JPH0834093A - Water-resistant printing film laminated steel panel - Google Patents
Water-resistant printing film laminated steel panelInfo
- Publication number
- JPH0834093A JPH0834093A JP19186194A JP19186194A JPH0834093A JP H0834093 A JPH0834093 A JP H0834093A JP 19186194 A JP19186194 A JP 19186194A JP 19186194 A JP19186194 A JP 19186194A JP H0834093 A JPH0834093 A JP H0834093A
- Authority
- JP
- Japan
- Prior art keywords
- adhesive layer
- resin
- pigment
- film
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、水回りに使用する製品
の部材製造に好適な耐水性印刷フィルムラミネ−ト鋼板
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water-resistant printing film laminated steel sheet suitable for manufacturing members for products used around water.
【０００２】[0002]
【従来技術】表面に無地もしくは柄模様を印刷した印刷
ポリエチレンテレフタレ−トフィルムを鋼板表面に積層
したラミネ−ト鋼板は、印刷ポリエチレンテレフタレ−
トフィルム（以下印刷ＰＥＴフィルムという）が塩化ビ
ニルフィルムに比べて硬度が高く、また、安価であるの
で、従来より家電製品や暖房機器などの外装部、内装建
材あるいは器物などに使用されている。このラミネ−ト
鋼板は鋼板表面に顔料を添加した着色接着剤層を設け
て、その上に印刷ＰＥＴフィルムを印刷面が接着剤層側
になるように積層して従来製造していた。ここで、接着
剤層に顔料を添加するのは鋼板の地色が外観になって表
れるのを防止するためである。2. Description of the Related Art Laminated steel sheets obtained by laminating a printed polyethylene terephthalate film having a solid or printed pattern on the surface of a steel sheet are printed polyethylene terephthalate sheets.
Since a hardened film (hereinafter referred to as a printed PET film) has higher hardness and is cheaper than a vinyl chloride film, it has been conventionally used for exterior parts such as home electric appliances and heating equipment, interior building materials, and articles. This laminated steel sheet has conventionally been manufactured by providing a colored adhesive layer containing a pigment on the surface of the steel sheet, and laminating a printed PET film on the colored adhesive layer so that the printed surface faces the adhesive layer. Here, the pigment is added to the adhesive layer in order to prevent the ground color of the steel sheet from appearing in appearance.
【０００３】しかし、このラミネ−ト鋼板は、接着剤層
に顔料を添加してあるため、耐水性が劣り、沸騰水浸漬
試験や耐湿性試験などを行うと、接着剤層中に水が浸透
して、フィルムが接着剤層から膨れたり、剥離したりす
る。このため、電気洗濯機や厨房機器の外装材のような
水回りの製品の部材に使用するには問題があった。そこ
で、接着剤を用いずに印刷インキ層だけで印刷ＰＥＴフ
ィルムを鋼板に積層する方法が提案されている（特開昭
５９−２３２８５２号公報）。しかし、印刷インキ層で
呈色と接着力を両立させることは困難で、接着剤層の場
合と同様にフィルムの膨れや剥離が発生してしまうもの
であった。However, since this laminated steel sheet has a pigment added to the adhesive layer, it is inferior in water resistance, and when subjected to a boiling water immersion test or a moisture resistance test, water penetrates into the adhesive layer. Then, the film swells or peels from the adhesive layer. Therefore, there is a problem in using it as a member of a product around water such as an exterior material of an electric washing machine or a kitchen appliance. Therefore, a method has been proposed in which a printed PET film is laminated on a steel sheet by using only a printing ink layer without using an adhesive (JP-A-59-232852). However, it is difficult to achieve both coloration and adhesive strength in the printing ink layer, and swelling or peeling of the film occurs as in the case of the adhesive layer.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、この接着剤
層の耐水性の問題を解決した印刷フィルムラミネ−ト鋼
板を提供するものである。SUMMARY OF THE INVENTION The present invention provides a printing film laminated steel sheet which solves the water resistance problem of the adhesive layer.
【０００５】[0005]
【課題を解決するための手段】本発明は、鋼板と接着剤
層との間に熱硬化型樹脂の着色プライマ−層を設け、接
着剤層を顔料無添加のものにした。According to the present invention, a colored primer layer of thermosetting resin is provided between a steel plate and an adhesive layer, and the adhesive layer is pigment-free.
【０００６】[0006]
【作用】プライマ−層は、熱硬化型樹脂であるので、接
着剤より緻密なマトリックスとなる。このため、顔料を
添加しても、マトリックスはその緻密な状態を維持し、
水の浸透を防止する。一方、接着剤層は顔料を含有しな
くなるので、緻密性が向上し、水が浸透しにくくなると
ともに、上下のプライマ−層と印刷ＰＥＴフィルムに対
する接着力も大きくなる。Since the primer layer is a thermosetting resin, it forms a denser matrix than the adhesive. Therefore, even if pigment is added, the matrix maintains its dense state,
Prevent water penetration. On the other hand, since the adhesive layer does not contain a pigment, the denseness is improved, water is less likely to permeate, and the adhesive strength between the upper and lower primer layers and the printed PET film is increased.
【０００７】熱硬化型着色プライマ−層の樹脂は、鋼板
との接着強度の大きいものが好ましく、例えば、エポキ
シ系樹脂、ポリエステル系樹脂などを使用すればよい。
顔料に対するマトリックスとしての緻密性を高めるため
に硬化剤を添加してもよい。この硬化剤としてはメラミ
ン樹脂、尿素、イソシアネ−ト樹脂などを用いればよ
い。プライマ−層は乾燥塗膜厚で２〜２０μｍにするの
が好ましい。なお、プライマ−層には必要に応じて着色
顔料、防錆顔料、体質顔料を添加してもよい。The resin for the thermosetting colored primer layer preferably has a high adhesive strength with the steel plate, and for example, an epoxy resin or a polyester resin may be used.
A curing agent may be added to improve the compactness of the pigment as a matrix. As the curing agent, melamine resin, urea, isocyanate resin or the like may be used. The primer layer preferably has a dry coating film thickness of 2 to 20 μm. A color pigment, a rust preventive pigment, and an extender pigment may be added to the primer layer as needed.
【０００８】接着剤層には、プライマ−層と印刷ＰＥＴ
フィルムを接着できるものであれば、特に限定はなく、
例えば、ポリエステル系樹脂、ポリウレタン系樹脂を用
いればよい。この接着剤層には顔料を添加しない。しか
し、接着力を高めるのに他の成分を添加することは可能
である。厚みは乾燥塗膜厚で１〜２０μｍにするのが好
ましい。The adhesive layer includes a primer layer and printed PET.
There is no particular limitation as long as it can bond the film,
For example, a polyester resin or a polyurethane resin may be used. No pigment is added to this adhesive layer. However, it is possible to add other components to enhance the adhesion. The dry coating thickness is preferably 1 to 20 μm.
【０００９】プライマ−層の色調は、接着剤層を通して
見えるので、印刷ＰＥＴフィルムの地模様にすることも
できるが、両者の色調を厳密に調和させるのは難しいの
で、フィルムは地模様を有する柄のものを使用するのが
好ましい。印刷インキとしては、アクリル系、ポリエス
テル系、ポリウレタン系などのベ−ス樹脂に顔料のほか
に種々の添加剤を配合したものを使用できるが、その中
でもベ−ス樹脂に２液型ポリウレタン系のものを用いた
ものが好ましい。Since the color tone of the primer layer can be seen through the adhesive layer, it can be the ground pattern of the printed PET film, but it is difficult to strictly match the color tones of the two, so that the film has a pattern having the ground pattern. It is preferable to use those of As the printing ink, acrylic resin, polyester resin, polyurethane resin, and other base resins mixed with various additives in addition to pigments can be used. Among them, the base resin is a two-component polyurethane type ink. The thing using the thing is preferable.
【００１０】本発明のラミネ−ト鋼板の製造は、めっき
鋼板、ステンレス鋼板などにクロメ−ト処理やリン酸塩
処理のような前処理を施して、エポキシ系樹脂やポリエ
ステル系樹脂などのプライマ−塗料をロ−ルコ−ト法、
カ−テンフロ−法、スプレ−法のような公知方法で塗布
した後、１２０〜２８０℃で２０〜９０秒間焼き付け乾
燥して、その上にポリエステル系樹脂やポリウレタン系
樹脂などの接着剤層をプライマ−層と同様の方法で形成
し、接着剤層が溶融状態にあるとき印刷ＰＥＴフィルム
を積層すればよい。In the production of the laminated steel sheet of the present invention, a plated steel sheet, a stainless steel sheet or the like is subjected to a pretreatment such as a chromate treatment or a phosphate treatment to obtain a primer such as an epoxy resin or a polyester resin. Roll coating method,
After coating by a known method such as the Carten flow method or the spray method, it is baked and dried at 120 to 280 ° C. for 20 to 90 seconds, and an adhesive layer such as a polyester resin or a polyurethane resin is coated on the primer. Formed in the same manner as the layer, and the printed PET film may be laminated when the adhesive layer is in a molten state.
【００１１】[0011]
実施例１ 溶融亜鉛めっき鋼板（板厚０.５ｍｍ、亜鉛付着量片面
４５ｇ／ｍ2）に塗布型クロメ−ト処理を施して、エポ
キシ樹脂系白色プライマ−塗料［硬化剤：メラミン樹
脂、樹脂／顔料＝１／１（重量比）］を乾燥塗膜厚で１
０μｍとなるように塗布して、焼き付け乾燥することに
よりプライマ−層を形成した後、ポリエステル−ポリウ
レタン樹脂系無着色接着剤（硬化剤：イソシアネ−ト樹
脂）を乾燥塗膜厚で５μｍとなるように塗布して、焼き
付け乾燥し、直ちに積層面を印刷面側にした印刷ＰＥＴ
フィルムＡを積層温度２００℃でラミネ−トした。ここ
で、印刷ＰＥＴフィルムＡには厚みが２５μｍのコロナ
放電処理済みＰＥＴフィルム［東洋紡績（株）製］に石
目調柄をベ−ス樹脂が２液型ポリウレタン系樹脂、硬化
剤がイソシアネ−ト樹脂の印刷インキでグラビア印刷し
た後、さらに同様の印刷インキでベタ印刷したものを用
いた。得られたラミネ−ト鋼板を沸騰水浸漬試験（６時
間浸漬）を行ったが、フィルムの膨れや剥離は認められ
なかった。また、高温湿潤試験（温度：７０℃、相対湿
度：９８％）を５００時間行ったが、同様にフィルムの
膨れや剥離は認められなかった。Example 1 A hot-dip galvanized steel sheet (plate thickness: 0.5 mm, zinc adhesion amount: 45 g / m 2 on one side) was subjected to a coating type chrome treatment to obtain an epoxy resin white primer coating [curing agent: melamine resin, resin / Pigment = 1/1 (weight ratio)] as dry film thickness
After coating to a thickness of 0 μm and baking and drying to form a primer layer, a polyester-polyurethane resin non-coloring adhesive (curing agent: isocyanate resin) is applied to a dry coating film thickness of 5 μm. Printed PET with the printed surface side of the laminated surface
Film A was laminated at a lamination temperature of 200 ° C. Here, for the printed PET film A, a PET film having a thickness of 25 μm and subjected to corona discharge treatment [manufactured by Toyobo Co., Ltd.] has a stone pattern with a base resin of a two-component polyurethane resin and a curing agent of isocyanate. Gravure printing was performed with a printing resin printing ink, and then solid printing was performed using the same printing ink. The obtained laminated steel sheet was subjected to a boiling water immersion test (immersion for 6 hours), but no swelling or peeling of the film was observed. Further, a high temperature wetting test (temperature: 70 ° C., relative humidity: 98%) was performed for 500 hours, but similarly, neither swelling nor peeling of the film was observed.
【００１２】実施例２ 合金化溶融亜鉛めっき鋼板（板厚０.４ｍｍ、亜鉛付着
量片面３０ｇ／ｍ2）に塗布型クロメ−ト処理を施し
て、ポリエステル樹脂系グレ−色プライマ−塗料［硬化
剤：イソシアネ−ト樹脂、樹脂／顔料＝１／１（重量
比）］を乾燥塗膜厚で７μｍとなるように塗布して、焼
き付け乾燥することによりプライマ−層を形成した後、
ポリエ−テル−ポリウレタン樹脂系無着色接着剤（硬化
剤：エポキシ樹脂）を乾燥塗膜厚で１０μｍとなるよう
に塗布して、焼き付け乾燥し、直ちに積層面を印刷面側
にした印刷ＰＥＴフィルムＢを積層温度１６０℃でラミ
ネ−トした。ここで、印刷ＰＥＴフィルムＢには厚みが
２５μｍのポリエステル樹脂コ−ティングＰＥＴフィル
ム［帝人（株）製］に砂目調柄を実施例１と同一の印刷
インキでグラビア印刷、ベタ印刷したものを用いた。得
られたラミネ−ト鋼板に実施例１と同様の沸騰水浸漬試
験、高温湿潤試験を行ったが、フィルムの膨れや剥離は
認められなかった。Example 2 An alloyed hot-dip galvanized steel sheet (sheet thickness 0.4 mm, zinc adhesion amount 30 g / m 2 on one side) was subjected to a coating type chrome treatment to obtain a polyester resin-based gray color primer coating [curing]. Agent: isocyanate resin, resin / pigment = 1/1 (weight ratio)] to a dry coating film thickness of 7 μm, and baking and drying to form a primer layer.
Polyether-polyurethane resin-based non-colored adhesive (curing agent: epoxy resin) is applied to a dry coating film thickness of 10 μm, baked and dried, and a printed PET film B in which the laminated surface is the printed surface side immediately. Was laminated at a lamination temperature of 160 ° C. Here, as the printing PET film B, a polyester resin coating PET film having a thickness of 25 μm (manufactured by Teijin Ltd.) having a grain pattern was gravure-printed and solid-printed with the same printing ink as in Example 1. Using. The obtained laminated steel sheet was subjected to the boiling water immersion test and the high temperature wetting test as in Example 1, but no swelling or peeling of the film was observed.
【００１３】実施例３ 合金化溶融亜鉛めっき鋼板（板厚０.６ｍｍ、亜鉛付着
量片面６０ｇ／ｍ2）に塗布型クロメ−ト処理を施し
て、エポキシ樹脂系ベ−ジュ色プライマ−塗料［硬化
剤：イソシアネ−ト樹脂、樹脂／顔料＝１／１（重量
比）］を乾燥塗膜厚で５μｍとなるように塗布して、焼
き付け乾燥することによりプライマ−層を形成した後、
ポリエ−テル−ポリウレタン樹脂系無着色接着剤（硬化
剤：エポキシ樹脂）を乾燥塗膜厚で３μｍとなるように
塗布して、焼き付け乾燥し、直ちに積層面を印刷面側に
した印刷ＰＥＴフィルムＣを積層温度１６０℃でラミネ
−トした。ここで、印刷ＰＥＴフィルムＣには厚みが２
５μｍのポリエステル樹脂コ−ティングＰＥＴフィルム
［帝人（株）製］に和紙調柄をベ−ス樹脂がポリエステ
ル系樹脂の印刷インキでグラビア印刷した後、さらに同
様の印刷インキでベタ印刷したものを用いた。得られた
ラミネ−ト鋼板に実施例１と同様の沸騰水浸漬試験、高
温湿潤試験を行ったが、フィルムの膨れや剥離は認めら
れなかった。Example 3 An alloyed hot-dip galvanized steel sheet (sheet thickness: 0.6 mm, zinc adhesion amount on one side: 60 g / m 2 ) was subjected to coating-type chrome treatment to obtain an epoxy resin-based beige color primer coating [ [Curing agent: isocyanate resin, resin / pigment = 1/1 (weight ratio)] to a dry coating film thickness of 5 μm, and baking and drying to form a primer layer.
Polyester-polyurethane resin-based non-colored adhesive (curing agent: epoxy resin) is applied to a dry coating film thickness of 3 μm, baked and dried, and a printed PET film C with the laminated surface immediately facing the printed surface. Was laminated at a lamination temperature of 160 ° C. Here, the printed PET film C has a thickness of 2
A 5 μm polyester resin coated PET film [manufactured by Teijin Ltd.] was used to gravure-print a Washi pattern with a polyester resin-based printing ink and then solid-print with the same printing ink. I was there. The obtained laminated steel sheet was subjected to the boiling water immersion test and the high temperature wetting test as in Example 1, but no swelling or peeling of the film was observed.
【００１４】実施例４ ＳＵＳ３０４ステンレス鋼板（板厚０.６ｍｍ）にリン
酸塩処理を施して、エポキシ樹脂系黒色プライマ−塗料
［硬化剤：メラミン樹脂、樹脂／顔料＝１／０.６（重
量比）］を乾燥塗膜厚で１０μｍとなるように塗布し
て、焼き付け乾燥することによりプライマ−層を形成し
た後、ポリエステル樹脂系無着色接着剤（硬化剤：ポリ
イソシアネ−ト）を乾燥塗膜厚で５μｍとなるように塗
布して、焼き付け乾燥し、直ちに印刷ＰＥＴフィルムＤ
を積層温度２１０℃でラミネ−トした。ここで、印刷Ｐ
ＥＴフィルムＤには厚みが２５μｍの易接着処理ＰＥＴ
フィルム［東レ（株）製］に和紙調柄を実施例１と同一
の印刷インキでグラビア印刷した後、さらに同様の印刷
インキでベタ印刷したものを用いた。得られたラミネ−
ト鋼板に沸騰水浸漬試験（１０時間浸漬）、高温湿潤試
験（温度：７０℃、相対湿度：９８％、試験時間：１０
００時間）行ったが、いずれもフィルムの膨れや剥離は
認められなかった。Example 4 A SUS304 stainless steel plate (plate thickness: 0.6 mm) was subjected to a phosphate treatment to obtain an epoxy resin-based black primer paint [curing agent: melamine resin, resin / pigment = 1 / 0.6 (weight). Ratio)] to a dry coating film thickness of 10 μm, and baking and drying to form a primer layer, and then a polyester resin non-coloring adhesive (curing agent: polyisocyanate) is applied as a dry coating film. It is applied to a thickness of 5 μm, baked and dried, and immediately printed PET film D
Was laminated at a lamination temperature of 210 ° C. Here, print P
PET with a thickness of 25 μm for ET film D
A film [manufactured by Toray Industries, Inc.] on which washi patterns were gravure-printed with the same printing ink as in Example 1 and then solid-printed with the same printing ink was used. The obtained Lamine
Steel sheet boiling water immersion test (10 hours immersion), high temperature wetness test (temperature: 70 ° C, relative humidity: 98%, test time: 10
However, neither swelling nor peeling of the film was observed.
【００１５】[0015]
比較例１ 実施例１において、プライマ−層の形成を省略して、ポ
リエステル−ポリウレタン樹脂系無着色接着剤の乾燥塗
膜厚みを１０μｍにした。得られたラミネ−ト鋼板に実
施例１と同様の沸騰水浸漬試験を行ったところ、接着剤
層の凝集破壊によりフィルムが剥離した。一方、高温湿
潤試験ではフィルムに微細な膨れが認められなかった。Comparative Example 1 In Example 1, the formation of the primer layer was omitted, and the dry coating film thickness of the polyester-polyurethane resin non-colored adhesive was set to 10 μm. When the obtained laminated steel sheet was subjected to a boiling water immersion test similar to that in Example 1, the film peeled due to cohesive failure of the adhesive layer. On the other hand, no fine swelling was found in the film in the high temperature wet test.
【００１６】比較例２ 実施例２において、ポリエステル樹脂系グレ−色プライ
マ−塗料の代わりにポリエステル樹脂系白色プライマ−
塗料［硬化剤：イソシアネ−ト樹脂、樹脂／顔料＝１／
１.２（重量比）］を用いて、乾燥塗膜厚１０μｍのプ
ライマ−層を形成した。また、ポリエ−テル−ポリウレ
タン樹脂系無着色接着剤の代わりに白色着色のもの［硬
化剤：エポキシ樹脂、樹脂／顔料＝１／１.２（重量
比）］）を用い、乾燥塗膜厚１０μｍの接着剤層を形成
した。得られたラミネ−ト鋼板に実施例１と同様の沸騰
水浸漬試験を行ったところ、フィルムは接着剤層の凝集
破壊によりフィルムが剥離した。また、高温湿潤試験で
もフィルムが全面剥離した。Comparative Example 2 In Example 2, a polyester resin type white primer was used instead of the polyester resin type gray color primer paint.
Paint [Curing agent: isocyanate resin, resin / pigment = 1 /
1.2 (weight ratio)] was used to form a primer layer having a dry coating film thickness of 10 μm. Also, a white colored one [curing agent: epoxy resin, resin / pigment = 1 / 1.2 (weight ratio)]) was used in place of the polyester-polyurethane resin-based uncolored adhesive, and the dry coating film thickness was 10 μm. The adhesive layer of was formed. When the obtained laminated steel sheet was subjected to a boiling water immersion test similar to that in Example 1, the film peeled off due to cohesive failure of the adhesive layer. Also, the film peeled off entirely in the high temperature wet test.
【００１７】比較例３ 実施例３において、エポキシ樹脂系ベ−ジュ色プライマ
−塗料の代わりにエポキシ樹脂系無着色プライマ−塗料
（硬化剤：イソシアネ−ト樹脂）を用い、乾燥塗膜厚で
５μｍのプライマ−層を形成した。また、ポリエ−テル
−ポリウレタン樹脂系無着色接着剤の代わりにベ−ジュ
色着色のもの［硬化剤：エポキシ樹脂、樹脂／顔料＝１
／１.２（重量比）］を用い、乾燥塗膜厚で１０μｍの
接着剤層を形成した。得られたラミネ−ト鋼板に実施例
１と同様の沸騰水浸漬試験、高温湿潤試験を行ったが、
前者ではフィルムの端面部分が大きく剥離し、後者では
接着剤層の凝集破壊によりフィルムが全面剥離した。Comparative Example 3 In Example 3, an epoxy resin non-colored primer paint (curing agent: isocyanate resin) was used in place of the epoxy resin beige color primer paint, and the dry coating film thickness was 5 μm. Was formed. Also, instead of the polyester-polyurethane resin-based uncolored adhesive, beige colored [curing agent: epoxy resin, resin / pigment = 1
/1.2 (weight ratio)] was used to form an adhesive layer having a dry coating film thickness of 10 μm. The obtained laminated steel sheet was subjected to the boiling water immersion test and high temperature wetting test as in Example 1,
In the former case, the end face portion of the film was largely peeled off, and in the latter case, the film was peeled off entirely by cohesive failure of the adhesive layer.
【００１８】[0018]
【発明の効果】以上のように、本発明のラミネ−ト鋼板
は、耐水性に優れているので、水回りの製品の部材に使
用しても、印刷ＰＥＴフィルムが剥離したり、膨れたり
することがない。As described above, since the laminated steel sheet of the present invention is excellent in water resistance, the printed PET film peels off or swells even when used as a member for products around water. Never.
Claims (1)
の接着剤層の上に印刷ポリエチレンテレフタレ−トフィ
ルムを印刷面が接着剤層側になるように積層したラミネ
−ト鋼板において、鋼板と接着剤層との間に熱硬化型樹
脂の着色プライマ−層を設け、接着剤層を顔料無添加の
ものにしたことを特徴とする耐水性印刷フィルムラミネ
−ト鋼板。1. A laminated steel sheet in which a colored adhesive layer is provided on the surface of a steel sheet, and a printed polyethylene terephthalate film is laminated on the adhesive layer so that the printed surface faces the adhesive layer side. A water-resistant printing film laminated steel sheet, characterized in that a colored primer layer of a thermosetting resin is provided between the adhesive layer and the adhesive layer, and the adhesive layer is pigment-free.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19186194A JP3096209B2 (en) | 1994-07-22 | 1994-07-22 | Water-resistant printed film laminated steel sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19186194A JP3096209B2 (en) | 1994-07-22 | 1994-07-22 | Water-resistant printed film laminated steel sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0834093A true JPH0834093A (en) | 1996-02-06 |
| JP3096209B2 JP3096209B2 (en) | 2000-10-10 |
Family
ID=16281721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19186194A Expired - Lifetime JP3096209B2 (en) | 1994-07-22 | 1994-07-22 | Water-resistant printed film laminated steel sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3096209B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007010113A1 (en) * | 2007-02-28 | 2008-09-04 | Hydro Aluminium Deutschland Gmbh | Composite film for filling material containers, comprises first- and second plastic layer, aluminum film arranged between the plastic layers, and first and second primer layer arranged between the plastic layers and the aluminum film |
-
1994
- 1994-07-22 JP JP19186194A patent/JP3096209B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007010113A1 (en) * | 2007-02-28 | 2008-09-04 | Hydro Aluminium Deutschland Gmbh | Composite film for filling material containers, comprises first- and second plastic layer, aluminum film arranged between the plastic layers, and first and second primer layer arranged between the plastic layers and the aluminum film |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3096209B2 (en) | 2000-10-10 |
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