a part of oxygen into ozone by passing dry oxygen or air into a silent discharge generated by applying a high voltage of about 10,000 volts. Is commonly used.
However, it is preferable to use an electrolytic ozone generator for the purpose of producing high-concentration ozone. The electrolytic ozone generator generates hydrogen gas from the cathode by electrolysis of pure water, and generates a mixed gas of ozone and oxygen from the anode. Conventionally, this hydrogen gas is burned into moisture,
Oxygen gas is treated by methods such as being diffused into the atmosphere. Further, although there are various types of fuel cells, it is considered that a fuel cell using pure hydrogen and pure oxygen as an electrolyte of potassium hydroxide can be expected to have high efficiency.

【発明が解決しようとする課題】上記の電解式オゾン発
生器は、電気分解という大なる電力消費を伴う装置で経
済的な問題があるにもかかわらず、その動作に伴って生
じる水素ガスおよび酸素ガスを従らに放散させて、その
有効利用ははかられていない。また、燃料電池は無公害
型の高効率発電装置にして、省エネルギー発電或いはコ
ージエネレーシヨンに有効に使用されているが、これ
は、水素および酸素の供給を必要とする。本発明は、上
記の電解式オゾン発生器と燃料電池の特徴を有効に組合
せて、電解式オゾン発生器において副次的に生成される
酸素ガスおよび水素ガスの一方または両方を燃料電池の
反応ガスとして使用し、また、燃料電池により発生され
た電力を電解式オゾン発生器の電力供給源として使用す
ることにより、大幅な省エネルギーおよび省資源の効果
を達成しようとするものである。
Although the electrolytic ozone generator described above has an economical problem in a device that consumes a large amount of electricity such as electrolysis, hydrogen gas and oxygen generated by its operation are generated. The gas is accordingly dissipated and its effective use has not been achieved. Further, the fuel cell is used as a pollution-free high-efficiency power generation device and is effectively used for energy-saving power generation or cogeneration, but it requires supply of hydrogen and oxygen. The present invention effectively combines the features of the electrolytic ozone generator and the fuel cell described above, and uses one or both of oxygen gas and hydrogen gas, which are secondarily generated in the electrolytic ozone generator, as a reaction gas of the fuel cell. By using the electric power generated by the fuel cell as the electric power supply source of the electrolytic ozone generator, it is intended to achieve significant energy saving and resource saving effects.

【課題を解決するための手段】本発明は、上記の課題を
解決するための手段として、電解式オゾン発生器と燃料
電池とを組合せ、電解式オゾン発生器から副次的に生成
される水素ガスおよび酸素ガスを各々単独に或いは同時
に燃料電池に供給して燃料電池の反応ガスとして使用す
るようにしたことを特徴とするオゾン発生器と燃料電池
との組合せシステムを提供する。この組合せシステムで
は、燃料電池により発生された電力を直接または電力母
線を介して電解式オゾン発生器に供給して、電解式オゾ
ン発生器の電力供給源として使用するのがよい。また、
燃料電池により生成された水を電解式オゾン発生器に供
給して、その原料水として使用するのがよい。また、燃
料電池から得られる熱は、熱交換器等を介して取出して
熱源として使用できる。
As a means for solving the above-mentioned problems, the present invention combines an electrolytic ozone generator and a fuel cell, and produces hydrogen secondarily from the electrolytic ozone generator. A combined system of an ozone generator and a fuel cell, characterized in that gas and oxygen gas are supplied to a fuel cell individually or simultaneously and are used as a reaction gas of the fuel cell. In this combined system, the electric power generated by the fuel cell may be supplied to the electrolytic ozone generator directly or via the power bus and used as a power supply source of the electrolytic ozone generator. Also,
The water generated by the fuel cell is preferably supplied to the electrolytic ozone generator and used as the raw material water. Further, the heat obtained from the fuel cell can be taken out through a heat exchanger or the like and used as a heat source.

【作用】本発明の組合せシステムでは、電解式オゾン発
生器によって副次的に発生される水素および酸素、並び
に燃料電池から発生される電力および熱および燃料電池
から生成される水は、すべて、無駄なく利用されて、省
エネルギーおよび省資源の効果が得られる。
In the combination system of the present invention, hydrogen and oxygen generated by the electrolytic ozone generator as a by-product, electric power and heat generated by the fuel cell, and water generated by the fuel cell are all wasted. It can be used without any energy saving and resource saving effect.

【実施例】以下、図面に示す実施例について説明する。
図1は本発明の第1の実施例を示す。図中、1は電解式
オゾン発生器を示し、純水の電気分解を行い陰極2から
は水素ガス4を発生し、陽極3からはオゾンと酸素との
混合ガス5を発生する。この混合ガス5はオゾンを消費
する物質6を通過することで、使用済みのオゾンと酸素
との混合ガス7となる。この混合ガス7を配管8の中間
に設けた吸湿器9で除湿し、オゾン還元器10でオゾン
を通常の酸素にすれば、混合ガス7は酸素ガスのみとな
り、これを配管13に接続する。図中、14は燃料電池
を示し、通常、その反応ガスの1つである酸素ガスは、
空気11をフィルター12に通してから配管13によっ
て燃料電池14に供給されるが、本発明では、前記のよ
うにオゾン還元器10を通して供給される酸素含有ガス
が、フィルター12を通して供給される空気に送り込ま
れるので、空気の酸素濃度が高められる。一方、燃料電
池14に使用されるもう一つの反応ガスとしては、通常
水素ガスの代わりに、石油類等の改質により製造された
水素ガスを多量に含む改質ガスを使用するが、本発明で
は前記の電解式オゾナイザー1の陰極2から生成した高
純度の水素ガス4を燃料電池14のもう一つの反応ガス
として使用するので著しく省資源となる。更に、燃料電
池14から反応成生物として高温水または熱水15が排
出されるので、これを熱交換器16により冷却して常温
水17とし、これは原理的に純水であるから、水道水2
2から純水装置23を通して出来るオゾンの原料となる
純水24と合流させて再利用する。一方、熱交換器16
で加熱された冷媒は配管18を通り、空調設備19等を
経て空調負荷21のエネルギー源として使用する。尚、
冷媒は循環ポンプ20により循環させる。次に、電力に
付いて説明すると、電解式オゾン発生器に供給される直
流電流29は、100ボルトないし200ボルトの交流
電源26から交流直流変換器27を介して供給される
が、この時燃料電池14で発電した直流電流25をスイ
ツチ28等を介して連系させることにより、電解式オゾ
ン発生器1に必要な電力の相当量を供給できるので、シ
ステムの外部からの供給電力は大幅に節減できる。図2
は、本発明の第2の実施例を示すもので図1に示す水素
ガス4の配管の中間に、バイパス配管30と水素吸蔵合
金31を取り付けた構成を示す。この様にすると、保守
点検等のために燃料電池14を停止した場合、31に水
素ガスを貯蓄でき、電解式オゾン発生器1を停止した時
でも、前記の貯蔵しておいた水素ガスを使用すれば燃料
電池14が稼動出来るので、システムの柔軟な運転を行
うことができる。図3は、本発明の他の実施例を示す。
これは、水素4の配管の中間にバイパス配管30と圧縮
機32および圧力容器33を取り付けたものである。こ
の様にすると、前記の図2と同様の機能を持たせること
が出来る。図4は、本発明のさらに他の実施例を示す。
これは、図1に示すオゾン還元器10の出口側の配管に
バイパス配管34と圧縮機35並びに圧力容器36を取
り付けたものを示す。この様にすると、酸素ガスだけを
別の用途に振り分けることもできるし、図2の説明と同
様の機能で使用することもできるので、やはり柔軟なシ
ステム運転を行うのに役立つ。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The embodiments shown in the drawings will be described below.
FIG. 1 shows a first embodiment of the present invention. In the figure, reference numeral 1 denotes an electrolytic ozone generator, which electrolyzes pure water to generate hydrogen gas 4 from a cathode 2 and a mixed gas 5 of ozone and oxygen from an anode 3. This mixed gas 5 becomes a mixed gas 7 of used ozone and oxygen by passing through a substance 6 that consumes ozone. If the mixed gas 7 is dehumidified by the moisture absorber 9 provided in the middle of the pipe 8 and the ozone is reduced to normal oxygen by the ozone reducer 10, the mixed gas 7 becomes only oxygen gas, which is connected to the pipe 13. In the figure, 14 indicates a fuel cell, and oxygen gas, which is one of the reaction gases, is
Although the air 11 is supplied to the fuel cell 14 through the pipe 13 after passing through the filter 12, in the present invention, the oxygen-containing gas supplied through the ozone reducer 10 is supplied to the air supplied through the filter 12 as described above. As it is sent in, the oxygen concentration of the air is increased. On the other hand, as another reaction gas used in the fuel cell 14, a reformed gas containing a large amount of hydrogen gas produced by reforming petroleum or the like is usually used instead of hydrogen gas. However, since the high-purity hydrogen gas 4 generated from the cathode 2 of the electrolytic ozonizer 1 is used as another reaction gas of the fuel cell 14, resource saving is significantly achieved. Furthermore, since high temperature water or hot water 15 is discharged from the fuel cell 14 as a reaction product, it is cooled by the heat exchanger 16 to normal temperature water 17, which is pure water in principle, and therefore tap water. Two
From 2 to the pure water device 23, it is reused by combining with pure water 24 which is a raw material of ozone. On the other hand, the heat exchanger 16
The refrigerant heated in 1 passes through the pipe 18, passes through the air conditioning equipment 19 and the like, and is used as an energy source of the air conditioning load 21. still,
The refrigerant is circulated by the circulation pump 20. Next, the electric power will be described. The direct current 29 supplied to the electrolytic ozone generator is supplied from the AC power supply 26 of 100 V to 200 V through the AC / DC converter 27. By connecting the direct current 25 generated by the battery 14 through the switch 28 and the like, a considerable amount of electric power required for the electrolytic ozone generator 1 can be supplied, so that the electric power supplied from the outside of the system is significantly reduced. it can. Figure 2
2 shows a second embodiment of the present invention and shows a configuration in which a bypass pipe 30 and a hydrogen storage alloy 31 are attached in the middle of the hydrogen gas 4 pipe shown in FIG. By doing so, when the fuel cell 14 is stopped for maintenance or inspection, hydrogen gas can be stored in 31 and the stored hydrogen gas is used even when the electrolytic ozone generator 1 is stopped. Then, the fuel cell 14 can be operated, so that the system can be flexibly operated. FIG. 3 shows another embodiment of the present invention.
This is one in which a bypass pipe 30, a compressor 32 and a pressure vessel 33 are attached in the middle of the hydrogen 4 pipe. By doing so, it is possible to provide the same function as in FIG. FIG. 4 shows another embodiment of the present invention.
This shows one in which a bypass pipe 34, a compressor 35, and a pressure vessel 36 are attached to the pipe on the outlet side of the ozone reducer 10 shown in FIG. By doing so, it is possible to distribute only the oxygen gas to another purpose, and it is also possible to use it with the same function as described in FIG. 2, which is also useful for flexible system operation.

【発明の効果】電解式オゾン発生器は、特殊電極を用い
ていわゆる水の電気分解を行い、オゾンガスを製造する
装置であるが、この際水素ガスと酸素ガスが副次的に生
成される。又、電気分解であるから電力を大量に消費す
る。一方、燃料電池は水素ガスと空気中の酸素ガスを反
応させて、その際生じる電気エネルギーを電力として取
り出すものであり、又反応の結果生成される物質は高温
水あるいは熱水である。本発明によれば、前記の水素ガ
スおよび酸素ガスは、各々単独に或いは同時に燃料電池
に利用され、従って、改質ガス等を別途に供給する必要
もなく、空気量も減らすことができる。逆に、電力多消
費装置の電解式オゾン発生器に燃料電池の発電した電力
とその時の反応生成物である純水とが供給され、従っ
て、オゾン製造の原単位を大きく改善する事ができる。
更に、燃料電池からの反応生成物はもともと熱水或は高
温水であるから、この熱の利用を加えることにより、省
エネルギー効果並びに経済的効果は更に大きなものとな
る。
The electrolytic ozone generator is a device for producing so-called ozone gas by electrolyzing water using a special electrode. At this time, hydrogen gas and oxygen gas are secondarily generated. Also, since it is electrolysis, it consumes a large amount of electric power. On the other hand, the fuel cell reacts hydrogen gas with oxygen gas in the air and takes out the electric energy generated at that time as electric power, and the substance produced as a result of the reaction is hot water or hot water. According to the present invention, the hydrogen gas and the oxygen gas are used individually or simultaneously in the fuel cell. Therefore, it is not necessary to separately supply the reformed gas and the like, and the air amount can be reduced. On the contrary, the electric power generated by the fuel cell and the pure water which is the reaction product at that time are supplied to the electrolytic ozone generator of the power consuming device, so that the basic unit of ozone production can be greatly improved.
Further, since the reaction product from the fuel cell is originally hot water or high temperature water, the use of this heat will further enhance the energy saving effect and the economic effect.

【図面の簡単な説明】[Brief description of drawings]

【図1】図1は本発明の一実施例を示す。FIG. 1 shows an embodiment of the present invention.

【図2】図2は本発明の他の実施例を示す。FIG. 2 shows another embodiment of the present invention.

【図3】図3は本発明のさらに他の実施例を示す。FIG. 3 shows still another embodiment of the present invention.

【図4】図4は本発明のさらに他の実施例を示す。FIG. 4 shows another embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1……電解式オゾン発生器 2……陰極 3
……陽極 4……水素ガス 5……オゾンと酸素
の混合ガス 6……オゾンを消費する物質 7……使用済みオゾンと酸素の混合物 8……配管 9……吸湿器 10……オゾン還元器 11……空気 12……フィルター 13
……配管 14……燃料電池 15……高温水また
は熱水 16……熱交換器 17……常温水 18
……配管 19……空調設備 20……循環ポンプ 21……空調負荷 22……水道水 23……純水装置 24……オゾンの原
料となる純水 25……直流電流 26……交流電源 27……交流直流変換器 28……スイツチ 29……電解オゾナイザーに供給される直流電流 30……バイパス配管 31……水素吸蔵合
金 32……圧縮機 33……圧力容器 34……バイパス配管 35……圧縮機 36……圧力容器
1 ... Electrolytic ozone generator 2 ... Cathode 3
…… Anode 4 …… Hydrogen gas 5 …… Ozone and oxygen mixed gas 6 …… Ozone consuming substance 7 …… Spent ozone and oxygen mixture 8 …… Piping 9 …… Hygroscope 10 …… Ozone reducer 11 ... Air 12 ... Filter 13
...... Piping 14 ...... Fuel cell 15 ...... High temperature water or hot water 16 ...... Heat exchanger 17 ...... Room temperature water 18
…… Piping 19 …… Air conditioning equipment 20 …… Circulation pump 21 …… Air conditioning load 22 …… Tap water 23 …… Pure water device 24 …… Pure water 25 as ozone raw material 25 …… DC current 26 …… AC power supply 27 ...... AC / DC converter 28 ...... Switch 29 ...... DC current supplied to the electrolytic ozonizer 30 ...... Bypass piping 31 ...... Hydrogen storage alloy 32 ...... Compressor 33 ...... Pressure vessel 34 ...... Bypass piping 35 ...... Compressor 36 ... Pressure vessel

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】電解式オゾン発生器と燃料電池とを組合
せ、電解式オゾン発生器から副次的に生成する水素ガス
および酸素ガスを各々単独に或いは同時に燃料電池に送
って、燃料電池の反応ガスとして使用することを特徴と
するオゾン発生器と燃料電池との組合せシステム。
1. A reaction of a fuel cell in which an electrolytic ozone generator and a fuel cell are combined, and hydrogen gas and oxygen gas, which are secondarily generated from the electrolytic ozone generator, are sent to the fuel cell either individually or simultaneously. A combined system of an ozone generator and a fuel cell, which is used as a gas.
【請求項2】請求項1において、燃料電池により発生し
た電力を直接または電力母線を介して電解式オゾン発生
器に送って、電解式オゾン発生器の電力供給源として使
用することを特徴とするオゾン発生器と燃料電池との組
合せシステム。
2. The method according to claim 1, wherein the electric power generated by the fuel cell is sent to the electrolytic ozone generator directly or via a power bus to be used as a power supply source of the electrolytic ozone generator. Combined system of ozone generator and fuel cell.
【請求項3】請求項1において、上記の燃料電池によっ
て生成された水を電解式オゾン発生器に送って、その原
料水とすることを特徴とするオゾン発生器と燃料電池と
の組合せシステム。
3. A combined system of an ozone generator and a fuel cell according to claim 1, wherein the water produced by the fuel cell is sent to an electrolytic ozone generator to be used as raw material water.
【請求項4】請求項1において、上記の燃料電池から得
られる熱を熱交換器等を介して取出して熱源として使用
することを特徴とするオゾン発生器と燃料電池との組合
せシステム。
4. A combined system of an ozone generator and a fuel cell according to claim 1, wherein heat obtained from the fuel cell is taken out through a heat exchanger or the like and used as a heat source.
JP3124883A 1991-04-27 1991-04-27 Combined system of ozonizer and fuel cell Pending JPH0837019A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3124883A JPH0837019A (en) 1991-04-27 1991-04-27 Combined system of ozonizer and fuel cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3124883A JPH0837019A (en) 1991-04-27 1991-04-27 Combined system of ozonizer and fuel cell

Publications (1)

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JPH0837019A true JPH0837019A (en) 1996-02-06

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JP3124883A Pending JPH0837019A (en) 1991-04-27 1991-04-27 Combined system of ozonizer and fuel cell

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004525488A (en) * 2001-02-21 2004-08-19 アイダテック, エル.エル.シー. Fuel cell system using stored hydrogen
EP2991145A1 (en) * 2014-08-29 2016-03-02 Clariant International Ltd. Device for storing electrical energy
DE102015108763A1 (en) * 2015-06-03 2016-12-08 Iav Gmbh Ingenieurgesellschaft Auto Und Verkehr Fuel cell with water decontamination device
DE102015210120A1 (en) * 2015-06-02 2017-01-12 BSH Hausgeräte GmbH Device for ozone treatment with an ozone killer
CN112538637A (en) * 2020-11-23 2021-03-23 珠海格力电器股份有限公司 Ozone generating device, control method and refrigerator

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6059672A (en) * 1983-09-09 1985-04-06 Kogyo Kaihatsu Kenkyusho Effective use of purge gas in ammonia synthesis industry
JPS61263065A (en) * 1985-04-22 1986-11-21 Hitachi Ltd Fuel cell system
JPH02163007A (en) * 1988-12-16 1990-06-22 Kajima Corp Cultivation apparatus utilizing fuel battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6059672A (en) * 1983-09-09 1985-04-06 Kogyo Kaihatsu Kenkyusho Effective use of purge gas in ammonia synthesis industry
JPS61263065A (en) * 1985-04-22 1986-11-21 Hitachi Ltd Fuel cell system
JPH02163007A (en) * 1988-12-16 1990-06-22 Kajima Corp Cultivation apparatus utilizing fuel battery

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004525488A (en) * 2001-02-21 2004-08-19 アイダテック, エル.エル.シー. Fuel cell system using stored hydrogen
EP2991145A1 (en) * 2014-08-29 2016-03-02 Clariant International Ltd. Device for storing electrical energy
DE102015210120A1 (en) * 2015-06-02 2017-01-12 BSH Hausgeräte GmbH Device for ozone treatment with an ozone killer
DE102015108763A1 (en) * 2015-06-03 2016-12-08 Iav Gmbh Ingenieurgesellschaft Auto Und Verkehr Fuel cell with water decontamination device
DE102015108763B4 (en) 2015-06-03 2021-08-12 Iav Gmbh Ingenieurgesellschaft Auto Und Verkehr Fuel cell with water decontamination device
CN112538637A (en) * 2020-11-23 2021-03-23 珠海格力电器股份有限公司 Ozone generating device, control method and refrigerator
CN112538637B (en) * 2020-11-23 2023-08-08 珠海格力电器股份有限公司 Ozone generating device, control method and refrigerator

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