JPH08311326A - Aromatic polycarbonate resin composition and molded product - Google Patents
Aromatic polycarbonate resin composition and molded productInfo
- Publication number
- JPH08311326A JPH08311326A JP11743095A JP11743095A JPH08311326A JP H08311326 A JPH08311326 A JP H08311326A JP 11743095 A JP11743095 A JP 11743095A JP 11743095 A JP11743095 A JP 11743095A JP H08311326 A JPH08311326 A JP H08311326A
- Authority
- JP
- Japan
- Prior art keywords
- component
- aromatic polycarbonate
- weight
- polycarbonate resin
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000003118 aryl group Chemical group 0.000 title claims abstract description 92
- 229920005668 polycarbonate resin Polymers 0.000 title claims abstract description 92
- 239000004431 polycarbonate resin Substances 0.000 title claims abstract description 92
- 239000000203 mixture Substances 0.000 title claims abstract description 80
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 25
- 239000000758 substrate Substances 0.000 claims abstract description 22
- -1 aromatic vinyl compound Chemical class 0.000 claims abstract description 19
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 10
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 9
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 9
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 9
- 229920003244 diene elastomer Polymers 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims description 19
- 229920005992 thermoplastic resin Polymers 0.000 claims description 7
- 150000008301 phosphite esters Chemical class 0.000 claims description 6
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 7
- 229920001577 copolymer Polymers 0.000 abstract description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract description 3
- 239000005062 Polybutadiene Substances 0.000 abstract description 3
- 229920002857 polybutadiene Polymers 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 2
- 229920001971 elastomer Polymers 0.000 description 17
- 239000005060 rubber Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 10
- 239000002131 composite material Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 3
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- XKMCVHMWMWTINX-UHFFFAOYSA-N (2,3,4-trichlorophenyl) dihydrogen phosphate Chemical compound OP(O)(=O)OC1=CC=C(Cl)C(Cl)=C1Cl XKMCVHMWMWTINX-UHFFFAOYSA-N 0.000 description 1
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 description 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- SSADPHQCUURWSW-UHFFFAOYSA-N 3,9-bis(2,6-ditert-butyl-4-methylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C)=CC(C(C)(C)C)=C1OP1OCC2(COP(OC=3C(=CC(C)=CC=3C(C)(C)C)C(C)(C)C)OC2)CO1 SSADPHQCUURWSW-UHFFFAOYSA-N 0.000 description 1
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 1
- DKOMHNDZTMTVGY-UHFFFAOYSA-N C(C)(C)C=1C(=C(C=CC=1)P(O)(O)O)C(C)C Chemical compound C(C)(C)C=1C(=C(C=CC=1)P(O)(O)O)C(C)C DKOMHNDZTMTVGY-UHFFFAOYSA-N 0.000 description 1
- FGXMMMNGOLPDRJ-UHFFFAOYSA-N CCCCCCCCC1=CC=CC(P(O)(O)O)=C1CCCCCCCC Chemical compound CCCCCCCCC1=CC=CC(P(O)(O)O)=C1CCCCCCCC FGXMMMNGOLPDRJ-UHFFFAOYSA-N 0.000 description 1
- XBLRPWWTIKQRQI-UHFFFAOYSA-N CCCCCCCCCCC1=CC=CC(P(O)(O)O)=C1CCCCCCCCCC Chemical compound CCCCCCCCCCC1=CC=CC(P(O)(O)O)=C1CCCCCCCCCC XBLRPWWTIKQRQI-UHFFFAOYSA-N 0.000 description 1
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- QAEPIAHUOVJOOM-UHFFFAOYSA-N OP(O)OP(O)O.C(CCCCCCCC)C1=C(C=CC=C1)C(O)(C(CO)(CO)CO)C1=C(C=CC=C1)CCCCCCCCC Chemical compound OP(O)OP(O)O.C(CCCCCCCC)C1=C(C=CC=C1)C(O)(C(CO)(CO)CO)C1=C(C=CC=C1)CCCCCCCCC QAEPIAHUOVJOOM-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- STKZSWMDNMKTDV-UHFFFAOYSA-N butoxy-dihydroxy-diphenyl-lambda5-phosphane Chemical compound C(CCC)OP(O)(O)(C1=CC=CC=C1)C1=CC=CC=C1 STKZSWMDNMKTDV-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- NJPPTRABUACKFL-UHFFFAOYSA-N decoxy-dihydroxy-diphenyl-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1P(O)(O)(OCCCCCCCCCC)C1=CC=CC=C1 NJPPTRABUACKFL-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- HDGDMUNGKHYYEA-UHFFFAOYSA-N dihydroxy-octoxy-diphenyl-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1P(O)(O)(OCCCCCCCC)C1=CC=CC=C1 HDGDMUNGKHYYEA-UHFFFAOYSA-N 0.000 description 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 1
- WZPMZMCZAGFKOC-UHFFFAOYSA-N diisopropyl hydrogen phosphate Chemical compound CC(C)OP(O)(=O)OC(C)C WZPMZMCZAGFKOC-UHFFFAOYSA-N 0.000 description 1
- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002148 esters Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- KCRLWVVFAVLSAP-UHFFFAOYSA-N octyl dihydrogen phosphite Chemical compound CCCCCCCCOP(O)O KCRLWVVFAVLSAP-UHFFFAOYSA-N 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
- QOQNJVLFFRMJTQ-UHFFFAOYSA-N trioctyl phosphite Chemical compound CCCCCCCCOP(OCCCCCCCC)OCCCCCCCC QOQNJVLFFRMJTQ-UHFFFAOYSA-N 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Manufacturing Optical Record Carriers (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、不用の基板が芳香族ポ
リカーボネート樹脂であるコンパクトディスクを使用し
た流動性、耐衝撃性、耐熱性の良好なメタリック調の芳
香族ポリカーボネート樹脂組成物およびそれからの成形
品に関するものである。コンパクトディスクは多くのユ
ーザーに使用されており、生産される量も年々増え続け
ている。従って、使用されなくなった不用のコンパクト
ディスクや販売店から返却されてくるコンパクトディス
クあるいは生産時発生する不良品等いわゆる再生すべき
コンパクトディスクが増えており、それらの再生方法に
ついて種々の検討が行われている。本発明は、資源の有
効利用ならびに環境保護の見地から、これら不用のコン
パクトディスクの再生利用を目的とするものである。FIELD OF THE INVENTION The present invention relates to a metallic aromatic polycarbonate resin composition having good fluidity, impact resistance and heat resistance, which uses a compact disk whose unnecessary substrate is an aromatic polycarbonate resin, and a composition thereof. It relates to molded articles. Compact discs are used by many users, and the volume produced is increasing year by year. Therefore, there are an increasing number of unnecessary compact discs that are no longer used, compact discs that are returned from dealers, or defective discs that are produced during production, such as so-called compact discs that should be regenerated. ing. The present invention aims to recycle these unnecessary compact discs from the viewpoint of effective use of resources and environmental protection.
【０００２】[0002]
【従来の技術】従来、基板が芳香族ポリカーボネート樹
脂で成形されたコンパクトディスクを再生利用する方法
としては、コンパクトディスクに付着しているアルミ
膜、インク、ＵＶコート膜等を取り除き基板の樹脂を再
利用する方法が考えられている。しかしながら、これら
アルミ膜、インク、ＵＶコート膜等を取り除く方法とし
てコンパクトディスクの表面を切削研磨する方法、振動
圧縮する方法等の物理的方法あるいは酸、アルカリ等を
用いた化学的方法等が考えられるが、いずれも操作が煩
雑でコストが高く一般的ではなかった。一方コンパクト
ディスクに付着しているアルミ膜、インク、ＵＶコート
膜等を取り除かずにそのまま粉砕し再溶融成形すると、
基板である芳香族ポリカーボネート樹脂が分解し、粘度
平均分子量が低下し、成形品の機械的特性が低下するた
めその使用が難しかった。2. Description of the Related Art Conventionally, as a method of recycling a compact disc whose substrate is made of an aromatic polycarbonate resin, the aluminum film, ink, UV coating film, etc. adhering to the compact disc are removed and the resin of the substrate is reused. A method of using is considered. However, as a method of removing these aluminum film, ink, UV coating film, etc., a physical method such as a method of cutting and polishing the surface of a compact disk, a method of vibration compression, or a chemical method using an acid, an alkali or the like can be considered. However, the operation is complicated and the cost is high, which is not general. On the other hand, if you do not remove the aluminum film, ink, UV coating film, etc. adhering to the compact disc and pulverize and re-melt-mold it as it is,
The aromatic polycarbonate resin as the substrate is decomposed, the viscosity average molecular weight is lowered, and the mechanical properties of the molded article are lowered, so that its use is difficult.
【０００３】[0003]
【発明が解決しようとする課題】本発明の目的は、不用
の基板が芳香族ポリカーボネート樹脂であるコンパクト
ディスクをそのまま粉砕、使用する流動性、耐衝撃性、
耐熱性の良好なメタリック調の外観を有する芳香族ポリ
カーボネート樹脂組成物およびそれからの成形品を提供
することにある。DISCLOSURE OF THE INVENTION An object of the present invention is to crush and use a compact disc whose unnecessary substrate is an aromatic polycarbonate resin as it is, to obtain fluidity, impact resistance,
It is intended to provide an aromatic polycarbonate resin composition having a good metallic appearance with good heat resistance and a molded article made from the same.
【０００４】[0004]
【課題を解決するための手段】本発明によれば、（Ａ）
（Ａ−１）基板が芳香族ポリカーボネート樹脂であるコ
ンパクトディスク粉砕化物１０〜１００重量％（ａ−１
成分）および（Ａ−２）芳香族ポリカーボネート樹脂９
０〜０重量％（ａ−２成分）よりなる樹脂混合物（ａ成
分）および（Ｂ）ジエンゴム成分に芳香族ビニル化合物
およびシアン化ビニル化合物をグラフトした熱可塑性グ
ラフト共重合体（ｂ成分）より実質的になり、ａ成分と
ｂ成分との割合が重量比で１５：８５〜９５：５の範囲
である芳香族ポリカーボネート樹脂組成物［Ｉ］および
それからの成形品が提供される。According to the present invention, (A)
(A-1) Compact disc pulverized product whose substrate is an aromatic polycarbonate resin 10 to 100% by weight (a-1
Component) and (A-2) Aromatic polycarbonate resin 9
A resin mixture (a component) consisting of 0 to 0% by weight (a-2 component) and a thermoplastic graft copolymer (b component) obtained by grafting an aromatic vinyl compound and a vinyl cyanide compound onto a (B) diene rubber component. Thus, the aromatic polycarbonate resin composition [I] and the molded article made from the aromatic polycarbonate resin composition [I] in which the weight ratio of the component a to the component b is in the range of 15:85 to 95: 5 are provided.
【０００５】芳香族ポリカーボネート樹脂組成物［Ｉ］
において使用されるａ成分は、基板が芳香族ポリカーボ
ネート樹脂であるコンパクトディスク粉砕化物（ａ−１
成分）および芳香族ポリカーボネート樹脂（ａ−２成
分）よりなる樹脂混合物である。ａ−１成分の基板が芳
香族ポリカーボネート樹脂であるコンパクトディスク粉
砕化物は、コンパクトディスクの生産から販売後迄のあ
らゆる経路から発生するいわゆる不良品、返却品、回収
品等の不用になったコンパクトディスクを粉砕化したも
のである。また、これらのコンパクトディスクにはアル
ミ膜、インク、ＵＶコート膜等が付着しており、この付
着したアルミ膜がメタリック調の外観を呈せしめること
となる。コンパクトディスク（１００重量％）中の芳香
族ポリカーボネートの量は９０重量％以上が好ましく、
９５重量％以上がより好ましく、９９重量％以上がさら
に好ましい。Aromatic polycarbonate resin composition [I]
The component a used in is a crushed compact disc (a-1) whose substrate is an aromatic polycarbonate resin.
Component) and an aromatic polycarbonate resin (a-2 component). The compact disc pulverized product whose substrate of the a-1 component is an aromatic polycarbonate resin is a so-called defective compact disc that is generated from every route from the production of the compact disc to the after-sales and is no longer needed. Is crushed. Further, an aluminum film, ink, a UV coating film, etc. are attached to these compact discs, and the attached aluminum film gives a metallic appearance. The amount of aromatic polycarbonate in the compact disc (100% by weight) is preferably 90% by weight or more,
95% by weight or more is more preferable, and 99% by weight or more is further preferable.
【０００６】コンパクトディスクの基板に使用されてい
る芳香族ポリカーボネート樹脂は、通常二価フェノール
とカーボネート前駆体とを溶液法または溶融法で反応さ
せて得られるものである。ここで使用する二価フェノー
ルとしては、例えば２,２−ビス（４−ヒドロキシフェ
ニル）プロパン（以下ビスフェノールＡと略称する）、
ビス（４−ヒドロキシフェニル）メタン、２,２−ビス
（４−ヒドロキシ−３,５−ジメチルフェニル）プロパ
ン、１,１−ビス（４−ヒドロキシフェニル）エタン、
２,２−ビス（４−ヒドロキシ−３−メチルフェニル）
プロパン等のビス（４−ヒドロキシフェニル）アルカン
およびビス（４−ヒドロキシフェニル）スルフォン等が
あげられ、ビス（４−ヒドロキシフェニル）アルカンが
好ましく、なかでもビスフェノールＡが特に好ましい。
また、カーボネート前駆体としてはカルボニルハライ
ド、ジアリールカーボネートまたはハロホルメート等が
使用され、具体的にはホスゲン、ジフェニルカーボネー
ト、二価フェノールのジハロホルメートまたはそれらの
混合物等が挙げられる。芳香族ポリカーボネート樹脂を
製造するに当り、前記二価フェノールは単独または２種
以上を使用することができ、必要に応じて分子量調節
剤、酸化防止剤、反応を促進するための触媒等を使用し
てもよい。またこの芳香族ポリカーボネート樹脂は三官
能以上の多官能性芳香族化合物を共重合した分岐ポリカ
ーボネート樹脂であっても、２種以上の芳香族ポリカー
ボネート樹脂を混合したものであっても差支えない。通
常は、粘度平均分子量で１４,０００〜１６,０００程度
のものが好ましく使用される。The aromatic polycarbonate resin used for the substrate of the compact disc is usually obtained by reacting a dihydric phenol with a carbonate precursor by a solution method or a melting method. Examples of the dihydric phenol used here include 2,2-bis (4-hydroxyphenyl) propane (hereinafter abbreviated as bisphenol A),
Bis (4-hydroxyphenyl) methane, 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane, 1,1-bis (4-hydroxyphenyl) ethane,
2,2-bis (4-hydroxy-3-methylphenyl)
Examples thereof include bis (4-hydroxyphenyl) alkane such as propane and bis (4-hydroxyphenyl) sulphone, and bis (4-hydroxyphenyl) alkane is preferable, and bisphenol A is particularly preferable.
As the carbonate precursor, carbonyl halide, diaryl carbonate, haloformate, or the like is used, and specific examples thereof include phosgene, diphenyl carbonate, dihaloformate of dihydric phenol, or a mixture thereof. In producing the aromatic polycarbonate resin, the dihydric phenol may be used alone or in combination of two or more, and if necessary, a molecular weight modifier, an antioxidant, a catalyst for accelerating the reaction, etc. may be used. May be. Further, this aromatic polycarbonate resin may be a branched polycarbonate resin obtained by copolymerizing a trifunctional or higher-functional polyfunctional aromatic compound or a mixture of two or more kinds of aromatic polycarbonate resins. Usually, those having a viscosity average molecular weight of about 14,000 to 16,000 are preferably used.
【０００７】ここでいう粘度平均分子量（Ｍ）とは、２
０℃で塩化メチレンを溶媒として求めた極限粘度［η］
を下記関係式に挿入して求めたものである。 ［η］＝１.２３×１０-4Ｍ0.83 The viscosity average molecular weight (M) referred to here is 2
Intrinsic viscosity [η] determined using methylene chloride as a solvent at 0 ° C
Is calculated by inserting [Η] = 1.23 × 10 −4 M 0.83
【０００８】一方、ａ−２成分の芳香族ポリカーボネー
ト樹脂は、前記ａ−１成分で説明した基板に使用されて
いる芳香族ポリカーボネート樹脂と同様のものが用いら
れる。その粘度平均分子量は、１０,０００〜６０,００
０のものが好ましく、１３,０００〜５０,０００のもの
がより好ましく用いられる。On the other hand, the a-2 component aromatic polycarbonate resin is the same as the aromatic polycarbonate resin used for the substrate described in the a-1 component. The viscosity average molecular weight is 10,000 to 60,000
0 is preferable, and 13,000 to 50,000 is more preferable.
【０００９】ａ成分において、ａ−１成分とａ−２成分
の混合割合は、ａ−１成分１０〜１００重量％に対して
ａ−２成分９０〜０重量％であり、ａ−１成分３０〜１
００重量％に対してａ−２成分７０〜０重量％が好まし
い。ａ−１成分が１０重量％より少なくなると（ａ−２
成分が９０重量％より多くなると）多量の不用なコンパ
クトディスクを再生利用するという目的に適さなくな
り、またメタリック調の外観を有さなくなり好ましくな
い。In the component a, the mixing ratio of the component a-1 and the component a-2 is 90 to 0% by weight with respect to the component a-1 of 10 to 100% by weight. ~ 1
The a-2 component is preferably 70 to 0% by weight with respect to 00% by weight. When the component a-1 is less than 10% by weight (a-2
If the amount of the component exceeds 90% by weight), it becomes unsuitable for the purpose of recycling a large amount of useless compact discs, and it does not have a metallic appearance, which is not preferable.
【００１０】芳香族ポリカーボネート樹脂組成物［Ｉ］
においてｂ成分として使用される熱可塑性グラフト共重
合体はジエンゴム成分を幹とし、それにグラフト共重合
可能な芳香族ビニル化合物成分およびシアン化ビニル化
合物成分をグラフト重合させた共重合体であり、具体的
にはＡＢＳ樹脂等を例示することができる。熱可塑性グ
ラフト共重合体を用いることにより該芳香族ポリカーボ
ネート樹脂組成物の耐衝撃性が改善される。この熱可塑
性グラフト共重合体のジエンゴム成分としては、例えば
ポリブタジエン、ポリイソプレンおよびスチレン−ブタ
ジエン共重合体等が挙げられ、ポリブタジエンが好まし
く使用される。これらのジエンゴム成分にグラフトされ
る芳香族ビニル化合物成分としては、例えばスチレン、
α−メチルスチレン、ハロゲン化スチレンおよびビニル
トルエン等が挙げられ、スチレンが好ましく使用され
る。また、シアン化ビニル化合物成分としては、アクリ
ロニトリル、メタアクリロニトリルおよびクロロアクリ
ロニトリル等が挙げられ、アクリロニトリルが好ましく
使用される。これらの熱可塑性グラフト共重合体は塊状
重合、溶液重合、懸濁重合、乳化重合のいずれかの重合
法で製造してもよく、また共重合の方式として一段共重
合でも、多段共重合でも差し支えない。また、２種以上
の共重合体を混合して使用してもよい。Aromatic polycarbonate resin composition [I]
The thermoplastic graft copolymer used as the b component in (b) is a copolymer having a diene rubber component as a backbone and a graft copolymerizable aromatic vinyl compound component and vinyl cyanide compound component graft-polymerized. Examples of the resin include ABS resin. The impact resistance of the aromatic polycarbonate resin composition is improved by using the thermoplastic graft copolymer. Examples of the diene rubber component of the thermoplastic graft copolymer include polybutadiene, polyisoprene and styrene-butadiene copolymer, and polybutadiene is preferably used. Examples of the aromatic vinyl compound component grafted to these diene rubber components include styrene and
Examples include α-methylstyrene, halogenated styrene, vinyltoluene and the like, and styrene is preferably used. Examples of the vinyl cyanide compound component include acrylonitrile, methacrylonitrile and chloroacrylonitrile, and acrylonitrile is preferably used. These thermoplastic graft copolymers may be produced by any one of bulk polymerization, solution polymerization, suspension polymerization and emulsion polymerization, and the copolymerization method may be one-stage copolymerization or multi-stage copolymerization. Absent. Further, two or more kinds of copolymers may be mixed and used.
【００１１】芳香族ポリカーボネート樹脂組成物［Ｉ］
において使用されるａ成分とｂ成分の配合割合は、ａ成
分１５〜９５重量％に対してｂ成分８５〜５重量％であ
り、好ましくはａ成分３０〜８５重量％に対してｂ成分
７０〜１５重量％であり、さらに好ましくはａ成分５０
〜７０重量％に対してｂ成分５０〜３０重量％である。
ａ成分が１５重量％未満すなわちｂ成分が８５重量％を
越えると、耐熱性が低下するようになり、ａ成分が９５
重量％を越えてｂ成分が５重量％未満になると、衝撃性
が低下し好ましくない。Aromatic polycarbonate resin composition [I]
The blending ratio of the component a and the component b used in the above is 85 to 5% by weight of the component b to 15 to 95% by weight of the component a, preferably 70 to 50% of the component b to 30 to 85% by weight of the component a. 15% by weight, more preferably component a 50
The component b is 50 to 30% by weight with respect to 70% by weight.
If the amount of the component a is less than 15% by weight, that is, if the amount of the component b exceeds 85% by weight, the heat resistance is deteriorated and the amount of the component a is 95%.
If the amount of the component b exceeds 5% by weight and the amount of component b is less than 5% by weight, the impact resistance decreases, which is not preferable.
【００１２】また、本発明によれば（Ａ）（Ａ−１）基
板が芳香族ポリカーボネート樹脂であるコンパクトディ
スク粉砕化物１０〜１００重量％（ａ−１成分）および
（Ａ−２）芳香族ポリカーボネート樹脂９０〜０重量％
（ａ−２成分）よりなる樹脂混合物（ａ成分）および
（Ｂ）ジエンゴム成分に芳香族ビニル化合物およびシア
ン化ビニル化合物をグラフトした熱可塑性グラフト共重
合体（ｂ成分）よりなり、ａ成分とｂ成分との割合が重
量比で２０：８０〜９５：５の範囲である熱可塑性樹脂
成分およびその樹脂成分１００重量部に対して、（Ｃ）
弾性重合体１〜１０重量部（ｃ成分）より実質的になる
芳香族ポリカーボネート樹脂組成物［ＩＩ］およびそれ
からの成形品が提供される。Further, according to the present invention, (A) (A-1) a compact disc pulverized product whose substrate is an aromatic polycarbonate resin 10 to 100% by weight (a-1 component) and (A-2) aromatic polycarbonate Resin 90 to 0% by weight
The resin mixture (a component) comprising (a-2 component) and (B) a thermoplastic graft copolymer (b component) in which an aromatic vinyl compound and a vinyl cyanide compound are grafted to a diene rubber component, the a component and the b component. (C) with respect to 100 parts by weight of the thermoplastic resin component and the resin component whose ratio by weight is in the range of 20:80 to 95: 5.
Provided are an aromatic polycarbonate resin composition [II] consisting essentially of 1 to 10 parts by weight of an elastic polymer (component c), and molded articles made from the same.
【００１３】芳香族ポリカーボネート樹脂組成物［Ｉ
Ｉ］におけるａ成分およびｂ成分は、上述した芳香族ポ
リカーボネート樹脂組成物［Ｉ］におけるａ成分および
ｂ成分の説明と同様のものが使用される。芳香族ポリカ
ーボネート樹脂組成物［ＩＩ］において、ａ−１成分と
ａ−２成分の混合割合は芳香族ポリカーボネート樹脂組
成物［Ｉ］における混合割合と同様、ａ−１成分１０〜
１００重量％に対して、ａ−２成分９０〜０重量％であ
り、ａ−１成分３０〜１００重量％に対して、ａ−２成
分７０〜０重量％が好ましい。Aromatic polycarbonate resin composition [I
As the component a and the component b in [I], the same ones as those described above for the component a and the component b in the aromatic polycarbonate resin composition [I] are used. In the aromatic polycarbonate resin composition [II], the mixing ratio of the a-1 component and the a-2 component is the same as that of the aromatic polycarbonate resin composition [I].
The a-2 component is 90 to 0 wt% with respect to 100 wt%, and the a-2 component is 70 to 0 wt% with respect to the a-1 component of 30 to 100 wt%.
【００１４】芳香族ポリカーボネート樹脂組成物［Ｉ
Ｉ］において使用されるａ成分とｂ成分の配合割合は、
ａ成分２０〜９５重量％に対して、ｂ成分８０〜５重量
％であり、好ましくはａ成分５０〜９０重量％に対し
て、ｂ成分５０〜１０重量％であり、さらに好ましくは
ａ成分６０〜８５重量％に対して、ｂ成分４０〜１５重
量％である。ａ成分が２０重量％未満すなわちｂ成分が
８０重量％を越えると、耐熱性が低下するようになり、
ａ成分が９５重量％を越えてｂ成分が５重量％未満にな
ると、衝撃性が低下し好ましくない。Aromatic polycarbonate resin composition [I
The mixing ratio of the component a and the component b used in [I] is
The component a is 20 to 95% by weight, the component b is 80 to 5% by weight, the component a is 50 to 90% by weight, the component b is 50 to 10% by weight, and more preferably the component a 60. The component b is 40 to 15% by weight with respect to 85% by weight. If the amount of the component a is less than 20% by weight, that is, if the amount of the component b exceeds 80% by weight, the heat resistance will decrease.
When the amount of the component a exceeds 95% by weight and the amount of the component b is less than 5% by weight, the impact resistance is lowered, which is not preferable.
【００１５】芳香族ポリカーボネート樹脂組成物［Ｉ
Ｉ］においてｃ成分として使用される弾性重合体は、ａ
成分およびｂ成分よりなる熱可塑性樹脂成分の耐衝撃性
をさらに改善するために用いられる。この弾性重合体と
しては、例えばブタジエン−アルキルメタクリレート−
スチレン共重合体、ブタジエン−アルキルメタクリレー
ト−スチレン−ジビニルベンゼン共重合体およびブタジ
エン−アルキルアクリレート−アルキルメタクリレート
共重合体等のアクリル系弾性重合体やポリオルガノシロ
キサンゴム成分とポリアルキル（メタ）アクリレートゴ
ム成分とが相互に絡み合った構造を有している複合弾性
重合体等が挙げられ、これらの弾性重合体は単独あるい
は２種以上混合して用いることができる。Aromatic polycarbonate resin composition [I
The elastic polymer used as the component c in [I] is a
It is used to further improve the impact resistance of the thermoplastic resin component consisting of the component and the component b. Examples of this elastic polymer include butadiene-alkyl methacrylate-
Acrylic elastic polymers such as styrene copolymer, butadiene-alkyl methacrylate-styrene-divinylbenzene copolymer and butadiene-alkyl acrylate-alkyl methacrylate copolymer, and polyorganosiloxane rubber component and polyalkyl (meth) acrylate rubber component Examples thereof include a composite elastic polymer having a structure in which and are intertwined with each other. These elastic polymers can be used alone or in combination of two or more kinds.
【００１６】前記の複合弾性重合体は、好ましくはポリ
オルガノシロキサンゴム成分１０〜９０重量％とポリア
ルキル（メタ）アクリレートゴム成分９０〜１０重量％
（各ゴム成分の合計量が１００重量％）から構成され両
ゴム成分が相互に絡み合い実質上分離できない構造を有
しかつその平均粒子径が０.０８〜０.６μｍである複合
ゴムであり、特に好ましくは前記複合ゴムにさらにビニ
ル単量体がグラフト重合された複合ゴムグラフト共重合
体である。また、その製造方法としては、ポリオルガノ
シロキサンゴム成分のラテックス中へ上記アルキル（メ
タ）アクリレート、架橋剤およびグラフト交叉剤を添加
し、ポリオルガノシロキサンゴム粒子へ含浸させたの
ち、通常のラジカル重合開始剤を作用させて行う。重合
の進行と共にポリオルガノシロキサンゴムの架橋網目に
相互に絡んだポリアルキル（メタ）アクリレートゴムの
架橋網目が形成され、実質上分離できないポリオルガノ
シロキサンゴム成分とポリアルキル（メタ）アクレリー
トゴム成分との複合ゴムのラテックスが得られる。この
複合弾性重合体に関しては例えば特開平１−２３０６６
４号公報に詳しく記載されている。この複合弾性重合体
は通常ＩＰＮポリマーと称されることもある。The above-mentioned composite elastic polymer is preferably 10 to 90% by weight of a polyorganosiloxane rubber component and 90 to 10% by weight of a polyalkyl (meth) acrylate rubber component.
(A total amount of each rubber component is 100% by weight), which is a composite rubber having a structure in which both rubber components are entangled with each other and cannot be substantially separated, and whose average particle diameter is 0.08 to 0.6 μm. Particularly preferred is a composite rubber graft copolymer obtained by further graft-polymerizing a vinyl monomer to the above composite rubber. As a method for producing the same, the above-mentioned alkyl (meth) acrylate, a cross-linking agent and a graft crossing agent are added to the latex of the polyorganosiloxane rubber component, and the polyorganosiloxane rubber particles are impregnated, followed by normal radical polymerization initiation. It is carried out by acting an agent. As the polymerization progresses, a crosslinked network of polyalkyl (meth) acrylate rubber entangled with each other in the crosslinked network of polyorganosiloxane rubber is formed, and a polyorganosiloxane rubber component and a polyalkyl (meth) acrylate rubber component which are substantially inseparable are formed. A composite rubber latex of is obtained. Regarding this composite elastic polymer, for example, JP-A-1-23066 is used.
It is described in detail in Japanese Patent No. 4 publication. This composite elastic polymer is sometimes referred to as an IPN polymer.
【００１７】芳香族ポリカーボネート樹脂組成物［Ｉ
Ｉ］においてＣ成分として使用される弾性重合体の配合
量は、ａ成分およびｂ成分よりなる熱可塑性樹脂成分１
００重量部に対して１〜１０重量部であり、好ましくは
２〜８重量部である。１重量部未満では衝撃性の改良が
不十分であり、１０重量部を越えると流動性、耐熱性お
よび剛性が低下し好ましくない。Aromatic polycarbonate resin composition [I
The amount of the elastic polymer used as the C component in [I] is the thermoplastic resin component 1 including the a component and the b component.
The amount is 1 to 10 parts by weight, preferably 2 to 8 parts by weight, based on 00 parts by weight. If it is less than 1 part by weight, the improvement of impact resistance is insufficient, and if it exceeds 10 parts by weight, fluidity, heat resistance and rigidity are deteriorated, which is not preferable.
【００１８】さらに、本発明によれば（Ａ）（Ａ−１）
基板が芳香族ポリカーボネート樹脂であるコンパクトデ
ィスク粉砕化物１０〜１００重量％（ａ−１成分）およ
び（Ａ−２）芳香族ポリカーボネート樹脂９０〜０重量
％（ａ−２成分）よりなる樹脂混合物（ａ成分）および
その樹脂混合物１００重量部に対して、（Ｃ）弾性重合
体３〜２０重量部（ｃ成分）より実質的になる芳香族ポ
リカーボネート樹脂組成物［ＩＩＩ］およびそれからの
成形品が提供される。Further, according to the present invention, (A) (A-1)
A resin mixture (a) comprising 10 to 100% by weight of a compact disc pulverized product whose substrate is an aromatic polycarbonate resin (a-1 component) and (A-2) 90 to 0% by weight of an aromatic polycarbonate resin (a-2 component). Aromatic polycarbonate resin composition [III] and a molded article made thereof, which are substantially composed of 3 to 20 parts by weight of (C) elastic polymer (component (c)) per 100 parts by weight of component) and the resin mixture thereof. It
【００１９】芳香族ポリカーボネート樹脂組成物［ＩＩ
Ｉ］におけるａ成分およびｃ成分は、それぞれ上述した
芳香族ポリカーボネート樹脂組成物［Ｉ］および［Ｉ
Ｉ］におけるａ成分、芳香族ポリカーボネート樹脂組成
物［ＩＩ］におけるｃ成分の説明と同様のものが使用さ
れる。Aromatic polycarbonate resin composition [II
The components a and c in [I] are the aromatic polycarbonate resin compositions [I] and [I] described above, respectively.
The same thing as the description of the component a in I] and the component c in the aromatic polycarbonate resin composition [II] is used.
【００２０】芳香族ポリカーボネート樹脂組成物［ＩＩ
Ｉ］において、ａ−１成分とａ−２成分の混合割合は芳
香族ポリカーボネート樹脂組成物［Ｉ］および［ＩＩ］
における混合割合と同様、ａ−１成分１０〜１００重量
％に対してａ−２成分９０〜０重量％であり、ａ−１成
分３０〜１００重量％に対してａ−２成分７０〜０重量
％が好ましい。Aromatic polycarbonate resin composition [II
I], the mixing ratio of the a-1 component and the a-2 component is the aromatic polycarbonate resin composition [I] and [II].
Similarly to the mixing ratio in (a), the a-1 component is 10 to 100% by weight, the a-2 component is 90 to 0% by weight, and the a-1 component is 30 to 100% by weight, and the a-2 component is 70 to 0% by weight. % Is preferred.
【００２１】芳香族ポリカーボネート樹脂［ＩＩＩ］に
おいて、ｃ成分として使用される弾性重合体は、ａ成分
である樹脂混合物の耐衝撃性を改良する目的で用いられ
る。この弾性重合体の配合量は、該樹脂混合物１００重
量部に対して３〜２０重量部であり、好ましくは５〜１
０重量部である。３重量部未満では衝撃性の改良が不十
分であり、２０重量部を越えると流動性、耐熱性および
剛性が低下し好ましくない。In the aromatic polycarbonate resin [III], the elastic polymer used as the component c is used for the purpose of improving the impact resistance of the resin mixture which is the component a. The amount of the elastic polymer compounded is 3 to 20 parts by weight, preferably 5 to 1 part by weight, based on 100 parts by weight of the resin mixture.
0 parts by weight. If it is less than 3 parts by weight, the improvement of impact resistance is insufficient, and if it exceeds 20 parts by weight, fluidity, heat resistance and rigidity are lowered, which is not preferable.
【００２２】また、本発明によれば上述した芳香族ポリ
カーボネート樹脂組成物［Ｉ］、［ＩＩ］および［ＩＩ
Ｉ］に、さらに（Ｄ）亜燐酸エステル（ｄ−１成分）お
よび／または燐酸エステル（ｄ−２成分）を配合するこ
とが好ましい。このｄ−１成分および／またはｄ−２成
分を配合することにより該芳香族ポリカーボネート樹脂
組成物［Ｉ］、［ＩＩ］および［ＩＩＩ］の熱安定性が
さらに向上し、粘度平均分子量の低下が抑制される。Further, according to the present invention, the above-mentioned aromatic polycarbonate resin compositions [I], [II] and [II].
It is preferable that (D) further contains (D) a phosphite ester (d-1 component) and / or a phosphite ester (d-2 component). By blending the d-1 component and / or the d-2 component, the thermal stability of the aromatic polycarbonate resin compositions [I], [II] and [III] is further improved and the viscosity average molecular weight is lowered. Suppressed.
【００２３】本発明でｄ−１成分として使用される亜燐
酸エステルは、例えばトリフェニルホスファイト、ジス
テアリルペンタエリスリトールジホスファイト、トリス
ノニルフェニルホスファイト、トリス（２,４−ジ−ｔ
ｅｒｔ−ブチルフェニル）ホスファイト、トリデシルホ
スファイト、トリオクチルホスファイト、トリオクタデ
シルホスファイト、ジデシル−モノフェニルホスファイ
ト、ジオクチル−モノフェニルホスファイト、ジイソプ
ロピル−モノフェニルホスファイト、モノブチル−ジフ
ェニルホスファイト、モノデシル−ジフェニルホスファ
イト、モノオクチル−ジフェニルホスファイト、ビス
（２,６−ジ−ｔｅｒｔ−ブチル−４−メチルフェニ
ル）ペンタエリスリトールジホスファイト、２,２−メ
チレンビス（４,６−ジ−ｔｅｒｔ−ブチルフェニル）
オクチルホスファイト、ビス（ノニルフェニル）ペンタ
エリスリトールジホスファイトおよびビス（２,４−ジ
−ｔｅｒｔ−ブチルフェニル）−４,４−ジフェニレン
ホスホナイト等の亜燐酸のトリエステルまたはエステル
部をアルキル基、フェニル基、アルキルアリール基等で
置換したジエステル、モノエステルであり、これらは単
独で使用してもまた２種以上併用してもよい。なかでも
トリスノニルフェニルホスファイト、ジステアリルペン
タエリスリトリールジホスファイトが好ましい。Examples of the phosphite used as the component d-1 in the present invention include triphenyl phosphite, distearyl pentaerythritol diphosphite, trisnonylphenyl phosphite and tris (2,4-di-t).
ert-butylphenyl) phosphite, tridecylphosphite, trioctylphosphite, trioctadecylphosphite, didecyl-monophenylphosphite, dioctyl-monophenylphosphite, diisopropyl-monophenylphosphite, monobutyl-diphenylphosphite, Monodecyl-diphenylphosphite, monooctyl-diphenylphosphite, bis (2,6-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphite, 2,2-methylenebis (4,6-di-tert- Butylphenyl)
The triester or ester part of phosphorous acid such as octyl phosphite, bis (nonylphenyl) pentaerythritol diphosphite and bis (2,4-di-tert-butylphenyl) -4,4-diphenylenephosphonite is an alkyl group. , A diester or a monoester substituted with a phenyl group, an alkylaryl group or the like, and these may be used alone or in combination of two or more kinds. Of these, trisnonylphenyl phosphite and distearyl pentaerythritolyl diphosphite are preferable.
【００２４】本発明でｄ−２成分として使用される燐酸
エステルは、例えばトリブチルホスフェート、トリメチ
ルホスフェート、トリクレジルホスフェート、トリフェ
ニルホスフェート、トリクロルフェニルホスフェート、
トリエチルホスフェート、ジフェニルクレジルホスフェ
ート、ジフェニルモノオルソキセニルホスフェート、ト
リブトキシエチルホスフェート、ジブチルホスフェー
ト、ジオクチルホスフェートおよびジイソプロピルホス
フェート等があげられ、これらは単独で使用してもまた
２種以上併用してもよい。なかでもトリフェニルホスフ
ェート、トリメチルホスフェートが好ましい。The phosphoric acid ester used as the d-2 component in the present invention is, for example, tributyl phosphate, trimethyl phosphate, tricresyl phosphate, triphenyl phosphate, trichlorophenyl phosphate,
Examples thereof include triethyl phosphate, diphenyl cresyl phosphate, diphenyl monoorthoxenyl phosphate, tributoxyethyl phosphate, dibutyl phosphate, dioctyl phosphate and diisopropyl phosphate. These may be used alone or in combination of two or more. . Of these, triphenyl phosphate and trimethyl phosphate are preferable.
【００２５】本発明で使用されるｄ−１成分および／ま
たはｄ−２成分の配合量は、芳香族ポリカーボネート樹
脂組成物［Ｉ］については、この組成物［Ｉ］１００重
量部に対して、芳香族ポリカーボネート樹脂組成物［Ｉ
Ｉ］については、ａ成分およびｂ成分よりなる熱可塑性
樹脂成分１００重量部に対して、芳香族［ＩＩＩ］につ
いては、ａ成分の樹脂混合物１００重量部に対して０.
００５〜２.０重量部が好ましい。より好ましくは０.０
０８〜１.８重量部、さらに好ましくは０.０１〜１.５
重量部である。ｄ−１成分および／またはｄ−２成分の
配合量が０.００５重量部未満では、該芳香族ポリカー
ボネート樹脂組成物［Ｉ］、［ＩＩ］および［ＩＩＩ］
の熱安定性への効果が少なく、２.０重量部を越えると
該芳香族ポリカーボネート樹脂組成物［Ｉ］、［ＩＩ］
および［ＩＩＩ］の耐衝撃性および剛性が低下し好まし
くない。With respect to the aromatic polycarbonate resin composition [I], the compounding amount of the d-1 component and / or the d-2 component used in the present invention is 100 parts by weight of the composition [I]. Aromatic polycarbonate resin composition [I
I] is 100 parts by weight of the thermoplastic resin component consisting of the components a and b, and the aromatic [III] is 0.1 parts by weight of the resin mixture of the component a.
005 to 2.0 parts by weight is preferable. More preferably 0.0
08-1.8 parts by weight, more preferably 0.01-1.5
Parts by weight. When the blending amount of the d-1 component and / or the d-2 component is less than 0.005 parts by weight, the aromatic polycarbonate resin composition [I], [II] and [III]
Has little effect on the thermal stability of the aromatic polycarbonate resin composition [I] or [II].
Also, the impact resistance and rigidity of [III] are lowered, which is not preferable.
【００２６】本発明の芳香族ポリカーボネート樹脂組成
物［Ｉ］、［ＩＩ］および［ＩＩＩ］は、さらに着色剤
を配合しても良い。この芳香族ポリカーボネート樹脂組
成物［Ｉ］、［ＩＩ］および［ＩＩＩ］においてａ−１
成分として使用される該コンパクトディスク粉砕化物に
はアルミ膜が付いているため、アルミ膜が輝いて綺麗な
メタリック調の外観になる。特に透明で綺麗なメタリッ
ク調の外観にするには、染料系の着色剤を使用するのが
良い。ただしカーボンブラックを使用する場合でメタリ
ック調の外観が必要な場合は、カーボンブラックの配合
量をできるだけ少なくしたほうがメタリック調の綺麗な
外観が得られる。また、本発明の芳香族ポリカーボネー
ト樹脂組成物には目的および効果を損なわない範囲で有
効発現量の添加剤を配合しても良く、例えば他の安定剤
や衝撃改質剤、離型剤、紫外線吸収剤、帯電防止剤、難
燃剤、可塑剤および滑剤等を配合しても良い。The aromatic polycarbonate resin composition [I], [II] and [III] of the present invention may further contain a colorant. A-1 in the aromatic polycarbonate resin compositions [I], [II] and [III]
Since the compacted disc pulverized product used as a component is provided with an aluminum film, the aluminum film shines and has a beautiful metallic appearance. In particular, it is preferable to use a dye-based coloring agent in order to obtain a transparent and beautiful metallic appearance. However, in the case where carbon black is used and a metallic appearance is required, a beautiful metallic appearance can be obtained by reducing the amount of carbon black compounded as much as possible. Further, the aromatic polycarbonate resin composition of the present invention may be blended with an effective expression amount of additives within a range that does not impair the purpose and effects, for example, other stabilizers and impact modifiers, release agents, ultraviolet rays. You may mix | blend an absorber, an antistatic agent, a flame retardant, a plasticizer, a lubricant, etc.
【００２７】本発明において、前述のメタリック調の外
観を有する成形品を得るには、任意の方法が採用され
る。例えば使用するすべての成分を溶融混練する方法が
好ましく採用され、単軸押出機、２軸押出機、加圧ニー
ダー等一般に使用されているものが使用できる。特に好
ましくは、ベント付きの２軸押出機であり、ベントから
真空排気ができるものが好ましい。この場合、ａ−１成
分のコンパクトディスクは粉砕機等で粉砕化されてお
り、特に粒径３０ｍｍ以下に粉砕されていることが好ま
しい。粉砕されていないと他成分と均一に混合すること
が困難であり、また溶融混練する時に使用する押出機等
への供給が難しくなり、満足な成形品が得られない。但
し、ここでいう粒径とは、粉砕されたものの長径をい
う。使用する原料は、タンブラー、ブレンダー、ナウタ
ーミキサー、バンバリーミキサー、混練ロール等であら
かじめ混合していても計量機を用いて独立に供給されて
も良い。In the present invention, any method may be used to obtain a molded product having the metallic appearance described above. For example, a method of melt-kneading all the components to be used is preferably adopted, and commonly used ones such as a single screw extruder, a twin screw extruder, and a pressure kneader can be used. A twin-screw extruder with a vent is particularly preferable, and one capable of evacuating from the vent is preferable. In this case, the compact disc of the component a-1 is crushed by a crusher or the like, and particularly preferably crushed to have a particle size of 30 mm or less. If it is not pulverized, it is difficult to uniformly mix it with other components, and it becomes difficult to supply it to an extruder or the like used for melt-kneading, so that a satisfactory molded product cannot be obtained. However, the particle size here means the major axis of the pulverized product. The raw materials to be used may be pre-mixed with a tumbler, blender, Nauter mixer, Banbury mixer, kneading roll or the like, or may be independently supplied using a measuring machine.
【００２８】本発明は、資源の有効利用ならびに環境保
護の見地から、不用のコンパクトディスクの再生利用を
目的とするものであり、本発明の芳香族ポリカーボネー
ト樹脂組成物［Ｉ］、［ＩＩ］および［ＩＩＩ］は、不
用のコンパクトディスクに付着しているアルミ膜、イン
ク、ＵＶコート膜等を取り除かずにそのまま粉砕し、再
溶融成形して得られる流動性、耐熱性、耐衝撃性の良好
なメタリック調の外観を有するものである。本発明の芳
香族ポリカーボネート樹脂組成物［Ｉ］、［ＩＩ］およ
び［ＩＩＩ］は、例えばＯＡ部品、家庭電化製品、オー
ディオ部品および雑貨等の部品に有用である。The present invention is intended to recycle unnecessary compact discs from the viewpoint of effective use of resources and environmental protection. The aromatic polycarbonate resin compositions [I], [II] and [III] has good fluidity, heat resistance, and impact resistance obtained by crushing as it is without removing the aluminum film, ink, UV coating film, etc. adhering to the unnecessary compact disc, and remelting. It has a metallic appearance. The aromatic polycarbonate resin compositions [I], [II] and [III] of the present invention are useful for parts such as OA parts, household appliances, audio parts and sundries.
【００２９】実施例１〜４０および比較例１〜８ 以下に実施例をあげて本発明をさらに説明する。表１〜
３記載の各成分を表１〜３記載の割合でタンブラーで混
合後、径３０ｍｍφのベント付き２軸押出機［池貝鉄工
（株）製ＰＣＭ３０型］でベントから真空排気させなが
らシリンダー温度２６０℃で溶融混練し押し出しペレッ
ト化した。このペレットを１１０℃で５時間乾燥後、射
出成形機［住友重機械工業（株）製Ｓ４８０／１５０］
でシリンダー温度２６０℃、金型温度７０℃で作成した
試験片を下記（１）〜（４）の方法で評価を行った。評
価結果は表１〜３に記載した。 （１）流動性（メルトフローレート）：ＪＩＳ Ｋ−７
２１０に準じ、荷重２.１６ｋｇｆ、温度２５０℃で測
定した。 （２）アイゾットノッチ付き衝撃強さ：測定試験片厚さ
３.２ｍｍとしＡＳＴＭ Ｄ−２５６に従って測定し
た。 （３）荷重たわみ温度：荷重１８.５ｋｇｆ／ｃｍ2の条
件下でＪＩＳ Ｋ−７２０７に従って測定した。 （４）外観：目視によって判定した。Examples 1-40 and Comparative Examples 1-8 The present invention will be further described with reference to the following examples. Table 1
After mixing the components described in No. 3 with a tumbler at the ratios shown in Tables 1 to 3, a twin-screw extruder with a vent having a diameter of 30 mm φ [PCM30 type manufactured by Ikegai Tekko KK] was evacuated from the vent at a cylinder temperature of 260 ° C It was melt-kneaded and extruded into pellets. After drying these pellets at 110 ° C. for 5 hours, an injection molding machine [S480 / 150 manufactured by Sumitomo Heavy Industries, Ltd.]
The test pieces prepared at a cylinder temperature of 260 ° C. and a mold temperature of 70 ° C. were evaluated by the following methods (1) to (4). The evaluation results are shown in Tables 1 to 3. (1) Fluidity (melt flow rate): JIS K-7
According to 210, the measurement was performed at a load of 2.16 kgf and a temperature of 250 ° C. (2) Impact strength with Izod notch: Measured according to ASTM D-256 with a test piece thickness of 3.2 mm. (3) Deflection temperature under load: Measured in accordance with JIS K-7207 under a load of 18.5 kgf / cm 2 . (4) Appearance: visually determined.
【００３０】なお表１〜３記載の各成分を示す記号は下
記の通りである。 ａ−１成分 コンパクトディスク粉砕化物［製品］ 基板が粘度平均分子量１５,０００のビスフェノールＡ
より得られた芳香族ポリカーボネート樹脂であり、その
量がコンパクトディスク中９９.６重量％であるアルミ
膜付着の直径１２０ｍｍのコンパクトディスクを粉砕機
で粉砕し、平均粒径６ｍｍにしたコンパクトディスク粉
砕化物。 ａ−２成分 ビスフェノールＡ系芳香族ポリカーボネート樹脂ペレッ
ト（粘度平均分子量：１５,０００） ｂ成分 ＡＢＳ−１：ＡＢＳ樹脂［三井東圧化学（株）製サンタ
ックＵＴ−６１］ ＡＢＳ−２：ＡＢＳ樹脂［ダイセル化学工業（株）製セ
ビアンＶ−６８０］ ｃ成分 弾性重合体−１：ブタジエン−アクリル酸アルキル−メ
タクリル酸アルキル共重合体［呉羽化学工業（株）製パ
ラロイドＥＸＬ２６０２］ 弾性集合体−２：ブタジエン−スチレン−メタクリル酸
メチル共重合体［鐘淵化学工業（株）製カネエースＢ−
５６］ 弾性重合体−３：ポリオルガノシロキサンゴム成分とポ
リアルキル（メタ）アクリレートゴム成分との複合弾性
重合体［三菱レイヨン（株）製メタブレンＳ−２００
１］ ｄ−１成分 亜燐酸エステル：トリスノニルフェニルホスファイト ｄ−２成分 燐酸エステル：トリメチルホスフェート 着色剤 着色剤−１：ペリノン系赤色染料［有本化学工業（株）
製プラストレッド８３７０］ 着色剤−２：カーボンブラック［三菱化成（株）製ＭＡ
−１００］The symbols showing the components shown in Tables 1 to 3 are as follows. a-1 component Compact disc pulverized product [Product] Bisphenol A whose substrate has a viscosity average molecular weight of 15,000
A pulverized product of an aromatic polycarbonate resin obtained by crushing a compact disc of 120 mm in diameter with an aluminum film, the amount of which is 99.6% by weight in a compact disc, by a pulverizer to obtain an average particle size of 6 mm. . a-2 component Bisphenol A aromatic polycarbonate resin pellets (viscosity average molecular weight: 15,000) b component ABS-1: ABS resin [Santac UT-61 manufactured by Mitsui Toatsu Chemicals, Inc.] ABS-2: ABS resin [ Daicel Chemical Industries Co., Ltd. Sebian V-680] c component Elastic polymer-1: butadiene-alkyl acrylate-alkyl methacrylate copolymer [Kureha Chemical Industry Co., Ltd. Paraloid EXL2602] Elastic assembly-2: butadiene -Styrene-methyl methacrylate copolymer [Kaneace B manufactured by Kanegafuchi Chemical Industry Co., Ltd.
56] Elastic Polymer-3: A composite elastic polymer of a polyorganosiloxane rubber component and a polyalkyl (meth) acrylate rubber component [METABRENE S-200 manufactured by Mitsubishi Rayon Co., Ltd.
1] Component d-1 Phosphite: Trisnonylphenylphosphite d-2 Component Phosphate: Trimethyl phosphate Colorant Colorant-1: Perinone red dye [Arimoto Chemical Industry Co., Ltd.]
Plastread 8370] Colorant-2: Carbon black [Mitsubishi Kasei Co., Ltd. MA
-100]
【００３１】[0031]
【表１】 [Table 1]
【００３２】[0032]
【表２】 [Table 2]
【００３３】[0033]
【表３】 [Table 3]
【００３４】[0034]
【発明の効果】本発明の芳香族ポリカーボネート樹脂組
成物は、基板が芳香族ポリカーボネート樹脂である不用
なコンパクトディスクを、これに付着しているアルミ
膜、インク、ＵＶコート膜等を取り除かずにそのまま粉
砕し、再溶融成形して得られる流動性、耐衝撃性、耐熱
性の良好なメタリック調の外観を有するものであり、ま
た資源の有効利用ならびに環境保護の見地から、不用な
コンパクトディスクの再生利用に優れており、本発明の
奏する工業的効果は格別なものである。EFFECT OF THE INVENTION The aromatic polycarbonate resin composition of the present invention is used as it is, without removing the unnecessary compact disc whose substrate is an aromatic polycarbonate resin, without removing the aluminum film, ink, UV coating film and the like adhering thereto. It has a metallic appearance with good fluidity, impact resistance, and heat resistance obtained by crushing and remelting, and it is a waste compact disc reproduction from the viewpoint of effective use of resources and environmental protection. It is excellent in use and the industrial effect of the present invention is exceptional.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 // Ｂ２９Ｋ 69:00 105:26 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 6 Identification code Office reference number FI technical display area // B29K 69:00 105: 26
Claims (16)
ボネート樹脂であるコンパクトディスク粉砕化物１０〜
１００重量％（ａ−１成分）および（Ａ−２）芳香族ポ
リカーボネート樹脂９０〜０重量％（ａ−２成分）より
なる樹脂混合物（ａ成分）および（Ｂ）ジエンゴム成分
に芳香族ビニル化合物およびシアン化ビニル化合物をグ
ラフトした熱可塑性グラフト共重合体（ｂ成分）より実
質的になり、ａ成分とｂ成分との割合が重量比で１５：
８５〜９５：５の範囲である芳香族ポリカーボネート樹
脂組成物。1. A compact disc pulverized product 10 wherein (A) and (A-1) substrates are aromatic polycarbonate resins.
An aromatic vinyl compound and a resin mixture (component a) consisting of 100% by weight (a-1 component) and 90 to 0% by weight (A-2) aromatic polycarbonate resin (a-2 component) and (B) a diene rubber component. It substantially consists of a thermoplastic graft copolymer (b component) grafted with a vinyl cyanide compound, and the ratio of the a component to the b component is 15:
An aromatic polycarbonate resin composition in the range of 85 to 95: 5.
族ポリカーボネート樹脂であるコンパクトディスク粉砕
化物３０〜１００重量％（ａ−１成分）および芳香族ポ
リカーボネート樹脂７０〜０重量％（ａ−２成分）より
なる樹脂混合物である請求項１記載の芳香族ポリカーボ
ネート樹脂組成物。2. The resin mixture (a component) comprises 30 to 100% by weight of a compact disc pulverized product whose substrate is an aromatic polycarbonate resin (a-1 component) and 70 to 0% by weight of an aromatic polycarbonate resin (a-). The aromatic polycarbonate resin composition according to claim 1, which is a resin mixture comprising two components).
０：７０〜８５：１５の範囲である請求項１記載の芳香
族ポリカーボネート樹脂組成物。3. The weight ratio of the component a and the component b is 3
The aromatic polycarbonate resin composition according to claim 1, which is in the range of 0:70 to 85:15.
００重量部に対して、（Ｄ）亜燐酸エステル（ｄ−１成
分）および／または燐酸エステル（ｄ−２成分）を０.
００５〜２.０重量部さらに含有した請求項１記載の芳
香族ポリカーボネート樹脂組成物。4. The aromatic polycarbonate resin composition 1
The amount of (D) phosphite ester (d-1 component) and / or phosphoric acid ester (d-2 component) was 0.00 parts by weight based on 0.
The aromatic polycarbonate resin composition according to claim 1, further comprising 005 to 2.0 parts by weight.
樹脂組成物を成形して得られたメタリック調の外観を有
する成形品。5. A molded product having a metallic appearance obtained by molding the aromatic polycarbonate resin composition according to claim 1.
ボネート樹脂であるコンパクトディスク粉砕化物１０〜
１００重量％（ａ−１成分）および（Ａ−２）芳香族ポ
リカーボネート樹脂９０〜０重量％（ａ−２成分）より
なる樹脂混合物（ａ成分）および（Ｂ）ジエンゴム成分
に芳香族ビニル化合物およびシアン化ビニル化合物をグ
ラフトした熱可塑性グラフト共重合体（ｂ成分）よりな
り、ａ成分とｂ成分との割合が重量比で２０：８０〜９
５：５の範囲である熱可塑性樹脂成分およびその樹脂成
分１００重量部に対して（Ｃ）弾性重合体１〜１０重量
部（ｃ成分）より実質的になる芳香族ポリカーボネート
樹脂組成物。6. A compact disc pulverized product (A) (A-1), wherein the substrate is an aromatic polycarbonate resin.
An aromatic vinyl compound and a resin mixture (component a) consisting of 100% by weight (a-1 component) and 90 to 0% by weight (A-2) aromatic polycarbonate resin (a-2 component) and (B) a diene rubber component. It is composed of a thermoplastic graft copolymer (b component) grafted with a vinyl cyanide compound, and the ratio of the a component to the b component is 20:80 to 9 by weight.
An aromatic polycarbonate resin composition consisting essentially of 1 to 10 parts by weight of the (C) elastic polymer (component c) per 100 parts by weight of the thermoplastic resin component and the resin component in the range of 5: 5.
族ポリカーボネート樹脂であるコンパクトディスク粉砕
化物３０〜１００重量％（ａ−１成分）および芳香族ポ
リカーボネート樹脂７０〜０重量％（ａ−２成分）より
なる樹脂混合物である請求項６記載の芳香族ポリカーボ
ネート樹脂組成物。7. The resin mixture (a component) comprises 30 to 100% by weight (a-1 component) of a compacted disc pulverized product whose substrate is an aromatic polycarbonate resin and 70 to 0% by weight (a-) of an aromatic polycarbonate resin. The aromatic polycarbonate resin composition according to claim 6, which is a resin mixture composed of two components).
０：５０〜９０：１０の範囲である請求項６記載の芳香
族ポリカーボネート樹脂組成物。8. The weight ratio of the component a to the component b is 5.
The aromatic polycarbonate resin composition according to claim 6, which is in the range of 0:50 to 90:10.
て、（Ｃ）弾性重合体２〜８重量部である請求項６記載
の芳香族ポリカーボネート樹脂組成物。9. The aromatic polycarbonate resin composition according to claim 6, wherein (C) the elastic polymer is 2 to 8 parts by weight with respect to 100 parts by weight of the thermoplastic resin component.
して、（Ｄ）亜燐酸エステル（ｄ−１成分）および／ま
たは燐酸エステル（ｄ−２成分）を０.００５〜２.０重
量部さらに含有した請求項６記載の芳香族ポリカーボネ
ート樹脂組成物。10. The phosphite ester (d-1 component) and / or the phosphoric acid ester (d-2 component) (D) is 0.005-2.0 parts by weight with respect to 100 parts by weight of the thermoplastic resin component. The aromatic polycarbonate resin composition according to claim 6, which further contains.
ト樹脂組成物を成形して得られたメタリック調の外観を
有する成形品。11. A molded product having a metallic appearance, which is obtained by molding the aromatic polycarbonate resin composition according to claim 6.
ーボネート樹脂であるコンパクトディスク粉砕化物１０
〜１００重量％（ａ−１成分）および（Ａ−２）芳香族
ポリカーボネート樹脂９０〜０重量％（ａ−２成分）よ
りなる樹脂混合物（ａ成分）およびその樹脂混合物１０
０重量部に対して、（Ｃ）弾性重合体３〜２０重量部
（ｃ成分）より実質的になる芳香族ポリカーボネート樹
脂組成物。12. A compact disc pulverized product 10 wherein (A) and (A-1) substrates are aromatic polycarbonate resins.
To 100% by weight (a-1 component) and (A-2) aromatic polycarbonate resin 90 to 0% by weight (a-2 component), a resin mixture (a component) and the resin mixture 10
An aromatic polycarbonate resin composition consisting essentially of 3 to 20 parts by weight of (C) elastic polymer (component c) per 0 parts by weight.
香族ポリカーボネート樹脂であるコンパクトディスク粉
砕化物３０〜１００重量％（ａ−１成分）および芳香族
ポリカーボネート樹脂７０〜０重量％（ａ−２成分）よ
りなる樹脂混合物である請求項１２記載の芳香族ポリカ
ーボネート樹脂組成物。13. The resin mixture (a component) comprises 30 to 100% by weight of a compact disc pulverized product whose substrate is an aromatic polycarbonate resin (a-1 component) and 70 to 0% by weight of an aromatic polycarbonate resin (a-). The aromatic polycarbonate resin composition according to claim 12, which is a resin mixture consisting of two components).
（Ｃ）弾性重合体５〜１０重量部である請求項１２記載
の芳香族ポリカーボネート樹脂組成物。14. Based on 100 parts by weight of the resin mixture,
13. The aromatic polycarbonate resin composition according to claim 12, which is 5 to 10 parts by weight of the elastic polymer (C).
（Ｄ）亜燐酸エステル（ｄ−１成分）および／または燐
酸エステル（ｄ−２成分）を０.００５〜２.０重量部さ
らに含有した請求項１２記載の芳香族ポリカーボネート
樹脂組成物。15. Based on 100 parts by weight of the resin mixture,
The aromatic polycarbonate resin composition according to claim 12, further comprising 0.005 to 2.0 parts by weight of (D) a phosphite ester (d-1 component) and / or a phosphite ester (d-2 component).
ート樹脂組成物を成形して得られたメタリック調の外観
を有する成形品。16. A molded product having a metallic appearance, which is obtained by molding the aromatic polycarbonate resin composition according to claim 12.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11743095A JP3442534B2 (en) | 1995-05-16 | 1995-05-16 | Aromatic polycarbonate resin composition and molded article |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11743095A JP3442534B2 (en) | 1995-05-16 | 1995-05-16 | Aromatic polycarbonate resin composition and molded article |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH08311326A true JPH08311326A (en) | 1996-11-26 |
| JP3442534B2 JP3442534B2 (en) | 2003-09-02 |
Family
ID=14711457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11743095A Expired - Fee Related JP3442534B2 (en) | 1995-05-16 | 1995-05-16 | Aromatic polycarbonate resin composition and molded article |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3442534B2 (en) |
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|---|---|---|---|---|
| WO1998049238A1 (en) * | 1997-04-28 | 1998-11-05 | Basf Aktiengesellschaft | Use of recycled cd material as an additive for glitter dyes |
| JP2001049108A (en) * | 1999-08-11 | 2001-02-20 | Teijin Chem Ltd | Flame-retarded resin composition and molded product comprising the same |
| WO2001072900A1 (en) * | 2000-03-28 | 2001-10-04 | Teijin Chemicals, Ltd. | Reclaimed resin composition |
| JP2002265798A (en) * | 2001-03-09 | 2002-09-18 | Teijin Chem Ltd | Recycled resin composition |
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1995
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998049238A1 (en) * | 1997-04-28 | 1998-11-05 | Basf Aktiengesellschaft | Use of recycled cd material as an additive for glitter dyes |
| JP2001049108A (en) * | 1999-08-11 | 2001-02-20 | Teijin Chem Ltd | Flame-retarded resin composition and molded product comprising the same |
| KR100718853B1 (en) * | 2000-03-28 | 2007-05-16 | 데이진 가세이 가부시키가이샤 | Reclaimed resin composition |
| WO2001072900A1 (en) * | 2000-03-28 | 2001-10-04 | Teijin Chemicals, Ltd. | Reclaimed resin composition |
| US7045555B2 (en) | 2000-03-28 | 2006-05-16 | Teijin Chemicals Ltd. | Regenerated resin composition |
| JP2002265798A (en) * | 2001-03-09 | 2002-09-18 | Teijin Chem Ltd | Recycled resin composition |
| JP2004238613A (en) * | 2003-01-17 | 2004-08-26 | Teijin Chem Ltd | Reclaimed resin composition, molded product of the same, method for producing the reclaimed resin composition and method for reusing the molded product |
| JP4571392B2 (en) * | 2003-01-17 | 2010-10-27 | 帝人化成株式会社 | Recycled resin composition and molded product thereof, method for producing recycled resin composition, and method for reusing molded product |
| JP2004352762A (en) * | 2003-05-27 | 2004-12-16 | Idemitsu Petrochem Co Ltd | Recycled aromatic polycarbonate resin composition and method for producing the same and injection-molded article |
| JP2005008816A (en) * | 2003-06-20 | 2005-01-13 | Idemitsu Petrochem Co Ltd | Reclaimed polycarbonate resin composition, its manufacturing process, and injection molded product of the same |
| JP2006192748A (en) * | 2005-01-14 | 2006-07-27 | Fujimori Kogyo Co Ltd | Regeneration method of aluminum foil-containing multilayered film and manufacturing method of regenerated product using it |
| JP4563190B2 (en) * | 2005-01-14 | 2010-10-13 | 藤森工業株式会社 | Reproduction method of multilayer film containing aluminum foil and production method of reproduction product using the same |
| JP2007002129A (en) * | 2005-06-24 | 2007-01-11 | Sony Corp | Resin composition |
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