JPH08173089A - Lustering agent for food - Google Patents

Lustering agent for food

Info

Publication number
JPH08173089A
JPH08173089A JP6336921A JP33692194A JPH08173089A JP H08173089 A JPH08173089 A JP H08173089A JP 6336921 A JP6336921 A JP 6336921A JP 33692194 A JP33692194 A JP 33692194A JP H08173089 A JPH08173089 A JP H08173089A
Authority
JP
Japan
Prior art keywords
food
carrageenan
luster
milk powder
protein
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6336921A
Other languages
Japanese (ja)
Other versions
JP3414871B2 (en
Inventor
Daisuke Hosokawa
大介 細川
Makoto Hamada
誠 浜田
Tatsuya Kawabe
達也 河辺
Fusao Kimizuka
房夫 君塚
Sadasuke Kainuma
禎介 貝沼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takara Shuzo Co Ltd
Original Assignee
Takara Shuzo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takara Shuzo Co Ltd filed Critical Takara Shuzo Co Ltd
Priority to JP33692194A priority Critical patent/JP3414871B2/en
Publication of JPH08173089A publication Critical patent/JPH08173089A/en
Application granted granted Critical
Publication of JP3414871B2 publication Critical patent/JP3414871B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)

Abstract

PURPOSE: To obtain a lustering agent for foods containing a milk protein and carrageenan as active ingredients, microbiologically safe, excellent in preservability, capable of being directly applied, coated or sprayed to a food, before baked, and giving the same luster as that in the case of liquid egg. CONSTITUTION: This lustering agent contains a milk protein such as defatted milk powder, whole milk powder, casein or whey protein preferably in an amount of >=5.0W/W% (15-30 W/W% in the case of the defatted milk powder), and carrageenan preferably in an amount of >=0.1W/W% as active ingredients. The lustering agent is coated on a food such as bread or confection and subsequently heated.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は食品の表面にツヤ(光
沢)を与えるツヤ出し剤及びその使用方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a glossing agent for imparting gloss to the surface of foods and a method for using the same.

【0002】従来、パンや菓子等の食品の光沢付与(以
下、「ツヤ出し」として記載する)は、焼成前の生地に
液卵を塗布する方法が一般的である。しかし液卵の使用
には内因性のサルモネラ菌による汚染の問題があり、毎
年、これが原因とされる食中毒が跡を絶たない。一方、
これに代る方法として、焼成後の生地に油脂を主成分と
する液を塗布又はスプレーする方法や、デンプンを主成
分とする液を塗布又はスプレーする方法も用いられてい
る。また、特開平3−39029号公報にはλ−カラギ
ーナン水溶液をパン生地に塗布し、冷凍後、解凍、焼成
すること等により、その表面をツヤ出しする方法も開発
されている。
[0002] Conventionally, for imparting gloss to foods such as bread and confectionery (hereinafter referred to as "shining"), a method of applying a liquid egg to a dough before baking is generally used. However, the use of liquid eggs has the problem of contamination with endogenous Salmonella, and every year, the food poisoning that causes it is unending. on the other hand,
As an alternative method, a method of applying or spraying a liquid containing fats and oils as a main component to the baked dough and a method of applying or spraying a liquid containing starch as a main component are also used. Further, Japanese Patent Laid-Open No. 3-39029 has developed a method of applying a λ-carrageenan aqueous solution to bread dough, and freezing, thawing, and baking the dough to make the surface glossy.

【0003】[0003]

【発明が解決しようとする課題】しかし、これらの方法
では油脂の酸化臭が問題になったり、ツヤの質が液卵の
ものと異なるという欠点があり、いまだ液卵を塗布する
方法に代る方法は見出されていない。また、前記公報の
λ−カラギーナン水溶液を冷凍工程のない通常のパン製
造工程に用いる場合にはツヤ出し効果は認められていな
い。したがって、酸化臭やツヤの質の点等の問題がない
ツヤ出し方法の開発は極めて重要な問題であった。本発
明は前記にかんがみ、微生物的に安全で、焼成前に塗布
又はスプレーでき、液卵と同等のツヤが得られる食品用
ツヤ出し剤及び食品のツヤ出し方法を提供することを目
的とする。
However, these methods have the drawbacks that the oxidative odor of fats and oils poses a problem and the quality of the gloss is different from that of liquid egg. Therefore, the method of applying liquid egg is still in place. No way has been found. Further, when the aqueous solution of λ-carrageenan of the above publication is used in a normal bread making process without a freezing process, no glossing effect is recognized. Therefore, the development of a glossing method without problems such as oxidative odor and gloss quality has been a very important issue. It is an object of the present invention to provide a luster for foods and a method for lustering foods, which is, in view of the above, microbially safe, which can be applied or sprayed before baking, and which has a gloss equivalent to that of liquid eggs.

【0004】[0004]

【課題を解決するための手段】本発明の第1の発明は、
乳蛋白質及びカラギーナンを有効成分とすることを特徴
とする食品用ツヤ出し剤、及び第2の発明は、該ツヤ出
し剤で食品の表面を被覆した後、加熱処理することを特
徴とする食品のツヤ出し方法に関する。
The first invention of the present invention is as follows:
A lustering agent for foods, which comprises milk protein and carrageenan as active ingredients, and a second invention is a food characterized by heat treatment after coating the surface of the food with the lustering agent. Regarding glossing method.

【0005】本発明者らは、液卵を使用する場合と同様
の操作によって、液卵と同等のツヤが得られる方法を検
討した結果、好適には乳蛋白質及びカラギーナンを含有
するツヤ出し剤を調製し、これを用いてパン、菓子等の
食品の表面を被覆すると、液卵を塗布した場合と同等の
ツヤが加熱処理後に得られることを見出した。
The present inventors have investigated a method of obtaining a gloss equivalent to that of liquid egg by the same operation as in the case of using liquid egg, and as a result, preferably a glossing agent containing milk protein and carrageenan was used. It was found that when prepared and coated on the surface of foods such as bread and confectionery, the same gloss as in the case of applying liquid egg is obtained after the heat treatment.

【0006】本発明におけるツヤとは対象食品の色調、
外観等を生かした透明なツヤをいう。本発明における乳
蛋白質とは乳成分由来のものであり、ホエー蛋白質やカ
ゼインなど分画されたもの、乳蛋白質を含有する脱脂粉
乳、全脂粉乳等でもよく、水可溶性又はコロイド状の分
散性の性質を有するものが好適である。更に、カラギー
ナンはκ、λ、ζのいずれも使用可能であるが、λ−カ
ラギーナンは溶液状態で用いる場合は加熱殺菌によりゲ
ル化しないのでより好適である。
The gloss in the present invention means the color tone of the target food,
It is a transparent luster that makes the most of its appearance. Milk protein in the present invention is derived from milk components, such as whey protein and casein fractionated, skim milk powder containing milk protein, may be whole milk powder, etc., water-soluble or colloidal dispersibility Those having properties are preferable. Further, carrageenan can be used in any of κ, λ, and ζ, but λ-carrageenan is more preferable when used in a solution state because it does not gel by heat sterilization.

【0007】本発明のツヤ出し剤中の乳蛋白質含量は
5.0w/w%以上が好ましいが、溶液で使用する場合
はコストの問題や、使用する乳蛋白質によって溶解性、
溶液の粘度を考慮したほうがよい。したがって、例えば
脱脂粉乳の場合は、15〜30w/w%(蛋白質として
5.25〜10.5w/w%)の範囲が好ましい。一
方、カラギーナン含量は0.1w/w%以上が好ましい
が、溶液で使用する場合は、乳蛋白質と同様にコスト、
溶解性、溶液の粘度を考慮したほうがよい。また、乳蛋
白質に対するカラギーナンの含量は、例えば溶液の乳蛋
白質含量7.0w/w%の場合は7.1〜21.4w/
w%、8.75w/w%の場合は2.3〜11.4w/
w%の範囲が好ましい。
The milk protein content of the glossing agent of the present invention is preferably 5.0 w / w% or more. However, when used in a solution, there are problems of cost and solubility depending on the milk protein used,
It is better to consider the viscosity of the solution. Therefore, for example, in the case of skim milk powder, the range of 15 to 30 w / w% (5.25 to 10.5 w / w% as protein) is preferable. On the other hand, the carrageenan content is preferably 0.1 w / w% or more, but when used in a solution, the cost is the same as that of milk protein,
It is better to consider the solubility and the viscosity of the solution. The content of carrageenan relative to milk protein is, for example, 7.1 to 21.4 w / when the milk protein content of the solution is 7.0 w / w%.
In the case of w% and 8.75 w / w%, 2.3 to 11.4 w /
A range of w% is preferred.

【0008】また、本発明によるツヤ出し剤の製造は、
乳蛋白質原料、カラギーナン及び副原料を混合すること
により固形のツヤ出し剤が得られるが、これをこのまま
適用するか、又は溶解使用してもよいし、これらの原料
を混合せずに単独で調製し食品を被覆するときに別々に
適用するか、又は溶解使用してもよい。ツヤ出し剤を液
状の製品として調製する場合は、ツヤ出し剤を溶解、分
散又は懸濁させた液としてもよく、この液を粉末化した
り、アルコール、食塩等を加えたりすることによって保
存性を持たせることも可能である。したがって、液卵の
場合は冷蔵保存が必要な上、使用期限が短いという短所
があるが、これと比較して本発明によるツヤ出し剤は安
全性、扱い易さ、保存性においても優れている。
The production of the glossing agent according to the present invention is
A solid lustering agent can be obtained by mixing the milk protein raw material, carrageenan and the auxiliary raw material, which may be applied as it is or dissolved and used, or prepared alone without mixing these raw materials. The food may be applied separately when it is coated, or may be dissolved and used. When preparing the glossing agent as a liquid product, it may be a solution in which the glossing agent is dissolved, dispersed or suspended, and the storability is improved by powdering this solution or adding alcohol, salt or the like. It is possible to have it. Therefore, liquid eggs have the disadvantage of requiring refrigeration storage and a short expiration date, but in comparison with this, the luster preparation of the present invention is superior in safety, easiness of handling, and storability. .

【0009】本発明のツヤ出し剤で食品を被覆する方法
として、好ましくは、刷毛塗り等の塗布又はスプレー等
による方法が使用できる。また、焼成等の加熱処理後の
食品に使用する場合も、同様の操作によってツヤ出し剤
を被覆させればよく、その後に加熱処理することによっ
ても同等のツヤを得ることが可能である。
As a method for coating food with the glossing agent of the present invention, a method such as brush coating or spraying can be preferably used. Also, when used in foods after heat treatment such as baking, the same luster may be coated by the same operation, and the same luster can be obtained by subsequent heat treatment.

【0010】本発明の加熱処理はツヤの得られる乾燥法
であればいずれでもよく、その方法、条件は対象食品に
よって適宜設定でき、方法としては、乾燥熱風による気
流乾燥法やトンネル乾燥法等の熱風乾燥法、オーブン等
を用いる一般的な焼成等がある。その条件としては、パ
ンの場合は例えば180〜230℃、5〜30分程度が
適当である。
The heat treatment of the present invention may be any drying method as long as it gives gloss, and the method and conditions can be appropriately set depending on the target food. Examples of the method include air flow drying method using hot dry air and tunnel drying method. There are a hot air drying method, general baking using an oven and the like. In the case of bread, appropriate conditions are, for example, 180 to 230 ° C. and 5 to 30 minutes.

【0011】本発明によるツヤ出し剤は、油脂やデンプ
ンを主成分とするツヤ出し剤のように、加熱処理による
酸化臭やツヤの質も問題もなく、液卵のようにスプレー
の困難性や保存性等についての欠点もないので、ハンド
リングにおいて優れ、微生物汚染を懸念することも不要
である。
The glossing agent according to the present invention has no problem of oxidizing odor and gloss due to heat treatment like a glossing agent containing oils and starch as a main component, and has difficulty in spraying like liquid egg. Since it has no drawbacks such as storability, it is excellent in handling and it is unnecessary to worry about microbial contamination.

【0012】本発明製品の対象食品としては、形状が固
形のパン、菓子等が好適に用いられるが、グラタン等の
ように半固形の食品でも使用可能である。
[0012] As the target food of the product of the present invention, bread and confectionery having a solid shape are preferably used, but semi-solid foods such as gratin can also be used.

【0013】[0013]

【実施例】以下、実施例によって本発明を更に具体的に
説明するが、本発明はこれらに限定されない。
The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto.

【0014】実施例1 脱脂粉乳とλ−カラギーナンの相乗効果を調べるために
以下の試験を行った。すなわち、20%脱脂粉乳液(乳
蛋白質濃度:7.0w/w%)中に表1に示す各濃度の
λ−カラギーナンを加えて調製した液を焼成前のパン生
地に塗布し、焼成後のツヤの程度を評価した。
Example 1 The following test was carried out to examine the synergistic effect of skim milk powder and λ-carrageenan. That is, a liquid prepared by adding each concentration of λ-carrageenan shown in Table 1 to a 20% skim milk powder (milk protein concentration: 7.0 w / w%) was applied to bread dough before baking, and gloss after baking was applied. Was evaluated.

【0015】[0015]

【表1】 表 1 ──────────────────────────────────── カラギーナン濃度 カラギーナン/乳蛋白質 評 価 (w/w%) (w/w%) ──────────────────────────────────── 0 0 弱いツヤがある 0.1 1.4 ツヤがある 0.5 7.1 良好なツヤがある 1.0 14.2 良好なツヤがある 1.5 21.4 良好なツヤがある(*1) ──────────────────────────────────── (*1:ツヤは得られる粘度が高く使い難い)[Table 1] Table 1 ──────────────────────────────────── Carrageenan concentration Carrageenan / milk protein rating (W / w%) (w / w%) ───────────────────────────────────── 0 0 There is weak luster 0.1 1.4 There is gloss 0.5 7.1 There is good luster 1.0 14.2 There is good luster 1.5 21.4 There is good luster (* 1) ──────────────────────────────────── (* 1: The glossiness is high and difficult to use)

【0016】上記配合と同様に対照としてλ−カラギー
ナンの1.0及び1.5%溶液のみを塗布したものは全
くツヤは認められなかった。このことからも通常の製パ
ン工程で使用する場合は脱脂粉乳とλ−カラギーナンを
併用することによってのみ良好なツヤが得られることが
示唆される。また、各溶液はそれぞれスプレードライす
ることにより粉末のツヤ出し剤を調製でき、保存性を持
たせることができるが、このようにして得た粉末は5倍
希釈して使用することにより、上と同じ結果を得ること
ができた。
As in the case of the above-mentioned formulation, no gloss was observed at all in the case where only 1.0 and 1.5% solutions of λ-carrageenan were applied as a control. This also suggests that when used in a normal baking process, good gloss can be obtained only by using skim milk powder and λ-carrageenan in combination. Moreover, each solution can be spray-dried to prepare a luster powder, and can be preserved. However, the powder thus obtained can be diluted five-fold and used to I was able to get the same result.

【0017】実施例2 ζ−カラギーナンと脱脂粉乳を組合せた表2の配合でツ
ヤ出し剤を調製し、焼成前のクッキーの生地に塗布し、
焼成後にツヤの状態を観察評価した。
Example 2 A glossing agent was prepared by combining ζ-carrageenan and skimmed milk powder, and the glossing agent was prepared and applied to the cookie dough before baking.
After firing, the glossy state was observed and evaluated.

【0018】[0018]

【表2】 表 2 ──────────────────────────────────── 原材料 ──────────────────────────────────── 液卵 0 0 0 0 100 脱脂粉乳 25 25 25 25 − (乳蛋白質 8.75 8.75 8.75 8.75) デキストリン 2.5 2.5 2.5 2.5 − アミノ酸液 0.8 0.8 0.8 0.8 − 炭酸ナトリウム 0.1 0.1 0.1 0.1 − ζ−カラギーナン 0 0.2 0.4 1.0 − 水 残量 残量 残量 残量 − 合 計 100 100 100 100 100 ──────────────────────────────────── カラギーナン/ 0 2.3 4.6 11.4 − 乳蛋白質 ──────────────────────────────────── ツヤの評価 ツヤ有 ツヤ優 ツヤ優 ツヤ優(*2) ツヤ優 ──────────────────────────────────── (単位:w/w%、*2:粘度が高く使いにくい。)[Table 2] Table 2 ──────────────────────────────────── Raw materials ─────── ───────────────────────────── Liquid egg 0 0 0 0 100 Skim milk powder 25 25 25 25- (milk protein 8.75 8.75 8.75 8.75 ) Dextrin 2.5 2.5 2.5 2.5 − Amino acid solution 0.8 0.8 0.8 0.8 − Sodium carbonate 0.1 0.1 0.1 0.1 − ζ − Carrageenan 0 0.2 0.4 1.0 − Water Remaining amount Remaining amount Remaining amount Remaining amount − Total 100 100 100 100 100 ──── ──────────────────────────────── Carrageenan / 0 2.3 4.6 11.4 − Milk protein ───────── ─────────────────────────── Glossy evaluation Luster Yes Luster Yu Luster Yu Luster Yu (* 2) Luster Yu ────── ───────────────────────── ──── (Unit: w / w%, * 2: viscosity is difficult to use high.)

【0019】上記結果から明らかなように、焼成後のク
ッキー表面のツヤは、カラギーナン濃度に比例してツヤ
が向上した。しかし、は粘度が高くなりすぎることに
より、使い勝手が悪く、、がの液卵使用区と同等
で最適であった。
As is clear from the above results, the gloss of the cookie surface after baking was improved in proportion to the carrageenan concentration. However, because the viscosity became too high, the usability was poor, and it was the same as that of the liquid egg use group and was optimal.

【0020】実施例3 ホエー蛋白質20重量部とλ−カラギーナン2重量部、
アルコール9重量部、食塩4重量部、アミノ酸液4重量
部、グルコース4重量部を水に溶解し、全量が100重
量部になるように調製する。これを使用時に2.5倍に
希釈してクロワッサンの表面に塗布し、180℃で、8
分間乾燥することにより、良好なツヤを得ると共に、程
よい焼き色も付いた。
Example 3 20 parts by weight of whey protein and 2 parts by weight of λ-carrageenan,
9 parts by weight of alcohol, 4 parts by weight of salt, 4 parts by weight of amino acid solution, and 4 parts by weight of glucose are dissolved in water to prepare a total amount of 100 parts by weight. When using it, dilute it 2.5 times and apply it on the surface of the croissant.
By drying for a minute, a good luster was obtained and a moderate brown color was also attached.

【0021】実施例4 濃口醤油25重量部と、上白糖22重量部、本みりん1
0重量部、化学調味料3重量部、だし汁20重量部、水
20重量部からなる焼き鳥のタレにホエー蛋白質を10
w/w%、λ−カラギーナンを0.8w/w%溶解し、
含有させることにより、焼き上った焼き鳥のテリ・ツヤ
が優れ、かつ、冷めてからもより長時間ツヤを維持する
ことができた。
Example 4 25 parts by weight of concentrated soy sauce, 22 parts by weight of white sucrose, 1 part of mirin
0 parts by weight, 3 parts by weight of chemical seasoning, 20 parts by weight of soup stock, and 20 parts by weight of water are added to the sauce of yakitori and 10 parts of whey protein.
w / w%, λ-carrageenan 0.8 w / w% dissolved,
By including it, the yakitori that had been cooked up had an excellent terry and luster, and it was possible to maintain the luster for a long time even after cooling.

【0022】[0022]

【発明の効果】以上説明したように、本発明に係るツヤ
出し方法は、パン・菓子等の食品の製造工程で、その表
面に塗布又はスプレー等で被覆せしめた後、焼成又は乾
燥することによって、液卵を使用したときと同等のツヤ
を得ることができる。したがって、従来法に比べ、微生
物面で安全であり、かつ汎用性が高く、保存性に優れ、
ツヤの質も優れたツヤ出し剤であり、これを使用したツ
ヤ出し方法の実施効果は極めて大きいと言える。
As described above, the glossing method according to the present invention is performed by baking or drying after coating or spraying the surface of food in the manufacturing process of food such as bread and confectionery. The same gloss as when using liquid egg can be obtained. Therefore, as compared with the conventional method, it is safe in terms of microorganisms, has high versatility, and has excellent preservability,
It is also a glossing agent having excellent luster quality, and it can be said that the effect of carrying out the glossing method using this is extremely large.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 君塚 房夫 滋賀県大津市瀬田3丁目4番1号 寳酒造 株式会社中央研究所内 (72)発明者 貝沼 禎介 滋賀県大津市瀬田3丁目4番1号 寳酒造 株式会社中央研究所内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Fusao Kimizuka 3-4-1 Seta, Otsu-shi, Shiga Prefecture, Central Research Laboratory, Mina Shuzo Co., Ltd. (72) Sadasuke Kainuma 3-4-1 Seta, Otsu, Shiga Prefecture No. Sake Brewing Co., Ltd. Central Research Institute

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 乳蛋白質及びカラギーナンを有効成分と
することを特徴とする食品用ツヤ出し剤。
1. A luster preparation for foods, which comprises milk protein and carrageenan as active ingredients.
【請求項2】 乳蛋白質が、脱脂粉乳、全脂粉乳、カゼ
イン又はホエー蛋白質から選択される請求項1記載の食
品用ツヤ出し剤。
2. The luster preparation for food according to claim 1, wherein the milk protein is selected from skimmed milk powder, whole milk powder, casein or whey protein.
【請求項3】 請求項1又は請求項2記載のツヤ出し剤
で食品の表面を被覆した後、加熱処理することを特徴と
する食品のツヤ出し方法。
3. A method for glossing a food, comprising coating the surface of the food with the glossing agent according to claim 1 or 2 and then heat-treating the food.
JP33692194A 1994-12-27 1994-12-27 Glossing agent for food Expired - Lifetime JP3414871B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33692194A JP3414871B2 (en) 1994-12-27 1994-12-27 Glossing agent for food

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33692194A JP3414871B2 (en) 1994-12-27 1994-12-27 Glossing agent for food

Publications (2)

Publication Number Publication Date
JPH08173089A true JPH08173089A (en) 1996-07-09
JP3414871B2 JP3414871B2 (en) 2003-06-09

Family

ID=18303868

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33692194A Expired - Lifetime JP3414871B2 (en) 1994-12-27 1994-12-27 Glossing agent for food

Country Status (1)

Country Link
JP (1) JP3414871B2 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63273430A (en) * 1987-05-01 1988-11-10 日本製粉株式会社 Improvement in breads
JPS63304940A (en) * 1987-06-03 1988-12-13 日本製粉株式会社 Production of semi-baked bread
JPH0292231A (en) * 1988-09-28 1990-04-03 Fuji Oil Co Ltd Production of bread
JPH0339029A (en) * 1989-07-07 1991-02-20 Nippon Sanso Kk Frozen dough and preparation therefor
JPH03244348A (en) * 1989-09-29 1991-10-31 Unilever Nv Foodstuff

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63273430A (en) * 1987-05-01 1988-11-10 日本製粉株式会社 Improvement in breads
JPS63304940A (en) * 1987-06-03 1988-12-13 日本製粉株式会社 Production of semi-baked bread
JPH0292231A (en) * 1988-09-28 1990-04-03 Fuji Oil Co Ltd Production of bread
JPH0339029A (en) * 1989-07-07 1991-02-20 Nippon Sanso Kk Frozen dough and preparation therefor
JPH03244348A (en) * 1989-09-29 1991-10-31 Unilever Nv Foodstuff

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