JPH08197711A - Doctor blade - Google Patents

Doctor blade

Info

Publication number
JPH08197711A
JPH08197711A JP3421195A JP3421195A JPH08197711A JP H08197711 A JPH08197711 A JP H08197711A JP 3421195 A JP3421195 A JP 3421195A JP 3421195 A JP3421195 A JP 3421195A JP H08197711 A JPH08197711 A JP H08197711A
Authority
JP
Japan
Prior art keywords
doctor blade
resistant layer
wear
plate cylinder
ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3421195A
Other languages
Japanese (ja)
Inventor
Katsuichi Fujimitsu
克一 藤光
Masayoshi Murai
正義 村井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Advanced Technologies Co Ltd
Toppan Inc
Original Assignee
Toyo Advanced Technologies Co Ltd
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Advanced Technologies Co Ltd, Toppan Printing Co Ltd filed Critical Toyo Advanced Technologies Co Ltd
Priority to JP3421195A priority Critical patent/JPH08197711A/en
Publication of JPH08197711A publication Critical patent/JPH08197711A/en
Pending legal-status Critical Current

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Abstract

PURPOSE: To improve wear resistance by coating the surface of a plate-like parent body formed with a material with elasticity with a wear-resistant layer formed of a harder material than the parent body, and specifying the spring const. of a doctor blade and Vickers hardness of the wear-resistant layer respectively to scrape off surely ink by following the rotation of a plate cylinder. CONSTITUTION: A doctor blade 1 consists of a plate-like body material 11 formed of a material with elasticity and a wear-resistant layer 12 with which the surface of the body material is coated. In addition, the spring const. of the doctor blade 1 is 2.5-5.0N/mm. When the value is under 2.5N/mm, as the blade can not completely scrape the ink on a plate cylinder, doctor stripes are generated and when it exceeds 5.0N/mm, as the doctor blade 1 can not follow the vibration under a tightly contact condition, leakage of scraping of the ink occurs. As the wear-resistant layer 12 of the doctor blade 1, a material harder than the parent body 11 is used and the Vickers hardness is in the range of 1,000-3,800. As the method for coating the body material 11 with the wear-resistant layer 12, a CVD method and a PVD method are used.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、グラビア印刷等に用い
られるドクター刃に関するもであって、特に長期間の使
用に耐えるドクター刃に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a doctor blade used for gravure printing or the like, and more particularly to a doctor blade capable of withstanding long-term use.

【0002】[0002]

【従来の技術】一般に、凹版印刷装置は版胴の円周面に
ドクター刃を所定の押圧力で押圧しておき、この版胴の
非画線部に付着したインキを除去するように構成されて
いる。ドクター刃の使用目的は、上記版胴の非画線部に
付着した余分なインキを完全に除去すると共に、画線部
内には所定量のインキを残しておくことにある。このよ
うなドクター刃の先端縁は常時版胴と摺動しているた
め、耐摩耗性が必要である。特に最近は、印刷速度の高
速化、大量印刷に対応し、耐摩耗性の高いドクター刃が
要求されている。
2. Description of the Related Art Generally, an intaglio printing apparatus is constructed so that a doctor blade is pressed against a circumferential surface of a plate cylinder with a predetermined pressing force to remove ink adhering to a non-image area of the plate cylinder. ing. The purpose of using the doctor blade is to completely remove the excess ink adhering to the non-image area of the plate cylinder while leaving a predetermined amount of ink in the image area. Since the tip edge of such a doctor blade constantly slides on the plate cylinder, abrasion resistance is required. Particularly in recent years, there has been a demand for doctor blades having high abrasion resistance and high printing speed and high-volume printing.

【0003】しかしながら、従来のドクター刃は鋼板が
用いられており、耐摩耗性が低い。そこで耐摩耗性の向
上をはかるために表面に硬質被膜を形成したドクター刃
が開発されている。例えば、特表昭62−503085
号に示されるドクター刃には、耐摩耗性をあげるため
に、ドクター刃の表面に針金火炎溶射やプラズ溶射によ
り硬質の基材を積層している。この方法では、ドクター
刃の表面に平滑な層が積層出来ず、表面が凹凸形状とな
る。ドクター刃の表面に凹凸形状が出来ると、インキを
十分にかきとることができず、ドクター筋という印刷不
良が発生し印刷物の不良を招くため、表面を研磨する必
要がある。
However, a conventional doctor blade uses a steel plate and has low wear resistance. Therefore, in order to improve wear resistance, doctor blades having a hard coating on the surface have been developed. For example, special table Sho 62-503085
In order to improve wear resistance, the doctor blade shown in No. 3 has a hard base material laminated on the surface of the doctor blade by wire flame spraying or plasm spraying. In this method, a smooth layer cannot be laminated on the surface of the doctor blade, and the surface becomes uneven. If the surface of the doctor blade has an uneven shape, the ink cannot be sufficiently scraped off, and a printing defect called a doctor streak occurs, which leads to a defective printed matter. Therefore, the surface needs to be polished.

【0004】また、この硬質被膜はドクター刃の一部分
にしか設けられていない為、耐摩耗層が被覆されていな
い部分から腐食が起こり、ドクター刃が折れることもあ
った。
Further, since the hard coating is provided only on a part of the doctor blade, corrosion may occur from the part not coated with the wear resistant layer and the doctor blade may be broken.

【0005】[0005]

【発明が解決しようとする課題】本発明の目的は、版胴
の非画線部に付着したインキを除去するための所定の硬
度を保持しながらも、ドクター刃の表面に凹凸形状がな
く、版胴の回転に追従する耐摩耗性を有するドクター刃
を提供することにある。
SUMMARY OF THE INVENTION An object of the present invention is to maintain a predetermined hardness for removing ink adhering to the non-image area of the plate cylinder, but to have no irregular shape on the surface of the doctor blade. An object of the present invention is to provide a doctor blade having abrasion resistance that follows the rotation of the plate cylinder.

【0006】[0006]

【課題を解決するための手段】本発明者らは前記の課題
について鋭意努力を重ねた結果、本発明を完成するに至
った。
Means for Solving the Problems The inventors of the present invention have completed the present invention as a result of earnest efforts for the above problems.

【0007】本発明は、弾性を有する材料で形成された
板状の母体と、この母体の表面に被覆され、この母材よ
り硬質の材料で形成された耐摩耗層を具備し、ドクター
刃のバネ定数が2.5〜5.0N/mmであり、耐摩耗層
のビッカーズ硬度が1000〜3800Hvであること
を特徴とするドクター刃を提供するものである。
According to the present invention, there is provided a plate-shaped base body made of a material having elasticity, and a wear resistant layer formed on the surface of the base body and made of a material harder than the base material. A doctor blade having a spring constant of 2.5 to 5.0 N / mm and a Vickers hardness of the wear resistant layer of 1000 to 3800 Hv.

【0008】また、前記ドクター刃全体を、母材より硬
質の材料で形成された耐摩耗層で被覆してなるドクター
刃をも提供するものである。
Further, the present invention also provides a doctor blade in which the entire doctor blade is covered with a wear resistant layer formed of a material harder than the base material.

【0009】[0009]

【作用】ドクター刃のバネ定数を2.5〜5.0N/mm
にすることにより、版胴の回転に追従して確実にインキ
をかき取ることができる。また、表面に母材より硬質の
材料を被覆したことにより、耐摩耗性が向上し、ドクタ
ー刃の寿命が長くなる。
[Operation] The spring constant of the doctor blade is 2.5-5.0 N / mm
By doing so, the ink can be reliably scraped off following the rotation of the plate cylinder. Further, by coating the surface with a material harder than the base material, the wear resistance is improved and the life of the doctor blade is extended.

【0010】[0010]

【実施例】以下、図面を参照して本発明をさらに具体的
に説明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described more specifically with reference to the drawings.

【0011】図1には、本発明のドクター刃を使用する
凹版印刷装置の一具体例を示す。図1において、本発明
のドクター刃1は保持機構2により版胴3の側方に保持
される。該版胴の下方にはインキ供給槽4が設けられて
おり、該インキ供給槽の中にはインキ5が貯溜されてい
る。前記版胴3が回転するとこの版胴3の周囲にインキ
が付着し、版胴に所定の角度及び押圧力で押圧されてい
る前記ドクター刃1によって版胴の非画線部に付着した
インキを除去するように構成されている。版胴3の上方
には圧胴6が転接され、これらの間に供給される紙葉7
に画線部内に保持されているインキを転写する。
FIG. 1 shows a specific example of an intaglio printing apparatus using the doctor blade of the present invention. In FIG. 1, the doctor blade 1 of the present invention is held laterally of the plate cylinder 3 by a holding mechanism 2. An ink supply tank 4 is provided below the plate cylinder, and ink 5 is stored in the ink supply tank. When the plate cylinder 3 rotates, ink adheres to the periphery of the plate cylinder 3, and the ink adhered to the non-image area of the plate cylinder is removed by the doctor blade 1 pressed against the plate cylinder at a predetermined angle and pressing force. It is configured to remove. An impression cylinder 6 is rollingly contacted above the plate cylinder 3 and paper sheets 7 supplied between them.
The ink held in the image area is transferred to.

【0012】また、図2は本発明のドクター刃の一具体
例を示す断面図である。図2において、ドクター刃1
は、弾性を有する材料で形成された板状の母体11と該
母体の表面に被着された耐摩耗層12とからなる。前記
母体は、その両縁部がより肉薄となるように研削加工さ
れており、刃先部13aおよび13bが形成されてい
る。
FIG. 2 is a sectional view showing a specific example of the doctor blade of the present invention. In FIG. 2, the doctor blade 1
Is composed of a plate-shaped base 11 made of an elastic material and a wear resistant layer 12 attached to the surface of the base. The mother body is ground so that both edges thereof are thinner, and blade edges 13a and 13b are formed.

【0013】本発明のドクター刃の母体としては、弾性
を有する材料が好ましく、例えば、熱処理された炭素
鋼、ステンレス鋼、チタン合金等の金属材料、または各
種の複合材料など従来ドクター刃の材料として公知のも
のがいずれも用いられる。
As the base material of the doctor blade of the present invention, a material having elasticity is preferable. For example, as a material of a conventional doctor blade such as a heat-treated metal material such as carbon steel, stainless steel, titanium alloy or various composite materials. Any known one can be used.

【0014】上記母体材料は厚みが100〜200μm
の薄板状であり、長さが750〜2000mmとなるよ
うに切断し、さらに両縁部を厚さ40〜150μm、長
さ0.1〜0.5mmとなるように研削加工して刃先部を
形成するのが好ましい。
The base material has a thickness of 100 to 200 μm.
It is a thin plate shape and is cut so that the length is 750 to 2000 mm, and both edges are further ground to have a thickness of 40 to 150 μm and a length of 0.1 to 0.5 mm to form a cutting edge portion. It is preferably formed.

【0015】ドクター刃の母体の厚みが100μmより
薄い場合は2.5N/mm以上のバネ定数が得られず、
版胴上のインキを完全にかき取ることが出来ないためド
クター筋が生じ、好ましくない。一方、厚さが200μ
mを超えると剛性が大きすぎるため版胴の摩耗が激し
く、また、バネ定数が5.0N/mmを超え、大きすぎ
るため、版胴の振れに密着した状態でドクター刃が追随
せず部分的にインキのかき取り漏れが生じるといった不
良が生じるため好ましくない。
When the thickness of the base body of the doctor blade is less than 100 μm, a spring constant of 2.5 N / mm or more cannot be obtained,
Since the ink on the plate cylinder cannot be completely scraped off, doctor streaks occur, which is not preferable. On the other hand, the thickness is 200μ
If it exceeds m, the rigidity of the plate cylinder will be too great, and the plate cylinder will be worn too much. Also, since the spring constant will exceed 5.0 N / mm and it will be too large, the doctor blade will not follow it while sticking to the runout of the plate cylinder It is not preferable because a defect such as scratching and leakage of ink occurs.

【0016】さらに、刃先部の厚さが40μmより薄い
場合は版胴に押圧した際折れる等の不良が生じ、インキ
を十分にかきとることができず、ドクター筋を発生させ
て印刷物の不良を招く。また、厚さが150μmを超え
る場合には、逆に版胴の方がすぐに摩耗し、その版胴の
寿命が短くなる等の不都合が生じる。
Further, when the thickness of the cutting edge portion is thinner than 40 μm, defects such as breakage occur when pressed against the plate cylinder, ink cannot be sufficiently scraped off, and doctor streaks are generated to cause defects in printed matter. Invite. On the other hand, when the thickness exceeds 150 μm, on the contrary, the plate cylinder wears more quickly and the life of the plate cylinder is shortened.

【0017】本発明のドクター刃の耐摩耗層には母体よ
り硬質の材料を用い、ビッカース硬度は1000〜38
00Hvの範囲であることが好ましい。かかる材料とし
ては、例えば、TiN、ZnO2、TiC、TiCN、
Al23、W2C、CrN、TiAlN、SiO2、Ti
2等のセラミック材料、あるいはMo、Ni等の硬質
の金属材料などが挙げられる。
A material harder than the base material is used for the wear resistant layer of the doctor blade of the present invention, and the Vickers hardness is 1000 to 38.
It is preferably in the range of 00 Hv. Examples of such a material include TiN, ZnO 2 , TiC, TiCN,
Al 2 O 3 , W 2 C, CrN, TiAlN, SiO 2 , Ti
Examples thereof include ceramic materials such as O 2 and hard metal materials such as Mo and Ni.

【0018】前記耐摩耗層を母体に被覆する方法として
は、CVD法、PVD法、低圧プラズマ溶射などを用い
ることができるが、CVD法またはPVD法が特に好ま
しい。CVD法またはPVD法により被覆した場合は、
被覆表面の粗さが、溶射法等に比較して5分の1以下と
はるかに小さく、ドクター筋が発生しない等の利点があ
る。
As a method of coating the wear resistant layer on the base material, a CVD method, a PVD method, a low pressure plasma spraying method or the like can be used, and a CVD method or a PVD method is particularly preferable. When coated by CVD method or PVD method,
The roughness of the coating surface is much smaller than one-fifth or less as compared with the thermal spraying method and the like, and there is an advantage that doctor streaks do not occur.

【0019】耐摩耗層の被覆厚は5〜50μmが好まし
い。耐摩耗層の被覆厚が5μmより薄いと所定の耐摩耗
性が得られないため好ましくない。また、耐摩耗層の被
覆厚が50μmを超えるとドクター刃自体のバネ定数が
高くなり過ぎ、版胴が摩耗するため好ましくない。
The coating thickness of the wear resistant layer is preferably 5 to 50 μm. If the wear-resistant layer has a coating thickness of less than 5 μm, predetermined wear resistance cannot be obtained, which is not preferable. Further, if the coating thickness of the wear resistant layer exceeds 50 μm, the spring constant of the doctor blade itself becomes too high, and the plate cylinder wears, which is not preferable.

【0020】つぎに、所定のドクター刃(鋼板:EBE
RLE社製−ドイツ、厚さ150μm)に下記の硬質被
膜をCVD法により被覆したもの(試験No.1〜1
5)を評価した。それぞれの評価結果を表1に示す。
Next, a predetermined doctor blade (steel plate: EBE
RLE (Germany, thickness 150 μm) coated with the following hard coating by the CVD method (Test Nos. 1 to 1)
5) was evaluated. The evaluation results are shown in Table 1.

【0021】表中のビッカース硬度はビッカース硬度計
にて測定した。また、本発明のドクター刃のバネ定数
は、以下の方法で測定した。概略図を図3に示す。はじ
めにドクター刃1の両刃先部の付け根の下にそれぞれ支
持台22を置く。そして、ドクター刃1の長さ方向の中
心点を上から圧子23で荷重:Pをかけ、その際のドク
ター刃1のたわみ:δを測定し、P/δよりバネ定数:
kを求めた。
The Vickers hardness in the table was measured with a Vickers hardness meter. The spring constant of the doctor blade of the present invention was measured by the following method. A schematic diagram is shown in FIG. First, the support bases 22 are placed under the roots of the two blade tips of the doctor blade 1. Then, a load: P is applied from above the center point of the doctor blade 1 in the longitudinal direction by the indenter 23, the deflection of the doctor blade 1 at that time: δ is measured, and the spring constant from P / δ:
I asked for k.

【0022】k=P/δ=(4Ebt3)/l3 式中、lは支持台間の距離(mm)、bはドクター刃の
幅(mm)、tはドクター刃の厚さ(mm)そしてEは
ヤング率をそれぞれ表す。本発明では支持台間の距離l
を30mm、ドクター刃の幅bを25mm、として測定
した。
K = P / δ = (4Ebt 3 ) / l 3 where l is the distance between supporting bases (mm), b is the width of the doctor blade (mm), and t is the thickness of the doctor blade (mm). E represents Young's modulus. In the present invention, the distance l between the supports is
Was 30 mm and the width b of the doctor blade was 25 mm.

【0023】 [表1] ━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━ 耐摩耗層 ───────────────── 試験No. 被膜材料 厚み ビッカース硬度 バネ定数 評価a) (μm) (Hv) (N/mm) ──────────────────────────────────── 1 ZrO2 2 1100 2.9 A 2 ZrO2 5 1100 3.7 B 3 ZrO2 10 1200 4.1 B 4 ZrO2 14 1150 4.3 B 5 ZrO2 20 1150 4.8 B 6 ZrO2 60 1150 5.3 C 7 Al23 10 1300 4.5 B 8 ZrO2 10 900 3.9 D 9 Al23 10 1100 4.2 B 10 TiN 10 1100 4.4 B 11 CrN 5 2100 2.5 B 12 TiC 10 3800 3.9 B 13 TiCN 10 2500 3.9 B 14 TiAlN 5 2500 3.9 B 15 W2C 10 2200 3.9 B ━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━ a)評価基準 A:厚みが薄いため、耐摩耗性に問題があった。[Table 1] ━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━ Abrasion resistant layer ──── ───────────── Test No. Coating material Thickness Vickers hardness Spring constant evaluation a) (μm) (Hv) (N / mm) ───────────────────────────── ─────── 1 ZrO 2 2 1100 2.9 A 2 ZrO 2 5 1100 3.7 B 3 ZrO 2 10 1200 1200 4.1 B 4 ZrO 2 14 1150 4.3 B 5 ZrO 2 20 1150 4. 8 B 6 ZrO 2 60 1150 5.3 C 7 Al 2 O 3 10 1300 4.5 B 8 ZrO 2 10 900 3.9 D 9 Al 2 O 3 10 1100 4.2 B 10 TiN 10 1100 4.4 B 11 CrN 5 2100 2.5 B 12 TiC 10 3800 3.9 B 13 TiCN 10 2500 3.9 B 14 TiAlN 5 2500 3.9 B 15 W 2 C 10 2200 3.9 B ━━━━━━━━━━━━━━━━━━ ━━━━━━━━━━━ ━━━━━━━━━━━━━━━━━ a) Evaluation criteria A: Since the thickness is thin, there was a problem in wear resistance.

【0024】B:耐摩耗性も良好で、ドクター筋の発生
はなかった。
B: Abrasion resistance was also good, and no doctor streak was generated.

【0025】C:耐摩耗性に問題はなかったが、バネ定
数が高くなり過ぎたため、逆に版胴の方の寿命が短くな
った。
C: There was no problem in wear resistance, but since the spring constant became too high, the life of the plate cylinder was shortened.

【0026】D:ドクター刃の耐摩耗性が悪く、寿命が
短かった。
D: The wear resistance of the doctor blade was poor and the life was short.

【0027】[0027]

【発明の効果】本発明のドクター刃を用いることによ
り、耐摩耗性が向上した。また、ドクター刃の耐摩耗層
の形成にCVD法およびPVD法を適用することで表面
の凹凸がなくなり、ドクター筋の発生がなくなった。さ
らに、ドクター刃全体を耐摩耗層で被覆することによ
り、ドクター刃の腐食が生じなくなり、ドクター刃の寿
命が長くなった。
By using the doctor blade of the present invention, the wear resistance is improved. Further, by applying the CVD method and the PVD method to the formation of the wear resistant layer of the doctor blade, the unevenness of the surface was eliminated and the generation of the doctor stripe was eliminated. Furthermore, by coating the entire doctor blade with a wear resistant layer, corrosion of the doctor blade did not occur and the life of the doctor blade was extended.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明のドクター刃を使用する凹版印刷装置の
一具体例である。
FIG. 1 is a specific example of an intaglio printing apparatus using a doctor blade of the present invention.

【図2】本発明のドクター刃の一具体例を示す断面図で
ある。
FIG. 2 is a sectional view showing a specific example of a doctor blade of the present invention.

【図3】ドクター刃のバネ定数の測定法を示す概略図で
ある。
FIG. 3 is a schematic diagram showing a method for measuring a spring constant of a doctor blade.

【符号の説明】[Explanation of symbols]

1 ドクター刃 2 保持機構 3 版胴 4 インキ供給槽 5 インキ 6 圧胴 7 紙葉 11 母体 12 耐摩耗層 13a 刃先部 13b 刃先部 22 支持台 23 圧子 DESCRIPTION OF SYMBOLS 1 Doctor blade 2 Holding mechanism 3 Plate cylinder 4 Ink supply tank 5 Ink 6 Pressure cylinder 7 Paper sheet 11 Base 12 Wear resistant layer 13a Blade tip 13b Blade tip 22 Support base 23 Indenter

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 弾性を有する材料で形成された板状の母
体と、この母体の表面に被覆され、この母材より硬質の
材料で形成された耐摩耗層を具備してなるドクター刃で
あって、該ドクター刃のバネ定数が2.5〜5.0N/m
mであり、かつ耐摩耗層のビッカーズ硬度が1000〜
3800Hvであるドクター刃。
1. A doctor blade comprising a plate-shaped base body formed of a material having elasticity and a wear-resistant layer formed on the surface of the base body and formed of a material harder than the base material. And the spring constant of the doctor blade is 2.5-5.0 N / m
m, and the Vickers hardness of the wear resistant layer is 1000 to
Doctor blade that is 3800 Hv.
【請求項2】 前記ドクター刃全体を、母材より硬質の
材料で形成された耐摩耗層で被覆してなる請求項1のド
クター刃。
2. The doctor blade according to claim 1, wherein the entire doctor blade is covered with a wear-resistant layer formed of a material harder than the base material.
JP3421195A 1995-01-30 1995-01-30 Doctor blade Pending JPH08197711A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3421195A JPH08197711A (en) 1995-01-30 1995-01-30 Doctor blade

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3421195A JPH08197711A (en) 1995-01-30 1995-01-30 Doctor blade

Publications (1)

Publication Number Publication Date
JPH08197711A true JPH08197711A (en) 1996-08-06

Family

ID=12407834

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3421195A Pending JPH08197711A (en) 1995-01-30 1995-01-30 Doctor blade

Country Status (1)

Country Link
JP (1) JPH08197711A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0908309A1 (en) * 1997-10-08 1999-04-14 Rolf Meyer Printing squeegee and method for its manufacturing
US6155167A (en) * 1999-01-21 2000-12-05 Meyer; Rolf Printing doctor with a coating of hard material and method for producing same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0908309A1 (en) * 1997-10-08 1999-04-14 Rolf Meyer Printing squeegee and method for its manufacturing
US6155167A (en) * 1999-01-21 2000-12-05 Meyer; Rolf Printing doctor with a coating of hard material and method for producing same

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