JPH08173097A - Meat modifier, oil and fat composition for meat cooking and meat and cooked meat product treated therewith - Google Patents

Meat modifier, oil and fat composition for meat cooking and meat and cooked meat product treated therewith

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Publication number
JPH08173097A
JPH08173097A JP6337818A JP33781894A JPH08173097A JP H08173097 A JPH08173097 A JP H08173097A JP 6337818 A JP6337818 A JP 6337818A JP 33781894 A JP33781894 A JP 33781894A JP H08173097 A JPH08173097 A JP H08173097A
Authority
JP
Japan
Prior art keywords
meat
ester
oil
monoglyceride
cooking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6337818A
Other languages
Japanese (ja)
Other versions
JP3208269B2 (en
Inventor
Manabu Toi
学 戸井
Yumiko Ono
由美子 大野
Hirotaka Sasaki
博隆 佐々木
Takaaki Yokoyama
高明 横山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP33781894A priority Critical patent/JP3208269B2/en
Publication of JPH08173097A publication Critical patent/JPH08173097A/en
Application granted granted Critical
Publication of JP3208269B2 publication Critical patent/JP3208269B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE: To provide a meat modifier which comprises an ester of monoor diglyceride and a polycarboxylic acid and a polyglycerol fatty acid ester, thus gives tasty meat flexible in meat texture and rich in broth as it suppresses meat-staining and reduces foaming on cooking. CONSTITUTION: This meat modifier comprises an ester of a mono- or diglyceride and a polycarboxylic acid, preferably an ester of a monoglyceride of a 12-22C fatty acid and succinic acid or an ester of a monoglyceride of a 12-22C fatty acid and diacetyl-tartaric acid and a plyglycerol fatty acid (preferably of 10 or less HLB).

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、柔らかい肉質で、肉汁
に富み、良好な風味の肉を提供できる肉の改質剤、食肉
調理用油脂組成物及びこれらのもので処理した食用肉又
は肉製品に関する。特に、本発明は、上記のような風味
良好な肉を得るのに際して加熱調理時の油の汚れ、泡の
発生を抑え、快適に調理を行うことができる肉の改質
剤、食肉調理用油脂組成物及びこれで処理した食用肉又
は肉製品に関する。
FIELD OF THE INVENTION The present invention relates to a meat modifier, a meat cooking oil and fat composition capable of providing meat having a tender meat quality, rich in gravy and having a good flavor, and edible meat or meat treated with them. Regarding the product. In particular, the present invention is a meat modifier and a meat cooking oil or fat that can suppress the generation of oil stains and bubbles during heating and can comfortably cook when obtaining meat with a good flavor as described above. Compositions and edible meats or meat products treated therewith.

【0002】[0002]

【従来の技術】牛、豚などの畜肉、鳥、カモなどの鳥肉
を用いた肉料理は数多くあるが、これらの調理に際して
の焼く、炒める、揚げるなどの調理方法に拘らず肉は、
適度な柔らかさを有し、そしてうま味成分である肉汁に
富んだ状態(ジューシーな状態)で食べられることが望
ましい。特に、例えばステーキやカツフライなどの加工
品でない鳥獣等の比較的大きな肉片を用いた肉料理やこ
れらの肉を原料とした挽き肉を主成分とするハンバーグ
などの成型食品においては、柔らかさやジューシーさは
肉をおいしく食べる重要な要素となる。しかし、一般に
上記のような肉、特にある程度の大きさを持つ肉片は加
熱調理で固く締まる性質があり、また肉汁も流出して失
われる傾向にある。また肉質が余り良くない肉の場合に
は、上記の硬さと共にスジっぽさも加わり、更に食感が
低下するとの問題もある。従って、このような肉を使用
した料理においても柔らかく、良好な食感でおいしく食
べることができる肉の改良が望まれる。
BACKGROUND OF THE INVENTION There are many meat dishes using livestock meat such as beef and pork, and poultry such as birds and ducks. Meat is irrespective of the cooking method such as baking, frying or frying when cooking.
It is desirable that it has moderate tenderness and can be eaten in a state (juicy state) rich in gravy, which is an umami ingredient. In particular, for example, meat dishes that use relatively large meat pieces such as birds and beasts that are not processed products such as steaks and cutlets, and molded foods such as hamburgers whose main ingredient is ground meat from these meats, the softness and juiciness are It becomes an important factor to eat meat deliciously. However, in general, the above-mentioned meat, in particular, a piece of meat having a certain size has a property of being tightly tightened by cooking, and the gravy also tends to flow out and be lost. In addition, in the case of meat whose meat quality is not very good, there is a problem that the above-mentioned hardness is accompanied by a streak-like texture and the texture is further deteriorated. Therefore, it is desired to improve meat that is soft and can be eaten deliciously with a good texture even in a dish using such meat.

【0003】従来から肉を柔らかくしたりあるいは肉の
保存性を高めたり等の肉を改質する方法には種々の方法
が知られている。例えば、有機酸モノグリセリド(例、
アセチル化モノグリセリド)を使用する方法(特開昭4
9−20353号公報)、レシチンを添加した植物性液
状油脂に肉を漬け込む方法(特開昭54−62356号
公報)、カルシウム塩に重炭酸ナトリウムとHLB10
以上の乳化剤(例、ショ糖脂肪酸エステル)との少なく
とも一方を加えた軟化剤を使用する方法(特開平4−1
48663号公報)、塩類等を使用する方法(特開平4
−36167号、及び特開昭61−239862号各公
報)、及び蛋白質分解酵素を使用する方法(特開昭59
−151839号、特開平4−278063号、同5−
7476号、及び同5−252911号各公報)などが
ある。
Conventionally, various methods are known as methods for modifying meat such as softening the meat or improving the storage stability of the meat. For example, organic acid monoglyceride (eg,
Method using acetylated monoglyceride (JP-A-4)
9-20353), a method of immersing meat in a vegetable liquid oil containing lecithin (JP-A-54-62356), sodium bicarbonate and HLB10 in calcium salt.
A method of using a softening agent to which at least one of the above-mentioned emulsifiers (eg, sucrose fatty acid ester) is added (JP-A-4-1).
No. 48663), a method of using salts, etc.
-36167 and JP-A-61-239862), and a method using a proteolytic enzyme (JP-A-59).
-151839, JP-A-4-278063, and 5-
Nos. 7476 and 5-252911).

【0004】また柔らかく、ふっくらとした食感及び/
又はジューシー感に富んだ挽き肉を主成分とする成型食
品を得ることを目的として、例えば、成型食品に重炭酸
ナトリウム、酸性剤及び安定剤を配合する方法(特開昭
54−59359号公報)、食用油脂、天然ワックス及
び食用界面活性剤からなる組成物を使用する方法(特開
平1−228427号公報)、水中油滴型乳化液を成型
食品に配合する方法(特開平5−103632号公
報)、及び油中水中油滴型乳化物を成型食品に配合する
方法(特開平5−176721号公報)などの方法も知
られている。
In addition, the soft and plump texture and /
Alternatively, for the purpose of obtaining a molded food product containing ground meat rich in juicy texture, for example, a method of adding sodium bicarbonate, an acidifying agent and a stabilizer to the molded food product (JP-A-54-59359), A method of using a composition comprising edible oil and fat, a natural wax and an edible surfactant (JP-A-1-228427), and a method of incorporating an oil-in-water emulsion in a molded food (JP-A-5-103632). , And a method of blending an oil-in-water-in-oil emulsion with a molded food (Japanese Patent Laid-Open No. 5-176721).

【0005】[0005]

【発明が解決しようとする課題】本願出願人は、上記の
ような方法に比べて肉質が柔らかく、肉汁に富み、良好
な風味の肉を提供できる肉の改質剤として、モノグリセ
リドあるいはジグリセリドとポリカルボン酸とのエステ
ルを含有する肉の改質剤について特許出願した(特願平
5−343815号)。本発明者は、上記のような肉の
改質剤についてその後更に研究を進めた。それによる
と、上記のようなエステルを含有する肉の改質剤を使用
して調理した場合、特に素材である肉が脂肪分を比較的
多く含む肉、例えば、バラ肉やステーキのような肉を用
いて焼く、炒めるなどの加熱調理をした場合に、調理器
具に予め敷いて使用する油(所謂敷き油)が調理中に黒
く汚れたり、またあくのような泡が発生し易いことが判
明した。
The applicant of the present invention has found that monoglyceride or diglyceride and polyglyceride can be used as a meat modifier capable of providing meat that is softer in meat quality, rich in gravy and has a good flavor as compared with the above method. A patent application was filed for a meat modifier containing an ester with a carboxylic acid (Japanese Patent Application No. 5-343815). The present inventor further advanced the research on the above-mentioned meat modifier. According to this, when cooked using the above-mentioned ester-containing meat modifier, the meat that is a raw material has a relatively large amount of fat, for example, meat such as rose meat and steak. It was found that the oil (so-called spreading oil) laid on the cooking utensil in advance (so-called spreading oil) is easily stained black or bubbles such as drilling are easily generated when cooked by using did.

【0006】従って、本発明の目的は、上記のような肉
の加熱調理の際の油の汚れや泡の発生を抑制でき、快適
に調理を行うことができ、肉質が柔らかく、肉汁に富ん
だおいしい肉を提供できる肉の改質剤、食肉調理用油脂
組成物及びこれらを用いて処理した食用肉又は肉製品を
提供することである。
Therefore, an object of the present invention is to suppress the generation of oil stains and bubbles during the above-described cooking of meat by heating, which enables comfortable cooking, has a soft meat quality and is rich in gravy. It is intended to provide a meat modifier capable of providing delicious meat, an oil and fat composition for cooking meat, and an edible meat or a meat product treated with the composition.

【0007】[0007]

【課題を解決するための手段】本発明は、モノグリセリ
ドあるいはジグリセリドとポリカルボン酸とのエステル
及びポリグリセリン脂肪酸エステルを含有する肉の改質
剤にある。
The present invention resides in a meat modifier containing an ester of a monoglyceride or diglyceride and a polycarboxylic acid and a polyglycerin fatty acid ester.

【0008】また本発明は、モノグリセリドあるいはジ
グリセリドとポリカルボン酸とのエステル及びポリグリ
セリン脂肪酸エステルを含有する肉の改質剤で処理した
食用肉又は肉製品にもある。
The invention also resides in an edible meat or meat product treated with a meat modifier containing an ester of a monoglyceride or diglyceride with a polycarboxylic acid and a polyglycerin fatty acid ester.

【0009】更に本発明は、食用油脂中に、モノグリセ
リドあるいはジグリセリドとポリカルボン酸とのエステ
ル及びポリグリセリン脂肪酸エステルが溶解又は分散さ
れてなる食肉調理用油脂組成物にもある。
Furthermore, the present invention also provides a fat and oil composition for cooking meat, which is obtained by dissolving or dispersing an ester of a monoglyceride or a diglyceride and a polycarboxylic acid and a polyglycerin fatty acid ester in the edible fat and oil.

【0010】更にまた本発明は、食用油脂中に、モノグ
リセリドあるいはジグリセリドとポリカルボン酸とのエ
ステル及びポリグリセリン脂肪酸エステルが溶解又は分
散されてなる食肉調理用油脂組成物で処理した食用肉又
は肉製品にもある。
Furthermore, the present invention provides an edible meat or meat product which has been treated with an oil and fat composition for meat cooking which comprises an ester of a monoglyceride or diglyceride and a polycarboxylic acid and a polyglycerin fatty acid ester dissolved or dispersed in the edible oil and fat. There is also

【0011】本発明者の検討によると、ポリグリセリン
脂肪酸エステルが添加された改質剤及び油脂組成物を用
いることにより、加熱調理の際に生じる油の汚れや泡の
発生が抑えられ、快適に調理でき、柔らかい肉質で肉汁
に富んだおいしい肉が得られることを見出し、本発明に
到達したものである。なお、上記のように肉が改質され
る理由は明らかではないが、特に畜肉や鳥肉から得られ
たある程度の大きさの肉片、あるいはこれらを原料とし
て得た挽き肉を主成分とする成型食品においては、腱等
の硬質タンパク(コラーゲン)が比較的多く含まれ、こ
れが加熱調理に際して収縮、凝集し、その結果、肉が締
まり、固くなると考えられる。本発明の改質剤、油脂組
成物を使用することにより、これらに含まれるモノグリ
セリドあるいはジグリセリドとポリカルボン酸とのエス
テルにより、タンパク質の収縮が抑制され、その結果、
柔らかな肉が得られると考えられる。また挽き肉を主成
分とする成型食品においては、肉の柔らかさやジューシ
ーさと共に、ふっくらした食感も付与され、よりおいし
い成型食品を得ることができる。
According to the study of the present inventor, the use of the modifier and the oil / fat composition to which the polyglycerin fatty acid ester is added suppresses the generation of oil stains and bubbles generated during heating and makes it comfortable. The inventors of the present invention have found that delicious meat that can be cooked, has a tender meat quality, and is rich in gravy can be obtained, and has arrived at the present invention. The reason why the meat is modified as described above is not clear, but a piece of meat of a certain size particularly obtained from livestock meat or poultry, or a molded food containing the minced meat obtained from these as a raw material as a main component. In, the hard protein (collagen) such as tendons is contained in a relatively large amount, and it is considered that this shrinks and agglomerates during cooking, and as a result, the meat becomes tight and hard. By using the modifier and oil composition of the present invention, the shrinkage of protein is suppressed by the ester of monoglyceride or diglyceride and polycarboxylic acid contained therein, and as a result,
It is believed that tender meat is obtained. In addition, the molded food containing ground meat as a main component is given a soft texture and juiciness as well as a plump texture, so that a more delicious molded food can be obtained.

【0012】本発明の好ましい態様は以下の通りであ
る。 (1)上記モノグリセリドとポリカルボン酸とのエステ
ルが、炭素数12〜22の飽和又は不飽和の脂肪酸のモ
ノグリセリドとコハク酸とのエステル、又は炭素数12
〜22の飽和又は不飽和の脂肪酸のモノグリセリドとジ
アセチル酒石酸とのエステルである。 (2)ポリグリセリン脂肪酸エステルがHLB10未満
(更に好ましくはHLB4以下)のポリグリセリン脂肪
酸エステルである。 (3)モノグリセリドあるいはジグリセリドとポリカル
ボン酸とのエステルとポリグリセリン脂肪酸エステルと
の混合重量比が、100:1〜1:5(更に好ましく
は、10:1〜1:2)である。
Preferred embodiments of the present invention are as follows. (1) The ester of the monoglyceride and the polycarboxylic acid is an ester of a monoglyceride of a saturated or unsaturated fatty acid having 12 to 22 carbon atoms and succinic acid, or 12 carbon atoms.
~ 22 esters of saturated or unsaturated fatty acid monoglycerides with diacetyltartaric acid. (2) The polyglycerin fatty acid ester is a polyglycerin fatty acid ester having an HLB of less than 10 (more preferably HLB of 4 or less). (3) The mixing weight ratio of the ester of monoglyceride or diglyceride and polycarboxylic acid and the polyglycerin fatty acid ester is 100: 1 to 1: 5 (more preferably 10: 1 to 1: 2).

【0013】(4)モノグリセリドあるいはジグリセリ
ドとポリカルボン酸とのエステルが、食用油脂中に0.
1〜90重量%(更に好ましくは0.5〜50重量%、
特に3〜30重量%)の量で溶解又は分散されている。 (5)ポリグリセリン脂肪酸エステルが、食用油脂中に
0.1〜50重量%(更に好ましくは0.5〜30重量
%、特に1〜10重量%)の量で溶解又は分散されてい
る。
(4) An ester of monoglyceride or diglyceride and polycarboxylic acid is added to edible oils and fats in an amount of 0.
1 to 90% by weight (more preferably 0.5 to 50% by weight,
In particular, it is dissolved or dispersed in an amount of 3 to 30% by weight. (5) Polyglycerin fatty acid ester is dissolved or dispersed in the edible oil and fat in an amount of 0.1 to 50% by weight (more preferably 0.5 to 30% by weight, particularly 1 to 10% by weight).

【0014】(6)肉の改質剤あるいは食肉調理用油脂
組成物が、肉の量に対してモノグリセリドあるいはジグ
リセリドとポリカルボン酸とのエステルとして0.05
〜5重量%(更に好ましくは0.1〜3重量%、特に
0.3〜2重量%)の範囲の添加量となるような量で使
用される。 (7)肉の改質剤あるいは食肉調理用油脂組成物が、肉
の量に対してポリグリセリン脂肪酸エステルとして0.
01〜10重量%(更に好ましくは0.05〜5量%、
特に0.1〜3重量%)の範囲の添加量となるような量
で使用される。
(6) A meat modifier or a fat-and-oil composition for cooking meat is 0.05 as an ester of monoglyceride or diglyceride and polycarboxylic acid with respect to the amount of meat.
It is used in an amount such that the added amount is in the range of -5 wt% (more preferably 0.1-3 wt%, especially 0.3-2 wt%). (7) A meat modifier or a fat and oil composition for cooking meat is used as a polyglycerin fatty acid ester in an amount of 0.
01 to 10% by weight (more preferably 0.05 to 5% by weight,
It is used in such an amount that the addition amount is in the range of 0.1 to 3% by weight).

【0015】(8)上記肉製品が、肉片を含む冷凍食
品、冷蔵食品、又はレトルト食品などの加熱調理済食
品、あるいは加熱調理用食品である。 (9)上記肉製品が、ハンバーグ、ミートローフ、ギョ
ーザ及びシューマイからなる群より選ばれた挽き肉を主
成分とする成型食品、あるいはこれらの冷凍食品、冷蔵
食品、又はレトルト食品などの加熱調理済食品、又は加
熱調理用食品である。
(8) The meat product is a cooked food such as a frozen food containing a piece of meat, a chilled food, or a retort food, or a food for cooking. (9) The above-mentioned meat product is a shaped food containing ground meat as a main component selected from the group consisting of hamburger steak, meat loaf, gyoza and shumai, or frozen foods thereof, chilled foods, or cooked foods such as retort foods, Alternatively, it is a food for cooking.

【0016】以下に、本発明の肉の改質剤、及び食肉調
理用油脂組成物について説明する。本発明において、モ
ノグリセリドを構成する脂肪酸残基としては、例えば、
グルコン酸残基、乳酸残基、そして炭素数2〜24の飽
和又は不飽和の脂肪酸残基を挙げることができる。また
ジグリセリドを構成する脂肪酸残基は、上記モノグリセ
リドを構成する脂肪酸残基として挙げた脂肪酸残基、後
述するポリカルボン酸残基あるいはこれらが混合された
ものを挙げることができる。本発明におけるモノグリセ
リドあるいはジグリセリドを構成する脂肪酸残基は、好
ましくは、炭素数8〜22の飽和又は不飽和の脂肪酸残
基(更に好ましくは炭素数12〜22の飽和又は不飽和
の脂肪酸残基)である。
The meat modifier and the fat and oil composition for cooking meat according to the present invention will be described below. In the present invention, as the fatty acid residue constituting the monoglyceride, for example,
Examples thereof include a gluconic acid residue, a lactic acid residue, and a saturated or unsaturated fatty acid residue having 2 to 24 carbon atoms. The fatty acid residue constituting the diglyceride may be the fatty acid residue mentioned as the fatty acid residue constituting the monoglyceride, the polycarboxylic acid residue described below, or a mixture thereof. The fatty acid residue constituting the monoglyceride or diglyceride in the present invention is preferably a saturated or unsaturated fatty acid residue having 8 to 22 carbon atoms (more preferably a saturated or unsaturated fatty acid residue having 12 to 22 carbon atoms). Is.

【0017】上記ポリカルボン酸としては、例えば、シ
ュウ酸、マロン酸、コハク酸、グルタル酸、アジピン
酸、ピメリン酸、スベリン酸、アゼライン酸などの飽和
ジカルボン酸;マレイン酸、メチルマレイン酸、フマル
酸、メチルフマル酸などの不飽和ジカルボン酸;リンゴ
酸、酒石酸、クエン酸などのヒドロキシカルボン酸;ヒ
ドロキシカルボン酸の水酸基が酢酸、あるいはシュウ酸
等の上記で挙げたカルボン酸で全部又は一部がエステル
化されたカルボン酸(例、ジアセチル酒石酸)を挙げる
ことができる。上記の中では、コハク酸又はジアセチル
酒石酸が特に好ましい。
Examples of the polycarboxylic acid include oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid and other saturated dicarboxylic acids; maleic acid, methylmaleic acid and fumaric acid. Unsaturated dicarboxylic acids such as methyl fumaric acid; hydroxycarboxylic acids such as malic acid, tartaric acid and citric acid; hydroxyl groups of hydroxycarboxylic acids are all or partly esterified with the above-mentioned carboxylic acids such as acetic acid or oxalic acid. Carboxylic acid (eg, diacetyltartaric acid) may be mentioned. Among the above, succinic acid or diacetyl tartaric acid is particularly preferable.

【0018】上記モノグリセリドあるいはジグリセリド
とポリカルボン酸とで得られるエステルは、その反応に
関与しないカルボン酸のプロトンが、遊離状態にあって
も良いし、また塩を構成していても良い。塩を構成する
対イオンとしては、例えば、カリウム、ナトリウム、カ
ルシウム、マグネシウム、及びアルミニウムなどのイオ
ンを挙げることができる。
In the ester obtained from the above monoglyceride or diglyceride and polycarboxylic acid, the proton of the carboxylic acid which is not involved in the reaction may be in a free state or may form a salt. Examples of the counter ion that constitutes the salt include ions such as potassium, sodium, calcium, magnesium, and aluminum.

【0019】上記エステルは、モノグリセリドあるいは
ジグリセリドとポリカルボン酸との反応モル数、脂肪酸
残基の種類などによって数種の構造のものが得られ、通
常はこれらの混合物として得られる。本発明では、モノ
グリセリドあるいはジグリセリドとポリカルボン酸との
反応モル数(混合比)が1:1により得られたものであ
ることが好ましい。
The above-mentioned ester can be obtained with several types of structures depending on the number of reaction moles of monoglyceride or diglyceride and polycarboxylic acid, the type of fatty acid residue, etc., and is usually obtained as a mixture thereof. In the present invention, the reaction mole number (mixing ratio) of the monoglyceride or diglyceride and the polycarboxylic acid is preferably 1: 1.

【0020】本発明において改質剤、あるいは食用油脂
中には、モノグリセリドとポリカルボン酸とのエステ
ル、及び/又はジグリセリドとポリカルボン酸とのエス
テルが含まれているが、これらの両者が含まれている場
合の両者の含有量比は特に限定されない。また本発明に
おいては、上記モノグリセリドあるいはジグリセリドと
飽和ジカルボン酸とのエステル、あるいはモノグリセリ
ドあるいはジグリセリドとヒドロキシカルボン酸の水酸
基が酢酸で全部又は一部がエステル化されたカルボン酸
とのエステルが好ましい。中でも、炭素数12〜22の
飽和又は不飽和の脂肪酸のモノグリセリドとコハク酸と
のエステル、又は炭素数12〜22の飽和又は不飽和の
脂肪酸のモノグリセリドとジアセチル酒石酸とのエステ
ルが好ましい。
In the present invention, the modifier or edible oil / fat contains an ester of a monoglyceride and a polycarboxylic acid and / or an ester of a diglyceride and a polycarboxylic acid, but both of them are included. When both are contained, the content ratio of both is not particularly limited. Further, in the present invention, an ester of the above monoglyceride or diglyceride and a saturated dicarboxylic acid, or an ester of a monoglyceride or diglyceride and a carboxylic acid in which hydroxyl groups of hydroxycarboxylic acid are wholly or partially esterified with acetic acid is preferable. Among these, esters of monoglycerides of saturated or unsaturated fatty acids having 12 to 22 carbon atoms and succinic acid, or esters of monoglycerides of saturated or unsaturated fatty acids having 12 to 22 carbon atoms and diacetyltartaric acid are preferable.

【0021】ポリグリセリンは、グリセリンの平均重合
度が通常1〜10のものが使用されるが、本発明で用い
るポリグリセリン脂肪酸エステルは、平均重合度2〜1
0のものが好ましい。またポリグリセリンと反応させる
脂肪酸は、炭素数8〜24の飽和又は不飽和の脂肪酸で
あるが、好ましくは炭素数16〜18の飽和又は不飽和
の脂肪酸である。これらの脂肪酸は混合物として用いて
も良い。また本発明において、ポリグリセリン脂肪酸エ
ステルは、その平均エステル化度は、1〜10であるこ
とが好ましい。更に、本発明において、ポリグリセリン
脂肪酸エステルは、そのHLBが10未満のものが好ま
しく、特に4以下のものである。
As the polyglycerin, those having an average degree of polymerization of glycerin of 1 to 10 are usually used, but the polyglycerin fatty acid ester used in the present invention has an average degree of polymerization of 2-1.
0 is preferable. The fatty acid to be reacted with polyglycerin is a saturated or unsaturated fatty acid having 8 to 24 carbon atoms, preferably a saturated or unsaturated fatty acid having 16 to 18 carbon atoms. These fatty acids may be used as a mixture. Further, in the present invention, the polyglycerol fatty acid ester preferably has an average degree of esterification of 1 to 10. Further, in the present invention, the polyglycerin fatty acid ester preferably has an HLB of less than 10, particularly 4 or less.

【0022】本発明の肉の改質剤は、前記のように、モ
ノグリセリドあるいはジグリセリドとポリカルボン酸と
のエステル及びポリグリセリン脂肪酸エステルを含むも
のであるが、この両者のエステルの混合重量比は、好ま
しくは、前者:後者=100:1〜1:5(更に好まし
くは、10:1〜1:2)である。なお、本発明の肉の
改質剤には、他の任意の成分が含まれていても良い。こ
のような成分としては、例えば、澱粉類、蛋白質類、糖
類、調味料などを挙げることができる。これらの成分を
使用することにより、例えば、得られる上記両エステル
が液状の場合には、これらの成分に含ませ、噴霧するな
どの方法で改質剤を粉末状とすることができる。
As described above, the meat modifier of the present invention contains an ester of a monoglyceride or a diglyceride and a polycarboxylic acid and a polyglycerin fatty acid ester, and the mixing weight ratio of the both esters is preferably. , Former: latter = 100: 1 to 1: 5 (more preferably 10: 1 to 1: 2). The meat modifier of the present invention may contain other arbitrary components. Examples of such components include starches, proteins, sugars, seasonings and the like. By using these components, for example, when the above-mentioned both esters to be obtained are in a liquid state, the modifier can be made into a powder by a method of including them in these components and spraying them.

【0023】本発明の肉の改質剤は、肉の量に対してモ
ノグリセリドあるいはジグリセリドとポリカルボン酸と
のエステルとして0.05〜5重量%(更に好ましく
は、0.1〜3重量%、特に0.3〜2重量%)の範囲
で使用することが好ましい。また肉の量に対してポリグ
リセリン脂肪酸エステルとして0.01〜10重量%
(更に好ましくは0.05〜5量%、特に0.1〜3重
量%)の範囲の添加量となるような量で使用されること
が好ましい。
The meat modifier of the present invention is 0.05 to 5% by weight (more preferably 0.1 to 3% by weight) as an ester of a monoglyceride or diglyceride and a polycarboxylic acid, based on the amount of meat. It is particularly preferable to use it in the range of 0.3 to 2% by weight). Also, 0.01 to 10% by weight as polyglycerin fatty acid ester based on the amount of meat
It is preferable to use it in an amount such that the addition amount is in the range of (more preferably 0.05 to 5% by weight, particularly 0.1 to 3% by weight).

【0024】本発明において、モノグリセリドあるいは
ジグリセリドとポリカルボン酸とのエステル及びポリグ
リセリン脂肪酸エステルは、食用油脂中に溶解又は分散
された状態にあってもよい。本発明で用いられる食用油
脂は、特に限定されない。これらの食用油脂としては、
例えば、大豆油、ナタネ油、パーム油、コーン油、綿実
油、椰子油、パーム核油、米油、ごま油、サフラワー
油、ハイオレイックサフラワー油、サンフラワー油、及
びハイオレイックサンフラワー油等の植物油脂;牛脂、
ラード、魚油、鯨油、及び乳脂等の動物油脂;これらの
分別油;またこれらを水素添加したもの;そしてエステ
ル交換したものを挙げることができる。これらの油脂の
うち、1種又は2種以上を組み合わせて使用できる。
In the present invention, the ester of monoglyceride or diglyceride and polycarboxylic acid and the polyglycerin fatty acid ester may be in a state of being dissolved or dispersed in edible oil and fat. The edible oil / fat used in the present invention is not particularly limited. As these edible oils and fats,
For example, soybean oil, rapeseed oil, palm oil, corn oil, cottonseed oil, coconut oil, palm kernel oil, rice oil, sesame oil, safflower oil, high oleic safflower oil, sunflower oil, and high oleic sunflower oil. Vegetable oils and fats; beef tallow,
Animal oils and fats such as lard, fish oil, whale oil, and milk fats; fractionated oils thereof; hydrogenated products thereof; and transesterified products thereof. Of these fats and oils, one kind or a combination of two or more kinds can be used.

【0025】本発明の食肉調理用油脂組成物には、食用
油脂中に、前記モノグリセリドあるいはジグリセリドと
ポリカルボン酸とのエステルが、0.1〜90重量%
(更に好ましくは、0.5〜50重量%、特に3〜30
重量%)の量で溶解又は分散されていることが好まし
い。またポリグリセリン脂肪酸エステルは、食用油脂中
に、0.1〜50重量%(更に好ましくは、0.5〜3
0重量%、特に1〜10重量%)の量で溶解又は分散さ
れていることが好ましい。
In the fat and oil composition for cooking meat of the present invention, 0.1 to 90% by weight of the ester of the above monoglyceride or diglyceride and polycarboxylic acid is contained in the edible oil and fat.
(More preferably 0.5 to 50% by weight, especially 3 to 30%)
It is preferably dissolved or dispersed in an amount of (wt%). The polyglycerin fatty acid ester is contained in the edible oil and fat in an amount of 0.1 to 50% by weight (more preferably 0.5 to 3%).
It is preferably dissolved or dispersed in an amount of 0% by weight, particularly 1 to 10% by weight.

【0026】本発明の食肉調理用油脂組成物には、肉料
理に応じて各種の調味成分を含有させることができる。
調味成分としては、通常肉料理に用いられる香辛料、う
ま味成分(MSG、だし汁、畜肉、魚介類あるいは野菜
のストック類、蛋白加水分解物などの粉末状のもの、又
はオイル)が代表的であるが、これらのものに限定され
るものではない。
The fat and oil composition for cooking meat of the present invention may contain various seasoning ingredients depending on the meat dish.
Typical seasoning components are spices and umami components (MSG, broth, meat, seafood or vegetable stocks, powdered products such as protein hydrolysates, or oils) that are commonly used in meat dishes. , But is not limited to these.

【0027】本発明の食肉調理用油脂組成物においても
その使用量は、前記の場合と同じである。すなわち、肉
の量に対して前記モノグリセリドあるいはジグリセリド
とポリカルボン酸とのエステルが、0.05〜5重量%
(更に好ましくは、0.1〜3重量%、特に0.3〜2
重量%)の範囲の添加量となるような量で使用されるこ
とが好ましい。また肉の量に対してポリグリセリン脂肪
酸エステルが、0.01〜10重量%(更に好ましくは
0.05〜5重量%、特に0.1〜3重量%)の範囲の
添加量となるような量で使用される好ましい。
Also in the fat and oil composition for cooking meat of the present invention, the amount used is the same as in the above case. That is, the amount of the ester of the monoglyceride or diglyceride and the polycarboxylic acid is 0.05 to 5% by weight with respect to the amount of meat.
(More preferably 0.1 to 3% by weight, particularly 0.3 to 2
It is preferably used in an amount such that the added amount is in the range of (wt%). In addition, the polyglycerin fatty acid ester is added in an amount of 0.01 to 10% by weight (more preferably 0.05 to 5% by weight, particularly 0.1 to 3% by weight) with respect to the amount of meat. It is preferably used in an amount.

【0028】本発明の肉の改質剤、及び食肉調理用油脂
組成物を用いる肉料理の対象となる肉は、例えば、牛、
豚、羊などの畜肉、鶏、七面鳥、カモ、ガチョウ等の鳥
肉、あるいはアジ、サケ、またはたら、ヒラメなどの白
身魚などの魚肉を挙げることができるが、特に畜肉、鳥
肉において効果が大である。また肉の部位としては、カ
タ、モモ等の比較的硬質のタンパク質を多く含む部位の
ものを用いるときに効果がある。更に肉の形態として
は、前述のように肉片としての形状のあるもの(厚切り
肉、薄切り肉、細切り肉)を用いるときに特に有効であ
るが、上記のような挽き肉を主体にした成型食品におい
ても効果がある。本明細書において、肉片とは畜肉等の
生肉から切り出した、比較的形状の大きな肉(例えば、
肉片の表面積が1cm2 程度以上のもの)を意味し、例
えば、ステーキ、焼き肉用の肉、あるいは照り焼き用の
肉などの肉片を挙げることができる。
Meat to be cooked using the meat modifier and the fat composition for cooking meat of the present invention is, for example, beef,
Examples thereof include livestock meat such as pigs and sheep, chicken meat such as chicken, turkey, duck, and geese, and fish meat such as white fish such as horse mackerel, salmon, cod, and flounder. Particularly effective for livestock and poultry. Is large. Further, as a meat part, it is effective when a part containing a lot of relatively hard proteins such as kata and peach is used. Further, as the form of the meat, it is particularly effective when using those having a shape as a piece of meat (thick cut meat, thin cut meat, fine cut meat) as described above, but a molded food mainly composed of the above ground meat Is also effective in. In the present specification, a piece of meat refers to meat with a relatively large shape that is cut out from raw meat such as livestock meat (for example,
The surface area of a piece of meat is about 1 cm 2 or more), and examples thereof include meat pieces such as steak, meat for grilled meat, and meat for teriyaki.

【0029】本発明の肉の改質剤は、肉が上記のような
肉片の場合には、この物を直接肉の表面に塗布、散布な
どの方法で使用することができる。また挽き肉などの場
合には、塗布、散布などの他に成型物中に練り込むなど
の方法で使用することもできる。そして本発明の肉の改
質剤は、焼く、炒める、揚げるなどの油脂を用いた調理
において有利に用いることができ、特に、肉を焼く、炒
めるなどの敷き油(調理前に調理器具に予め敷く油脂)
を用いた調理において有利に用いることができる。な
お、本発明の油脂組成物は、上記のような調理の際に使
用する油脂として好ましい形態ということができる。こ
のような調理に適用できる肉料理としては、料理の過程
で焼く、炒めるなど加熱調理が含まれる肉料理において
有効であり、例えば、焼き肉、ステーキ、照り焼き、酢
豚、肉野菜炒め、カレー、シチューなどの比較的大きな
肉片を用いた肉料理、あるいはまたハンバーグ、ミート
ローフ、ギョーザ、及びシューマイなどの挽き肉を主成
分とした成型食品の肉料理を挙げることができる。
When the meat is a piece of meat as described above, the meat modifying agent of the present invention can be used by a method such as directly coating or spraying the meat on the surface of the meat. In the case of minced meat or the like, it can be used by a method such as kneading into a molded product, in addition to coating and spraying. The meat modifier of the present invention can be advantageously used in cooking with fats and oils such as baking, frying, and frying. In particular, bedding oil such as baking and frying meat (prepared in a cooking appliance before cooking in advance. Oil and fat spread)
Can be advantageously used in cooking with. It should be noted that the oil / fat composition of the present invention can be said to be in a preferable form as an oil / fat used in the above-mentioned cooking. Meat dishes that can be applied to such cooking are effective in meat dishes that include heat cooking such as baking and frying in the course of cooking.For example, roasted meat, steak, teriyaki, vinegared pork, stir-fried meat, curry, stew. Meat dishes using relatively large pieces of meat such as, and also meat dishes of molded foods containing ground meat such as hamburger steak, meatloaf, gyoza, and shumai as a main component.

【0030】本発明の改質剤あるいは油脂組成物は、冷
凍、冷蔵、あるいはレトルトなどの常温保存可能な肉片
を含む肉製品、あるいはこれらの形態の挽き肉を主成分
とした成型食品においても適用できる。本発明の改質剤
あるいは油脂組成物で処理された肉片を含む肉製品、あ
るいは挽き肉を主成分とした成型食品は、既に加熱調理
されているものでも良いし(加熱調理済食品)、あるい
はまた食べるときに加熱調理するように調理されている
ものでも良い(未加熱調理食品、加熱調理用食品)。す
なわち、加熱調理済食品においては、これを製造する際
の加熱調理工程で本発明の改質剤、あるいは油脂組成物
で処理されていれば良く、一方未加熱調理食品において
は、食べるときの加熱調理する際に本発明の改質剤、あ
るいは油脂組成物が作用するように予め肉に付着させた
り、食品中に含有させる等の処理をしておけば良い。
The modifier or oil / fat composition of the present invention can also be applied to meat products containing meat pieces that can be stored at room temperature, such as frozen, refrigerated, or retort, or molded foods containing ground meat of these forms as a main component. . The meat product containing the meat pieces treated with the modifier or the oil and fat composition of the present invention, or the molded food containing ground meat as a main component may be one that has already been cooked (cooked food), or It may be cooked as it is eaten (uncooked food, cooked food). That is, in the cooked food, it is sufficient that it is treated with the modifying agent of the present invention or the oil and fat composition in the cooking step in producing the same, while in the uncooked food, it is heated when eating. It may be preliminarily treated such that it is attached to meat or contained in food so that the modifier of the present invention or the oil and fat composition may act during cooking.

【0031】本発明の改質剤あるいは油脂組成物で処理
された肉を含む肉製品は、保存後、油脂を用いて焼く、
炒めるなどの加熱(再加熱も含む)を行う場合において
も、油の汚れや泡の発生が抑えられ、快適に調理でき、
肉片の場合には、肉の柔らかさやジューシーさが維持さ
れ、良好な風味の食品を得ることができ、また挽き肉を
主成分とする成型食品においては、柔らかさ等と共にふ
っくらとした食感も付与された食品を得ることができ
る。本発明の改質剤あるいは油脂組成物で処理した肉片
を含む肉製品としては、例えば、カレー、ハヤシ、シチ
ュー、酢豚などを挙げることができる。また挽き肉を主
成分とした成型食品で、冷凍、冷蔵、あるいはレトルト
食品の例も前述した、ハンバーグ等を挙げることができ
る。
Meat products containing meat treated with the modifier or fat composition of the present invention, after storage, are baked with fat or oil,
Even when heating (including reheating) such as frying, the generation of oil stains and bubbles is suppressed, and you can cook comfortably,
In the case of meat pieces, the softness and juiciness of the meat can be maintained, and foods with a good flavor can be obtained, and in the case of molded foods containing ground meat as the main component, softness and a soft texture are also imparted. It is possible to obtain the processed food. Examples of meat products containing meat pieces treated with the modifying agent or the oil and fat composition of the present invention include curry, hayashi, stew, vinegared pork and the like. Examples of the molded food containing ground meat as a main component, such as frozen, refrigerated, or retort-packed food, include the hamburger and the like described above.

【0032】[0032]

【実施例】以下に、本発明の実施例及び比較例を示し、
本発明を更に具体的に説明する。 [実施例1]厚さ15mmの国産牛サーロイン肉120
gに適当量の食塩、胡椒を振りかけた後、コハク酸モノ
グリセリド(炭素数16〜18(炭素数18を主体)の
飽和モノグリセリドとコハク酸との混合比が1:1のエ
ステル、花王(株)製)とデカグリセリンデカステアレ
ート(DAS−750、HLB:3、平均エステル化
度:10、阪本薬品(株)製)との混合物(重量比2:
1)1.5gを肉表面に散布した。サラダ油10gをフ
ライパンに敷き、肉を焼成した。
EXAMPLES Examples and comparative examples of the present invention will be shown below.
The present invention will be described more specifically. [Example 1] Domestic beef sirloin meat 120 having a thickness of 15 mm
g, sprinkled with an appropriate amount of salt and pepper, and then succinic acid monoglyceride (saturated monoglyceride having 16 to 18 carbon atoms (mainly having 18 carbon atoms) and succinic acid having a mixing ratio of 1: 1; Kao Corporation) Manufactured by Sakamoto Yakuhin Co., Ltd.) and decaglycerin decastearate (DAS-750, HLB: 3, average degree of esterification: 10, manufactured by Sakamoto Yakuhin Co., Ltd.) (weight ratio 2 :).
1) 1.5 g was sprinkled on the meat surface. 10 g of salad oil was spread on a frying pan and the meat was baked.

【0033】[比較例1]上記実施例1において、コハ
ク酸モノグリセリドとデカグリセリンデカステアレート
との混合物の代わりにコハク酸モノグリセリドのみを1
g使用した以外は、上記実施例1と同様にして肉を焼成
した。
[Comparative Example 1] In Example 1, the succinic acid monoglyceride alone was used instead of the mixture of succinic acid monoglyceride and decaglycerin decastearate.
Meat was baked in the same manner as in Example 1 except that g was used.

【0034】[比較例2]上記実施例1において、コハ
ク酸モノグリセリドとデカグリセリンデカステアレート
との混合物を使用しなかった以外は、上記実施例1と同
様にして肉を焼成した。
Comparative Example 2 Meat was baked in the same manner as in Example 1 except that the mixture of succinic acid monoglyceride and decaglycerin decastearate was not used in Example 1 above.

【0035】[実施例2]厚さ5mmのオーストラリア
産牛カルビ肉100gに対してコハク酸モノグリセリド
(炭素数16〜18(炭素数18を主体)の飽和モノグ
リセリドとコハク酸との混合比が1:1のエステル、花
王(株)製)とテトラグリセリンペンタオレエート(P
O−310、HLB:2、平均エステル化度:5、阪本
薬品(株)製)との混合物(重量比2:1)1.5gを
肉表面に散布した。その後、230℃のホットプレート
上で焼成し、焼き肉を作った。
Example 2 100 g of beef rib meat from Australia having a thickness of 5 mm was mixed with succinic acid monoglyceride (saturated monoglyceride having 16 to 18 carbon atoms (mainly having 18 carbon atoms) and succinic acid at a mixing ratio of 1 :). 1 ester, manufactured by Kao Corporation, and tetraglycerin pentaoleate (P
1.5 g of a mixture (weight ratio 2: 1) with O-310, HLB: 2, average degree of esterification: 5, manufactured by Sakamoto Yakuhin Co., Ltd. was sprayed on the meat surface. Then, it baked on the hotplate of 230 degreeC, and made the roast meat.

【0036】[実施例3]上記実施例2において、コハ
ク酸モノグリセリドを用いる代わりに、ジアセチル酒石
酸モノグリセリド(ジアセチル酒石酸モノグリセリド
(炭素数16〜18(炭素数18を主体)の飽和モノグ
リセリドとジアセチル酒石酸との混合比が1:1のエス
テル、太陽化学(株)製)を使用した以外は、実施例2
と同様にして焼き肉を作った。
[Example 3] In Example 2, instead of using succinic acid monoglyceride, diacetyl tartaric acid monoglyceride (diacetyl tartaric acid monoglyceride (having saturated monoglyceride having 16 to 18 carbon atoms (mainly having 18 carbon atoms) and diacetyl tartaric acid) was used. Example 2 except that an ester having a mixing ratio of 1: 1 and manufactured by Taiyo Kagaku Co., Ltd. was used.
I made roasted meat in the same way.

【0037】[比較例3]上記実施例2において、コハ
ク酸モノグリセリドとテトラグリセリンペンタオレエー
トとの混合物の代わりにコハク酸モノグリセリドのみを
1g使用した以外は、上記実施例2と同様にして肉を焼
成した。
Comparative Example 3 A meat was prepared in the same manner as in Example 2 except that 1 g of succinic acid monoglyceride was used instead of the mixture of succinic acid monoglyceride and tetraglycerin pentaoleate. Baked.

【0038】[比較例4]上記実施例2において、コハ
ク酸モノグリセリドとテトラグリセリンペンタオレエー
トとの混合物を使用しなかった以外は、上記実施例2と
同様にして肉を焼成した。
Comparative Example 4 Meat was baked in the same manner as in Example 2 except that the mixture of succinic acid monoglyceride and tetraglycerin pentaoleate was not used in Example 2.

【0039】[肉の改質剤としての評価]調理の快適性
について以下のように評価した。 (1)調理中の泡の発生状態 パネルとして主婦10人による実際の調理で泡の発生状
態を目視による観察で評価させた。評価は、以下の5段
階評価で行い、その平均値で表わした。 5:泡の発生が殆どない。 4:泡の発生が一部に生じた。 3:泡の発生が全体に生じたが、許容範囲である。 2:泡の発生が気になるほど全体に生じた。 1:泡の発生が非常に多い。
[Evaluation as Meat Modifier] The comfort of cooking was evaluated as follows. (1) State of foam generation during cooking As a panel, 10 housewives evaluated the state of foam generation in actual cooking by visual observation. The evaluation was carried out according to the following five-stage evaluation and expressed as an average value. 5: Almost no bubbles were generated. 4: Some bubbles were generated. 3: Generation of bubbles occurred on the whole, but it was within the allowable range. 2: Foam was generated on the whole so as to be noticeable. 1: Very many bubbles are generated.

【0040】(2)調理後の油脂の汚れ フライパンやホットプレート上に残った油脂を採取し、
その油の濁りを下記の方法で測定し、評価した。なお、
吸光度は、本発明の改質剤を添加しなかった場合(比較
例2及び4)の値を100として表した。回収した油を
遠心分離(3000rpm)し、上澄み部分の吸光度を
520nmの光で測定した。吸光度が大きいほど油の着
色が著しい。すなわち、油が濁っていること示す。
(2) Contamination of oils and fats after cooking Oils and fats remaining on the frying pan and hot plate are collected,
Turbidity of the oil was measured and evaluated by the following method. In addition,
The absorbance was expressed as 100 when the modifier of the present invention was not added (Comparative Examples 2 and 4). The recovered oil was centrifuged (3000 rpm), and the absorbance of the supernatant was measured with light of 520 nm. The greater the absorbance, the more marked the oil coloring. That is, it indicates that the oil is cloudy.

【0041】(3)肉の柔らかさの評価 「肉の柔らかさ」は、ミートシェア(ワーナーブラッツ
ラー社製)による剪断応力値を測定することにより評価
した。測定値が小さい程、肉が柔らかいことを示す。結
果を以下の表1に示す。
(3) Evaluation of meat tenderness "Meat tenderness" was evaluated by measuring the shear stress value by meat shear (manufactured by Warner Bratzler). The smaller the measured value, the softer the meat. The results are shown in Table 1 below.

【0042】[0042]

【表1】 表1 ──────────────────────────────────── 実施例 比較例 比較例 実施例 実施例 比較例 比較例 1 1 2 2 3 3 4 ──────────────────────────────────── 剪断応力値 2.4 2.5 5.0 1.8 1.9 1.7 3.4 (kg) ──────────────────────────────────── 油の濁り 115 980 100 120 120 560 100 (吸光度) ──────────────────────────────────── 泡の観察 4.6 2.8 4.6 4.8 4.9 3.2 4.9 ────────────────────────────────────[Table 1] Table 1 ──────────────────────────────────── Examples Examples Comparative Examples Comparative Examples Example Comparative Example Comparative Example 1 1 2 2 3 3 4 ──────────────────────────────────── Shearing Stress value 2.4 2.5 5.0 1.8 1.9 1.7 3.4 (kg) ──────────────────────── ──────────── Turbidity of oil 115 980 100 100 120 120 560 100 (absorbance) ────────────────────────── ─────────── Observation of bubbles 4.6 2.8 4.6 4.6 4.8 4.9 3.2 4.9 ────────────── ─────────────────────

【0043】上記表1に示された結果から、本発明の改
質剤を使用した場合(実施例1〜3)には、ポリグリセ
リン脂肪酸エステルが添加されているため、油の濁りも
少なく、ま泡の発生も抑制できることがわかる。また測
定した剪断応力値から本発明の改質剤を用いることによ
り肉が柔らかくなることがわかる。
From the results shown in Table 1 above, when the modifier of the present invention was used (Examples 1 to 3), the polyglycerin fatty acid ester was added, so that the oil was less turbid and It can be seen that the generation of foam can also be suppressed. Further, it can be seen from the measured shear stress value that the meat becomes softer by using the modifier of the present invention.

【0044】[実施例4]厚さ15mmの国産牛サーロ
イン肉120gに適当量の食塩、胡椒を振りかけた後、
下記組成の調理用油脂組成物(A)10gをフライパン
に敷き、肉を焼成した。 調理用油脂(A)の配合 配合量(重量部) コーン油 85 実施例1で用いたコハク酸モノグリセリド 10 実施例1で用いたデカグリセリンデカステアレート 5 ───────────────────────────────── 合計 100
Example 4 120 g of domestic beef sirloin meat having a thickness of 15 mm was sprinkled with an appropriate amount of salt and pepper, and then,
10 g of the cooking oil composition (A) having the following composition was spread on a frying pan, and the meat was baked. Blending of cooking fats and oils (A) Blending amount (parts by weight) Corn oil 85 Succinic acid monoglyceride used in Example 1 10 Decaglycerin decasterate 5 used in Example 1 5 ──────────── ────────────────────── Total 100

【0045】[比較例5]上記実施例4において、調理
用油脂組成物(A)の代わりに、下記組成の調理用油脂
組成物(B)を用いた以外は、実施例4と同様に肉を焼
成した。 調理用油脂(B)の配合 配合量(重量部) コーン油 90 実施例1で用いたコハク酸モノグリセリド 10 ───────────────────────────────── 合計 100
COMPARATIVE EXAMPLE 5 Meat was prepared in the same manner as in Example 4 except that the cooking oil / fat composition (A) was replaced with the cooking oil / fat composition (B) having the following composition. Was baked. Blending of cooking fats and oils (B) Blending amount (parts by weight) Corn oil 90 Succinic acid monoglyceride 10 used in Example 1 ───────────────────────── ────────── Total 100

【0046】[比較例6]上記実施例4において、調理
用油脂組成物(A)の代わりに、サラダ油を用いた以外
は、実施例4と同様に肉を焼成した。
[Comparative Example 6] Meat was baked in the same manner as in Example 4 except that salad oil was used in place of the cooking oil composition (A) in Example 4 above.

【0047】[調理用油脂としての評価]上記の調理の
快適性及び得られた肉の柔らかさについて前記と同様な
方法で評価した。結果を下記の表2に示す。
[Evaluation as fats and oils for cooking] The comfort of the above cooking and the tenderness of the obtained meat were evaluated by the same method as described above. The results are shown in Table 2 below.

【0048】[0048]

【表2】 表2 ──────────────────────────────────── 実施例4 比較例5 比較例6 ──────────────────────────────────── 剪断応力値(kg) 2.8 2.8 5.0 ──────────────────────────────────── 油の濁り(吸光度) 115 860 100 ──────────────────────────────────── 泡の観察 4.6 3.0 4.6 ────────────────────────────────────[Table 2] Table 2 ──────────────────────────────────── Example 4 Comparative Example 5 Comparative Example 6 ──────────────────────────────────── Shear stress value (kg) 2.8 2.8 5 0.0 ───────────────────────────────────── Oil turbidity (absorbance) 115 860 100 ─── ───────────────────────────────── Observation of bubbles 4.6 3.0 4.6 4.6 ───── ───────────────────────────────

【0049】上記表2に示された結果から、コハク酸モ
ノグリセリド及びポリグリセリン脂肪酸エステルが添加
されてなる本発明の油脂組成物を使用(実施例4)する
ことにより、柔らかい肉が得られ、かつこのような肉を
油の濁りが少なく、また泡の発生も少ない状態で快適に
調理できることがわかる。
From the results shown in Table 2 above, by using the oil and fat composition of the present invention to which succinic acid monoglyceride and polyglycerin fatty acid ester were added (Example 4), soft meat was obtained, and It can be seen that such meat can be cooked comfortably with less turbidity of oil and generation of bubbles.

【0050】[0050]

【発明の効果】本発明の肉の改質剤あるいは油脂組成物
を使用することにより、肉質が柔らかく、肉汁に富んだ
肉を得ることができ、また加熱調理時の泡の発生や調理
後の油脂の汚れも抑制でき、快適に調理できる。また本
発明の肉の改質剤あるいは油脂組成物を使用することに
より、冷凍(冷蔵)食品、あるいはレトルト食品のよう
な保存可能な肉製品においても、その保存後でも上記の
ような肉の改質効果は維持されており、このような製品
を得るための加熱調理においても泡の発生や調理後の油
脂の汚れも抑制できる。
EFFECTS OF THE INVENTION By using the meat modifier or oil composition of the present invention, it is possible to obtain meat that is soft in meat quality and rich in gravy, and foams during cooking or after cooking. You can also control the dirt of oils and fats and cook comfortably. In addition, by using the meat modifier or oil composition of the present invention, storable meat products such as frozen (refrigerated) foods or retort foods, and even after the storage thereof, the above-mentioned meat modification is performed. The quality effect is maintained, and it is possible to suppress the generation of bubbles and stains of oils and fats after cooking even in heating cooking for obtaining such a product.

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】 モノグリセリドあるいはジグリセリドと
ポリカルボン酸とのエステル及びポリグリセリン脂肪酸
エステルを含有する肉の改質剤。
1. A meat modifier containing an ester of a monoglyceride or a diglyceride and a polycarboxylic acid and a polyglycerin fatty acid ester.
【請求項2】 上記モノグリセリドとポリカルボン酸と
のエステルが、炭素数12〜22の飽和又は不飽和の脂
肪酸のモノグリセリドとコハク酸とのエステル、又は炭
素数12〜22の飽和又は不飽和の脂肪酸のモノグリセ
リドとジアセチル酒石酸とのエステルである請求項1に
記載の肉片の改質剤。
2. The ester of monoglyceride and polycarboxylic acid is an ester of monoglyceride of a saturated or unsaturated fatty acid having 12 to 22 carbon atoms and succinic acid, or a saturated or unsaturated fatty acid of 12 to 22 carbon atoms. The meat fragment modifier according to claim 1, which is an ester of the monoglyceride and diacetyltartaric acid.
【請求項3】 ポリグリセリン脂肪酸エステルがHLB
10未満のポリグリセリン脂肪酸エステルである請求項
1に記載の肉の改質剤。
3. A polyglycerin fatty acid ester is HLB.
The meat modifier according to claim 1, which is less than 10 polyglycerin fatty acid ester.
【請求項4】 上記請求項1〜3のいずれかの項に記載
の改質剤で処理した食用肉又は肉製品。
4. An edible meat or meat product treated with the modifier according to any one of claims 1 to 3.
【請求項5】 食用油脂中に、モノグリセリドあるいは
ジグリセリドとポリカルボン酸とのエステル及びポリグ
リセリン脂肪酸エステルが溶解又は分散されてなる食肉
調理用油脂組成物。
5. A meat cooking oil and fat composition comprising an ester of a monoglyceride or a diglyceride and a polycarboxylic acid and a polyglycerin fatty acid ester dissolved or dispersed in the edible oil and fat.
【請求項6】 上記モノグリセリドとポリカルボン酸と
のエステルが、炭素数12〜22の飽和又は不飽和の脂
肪酸のモノグリセリドとコハク酸とのエステル、又は炭
素数12〜22の飽和又は不飽和の脂肪酸のモノグリセ
リドとジアセチル酒石酸とのエステルである請求項5に
記載の食肉調理用油脂組成物。
6. The ester of monoglyceride and polycarboxylic acid is an ester of monoglyceride of saturated or unsaturated fatty acid having 12 to 22 carbon atoms and succinic acid, or saturated or unsaturated fatty acid of 12 to 22 carbon atoms. The oil and fat composition for cooking meat according to claim 5, which is an ester of the monoglyceride of 1 and diacetyl tartaric acid.
【請求項7】 ポリグリセリン脂肪酸エステルがHLB
10未満のポリグリセリン脂肪酸エステルである請求項
5に記載の食肉調理用油脂組成物。
7. The polyglycerin fatty acid ester is HLB.
The oil and fat composition for cooking meat according to claim 5, which is a polyglycerin fatty acid ester of less than 10.
【請求項8】 請求項5〜7のいずれかの項に記載の食
肉調理用油脂組成物で処理した食用肉又は肉製品。
8. An edible meat or meat product treated with the fat and oil composition for cooking meat according to any one of claims 5 to 7.
JP33781894A 1994-12-27 1994-12-27 Meat modifier, meat cooking fat composition, and edible meat or meat product treated with these Expired - Fee Related JP3208269B2 (en)

Priority Applications (1)

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JP33781894A JP3208269B2 (en) 1994-12-27 1994-12-27 Meat modifier, meat cooking fat composition, and edible meat or meat product treated with these

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33781894A JP3208269B2 (en) 1994-12-27 1994-12-27 Meat modifier, meat cooking fat composition, and edible meat or meat product treated with these

Publications (2)

Publication Number Publication Date
JPH08173097A true JPH08173097A (en) 1996-07-09
JP3208269B2 JP3208269B2 (en) 2001-09-10

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ID=18312256

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Country Link
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