JPH08286521A - Image forming device using intermediate transfer method - Google Patents

Abstract

PURPOSE: To obtain images without producing voids even when a image forming device is repeatedly used by incorporating a fluorine-base surfactant into the surface material of an intermediate transfer body to increase the cleaning property of the intermediate transfer body and the transfer efficiency of a toner image from the intermediate transfer body to a transfer material. CONSTITUTION: In this image forming device, a negative charge toner image formed on an image holding body is first transferred to an intermediate transfer body and then secondary transferred to a transfer material. The surface material of the intermediate transfer body contains a fluorine-base surfactant. Namely, in order to efficiently transfer a toner image formed on the intermediate transfer body surface to a transfer material, excellent release property between the surface of the intermediate transfer body surface and the toner is necessary. Therefore, by using an intermediate transfer body containing a fluorine-base surfactant having high release property, the production of voids can be suppressed. As for the fluorine-based surfactant used, any of nonion, anion, cation or amphoteric surfactants can be used.

Description

Detailed Description of the Invention

BACKGROUND OF THE INVENTION The present invention relates to a copying machine, a printer,
The present invention relates to an image forming apparatus using an electrophotographic method such as a facsimile, and more specifically, an image forming apparatus using an intermediate transfer method involving an intermediate transfer member such as an intermediate transfer belt and an intermediate transfer method used for the same. Regarding the body

[0002]

2. Description of the Related Art Generally, a full-color image is expressed by superimposing at least three primary colors of cyan, magenta, and yellow, and a full-color image forming apparatus has a structure in which a plurality of color images are transferred on a transfer medium in an overlapping manner. ing. Specifically, a transfer drum system that sequentially transfers color images to a transfer material fixed on a transfer drum to obtain a full-color image, and a primary transfer of color images to an intermediate transfer member in sequence, and the primary transfer images are batched. It is roughly classified into an intermediate transfer method in which secondary transfer is performed on a transfer material. Comparing these transfer methods, the intermediate transfer method is advantageous in terms of paper-free property and full-page copying.

An image forming apparatus using the intermediate transfer system will be described below. FIG. 1 schematically shows a full-color electrophotographic apparatus using the intermediate transfer system. The latent image formed on the photoconductor 13 is visualized as a toner image of the first color by the developing unit 4, and is primarily transferred to the intermediate transfer body 6 at the contact portion with the intermediate transfer body 6. In the case of full color, this process is repeated for three colors or four colors to form a full color image on the intermediate transfer member 6. Next, the full-color image formed on the intermediate transfer member 6 is transferred onto the transfer material 11 such as paper on the transfer roller 11.
The second transfer is performed on the 4 in a lump. After that, the transfer material 24 is output as a full-color image through a fixing process not shown in FIG. Conventionally, the sweeper brush 8 is provided as a means for supplying a lubricant to the intermediate transfer member.

In such an intermediate transfer system, in order to obtain a sufficient image density, it is necessary that the image formed on the intermediate transfer member is transferred uniformly to the transfer material with a transfer efficiency of 90% or more. Is. However, there is a problem in that a part of the toner to be originally transferred remains on the intermediate transfer member, and there are many abnormal images called so-called worm-eating prints in which the toner is not part of the image. As a means for solving this problem, it has been proposed to use a material such as a fluororesin having excellent releasability from a toner as an intermediate transfer member material, but the worm-eating print has not completely disappeared.
Therefore, as a technique for further improving the insect bite printing, a method of supplying an organic fluorine compound to the surface of an intermediate transfer member is disclosed in JP-A No. 58-187968.
-198476 discloses a method of adding a wettability control agent to an intermediate transfer body material, and JP-A-2-213881 discloses forming a protective film having a lubricating property such as zinc stearate on the surface of the intermediate transfer body. The method of doing is also disclosed in Japanese Patent Laid-Open No. 3-242.
Japanese Patent Publication No. 667 proposes a method of controlling the surface roughness of silicone rubber as an intermediate transfer material. In addition to these techniques for improving the lubricity of the surface of the intermediate transfer member, a technique for mechanically removing the adhered residual toner has been proposed. For example, Japanese Patent Application Laid-Open No. 4-305666 discloses a method of polishing the surface of the intermediate transfer member by providing a contact member of the intermediate transfer member with a peripheral speed difference. A method of polishing the surface when toner filming occurs is disclosed in Japanese Patent Laid-Open No. 5-313526.
Japanese Patent Laid-Open No. 5-323802 proposes a method of polishing after detecting the surface roughness of the intermediate transfer body, and Japanese Patent Laid-Open No. 5-323802 proposes a method of polishing the intermediate transfer body for every fixed number of copies. However, it is difficult to always maintain a stable image quality even by repeated use by the method of supplying a lubricant to the surface of the intermediate transfer body or the method of polishing the surface of the intermediate transfer body. Further, a coating device, a polishing device, and a timing control device therefor are required, which complicates the device and increases the cost.

[0005]

SUMMARY OF THE INVENTION The present invention solves the above-mentioned problems in an image forming apparatus using an intermediate transfer system, that is, the cleaning property of the intermediate transfer member and the toner image from the intermediate transfer member to the transfer material. It is an object of the present invention to provide an image forming apparatus which is excellent in transfer efficiency and can obtain an image that does not particularly cause insect-giving prints even after repeated use.

[0006]

According to the present invention, there is provided an intermediate transfer system in which a negatively charged toner image formed on an image carrier is primarily transferred onto an intermediate transfer member and then secondarily transferred onto a transfer material. In the image forming apparatus, the image forming apparatus is characterized in that the surface material of the intermediate transfer member contains a fluorinated surfactant. Further, according to the present invention, there is provided an image forming apparatus of the above-mentioned intermediate transfer type image forming apparatus, characterized in that the surface material of the intermediate transfer member contains a fluorinated surfactant and a lubricant. . Further, according to the present invention, there is provided an intermediate transfer member used in an image forming apparatus of an intermediate transfer system, characterized in that the surface material contains a fluorinated surfactant. Furthermore, according to the present invention, there is provided an intermediate transfer member for use in an intermediate transfer type image forming apparatus, wherein the surface material contains a fluorine-based surfactant and a lubricant.

In order for the toner image formed on the surface of the intermediate transfer member to be efficiently transferred to the transfer agent, the releasability between the surface of the intermediate transfer member and the toner must be excellent. As in the present invention, by using an intermediate transfer member containing a fluorine-based surfactant having a high releasability, it is possible to suppress the occurrence of insect-eating images. Compared to the conventional intermediate transfer member using a fluorine-based resin, the effect of suppressing the worm-eating image is remarkable.

The fluorosurfactant used in the present invention may be nonionic, anionic, cationic or amphoteric. Specifically, examples of the nonionic fluorosurfactant include a perfluoroalkyl group-lipophilic containing oligomer, a perfluoroalkyl group hydrophilic group-containing oligomer, and a perfluoroalkylethylene oxide adduct. . Further, as the cationic fluorosurfactant, a perfluoroalkyl group-containing quaternary ammonium salt and the like, and as the anionic fluorosurfactant, a perfluoroalkyl group-containing sulfonic acid,
Monovalent metal salts of carboxylic acids, phosphoric acid esters, and the like, and further amphoteric fluorochemical surfactants include betaine containing a perfluoroalkyl group. Regarding these fluorine-based surfactants, for example, reference (R &
D Report No. 6 Fluorine Compound Chemistry and Industry: CM Co., Ltd., pp. 384-411.

Since the fluorine-based surfactant is used by being mixed with the resin forming the intermediate transfer member, it is preferable that the substance has a melting point of 40 ° C. or higher and is solid at room temperature. If the melting point is less than 40 ° C., that is, paste or liquid at room temperature, there is no problem if a small amount is added, but if the addition amount is increased, the surface of the intermediate transfer member becomes sticky and the toner filming occurs. It is not preferable. The particularly preferable melting point of the fluorine-based surfactant is 100 ° C. or higher.

The amount of the fluorine-based surfactant added is 10
It is 1 to 10 parts by weight, preferably 3 to 5 parts by weight, relative to 0 parts by weight. In order to suppress the insect-eating image, the larger the amount of the fluorine-based surfactant added, the more the effect is obtained. Is deteriorated and is not preferable. If the amount of the fluorine-based surfactant added is less than 1 part by weight per 100 parts by weight of the resin, the effect of preventing worm-eating images cannot be sufficiently obtained.

In the intermediate transfer member of the present invention, a lubricant can be added in addition to the above-mentioned fluorine-containing surfactant. By using the lubricant together, a sufficient worm-eating effect can be obtained even if the amount of the fluorosurfactant added is reduced. Since many fluorine-based surfactants are relatively expensive, reducing the amount added is also advantageous in terms of cost. Further, when used in combination with a lubricant, the fluorosurfactant has a melting point of 40.
It can be used even if the temperature is lower than ℃.

As the lubricant, natural waxes such as montan wax, carnauba wax and hydrogenated castor oil; higher fatty acids or their esters, higher fatty acid triglycerides,
Synthetic waxes such as higher aliphatic alcohols or esters thereof, higher fatty acid monoamides and higher fatty acid bisamides;
General waxes such as polyolefin waxes such as polyethylene wax and polypropylene wax, hydrophobic organic resin particles such as fluorine resin particles and silicon resin particles; inorganic solid lubricants such as graphite, molybdenum disulfide and lead oxide Can be mentioned. These may be used alone or in combination of two or more, but have a melting point of 4
It is preferable to use a material having a temperature of 0 ° C. or higher, preferably 100 ° C. or higher.

The content of the fluorinated surfactant and the lubricant is 0.01 to 2 parts by weight, preferably 0.5, with respect to 100 parts by weight of the resin constituting the intermediate transfer member.
1 to 20 parts by weight of the lubricant, preferably 5 to
10 parts by weight. If the amount of the lubricant is less than 1 part by weight, a sufficient worm-eating prevention effect cannot be obtained, and if the amount exceeds 20 parts by weight, the resin strength
Moldability is impaired.

As a base material for the intermediate transfer member, a general resin can be used, but a fluororesin is preferable from the viewpoints of environmental stability of charging, releasability and flame retardancy. The intermediate transfer member may have a single layer structure or a multi-layer structure if necessary. When a multi-layered structure is adopted, it is preferable to use a fluororesin on at least the surface on which an image is formed. As the fluororesin, polytetrafluoroethylene, tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer, tetrafluoroethylene-hexafluoropropylene copolymer, tetrafluoroethylene-hexafluoropropylene-perfluoroalkyl vinyl ether copolymer, tetra Fluoroethylene-ethylene copolymer,
Examples thereof include polychlorotrifluoroethylene copolymer, chlorotrifluoroethylene-ethylene copolymer, polyvinylidene fluoride, polyvinyl fluoride and the like. In the present invention, especially in consideration of molding processability,
Tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer, tetrafluoroethylene-ethylene copolymer, polyvinylidene fluoride and the like are preferable.

The intermediate transfer member is required to have a surface resistance value of 10 ⁷ to 10 ¹² Ω / □ from the image forming process. For this purpose, an inorganic conductive material or the like is added. The resistance value of the intermediate transfer member may be adjusted by a method such as As the inorganic conductive material, conventionally known materials can be used, and examples thereof include carbon black, graphite, metal powder, and metal oxide powder. These may be used in combination of a plurality of types, and are adjusted so as to have a desired resistance value depending on the added amount.

[0016]

Next, the present invention will be described in detail with reference to examples.

Example 1 The following materials were mixed and extrusion-molded to produce a seamless belt-shaped intermediate transfer member. Ethylene-tetrafluoroethylene copolymer resin (ETFE) 100 parts by weight Ketjen Black 20 parts by weight Fluorosurfactant 3 parts by weight (Saflon S-381 (viscous liquid); Asahi Glass) Obtained intermediate transfer member Was attached to a full-color copying machine Puritail 550 manufactured by Ricoh, and the initial test image and the image at the time of outputting 10,000 sheets were observed to evaluate the insect biting image. The results are shown in Table 1. The evaluation was made into 5 levels, and the allowable level rank was 3 or higher. The fluorochemical surfactant is perfluoroacrylate.

Example 2 The amount of the fluorine-based surfactant added in Example 1 was changed to 10
An intermediate transfer member was similarly prepared as a part by weight and evaluated.
The results are shown in Table 1.

Example 3 An intermediate transfer member was prepared and evaluated in the same manner, except that the fluorine-based surfactant used in Example 1 was as follows. The results are shown in Table 1.
Shown in Fluorine-based surfactant 7 parts by weight (EF102 (melting point 250 ° C.); Mitsubishi Metals) The fluorine-based surfactant has a structure represented by the following formula.

Example 4 The following materials were mixed and extrusion-molded to obtain a seamless belt-shaped substrate. Ethylene-tetrafluoroethylene copolymer resin (ETFE) 100 parts by weight Ketjen Black 20 parts by weight A surface layer forming component having the following constitution is spray-coated thereon,
It was used as an intermediate transfer member. {Surface layer-forming component} Fluorine resin (Lumiflon 200; Asahi Glass) 100 parts by weight (solid content) Curing agent for Lumiflon 20 parts by weight Tin oxide conductive particles (S-1; Mitsubishi Materials) 120 parts by weight Fluorosurfactant 1 Parts by weight (EF104 (melting point 250 ° C.); Mitsubishi Metals) Leveling agent (KP321; Shin-Etsu Chemical) 1 part by weight Toluene 200 parts by weight Xylene 200 parts by weight Methyl ethyl ketone 20 parts by weight Evaluation was performed in the same manner as in Example 1 and the results are shown in Table 1. It was shown to. The fluorosurfactant has a structure represented by the following formula.

Example 5 An intermediate transfer member was prepared in the same manner as in Example 4 except that the content of the fluorine-containing surfactant as a constituent of the surface layer was 6 parts by weight, and the evaluation was carried out. The results are shown in Table 1.

Example 6 The following materials were mixed and extrusion-molded to obtain a seamless belt-shaped intermediate transfer member. Ethylene-tetrafluoroethylene copolymer resin (ETFE) 100 parts by weight Ketjen Black 20 parts by weight Fluorosurfactant 0.5 parts by weight (EF102 (melting point 250 ° C .; Mitsubishi Metals) Lubricants 10 parts by weight (Famex L -12 (melting point 230 ° C; Ajinomoto) Evaluation was carried out in the same manner as in Example 1, and the results are shown in Table 1. The lubricants are N-lauroyl and L-rosin.

Example 7 An intermediate transfer member was prepared by adding the following lubricant to the constituent components of the surface layer in Example 4. Lubricant (Kao wax EB-P (melting point 145 ° C.); Kao) 8 parts by weight Evaluation was carried out in the same manner as in Example 1, and the results are shown in Table 1. The lubricant is fatty acid bisamide.

Example 8 An intermediate transfer member was prepared by using the following lubricant instead of the lubricant as a constituent component of the surface layer in Example 6. Lubricant (Luwax OA5 (melting point 100 ° C.); BASF) Evaluation was performed in the same manner as in Example 1, and the results are shown in Table 1. The lubricant is polyethylene wax.

Example 9 An intermediate transfer member was prepared by using the following lubricant instead of the lubricant as a constituent component of the surface layer in Example 6. Lubricant (Luwax S (melting point 81 ° C .; BASF) Evaluation was performed in the same manner as in Example 1, and the results are shown in Table 1. The lubricant is montanic acid wax.

Example 10 An intermediate transfer member was prepared by using the following lubricant instead of the lubricant as a constituent component of the surface layer in Example 6. Lubricant (VTL-L (melting point 15 ° C.); Kawaken Fine Chemicals) Evaluation was performed in the same manner as in Example 1, and the results are shown in Table 1. The lubricant is a fatty acid ester type.

Comparative Example 1 An intermediate transfer member was prepared without using the fluorosurfactant of Example 1 and evaluated in the same manner as in Example 1. The results are shown in Table 1.

Comparative Example 2 An intermediate transfer member was prepared without using the fluorosurfactant of Example 4 and evaluated in the same manner as in Example 1. The results are shown in Table 1.

Comparative Example 3 An intermediate transfer member was prepared without using the fluorosurfactant of Example 6 and evaluated in the same manner as in Example 1. The results are shown in Table 1.

Comparative Example 4 An intermediate transfer member was prepared without using the lubricant of Example 6 and evaluated in the same manner as in Example 1. The results are shown in Table 1.

[0031]

According to the present invention, since the cleaning property of the intermediate transfer member is high and the transfer efficiency of the toner image from the intermediate transfer member to the transfer agent is high, it is possible to obtain a high quality image free from worm-eating images. You can

[0032]

[Brief description of drawings]

FIG. 1 is an explanatory diagram of an image forming apparatus using an intermediate transfer double transfer system.

[Explanation of symbols] 1 charging unit 2 exposure unit 3 potential sensor 4 developing unit 5 P sensor 6 intermediate transfer belt 7 Pcc (pre-cleaning static eliminator) 8 sweeper brush 9 drum cleaning 10 static elimination lamp 11 transfer roller 12 static elimination needle 13 Photoconductor 24 Transfer body

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Mitsuru Seto 1-3-6 Nakamagome, Ota-ku, Tokyo Within Ricoh Co., Ltd. (72) Inventor Shigeru Fukuda 1-3-6 Nakamagome, Ota-ku, Tokyo Shares Company Ricoh

Claims (4)

[Claims] 1. An image forming apparatus of an intermediate transfer system in which a negatively charged toner image formed on an image carrier is primarily transferred onto an intermediate transfer member and then secondarily transferred onto a transfer material. An image forming apparatus, wherein a surface material contains a fluorine-based surfactant. 2. An image forming apparatus of an intermediate transfer system in which a negatively charged toner image formed on an image carrier is primarily transferred onto an intermediate transfer member and then secondarily transferred onto a transfer material. An image forming apparatus characterized in that a surface material contains a fluorinated surfactant and a lubricant. 3. An intermediate transfer member used in an image forming apparatus of an intermediate transfer system, wherein the surface material contains a fluorine-based surfactant. 4. An intermediate transfer member used in an image forming apparatus of an intermediate transfer system, wherein the surface material contains a fluorine-based surfactant and a lubricant. [0001]