JPH08160002A - Oxygen sensor structure - Google Patents

Oxygen sensor structure

Info

Publication number
JPH08160002A
JPH08160002A JP6305178A JP30517894A JPH08160002A JP H08160002 A JPH08160002 A JP H08160002A JP 6305178 A JP6305178 A JP 6305178A JP 30517894 A JP30517894 A JP 30517894A JP H08160002 A JPH08160002 A JP H08160002A
Authority
JP
Japan
Prior art keywords
oxygen sensor
outer cylinder
end side
protective outer
sensor structure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6305178A
Other languages
Japanese (ja)
Other versions
JP3369766B2 (en
Inventor
Tomimasa Itou
富政 伊藤
Koichi Takahashi
浩一 高橋
Takuya Saito
卓也 斉藤
Takao Kojima
孝夫 小島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Niterra Co Ltd
Original Assignee
NGK Spark Plug Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NGK Spark Plug Co Ltd filed Critical NGK Spark Plug Co Ltd
Priority to JP30517894A priority Critical patent/JP3369766B2/en
Publication of JPH08160002A publication Critical patent/JPH08160002A/en
Application granted granted Critical
Publication of JP3369766B2 publication Critical patent/JP3369766B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403Cells and electrode assemblies
    • G01N27/406Cells and probes with solid electrolytes
    • G01N27/407Cells and probes with solid electrolytes for investigating or analysing gases
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403Cells and electrode assemblies
    • G01N27/406Cells and probes with solid electrolytes
    • G01N27/407Cells and probes with solid electrolytes for investigating or analysing gases
    • G01N27/4078Means for sealing the sensor element in a housing

Abstract

PURPOSE: To provide an oxygen sensor structure in which the deformation or damage of a metal cylinder due to flying stone can be suppressed to the minimum. CONSTITUTION: The oxygen sensor 1 is so mounted at its outer cylinder 39 at a main body fitting 29 as to cover an inner cylinder 33, a ceramic separator 35, and the outside of a waterproof sealing member 37. The cylinder 39 is formed out of a first cylindrical part 39H1 of the end side having a thickness of 1mm or less, a first stepped part 39D1 bent at about 45 deg. to the part 39H1, a second cylindrical part 39H2 of the center side, a second stepped part 39D2 bent substantially perpendicularly to the part 39H2, and a third cylindrical part 39H3 of the rear end side. The cylinder 39 is welded over the entire outer periphery to the fitting 29 on the lower end side of the part 39H1 having the largest diameter. It is radially clamped by the part 39H3 having the smallest diameter.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、例えば内燃機関からの
排気ガス中の酸素濃度を検出する酸素センサ等に適用さ
れる酸素センサ構造に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an oxygen sensor structure applied to, for example, an oxygen sensor for detecting the oxygen concentration in exhaust gas from an internal combustion engine.

【0002】[0002]

【従来の技術】従来より、自動車等の内燃機関の排気ガ
ス中の酸素濃度を検出する酸素センサとして、酸素イオ
ン伝導性の固体電解質(例えばジルコニア)等からなる
起電力型のものと、金属酸化物(チタニア)等の抵抗変
化型のものがあり、内燃機関の空燃比等を制御する目的
で使用されている。
2. Description of the Related Art Conventionally, as an oxygen sensor for detecting the oxygen concentration in the exhaust gas of an internal combustion engine of an automobile or the like, an electromotive force type sensor made of an oxygen ion conductive solid electrolyte (for example, zirconia) and a metal oxide are used. There is a resistance change type such as an object (titania), which is used for the purpose of controlling the air-fuel ratio of the internal combustion engine.

【0003】この種の酸素センサにおいては、固体電解
質や金属酸化物からなる検出素子は、(センサを排気管
に装着する)主体金具及び金属筒体等からなる容器(セ
ンサケース)内に収容されており、検出素子に接続され
たリード線は、酸素センサの後端側からセンサケース外
部に伸びている。
In this type of oxygen sensor, a detection element made of a solid electrolyte or a metal oxide is housed in a container (sensor case) made of a metal shell (for mounting the sensor on an exhaust pipe) and a metal cylinder. The lead wire connected to the detection element extends from the rear end side of the oxygen sensor to the outside of the sensor case.

【0004】また、近年では、排気ガス規制の強化の一
手法として、触媒の後方にも酸素センサを取り付け、一
方のセンサにて空燃比制御が行われた時に、他方のセン
サにて触媒から排出される排気ガスの状態をモニター
し、その結果から触媒の劣化を検知することが始められ
ている。
Further, in recent years, as one method of strengthening the exhaust gas regulation, an oxygen sensor is also attached to the rear of the catalyst so that when one sensor controls the air-fuel ratio, the other sensor discharges the catalyst. It has begun to detect the deterioration of the catalyst from the result of monitoring the state of exhaust gas generated.

【0005】[0005]

【発明が解決しようとする課題】ところが、触媒の後方
に配設される酸素センサは、通常、車体下部に取り付け
られることになるので、つまり、路面のすぐ近くに配置
されることになるので、路面から種々の干渉を受けるこ
とがあった。
However, since the oxygen sensor arranged behind the catalyst is usually attached to the lower part of the vehicle body, that is, it is arranged in the immediate vicinity of the road surface, There were various interferences from the road surface.

【0006】例えば、酸素センサが路上に溜った水等に
完全に埋まってしまうことがある。そして、酸素センサ
が水没するとセンサ内部に水が浸入し易くなるので、そ
の対策として、例えば検出素子からセンサケース外部に
伸びるリード線を、センサの後端側でゴム等によりシー
ルする方法などがある。
For example, the oxygen sensor may be completely buried in water accumulated on the road. When the oxygen sensor is submerged in water, water easily enters the inside of the sensor. As a countermeasure, for example, there is a method of sealing a lead wire extending from the detection element to the outside of the sensor case with rubber or the like on the rear end side of the sensor. .

【0007】更に、例えば非舗装道路等を車両走行中
に、前輪タイヤからの飛石がセンサケースに当り、その
金属筒体等に変形や破損が発生することがある。そし
て、この様な変形等が発生すると、シール性が十分では
なくなるおそれがあり、特にシール性が低下した場合に
上述した水没が発生すると、センサ内部に水が浸入し易
くなるので、金属筒体の変形や破損に対する十分な対策
が望まれている。
Further, while the vehicle is traveling on an unpaved road, for example, flying stones from the front tires may hit the sensor case, causing deformation or damage to the metal cylinder or the like. When such a deformation occurs, the sealing performance may not be sufficient, and particularly when the above-mentioned submersion occurs when the sealing performance deteriorates, water easily enters the inside of the sensor. Sufficient measures against deformation and damage of the are desired.

【0008】本発明は、前記課題を解決するためになさ
れたものであり、飛石等による金属筒体の変形や破損等
を最小限に抑えることができる酸素センサ構造を提供す
ることを目的とする。
The present invention has been made to solve the above problems, and an object of the present invention is to provide an oxygen sensor structure capable of minimizing the deformation or damage of a metal cylinder due to flying stones or the like. .

【0009】[0009]

【課題を解決するための手段】前記目的を達成するため
に請求項1の発明は、先端側が測定対象に向けられる酸
素センサ自身を取付部位に取り付ける主体金具と、該主
体金具の後端側に取り付けられた金属保護外筒と、を備
えた酸素センサ構造において、前記金属保護外筒が、軸
方向における配置位置が異なる3種以上の筒状部を備え
るとともに、先端側の筒状部にて前記主体金具に全周溶
接され、且つ中央側の筒状部より後端側の筒状部の内部
に防水シール部材が配置され、更に、隣合う前記筒状部
同士を接続する構成として2箇所以上の応力吸収部を備
えたことを特徴とする酸素センサ構造を要旨とする。
In order to achieve the above-mentioned object, the invention of claim 1 has a metallic shell for mounting an oxygen sensor itself, the tip side of which is directed to a measuring object, at a mounting portion, and a metallic shell on the rear end side. In the oxygen sensor structure provided with the attached metal protective outer cylinder, the metal protective outer cylinder includes three or more types of tubular portions having different arrangement positions in the axial direction, and the distal end side tubular portion has a tubular portion. Two parts are welded all around the metal shell, a waterproof seal member is arranged inside the tubular portion on the rear end side of the tubular portion on the center side, and the adjacent tubular portions are connected to each other. The gist is an oxygen sensor structure including the above-described stress absorbing portion.

【0010】請求項2の発明は、前記3種以上の筒状部
の径が異なり、前記先端側の筒状部が最大径の筒状部で
あり、前記後端側の筒状部が最小径の筒状部であること
を特徴とする前記請求項1記載の酸素センサ構造を要旨
とする。
According to a second aspect of the present invention, the three or more types of tubular portions have different diameters, the tubular portion on the front end side is the tubular portion having the largest diameter, and the tubular portion on the rear end side is the most tubular portion. The oxygen sensor structure according to claim 1, wherein the oxygen sensor structure is a tubular portion having a small diameter.

【0011】請求項3の発明は、前記応力吸収部が、前
記金属保護外筒の周方向に環状に形成された、段差、凹
部又は凸部のいずれかであることを特徴とする前記請求
項1又は2記載の酸素センサ構造を要旨とする。
The invention of claim 3 is characterized in that the stress absorbing portion is any one of a step, a concave portion and a convex portion formed in an annular shape in the circumferential direction of the metal protective outer cylinder. The gist is the oxygen sensor structure described in 1 or 2.

【0012】請求項4の発明は、先端側が測定対象に向
けられる酸素センサ自身を取付部位に取り付ける主体金
具と、該主体金具の後端側に取り付けられた金属保護外
筒と、を備えた酸素センサ構造において、前記金属保護
外筒は、先端側にて前記主体金具に全周溶接されるとと
もに、後端側の内部に防水シール部材が配置され、更に
前記金属保護外筒は、その周方向に環状に形成された蛇
腹状の応力吸収部を備えたことを特徴とする酸素センサ
構造を要旨とする。
According to a fourth aspect of the present invention, there is provided an oxygen comprising a metallic shell for mounting an oxygen sensor itself, the tip side of which is directed to an object to be measured, at a mounting portion, and a metal protective outer cylinder mounted at a rear end side of the metallic shell. In the sensor structure, the metal protective outer cylinder is welded to the metal shell at the front end side, and a waterproof seal member is arranged inside the rear end side. An oxygen sensor structure is characterized in that it has a bellows-shaped stress absorbing portion formed in a ring shape.

【0013】請求項5の発明は、前記金属保護外筒の厚
さが0.3〜1mmの範囲であることを特徴とする前記請
求項1〜4のいずれか記載の酸素センサ構造を要旨とす
る。ここで、検出素子としては、例えば酸素濃度によっ
て起電力が変化する固体電解質(例えばジルコニアやイ
ットリア等)を用いた検出素子や、抵抗値が変化する金
属酸化物(例えばチタニア等)を用いた検出素子を採用
できる。
A fifth aspect of the present invention provides the oxygen sensor structure according to any one of the first to fourth aspects, characterized in that the thickness of the metal protective outer cylinder is in the range of 0.3 to 1 mm. To do. Here, as the detection element, for example, a detection element using a solid electrolyte (eg, zirconia or yttria) whose electromotive force changes depending on the oxygen concentration, or a detection using a metal oxide (eg, titania) whose resistance value changes The element can be adopted.

【0014】前記防水シール部材(グロメット)として
は、耐熱性を備えていることが好ましく、例えばシリコ
ンゴム、フッ素ゴム等を採用できる。前記筒状体の径と
しては、内径又は外径のいずれか一方を採用できる。前
記金属保護外筒が例えばSUS304のステンレスで形
成されている場合は、その厚さは0.5mm前後が好適で
ある。
The waterproof seal member (grommet) preferably has heat resistance, and for example, silicone rubber or fluororubber can be adopted. Either the inner diameter or the outer diameter can be adopted as the diameter of the tubular body. When the metal protective outer cylinder is made of, for example, SUS304 stainless steel, its thickness is preferably about 0.5 mm.

【0015】前記金属保護外筒の隣合う筒状部の径の比
が、(小径/大径)=0.65〜0.90の範囲である
場合、且つ/又は段差が、1.0〜3.0mmの範囲の場
合には、段差にて金属保護外筒が適度に屈曲してクッシ
ョンの役目を果たし、シール部分への悪影響を防止する
ことできるので、一層好適である。
When the ratio of the diameters of the adjacent cylindrical portions of the metal protective outer cylinder is in the range of (small diameter / large diameter) = 0.65 to 0.90, and / or the step difference is 1.0 to. In the case of the range of 3.0 mm, the metal protective outer cylinder is appropriately bent at the step to serve as a cushion, and it is possible to prevent an adverse effect on the seal portion, which is more preferable.

【0016】[0016]

【作用】請求項1の発明では、金属保護外筒の3種以上
の筒状部のうち、先端側の筒状部にて主体金具に全周溶
接されるとともに、後端側の筒状部の内部に防水シール
部材が配置され、更に隣合う筒状部の間に応力吸収部を
備えている。
According to the invention of claim 1, among the three or more types of tubular portions of the metal protective outer cylinder, the tubular portion on the front end side is welded all around to the metal shell and the tubular portion on the rear end side. A waterproof seal member is disposed inside the, and a stress absorbing portion is provided between the adjacent tubular portions.

【0017】従って、例えば飛石等により金属保護外筒
に横方向に外力が加わった場合でも、各応力吸収部で屈
曲することによりその外力の影響を緩和するので、金属
保護外筒の変形や破損などを最小限に抑えることが可能
である。例えば図1に示す様に、金属保護外筒のA部
(筒状部)に飛石が当たってA部が傾斜した場合でも、
そのA部の傾斜をB部(段差)によって吸収するため、
飛石による変形の程度を最小限に抑えて、例えばA部に
おけるシール部分の防水性を確保することが可能であ
る。また、C部(筒状部)に飛石が当たってC部が傾斜
する様な場合でも、B部及びD部(段差)がクッション
となって、同様に変形の程度を最小限に抑え、A部のシ
ール部分における防水性を確保することができるととも
に、例えば溶接部分への影響も緩和して、高い防水性を
保つことが可能である。
Therefore, even if an external force is applied to the metal protective outer cylinder in the lateral direction due to, for example, flying stones, the influence of the external force is relieved by bending at each stress absorbing portion, so that the metal protective outer cylinder is deformed or damaged. Etc. can be minimized. For example, as shown in FIG. 1, even when a stepping stone hits the A part (cylindrical part) of the metal protective outer cylinder and the A part is inclined,
Since the inclination of the A portion is absorbed by the B portion (step),
It is possible to minimize the degree of deformation due to stepping stones and to secure the waterproofness of the seal portion in the A portion, for example. Further, even when flying stones hit the C portion (cylindrical portion) and the C portion inclines, the B portion and the D portion (steps) serve as cushions, and similarly, the degree of deformation is minimized. It is possible to secure the waterproofness in the sealed portion of the portion, and also to mitigate the effect on the welded portion, for example, to maintain the high waterproofness.

【0018】請求項2の発明では、3種以上の筒状部の
径が異なるとともに、先端側の筒状部が最大径の筒状部
であり、且つ後端側の筒状部が最小径の筒状部であるの
で、金属保護外筒の径は、後端側にゆくほど細くなって
いる。つまり、固定側の筒状部が最大径で、伸びる先ほ
ど細くなる構造であるので、センサが安定して固定され
ることになる。
According to the second aspect of the present invention, the diameters of the three or more types of tubular portions are different, the tubular portion on the front end side is the tubular portion having the maximum diameter, and the tubular portion on the rear end side is the minimum diameter. Since it is a tubular portion, the diameter of the metal protective outer cylinder becomes smaller toward the rear end side. That is, since the cylindrical portion on the fixed side has the maximum diameter and becomes thinner as it extends, the sensor is stably fixed.

【0019】請求項3の発明では、応力吸収部として、
金属保護外筒の周方向に環状に形成された、段差、凹部
又は凸部のいずれかを採用することができる。請求項4
の発明では、金属保護外筒は、先端側にて主体金具に全
周溶接されるとともに、後端側の内部に防水シール部材
が配置され、更に金属保護外筒は、その周方向に環状に
形成された蛇腹状の応力吸収部を備えている。
In the invention of claim 3, as the stress absorbing portion,
Any of a step, a concave portion, or a convex portion formed in an annular shape in the circumferential direction of the metal protective outer cylinder can be adopted. Claim 4
In the invention, the metal protective outer cylinder is welded all around to the metal shell at the front end side, and the waterproof sealing member is arranged inside the rear end side. Further, the metal protective outer cylinder is annular in the circumferential direction. It has a formed bellows-shaped stress absorbing portion.

【0020】従って、前記請求項1の発明と同様に、例
えば飛石等により金属保護外筒に横方向に外力が加わっ
た場合でも、蛇腹状の応力吸収部で屈曲することにより
その外力の影響を緩和するので、金属保護外筒の変形や
破損などを最小限に抑えることが可能である。
Therefore, similarly to the first aspect of the invention, even when an external force is applied laterally to the metal protective outer cylinder by, for example, stepping stones or the like, it is bent by the bellows-shaped stress absorbing portion and the influence of the external force is exerted. Since it is relieved, it is possible to minimize the deformation and damage of the metal protective outer cylinder.

【0021】請求項5の発明では、金属保護外筒の厚さ
が0.3〜1mmの範囲であるので、例えば飛石等が金属
保護外筒に当たった場合には、前記段差等にて金属保護
外筒が適度に屈曲してクッションの役目を果たし、変形
の程度を最小限に抑えて、シール部分への悪影響を防止
することが可能である。
In the invention of claim 5, since the thickness of the metal protective outer cylinder is in the range of 0.3 to 1 mm, for example, when stepping stones or the like hit the metal protective outer cylinder, the metal is formed at the step or the like. It is possible to prevent the adverse effect on the seal portion by minimizing the degree of deformation by the protective outer cylinder bending appropriately and acting as a cushion.

【0022】[0022]

【実施例】以上説明した本発明の構成・作用を一層明ら
かにするために、以下本発明の好適な実施例について説
明する。尚、各図において上部及び下部は、センサの後
端側及び先端側を各々示す。 (実施例1)図2に示す様に、本実施例の酸素センサ1
は、酸素濃度を検出する素子として、起電力を検出する
タイプの、例えばジルコニア等の酸素イオン伝導性の固
体電解質からなる検出素子3を用いたものである。
Preferred embodiments of the present invention will be described below in order to further clarify the structure and operation of the present invention described above. In each figure, the upper and lower parts respectively indicate the rear end side and the front end side of the sensor. (Example 1) As shown in FIG. 2, the oxygen sensor 1 of this example
Uses an electromotive force detection type detection element 3 made of an oxygen ion conductive solid electrolyte such as zirconia as an element for detecting oxygen concentration.

【0023】この検出素子3は、一端(先端側)が閉塞
され且つ他端(後端側)が開口するとともに、その中央
外側に鍔部3aを有する筒状体であり、検出素子3の内
面側及び外面側には、例えば白金等からなる内面電極5
及び外面電極7が各々形成されている。また、これらの
電極5,7には、端子金具9(図では一方のみ示す)が
接続され、端子金具9には、外部に信号を取り出すリー
ド線13,14が接続されている。
The detection element 3 is a cylindrical body having one end (front end side) closed and the other end (rear end side) opened, and a flange 3a outside the center thereof. The inner surface electrode 5 made of, for example, platinum is provided on the side and the outer surface side.
And outer surface electrodes 7 are respectively formed. Further, a terminal fitting 9 (only one of which is shown in the figure) is connected to the electrodes 5 and 7, and lead wires 13 and 14 for extracting a signal to the outside are connected to the terminal fitting 9.

【0024】前記検出素子3の長い凹状の内部空間に
は、検出素子3を加熱するために、棒状のヒータ17が
挿入されており、このヒータ17の図示しない電極に接
続された端子金具10(図では一方のみ示す)にもリー
ド線15,16が接続されている。
A rod-shaped heater 17 is inserted in the long concave internal space of the detecting element 3 in order to heat the detecting element 3, and a terminal fitting 10 (which is connected to an electrode (not shown) of the heater 17 is connected. Lead wires 15 and 16 are also connected to (only one side is shown in the drawing).

【0025】この検出素子3は、セラミックス製の筒状
の保持部材21,タルク粉末25,セラミック製の筒状
押部材27等を介して、耐熱金属製の主体金具29内に
固定されている。つまり、検出素子3が主体金具29を
貫いて図の上下に伸びる様に、その軸中心を合わせて固
定されている。
The detecting element 3 is fixed in a metal shell 29 made of heat-resistant metal through a cylindrical holding member 21 made of ceramics, talc powder 25, a cylindrical pushing member 27 made of ceramics and the like. That is, the detection element 3 is fixed with its axial center aligned so that it extends through the metal shell 29 and extends vertically.

【0026】前記主体金具29の下部には、検出素子3
の先端側の周囲を覆う(開口部31aを有する)保護キ
ャップ31が装着されている。また、主体金具29の上
部(後端側)には、検出素子3及びヒータ17の周囲を
覆う様に、例えばステンレスからなる耐熱金属製の内筒
33が、例えば加締め等によって取り付けられている。
Below the metal shell 29, the detection element 3
A protective cap 31 (having an opening 31a) that covers the periphery of the tip side of the is attached. Further, on the upper portion (rear end side) of the metal shell 29, an inner cylinder 33 made of a heat-resistant metal made of, for example, stainless steel is attached by caulking or the like so as to cover the periphery of the detection element 3 and the heater 17. .

【0027】更に、内筒33の上部には、リード線13
〜16が貫通する略円柱状のセラミックセパレータ35
が配置されるとともに、セラミックセパレータ35の上
側には、(同様にリード線13〜16が貫通する)耐熱
性のグロメットゴムである防水シール部材37が配置さ
れている。尚、このセラミックセパレータ35の外周に
は段差35aがあり、この段差35aにて、内筒33の
(内側に曲げられた)上端が33aが係止している。
Further, the lead wire 13 is provided on the upper part of the inner cylinder 33.
To 16 through which a substantially cylindrical ceramic separator 35 penetrates
And a waterproof seal member 37, which is a heat-resistant grommet rubber (also through which the lead wires 13 to 16 penetrate), is arranged above the ceramic separator 35. There is a step 35a on the outer circumference of the ceramic separator 35, and the upper end (bent inward) 33a of the inner cylinder 33 is locked at the step 35a.

【0028】特に本実施例では、内筒33、セラミック
セパレータ35及び防止シール部材37の外側を覆う様
に、主体金具29の上部に外筒39が取り付けられてい
る。この外筒39は、厚さが1mm以下(例えば0.6m
m)であり、図の下側より、先端側の外径19mmの第1
筒状部39H1、第1筒状部39H1とほぼ45゜に曲げ
られた(主体金具29の鍔部29aの上端29a1から
の)軸方向高さ25mm・径方向段差幅1.5mmの第1段
差部39D1、中央側の外径16mmの第2筒状部39H
2、第2筒状部39H2とほぼ直角に曲げられた(同じく
鍔部29aの上端29a1からの)軸方向高さ45mm・
径方向段差幅1.5mmの第2段差部39D2、後端側の
外径12mmの第3筒状部39H3から構成されている。
Particularly, in this embodiment, an outer cylinder 39 is attached to the upper portion of the metal shell 29 so as to cover the inner cylinder 33, the ceramic separator 35 and the prevention seal member 37. This outer cylinder 39 has a thickness of 1 mm or less (for example, 0.6 m
m), and from the bottom of the figure, the first with an outer diameter of 19 mm on the tip side
Cylindrical portion 39H1 and first tubular portion 39H1 and first step with a height of 25 mm in the axial direction and a radial step width of 1.5 mm (from the upper end 29a1 of the collar portion 29a of the metallic shell 29) bent at approximately 45 ° Portion 39D1, second cylindrical portion 39H having an outer diameter of 16 mm on the central side
2, axial height 45 mm (also from the upper end 29a1 of the collar portion 29a) bent almost at right angles to the second tubular portion 39H2.
It comprises a second step portion 39D2 having a radial step width of 1.5 mm and a third tubular portion 39H3 having an outer diameter of 12 mm on the rear end side.

【0029】そして、外筒39は、最も径の大きな第1
筒状部39H1の下端側にて、主体金具29の上部29
bに外嵌するとともに、防水のために例えばレーザ溶接
にて全周溶接されている。また、最も径の小さな第3筒
状部39H3にて、径方向に例えば六角加締め、八角加
締め、丸加締め等の加締めが行われて、防水シール部材
37を押圧固定している。
The outer cylinder 39 is the first with the largest diameter.
At the lower end side of the tubular portion 39H1, the upper portion 29 of the metallic shell 29 is
It is externally fitted to b and is welded all around by, for example, laser welding for waterproofing. Further, the third cylindrical portion 39H3 having the smallest diameter is crimped in the radial direction, for example, hexagonal crimping, octagonal crimping, round crimping, etc., to press and fix the waterproof seal member 37.

【0030】この様に、本実施例では、外筒39の厚さ
が1mm以下で、2箇所に段差部39D1,39D2が設け
られ、更に各筒状部39H1〜H3の外径が異なる様に構
成されているので、仮に飛石等により外筒39に横方向
に外力が加わった場合でも、段差部39D1,39D2が
屈曲することによって、その外力の影響を緩和すること
ができる。つまり、このセンサ構造によって、外筒39
の変形を最小限に抑えて、防水シール部分に対する歪み
等を低減できるので、十分な防水性を確保することがで
きる。その結果、悪路等の過酷な環境であっても、セン
サの全使用期間を通じて良好に酸素濃度を検出すること
ができるという顕著な効果を奏する。
As described above, in this embodiment, the thickness of the outer cylinder 39 is 1 mm or less, the step portions 39D1 and 39D2 are provided at two positions, and the outer diameters of the cylindrical portions 39H1 to H3 are different. Since it is configured, even if an external force is applied to the outer cylinder 39 in the lateral direction by flying stones or the like, the stepped portions 39D1 and 39D2 are bent, so that the influence of the external force can be mitigated. That is, this sensor structure allows the outer cylinder 39
It is possible to minimize the deformation of the above and reduce the distortion or the like of the waterproof seal portion, so that it is possible to secure sufficient waterproofness. As a result, even in a harsh environment such as a bad road, there is a remarkable effect that the oxygen concentration can be satisfactorily detected during the entire usage period of the sensor.

【0031】また、酸素センサ1が、車両の触媒の下流
側に取り付けられた場合には、水没すると、熱応力によ
って外筒39自身が変形しようとするが、その場合で
も、段差部39D1,39D2が応力の緩衝となるので、
その変形が抑えられ、その点でも高い防水性を確保でき
るという利点がある。 (実施例2)次に、実施例2について説明するが、前記
実施例1と同様な部分の説明は、簡略化又は省略する。
Further, when the oxygen sensor 1 is mounted on the downstream side of the catalyst of the vehicle, when it is submerged in water, the outer cylinder 39 itself tends to deform due to thermal stress, but even in that case, the step portions 39D1 and 39D2 are also formed. As a buffer for stress,
There is an advantage that the deformation can be suppressed and high waterproofness can be secured also in that respect. (Embodiment 2) Next, Embodiment 2 will be described, but the description of the same parts as those in Embodiment 1 will be simplified or omitted.

【0032】図3に示す様に、本実施例の酸素センサ5
1は、酸素濃度を検出する素子として、抵抗の変化を検
出するタイプの、例えばチタニア等の金属酸化物からな
る感知物質を備えた検出素子53を用いたものである。
この検出素子53は、アルミナ等の基板53aの先端側
に、チタニア等の金属酸化物53bを配置した棒状体で
あり、金属酸化物53bには図示しない電極が接続され
ている。これらの電極には、端子金具55(図では一方
のみ示す)が接続され、端子金具55には、外部に信号
を取り出すリード線56,57が接続されている。ま
た、前記基板53aには、金属酸化物53bを加熱する
ために、図示しないヒータが形成されており、このヒー
タにも、端子金具60(図では一方のみ示す)を介し
て、リード線58,59が接続されている。
As shown in FIG. 3, the oxygen sensor 5 of the present embodiment.
1 uses a detection element 53 of a type that detects a change in resistance, which includes a sensing substance made of a metal oxide such as titania, as an element that detects oxygen concentration.
The detection element 53 is a rod-shaped body in which a metal oxide 53b such as titania is arranged on the tip side of a substrate 53a such as alumina, and an electrode (not shown) is connected to the metal oxide 53b. Terminal fittings 55 (only one is shown in the figure) are connected to these electrodes, and lead wires 56 and 57 for taking out signals to the outside are connected to the terminal fittings 55. Further, a heater (not shown) is formed on the substrate 53a to heat the metal oxide 53b, and a lead wire 58, 59 is connected.

【0033】前記検出素子53及び端子金具55,60
の一部は、鍔部61aを有するセラミックス製の筒状の
保持部材61内にて、ガラス63にてシールされて固定
されており、保持部材61は、滑石65を介して、耐熱
金属製の主体金具67内に固定されている。つまり、検
出素子53は、保持部材61に保持された状態で、主体
金具67を貫いて図の上下に伸びる様に、その軸中心を
合わせて固定されている。
The detection element 53 and the terminal fittings 55, 60
Is partially fixed by being sealed with glass 63 in a cylindrical holding member 61 made of ceramics having a flange portion 61a, and the holding member 61 is made of a heat resistant metal through a talc 65. It is fixed in the metallic shell 67. That is, the detection element 53, while being held by the holding member 61, is fixed so that its axial center is aligned so as to penetrate the metal shell 67 and extend vertically.

【0034】また、検出素子53の上方には、リード線
56〜59が貫通するセラミック製のセパレータ54と
耐熱性のグロメットゴムである防水シール部材71とが
配置されている。尚、前記主体金具67の下部には、検
出素子53の先端側の周囲を覆う(開口部69aを有す
る)保護キャップ69が装着されている。
A ceramic separator 54, through which the lead wires 56 to 59 penetrate, and a waterproof sealing member 71, which is a heat-resistant grommet rubber, are arranged above the detecting element 53. A protective cap 69 is attached to the lower portion of the metallic shell 67 to cover the periphery of the front end side of the detection element 53 (having an opening 69a).

【0035】特に本実施例では、保持部材61及びグ防
水シール部材71の外側を覆う様に、主体金具67の上
部に外筒73が取り付けられている。この外筒73は、
厚さが1mm以下(例えば0.5mm)であり、図の下側よ
り、先端側の外径20mmの第1筒状部73H1、第1筒
状部73H1とほぼ45゜に曲げられた(主体金具67
の鍔部67aの上端67a1からの)軸方向高さ15mm
・径方向段差幅1.5mmの第1段差部73D1、中央側
の外径17mmの第2筒状部73H2、第2筒状部73H2
とほぼ直角に曲げられた(同じく鍔部67aの上端67
a1からの)軸方向高さ40mm・径方向段差幅2.0mm
の第2段差部73D2、後端側の外径13mmの第3筒状
部73H3から構成されている。
Particularly in this embodiment, an outer cylinder 73 is attached to the upper part of the metal shell 67 so as to cover the outer sides of the holding member 61 and the waterproof seal member 71. This outer cylinder 73 is
The thickness is 1 mm or less (for example, 0.5 mm), and the first tubular portion 73H1 and the first tubular portion 73H1 having an outer diameter of 20 mm on the leading end side are bent at approximately 45 ° from the lower side of the figure (mainly Metal fittings 67
Axial height 15mm (from the upper end 67a1 of the collar 67a)
First radial step portion 73D1 having a radial step width of 1.5 mm, second tubular portion 73H2 having a central outer diameter of 17 mm, and second tubular portion 73H2
Is bent almost at a right angle (also the upper end 67 of the collar portion 67a).
Axial height 40 mm, radial step width 2.0 mm (from a1)
The second step portion 73D2 and the rear end side third cylindrical portion 73H3 having an outer diameter of 13 mm.

【0036】そして、外筒73は、最も径の大きな第1
筒状部73H1の下端側にて、主体金具67の上部の段
差67bに外嵌するとともに、防水のために全周溶接さ
れている。また、最も径の小さな第3筒状部73H3に
て、径方向に例えば六角加締め、八角加締め、丸加締め
等の加締めが行われて、防水シール部材71が押圧固定
されている。
The outer cylinder 73 is the first with the largest diameter.
At the lower end side of the tubular portion 73H1, it is fitted onto the step 67b above the metallic shell 67 and welded all around for waterproofing. Further, the third tubular portion 73H3 having the smallest diameter is crimped in the radial direction, for example, hexagonal crimping, octagonal crimping, round crimping, etc., and the waterproof seal member 71 is pressed and fixed.

【0037】この様に、本実施例では、外筒73の厚さ
が1mm以下で、2箇所に段差部73D1,73D2が設け
られ、更に各筒状部73H1〜H3の外径が異なる様に構
成されているので、前記実施例1と同様に、飛石等によ
り外筒73に横方向に外力が加わった場合でも、段差部
73D1,73D2が屈曲することによって、外筒73の
変形を最小限に抑えて、防水シール部分に対する歪み等
を低減し、十分な防水性を確保することができる。その
結果、センサの全使用期間を通じて良好に酸素濃度を検
出することができる。
As described above, in this embodiment, the thickness of the outer cylinder 73 is 1 mm or less, the step portions 73D1 and 73D2 are provided at two places, and the outer diameters of the cylindrical portions 73H1 to H3 are different. Since it is configured, as in the first embodiment, even when an external force is applied to the outer cylinder 73 in the lateral direction due to flying stones or the like, the stepped portions 73D1 and 73D2 are bent to minimize the deformation of the outer cylinder 73. It is possible to suppress the distortion and the like to the waterproof seal portion and secure sufficient waterproofness. As a result, the oxygen concentration can be satisfactorily detected over the entire usage period of the sensor.

【0038】特に本実施例では、内部空間が大きいの
で、より大きな外力に対する適応能力が高いという利点
がある。以上本発明の実施例について説明したが、本発
明はこうした実施例に何等限定されるものではなく、本
発明の要旨を逸脱しない範囲において、種々なる態様で
実施し得ることは勿論である。
Particularly in this embodiment, since the internal space is large, there is an advantage that the adaptability to a larger external force is high. Although the embodiments of the present invention have been described above, the present invention is not limited to these embodiments, and it is needless to say that the present invention can be implemented in various modes without departing from the scope of the present invention.

【0039】例えば、図4(a)に示す様に、防水シー
ル部材81の上部にまで外筒82が形成されているも
の、図4(b)に示す様に、先端側の筒状部83と後端
側の筒状部84とが同じ径のもの、図4(c)に示す様
に、防水シール部材86が配置された後端側の筒状部8
7より先端側の位置に小径の筒状部89が設けられたも
の、図4(d)に示す様に、多くの段差部90を用いた
もの、図4(e)〜(g)に示す様に、段差ではなく凹
状又は凸状の応力吸収部91,92,93としたもの等
にも適用できる。
For example, as shown in FIG. 4 (a), the outer cylinder 82 is formed up to the upper part of the waterproof seal member 81, and as shown in FIG. 4 (b), the tubular portion 83 on the tip side. And the tubular portion 84 on the rear end side have the same diameter, as shown in FIG. 4C, the tubular portion 8 on the rear end side on which the waterproof seal member 86 is arranged.
7 is provided with a small-diameter tubular portion 89 at a position closer to the tip end side, one using many stepped portions 90 as shown in FIG. 4 (d), and one shown in FIGS. 4 (e) to 4 (g). Similarly, the stress absorbing portions 91, 92, 93 having concave or convex shapes instead of the steps can be applied.

【0040】更に、図4(h)に示す様に、筒状部95
に蛇腹状の応力吸収部96を設けてもよい。つまり、上
述した実施例の様に、内部が空間になっている構造の場
合は、先端部の受熱は外筒からの伝熱が殆どなので、蛇
腹の様に伝熱パスを長くすることによって、グロメット
ゴムの受ける熱が減少し、結果として全長を短縮でき
る。
Further, as shown in FIG. 4 (h), the tubular portion 95
A bellows-shaped stress absorbing portion 96 may be provided in the. That is, in the case of a structure in which the inside is a space, as in the above-described embodiment, most of the heat received at the tip is from the outer cylinder, so by increasing the heat transfer path like a bellows, The heat received by the grommet rubber is reduced, resulting in a shorter overall length.

【0041】また、例えば前記実施例1,2における段
差部の角度は、筒状部に対して、テーパ状に、例えば3
0〜90゜の範囲で傾斜されればよく、より好ましくは
45゜以上である。更に、筒状部の側面は、軸方向に対
して平行でもよいが、テーパ状に多少傾斜していても差
し支えない。
Further, for example, the angle of the stepped portion in the first and second embodiments is, for example, 3 in a taper shape with respect to the tubular portion.
The angle may be in the range of 0 to 90 °, more preferably 45 ° or more. Further, the side surface of the tubular portion may be parallel to the axial direction, but may be slightly inclined in a taper shape.

【0042】また、例えば上述した酸素センサは、例え
ば車両の排気ガスを浄化する触媒の下流側に配置される
と、飛石等によって金属筒体が変形してもシール性が損
なわれず、その機能を発揮できるので好適であるが、そ
の位置に限定されるものではない。例えば、触媒の上流
等の車両の床下などに配置されても十分にその機能を発
揮できる。
Further, for example, when the oxygen sensor described above is arranged, for example, on the downstream side of a catalyst for purifying exhaust gas of a vehicle, the sealing performance is not impaired even if the metal cylinder is deformed by flying stones or the like, and its function is maintained. It is preferable because it can be exerted, but it is not limited to that position. For example, even if it is arranged under the floor of the vehicle, such as upstream of the catalyst, it can sufficiently exhibit its function.

【0043】[0043]

【発明の効果】以上詳述した様に、請求項1の発明で
は、金属保護外筒の3種以上の筒状部のうち、先端側の
筒状部にて主体金具に全周溶接されるとともに、後端側
の筒状部の内部に防水シール部材が配置され、更に隣合
う筒状部の間に応力吸収部を備えている。
As described in detail above, according to the invention of claim 1, of the three or more types of tubular portions of the metal protective outer tube, the tubular portion on the tip side is welded all around to the metal shell. At the same time, a waterproof seal member is arranged inside the tubular portion on the rear end side, and a stress absorbing portion is provided between adjacent tubular portions.

【0044】従って、例えば飛石等により金属保護外筒
に横方向に外力が加わった場合でも、各応力吸収部で屈
曲することによりその外力の影響を緩和するので、金属
保護外筒の変形を最小限に抑えて、十分な防水性を確保
することができる。その結果、センサの全使用期間を通
じて良好な防水性能を発揮し、測定精度の維持と向上を
達成することができるという顕著な効果を奏する。
Therefore, even if an external force is applied laterally to the metal protective outer cylinder due to, for example, flying stones, the influence of the external force is mitigated by bending at each stress absorbing portion, so that the deformation of the metal protective outer cylinder is minimized. It can be kept to the limit and sufficient waterproofness can be secured. As a result, there is a remarkable effect that good waterproof performance is exhibited throughout the entire period of use of the sensor, and the measurement accuracy can be maintained and improved.

【0045】また、センサが水没した場合には、金属保
護外筒は温度変化による熱膨張によって変形しようとす
るが、この応力吸収部によって熱膨張を吸収することが
できるので、センサの全体の変形が抑制され、よって、
防水シール部分のシール性が損なわれることを防ぐこと
ができるという利点がある。
Further, when the sensor is submerged in water, the metal protective outer cylinder tends to be deformed by thermal expansion due to temperature change. However, since the stress absorbing section can absorb the thermal expansion, the entire deformation of the sensor. Is suppressed, thus
There is an advantage that it is possible to prevent the sealing property of the waterproof sealing portion from being impaired.

【0046】請求項2の発明では、3種以上の筒状部の
径が異なるとともに、先端側の筒状部が最大径の筒状部
であり、且つ後端側の筒状部が最小径の筒状部であるの
で、金属保護外筒の径は後端側にゆくほど細くなり、セ
ンサが安定して固定されるという効果がある。
According to the second aspect of the present invention, the diameters of the three or more tubular portions are different, the tubular portion on the front end side is the tubular portion with the maximum diameter, and the tubular portion on the rear end side is the minimum diameter. Since it is the tubular portion, the diameter of the metal protective outer cylinder becomes smaller toward the rear end side, and there is an effect that the sensor is stably fixed.

【0047】請求項3の発明では、応力吸収部として、
金属保護外筒の周方向に環状に形成された、段差、凹部
又は凸部のいずれかを採用することができる。請求項4
の発明では、金属保護外筒は、先端側にて主体金具に全
周溶接されるとともに、後端側の内部に防水シール部材
が配置され、更に金属保護外筒は、その周方向に環状に
形成された蛇腹状の応力吸収部を備えている。
In the invention of claim 3, as the stress absorbing portion,
Any of a step, a concave portion, or a convex portion formed in an annular shape in the circumferential direction of the metal protective outer cylinder can be adopted. Claim 4
In the invention, the metal protective outer cylinder is welded all around to the metal shell at the front end side, and the waterproof sealing member is arranged inside the rear end side. Further, the metal protective outer cylinder is annular in the circumferential direction. It has a formed bellows-shaped stress absorbing portion.

【0048】従って、前記請求項1の発明と同様に、例
えば飛石等により金属保護外筒に横方向に外力が加わっ
た場合でも、蛇腹状の応力吸収部で屈曲することによ
り、金属保護外筒の変形や破損などを最小限に抑えるこ
とができる。請求項5の発明では、金属保護外筒の厚さ
が前記所定の範囲であるので、横方向の外力を受けた場
合でも、筒状部がそれほど変形することなく、段差等に
て金属保護外筒が適度に屈曲してクッションの役目を果
たし、シール部分への悪影響を防止することができる。
Therefore, as in the first aspect of the present invention, even when an external force is applied to the metal protective outer cylinder in the lateral direction by, for example, flying stones, the metal protective outer cylinder is bent by bending at the bellows-shaped stress absorbing portion. It is possible to minimize deformation and damage of the. In the invention of claim 5, since the thickness of the metal protective outer cylinder is within the predetermined range, the tubular portion is not deformed so much even when an external force in the lateral direction is received, and the metal protective outer cylinder is not deformed at a step or the like. It is possible to prevent the adverse effect on the seal portion by bending the cylinder appropriately and acting as a cushion.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明の酸素センサ構造の作用を示す説明図
である。
FIG. 1 is an explanatory view showing the operation of the oxygen sensor structure of the present invention.

【図2】 実施例1の酸素センサを一部判断して示す説
明図である。
FIG. 2 is an explanatory diagram showing a partial judgment of the oxygen sensor of the first embodiment.

【図3】 実施例2の酸素センサを一部判断して示す説
明図である。
FIG. 3 is an explanatory view showing a partial judgment of an oxygen sensor according to a second embodiment.

【図4】 その他の実施例を示す説明図である。FIG. 4 is an explanatory diagram showing another embodiment.

【符号の説明】[Explanation of symbols]

1,51…酸素センサ 3,53…検出素子 13,14,15,16,56,57,58,59…リ
ード線 29,67…主体金具 33…内筒 37,71,81,86…防水シール部材 39,73,82…外筒 39H1,39H2,39H3,73H1,73H2,73
H3,83,84,87,39D1,39D2,73D1,
73D2,90…段差部 89,95…筒状部 91,92,93,96…応力吸収部
1, 51 ... Oxygen sensor 3, 53 ... Detection element 13, 14, 15, 16, 56, 57, 58, 59 ... Lead wire 29, 67 ... Metal shell 33 ... Inner cylinder 37, 71, 81, 86 ... Waterproof seal Member 39, 73, 82 ... Outer cylinder 39H1, 39H2, 39H3, 73H1, 73H2, 73
H3, 83, 84, 87, 39D1, 39D2, 73D1,
73D2, 90 ... Step portion 89, 95 ... Cylindrical portion 91, 92, 93, 96 ... Stress absorbing portion

───────────────────────────────────────────────────── フロントページの続き (72)発明者 小島 孝夫 愛知県名古屋市瑞穂区高辻町14番18号 日 本特殊陶業株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Takao Kojima 14-18 Takatsuji-cho, Mizuho-ku, Nagoya-shi, Aichi Nihon Special Ceramics Co., Ltd.

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 先端側が測定対象に向けられる酸素セン
サ自身を取付部位に取り付ける主体金具と、該主体金具
の後端側に取り付けられた金属保護外筒と、を備えた酸
素センサ構造において、 前記金属保護外筒が、軸方向における配置位置が異なる
3種以上の筒状部を備えるとともに、先端側の筒状部に
て前記主体金具に全周溶接され、且つ中央側の筒状部よ
り後端側の筒状部の内部に防水シール部材が配置され、
更に、隣合う前記筒状部同士を接続する構成として2箇
所以上の応力吸収部を備えたことを特徴とする酸素セン
サ構造。
1. An oxygen sensor structure comprising: a metal shell for mounting an oxygen sensor itself, the front end of which is directed toward an object to be measured, at a mounting portion; and a metal protective outer cylinder mounted on a rear end side of the metal shell, The metal protective outer cylinder is provided with three or more kinds of tubular parts having different axial arrangement positions, and is welded all around to the metal shell at the distal end tubular part, and is located behind the central tubular part. A waterproof seal member is arranged inside the end-side tubular portion,
Further, the oxygen sensor structure is characterized in that it is provided with two or more stress absorbing parts as a structure for connecting the adjacent cylindrical parts.
【請求項2】 前記3種以上の筒状部の径が異なり、前
記先端側の筒状部が最大径の筒状部であり、前記後端側
の筒状部が最小径の筒状部であることを特徴とする前記
請求項1記載の酸素センサ構造。
2. The three or more types of tubular portions have different diameters, the tip-side tubular portion is the tubular portion having the largest diameter, and the tubular portion on the rear end side is the tubular portion having the minimum diameter. The oxygen sensor structure according to claim 1, wherein:
【請求項3】 前記応力吸収部が、前記金属保護外筒の
周方向に環状に形成された、段差、凹部又は凸部のいず
れかであることを特徴とする前記請求項1又は2記載の
酸素センサ構造。
3. The step according to claim 1 or 2, wherein the stress absorbing portion is any one of a step, a concave portion and a convex portion formed in an annular shape in the circumferential direction of the metal protective outer cylinder. Oxygen sensor structure.
【請求項4】 先端側が測定対象に向けられる酸素セン
サ自身を取付部位に取り付ける主体金具と、該主体金具
の後端側に取り付けられた金属保護外筒と、を備えた酸
素センサ構造において、 前記金属保護外筒は、先端側にて前記主体金具に全周溶
接されるとともに、後端側の内部に防水シール部材が配
置され、更に前記金属保護外筒は、その周方向に環状に
形成された蛇腹状の応力吸収部を備えたことを特徴とす
る酸素センサ構造。
4. An oxygen sensor structure comprising: a metal shell for mounting an oxygen sensor itself, the tip side of which is directed to an object to be measured, at a mounting site; and a metal protective outer cylinder mounted on a rear end side of the metal shell, The metal protective outer cylinder is welded to the metal shell all around the front end side, and a waterproof seal member is arranged inside the rear end side. Further, the metal protective outer cylinder is formed annularly in the circumferential direction. An oxygen sensor structure having a bellows-shaped stress absorbing portion.
【請求項5】 前記金属保護外筒の厚さが0.3〜1mm
の範囲であることを特徴とする前記請求項1〜4のいず
れか記載の酸素センサ構造。
5. The thickness of the metal protective outer cylinder is 0.3 to 1 mm.
The oxygen sensor structure according to any one of claims 1 to 4, wherein the oxygen sensor structure is in a range of.
JP30517894A 1994-12-08 1994-12-08 Oxygen sensor structure Expired - Lifetime JP3369766B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30517894A JP3369766B2 (en) 1994-12-08 1994-12-08 Oxygen sensor structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30517894A JP3369766B2 (en) 1994-12-08 1994-12-08 Oxygen sensor structure

Publications (2)

Publication Number Publication Date
JPH08160002A true JPH08160002A (en) 1996-06-21
JP3369766B2 JP3369766B2 (en) 2003-01-20

Family

ID=17942000

Family Applications (1)

Application Number Title Priority Date Filing Date
JP30517894A Expired - Lifetime JP3369766B2 (en) 1994-12-08 1994-12-08 Oxygen sensor structure

Country Status (1)

Country Link
JP (1) JP3369766B2 (en)

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US6319378B1 (en) 1998-08-12 2001-11-20 Denso Corporation Gas sensor having improved structure
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JP2014146022A (en) * 2013-01-04 2014-08-14 Artience Lab Inc Illumination apparatus, and image recording medium

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