JPH0816788B2 - Recording method - Google Patents
Recording methodInfo
- Publication number
- JPH0816788B2 JPH0816788B2 JP1195624A JP19562489A JPH0816788B2 JP H0816788 B2 JPH0816788 B2 JP H0816788B2 JP 1195624 A JP1195624 A JP 1195624A JP 19562489 A JP19562489 A JP 19562489A JP H0816788 B2 JPH0816788 B2 JP H0816788B2
- Authority
- JP
- Japan
- Prior art keywords
- developer
- resin
- magnetic
- image
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は彩色性に優れた磁性現像剤を用いた記録方法
に関する。更には有機強磁性樹脂を主成分として構成さ
れた彩色性に優れた磁性現像剤を用いた記録方法に関す
る。TECHNICAL FIELD The present invention relates to a recording method using a magnetic developer having excellent coloring properties. Further, the present invention relates to a recording method using a magnetic developer composed mainly of an organic ferromagnetic resin and excellent in coloring.
［従来技術］ 従来、一般に所謂−成分磁性現像剤は熱可塑性樹脂を
主成分とした現像剤粒子の内部に不透明な金属強磁性体
粒子を含有しているために、黒色の磁性現像剤像乃至は
濁った色の磁性現像剤像の記録を得るには良いが、色鮮
やかな磁性現像剤像の記録を得ることは出来なかった。[Prior Art] Conventionally, a so-called -component magnetic developer generally contains an opaque metal ferromagnetic particle inside a developer particle containing a thermoplastic resin as a main component, so that a black magnetic developer image or Was good for obtaining a magnetic developer image having a cloudy color, but could not obtain a bright magnetic developer image.
［発明の目的］ 本発明は前述した従来の記録方法とは異なり、有機強
磁性樹脂を主成分として構成した磁性現像剤を用いるこ
とにより、従来出来なかった磁性現像剤を用いても彩色
性に優れた色鮮やかな磁性現像剤像記録が得られる新規
な記録方法を提供することを目的とする。更には異なる
色の磁性現像剤像を重ねることによって彩色再現性が優
れた記録方法を提供することを目的とする。[Object of the Invention] Unlike the above-described conventional recording method, the present invention uses a magnetic developer containing an organic ferromagnetic resin as a main component, so that the coloring property can be improved even when a magnetic developer which has not been conventionally available is used. An object of the present invention is to provide a novel recording method capable of obtaining an excellent color magnetic developer image recording. Another object is to provide a recording method having excellent color reproducibility by superposing magnetic developer images of different colors.
［課題を解決するための手段］ 本発明は、現像剤供給容器内の、加熱によって軟化
し、軟化温度以上で熱硬化する有機強磁性樹脂を主成分
として構成され、かつ可視光の波長以下の大きさの強磁
性金属を含む磁性現像剤を、内部に磁界発生手段を有す
る現像剤保持部材上に担持させ、該磁性現像剤を現像部
に供給して潜像保持体の潜像を現像し現像剤像を形成
し、該現像剤像を記録紙に転写し、該現像剤の熱硬化温
度又は増粘温度未満で加熱し、該記録紙に該現像剤像を
軟化定着させることを特徴とする記録方法に関する。MEANS FOR SOLVING THE PROBLEM The present invention is mainly composed of an organic ferromagnetic resin in a developer supply container, which is softened by heating and thermosets at a softening temperature or higher, and has a wavelength of visible light or less. A magnetic developer containing a ferromagnetic metal of a size is carried on a developer holding member having a magnetic field generating means inside, and the magnetic developer is supplied to the developing section to develop the latent image on the latent image carrier. Forming a developer image, transferring the developer image to a recording paper, and heating the developer image at a temperature lower than a thermosetting temperature or a thickening temperature of the developer to soften and fix the developer image on the recording paper. Recording method.
本発明によれば、磁性現像剤が、有機強磁性樹脂を主
成分として構成され、かつ可視光の波長以下の大きさの
強磁性金属を含むことから、磁性現像剤を用いても彩色
性に優れた色鮮やかな定着した現像剤像が得られ、異な
る色の磁性現像剤像を重ねることによっても彩色再現性
が優れた記録ができ、さらに、上記磁性現像剤は、可視
光の波長以下の大きさの鉄、ニッケル、コバルト等の単
体金属又は合金の如き強磁性金属（金属イオンを含む）
を含むことにより、磁気特性が補われるため、現像剤保
持部材方向に充分な磁気的吸引力をもたせることが出来
ることから現像剤の飛散も少なく、現像剤粒子同志の凝
集も避けられ忠実な現像が可能となり、かつこの強磁性
金属は、可視光の波長以下の大きさであることから、光
透過性が損なわれることがないから、彩色性と彩色再現
性に優れた色鮮やかな磁性現像剤像記録ができ、さら
に、上記有機強磁性樹脂は、加熱によって軟化し、軟化
温度以上で熱硬化するものであり、現像剤像の記録紙へ
の定着が磁性現像剤の熱硬化温度又は増粘温度未満の温
度で行なわれることから、定着記録画像は良好な柔軟性
を有することになり、こすったり、記録紙を折っても充
分に定着された定着記録画像が得られるようになる。According to the present invention, since the magnetic developer is composed of an organic ferromagnetic resin as a main component and contains a ferromagnetic metal having a size equal to or less than the wavelength of visible light, the magnetic developer can be colored even if it is used. An excellent vividly fixed developer image can be obtained, and recording with excellent color reproducibility can be achieved by superimposing magnetic developer images of different colors. Further, the magnetic developer has a wavelength of visible light or less. Ferromagnetic metals (including metal ions) such as iron, nickel, cobalt, etc. of a single size or alloys
By including the magnetic properties, it is possible to provide a sufficient magnetic attraction force in the direction of the developer holding member, so that the scattering of the developer is small and the agglomeration of the developer particles is avoided, so that faithful development is possible. In addition, since this ferromagnetic metal has a size not larger than the wavelength of visible light, the light transmissivity is not impaired. Therefore, a colorful magnetic developer excellent in chromaticity and chromatic reproducibility. Image recording is possible. Furthermore, the organic ferromagnetic resin is softened by heating and heat-cured at a softening temperature or higher. Since it is carried out at a temperature lower than the temperature, the fixed recorded image has good flexibility, and a sufficiently fixed fixed recorded image can be obtained even by rubbing or folding the recording paper.
使用する有機磁性樹脂としては例えば日本化学会（'8
9/春）予稿集1IKO4,1IKO7,1IKO8、等に開示されてい
る。例えばトリアリールメチル構造を有するビレン−芳
香族アルデヒト系からなる縮合多環多核芳香族（COPNA
樹脂）等公知の光脱水素法や放電法によって付対電子構
造を作って必要なスピンを充分に立てて作った目的の特
性的特性にあった有機磁性樹脂を使用すれば良い。これ
らの樹脂はある温度で軟化し、その温度より高い温度で
熱硬化する。一般に熱硬化すると高分子化し、その色彩
は深色化する。Examples of the organic magnetic resin used include the Chemical Society of Japan ('8
9 / Spring) Proceedings 1IKO4, 1IKO7, 1IKO8, etc. For example, a fused polycyclic polynuclear aromatic (COPNA) consisting of a biren-aromatic aldecht system having a triarylmethyl structure.
It is possible to use an organic magnetic resin having a desired characteristic property such as a resin) prepared by forming a paired electron structure by a known photodehydrogenation method or a discharge method so that a necessary spin is sufficiently established. These resins soften at a certain temperature and thermoset at a temperature higher than that temperature. Generally, when it is heat-cured, it becomes a polymer and its color becomes deep.
また使用する加熱定着装置は、その方式に限定されな
いが例えば熱ローラ定着器を使用すれば良い。The heat fixing device to be used is not limited to that type, but a heat roller fixing device may be used, for example.
［実施例］ 以下に本発明の図示の実施例に基ずいて説明する。[Example] The following description will be given based on an illustrated example of the present invention.
第１図は現像剤の特徴を示したもので、第１−１図〜
第１−３図は本発明に係る有機強磁性樹脂を主成分とし
て構成された磁性現像剤を示す概略断面図である。第１
−４図は従来の磁性現像剤を示す概略断面図である。図
において１は磁性現像剤、２は加熱によって軟化し該軟
化温度以上で熱硬化する有機強磁性樹脂かもしくはこの
樹脂を主成分とした樹脂で熱可塑性樹脂との混合樹脂
で、それ自体が着色されているかもしくは染料でも着色
されている。３は有機強磁性樹脂かもしくはこの樹脂を
主成分とした樹脂で、それ自体が着色されているかもし
くは染料でも着色されており、４は熱可塑性樹脂であ
る。５は無機強磁性粉で着色剤としての顔料の役目も果
たしている。第１−１図は現像剤の全体が有機強磁性樹
脂を主成分として構成された磁性現像剤で、加熱によっ
て軟化し該軟化温度以上で熱硬化する有機強磁性樹脂か
もしくはこの樹脂を主成分とした樹脂で熱可塑性樹脂と
の混合樹脂で、それ自体が着色されているかもしくは染
料でも着色されている。第１−２図は現像剤の内部が有
機強磁性樹脂かもしくはこの樹脂を主成分とした樹脂で
構成されていて、それ自体が着色されているかもしくは
染料でも着色されており、この周囲が熱可塑性樹脂で被
覆された構造の現像剤を示す。第１−３図は有機強磁性
樹脂かもしくはこの樹脂を主成分とした樹脂３で、それ
自体が着色されているかもしくは染料でも着色されてた
粒子の周囲が、熱可塑性樹脂４で結着された構造からな
る現像剤を示す。第１−４図は従来の磁性現像剤で熱可
塑性樹脂４の内部にFe3O4等の無機強磁性粉が分散され
ており、着色剤としての顔料の役目も果たし、目的によ
っては無機強磁性粉を着色している。しかしこの場合は
どんなに頑張っても明るい彩色性の優れた色は出せな
い。FIG. 1 shows the characteristics of the developer.
1-3 are schematic cross-sectional views showing a magnetic developer composed mainly of an organic ferromagnetic resin according to the present invention. First
4 is a schematic sectional view showing a conventional magnetic developer. In the figure, 1 is a magnetic developer, 2 is an organic ferromagnetic resin that is softened by heating and thermoset at a temperature above the softening temperature, or a resin containing this resin as a main component and a mixed resin with a thermoplastic resin, which itself is colored. It is either colored or dyed. Reference numeral 3 is an organic ferromagnetic resin or a resin containing this resin as a main component, which itself is colored or colored with a dye, and 4 is a thermoplastic resin. Inorganic ferromagnetic powder 5 also serves as a pigment as a colorant. FIG. 1-1 shows a magnetic developer in which the entire developer is composed of an organic ferromagnetic resin as a main component, and either an organic ferromagnetic resin which is softened by heating and thermoset at the softening temperature or higher, or a main component of which is the resin. The above resin is a mixed resin with a thermoplastic resin and is colored by itself or with a dye. Fig. 1-2 shows that the inside of the developer is composed of an organic ferromagnetic resin or a resin containing this resin as a main component, and the developer itself is colored or is also colored with a dye. 1 shows a developer having a structure coated with a plastic resin. FIG. 1-3 shows an organic ferromagnetic resin or a resin 3 containing this resin as a main component, and the periphery of the particles which are themselves colored or are dyed with a dye are bound with a thermoplastic resin 4. 2 shows a developer having a different structure. Fig. 1-4 shows a conventional magnetic developer in which inorganic ferromagnetic powder such as Fe 3 O 4 is dispersed in the thermoplastic resin 4, and it also serves as a pigment as a colorant. Magnetic powder is colored. However, in this case, no matter how hard you try, you can't get a bright color.
第２図は上記加熱によって軟化し該軟化温度以上で熱
硬化する有機強磁性現像剤の現像剤像を記録紙上に定着
せしめる定着温度Tfを示し、さらに詳しくは第３図で示
した記録装置の熱ローラ定着装置の温度制御された熱ロ
ーラ温度Ｔを時間ｔに対して示す。温度制御方法は公知
の方法で充分である。例えば特開昭62-206580号証明細
書等に開示された方法で良い。熱ローラ温度Ｔはｔ＝０
で温度が立ち上がり、有機磁性樹脂の軟化温度T1より高
温で、有機強磁性現像剤の硬化温度又は増粘温度T2未満
の温度の温度範囲に温度制御されて定着される。ここで
Ｔは定着温度を意味し、熱ローラ温度のみに限定される
ものではない。FIG. 2 shows a fixing temperature T f at which a developer image of an organic ferromagnetic developer which is softened by the above-mentioned heating and thermally cured at the softening temperature or higher is fixed on the recording paper, and more specifically, the recording apparatus shown in FIG. The temperature-controlled heat roller temperature T of the heat roller fixing device is shown with respect to time t. A known method is sufficient as the temperature control method. For example, the method disclosed in the specification of JP-A-62-206580 may be used. Heat roller temperature T is t = 0
The temperature rises, and the temperature is controlled to a temperature range higher than the softening temperature T 1 of the organic magnetic resin and lower than the curing temperature or the thickening temperature T 2 of the organic ferromagnetic developer, and the fixing is performed. Here, T means a fixing temperature and is not limited to the heat roller temperature.
第３図は本実施例で用いた記録装置の概略を示す図
で、11は電子写真感光体から成る静電潜像保持体、12は
帯電器、13は像露光、14、15は現像装置で、14-1と15-1
はその内部に磁界発生手段を有する現像剤保持部材（現
像ローラ）、16は無端状の転写ベルト、17、18は駆動ロ
ーラ、19は転写ベルトを帯電させるための帯電器、20は
給紙トレイ、21は給紙ローラ、22は給紙ガイド、23は記
録紙24を転写ベルトから分離させるための放電器、25は
熱ローラ定着装置、26はクリーニング装置である。静電
潜像保持体11上に形成された静電潜像を現像装置14、又
は15で静電潜像保持体11の回転ごとに現像される。転写
ベルト16の帯電面に給紙ガイド22を通過して給紙された
記録紙24は転写ベルトに静電的に付着し、回動する転写
ベルトに従って搬送され、電子写真感光体から成る静電
潜像保持体11との最近接点で静電潜像保持体11上の現像
剤像を必要な回数だけ繰り返し転写して、時によって又
画面の場所によって異なる色の現像剤像を重ねて転写
し、その後放電器23によって転写ベルト16上の電荷を弱
めることによって表面に未定着現像剤像を有する記録紙
24を転写ベルトから分離し熱ローラ定着装置25に送って
定着する。この時の定着温度は第２図に示したT1とT2の
温度範囲内に制御されて定着される。FIG. 3 is a diagram showing an outline of the recording apparatus used in this embodiment, 11 is an electrostatic latent image holding member composed of an electrophotographic photosensitive member, 12 is a charger, 13 is image exposure, and 14 and 15 are developing devices. And 14-1 and 15-1
Is a developer holding member (developing roller) having magnetic field generating means inside thereof, 16 is an endless transfer belt, 17 and 18 are drive rollers, 19 is a charger for charging the transfer belt, and 20 is a paper feed tray. , 21 is a paper feed roller, 22 is a paper feed guide, 23 is a discharger for separating the recording paper 24 from the transfer belt, 25 is a heat roller fixing device, and 26 is a cleaning device. The electrostatic latent image formed on the electrostatic latent image holder 11 is developed by the developing device 14 or 15 each time the electrostatic latent image holder 11 is rotated. The recording paper 24 fed through the paper feed guide 22 to the charged surface of the transfer belt 16 is electrostatically adhered to the transfer belt and is conveyed along the rotating transfer belt, and is composed of an electrophotographic photosensitive member. The developer image on the electrostatic latent image carrier 11 is repeatedly transferred as many times as necessary at the closest contact point with the latent image carrier 11, and the developer images of different colors are transferred at different times depending on the screen location. , Recording paper having an unfixed developer image on its surface by weakening the charge on the transfer belt 16 by the discharger 23 thereafter.
24 is separated from the transfer belt and sent to the heat roller fixing device 25 to be fixed. The fixing temperature at this time is controlled and fixed within the temperature range of T 1 and T 2 shown in FIG.
使用した有機強磁性樹脂は日本化学会（'89/春）予稿
集1IKO4,1IKO7,1IKO8に開示されているトリアリールメ
チル構造を有するビレン−芳香族アルデヒト系から成る
縮合多核芳香族（COPNA樹脂）を公知の光脱水法や放電
法によって不対電子構造を作って、必要なスピンを充分
に立てて作った有機強磁性樹脂を使った。この樹脂は摂
氏55〜60度で軟化し（T1＝55〜60度）、摂氏220度以上
で硬化した。僅かな金属イオンの含有（例えばFeイオン
含有）によっても彩色豊かな赤色と黄色の有機強磁性樹
脂が得られた。この粒径が約12マイクロメーターの粒子
はその内部に磁界発生手段を有する現像剤保持部材14-
1、15-1の表面に充分に磁力によって引き付けられる力
であった。含有する金属イオンが例えばFeイオンのよう
な強磁性金属の場合は得られる有機強磁性樹脂粒子に作
用する磁力を補助的に強くする効果が得られた。The organic ferromagnetic resin used is a condensed polynuclear aromatic (COPNA resin) consisting of a biren-aromatic aldecht system having a triarylmethyl structure, which is disclosed in the Chemical Society of Japan ('89 / Spring) Proceedings 1IKO4, 1IKO7, 1IKO8. Was used to form an unpaired electron structure by a known photodehydration method or discharge method, and an organic ferromagnetic resin was used which was prepared by sufficiently raising the necessary spin. The resin softened at 55-60 degrees Celsius (T 1 = 55-60 degrees) and hardened at 220 degrees Celsius or higher. Red and yellow organic ferromagnetic resins with rich colors were obtained even with a small amount of metal ions (for example, Fe ions). The particles having a particle diameter of about 12 micrometers are the developer holding member 14- having a magnetic field generating means inside thereof.
It was a force that was sufficiently attracted to the surface of 1, 15-1 by magnetic force. When the contained metal ion is a ferromagnetic metal such as Fe ion, the effect of supplementarily increasing the magnetic force acting on the obtained organic ferromagnetic resin particles was obtained.
また使用した熱可塑性樹脂は軟化温度が約60度のスチ
レン系の樹脂であった。上記有機強磁性樹脂に全樹脂の
重量当たりの重量比で10％のこの熱可塑性樹脂を混入さ
せて作った有機磁性現像剤の硬化温度又は増粘温度T2は
摂氏215度〜225度であった。したがって定着温度TfをT1
とT2の間の135℃で定着させた。なお重量比で50％以上
の熱可塑性樹脂を混入させると、粒径が約12マイクロメ
ータのこの粒子はその内部に磁界発生手段を有する現像
剤保持部材14-1、15-1の表面に充分に磁力によって引き
付けられなくなり、有機強磁性樹脂の構成比を全樹脂の
重量当たりの重量比に対して50％以上に成るように構成
しなければならないことがわかった。有機強磁性樹脂を
主成分とした磁性現像剤の「主成分」の意味は、この意
味である。このことは従来の磁性現像剤と異なり、全体
がもしくはほぼ全体が強磁性体であり全体が常に均一に
磁力を受け、有機強磁性樹脂を使用することの磁気的意
味を有意義に保持することからも大切である。たとえ現
像剤の粒子が更に破壊されて小さくなっても確実にその
粒径に依存した磁力が働くからである。The thermoplastic resin used was a styrene resin having a softening temperature of about 60 degrees. Curing temperature or thickening temperature T 2 of 10% of the organic magnetic developer made by the thermoplastic resin is mixed in weight ratio per weight of the total resin in the organic ferromagnetic resin was 215 ° to 225 ° C It was Therefore, the fixing temperature T f is set to T 1
It was fixed at 135 ° C. between T 2 and T 2 . When 50% or more by weight of the thermoplastic resin is mixed, the particles having a particle size of about 12 micrometers are sufficiently formed on the surface of the developer holding members 14-1 and 15-1 having the magnetic field generating means therein. It was found that the organic ferromagnetic resin must not be attracted by the magnetic force, and the composition ratio of the organic ferromagnetic resin must be 50% or more based on the weight ratio of the total resin. This is the meaning of the "main component" of the magnetic developer containing an organic ferromagnetic resin as the main component. This is because unlike the conventional magnetic developer, the whole or almost the whole is a ferromagnetic substance and the whole receives a uniform magnetic force, and the magnetic meaning of using the organic ferromagnetic resin is significantly retained. Is also important. This is because even if the particles of the developer are further destroyed and become smaller, the magnetic force depending on the particle size is surely exerted.
上記に示した別の熱可塑性樹脂を含まない有機強磁性
樹脂から構成された有機磁性現像剤と熱可塑性樹脂を10
％含む有機磁性現像剤を使って、第１表に示すように （１）T2＞Tf＞T1、Tf＝摂氏135度の定着条件と （２）Tf＞T2＞T1、Tf＝摂氏230度の定着条件とで 現像記録した現像剤像を定着させたところ、 （１）T2＞Tf＞T1、Tf＝摂氏135度の定着条件のもとで
記録した定着記録像は柔軟性があり、こすっても充分に
定着されているが、（２）Tf＞T2＞T1、Tf＝摂氏230度
の定着条件のもとで記録した定着記録像は柔軟性がな
く、こすったり折ると、脆く時には落ちてしまった。An organic magnetic developer composed of an organic ferromagnetic resin containing no other thermoplastic resin as described above and a thermoplastic resin 10
% Using an organic magnetic developer containing (1) T 2 > T f > T 1 , T f = 135 ° C. fixing conditions and (2) T f > T 2 > T 1 , T f = 230 degrees Celsius fixing conditions, the developer image recorded and fixed was fixed (1) T 2 > T f > T 1 , T f = 135 degrees Celsius fixing conditions The fixed recorded image has flexibility and is sufficiently fixed even by rubbing, but (2) Fixed recording recorded under the fixing conditions of T f > T 2 > T 1 and T f = 230 degrees Celsius. The statue was inflexible and when rubbed or folded it became brittle and fell off.
また異なる色の有機強磁性現像剤像を記録紙上に重ね
て記録したところ、彩色性の優れた混色像が得られた。
この色は従来の無機磁性体を内部に含有した磁性現像剤
では得られない彩色性豊かな現像剤像であった。勿論一
色の現像剤像においても同様であることは言うまでもな
いことである。Further, when organic ferromagnetic developer images of different colors were overlaid and recorded on a recording paper, a color mixture image excellent in coloring was obtained.
This color was a developer image with rich coloring that could not be obtained with a conventional magnetic developer containing an inorganic magnetic material. It goes without saying that the same applies to a single color developer image.
〔発明の効果〕 本発明においては、上述した構成により、磁性現像剤
を用いても彩色性に優れた色鮮やかな定着した現像剤像
が得られ、また、光透過が損なわれることなく充分な磁
気的吸引力が得られることにより、彩色性に優れ、かつ
現像剤の飛散や現像剤同志の凝集が生じにくく、忠実な
現像が可能であり、さらに定着画像は良好な柔軟性を有
することになり、こすったり記録紙を折っても充分に定
着された定着録画像が得られる。 [Advantages of the Invention] In the present invention, due to the above-described constitution, a vividly fixed developer image having excellent colorability can be obtained even when a magnetic developer is used, and the light transmission is sufficient without being impaired. Since the magnetic attraction is obtained, the coloring property is excellent, the scattering of the developer and the aggregation of the developers do not easily occur, faithful development is possible, and the fixed image has good flexibility. Even if the recording paper is rubbed or the recording paper is broken, a sufficiently fixed fixed recorded image can be obtained.
添付図面中、第１−１図、第１−２図及び第１−３図は
本発明に係る磁性現像剤の概略断面図を示し、第１−４
図は、従来の磁性現像剤の概略的断面図を示す。 第２図は、有機強磁性現像剤の熱定着性を説明するため
の図である。 第３図は、本実施例で用いた記録装置の概略図を示す。In the accompanying drawings, FIGS. 1-1, 1-2, and 1-3 show schematic cross-sectional views of the magnetic developer according to the present invention.
The figure shows a schematic cross-sectional view of a conventional magnetic developer. FIG. 2 is a diagram for explaining the heat fixing property of the organic ferromagnetic developer. FIG. 3 shows a schematic view of the recording apparatus used in this example.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｇ０３Ｇ 13/09 15/08 ５０７ Ｌ 15/16 15/20 １０２ １０９ Ｇ０３Ｇ 9/08 ３０１ ３６１ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI Technical display location G03G 13/09 15/08 507 L 15/16 15/20 102 109 G03G 9/08 301 361
Claims (5)
し、軟化温度以上で熱硬化する有機強磁性樹脂を主成分
として構成され、かつ、可視光の波長以下の大きさの強
磁性金属を含む磁性現像剤を、内部に磁界発生手段を有
する現像剤保持部材上に担持させ、該磁性現像剤を現像
部に供給して潜像保持体の潜像を現像し現像剤像を形成
し、該現像剤像を記録紙に転写し、該現像剤の熱硬化温
度又は増粘温度未満で加熱し、該記録紙に該現像剤像を
軟化定着させることを特徴とする記録方法。1. A ferromagnetic metal which is composed mainly of an organic ferromagnetic resin which is softened by heating and heat-cured at a softening temperature or higher in a developer supply container and has a size not larger than a wavelength of visible light. A magnetic developer containing is carried on a developer holding member having a magnetic field generating means inside, and the magnetic developer is supplied to a developing portion to develop the latent image on the latent image carrier to form a developer image, A recording method comprising transferring the developer image to a recording paper, heating the developer image at a temperature lower than a thermosetting temperature or a thickening temperature of the developer, and softening and fixing the developer image on the recording paper.
特徴とする特許請求の範囲第１項に記載の記録方法。2. The recording method according to claim 1, wherein the ferromagnetic metal is a metal ion.
されていることを特徴とする特許請求の範囲第２頁に記
載の記録方法。3. The recording method according to claim 2, wherein the metal ion is contained in the organic ferromagnetic resin.
現像剤であることを特徴とする特許請求の範囲第１項乃
至第３項記載の記録方法。4. The recording method according to any one of claims 1 to 3, wherein the magnetic developer is a colored magnetic developer.
て搬送され、該記録紙に該現像剤像が転写されることを
特徴とする特許請求の範囲第１項乃至第４項記載の記録
方法。5. The recording sheet according to claim 1, wherein the recording sheet is electrostatically adhered to the transfer belt and conveyed, and the developer image is transferred to the recording sheet. Recording method described in section.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1195624A JPH0816788B2 (en) | 1989-07-28 | 1989-07-28 | Recording method |
| US08/157,433 US5407769A (en) | 1989-07-28 | 1993-11-26 | Magnetic toner having triaryl methyl organic resin |
| US08/355,494 US5523190A (en) | 1989-07-28 | 1994-12-14 | Magnetic toner and recording method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1195624A JPH0816788B2 (en) | 1989-07-28 | 1989-07-28 | Recording method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0359672A JPH0359672A (en) | 1991-03-14 |
| JPH0816788B2 true JPH0816788B2 (en) | 1996-02-21 |
Family
ID=16344266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1195624A Expired - Fee Related JPH0816788B2 (en) | 1989-07-28 | 1989-07-28 | Recording method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0816788B2 (en) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62192383A (en) * | 1986-02-20 | 1987-08-22 | Hidetoshi Tsuchida | Polytetraazaporphine iron complex and organic magnetic material |
| JP2583223B2 (en) * | 1987-01-19 | 1997-02-19 | 富士通株式会社 | Carrier for magnetic brush development |
| JPS63202758A (en) * | 1987-02-19 | 1988-08-22 | Casio Electronics Mfg Co Ltd | Dry magnetic developer |
| JPS63228171A (en) * | 1987-03-17 | 1988-09-22 | Matsushita Electric Ind Co Ltd | Low-temperature fixable toner |
| JPS6438757A (en) * | 1987-08-05 | 1989-02-09 | Toyo Ink Mfg Co | Thermosetting powdery toner for developing electrostatic charge image |
| JPH0615708B2 (en) * | 1987-12-23 | 1994-03-02 | 矢崎総業株式会社 | Cooling device for continuous annealing machine |
-
1989
- 1989-07-28 JP JP1195624A patent/JPH0816788B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| 日本化学会第５８春季年会（１９８９年）講演予稿集▲ＩＩ▼Ｐ．１０９８〜１１００ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0359672A (en) | 1991-03-14 |
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