JPH08151240A - Production of warm-colored artificial stone - Google Patents
Production of warm-colored artificial stoneInfo
- Publication number
- JPH08151240A JPH08151240A JP6319161A JP31916194A JPH08151240A JP H08151240 A JPH08151240 A JP H08151240A JP 6319161 A JP6319161 A JP 6319161A JP 31916194 A JP31916194 A JP 31916194A JP H08151240 A JPH08151240 A JP H08151240A
- Authority
- JP
- Japan
- Prior art keywords
- warm
- artificial stone
- colored
- blast furnace
- cao
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002969 artificial stone Substances 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000000292 calcium oxide Substances 0.000 claims abstract description 22
- 235000012255 calcium oxide Nutrition 0.000 claims abstract description 22
- 238000001816 cooling Methods 0.000 claims abstract description 21
- 238000002844 melting Methods 0.000 claims abstract description 21
- 230000008018 melting Effects 0.000 claims abstract description 21
- 239000002893 slag Substances 0.000 claims abstract description 20
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000010433 feldspar Substances 0.000 claims abstract description 14
- 230000001590 oxidative effect Effects 0.000 claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 9
- 239000003086 colorant Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims description 22
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 15
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 12
- 238000002156 mixing Methods 0.000 abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910018404 Al2 O3 Inorganic materials 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 238000010586 diagram Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 4
- 229910000423 chromium oxide Inorganic materials 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 239000011651 chromium Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000004566 building material Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B5/00—Treatment of metallurgical slag ; Artificial stone from molten metallurgical slag
- C04B5/06—Ingredients, other than water, added to the molten slag or to the granulating medium or before remelting; Treatment with gases or gas generating compounds, e.g. to obtain porous slag
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、高炉スラグを主たる原
料として用い、風呂のタイルや、壁面材および床材等の
建築材料に利用される暖色系に着色された暖色系人造石
の製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention uses a blast furnace slag as a main raw material, and a method for producing a warm color artificial stone colored in a warm color used for building materials such as bath tiles, wall materials and floor materials. It is about.
【０００２】[0002]
【従来の技術】高炉スラグは、鉄鋼製造の副産物であ
り、原料コストが安く、大量に発生するので安定供給が
可能である等の利点を有しており、その活用が図られて
いる。ところが、建築材料のような用途に用いる着色岩
石を高炉スラグから製造する際には、第１に寒色または
暖色の所望の着色が施せること、第２に結晶質岩石で見
た目に潤い（光沢）を与える石質であること、第３に製
造コストおよび原料コストが極力安価であることが求め
られる。Blast furnace slag is a by-product of steel production, and has advantages such as low raw material cost and stable production because it is produced in large quantities. However, when manufacturing colored rocks used for applications such as building materials from blast furnace slag, first, it is possible to give a desired color of cold color or warm color, and secondly, it is moistened (glossy) with crystalline rock. It is required that the stone quality be given, and thirdly that the manufacturing cost and the raw material cost be as low as possible.
【０００３】ところが、高炉スラグを主原料として単に
溶融固化しただけでは、黒色の固化物が生成され、着色
材を添加しても黒色に邪魔されて所望の色が得られない
という現象が生じる。そこで、高炉スラグを主原料とし
て所望の色の人造石を製造できるように、従来から種々
の試みが成されており、近年においては、長石、アルミ
ナ、および酸化クロムを高炉スラグに添加および混合
し、酸化雰囲気が確保された旋回溶融炉で溶融すること
によって、暖色系人造石を製造できることが確認されて
いる。However, if the blast furnace slag is simply melted and solidified as a main raw material, a black solidified product is produced, and even if a coloring material is added, the black color hinders a desired color from being obtained. Therefore, various attempts have been made in the past so that artificial stones of a desired color can be produced using blast furnace slag as a main raw material.In recent years, feldspar, alumina, and chromium oxide have been added to and mixed with blast furnace slag. It has been confirmed that a warm-colored artificial stone can be manufactured by melting in a swirling melting furnace in which an oxidizing atmosphere is secured.
【０００４】具体的には、高炉スラグ２０重量部、長石
４５重量部、アルミナ３５重量部、酸化クロム０．３重
量部からなる混合物を酸化雰囲気下の旋回溶融炉で溶融
したり、高炉スラグ４０重量部、長石２０重量部、アル
ミナ４０重量部、酸化クロム０．３重量部からなる混合
物を酸化雰囲気下の旋回溶融炉で溶融することによっ
て、暖色系人造石を製造できることが確認されている。Specifically, a mixture of 20 parts by weight of blast furnace slag, 45 parts by weight of feldspar, 35 parts by weight of alumina, and 0.3 parts by weight of chromium oxide is melted in a swirling melting furnace in an oxidizing atmosphere, or blast furnace slag 40 is used. It has been confirmed that a warm color artificial stone can be produced by melting a mixture of 20 parts by weight of feldspar, 40 parts by weight of alumina, and 0.3 parts by weight of chromium oxide in a swirling melting furnace under an oxidizing atmosphere.
【０００５】[0005]
【発明が解決しようとする課題】しかしながら、上記従
来の暖色系人造石の製造方法では、高炉スラグに対する
長石およびアルミナの添加量により暖色系人造石が得ら
れなかったり、ガラス化していることがあり、良質の暖
色系人造石を安定して得ることができないという問題が
ある。However, in the above-mentioned conventional method for producing a warm-colored artificial stone, the warm-colored artificial stone may not be obtained or vitrified due to the addition amount of feldspar and alumina to the blast furnace slag. However, there is a problem that high quality warm color artificial stone cannot be obtained stably.
【０００６】従って、本発明においては、良質の暖色系
人造石を安定して得ることができる暖色系人造石の製造
方法を提供することを目的としている。Therefore, it is an object of the present invention to provide a method for producing a warm-colored artificial stone capable of stably obtaining a high-quality warm-colored artificial stone.
【０００７】[0007]
【課題を解決するための手段】上記目的を解決するため
に、高炉スラグに、長石および生石灰のうちの一種以上
とアルミナとを添加すると共に、暖色系着色剤を添加し
て原料とし、該原料を溶融した後に冷却する暖色系人造
石の製造方法であって、下記の特徴を有している。In order to solve the above-mentioned object, one or more of feldspar and quicklime and alumina are added to a blast furnace slag, and a warm colorant is added as a raw material. A method for producing a warm-colored artificial stone, which comprises cooling after melting, and has the following features.
【０００８】即ち、暖色系人造石の製造方法は、上記原
料のＳｉＯ2 、ＣａＯおよびＡｌ2Ｏ3 の化学組成が、
図１のＡ、Ｂ、ＣおよびＤで囲まれた範囲内であり、上
記溶融が、酸化条件下で行われ、上記冷却が、１１００
〜９００℃間を２０℃／ｍｉｎ以下の冷却速度とするこ
とを特徴としている。That is, in the method for producing a warm color artificial stone, the chemical composition of the above-mentioned raw materials SiO 2 , CaO and Al 2 O 3 is
In the range surrounded by A, B, C and D in FIG. 1, the melting is performed under oxidizing conditions and the cooling is 1100.
It is characterized in that a cooling rate of 20 ° C./min or less is set between −900 ° C.
【０００９】[0009]
【作用】上記の構成において、高炉スラグは、Ｓｉ
Ｏ2 、ＣａＯ、Ａｌ2 Ｏ3 等を含有しており、この３成
分で全成分中の９０重量％を占めている。また、長石
は、ＳｉＯ2 を主成分とし、生石灰は、ＣａＯを主成分
としている。そして、これらの長石および生石灰は、原
料中の塩基度（ＣａＯ／ＳｉＯ2 ）を調整することによ
って、暖色系人造石に艶を付与するようになっている。
また、アルミナ（Ａｌ2Ｏ3 ）と酸化クロム（Ｃｒ2 Ｏ
3 ）は、暖色系を発色させるためのものである。暖色系
着色剤の添加量により、暖色系人造石の着色の濃淡を変
化させることができ、酸化クロム（Ｃｒ2 Ｏ3 ）を暖色
系着色剤として使用した場合には、α−Ａｌ2 Ｏ3 の一
部がＣｒと置換することによりピンクやワインレッドに
発色することになる。In the above structure, the blast furnace slag is made of Si.
It contains O 2 , CaO, Al 2 O 3, etc., and these three components account for 90% by weight of all components. Further, feldspar has SiO 2 as a main component, and quick lime has CaO as a main component. These feldspars and quicklime are designed to give luster to warm-colored artificial stones by adjusting the basicity (CaO / SiO 2 ) in the raw materials.
In addition, alumina (Al 2 O 3 ) and chromium oxide (Cr 2 O 3
3 ) is for developing a warm color system. The tint of coloring of the warm-colored artificial stone can be changed by the addition amount of the warm-colored colorant, and when chromium oxide (Cr 2 O 3 ) is used as the warm-colored colorant, α-Al 2 O 3 By substituting a part of Cr with Cr, a color develops pink or wine red.
【００１０】また、上記の原料を酸化条件下で溶融する
理由は、以下の通りである。高炉スラグは、上述のＳｉ
Ｏ2 、ＣａＯ、Ａｌ2 Ｏ3 の３成分の他、微量成分とし
て、ＭｇＯ、ＭｎＯ、ＴｉＯ2 、Ｆｅ2 Ｏ3 、ＳＯ3 等
を含有している。ＳＯ3 は、約１重量％含まれており、
大部分または一部が硫黄（Ｓ）として存在している。こ
の硫黄は、暖色系着色剤として添加された金属酸化物
や、高炉スラグ中に含まれる金属酸化物と反応して黒色
系の硫化物を形成したり、良好な発色に有効な金属酸化
物を消費させるため、目的とする暖色系人造石の製造を
阻害することになる。そこで、硫黄が空気中で容易に燃
焼して二酸化硫黄になることに着目し、原料を直接的に
空気雰囲気（酸化条件）下で加熱・溶融させることによ
って、硫黄を二酸化硫黄として除去するためである。The reason for melting the above raw materials under oxidizing conditions is as follows. Blast furnace slag is the above-mentioned Si
In addition to the three components of O 2 , CaO and Al 2 O 3 , MgO, MnO, TiO 2 , Fe 2 O 3 , SO 3 and the like are contained as minor components. SO 3 is contained in about 1% by weight,
Most or part is present as sulfur (S). This sulfur reacts with a metal oxide added as a warm colorant or a metal oxide contained in the blast furnace slag to form a black sulfide, or a metal oxide effective for good color development. Since it is consumed, it hinders the production of the target warm-colored artificial stone. Therefore, paying attention to the fact that sulfur easily burns in the air to become sulfur dioxide, in order to remove sulfur as sulfur dioxide by directly heating and melting the raw material in the air atmosphere (oxidizing condition). is there.
【００１１】尚、空気雰囲気（酸化条件）下での加熱・
溶融には、化石燃料またはプラズマ火炎の吹き付け、或
いは電磁波照射により原料を加熱溶融させ、加熱と同時
に溶融部分に十分な空気を供給する方法が採用されてい
ても良いし、加熱溶融している原料に旋回力を付与しな
がら火炎で硫黄成分を燃焼させる方法が採用されていて
も良い。Heating under an air atmosphere (oxidizing conditions)
For melting, a method of blowing fossil fuel or plasma flame, or heating and melting the raw material by irradiation of electromagnetic waves, and supplying sufficient air to the melting portion at the same time as heating may be adopted. A method of burning a sulfur component with a flame while imparting a turning force to the above may be adopted.
【００１２】また、１１００〜９００℃間を２０℃／ｍ
ｉｎ以下（好ましくは１５℃／ｍｉｎ以下）の冷却速度
で冷却する理由は、１１００〜９００℃間を２０℃／ｍ
ｉｎを越える冷却速度で冷却すると、α−Ａｌ2 Ｏ3 の
結晶が析出しにくくガラス化するからである。Further, between 1100 and 900 ° C., 20 ° C./m
The reason for cooling at a cooling rate of in or less (preferably 15 ° C / min or less) is 20 ° C / m between 1100 and 900 ° C.
This is because when cooled at a cooling rate exceeding in, crystals of α-Al 2 O 3 are hard to precipitate and vitrify.
【００１３】[0013]
【実施例】表１は、表中の高炉スラグ、長石、生石灰、
およびアルミナを実施例１・２、比較例１・２の配合割
合で混合して原料を作成し、旋回溶融炉を用いて酸化条
件下で溶融した後、１１００〜９００℃間を２０℃／ｍ
ｉｎ以下の冷却速度で冷却して得られた暖色系人造石の
色調および石質を示したものである。この結果、実施例
１・２の配合割合によれば、ワインレッドの色調で結晶
質の暖色系人造石が得られることが判明し、比較例１・
２の配合割合によれば、グリーンの色調でガラス質の人
造石が得られることが判明した。EXAMPLES Table 1 shows blast furnace slag, feldspar, quicklime,
Alumina and alumina were mixed at the compounding ratios of Example 1.2 and Comparative Example 1.2 to prepare a raw material, and the raw material was melted under an oxidizing condition using a swirling melting furnace, and then a temperature of 1100 to 900 ° C. was 20 ° C./m.
It shows the color tone and stone quality of warm-colored artificial stone obtained by cooling at a cooling rate of in or less. As a result, according to the blending ratio of Examples 1 and 2, it was found that a crystalline warm-colored artificial stone having a wine red color tone was obtained, and Comparative Example 1
It was found that a vitreous artificial stone with a green color tone was obtained according to the mixing ratio of 2.
【００１４】[0014]
【表１】 [Table 1]
【００１５】表２および表３は、表中の高炉スラグ、長
石、およびアルミナを実施例３〜１７、比較例３〜５の
配合割合で混合して原料を作成し、旋回溶融炉を用いて
酸化条件下で溶融した後、１１００〜９００℃間を２０
℃／ｍｉｎ以下の冷却速度で冷却して得られた暖色系人
造石の色調および石質を示したものである。この結果、
実施例３〜１４・１７の配合割合によれば、ワインレッ
ドの色調で結晶質の暖色系人造石が得られることが判明
し、実施例１５・１６の配合割合によれば、ピンクの色
調で結晶質の暖色系人造石が得られることが判明し、比
較例３〜５の配合割合によれば、グリーンまたはベージ
ュの色調でガラス質の人造石が得られることが判明し
た。In Tables 2 and 3, the blast furnace slag, feldspar, and alumina in the tables are mixed at the compounding ratios of Examples 3 to 17 and Comparative Examples 3 to 5 to prepare raw materials, which are then used in a swirling melting furnace. After melting under oxidizing conditions, the temperature between 1100 and 900 ° C is 20
It shows the color tone and stone quality of warm-colored artificial stone obtained by cooling at a cooling rate of ° C / min or less. As a result,
According to the blending ratios of Examples 3 to 14 and 17, it was found that a crystalline warm-colored artificial stone having a wine red color tone was obtained, and according to the blending ratios of Examples 15 and 16, a pink tone was obtained. It was found that a crystalline warm-colored artificial stone was obtained, and it was found that, according to the blending ratios of Comparative Examples 3 to 5, a glassy artificial stone with a green or beige color tone was obtained.
【００１６】[0016]
【表２】 [Table 2]
【００１７】[0017]
【表３】 [Table 3]
【００１８】表４は、表中の高炉スラグ、長石、および
アルミナを上述の実施例８・１３にそれぞれ対応する比
較例６・７の配合割合で混合して原料を作成し、旋回溶
融炉を用いて酸化条件下で溶融した後、１１００〜９０
０℃間を３０℃／ｍｉｎ以下の冷却速度で冷却して得ら
れた暖色系人造石の色調および石質を示したものであ
る。この結果、比較例６・７の冷却速度によれば、グリ
ーンの色調でガラス質の人造石が得られることが判明し
た。Table 4 shows that the blast furnace slag, feldspar, and alumina in the table are mixed in the mixing ratios of Comparative Examples 6 and 7 corresponding to the above Examples 8 and 13 to prepare raw materials, and the swirling melting furnace is prepared. After melting under oxidizing conditions using 1100-90
Fig. 3 shows the color tone and stone quality of a warm-colored artificial stone obtained by cooling 0 ° C at a cooling rate of 30 ° C / min or less. As a result, according to the cooling rates of Comparative Examples 6 and 7, it was revealed that a vitreous artificial stone with a green color tone was obtained.
【００１９】[0019]
【表４】 [Table 4]
【００２０】次に、表１〜３に示すように、実施例１〜
１７および比較例１〜５の配合割合からＳｉＯ2 とＣａ
ＯとＡｌ2 Ｏ3 との化学組成を求め、図１に示すよう
に、ガラス質を“●”、ワインレッドの結晶質を
“○”、ピンクの結晶質を“□”として対応する点にプ
ロットした。この結果、Ａ（ＳｉＯ2 ６０％、ＣａＯ０
％、Ａｌ2 Ｏ3 ４０％）、Ｂ（ＳｉＯ2 ３４％、ＣａＯ
２６％、Ａｌ2 Ｏ3 ４０％）、Ｃ（ＳｉＯ2 １３％、Ｃ
ａＯ２６％、Ａｌ2 Ｏ3 ６１％）、Ｄ（ＳｉＯ2 １３
％、ＣａＯ０％、Ａｌ2 Ｏ3 ８７％）で囲まれる範囲内
のＳｉＯ2 ・ＣａＯ・Ａｌ2 Ｏ3 となるように、高炉ス
ラグに長石および生石灰の一種以上とアルミナとを添加
すると共に、暖色系着色剤を添加して原料とした後、酸
化条件下で溶融し、１１００〜９００℃間を２０℃／ｍ
ｉｎ以下の冷却速度で冷却することによって、良質の暖
色系人造石を安定して得ることができることが明らかに
なった。Next, as shown in Tables 1 to 3, Examples 1 to 1
17 and SiO 2 and Ca from the mixing ratios of Comparative Examples 1 to 5.
The chemical composition of O and Al 2 O 3 was determined, and as shown in FIG. 1, the glassy substance was designated as “●”, the wine red crystalline substance as “○”, and the pink crystalline substance as “□”. Plotted. As a result, A (SiO 2 60%, CaO 0
%, Al 2 O 3 40%), B (SiO 2 34%, CaO
26%, Al 2 O 3 40%), C (SiO 2 13%, C
aO 26%, Al 2 O 3 61%), D (SiO 2 13
%, CaO 0%, Al 2 O 3 87%) added to the blast furnace slag with one or more of feldspar and quick lime and alumina so that the SiO 2 · CaO · Al 2 O 3 is within a range surrounded by warm color. After adding a colorant as a raw material and melting it under oxidizing conditions, the temperature between 1100 and 900 ° C is 20 ° C / m.
It has been clarified that a good quality warm-colored artificial stone can be stably obtained by cooling at a cooling rate of in or less.
【００２１】[0021]
【発明の効果】本発明は、以上のように、高炉スラグ
に、長石および生石灰のうちの一種以上とアルミナとを
添加すると共に、暖色系着色剤を添加して原料とし、該
原料を溶融した後に冷却するものであって、上記原料の
ＳｉＯ2 、ＣａＯおよびＡｌ2 Ｏ3 の化学組成が、図１
のＡ、Ｂ、ＣおよびＤで囲まれた範囲内であり、上記溶
融が、酸化条件下で行われ、上記冷却が、１１００〜９
００℃間を２０℃／ｍｉｎ以下の冷却速度とする構成で
あるから、良質の暖色系人造石を安定して得ることがで
きるという効果を奏する。As described above, according to the present invention, one or more of feldspar and quicklime and alumina are added to blast furnace slag, and a warm colorant is added as a raw material, and the raw material is melted. After cooling, the chemical composition of SiO 2 , CaO and Al 2 O 3 of the above raw materials is
Within the range surrounded by A, B, C and D, the melting is performed under oxidizing conditions, and the cooling is 1100 to 9
Since the cooling rate is set to 20 ° C./min or less between 00 ° C., a high quality warm color artificial stone can be stably obtained.
【図１】ＳｉＯ2 、ＣａＯおよびＡｌ2 Ｏ3 の化学組成
の関係を示すグラフである。FIG. 1 is a graph showing the relationship between the chemical compositions of SiO 2 , CaO and Al 2 O 3 .
Claims (1)
の一種以上とアルミナとを添加すると共に、暖色系着色
剤を添加して原料とし、該原料を溶融した後に冷却する
暖色系人造石の製造方法であって、 上記原料のＳｉＯ2 、ＣａＯおよびＡｌ2 Ｏ3 の化学組
成が、図１のＡ、Ｂ、ＣおよびＤで囲まれた範囲内であ
り、 上記溶融が、酸化条件下で行われ、 上記冷却が、１１００〜９００℃間を２０℃／ｍｉｎ以
下の冷却速度とすることを特徴とする暖色系人造石の製
造方法。1. Production of a warm-colored artificial stone in which one or more of feldspar and quicklime and alumina are added to a blast furnace slag and a warm-colored colorant is added as a raw material, and the raw material is melted and then cooled. The chemical composition of SiO 2 , CaO and Al 2 O 3 as the raw materials is within the range surrounded by A, B, C and D in FIG. 1, and the melting is performed under oxidizing conditions. The method for producing a warm-colored artificial stone, wherein the cooling is performed at a cooling rate of 20 ° C / min or less between 1100 and 900 ° C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6319161A JPH08151240A (en) | 1994-11-28 | 1994-11-28 | Production of warm-colored artificial stone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6319161A JPH08151240A (en) | 1994-11-28 | 1994-11-28 | Production of warm-colored artificial stone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08151240A true JPH08151240A (en) | 1996-06-11 |
Family
ID=18107119
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6319161A Pending JPH08151240A (en) | 1994-11-28 | 1994-11-28 | Production of warm-colored artificial stone |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08151240A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030046064A (en) * | 2001-12-04 | 2003-06-12 | 이성문 | Building materials and bricks, sidewalk blocks, tiles, textures, soil bioboards (soil boards) using industrial wastes and limestone and spurs. |
| KR102117863B1 (en) * | 2019-11-29 | 2020-06-03 | 해원엠에스씨(주) | Marble panel comprising slag and stone powder and manufacturing method thereof |
-
1994
- 1994-11-28 JP JP6319161A patent/JPH08151240A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030046064A (en) * | 2001-12-04 | 2003-06-12 | 이성문 | Building materials and bricks, sidewalk blocks, tiles, textures, soil bioboards (soil boards) using industrial wastes and limestone and spurs. |
| KR102117863B1 (en) * | 2019-11-29 | 2020-06-03 | 해원엠에스씨(주) | Marble panel comprising slag and stone powder and manufacturing method thereof |
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