JPH08110606A - Silver halide photographic sensitive material and development processing method therefor - Google Patents

Abstract

PURPOSE: To provide the silver halide photographic sensitive material ensuring sufficient high contrast in a photomechanical process, superior in sharpness and reversal character quality and resistant to occurrence of residual dye stains and black spots and superior on storage stability and freed of decoloration by manual operation in a light room handling and the like and to provide its rapid processing method. CONSTITUTION: The silver halide photographic sensitive material having at least one silver halide contains at least one kind of compound represented by the formula in the emulsion layer and/or its adjacent layer and a dye dispersed in a solid state having an absorption maximum in a wavelength region of 300-500nm in a nonphotosensitive layer formed on the outside of the emulsion layer from the support. In the formula, R1 is an H atom or an optionally substituted alkyl or alkoxy group; R2 is an optionally substituted alkyl or acyl or acylamino group; X is an anion; and y is 1 or 2 and, when y is 1, an intramolecular salt is formed.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a silver halide photographic light-sensitive material, and more specifically, it has a sufficient film-hardening property in photolithography, is excellent in the quality of sharpness and clear characters, and has a residual color, storage with time,
The present invention relates to a silver halide photographic light-sensitive material which can be returned in a bright room without discoloration and a low replenishment rapid processing method thereof.

[0002]

2. Description of the Related Art In silver halide photographic light-sensitive materials,
It is well known to incorporate a dye in a constituent layer of a light-sensitive material in order to absorb light having a specific wavelength for the purpose of light absorption filter, prevention of halation, or adjustment of sensitivity of the light-sensitive material.

For example, in a printing plate making process, a light-sensitive material used in a returning process under a bright room (hereinafter referred to as a bright room returning sensitive material) uses the above dye for the purpose of sensitivity adjustment. Here, since the usual silver halide emulsion is water-based coating, the dye used is also usually water-soluble. Therefore, it has become clear in recent years that even if a dye is selectively added to a specific layer, the dye diffuses to other layers immediately after coating, which deteriorates the blank character width in the bright-room return sensitive material. For this reason, a method of adding a dye dispersed in a microcrystalline state has been developed as a means of incorporating a non-diffusible dye into a light-sensitive material. A new problem has arisen that the residual color is deteriorated.

When the above-mentioned non-diffusible dye is added to the antihalation layer, a high contrast image excellent in photographic performance can be obtained, but there is a problem that the residual color is similarly deteriorated.

Further, the water-soluble dye causes color fading during handling during plate making, and is a particularly important problem in light-reversed light-sensitive materials, which require many manual steps. When the degree of hardening is increased in order to prevent the color fading of the dye for the purpose of preventing this, deterioration of the storage stability over time due to the transfer of the hardening agent occurs in addition to the above-mentioned deterioration of the residual color.

On the other hand, in the silver halide photographic light-sensitive material for photolithography, a lithographic silver halide photographic light-sensitive material is well known in the art because it requires a photographic image having an extremely high contrast. Since the concentration cannot be increased, it has a drawback that it is unstable to air oxidation. Therefore, there is a demand for an image forming system which eliminates the instability of the image forming method by the above developing method (lith development system) and develops with a developer having good storage stability to obtain super-high contrast photographic characteristics. , U.S. Patent 4,166,
742, 4,168,977, 4,221,857, 4,224,401
No. 4,243,739, No. 4,272,606, No. 4,311,781, the surface latent image type silver halide photographic light-sensitive material added with a specific hydrazine compound has a pH of 11.0 to 12.3.
A system has been proposed which has a good storage stability in a developer containing 0.15 mol / liter or more of a sulfite preservative and forms a super-high contrast negative image having a gamma (γ) of more than 10.

However, in this new image forming system, due to the remarkable nucleation action of the hydrazine compound, the nucleation action extends to the non-exposed portion around the exposed portion, and the image is substantially enlarged to reproduce a faithful image. There was a drawback that I could not. Therefore, particularly stringent quality is required such as enlargement (expansion), reduction (expansion) quality of halftone pictures in line drawing process, reproducibility of bright-colored images, quality of blank characters in return process, or scanner output in color separation process. In the field, there is an insufficient point in image quality.

Further, in this new image forming system,
Since the pH of the developer is high, it is easily affected by air oxidation, and the storability of the developer was not sufficient. Therefore, a highly active hydrazine compound that gives a high contrast even in a developer having a pH of about 10.5 is disclosed in US Pat. Nos. 167,814, 4,988,604, and 4,994,346.
It is disclosed in JP-A-63-234244 and 63-249838. Such an image forming system has the advantages that it is not easily affected by air oxidation and has excellent storage stability for the developer, and that carbonate buffer can be used instead of phosphate buffer, which has a large impact on the environment, but it has the drawback of black spots. have.

When processing is performed using an automatic processor,
Conventionally, it usually took 90 seconds or more for the entire process,
In recent years, it has been desired to shorten the developing time in order to increase the number of printing points and the working time.

Accelerating the development process means shortening the development and fixing time, which leads to deterioration of residual color. Accordingly, a silver halide photographic light-sensitive material and a rapid processing method thereof which have high contrast and sharpness in photoengraving, excellent quality of clear characters, no residual color, black spots, no color loss due to manual work in a bright room, and excellent storability over time are provided. Was wanted.

[0011]

SUMMARY OF THE INVENTION The object of the present invention is to ensure sufficient contrast in photoengraving, to provide excellent sharpness and quality of clear characters, and to be free from residual color and black spots and excellent in storage stability over time.
It is an object of the present invention to provide a silver halide photographic light-sensitive material which is free from discoloration by a manual operation such as in a bright room and a rapid processing method thereof.

[0012]

In a silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer on one side on a support, the following general formula is contained in the emulsion layer and / or the adjacent layer. Formula [1]
A halogen containing a support and a non-photosensitive layer in which a dye having an absorption maximum at 300 to 500 nm is dispersed in a solid state is provided outside the emulsion layer with respect to a support. Silver halide photographic light-sensitive material.

[0013]

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In the formula, R ₁ represents a hydrogen atom or an optionally substituted alkyl group or alkoxy group, and R ₂ represents an optionally substituted alkyl group, an acyl group or an acylamino group. X represents an anion, y is 1 or 2, and when y is 1, it forms an inner salt.

In the general formula [1], R ₂ is an alkylenesulfonic acid or an acylamino group, wherein the silver halide photographic light-sensitive material is described.

In the general formula [1], R ₂ is-
(−CH ₂ −) _m −SO ₃ ⁻ , −NR ₃ COR4, − (− CH ₂ −) p−CONR
₇ R ₈ ,-(-CH _2- ) q-NR ₉ R ₁₀ ,-(CH _2- ) s-CH- (LR ₁₂ )
Represents -R ₁₁ , R ₃ represents a hydrogen atom or an alkyl group which may have a substituent, R ₄ represents an alkyl group which may have a substituent, an alkoxyl group, -O-(-CH _2- ) n−SO ₃ ⁻ , −NR _{5
R 6, - (- CH 2} -) n-SO 3 - represents, R _5, R ₆ is an alkyl group which may have a hydrogen atom or a _{substituent, - (- CH 2 -)} n-SO
₃ ^- represents, R ₇ represents a hydrogen atom, or an optionally substituted alkyl group or an aryl group, R ₈ is a hydrogen atom, or an alkyl group, or R ₇ may have a substituent 5 Member or a group forming a 6-membered aliphatic ring, R ₉ represents a hydrogen atom, an optionally substituted alkyl group or —COR ₄ ,
₁₀ is a hydrogen atom or an optionally substituted alkyl group, or _{- (- CH 2 -) r} -SO 3 - represents, L is represents -O- or -NR _13, R ₁₁ is a hydrogen atom or a substituent Represents an alkyl group which may have a group, R ₁₂ represents a hydrogen atom or an alkyl group which may have a substituent, —COR ₁₄ , —CONHR ₁₅ , R ₁₃ , R ₁₄ , R
₁₅ represents a hydrogen atom or an alkyl group which may have a substituent, m is 0 or 2 to 4, n is 1 to 3, p is 0 to 2, q and r are 1 to 3, and s is 2 3. The silver halide photographic light-sensitive material as described in 3, wherein

[0017], R ₁ in the general formula (1) is a hydrogen atom or an optionally substituted alkyl group or an alkoxy group, R ₂ is _{- (- CH 2 -) m} -SO 3 - or NR _The silver halide photographic light-sensitive material as described above, which is ₃ COR ₄ .

The silver halide photographic light-sensitive material as described above, wherein the silver halide emulsion comprises silver chloride grains or silver chlorobromide grains having a silver chloride content of 80 mol% or more.

The silver halide photographic light-sensitive material as described above, wherein the silver halide emulsion layer and / or the hydrophilic colloid layer contains at least one hydrazine compound.

The silver halide photographic light-sensitive material described in
A method for developing a silver halide photographic light-sensitive material, which comprises developing with a developer having a pH of 9.0 to 0.7.

In the method of developing a silver halide photographic light-sensitive material as described in 1, the processing of the silver halide photographic light-sensitive material is characterized in that the developing solution is replenished with a replenishing amount of 300 ml or less per 1 m ^{2 of the} light-sensitive material. Method.

In the method of processing a silver halide photographic light-sensitive material described above, the total processing time (Dry to Dry) of the step of processing with an automatic processor is 60 seconds or less, and the silver halide photographic light-sensitive material is characterized. Processing method.

10. In a silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer on one side of a support, the emulsion layer and / or the adjacent layer is represented by the above-mentioned general formula [1]. A silver halide photographic light-sensitive material comprising a colloid layer containing at least one of the compounds shown and containing a solid-dispersed dye between the silver halide emulsion layer and a support. 11. The silver halide photographic light-sensitive material according to 10, wherein the silver halide emulsion layer and / or the hydrophilic colloid layer contains at least one hydrazine compound. The silver halide photographic light-sensitive material described in 12 and 11 is adjusted to pH 9.0 to 10.7.
The method for developing a silver halide photographic light-sensitive material, which comprises developing with a developing solution of 1.

In the method of developing a silver halide photographic light-sensitive material described in 13 or 12, the developing solution is replenished in an amount of 300 ml or less per 1 m ^{2 of the} light-sensitive material. Processing method.

In the method of processing a silver halide photographic light-sensitive material described in 14 or 13, the total processing time (Dry to Dry) of the step of processing with an automatic developing machine is 60 seconds or less, the silver halide photographic Method of processing photosensitive material.

15. At least one hydrophilic colloid layer having at least one silver halide emulsion layer on one side of the support and no silver halide emulsion layer on the other side of the support.
In the silver halide photographic light-sensitive material having a layer, the hydrophilic colloid layer not containing the silver halide emulsion layer contains one of the compounds represented by the above general formula [1] and a solid dispersed dye. Silver halide photographic light-sensitive material.

The silver halide photographic light-sensitive material described in 16 and 15
A method for developing a silver halide photographic light-sensitive material, which comprises developing with a developer having a pH of 9.0 to 0.7.

In the method for developing a silver halide photographic light-sensitive material described in 17, 16, the silver halide photographic light-sensitive material is characterized in that the developing solution is replenished in an amount of 300 ml or less per 1 m ^{2 of the} light-sensitive material. Processing method.

In the method for processing a silver halide photographic light-sensitive material described in 18, 17, the total processing time (Dry to Dry) of the step of processing with an automatic developing machine is 60 seconds or less. It consists of the processing method of the light-sensitive material.

The compounds represented by the general formula [1] used in the present invention are exemplified below, but the present invention is not limited thereto.

[0031]

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[0032]

[Chemical 4]

[0033]

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[0034]

[Chemical 6]

These compounds can be easily synthesized by the methods described in the literature. For example, “Chem.Ber. Volume 40 1831
Page (1907) "and J. Phya. Chem. 68: 3149".

The synthetic examples of these compounds are shown below.

Synthesis of Exemplified Compound (4) 10 g of 4-aminopyridine in acetonitrile (150 ml) was heated to 60 ° C., 15 g of chloroacetyl chloride in acetonitrile (40 ml) was added dropwise, and then heated to 90 ° C. under reflux.
It was stirred for 12 hours. After cooling to room temperature, the precipitated crystals were collected by filtration and dried to obtain 41.5 g of 4-chloroacetamidopyridine.

4-chloroacetamidopyridine 2 obtained in an aqueous solution of 26 g of sodium sulfite (dissolved in 900 ml by heating)
1.5 g of an aqueous solution (200 ml) was added dropwise, and the mixture was stirred at 75 ° C for 12 hours. Then, 10 ml of concentrated hydrochloric acid was added, and the mixture was stirred at room temperature for 1 hour, and the precipitated crystals were collected by filtration, washed with water and dried to obtain 20 g of 4-sulfoacetamidopyridine.

Obtained 4-sulfoacetamidopyridine 20
g and tripropylamine (15 g) were dissolved in an acetonitrile solution (heat dissolved in 50 ml), 20 g of pyrrolidinocarbonyl chloride was added dropwise, and the mixture was stirred at 75 ° C. for 12 hours. The precipitated crystals were collected by filtration and dried to obtain 14 g of the hardener (4). The chemical structure was confirmed by various spectra and elemental analysis.

Synthesis of Exemplified Compound (5) 20 g of 4-pyridineethanesulfonic acid and tripropylamine (17 g) were dissolved in 60 ml of acetonitrile, 16 g of pyrrolidinocarbonyl chloride was added dropwise, and the mixture was stirred at room temperature for 12 hours. The precipitated crystals are collected by filtration and dried to give a hardening agent (5) 25.5 g.
I got The chemical structure was confirmed by various spectra and elemental analysis.

These compounds are dissolved in water or a hydrophilic solvent such as methanol or ethanol and then added to the coating solution of the silver halide photographic light-sensitive material of the present invention. The compound of the above formula [1] of the present invention may be used in combination with other known hardeners, and specific examples of known hardeners that can be used in combination include aldehyde type compounds such as formalin, glyoxal and succinaldehyde. Compound, Japanese Patent Publication No.47-6151
No. 3, for example, acid-releasing triazine compounds such as 2-hydroxy-4,6-dichloro-1,3,5-triazine sodium,
Alternatively, vinyl sulfone type compounds may be mentioned.

The silver halide emulsion layer and / or the adjacent layer of the present invention means a silver halide emulsion layer and / or a layer coated adjacently thereto, and examples thereof include an intermediate layer, a filter layer, an antistatic layer and a development control layer. Layer, subbing layer, antihalation layer,
It means a hydrophilic colloid layer such as a sensitivity adjusting layer and a protective layer.
For example, a silver halide photographic light-sensitive material constituent layer containing gelatin or the like is a preferred embodiment, and the amount of gelatin used in these layers is not uniform depending on the compound or the type of coating solution. The dry weight is preferably 0.01 to 2.0 millimoles per gram, more preferably 0.0
A range of 3 to 1.0 mmol is preferred.

The dye having an absorption maximum in the range of 300 to 500 nm in the present invention is, for example, JP-A-63-282738 or JP-A-5-197.
The dyes described in Nos. 078, 4-19642, and 5-53240 are solid disperse dyes, and the dye is added to a hydrophilic colloid as a solid fine particle dispersion. That is, at least one of the dyes is added in the form of a solid fine particle dispersion which is substantially water-insoluble and is dispersed in an aqueous system. More preferably, it is preferably dispersed in an aqueous system substantially free of an organic solvent and / or a surfactant. The state of the solid fine particle dispersion which is substantially insoluble in water is water containing impurities below a level that does not adversely affect the silver halide photographic emulsion in an aqueous system in which an organic solvent and / or a surfactant is not present. More preferably, it means a state of being dispersed in ion-exchanged water or distilled water.

Examples of these solid disperse dyes are shown below, but the present invention is not limited to these exemplified compounds.

[0045]

[Chemical 7]

[0046]

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The addition amount of these solid fine particle dyes is 10 mg to 1000 mg, and more preferably 30 mg to 500 mg, per square meter of the light-sensitive material. When the solid disperse dye-containing hydrophilic colloid layer, for example, a gelatin layer is provided outside the emulsion layer of the silver halide photographic light-sensitive material, the gelatin coating amount is 1.5 per square meter of the light-sensitive material.
g or less, preferably 0.2 to 1.2 g.

When used in the antihalation layer or backing layer, the amount of the solid fine particle dye added is 5 mg to 1000 mg, and preferably 10 mg to 500 mg, per square meter of the light-sensitive material. The gelatin coating amount is 1.5 g or less per square meter of the light-sensitive material, more preferably 0.2 to 1.2 g.

The hydrazine derivative and the nucleation accelerator which are added to the silver halide emulsion layer and / or the adjacent layer of the present invention will be described. The hydrazine compound used is a compound represented by the following general formula [H].

[0050]

[Chemical 9]

[0051]

[Chemical 10]

In the formula, A represents an aryl group or a heterocyclic group containing at least one sulfur atom or oxygen atom, and n represents an integer of 1 or 2. When n = 1, R ₁ and R ₂ are each a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group, Alternatively, it represents a heterocyclic oxy group, and R ₁ and R ₂ may form a ring together with a nitrogen atom. When n = 2, R ₁
And R ₂ are each a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a saturated or unsaturated heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group, or a heterocyclic oxy group. Represents a group. However, when n = 2, at least one of R ₁ and R ₂ is an alkenyl group, an alkynyl group, a saturated heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group, or a heterocyclic oxy group. Shall represent a group. Further, the groups represented above may be substituted.

R ₃ represents an alkynyl group or a saturated heterocyclic group. The compound represented by the general formula [A] or [B] includes a compound in which at least one H of —NHNH— in the formula is substituted with a substituent.

More specifically, A is an aryl group (eg, phenyl, naphthyl, etc.) or a heterocyclic group containing at least one sulfur atom or oxygen atom (eg, thiophene, furan, benzothiophene, pyran, etc.). Represent

R ₁ and R ₂ are each a hydrogen atom, an alkyl group (eg, methyl, ethyl, methoxyethyl, cyanoethyl, hydroxyethyl, benzyl, trifluoroethyl, etc.), an alkenyl group (eg, allyl, butenyl,
Pentenyl, pentadienyl, etc.), alkynyl group (eg, propargyl, butynyl, pentynyl, etc.), aryl group (eg, phenyl, naphthyl, cyanophenyl,
Methoxyphenyl, etc.), heterocyclic groups (eg, pyridine,
Unsaturated heterocyclic groups such as thiophene and furan and saturated heterocyclic groups such as tetrahydrofuran and sulfolane), hydroxy groups, alkoxy groups (eg, methoxy, ethoxy,
Benzyloxy, cyanomethoxy etc.), alkenyloxy group (eg allyloxy, butenyloxy etc.), alkynyloxy group (eg propargyloxy, butynyloxy etc.), aryloxy group (eg phenoxy, naphthyloxy etc.) or heterocyclic oxy Represents a group (eg, pyridyloxy, pyrimidyloxy, etc.), n
When = 1, R ₁ and R ₂ together with the nitrogen atom may form a ring (eg, piperidine, piperazine, morpholine, etc.). These above groups may be substituted.

However, when n = 2, at least one of R ₁ and R ₂ is an alkenyl group, an alkynyl group, a saturated heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group or a hetero group. It represents a ring oxy group, and these groups may be substituted.

Specific examples of the alkynyl group and saturated heterocyclic group represented by R ₃ include those mentioned above.

Various substituents can be introduced into the aryl group represented by A or the heterocyclic group having at least one sulfur atom or oxygen atom. Examples of the substituent that can be introduced include a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an acyloxy group, an alkylthio group, an arylthio group, a sulfonyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a carbamoyl group, and a sulfamoyl group, Acyl group, amino group, alkylamino group, arylamino group, acylamino group, sulfonamide group, arylaminothiocarbonylamino group,
Examples thereof include a hydroxy group, a carboxy group, a sulfo group, a nitro group and a cyano group. Of these substituents, the sulfonamide group is preferred.

In each general formula, A preferably contains at least one diffusion resistant group or silver halide adsorption promoting group. As the anti-diffusion group, a ballast group commonly used in non-moving photographic additives such as couplers is preferable. The ballast group is a group having a carbon number of 8 or more and relatively inert to photographic properties, and is selected from, for example, an alkyl group, an alkoxy group, a phenyl group, an alkylphenyl group, a phenoxy group and an alkylphenoxy group. You can

Examples of the silver halide adsorption promoting group include groups described in US Pat. No. 4,385,108 such as thiourea group, thiourethane group, heterocyclic thioamide group, mercapto heterocyclic group and triazole group.

H of --NHNH-- in the general formulas [A] and [B], that is, the hydrogen atom of hydrazine, is a sulfonyl group (eg, methanesulfonyl, toluenesulfonyl, etc.), an acyl group (eg, acetyl, trifluoroacetyl, It may be substituted with a substituent such as ethoxycarbonyl) and an oxalyl group (eg, ethoxalyl, pyruvoyl, etc.), and the compounds represented by the general formulas [A] and [B] include such compounds.

More preferred compounds in the present invention are the compounds of the general formula [A] when n = 2, and the compounds of the general formula [B]
Is a compound of.

In the compound of the general formula [A] with n = 2,
R ₁ and R ₂ are a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a saturated or unsaturated heterocyclic group, a hydroxy group, or an alkoxy group, and R ₁ and R ₂
At least one of them is an alkenyl group, an alkynyl group,
Compounds representing a saturated heterocyclic group, a hydroxy group, or an alkoxy group are more preferable.

Typical compounds represented by the above general formulas [A] and [B] are shown below. However, as a matter of course, the specific compounds of the general formulas [A] and [B] that can be used in the present invention are not limited to these compounds.

Specific compound examples

[0066]

[Chemical 11]

[0067]

[Chemical 12]

[0068]

[Chemical 13]

Examples of the nucleation accelerator used in the present invention include amine compounds, hydrazine compounds, quaternary onium salt compounds and carbinol compounds, with amine compounds and carbinol compounds being preferred. These nucleation accelerators are disclosed in JP-A-4-56749, JP-A-63-124045, and JP-A-63-124045.
-187340 gazette is mentioned. These compounds preferably have a diffusion resistance or a silver halide adsorption group in the molecule. Other specific examples include the compounds described in the following patents. JP-A-5-134339,
The compounds described in JP-A-5-134337, JP-A-5-127286 and JP-A-5-232616.

More specifically, the following nucleation accelerators are listed, but the present invention is not limited thereto.

As compounds described in JP-A-4-56949

[0072]

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[0073]

[Chemical 15]

[0074]

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[0075]

[Chemical 17]

The silver halide grains used in the present invention have a composition of silver chloride or silver chlorobromide having a silver chloride content of 80 mol% or more, preferably 90 mol% or more.

In the present invention, a monodisperse emulsion is preferred. As a preferable monodisperse silver halide grain in a monodisperse emulsion, the weight of silver halide contained within a grain size range of ± 20% around the average grain size r is 60% of the total weight of silver halide grains. % Or more, particularly preferably 70% or more, further preferably 80% or more.

The emulsion of the present invention has a monodispersity degree defined by (standard deviation of grain size / average grain diameter) × 100 = monodispersity degree of 20% or less, and more preferably 15% or less.

The silver halide emulsion of the present invention is prepared according to the
Group VIII or Group VI metal ions can be used during silver halide preparation. Preferred is an iridium ion or a rhodium ion. Any conventionally known water-soluble iridium salt can be used as the iridium ion, and desirable iridium salts are iridium (III) chloride IrCl ₃ and iridium (IV) chloride IrC.
l ₄ , potassium hexachloroiridium (IV) K ₂ IrC
l ₆ , ammonium hexachlororhodium (III) (NH) ₃
IrCl ₆ etc.

As the water-soluble rhodium compound for supplying rhodium ions, sodium hexachlororhodium (III) Na ₃ RhCl ₆ , potassium hexabromorhodium (III) K ₃ RhCl ₆ , rhodium chloride ammine complex, rhodium chloride (III) RhCl ₃ , 4H ₂ O, etc.

The amount of the water-soluble iridium compound added is preferably 10 ^-8 to 10 ^-5 mol per mol of silver halide. The amount of the water-soluble rhodium salt added is 10 ⁻¹⁰ to 10 ⁻³ mol, and more preferably 10 ⁻⁹ to 1 per mol of silver halide.
It is 0 ^-4 mol. The time of addition of these is preferably during the formation of silver halide grains or before physical ripening. As an addition method, it may be added alone in a liquid phase in which silver halide grains are formed, or may be mixed in advance in an addition liquid necessary for grain formation.

The emulsion used in the light-sensitive material of the present invention can be produced by a known method. For example, Research Disclosure (RD) No.17643 (December 1978), pages 22-23, 1
-Emulsion Preparation and Types, and (RD) No. 18716 (November 1979) -The method described on page 648 can be used.

In addition, “The theory of the ph” by TH James
otographic process ”4th edition, published by Macmillan (1977
Pp. 38-104, GF Daufin, "Photographic Emulsion Chemistry", Focal p.
Published by ress (1966), P. Glafkides "Physics and Chemistry of Photography""Chimie et physique photographique" Paul Mon
Published by tel (1967), VL Zelikman et al. "Making and Coating photographic Emul"
It is prepared by the method described in “sion” Focal press, Inc. (1964).

That is, the mixing conditions such as the forward mixing method, the reverse mixing method, the double jet method and the controlled double jet method under the solution conditions such as the neutral method, the acidic method and the ammonia method, the conversion method, the core / shell method. It can be produced using the particle preparation conditions such as and the like and a combination method thereof.

The silver halide photographic emulsion is spectrally sensitized with a known spectral sensitizing dye. The dyes used include cyanine dyes, merocyanine dyes, complex cyanine dyes, complex merocyanine dyes, holopolar cyanine dyes, hemicyanine dyes, styryl dyes and hemioxonol dyes. Particularly useful dyes are those belonging to the cyanine dyes, merocyanine dyes and complex merocyanine dyes.

Gelatin is advantageously used as the binder of the silver halide emulsion, but other hydrophilic colloids can also be used. For example gelatin derivatives,
Graft polymers of gelatin and other polymers, proteins such as albumin and casein, and cellulose derivatives such as hydroxyethyl cellulose, carboxymethyl cellulose, and cellulose sulfates can be used. The dry (Dry) film thickness of the main image forming layer is preferably thin, and is preferably 0.5 μm or less.

The emulsion may be subjected to a water washing method such as a noodle water washing method or a flocculation sedimentation method in order to remove soluble salts. A preferred washing method is, for example, Japanese Patent Publication Sho
A method using an aromatic hydrocarbon aldehyde resin containing a sulfo group described in JP-A No. 35-16086, or a method using aggregating polymer agents such as G-3 and G-8 described in JP-A-2-7037 is particularly preferable. As a desalting method.

In the emulsion according to the present invention, various photographic additives can be used in addition to the above additives in the steps before and after physical ripening or chemical ripening. Known additives include
For example, RD No.17643 (December 1978), No.18716 (1979)
November) and No. 308119 (December 1989). The types of compounds and the places where they are described in these three Research Disclosures are listed below.

Additive RD-17643 RD-18716 RD-308119 Page Classification Page Classification Page Classification Chemical sensitizer 23 III 648 Upper right 996 III Sensitizing dye 23 IV 648-649 996-8 IVA Desensitizing dye 23 IV 998 IVB Dye 25-26 VIII 649-650 1003 VIII Development accelerator 29 XXI 648 Upper right fog inhibitor / stabilizer 24 IV 649 Upper right 1006-7 VI Whitening agent 24 V 998 V Surfactant 26-7 XI 650 Right 1005-6 XI Antistatic agent 27 XII 650 Right 1006 to 7 XIII Plasticizer 27 XII 650 Right 1006 XII Sliding agent 27 XII Matting agent 28 XVI 650 Right 1008 to 9 XVI Binder 26 XXII 1003 to 4 IX Support 28 XVII 1009 XVII According to the present invention Examples of the support that can be used in the light-sensitive material include the above-mentioned RD-17643, page 28 and RD-308119, 100.
Examples include those described on page 9. A suitable support is polyethylene terephthalate film,
In order to improve the adhesion of the coating layer on the surface of these supports, an undercoat layer may be provided, corona discharge, ultraviolet irradiation or the like may be applied.

The silver halide photographic light-sensitive material of the present invention is processed using the developer described in Japanese Patent Application No. 6-83218. The pH of the developer to be processed is preferably 9.0 to 10.7, more preferably 9.8 to 10.7, and further preferably 10 to 107.

Further, the silver halide photographic light-sensitive material of the present invention is preferably processed by using an automatic developing machine. During development, a constant amount of developing solution is replenished in proportion to the processing area of the light-sensitive material. While being processed. The replenishment rate is less than 300 ml per square meter to reduce the amount of waste liquid. It is preferably 300 to 100 ml.

The silver halide photographic light-sensitive material of the present invention is rapidly processed with a total processing time (Dry to Dry) of 60 seconds. Here, the total processing time (Dry to Dry) means the time from when the leading edge of the film to be processed is inserted into the automatic processor until it comes out through the drying zone, and the total processing time of the present invention is 20 to 60. Seconds are preferred, and more preferably total processing time is 30
~ 60 seconds. If it is less than 20 seconds, desensitization and softening will be great and satisfactory photographic performance cannot be obtained. The total processing time referred to here means the total process time required for processing steps such as development, fixing, washing, stabilizing, and drying.

[0093]

EXAMPLES Examples of the present invention will be described below.
However, as a matter of course, the present invention is not limited to the embodiments described below.

Example 1 (Preparation of Silver Halide Emulsion) Ammonium hexachlororhodium (III) was added to silver 1 at the time of mixing using the double-sided mixing method.
After adding 8 × 10 ^-5 mol per mol and desalting by a conventional method, monodisperse (variation coefficient 10%) silver chloroiodobromide (98 mol% silver chloride, the rest is silver bromide) having an average particle size of 0.13 μm An emulsion of cubic grains was obtained.

4-hydroxy-6-methyl-1, was added to the resulting emulsion.
Add 3,3a, 7-tetrazaindene, potassium potassium bromide and citric acid, and add 3 × 10 ^-6 mol of inorganic sulfur per mol of silver, and perform chemical ripening at a temperature of 60 ° C until high sensitivity is obtained. went. After the ripening, 3 × 10 ⁻⁴ mol of 4-hydroxy-6-methyl-1,3,3a, 7-tetrazaindene and 1-phenyl-5-mercaptotetrazole and gelatin were added.

(Preparation of silver halide photographic light-sensitive material) On one undercoat layer of a polyethylene terephthalate film having a thickness of 100 μm and subjected to the antistatic treatment described in Example 1 of JP-A-3-92175, the following formulation ( The silver halide emulsion layer of 1) was coated so that the amount of silver was 2.8 g / m ² and the amount of gelatin was 1.0 g / m ^2, and a gelatin intermediate layer of the following formulation (2) was coated on it with a gelatin amount of 0.5. the coating is in g / m ^2, the amount of gelatin coating solution having the following composition (3) in the upper layer as a protective layer were simultaneously multi-layer coating so as to 0.5 g / m ² more. Also,
On the undercoat layer on the opposite side, a backing layer of the following formula (4) was applied so that the amount of gelatin would be 0.4 g / m ^2, and a polymer layer of the following formula (5) was further formed thereon. The backing protective layer of the following prescription (6) has a gelatin content of 0.4 g.
A sample was obtained by simultaneous multi-layer coating so that the surface area became / m ² .

Formulation 1 (Silver Halide Emulsion Layer Composition) Gelatin 1.0 g / m ² Hydrazine derivative according to the present invention Amount shown in Table 1 Nucleation accelerator (23) 30 mg / m ² Sodium dodecylbenzenesulfonate 10 mg / m ² 5-Methylbenzotriazole 10 mg / m ² compound (m) 6 mg / m ² latex polymer (f) 1.0 mg / m ² Dye according to the present invention Amount shown in Table 1 Sodium-iso-amyl-n-decyl sulphosuccinate 0.7 mg / m ² Styrene-maleic acid copolymer hydrophilic polymer (thickener) 20 mg / m ² Formulation 2 (gelatin intermediate layer composition) Gelatin 0.5 mg / m ² Styrene-maleic acid copolymer hydrophilic polymer (Thickener) 10 mg / m ² Sodium-iso-amyl-n-decylsulfosuccinate 0.4 mg / m ² Formulation 3 (emulsion protective layer composition) Gelatin 0.5 mg / m ² Dye according to the present invention Quantity Sodium-iso-amyl-n-decylsulfosuccinate 1 2 mg / m ² matting agent: monodisperse silica with an average particle size of 3 μm 15 mg / m ² matting agent: monodisperse silica with an average particle size of 8 μm 20 mg / m ² 1,3-vinylsulfonyl-2-propanol 50 mg / m ² surfactant Agent (h) 1 g / m ² colloidal silica (average particle size 0.005 μm) 20 mg
/ Amount of hardener in Table 1 wherein m ² invention formulation 4 (Backing layer composition) Gelatin 0.4 mg / m ² Sodium -iso- amyl -n- decyl sulfosuccinate 5 mg / m ² latex polymer (f) 0.3 mg / m ² Colloidal silica (average particle size 0.05 μm) 70 mg / m ² Styrene-maleic acid copolymer hydrophilic polymer (thickener) 20 mg / m ² Compound (i) 100 mg / m ² Formulation 5 (polymer layer Composition) Latex (n) [styrene: butadiene: acrylic acid = 30: 66: 5] 1.0 mg / m ² glyoxal 10 mg / m ² Formulation 6 (backing protective layer) Gelatin 0.4 mg / m ² Matting agent: average particle size 5 μm Monodispersed polymethylmethacrylate 50 mg / m ² Sodium-iso-amyl-n-decylsulfosuccinate 10 mg / m ² Surfactant (h) 1 mg / m ² H- (OCH ₂ CH ₂ ) ₆₈ -OH 50 mg / m ² glyoxal 40 mg / m ² Samples 1-1 to 1-10 were prepared by the above method. Also,
In the preparation of silver chlorobromide emulsion, the mol% of silver chloride is 98 to 50
Create a sample that differs only in the place where it is reduced to 1-11-1
It was set to -12. Further, when the samples 1-8 and 1-10 were processed, the different samples were designated as 1-13 and 1-14 only when the pH of the developing solution was changed from 10.4 to 11.7.

[0098]

Embedded image

The surface resistivity of the backing side after coating and drying was 1 × 10 ¹¹ at 23 ° C. and 20% RH. The sample obtained was in close contact with the step wedge, and the bright room printer P-627GM
(Dainippon Screen Mfg. Co., Ltd.), after exposing, use the developer and fixer of the following composition
R26 (manufactured by Konica Corporation) was used for processing.

Developer Formulation (Composition A) Pure Water (Ion Exchange Water) 150 ml Ethylenediaminetetraacetic acid disodium salt 2 g Diethylene glycol 50 g Potassium sulfite (55% W / V aqueous solution) 100 ml Potassium carbonate 50 g Hydroquinone 15 g 5-Methylbenzotriazole 200 mg 1 -Phenyl-5-mercaptotetrazole 30mg Adjust pH to 10.4 with potassium hydroxide (Composition B) Pure water (ion exchanged water) 3ml Ethylenediaminetetraacetic acid disodium salt 25mg Diethylene glycol 50g Acetic acid (90% aqueous solution) 0.3ml 2-Nitroindazole 110 mg 1-Phenyl-3-pyrazolidone 700 mg When the above composition was used, the above compositions A and B were dissolved in this order in 500 ml of water, and purified to 1 liter with pure water.

Fixer formulation Ammonium thiosulfate (72.5% W / V aqueous solution) 240 ml Sodium sulfite 17 g Sodium acetate trihydrate 6.5 g Boric acid 6.0 g Sodium citrate dihydrate 2.0 g Pure water (ion exchanged water) 17 ml Sulfuric acid ( 50% W / V aqueous solution) 2.0 g Aluminum sulphate (aqueous solution having an Al ₂ O ₃ conversion content of 8.1% W / V) 8.5 g When used, dissolve the above compositions A and B in this order in 500 ml of water, and 1 liter of pure water It was used after finishing. The pH of this fixer was 4.3 for acetic acid.

(Development processing conditions) (Process) (Temperature) (Time) Development 38 ° C. 12 seconds Fixing 35 ° C. 10 seconds Water washing 30 ° C. 10 seconds Drying 50 ° C. 13 seconds Total 45 seconds The above processing time includes transit time.

(Evaluation of gamma) The density of the developed sample thus obtained was measured with a digital densitometer PDA-65 (manufactured by Konica Corporation). Gamma is expressed by the tangent of density 0.1 and 3.0.
If the gamma value is less than 6, it cannot be used as a plate-making film, and if it is 6 or more and less than 10, it is insufficient.

When the gamma value is 10 or more, a super-high contrast image can be obtained.

(Evaluation of Color Remaining Property) The unexposed film was subjected to a development treatment under the conditions of a washing water flow rate of 5.0 ml / min in an automatic processor,
The residual color level when the sheets were stacked was evaluated on a scale of five. An evaluation rank of 5 is the best level, and ranks of 3 and above are practically usable levels.

(Evaluation of Fog) The unexposed portion of the obtained developed sample was subjected to density measurement by the digital densitometer PDA-65 to evaluate the fog value. Density of unexposed area (fog value)
A value of 0.06 or above is not practical.

(Evaluation of storability with time) The obtained sample was cut in half and one of them was stored at 23 ° C and 50% RH for 3 days. The other one was stored at 50 ° C and 55% RH for 3 days as a test for historical use, and both samples were processed as above, and then digital densitometer PDA-65.
The density of light is measured to obtain the density of 3.0 from each sample, and Log (exposure light quantity [D = 3.0 23 ℃ 50% RH]) / (exposure light quantity [D = 3.0 50 ℃ 55% RH ]) Is the change in sensitivity with time.

(Evaluation of Nuki Character Width) As described in JP-A-58-190943, an embedding base / film on which a line image positive image is formed (line image original) / embedding base / halftone image is formed. Films (halftone dot originals) are stacked in this order, and the protective layer of each sample film and the halftone dots of the halftone dot originals are brought into close contact with each other face-to-face, and 50% halftone dot area is placed on the film. Proper exposure was given so that it would be 50%, and the character width of 100 μm on the line drawing original was reproduced on the sample film when the above-mentioned processing was performed, and the width was defined as the blank character width. 80 μm
The above is the practical range.

(Evaluation of black spots) The unexposed portions of the obtained developed sample were visually observed with a 40-fold magnifying glass to observe black spots. The case where no black spots were generated was designated as 5, and the rank was expressed as 4, 3, 2, 1 according to the degree of occurrence of black spots. Ranks 1 and 2 are practically unfavorable levels.

The results are shown in Tables 1 and 2.

[0111]

[Table 1]

[0112]

[Table 2]

Example 2 (Preparation of silver halide emulsion) 68 mol% of silver chloride and 30 mol of silver bromide
A silver nitrate aqueous solution and a mixed aqueous solution of NaCl, KBr, and KI were mixed by a controlled double jet method so that a silver halide composition of mol% and silver iodide 2 mol% was mixed to grow silver halide grains. In this case, mixing is 36 ℃, pAg7.8, pH3.0
Performed under the conditions of the Na ₃ RhCl ₆ per mol of silver 2 × 10 during grain formation ^- was 7 mol of K ₂ IrCl ₆ and 8 × 10 ^-7 mol per mol.

Then, the emulsion was desalted with modified gelatin Exemplified G-8 described in JP-A-2-280139.

The obtained emulsion had an average grain size of 0.2 μm and a coefficient of variation.
The emulsion consisted of 10% cubic grains. The emulsion thus obtained contains 1.2 mg of chloroauric acid of 3 mg per mol of silver.
g of sodium thiosulfate was added, and chemical ripening was carried out at 60 ° C. for 40 minutes under the conditions of pH 5.4 and pH Ag 7.0. After the ripening, 900 mg of 4-hydroxy-6-methyl-1,3,3a, 7-tetrazaindene was added per mol of silver, 50 mg of 1-phenyl-5-mercaptotetrazole was added, and further 150 mg of potassium iodide, Spectral sensitization was performed by adding 200 mg of the following spectral sensitizing dye (S-3).

[0116]

[Chemical 19]

(Preparation of silver halide photographic light-sensitive material) One side of a 100 μm thick polyethylene terephthalate film having a 0.1 μm thick undercoat layer (described in Example 1 of JP-A-59-19941) on both sides Then, a subbing layer of the following formulation 7 is applied, and a silver halide emulsion layer of the following formulation 8 is coated thereon with a gelatin amount of 1.
8 g / m ² and silver amount of 3.5 g / m ^2, and a protective layer of the following Formulation 9 on it with a gelatin amount of 1.5 g.
Painted to be / m ^{2 etc.} On the other subbing layer on the opposite side, a backing layer was coated according to the following formulation 10 so that the amount of gelatin was 2.4 g / m ^2, and a protective layer of the following formulation 11 with the amount of gelatin was further applied thereon. A sample was obtained by coating so as to be 1 g / m ² .

Formulation 7 (gelatin undercoat layer composition) Gelatin 0.6 g / m ² Dye described in Table 2 Styrene-maleic acid copolymer hydrophilic polymer (thickener) 10 mg / m ² Sodium-iso-amyl-n -Decylsulfosuccinate 0.4 mg / m ² Formulation 8 (silver halide emulsion composition) Gelatin 1.8 g / m ² Silver halide emulsion Silver amount 3.5 g / m ² Antifoggant: 2-mercaptoxanthine 2 mg / m ² : 5-Methylbenzotriazole 10 mg / m ² Hydrazine derivative according to the present invention: H-16 Amount shown in Table 2 Nucleation accelerator example (23) 20 mg / m ² Water-soluble polymer Amount shown in Table 2 Polymer latex 1.0 mg / m ² Polyethylene glycol (molecular weight 4000) 30 mg / m ² Surfactant: saponin 0.1 g / m ² : sodium sulfosuccinate-iso-pentyl-n-decyl ester 8 mg / m ² Formulation 9 (emulsion protective layer composition) Gelatin 1.5 mg / m ² matting agent: average particle size 3.5μm silica 20mg m ² Surfactant: Sodium sulfosuccinic acid di (2-ethylhexyl) ester 10 mg / m ² Surfactant (h) 2 mg / m ² promoter: hydroquinone: 1-phenyl-4-hydroxy-4'-Mechirupira Zolidone 5 mg / m ² dye Amount shown in Table 2 Hardener Amount shown in Table 2 Formulation 10 (Backing layer composition) Compound (D-2) 30 mg / m ² Compound (D-3) 75 mg / m ² Compound (D -4) 30mg / m ² Gelatin 2.4mg / m ² Surfactant: Sodium dodecylbenzene sulfonate 50mg / m ²

[0119]

Embedded image

Formulation 11 (backing protective layer) Gelatin 1 mg / m ² Matting agent: polymethylmethacrylate 50 mg / m ^{2 having an} average particle size of 4.0 μm Surfactant: sodium sulfosuccinate di (2-ethylhexyl) ester 10 mg / m ² Hardener: Bisvinylsulfomethyl ether 25 mg / m ² : 2-Hydroxy-4,6-dichloro-1,3,5-triazine 35 mg / m ² Sodium Samples 2-1, 2-3, 2-5, 2-7,
2-10 was produced.

Further, those obtained by changing the dye addition layer to an emulsion protective layer are 2-2, 2-6 and 2-9, respectively, and the support undercoat layer is 2-4. 2-8, 2-11
The obtained sample was evaluated by the following method.

(Evaluation of gamma) The density of the obtained developed sample was measured with a digital densitometer PDA-65 (manufactured by Konica [Co.]). Gamma is expressed by the tangent of density 0.1 and 3.0.
If the gamma value is less than 6, it cannot be used as a plate-making film, and if it is 6 or more and less than 10, it is insufficient. An ultra-high contrast image can be obtained only when the gamma value is 10 or more.

(Evaluation of linearity) The linearity correction mechanism of the SG-747 type scanner (manufactured by Dainippon Screen Mfg. Co., Ltd.) was released, and a 21-step test pattern in which the mesh% was changed in 5% increments was used. Output at 700 lines / inch. At this time, the laser power was changed and output was performed, and the same developing treatment as in Example 1 was performed. Sensitivity is net 100
When the transmission density of the% portion was 5.0, the relative sensitivity was expressed as the appropriate exposure.

Further, the actual net% of the portion that originally output 50% net% was measured, and the difference from the setting (50%) was obtained and linearity was calculated. That is, the smaller the difference between them, the better the linearity. Further, the exposure amount of 10% before and after the appropriate exposure amount was changed, and the change of the halftone dot ratio to be 50% was obtained, and this was used as the exposure latitude.

The treating agent was the same as in Example 1 except that the pH of the developing solution was fixed at 10.5.

The above samples 2-9, 2-10, 2-11,
When processing 2-8, the samples which were treated differently only when the pH of the developing solution was increased from 10.5 to 11.7 were 2-12 and 2-
It was set to 13, 2-14, and 2-15.

The above results are shown in Tables 3 and 4.

[0128]

[Table 3]

[0129]

[Table 4]

From the results of Tables 3 and 4, it can be said that the samples of the present invention have high contrast, excellent linearity and residual color.

Example 3 The comparative dyes shown in Table 5 and the dyes of the present invention were added to the backing layer (formulation 4) of the sample prepared in Example 1 and the others were coated and dried in the same manner as in Example 1 to prepare Sample 3 -1, 3-2,
3-3, 3-4, 3-5, and 3-6 were created.

(Evaluation of Residual Color) The unexposed film was developed under the condition of a washing water flow rate of 5.0 ml / min in an automatic processor, and the residual color level when 5 sheets were overlaid was evaluated in 5 ranks. A rank of 5 is the best level, and a rank of 3 or higher is a level that can be practically used.

(Evaluation of discoloration) After leaving the sample under the conditions of 23 ° C. and 80% RH for 2 hours, the backing side of the sample was lightly rubbed with dry gauze. At this time, the degree of coloration on the gauze was visually evaluated, and evaluated in 5 ranks. Rank 5 is the best level with no color on the gauze, Rank 3
The above is the level that can be practically used.

(Evaluation of storability with time) The obtained sample was cut in half and one of them was stored at 23 ° C and 50% RH for 3 days. The other one was stored at 50 ° C and 55% RH for 3 days as a test for historical use, and both samples were processed as above, and then digital densitometer PDA-65.
The density of light is measured to obtain a density of 3.0 from each sample, and Log (exposure light quantity [D = 3.0 23 ℃ 50% RH]) / (exposure light quantity [D = 3.0 50 ℃ 55% RH]) was taken as the change in sensitivity with time.

The results are shown in Tables 5 and 6.

[0136]

[Table 5]

[0137]

[Table 6]

From the results shown in Tables 5 and 6, the samples of the present invention are excellent in the residual color and color fading, and have good stability with time.

[0139]

EFFECTS OF THE INVENTION According to the present invention, it has good contrast and is excellent in sharpness, clear character quality, residual color, black spots, color fading, and storage stability over time, and fading by hand such as in a bright room. It was possible to provide a silver halide photographic light-sensitive material which does not have the above and a rapid processing method thereof.

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Claims (18)

[Claims] 1. A silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer on one side of a support, wherein the emulsion layer and / or the adjacent layer is represented by the following general formula [1]: A halogenated layer containing at least one of the compounds represented, characterized in that a non-photosensitive layer in which a dye having an absorption maximum at 300 to 500 nm is dispersed in a solid state is provided outside the emulsion layer with respect to a support. Silver photographic light-sensitive material. Embedded image In the formula, R ₁ represents a hydrogen atom or an alkyl group or an alkoxy group which may have a substituent, and R ₂ represents an alkyl group, an acyl group or an acylamino group which may have a substituent. X represents an anion, y is 1 or 2, and y is 1
When, an inner salt is formed. 2. The silver halide photographic light-sensitive material according to claim 1, wherein R ₂ in the general formula [1] is an alkylene sulfonic acid or an acylamino group. 3. In the general formula [1], R ₂ is-(-
CH ₂ −) _m −SO ₃ ⁻ , −NR ₃ COR 4, − (− CH ₂ −) p −CONR ₇ R ₈ ,
− (− CH ₂ −) q−NR ₉ R ₁₀ , − (CH ₂ −) s−CH− (LR ₁₂ ) −R ₁₁
The stands, R ₃ represents an alkyl group which may have a hydrogen atom or a substituent, R ₄ represents an alkyl group which may have a substituent, an alkoxyl _{group, -O - (- CH 2 -} ) n- SO ₃ ^-, -NR
₅ R ₆ , represents — (— CH ₂ —) n—SO ₃ ^— , R ₅ and R ₆ represent a hydrogen atom or an alkyl group which may have a substituent, — (— CH ₂ —) n—
Represents SO ₃ ^— , R ₇ represents a hydrogen atom, or an alkyl group which may have a substituent or an aryl group, R ₈ represents a hydrogen atom,
Or an alkyl group which may have a substituent or a group which forms a 5-membered or 6-membered aliphatic ring with R ₇ and R ₉ represents a hydrogen atom or an alkyl group which may have a substituent or -COR ₄ Represents
R _{1 0} is a hydrogen atom or an optionally substituted alkyl group, or _{- (- CH 2 -) r} -SO 3 - represents, L is represents -O- or -NR _13, R ₁₁ is a hydrogen atom or even represent an alkyl group having a substituent, R ₁₂ represents a hydrogen atom or an optionally substituted alkyl _{group, -COR 14, -CONHR 15, R} 13, R 14,
R ₁₅ represents a hydrogen atom or an alkyl group which may have a substituent, m is 0 or 2 to 4, n is 1 to 3, p is 0 to 2, q
2. The silver halide photographic light-sensitive material according to claim 1, wherein r is 1 to 3 and s is 2 to 3. 4. In the general formula [1], R ₁ is a hydrogen atom or an alkyl group or an alkoxy group which may have a substituent, and R ₂ is — (— CH ₂ —) m—SO ₃ ^— or The silver halide photographic light-sensitive material according to claim 1, which is NR ₃ COR ₄ . 5. The silver halide photographic light-sensitive material according to claim 1, wherein the silver halide emulsion comprises silver chloride grains or silver chlorobromide grains having a silver chloride content of 80 mol% or more. 6. The silver halide photographic light-sensitive material according to claim 5, wherein the silver halide emulsion layer and / or the hydrophilic colloid layer contains at least one hydrazine compound. 7. A method for developing a silver halide photographic light-sensitive material, which comprises developing the silver halide photographic light-sensitive material according to claim 6 with a developer having a pH of 9.0 to 0.7. 8. The method of processing a silver halide photographic light-sensitive material according to claim 7, wherein the replenishing amount of the developing solution is 1
A method of processing a silver halide photographic light-sensitive material, which comprises performing development processing with a replenishing amount of 300 ml or less per m ² . 9. The silver halide photographic light-sensitive material processing method according to claim 8, wherein the total processing time (Dry to Dry) of the step of processing with an automatic processor is 60 seconds or less. Processing method of silver photographic light-sensitive material. 10. A silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer on one side of a support, wherein the emulsion layer and / or the adjacent layer is represented by the general formula [1]. A silver halide photographic light-sensitive material comprising a colloid layer containing at least one of the compounds shown and containing a solid-dispersed dye between the silver halide emulsion layer and a support. 11. The silver halide photographic light-sensitive material according to claim 10, wherein the silver halide emulsion layer and / or the hydrophilic colloid layer contains at least one hydrazine compound. 12. A method of developing a silver halide photographic light-sensitive material, which comprises developing the silver halide photographic light-sensitive material according to claim 11 with a developer having a pH of 9.0 to 0.7. 13. The method of developing a silver halide photographic light-sensitive material according to claim 12, wherein the developing solution is replenished in an amount of 300 ml or less per 1 m ^{2 of the} light-sensitive material. Method of processing photosensitive material. 14. The method for processing a silver halide photographic light-sensitive material according to claim 13, wherein the total processing time (Dry to Dry) of the step of processing with an automatic processor is 60 seconds or less. Processing method of silver photographic light-sensitive material. 15. A hydrophilic colloid layer having at least one silver halide emulsion layer on one side of the support and no silver halide emulsion layer on the other side of the support.
In the silver halide photographic light-sensitive material having a layer, the hydrophilic colloid layer not containing the silver halide emulsion layer contains one of the compounds represented by the above general formula [1] and a solid dispersed dye. Silver halide photographic light-sensitive material. 16. A method for developing and processing a silver halide photographic light-sensitive material, which comprises developing the silver halide photographic light-sensitive material according to claim 15 with a developer having a pH of 9.0 to 0.7. 17. The method of developing a silver halide photographic light-sensitive material according to claim 16, wherein the developing solution is replenished in an amount of 300 ml or less per 1 m ^{2 of the} light-sensitive material. Method of processing photosensitive material. 18. The method of processing a silver halide photographic light-sensitive material according to claim 17, wherein the total processing time (Dry to Dry) of the step of processing with an automatic processor is 60 seconds or less. Processing method of silver photographic light-sensitive material.