JPH08290512A - Non-skid base sheet - Google Patents

Non-skid base sheet

Info

Publication number
JPH08290512A
JPH08290512A JP12442195A JP12442195A JPH08290512A JP H08290512 A JPH08290512 A JP H08290512A JP 12442195 A JP12442195 A JP 12442195A JP 12442195 A JP12442195 A JP 12442195A JP H08290512 A JPH08290512 A JP H08290512A
Authority
JP
Japan
Prior art keywords
foam
base
coating layer
base material
resin composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP12442195A
Other languages
Japanese (ja)
Inventor
Hideo Yuhi
英雄 由肥
Hiroaki Mihashi
弘明 三橋
Akira Kawabata
昭 川端
Takashi Tomonaga
隆 友永
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ASAHI KAKO KK
Original Assignee
ASAHI KAKO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ASAHI KAKO KK filed Critical ASAHI KAKO KK
Priority to JP12442195A priority Critical patent/JPH08290512A/en
Publication of JPH08290512A publication Critical patent/JPH08290512A/en
Pending legal-status Critical Current

Links

Landscapes

  • Laminated Bodies (AREA)
  • Carpets (AREA)

Abstract

PURPOSE: To provide a non-skid sheet base laminated with a foam-contg. elastic coating layer consisting of a thermosetting resin compsn. incorporated with a heat expandable foamed body. CONSTITUTION: On one or both of faces of a base material such as a woven fabric, a knitted fabric and a non-woven fabric, a foam-contg. elastic coating layer is laminated with a thermo-setting resin compsn. prepd. by compounding a chlorosulfonated polyethylene as a main component and an NBR, an SBR, etc., for improving adhesiveness with the base material. Therefore, a non-skid effect with elasticity, light and soft touch and excellent adhesiveness to the base fabric is exhibited, it is suitable for a non-skid base sheet, etc., for furnitures mats, etc. In addition, problems of the conventional foam-contg. elastic bodies such as fluctuation of foaming, inferior durability as well as yellowing and discoloring of a formed film can be improved.

Description

【発明の詳細な説明】Detailed Description of the Invention

【産業上の利用分野】本発明は滑り止め基材シ−トに関
し、弾力性を有し軽くてソフト感触でかつ基布との接着
性がすぐれた家具、マット、テ−ブルクロス、鞄材等に
好適に用いられる滑り止め基材シ−トに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a non-slip base sheet, which is a furniture, a mat, a table cloth, a bag material, etc. having elasticity, lightness, soft feel and excellent adhesion to a base cloth. The present invention relates to a non-slip base sheet suitable for use in.

【0002】[0002]

【従来の技術】従来、滑り止め基材としては、塩化ビニ
−ル樹脂或いはアクリル系樹脂、ポリウレタン系樹脂等
のいわゆるソフトタイプの粘着度の強い樹脂を織物、編
物、紙等に塗布またはプリントし、裏面に粘着性を持っ
た材料による防滑加工、摩擦係数の大きいゴム様柔軟
材、或いは発泡シ−トや樹脂ラテックスで被覆したシ−
ト材料等を用い、シ−ト材料の摩擦抵抗を増大させる加
工等が行なわれている。
2. Description of the Related Art Conventionally, as a non-slip base material, a so-called soft type resin having strong adhesiveness such as vinyl chloride resin, acrylic resin, polyurethane resin or the like is applied or printed on woven fabric, knitted fabric, paper or the like. , Anti-slip processing on the back surface with a material with adhesiveness, rubber-like soft material with a large friction coefficient, or a sheet coated with foamed sheet or resin latex
For example, processing for increasing the friction resistance of the sheet material is performed by using the sheet material or the like.

【0003】[0003]

【発明の解決しようとする課題】これらの発泡体シ−ト
等では、滑り止め効果が低く、被覆層自体の強度や堅牢
性が劣り、かつ嵩高である為その用途やサイズ等が限ら
れ、また、外圧によって破壊し易く、重い家具や鞄材等
に用いられた場合、本来の形態が崩れてしまう難点があ
った。また、鞄やそれらの肩掛けベルト等に使用された
場合、強い表面摩擦や圧縮強度が加えられる結果、発泡
体が破壊され易く、滑り止めや止着効果が著しく減殺さ
れる欠点があった。このように、特に発泡体シ−トで
は、一般に変形に対する自由度が高く、その表面に凹凸
状態を形成し易い複雑な表面を有するため摩擦抵抗が高
いとはいえ、被覆層自体の堅牢性が劣り、さらに風合い
洗濯適性や経時変化が劣るといった難点があった。本発
明は、織布、編布又は不織布、フェルト等からなる基材
の少なくとも片面に、加熱で膨張する発泡体を添加した
熱硬化性樹脂組成物からなる含泡弾性被覆層を積層した
ことを特徴とする滑り止め基材シ−トを提供することを
第一の目的としている。また、本発明の第二の目的は、
弾力性を有し軽くてソフトタッチでかつ基布との接着性
のすぐれた含泡弾性被覆層を積層した滑り止め基材シ−
トを工業的有利に得ることにある。
In these foam sheets and the like, the anti-slip effect is low, the strength and toughness of the coating layer itself is poor, and the volume is bulky, so that its use and size are limited. In addition, it is easily broken by external pressure, and when used for heavy furniture, bags, etc., there is a problem in that the original shape is lost. In addition, when it is used for a bag or shoulder belts thereof, strong foam friction and compressive strength are added, and as a result, the foam is easily broken, and the slip resistance and the fastening effect are significantly reduced. As described above, in particular, the foam sheet has a high degree of freedom with respect to deformation and has a high friction resistance because it has a complicated surface on which irregularities are easily formed, but the robustness of the coating layer itself is high. Inferiority, and further, there was a problem in that it was inferior in texture washability and deterioration over time. The present invention provides that a foam-containing elastic coating layer made of a thermosetting resin composition containing a foam that expands by heating is laminated on at least one surface of a base material made of woven cloth, knitted cloth or non-woven cloth, felt or the like. The first object is to provide a characteristic non-slip base sheet. The second object of the present invention is to
A non-slip base sheet that is laminated with a foam-containing elastic coating layer that is elastic, light, soft-touch, and has excellent adhesion to the base fabric.
To obtain industrial advantages.

【0004】[0004]

【課題を解決するための手段】上記目的を達成するた
め、本発明では発泡体の強度を高くし、一方、発泡倍率
を可及的低く抑制しようとするものである。すなわちシ
−ト面上に形成する発泡体は、織物や編物の凹部に多量
に層着し、かつ凸部の表面に飛び出さないようにコ−テ
ィング剤を塗工し、さらにコ−ティングされた樹脂(ゴ
ム)の表面は適度な硬さを保持できるとの知見にもとづ
き、これらの組み合わせにかかる工程結合を解決課題の
手段とするものである。このため、本発明においては、
加熱膨張せしめる発泡体を含有する含泡弾性被覆層を積
層する熱硬化性樹脂組成物には、主体としてゴム類、特
に熱硬化性合成ゴムのうち、クロロスルホン化ポリエチ
レンを採用し、さらに該クロロスルホン化ポリエチレン
に、NR、SBR、BR、NBR、VMQ、MQ、CR
等より選ばれた一種又は二種以上が配合されたものを用
いることができる。該クロロスルフォン化ポリエチレン
は従来のゴム類にみられる熱や光に対して黄変しない、
薬品に対する抵抗力がある等のすぐれた性能特性を有し
ている。また屋内で使用される場合は、一般の合成ゴム
類と併用し、基布との接着効果を上げたり、風合い等の
表面効果を出したりすることができる。
In order to achieve the above object, the present invention intends to increase the strength of the foam and, at the same time, to suppress the expansion ratio as low as possible. That is, the foam formed on the sheet surface is layered in a large amount in the recesses of the woven fabric or knit and is coated with a coating agent so as not to jump out to the surface of the protrusions, and further coated. Based on the knowledge that the surface of a resin (rubber) can maintain an appropriate hardness, the process bonding relating to these combinations is used as a means for solving the problem. Therefore, in the present invention,
In the thermosetting resin composition for laminating the foam-containing elastic coating layer containing the foam to be heated and expanded, chlorosulfonated polyethylene is adopted as the main component of rubbers, especially thermosetting synthetic rubber, and NR, SBR, BR, NBR, VMQ, MQ, CR on sulfonated polyethylene
It is possible to use one or a mixture of two or more selected from the above. The chlorosulphonated polyethylene does not yellow to the heat and light found in conventional rubbers,
It has excellent performance characteristics such as resistance to chemicals. When it is used indoors, it can be used in combination with general synthetic rubbers to enhance the adhesive effect with the base cloth and to provide surface effects such as texture.

【0005】そして、本発明においては、熱硬化性合成
ゴム、クロロスルフォン化ポリエチレンを主体とし、基
材との接着性をあげるため、NBRやSBR、ポリブテ
ン等をブレンドして耐摩耗性や耐衝撃性を向上させるこ
とができる。また、熱硬化性樹脂組成物において加熱膨
張するマイクロカプセルは0.1〜20重量%、2〜2
0μmを用いることができ、炭酸カルシウム10〜90
重量%、その他の添加剤を配合することができる。さら
に、熱発泡開始温度が50〜230℃、好ましくは比較
的低い50〜160℃のものを選んで、表面に発泡体が
集中することなくゴム塗布層を均一に発泡させる。さら
に、塗布面は目的に合わせて、基布の片面或いは両面に
塗布する水の浸透を防止する目的で基布に撥水加工を施
すこともできる。また、熱硬化性樹脂組成物の塗布量は
30〜500g以下が適当である。さらに、前記前記熱
硬化性樹脂組成物を用い、グラビアロ−ル法等によりコ
−ティングし、乾燥、熱処理を行なうことにより、比較
的凸部高さの均等な止着性のすぐれた突起状体からなる
含泡弾性被覆層を点在突設せしめることができる。
In the present invention, thermosetting synthetic rubber and chlorosulphonated polyethylene are mainly used, and NBR, SBR, polybutene, etc. are blended in order to improve the adhesiveness to the base material, so that abrasion resistance and impact resistance are improved. It is possible to improve the sex. In the thermosetting resin composition, the heat-expandable microcapsules are 0.1 to 20% by weight, 2 to 2%.
0 μm can be used, and calcium carbonate 10 to 90
% By weight, and other additives can be added. Furthermore, a material having a thermal foaming initiation temperature of 50 to 230 ° C., preferably a relatively low temperature of 50 to 160 ° C. is selected to uniformly foam the rubber coating layer without the foam being concentrated on the surface. Further, the coated surface may be subjected to a water repellent treatment for the purpose of preventing the permeation of water applied to one side or both sides of the base cloth depending on the purpose. The amount of the thermosetting resin composition applied is preferably 30 to 500 g or less. Further, by using the above-mentioned thermosetting resin composition, coating by a gravure roll method or the like, drying, and heat treatment, and thus a protrusion having a relatively uniform height and excellent fastening property. It is possible to make the foam-containing elastic coating layer consisting of (4) scattered.

【0006】[0006]

【作用】本発明の滑り止め基材シ−トは、弾力性を有
し、軽くてソフトタッチで、基布との接着性のすぐれた
含泡弾性被覆層を積層したものである為、家具、マッ
ト、テ−ブルクロス、鞄材等に好適に用いられる滑り止
め基材シ−トを提供するように働く。また、従来、含発
泡弾性体では、マイクロカプセルによる発泡むら、熱処
理後の窪み陥落現象、或いは黄褐変色や造膜の耐久性が
劣る等の難点がみられるが、本発明の基材シ−トでは、
発泡体の強度、発泡倍率及び塗工、さらに表面硬度の各
工程での特定及び組み合わせにより、これらの難点を解
消できるように働く。
The non-slip base sheet of the present invention is a laminate of a foam-containing elastic coating layer having elasticity, lightness and soft touch, and excellent adhesiveness to a base cloth. , A mat, a table cloth, a bag material, and the like, which serve to provide a non-slip base sheet suitable for use. Further, conventionally, in the foam-containing elastic body, although there are drawbacks such as foaming unevenness due to microcapsules, dent depression phenomenon after heat treatment, yellowish brown discoloration and poor durability of film formation, the base sheet of the present invention In the
By identifying and combining the strength, foaming ratio, coating, and surface hardness of the foam in each step, these problems can be solved.

【0007】[0007]

【実施例】以下実施例を挙げて説明する。 実施例1 ポリアミド,420デニ−ル,密度53×33を用い、
まず、基布の両面に下記配合液を塗布する。次に、ドク
タ−ナイフを用い、フロ−ティング方式で塗工する。塗
布量は30〜100g/m2 (固形分)であった。次い
で、乾燥温度、110〜120℃で2分間で熱処理を兼
ねて実施した。さらに、ファッション性や美感を出すた
めにパステル調のベ−ジュ色に着色した。 熱硬化性樹脂組成物配合 以下数字はいずれも重量部を示す。 ハイパロン#20(デュポン社) 20 〜 30 ステアリン酸 0.6〜1.0 白菊ロジン 0.6〜1.0 トルエン 60 〜100 トリマレ#77(三塩基性マレイン酸鉛) 10 〜 15 キュアリング5K(架橋促進剤) 1 〜1.5 コスモネ−トM−200 2 〜 10 NCC410(堺化学,炭酸カルシウム) 10 〜 40 SZ,ブラウン7010(大日精化) 3 〜 5 ディクトンホワイトA5260 5 〜 20 (大日本インキ,酸化チタン) 上記処理によって得られた基材シ−トは、適度の柔軟
性、撥水性と併せ、乾湿度条件の耐久性並びに洗濯適性
を有し、表面摩擦では、滑動開始角度は約40度であ
り、被支持体に摩擦接触して支持体と被支持体の間の滑
りを防止し、好ましい滑り防止効果が得られた。また、
市販品ゴム引布と比べて化学的に安定しており、熱や光
に対して黄褐変がみられないので、窓際などの太陽光の
射し込みにも耐久性を有し、たとえば室内用マットやテ
−ブルクロス等の日用品の用途に適している。なお、表
面摩擦は表面平滑な台板上に10cm×10cmの試料
を取り付け、その上に天秤分銅の300gを置き台板を
傾斜させたときの滑動開始角度を測定することにより行
った。
EXAMPLES Examples will be described below. Example 1 Polyamide, 420 denier, density 53 × 33,
First, the following formulation liquid is applied to both sides of the base cloth. Next, using a doctor knife, coating is performed by a floating method. The coating amount was 30 to 100 g / m 2 (solid content). Then, it was performed at a drying temperature of 110 to 120 ° C. for 2 minutes while also performing a heat treatment. Furthermore, it was colored in pastel beige for fashion and beauty. Blending of thermosetting resin composition All the numbers below indicate parts by weight. Hypalon # 20 (DuPont) 20-30 Stearic acid 0.6-1.0 Shiragiku rosin 0.6-1.0 Toluene 60-100 Trimale # 77 (tribasic lead maleate) 10-15 Curing 5K ( Crosslinking accelerator) 1 to 1.5 Cosmonate M-200 2 to 10 NCC410 (Sakai chemistry, calcium carbonate) 10 to 40 SZ, Brown 7010 (Dainichiseika) 3 to 5 Dictone White A52605 to 20 (Dai Nippon) Ink, titanium oxide) The substrate sheet obtained by the above treatment has appropriate flexibility and water repellency as well as durability under dry and humidity conditions and washing suitability. The angle was 40 degrees, which prevented frictional contact with the supported body to prevent slippage between the supported body and the supported body, and a preferable anti-slip effect was obtained. Also,
It is more chemically stable than commercially available rubberized fabrics and does not show yellowing to heat or light, so it has durability even when exposed to sunlight, such as at the window, and for example indoor mats and Suitable for daily use such as table cloth. The surface friction was measured by mounting a 10 cm × 10 cm sample on a flat base plate, placing 300 g of a balance weight on the base plate, and measuring the sliding start angle when the base plate was tilted.

【0008】実施例2 ポリエステル不織布160g/m2 を用い、基布の片面
に下記配合物を塗布し次にロ−ルオンナイフ方式を用い
て塗工した。塗布量は、60〜150g/m2(固形
分)であった。次いで、乾燥温度110〜130℃で3
〜4分乾燥した。 熱硬化性樹脂組成物配合 ハイパロン#20(デュポン社) 10 〜15重量部 ステアリン酸 0.3〜0.5 白菊ロジン 0.3〜0.5 トルエン 30 〜 60 マツモトマイクロスフェアF30D(松本油脂) 3 〜 10 アディナタブLA−63P 1 〜 3 ディクトンホワイト7387(酸化チタン) 3 〜 10 ディクトンID−A5348(顔料) 1 〜 3 MEK 20 〜 40 DN206(NBR) 20 〜 40 ニップシ−ルVN−3 18 〜 36 ZnO#1(亜鉛華) 1 〜 2 ステアリン酸 0.4〜 0.6 ロ−ボ−RD(老化防止剤) 0.8〜 1.2 DOP(可塑剤) 4 〜 9 硫黄 0.4〜 0.6 ノワクセラ−TT(大内化学,加硫促進剤) 0.3〜 0.5 同 上 CZ( 〃 ) 0.4〜 0.6 同 上 TE( 〃 ) 0.6〜 0.9 NCC410(堺化学,炭酸カルシウム) 10 〜 30 上記処理によって得られた基材シ−トは、適度の柔軟性
を有し、熱硬化性樹脂組成物にNBRを配合しており、
基布との接着性並びに耐水性の改善を図ることができ
る。また、表面摩擦では、滑動開始角度は40〜45度
であり、好ましい滑り防止効果が得られた。このため、
玄関マット等の他、椅子クッションや屋外携帯時も多い
鞄肩吊りベルト裏側接触箇所等の用途に適している。
Example 2 Using a polyester nonwoven fabric of 160 g / m 2 , one side of a base fabric was coated with the following composition and then coated by a roll-on knife system. The coating amount was 60 to 150 g / m 2 (solid content). Then, at a drying temperature of 110 to 130 ° C., 3
Dry for ~ 4 minutes. Thermosetting resin composition blended Hypalon # 20 (DuPont) 10 to 15 parts by weight Stearic acid 0.3 to 0.5 Shiragiku rosin 0.3 to 0.5 Toluene 30 to 60 Matsumoto Microsphere F30D (Matsumoto Yushi) 3 -10 Adinatab LA-63P1-3 Dictone White 7387 (titanium oxide) 3-10 Dictone ID-A5348 (pigment) 1-3 MEK20-40 DN206 (NBR) 20-40 Nipsil VN-318-36 ZnO # 1 (zinc white) 1-2 stearic acid 0.4-0.6 Robo-RD (anti-aging agent) 0.8-1.2 DOP (plasticizer) 4-9 sulfur 0.4-0. 6 Nowaxera-TT (Ouchi Chemical, vulcanization accelerator) 0.3 to 0.5 Same as above CZ (〃) 0.4 to 0.6 Same as above TE (〃) 0.6 to 0.9 NCC410 (Sakai Chemistry, calcium carbonate) 10 to 30 The base sheet obtained by the above treatment has appropriate flexibility and contains NBR in the thermosetting resin composition.
It is possible to improve the adhesiveness with the base cloth and the water resistance. Further, in the surface friction, the sliding start angle was 40 to 45 degrees, and a preferable anti-slip effect was obtained. For this reason,
In addition to the entrance mats, it is also suitable for chair cushions and places where the shoulder straps on the back side of the bag often come in contact with the outside.

【0009】実施例3 ポリエステル・スパン織物を使用し、基布の片面に前記
実施例2と同じ配合の熱硬化性樹脂組成物によりコンマ
・コ−タ−を用いて塗工した。塗布量は50〜80g/
2 であった。乾燥温度120〜150℃で3〜5分間
乾燥を行った。上記処理によって得られた基材シ−ト
は、風合いがソフトタッチであり、また表面摩擦は滑動
開始角度は約45度であり、好ましい滑り防止効果が得
られた。さらに耐水性が強く、長時間にわたり水に濡れ
ても接着性が維持され剥離することがない特長を具えて
いる。このため素足で踏むソフトな感触が要求されると
共に、これを清潔に保つ為に頻繁な洗濯が必要なたとえ
ば風呂場入口の足ふきマットや玄関マット、花瓶等の室
内装置品の下敷きマット用として好適である。なお、本
発明の一実施例を示したが、本発明は上記した実施例に
限定されるものではなく、本発明の要旨を逸脱しない範
囲の設計変更等は本発明に含まれる。
Example 3 A polyester spun fabric was used, and one side of a base fabric was coated with a thermosetting resin composition having the same composition as in Example 2 using a comma coater. Application amount is 50-80g /
m 2 . Drying was performed for 3 to 5 minutes at a drying temperature of 120 to 150 ° C. The base sheet obtained by the above treatment had a soft touch to the touch and a sliding start angle of about 45 degrees in terms of surface friction, and a favorable anti-slip effect was obtained. In addition, it has strong water resistance and has the feature that it retains its adhesiveness and does not peel off even if it gets wet with water for a long time. For this reason, a soft feel of stepping on bare feet is required, and frequent washing is required to keep it clean.For example, for underlay mats for indoor equipment such as bathing mats, entrance mats, vases, etc. It is suitable. Although one embodiment of the present invention has been shown, the present invention is not limited to the above-described embodiment, and design changes and the like within the scope not departing from the gist of the present invention are included in the present invention.

【0010】[0010]

【発明の効果】本発明の滑り止め基材シ−トは、弾力性
を有し、軽くてソフトタッチで、基布に対してすぐれた
接着性を有すると共に、好ましい滑り防止効果を発揮す
ることができるため、家具、マット、テ−ブルクロス、
鞄材等の滑り止めその他の基材シ−トとして好適であ
る。また、従来、含発泡弾性体ではマイクロカプセルに
よる発泡むら、造膜の耐久性が劣る他、黄褐変色等の難
点がみられるが、本発明の含泡弾性被覆層の構成では、
発泡体の耐久性の補強ならびに黄褐変色等を改善するこ
とができる等の効果を奏する。
EFFECT OF THE INVENTION The non-slip base sheet of the present invention has elasticity, is light and soft-touch, has excellent adhesiveness to a base cloth, and exhibits a preferable anti-slip effect. Furniture, mats, table cloths,
It is suitable as a non-slip base material sheet such as a bag material. In addition, conventionally, in the foam-containing elastic body, uneven foaming by microcapsules, inferior durability of film formation, and other problems such as yellowish brown discoloration are observed, but in the structure of the foam-containing elastic coating layer of the present invention,
The effect of reinforcing the durability of the foam and improving the yellowish brown discoloration can be obtained.

─────────────────────────────────────────────────────
─────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成7年11月2日[Submission date] November 2, 1995

【手続補正1】[Procedure Amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0007[Correction target item name] 0007

【補正方法】追加[Correction method] Added

【補正内容】[Correction content]

【0007】[0007]

【実施例】以下実施例を挙げて説明する。 実施例1 ポリアミド,420デニール,密度53×33を用い、
まず、基布の両面に下記配合液を塗布する。次に、ドク
ターナイフを用い、フローティング方式で塗工する。塗
布量は30〜100g/m(固形分)であった。次い
で、乾燥温度、110〜120℃で2分間で熱処理を兼
ねて実施した。さらに、ファッション性や美感を出すた
めにパステル調のベージュ色に着色した。 熱硬化性樹脂組成物配合 以下数字はいずれも重量部を示す。 ハイパロン#20(デュポン社) 20 〜 30 ステアリン酸 0.6〜1.0 白菊ロジン 0.6〜1.0 トルエン 60 〜100 トリマレ#77(三塩基性マレイン酸鉛) 10 〜 15 キュアリング5K(架橋促進剤) 1 〜1.5 コスモネートM−200 2 〜 10 NCC410(堺化学,炭酸カルシウム) 10 〜 40 SZ,ブラウン7010(大日精化) 3 〜 5 ディクトンホワイトA5260 5 〜 20 (大日本インキ,酸化チタン) マツモト マイクロスフェアーF−50 3 〜 10 上記処理によって得られた基材シートは、適度の柔軟
性、撥水性と併せ、乾湿度条件の耐久性並びに洗濯適性
を有し、表面摩擦では、滑動開始角度は約40度であ
り、被支持体に摩擦接触して支持体と被支持体の間の滑
りを防止し、好ましい滑り防止効果が得られた。また、
市販品ゴム引布と比べて化学的に安定しており、熱や光
に対して黄褐変がみられないので、窓際などの太陽光の
射し込みにも耐久性を有し、たとえば室内用マットやテ
ーブルクロス等の日用品の用途に適している。なお、表
面摩擦は表面平滑な台板上に10cm×10cmの試料
を取り付け、その上に天秤分銅の300gを置き台板を
傾斜させたときの滑動開始角度を測定することにより行
った。
EXAMPLES Examples will be described below. Example 1 Polyamide, 420 denier, density 53 × 33,
First, the following formulation liquid is applied to both sides of the base cloth. Next, using a doctor knife, coating is carried out in a floating manner. The coating amount was 30 to 100 g / m 2 (solid content). Next, it was performed at a drying temperature of 110 to 120 ° C. for 2 minutes while also serving as a heat treatment. In addition, it is colored in pastel beige for fashion and beauty. Blending of thermosetting resin composition All the numbers below indicate parts by weight. Hypalon # 20 (DuPont) 20-30 Stearic acid 0.6-1.0 Shiragiku rosin 0.6-1.0 Toluene 60-100 Trimale # 77 (tribasic lead maleate) 10-15 Curing 5K ( Crosslinking accelerator) 1 to 1.5 Cosmonate M-200 2 to 10 NCC410 (Sakai chemistry, calcium carbonate) 10 to 40 SZ, Brown 7010 (Dainichiseika) 3 to 5 Dikton White A52605 to 20 (Dainippon Ink) , Titanium oxide) Matsumoto Microsphere F-50 3-10 The base sheet obtained by the above treatment has appropriate flexibility and water repellency as well as durability under dry and humidity conditions and washing suitability, and surface friction. Has a sliding start angle of about 40 degrees, and prevents frictional contact with the supported body to prevent slipping between the supported body and a preferable sliding state. Prevention effect was obtained. Also,
It is more chemically stable than commercially available rubberized fabrics and does not show yellowing to heat or light, so it has durability even when exposed to sunlight, such as at the window, and for example indoor mats and Suitable for daily use such as table cloths. The surface friction was measured by mounting a 10 cm × 10 cm sample on a flat base plate, placing 300 g of a balance weight on the base plate, and measuring the sliding start angle when the base plate was tilted.

【手続補正書】[Procedure amendment]

【提出日】平成8年2月16日[Submission date] February 16, 1996

【手続補正2】[Procedure Amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0005[Name of item to be corrected] 0005

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0005】そして、本発明においては、熱硬化性合成
ゴム、クロロスルフォン化ポリエチレンを主体とし、基
材との接着性をあげるため、NBRやSBR、ポリブテ
ン等をブレンドして耐摩耗性や耐衝撃性を向上させるこ
とができる。また、熱硬化性樹脂組成物において加熱膨
張するマイクロカプセルは0.1〜20重量%、2〜2
0μmを用いることができ、炭酸カルシウム10〜90
重量%、その他の添加剤を配合することができる。さら
に、熱発泡開始温度が50〜230℃、好ましくは比較
的低い50〜160℃のものを選んで、表面に発泡体が
集中することなくゴム塗布層を均一に発泡させる。さら
に、塗布面は目的に合わせて、基布の片面或いは両面に
塗布する水の浸透を防止する目的で基布に撥水加工を施
すこともできる。また、熱硬化性樹脂組成物の塗布量は
30〜500g以下が適当である。さらに、前記熱硬化
性樹脂組成物を用い、グラビアロール法等によりコーテ
ィングし、乾燥、熱処理を行なうことにより、比較的凸
部高さの均等な止着性のすぐれた突起状体からなる含泡
弾性被覆層を点在突設せしめることができる。
In the present invention, thermosetting synthetic rubber and chlorosulphonated polyethylene are mainly used, and NBR, SBR, polybutene, etc. are blended in order to improve the adhesiveness to the base material, so that abrasion resistance and impact resistance are improved. It is possible to improve the sex. In the thermosetting resin composition, the heat-expandable microcapsules are 0.1 to 20% by weight, 2 to 2%.
0 μm can be used, and calcium carbonate 10 to 90
% By weight, and other additives can be added. Furthermore, a material having a thermal foaming initiation temperature of 50 to 230 ° C., preferably a relatively low temperature of 50 to 160 ° C. is selected to uniformly foam the rubber coating layer without the foam being concentrated on the surface. Further, the coated surface may be subjected to a water repellent treatment for the purpose of preventing the permeation of water applied to one side or both sides of the base cloth depending on the purpose. The amount of the thermosetting resin composition applied is preferably 30 to 500 g or less. Further, by using the thermosetting resin composition, coating by a gravure roll method, etc., and drying and heat treatment, thereby forming a foam-containing protrusion having a relatively uniform height and excellent adhesion. The elastic coating layer can be provided so as to be scattered.

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 織布、編布又は不織布、フェルト等から
なる基材の少なくとも片面に、加熱で膨張する発泡体を
添加した熱硬化性樹脂組成物からなる含泡弾性被覆層を
積層したことを特徴とする滑り止め基材シ−ト。
1. A foam-containing elastic coating layer made of a thermosetting resin composition containing a foam expandable by heating is laminated on at least one surface of a base material made of woven cloth, knitted cloth or non-woven cloth, felt or the like. A non-slip base material sheet characterized by:
【請求項2】 前記樹脂組成物の主成分が、クロロスル
フォン化ポリエチレン又はクロロスルフォン化ポリエチ
レンにNR、SBR等より選ばれた一種又は二種以上を
配合したものである請求項1記載の滑り止め基材シ−
ト。
2. The non-slip material according to claim 1, wherein the main component of the resin composition is chlorosulfonated polyethylene or chlorosulfonated polyethylene mixed with one or more selected from NR and SBR. Base material
To.
【請求項3】 前記熱硬化性樹脂組成物により、互いに
間隔をおいて分布され且つ比較的均等な凸部高さの突起
状体からなる含泡弾性被覆層を点在突設せしめてなる請
求項1又は2記載の滑り止め基材シ−ト。 【0001】
3. A foam-containing elastic coating layer formed by the thermosetting resin composition, which is formed of protrusions which are distributed at intervals and have relatively uniform convex heights. Item 3. The non-slip base sheet according to item 1 or 2. [0001]
JP12442195A 1995-04-25 1995-04-25 Non-skid base sheet Pending JPH08290512A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12442195A JPH08290512A (en) 1995-04-25 1995-04-25 Non-skid base sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12442195A JPH08290512A (en) 1995-04-25 1995-04-25 Non-skid base sheet

Publications (1)

Publication Number Publication Date
JPH08290512A true JPH08290512A (en) 1996-11-05

Family

ID=14885072

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12442195A Pending JPH08290512A (en) 1995-04-25 1995-04-25 Non-skid base sheet

Country Status (1)

Country Link
JP (1) JPH08290512A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1309552C (en) * 2004-04-16 2007-04-11 微细科技股份有限公司 Method for producing foamed material with stereo convex grains using thermoplastic elastomer
CN110591592A (en) * 2019-09-25 2019-12-20 无锡旺绿鸿纺织品有限公司 Environment-friendly anti-slip strip-shaped foaming coating and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1309552C (en) * 2004-04-16 2007-04-11 微细科技股份有限公司 Method for producing foamed material with stereo convex grains using thermoplastic elastomer
CN110591592A (en) * 2019-09-25 2019-12-20 无锡旺绿鸿纺织品有限公司 Environment-friendly anti-slip strip-shaped foaming coating and preparation method thereof
JP2021049769A (en) * 2019-09-25 2021-04-01 無錫旺緑鴻紡織品有限公司 Environmentally friendly bar-like non-slip foam coating layer and method for producing the same

Similar Documents

Publication Publication Date Title
US6265082B1 (en) Fire retardant compositions and methods for their preparation and use
KR19980042003A (en) Foam structure
GB2048164A (en) Multilayer sheet structure suitable for use in making a wet suit and wet suit made thereof
US6921566B2 (en) Cushioned grip tape
US7833596B2 (en) Plastic floor covering and method for obtaining same
JPH0652006B2 (en) Floor tiles
US20060160449A1 (en) Moisture-absorbing, quick drying, thermally insulating, elastic laminate and method for making the same
US20050079314A1 (en) Moisture barrier and energy absorbing cushion
DE60306983D1 (en) Elastic floor covering with textile insert
US4569707A (en) Method of making foamed slip resistant surfaces
JP6061561B2 (en) Sheet material and article
JP2624418B2 (en) Laying tiles
JPH08290512A (en) Non-skid base sheet
JP4248084B2 (en) Foamed polyolefin leather
US20030036323A1 (en) Shelf liner/table top assembly
JPH0830310B2 (en) Cushioning heavy walking floor material
JPS5912826B2 (en) Cushion flooring
US7491439B2 (en) Shelf liner with natural fibers
JP3076524B2 (en) Multifunctional non-slip base material sheet
JPS61119780A (en) Tile carpet
JPH05279967A (en) Leather-like molded article
JP4098602B2 (en) Anti-slip flooring
JP2662752B2 (en) Laying tiles
CN101053542B (en) Pressure-sensitive adhesive tape or sheet, and process for producing pressure-sensitive adhesive tape or sheet
US20210380202A1 (en) Adhesive Foam Fishing Equipment Storage Pad