JPH08290169A - Perforated container for housing tourmaline carrier with respectively freely fittable and separable chambers and means for surface activation of water and interface purifying method of the same water system - Google Patents

Abstract

PURPOSE: To provide a method and means for surface activating water and purifying the wall surfaces of the same water system. CONSTITUTION: There are granular materials 10 for carrying fine powder of tourmaline consisting of the fine powder of the tourmaline having a diameter of about 0.3 to 5 microns and the carriers of the fine powder of the tourmaline of about 10<6> to 10<10> Ω.cm in the specific volumetric DC electric resistance thereof. There are four chambers of the carrier housing chambers 20 in which many of these granular materials 10 are housed and which consist of a pair of freely fittable and separable members. The carrier housing chambers 20 each has hexagonal through holes vertically penetrating the center thereof. Then, these chambers do not require piping work, are easily selectable in their capacity and are capable of dealing, according to circumstances, with the sizes of the scale of the equipment at the position where the chambers are installed.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates generally to tourmaline products, and more particularly to an immersion type of tourmaline carrier using tourmaline fine powder contained in a container having a large number of water passage holes. The present invention relates to a water surface-active means and its container. In particular, the present invention relates to a method for purifying a wall surface in contact with an interface of the same water system as a surface activating means of a porous container and water in which each chamber of the container can be fitted and separated freely and whose volume can be freely adjusted.

[0002]

2. Description of the Related Art The inventors of the present application filed in 1988 that a tourmaline crystal is a permanent electrode, which means that it holds the electrode itself without externally supplying electric energy. I found that I had a pair of electrodes.
This is just like the permanent pole in a magnet. However, it is a different phenomenon in that a weak current exists. It is difficult to know the properties of this electrode by measurement or the like in a crystal body of a normal size. The inventor of the present application was able to prove this by conducting some experiments using fine crystals crushed to a size of about 3 microns.

Therefore, regarding this, a patent application (Japanese Patent Application No. 1-25
7130) while the details are available in the journal "Solid State Physics" (198
9, Vol.24, 12), and then published at several academic conferences and journals, including the Physical Society of Japan. Since then, the theory has been confirmed by experiments by researchers at national universities and research institutes. In addition, products that apply the properties of tourmaline are already expanding in various fields. Furthermore, various patent applications related to this have been filed. The main ones are
Japanese Patent Application No. 2-46449, Japanese Patent Application No. 4-122925, Japanese Patent Application No. 4-175951, Japanese Patent Application No. 5-36234 and Japanese Patent Application No. 5-203731.

[0004]

For the purpose of cleaning and maintaining cooling towers and the like without using chemical agents that are harmful to the human body and the environment, attempts have been made to use magnets and electrodes called electromagnetic methods. . However, the effect is weak in each case.
Therefore, the same inventor of the present application invented a water surface activation device using tourmaline and filed a patent application (Japanese Patent Application No. 1-257130). However, also in the above-mentioned case, since the devices are large in size because the devices are connected to the middle of the circulation pipe and the construction is required, the equipment cost is expensive and unusable.

Therefore, the same inventor of the present application made the invention of Japanese Patent Application No. 5-203731 of the immersion type again and applied for a patent. The immersion container type is less expensive than the connection type and does not require piping, electrical work, etc. for mounting. In addition, the number of uses can be easily increased or decreased, and the size of the water tank such as the cooling tower and the usage conditions can be easily accommodated. However, since this is a fixed type cylinder and not an assembly / separation type cylinder, welding processing is required, and it is necessary to prepare various sizes with a fixed internal volume. On top of that, separate and take out the carried material in the container, regenerate it and store it in the container,
It was difficult to recycle it to reassemble it.

[0006] At this point, it was thought that the surface action and effect of water would not be produced until the water flowed due to circulation or the like and brought into sufficient contact with the tourmaline carrier, so that the water flowed. It was a mandatory configuration requirement. Along with this, since the concept of "same water system" was not understood, this was not an essential constituent requirement for the interface purification method.

[0007] However, by using tourmaline to purify the water supply / drainage pipes of buildings such as buildings, the water tank and the wall surfaces of the water supply equipment attached to this, water and materials in the pipes and water tanks caused by pollution of the wall surfaces. There is a demand for an interfacial purification system (method) and a device therefor, which are intended to prevent the secondary pollution of the above, and also to prevent the back flow of a bad odor by cleaning the inner surface of the drainage pipe. Conventionally, purification of water quality has been an important issue in the fields of industry and life, and the terms water treatment industry and water treatment technology have become common.

The water treatment referred to here is to purify the water quality and to remove various impurities contained in the water. However, water dissolves many things and also precipitates. This causes the water to wash the surface of the solid it comes in contact with. On the other hand, it also contaminates and corrodes this surface. No matter how purified water is, if the inner surface of the water container or the flowing pipe is dirty, the water becomes dirty again. Interface purification is also necessary for water purification. In addition, "interfacial purification" in the text means "purifying the water contact wall surface by the interfacial activity of water". That is, the interface is the interface of water, and the part where the solid comes into contact with water is not the interface,
This is because it is a "wall surface".

What is necessary to make water having a surface-purifying action is to make a surface-active substance having a surface-active action, and a chemical agent called a surfactant is used for this purpose. However, most of the water used for supplying water to buildings, condominiums, and other structures is tap water and part of it is groundwater. The inner wall surfaces of these water supply pipes, aquariums, equipment, etc., make various stains with the use of organic substances called water stains, iron rust, calcium scales, dead bodies of microorganisms, etc. as they are used. The dirt on the inner wall created by the company recontaminates the water itself.

Hygiene is not permitted to use chemical agents for cleaning the interface. Attempts have been made to artificially add calcium or silica to water to form these thin scales on the inner surface of pipes and the like to protect the pipes, but it is difficult to maintain the effect, and it is rarely used. On the other hand, many methods and products that do not use chemical agents are provided on the market, such as a method using an electric field and a magnetic field, a degassing method that greatly reduces oxygen in water, and a method using ceramics. The principle of many of these is not clear, the effect is not reproducible depending on the water quality, and the equipment cost and maintenance cost are expensive, so that they have not been widely used.

The applicant of the present invention discovered in 1988 that a permanent electrode was present on tourmaline, and by using this electrode, by electrolyzing water at a weak voltage below the water decomposition pressure. Some of the water molecules are ionized into hydrogen ions (H ⁺ ) and hydroxide ions (OH ⁻ ), and the hydrogen ions are easily electrically neutralized by the cathode of the tourmaline electrode to become hydrogen gas H ₂ , Ions are difficult to neutralize at the cathode, so they remain in water,
Bind with water molecules H ₂ O make hydroxyl ions with the molecular structure of H-O-H ₂ O, this material was found to have a property as a surface-active substance to make the surfactant water. This has been proved in various fields, and even in academic journals it is called Kubo theory and is regarded as one of the functional waters.

[0012] The applicant of the present application filed in 1989
9) In the application filed on October 3, 2010, a water-flowing device filled with ceramic granules (spherical) was used as a tourmaline carrier,
We have applied for a device for activating the interface of water and tourmaline particles under the name of "device and method for cleaning interface using tourmaline and tourmaline particles". This invention is a new technology using a tourmaline permanent electrode, but connecting a water-passing device to the middle of the water supply pipe to pass the entire amount of water is the same as conventional electric, magnetic and ceramic. Is the same.

This is the same as the conventional one using electric, magnetic and various ceramics, and a water-flowing device filled with tourmaline particles must be connected to the middle of the water supply (pumping) pipe. . It has been reported that the surface active action of water produced by tourmaline is lost in about 2 to 4 hours depending on the water quality. In addition, the time and amount of water used in most buildings such as buildings, condominiums and schools is 1
It is about half of the day and very few at midnight. This function, which was created in the meantime, will not exist in the water used for a while after the next morning. Even if the entire amount of water is passed through the water passing device, a considerable part of the water having surface activity loses this effect. As a result, the interface cleaning action on the piping system also works intermittently, and the effect is greatly reduced as a whole.

Therefore, the conventional drawbacks described above are greatly improved by removing the stains on the inner wall surfaces of all water pipes and water tanks of buildings, condominiums, factories, and other structures to prevent the progress of corrosion and to achieve this effect. It was required to be used for conservation and to prevent water from secondary pollution. In addition to this effect, many secondary effects such as improvement of taste of drinking water, improvement of cleaning power, purification of wall surface of drainage pipe inner wall due to residual surface activity effect in drainage, prevention of backflow of offensive odor, etc. What gave birth to was requested.

[0015]

[Means for Solving the Problems] When a water container containing a tourmaline carrier in which each chamber can be fitted and separated freely is immersed in water, the amount of the surface-active substance formed in the water is smaller than the amount of water. Is. However, when this action time is long enough, the surface activity created in the water is strong enough. For example, if a water container in which the tourmaline carrier is stored and fitted is immersed in a water tank on the rooftop of a building, the water in the pipes can be left overnight even when there is no running water in the pipes. The surface activation is widespread. In office buildings, there is almost no water on holidays. However, the surface activity of non-flowing water is constantly developing.

In view of the above problems, therefore, the present invention relates to a tourmaline carrier accommodating porous container in which the respective chambers can be fitted and separated, the water interface activating means, and the same water system interface cleaning method. The volume specific DC electric resistance is 10 ⁶ Ω · cm
Basically, it is about 10 ¹⁰ Ω · cm. Next, each chamber for accommodating the carrier carrying the tourmaline fine powder is composed of a plurality of accommodating and separable accommodating chambers, and a pair of hexagonal shafts for engaging and retaining the accommodating chambers and connecting them. A water surface activated porous container having a detachable coupling and holding means composed of a nut or the like was used. Then, based on this, the interface activating means and interface cleaning method were developed.

The concrete construction of the tourmaline carrier accommodating porous container in which the chambers can be fitted and separated according to the present invention, the interface activating means for water, and the interface cleaning method for the same water system will be described in detail below. . First, the construction of the interface activating means for water using the tourmaline carrier-accommodating porous container in which the respective chambers of the present invention according to claim 1 of the present invention can be fitted and separated will be described. First of all, there is tourmaline fine powder. This tourmaline fine powder has a diameter of 0.3.
.About.5 microns, especially about 0.5 to 3 microns. Next, there is a support. This carrier is for supporting the above tourmaline fine powder, and has a volume specific DC electric resistance of about 10 ⁶ Ω · cm to 10 ¹⁰ Ω · cm.

Then, there are a plurality of carrier storage chambers. The plurality of carrying object storage chambers accommodate the above-mentioned carrying objects, and each of them comprises a pair of separable fitting bodies. In addition, there are a large number of surface-active substance outlet pores. The large number of pores through which the surface-active substances pass are provided in the carrier storage chamber. Finally, there is a detachable coupling holding means consisting of a pair of hexagonal shafts and nuts and the like. The detachable coupling / holding means composed of a pair of hexagonal shafts and nuts is for coupling the plurality of carrying object storage chambers and for retaining and fitting the respective fitting / separating bodies.

Next, the chambers according to the present invention as set forth in claim 2 of the present invention are a tourmaline carrier-containing porous container in which the chambers can be fitted and separated freely, water interface activation means, and the same water system interface purification method. The construction of the interface activating means for water using the tourmaline carrier-containing porous container which can be fitted and separated freely will be described. The present invention has the same configuration as the invention of claim 1 except for the following points. Therefore, from the whole sentence of the description of the configuration of the invention of claim 1 above, the following points are excluded and cited, and the following description of the configuration is added thereto. The difference lies in the carrier. This carrier is composed of a mixture of a plurality of substances, and its volume specific direct current electrical resistance is the volume specific direct current electrical resistance of the plurality of substances as a whole.

Further, according to the invention, each of the chambers according to the third aspect of the present invention is a porous container for holding a tourmaline carrier, in which the chambers can be fitted and separated freely, a means for activating the interface of water, and an interface cleaning method of the same water system. The construction of the interface activating means for water using a tourmaline carrier-containing porous container that can be fitted and separated will be described. The present invention has the same configuration as the invention of claim 1 except for the following points. Therefore, from the whole sentence of the description of the configuration of the invention of claim 1 above, the following points are excluded and cited, and the following description of the configuration is added thereto. The difference is also the carrier. This carrier is a carrier having an electron transporting property of transporting electrons by the grain boundary of the ceramic crystal grains having different dielectric constants which compose the carrier.

The invention according to claims 4, 5 and 6 of the present invention of a tourmaline carrier accommodating porous container in which each chamber can be fitted and separated freely, water interface activation means, and the same water system interface purification method according to the present invention. The construction of the tourmaline carrier-containing porous container in which the respective chambers can be fitted and separated will be described. The present invention is the same as the configurations of the inventions of claims 1, 2 and 3 except for the following points. Therefore, from the whole sentence of the description of the structure of the inventions of claims 1, 2 and 3, respectively, the following points are excluded from the full text, and the following description of the structure is added thereto. The difference is that the plurality of carrier storage chambers are prepared so as to store the respective carriers described above.

Finally, each chamber according to the present invention is a porous container for holding an electric stone carrier, in which each chamber according to the present invention can be fitted and separated freely, a means for activating the interface between water and a method for cleaning the interface of the same water system. The configuration of the same water system interface cleaning method using a tourmaline carrier-containing porous container in which fitting and separation are possible will be described. First, the following water surface activation means is put into a water tank. By this injection, even when the inner wall of the water tank or the water in the water tank is stopped, the water contact wall surface such as the water pipe wall surface of the same water system that continuously shares the water interface with the water in the water tank is purified even when the water flow is stopped.

In the above-mentioned water surface activation means, first, there are a plurality of carrier storage chambers. The plurality of loaded object storage chambers contain the following loaded objects, and each of them is composed of a pair of separable fitting bodies. Next, there are a large number of surface-active substance outlet pores. The large number of pores through which the surface-active substances pass are provided in the above-mentioned loaded material storage chamber. Then, there is a detachable coupling holding means. The detachable coupling / holding means is a pair of 6 for coupling the plurality of carrier storage chambers and for retaining the respective fitting / separating bodies.
It consists of a square shaft and nuts.

The above-mentioned carrier is for carrying fine tourmaline powder having a diameter of about 0.3 to 5 microns, especially 0.5 to 3 microns, and is a carrier composed of a single substance or a mixture of a plurality of substances and the whole thereof. Volume specific DC electric resistance of about 10 ⁶ Ω · cm to 10 ¹⁰ Ω · cm, especially 10 ⁷ Ω · c
It has an electron-transporting property of transporting electrons, depending on the electrical properties of the grain boundaries of ceramic crystal grains with different permittivities that compose the carrier, with a grain size of m to 10 ⁹ Ω · cm. .

[0025]

In the present invention, the tourmaline carrier-containing porous container in which the chambers can be fitted and separated from each other, the water interface activating means, and the interface cleaning method of the same water system have the following effects because they have the above configurations. occured. First, the operation of the invention described in claims 1 and 4 of the present invention will be described. First of all,
Carry fine tourmaline powder. Further, this carrier has a volume-specific DC electric resistance of 10 ⁶ Ω · cm to 10 ¹⁰ Ω · c.
Since it is about m 2, an electric current flows to the outside of the supported material, and an electrode reaction occurs. Furthermore, a plurality of carrying object storage chambers
The above-mentioned carrier is stored. In particular, the plurality of carrier storage chambers enhance the contact action with the water therein to improve the surface activation effect of water described later. Further, a large number of surface-active substance discharge pores provided in the carrier storage chamber allow the surfactant to flow out of the carrier storage chamber. Finally, a detachable coupling / holding means composed of a pair of hexagonal shafts and nuts couples the plurality of carrier storage chambers and also retains the respective fitting / separating bodies in a fitted manner.

Next, the operation of the invention described in claims 2 and 5 of the tourmaline carrier-containing porous container in which the respective chambers can be fitted and separated freely, the interface activating means of water, and the interface cleaning method of the same water system. Will be explained. This invention is the same as the operation of the invention of claim 1 except for the following points. Therefore, from the whole sentence of the explanation of the operation of the invention of claim 1 above, the following points are excluded from the full text, and the following explanation of the operation is added thereto. The difference lies in the carrier. This carrier is formed by mixing a plurality of substances, and the volume specific direct current electrical resistance is the value of the volume specific direct current electrical resistance of the plurality of substances as a whole, so that the same effect as in claim 1 is produced.

Further, the functions of the invention described in claims 3 and 6 of the porous stone container for storing the tourmaline carrier in which the respective chambers can be fitted and separated according to the present invention, the means for activating the interface of water, and the interface cleaning method of the same water system. Will be explained. This invention is the same as the operation of the invention of claim 1 except for the following points. Therefore, from the whole sentence of the explanation of the operation of the invention of claim 1 above, the following points are excluded from the whole sentence, and the following explanation of the operation is added thereto. The difference is also the carrier. The carrier is a substance having an electron transporting property of transporting electrons by the grain boundary depending on the electrical property of the grain boundary of the ceramic crystal grains having different dielectric constants which compose the carrier. Similar effects occur.

Finally, the chambers according to the present invention as set forth in claim 7 of a tourmaline carrier accommodating porous container in which the respective chambers according to the present invention can be fitted and separated, water interface activation means, and the same water system interface purification method. The operation of the same water-based interface cleaning method using a tourmaline carrier-containing porous container in which fitting and separation are possible will be described. First, the following water surface activation means is put into a water tank. By this input, the water contact wall surface such as the water pipe wall surface of the same water system that continuously shares the water interface with the water in the water tank due to the interfacial activity of the water by the inner wall of the water tank and the water in the water tank when water flow is stopped. Purified even when running water is stopped.

In the above water surface activating means, first, the plurality of carrier storage chambers each comprise a pair of separable fitting bodies, and store the following carriers. Next, a large number of surface-active-substance passage pores provided in the above-mentioned carrier storage chamber allow the surface-active substance to flow out of the support storage chamber. Then, the detachable joint holding means joins the plurality of carrier storage chambers and fits and holds the respective fitting and separating bodies.

The above-mentioned carrier is a carrier for carrying tourmaline fine powder having a diameter of about 0.3 to 5 microns, particularly 0.5 to 3 microns, and is a carrier composed of a single substance or a mixture of a plurality of substances and the whole thereof. Volume specific DC electric resistance of about 10 ⁶ Ω · cm to 10 ¹⁰ Ω · cm, especially 10 ⁷ Ω · c
It has an electron-transporting property of transporting electrons, depending on the electrical properties of the grain boundaries of ceramic crystal grains with different permittivities that compose a support material, or m-10 ⁹ Ω · cm. Therefore, a weak current flows and an electrode reaction is possible.

[0031]

[Embodiments] Now, a method for purifying water supply / drainage pipes of a building or the like and an interface of the same water system such as a water tank connected to the pipes and equipment used will be described. This means that a tourmaline carrier, especially a container filled with ceramic granules, is immersed in the water of the aquarium of the building, and even if the granules and water do not move, they have a common interface with the water in the aquarium. The present invention relates to a method and apparatus for forming a monomolecular film of a surface-active substance on the interface of water and utilizing its surface-active action and effect.

First, the overall flow will be described below. A tourmaline carrier (ceramic granules) filled with a large surface area container having many water passage holes is immersed in the water storage of a water tank or an elevated water tank of a building or the like. The water in the water tanks (cold, hot) attached to the pipes and equipment that have a common interface continuously with the water interface in these water tanks is considered as one water system. The container filled with tourmaline carrier is immersed in the water of the main water tank of this one water system. The tourmaline carrier in the container, which is settled in water, successively produces surface-active substances by the weak electrolysis of water by the permanent electrode of the tourmaline.

All the surface-active substances move rapidly to the water interface and form a monomolecular film at this interface. The purpose of this is to purify all solid surfaces that come into contact with water, such as the inner surfaces of pipes, water tanks, pumps, etc., that are used around all water in buildings and other structures, and to maintain their effects. System. Therefore, this system also includes water for various independent water tanks and devices such as a cooler, a water heater, a dirty water tank, a bathtub, and a pool, and piping. Then, each is treated as a single water system with one interface and treated in the same way.

Since the surface-active substance formed in water by the electrode reaction of tourmaline is a substance that does not have symmetrical positive ions in water and violates the principle of electrochemical neutrality, it tries to go out of water. To do. That is, it exhibits hydrophobicity. Since this hydrophobic group has a negative charge, it is electrically positive within the water molecule that has the property of being an electric dipole.
Combines with one hydrogen molecule to form a hydroxyl ion. This hydrophobic group rapidly moves to the water interface in search of a stable place, and orients the hydrophobic group toward the outside of the water (this is explained with reference to the drawing immediately before the [effect of the invention] in the rear part). To). The migration of the hydrophobic group is based on the “hopping model” method in which the water molecules in the water are separated from the bound water molecules and are moved like a stone. Therefore, it is much faster than moving through the water molecules in water in the form of hydroxyl ions. In this way, hydroxyl ions move to the interface rapidly regardless of the flow or movement of water.

The applicant of the present patent application has recently studied the solution of this problem from various angles, but has finally found that it can be solved by the following. First, the generation of the surface-active substance hydroxyl ion using ceramic granules loaded with tourmaline and the subsequent behavior will be described. In the space on the surface of the ceramic granules, positive and negative electrodes on both ends of countless minute crystals of tourmaline create a micro electric field.
Due to this electric field, the water in contact with the surface of the particulate matter produces hydrogen gas and hydroxyl ions by electrolysis below the decomposition pressure. Replenishment of electrons consumed for neutralization of hydrogen ions by this weak electrolysis is carried out in a carrier carrying tourmaline and water in the reaction system.

In the case of ceramics, electrodes can be maintained by the potential difference created by the grain boundaries of ceramics having different dielectric constants and the appropriate value of the electric resistance of the material at the grain boundaries. Symmetrical plus ion H ⁺ Loss ion OH ⁻ is a negative ion formed by combining with water molecules, hydroxyl ion H ₃ O ₂ ⁻ is electrochemical in water except in the state where H—O ⁻ group is outside water. It is a state contrary to the principle of neutrality. The stable location of these ions means that there is only the boundary between water and air, or solid and hydrophobic substances, that is, the water interface. The H-O ^- group is forced to move rapidly toward this interface. Compared to moving water molecules by scooping them in the form of molecules bound to water molecules, only H-O ^- groups easily move by the hopping model, which causes surrounding water molecules to move easily and blink. In the meantime, it reaches the interface and bonds with the water molecules at the interface to stabilize and form hydroxyl ions.

The hydroxyl ions at the interface are H-
The H atom of the O ⁻ group is directed in the opposite direction to water, and the oxygen atom is oriented at the interface in the form of bonding with the two hydrogen atoms of the water molecule, forming a monomolecular film of this ion. This is the same as the behavior of other surface-active substances to form a monolayer at the water interface.
It also shows that the H—O ⁻ group of the hydroxyl ion has a hydrophobic group. Tourmaline electrodes make this surface-active substance one after another in water. Unlike other surface-active substances, this surface-active substance does not require stirring or the like for mixing and dissolving in water. The hydrophobic groups themselves of the surface-active substance move rapidly in water to the interface.

Then, all interfaces are covered with a monolayer of hydroxyl ions. In this way, the hydroxyl ions after saturating the interface form an aggregate micelle (Micell) of the surface-active substance by directing the hydrophobic group inward in water. The state is shown in the figure. After covering the interface with a monolayer, the rate of hydroxyl ion formation when forming micelles in water is much slower than when forming a monolayer at the interface. These micelles made in water serve to consume the surfactant and replenish any intervening monolayer voids.
In this way, the surface-active substances made by tourmaline rapidly gather at the place where the action of the surface-active substances is required, that is, at the interface of water without transporting or stirring by water flow, and form a monomolecular film. I knew that. This is an important new finding for solving the problem of the present invention.

Based on this finding, the following water system interface purification system could be constructed. this,
Take the water supply system of a building as an example. The water supply system of a building can be divided into several systems that share an interface independently. The first water system is a water tank for first storing water such as tap water. Next, there is a pump for pumping this water and water for a pump connected to the front and back of this pump. This pump will supply water to the elevated water tank. Here, the continuity of the water interface is lost. The second water system is the water stored in the elevated water tank that stores the water supplied by the first water system, and the water in the water supply pipe for supplying this water to each floor by using the head of the water. . This ends with a faucet at the end and a water shutoff valve. The interface between the first and second water is cut off by a ball tap at the end of the pumping pipe at the end of the make-up water of the pipe for supplying water to the elevated water tank.

Next, a device to be immersed in the water tank will be described. This uses a stainless steel container filled with ceramic granules carrying tourmaline. The hydrogen gas produced by the reaction between those particulates and water becomes small bubbles and is released into the water by its buoyancy. Further, the surface-active substance hydroxyl ion moves in water by the hopping method, and in consideration of reaching the interface, the surface area of the container is large so that the hydroxyl ion is easily diffused, and the total area of the holes of the flow holes is also large, Fill a container of a shape suitable for immersion with the granules. This container is dipped and installed in the water of the first water receiving tank and the second water elevated water tank so that it can be easily pulled up by a stainless wire or the like.

Hydroxyl ions and hydrogen gas are produced one after another by the electrode reaction between the tourmaline carrier in the container of water placed in this state and water. The surface-active substance hydroxyl ion rapidly moves to the water interface and covers the interface with a monolayer in which the ion is oriented. This monomolecular film is, first, to the interface of the elevated water tank with the air of the water, and then to the wall surface and bottom surface in contact with the water in the water tank, and then
It gradually expands to the pipe wall of the main water supply for supplying water from the elevated water tank, and to the inner surface of each water supply branch pipe that supplies water to each faucet. Furthermore, the surface of the microscopic complex surface structure of the rust surface part (called floating rust), which is complicated and has many pinholes created by rust and various impurities generated at the interface of these water tanks and pipes, is also treated with water. As long as it is in contact, it is the interface targeted by this surfactant and hydroxyl ions.

At these interfaces, not only iron rust but also calcium, silica and the like form compounds, which deposit over a long period of time to form scales, and many organic substances, carcasses of microorganisms, etc. form "neck". ing. These are all substances that are the targets of the action of surface-active substances that are created in the water of the interface. That is, it is the same as the component of "dirt" in cleaning. Some of these substances are hydrophobic, and water does not easily penetrate into microscopic pinholes such as floating rust, but the surface-active substance hydroxyl ion formed in water is , The interface is changed to an interface that is easily wetted by water, and various surface active effects useful for interface purification are produced. As described above, the pollutants on the wall surface in the water supply system connected to the elevated water tank have many kinds and complicated shapes and properties, but they are all targets of the action of the surface-active substances and hydroxyl ions.

The following is a description of the embodiment of the present invention of a porous stone container for storing tourmaline carrier, in which the chambers can be fitted and separated, the interface activating means for water, and the interface cleaning method for the same water system. It will be described in detail with reference to the accompanying drawings. FIG. 1 is a front cross-sectional view of an embodiment of a four-chamber tourmaline carrier storage porous container according to the present invention in which the chambers can be fitted and separated freely. 2 is a bottom view of the embodiment of FIG.

First, the tourmaline fine powder-supporting granular material 1 is used.
There are many 0s (see FIGS. 1, 3, 5 and especially 8). The tourmaline fine powder-supporting granules 10 are composed of tourmaline fine powder 11 and a carrier 12 of the tourmaline fine powder 11. This tourmaline fine powder 11 has a diameter of 0.3 to 5 microns.
It is about 0.5 to 3 microns. The carrier 12 made of ceramics supports the tourmaline fine powder 11 and has a volume specific DC electric resistance of about 10 ⁶ Ω · cm to 10 ¹⁰ Ω · cm, particularly 10 ⁷ Ω · cm ~ 1
It is about 0 ⁹ Ω · cm. In this embodiment, ceramic is used as the carrier 12, but the present invention is not limited to this, and various tourmaline carriers such as fibers and rubber are used as long as the resistance is within the range. Available according to.

Further, there are four carrier storage chambers 20. These carrier storage chambers 20 are composed of a pair of separable fitting bodies each having a hexagonal through hole that vertically penetrates the center thereof. Specifically, this is a bowl 22 type with a lid 21 (see FIGS. 1, 3 and 5). The carrying object storage chamber 20 is 6 in the embodiment of FIG. 3 and 8 in the embodiment of FIG. According to the present invention, since the carrying-material storage chamber 20 can be freely increased and combined, its capacity size can be freely set.
It should be noted that the carrying object storage chamber 20 shown in FIGS. 3 and 5 is shown in a smaller size than that of 1, but this is only due to the size of the drawing sheet. The size of each room is the same.

However, the above-mentioned loaded-material storage chamber 20 contains a large number of the loaded granular materials 10. In addition,
In the figure, the tourmaline fine powder-carrying granules 10 are drawn as if they are sparsely stored in the above-mentioned carrier storage chamber 20, but this is simplified by simplifying the drawing. This is because the presence of the particulate matter 10 is made clear. Therefore, in reality, each tourmaline fine powder-carrying granular material 1 is so hidden that it is hidden by the tourmaline fine powder-carrying granular material 10 group and the wall of the carrier storage chamber 20 behind it cannot be seen.
Many 0s are stored in a state of being close to each other.

In addition, a large number of surface-active substance discharge pores 23
(See FIGS. 2, 4 and 6). The large number of surface-active-substance discharge pores 23 are provided in the carrier storage chamber 20 and allow the surfactant to flow out from the carrier storage chamber 20. Finally, there is a detachable coupling holding means 30. The detachable coupling holding means 30 comprises a pair of hexagonal shafts 31 and nuts 32. The pair of hexagonal shafts 31 and the nuts 32 are provided in the above-mentioned four chambers 2 for carrying materials.
0 is coupled through the through hole, and at the same time, the respective fitting and separating bodies 21, 22 are fitted and held.

Thus, the above tourmaline fine powder-supported material 10
It is preferable that the material has a large contact area with water, which is provided with a large number of particles, unevenness and perforations, and does not lose its shape. The carrier 12 may be a mixture of a plurality of substances. However, the value of the volume specific direct current electrical resistance in this case is
The volume specific DC electric resistance of the plurality of substances as a whole is 10
It should be about ⁶ Ω · cm to 10 ¹⁰ Ω · cm. Further, although there are various shapes of the support, such as a granular shape and a planar shape, it is preferable that the contact area with water is increased and that the hydroxyl ions of the surface-active substance pass out from the inside of the container to the outside and easily diffuse.

As described above, one embodiment of the embodiment of the interface activating means for the electric stone carrier-containing porous container in which the respective chambers of the present invention shown in FIG. As in the end view, the hexagonal shaft 31 (with the lower nut 32 and the washer 33) of the detachable coupling holding means 30 is passed through the shallow bowl 22 of the tourmaline carrier storage porous container 20 at the bottom. Then, the shaft pipe 34 is inserted into the hexagonal shaft 31, and the tourmaline fine powder-carrying granular material 10 is put into the shallow bowl 22. Then, the lid 21 is passed through the hexagonal shaft 31 to cover the shallow bowl 22. Then, another washer 33 is passed through the hexagonal shaft 31 to move to the next insertion of the shallow bowl 22, and this is repeated to assemble it.

Thus, the explanation for the hydroxyl ion in [0034] above is detailed here. First, the hydroxyl ion 40 has a structure as shown in FIG. This consists of a hydrophobic group 41 and a water-immersive group 42. As shown in FIG. 10, when a predetermined voltage is applied to water, the voltage decomposes into H ⁺ and OH ⁻ ions (which is said to be about 1 V) and H ₂ And a voltage that causes decomposition in O ₂ .

Then, the hydroxyl ion 40 as the surface-active substance is converted into the hydrophobic group 4 as shown in FIG.
1 is separated from water 50 The interface of water 50 (water surface 51, container 6
0 wall surface 61) to move quickly. Figure 11
In (a) (b) (c) (d), the hydroxyl ions 40 increase and form a monolayer at the water interface.
It shows the state that is being made. And, when the dirt substance (hydrophobic substance) 70 is included in the water 50,
(D) As shown in the figure, the hydrophobic group 41 is directed toward the dirt substance 70, and it is wrapped.

In the present invention, the reducing action at the interface of water and the action of reducing the activity of chlorine contained in tap water are major features of the hydroxyl ion monomolecular film.
The monolayer formed by the hydroxyl ions at the interface directs the hydrogen atoms of its hydrophobic groups in the direction opposite to water, and the oxygen atoms bind to water molecules, suppressing their action. This explains that the water at the interface has a reducing property. Further, the chlorine contained in the tap water, a strong chlorine compounds chemically active, in water ^{_{Cl 2 → HOCl → OCl - →}} C
l ^- OH of the water ^- hydrolysis proceeds rapidly by.

This reaction becomes less active as it proceeds to the right. The most active Cl ₂ is halved. This is why the chlorine odor disappears instantly even if a small amount of tourmaline ceramic support is added to tap water, and the total amount of chlorine compounds in the water does not decrease. The above-mentioned two actions synergistically cover the passivation compound of iron on the wall surface of the pipe or the water tank and clean the wall surface. After that, this is prevented from the recurrence of corrosion and contamination, and rather, it is brought into a better state to show the maintenance and maintenance of the effect of surface activity.

[0054]

EFFECTS OF THE INVENTION The porous stone container for storing electric tourmaline material in which the respective chambers can be fitted and separated according to the present invention, the means for activating the interface of water and the method for cleaning the interface of the same water system are as described above. A great effect has occurred. That is, the deterioration of water permeability in the case of the conventional large-scale tourmaline surface-active device using tourmaline is changed to a four-chamber tourmaline carrier-accommodating porous container in which the immersion type chambers can be fitted and separated. This allowed the layer to be made very thin without reducing the amount of tourmaline support used for it. As a result, the water that has entered the layer of tourmaline carrier from the pores of the inner tube easily passes through the thin layer of that tourmaline carrier, and the surface-active substance passes through the water and the pores of the container. It came out of and diffused to the water interface, and the surface-active effect was greatly enhanced.

Both the above-mentioned double-tube type container and the container of the present invention are basically the same in that they are easy to handle because they are simply placed in water and no piping work is required. The major difference is that, in the case of the container of the present invention, the capacity can be easily selected and the capacity of the facility such as water supply at the place of installation can be flexibly accommodated. That is, it is only necessary to increase or decrease the load storage chamber according to the scale of the equipment. Then, it is only necessary to use a hexagonal shaft having a length corresponding to the number of the carrying object storage chambers.

Moreover, not only the assembly and disassembly thereof are very easy and the cost can be greatly reduced, but also when the tourmaline fine powder-supporting granules are regenerated, It can be easily taken out from the container and can be easily enclosed after the treatment.

[Brief description of drawings]

FIG. 1 is a front sectional view of an embodiment of a four-chamber tourmaline carrier-containing porous container in which each chamber according to the present invention can be fitted and separated.

2 is a bottom view of the embodiment of FIG. 1. FIG.

FIG. 3 is a front sectional view of an embodiment of a 6-chamber tourmaline carrier-containing porous container in which each chamber according to the present invention can be fitted and separated.

FIG. 4 is a bottom view of the embodiment of FIG.

FIG. 5 is a front sectional view of an example of an eight-chamber tourmaline carrier-containing porous container in which each chamber according to the present invention can be fitted and separated.

FIG. 6 is a bottom view of the embodiment of FIG.

FIG. 7 is an end view of a partially omitted front cross-section of an embodiment of the interface activating means for a tourmaline carrier accommodating a tourmaline carrier in which each chamber according to the present invention can be fitted and separated, and its assembly. It shows the state of stages.

FIG. 8 is a front sectional view showing a tourmaline fine powder-carrying granular material stored in the container of the present invention.

FIG. 9 is a structural diagram of hydroxyl ion.

FIG. 10 is an electrolysis diagram of water.

FIG. 11 is an explanatory diagram showing the state of hydroxyl ions in water.

[Explanation of symbols]

 10 Tourmaline fine powder-supported granules 11 Tourmaline fine powder 12 Carried substance 20 Carried substance storage chamber 21 Lid 22 Shallow bowl 23 Many surface active substance through holes 30 Removable bond holding means 31 Hexagonal shaft 32 Nut 34 Shaft Pipe

Claims (7)

[Claims] 1. A tourmaline fine powder having a diameter of about 0.3 to 5 microns, especially about 0.5 to 3 microns, which carries the tourmaline fine powder and has a volume specific direct current electrical resistance of 10 ⁶ Ω.
・ Cm to 10 ¹⁰ Ω ・ cm, especially 10 ⁷ Ω ・ cm to 10 ⁹ Ω ・ c
About m m carrier, a plurality of carrier accommodating chambers each accommodating the carrier, each of which is composed of a pair of separable mating bodies, and a large number of surface-active substance discharge cells provided in the carrier accommodating chamber. A hole, a detachable coupling / holding means that is composed of a pair of hexagonal shafts for coupling and holding the plurality of carrier storage chambers, and each of the above-described respective fitting / separating bodies, and a nut, and the like. A water surface activating means that uses a tourmaline carrier-containing porous container in which each chamber can be fitted and separated freely. 2. A tourmaline fine powder having a diameter of about 0.3 to 5 μm, particularly 0.5 to 3 μm, and a carrier which carries the tourmaline fine powder and is a mixture of a plurality of substances, and as a whole. Volume specific DC electric resistance is 10 ⁶ Ω · cm
-10 ¹⁰ Ω ・ cm, especially 10 ⁷ Ω ・ cm -10 ⁹ Ω ・ c
About m m of carrier, a plurality of carrier storage chambers each accommodating the carrier and each consisting of a pair of separable bodies, and a large number of surface-active substance discharges provided in the carrier storage chamber And a removable coupling / holding means composed of a pair of hexagonal shafts and nuts for connecting the plurality of carrier storage chambers and fittingly holding the respective fitting / separating bodies. A surface activating means for water using a tourmaline carrier-containing porous container in which each chamber can be fitted and separated freely. 3. A tourmaline fine powder having a diameter of about 0.3 to 5 μm, particularly 0.5 to 3 μm, and a grain boundary of ceramic crystal grains having different permittivities, which carry the tourmaline fine powder and which constitute the carrier. A carrier having an electron-transporting property whose grain boundary transports electrons depending on the electrical properties of the carrier, and a plurality of carrier-containing chambers each containing the carrier and each of which is composed of a pair of separable mating bodies. A large number of surface-active substance passage holes provided in the carrier storage chamber, a pair of hexagonal shafts for connecting the plurality of carrier storage chambers and fittingly holding the respective fitting and separating bodies. A water interface activating means using a tourmaline carrier-accommodating porous container in which each chamber can be fitted / separated, characterized by comprising a detachable coupling / holding means including a nut and a nut. 4. A plurality of carrier storage chambers for accommodating the following carriers, each of which comprises a pair of mating and separable bodies,
A large number of surface-active substance passage holes provided in the carrier storage chamber, a pair of hexagonal shafts for connecting the plurality of carrier storage chambers and fittingly holding the respective fitting and separating bodies. A removable electric stone carrier-containing perforated container in which each chamber can be fitted and separated, characterized by comprising a detachable coupling and holding means including a nut and a nut. The carrier described above carries fine tourmaline powder having a diameter of about 0.3 to 5 microns, especially about 0.5 to 3 microns, and its volume specific DC electric resistance is 10 ⁶ Ω.
・ Cm to 10 ¹⁰ Ω ・ cm, especially 10 ⁷ Ω ・ cm to 10 ⁹ Ω ・ c
It is about m. 5. A plurality of carrier storage chambers for accommodating the following carriers, each of which comprises a pair of mating separable bodies,
A large number of surface-active substance passage holes provided in the carrier storage chamber, a pair of hexagonal shafts for connecting the plurality of carrier storage chambers and fittingly holding the respective fitting and separating bodies. A removable electric stone carrier-containing perforated container in which each chamber can be fitted and separated, characterized by comprising a detachable coupling and holding means including a nut and a nut. The above-mentioned carrier is a carrier that carries tourmaline fine powder having a diameter of about 0.3 to 5 microns, especially 0.5 to 3 microns, and is a mixture of a plurality of substances, and has a volume-specific DC electric resistance as a whole. Is 10 ⁶ Ω · cm
It is about 10 to 10 ¹⁰ Ω · cm, especially about 10 ⁷ Ω · cm to 10 ⁹ Ω · cm. 6. A plurality of carrier storage chambers for accommodating the following carriers, each of which comprises a pair of separable mating bodies,
A large number of surface-active substance passage holes provided in the carrier storage chamber, a pair of hexagonal shafts for connecting the plurality of carrier storage chambers and fittingly holding the respective fitting and separating bodies. A removable electric stone carrier-containing perforated container in which each chamber can be fitted and separated, characterized by comprising a detachable coupling and holding means including a nut and a nut. The above-mentioned carrier is for supporting tourmaline fine powder having a diameter of about 0.3 to 5 μm, especially 0.5 to 3 μm, and the electrical properties of grain boundaries of ceramic crystal grains having different permittivities that constitute the carrier are determined. Therefore, the grain boundary has an electron transporting property of transporting electrons. 7. The same water system that continuously shares the water interface with the water in the aquarium even when the inner wall of the aquarium or the running of the water in the aquarium is stopped by introducing the following water interface activation means into the aquarium. Purification of water contact wall surface such as water pipe wall surface even when water flow is stopped . The above-mentioned water surface activating means accommodates the following bearings, and each of the plurality of bearings storage chambers is composed of a pair of mating / separating bodies, and a large number of interfaces provided in the bearings storage chamber. An active substance discharge hole, and a detachable coupling / holding means composed of a pair of hexagonal shafts and nuts for coupling and holding the above-mentioned plurality of carrier storage chambers and for fitting and holding the above-mentioned respective fitting / separating bodies. . The above-mentioned carrier is
A carrier which carries fine tourmaline powder having a diameter of about 0.3 to 5 microns, particularly 0.5 to 3 microns, and which is a carrier composed of a single substance or a mixture of a plurality of substances and has a volume specific direct current electrical resistance of 10 ⁶ as a whole. Ω ・ cm to ^{10 10} Ω ・ cm
Electron transporting property in which electrons are transported depending on the electrical properties of the grain boundaries of ceramic crystal grains having a dielectric constant of about 10 ⁷ Ω · cm to 10 ⁹ Ω · cm or having different dielectric constants that constitute the carrier. Is to have.