JPH0792792A - Developing device and image forming device with this developing device - Google Patents

Developing device and image forming device with this developing device

Info

Publication number
JPH0792792A
JPH0792792A JP23603093A JP23603093A JPH0792792A JP H0792792 A JPH0792792 A JP H0792792A JP 23603093 A JP23603093 A JP 23603093A JP 23603093 A JP23603093 A JP 23603093A JP H0792792 A JPH0792792 A JP H0792792A
Authority
JP
Japan
Prior art keywords
image
toner
contact
developing roller
developer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP23603093A
Other languages
Japanese (ja)
Other versions
JP2930508B2 (en
Inventor
Koji Imamiya
弘二 今宮
Takashi Shimazaki
隆 島崎
Shigenobu Osawa
重信 大沢
Yoshiyuki Fukuda
善行 福田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP23603093A priority Critical patent/JP2930508B2/en
Publication of JPH0792792A publication Critical patent/JPH0792792A/en
Application granted granted Critical
Publication of JP2930508B2 publication Critical patent/JP2930508B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To provide images with no image degrading such as printing density unevenness while generating no contamination on a photoreceptor drum, a developing device with a long service life and an image forming device equipped with the developping device. CONSTITUTION:This device is provided with a photoreceptor drum 1 for carrying latent images, a resilient developping roller 12 which is brought into contact with the drum 1 and supplies toner to develop latent images and a flexible blade which forms a thin toner layer on the roller 12 while being in contact with the roller 12. The roller 12 comprises a metal shaft 12a and a high- molecular resilient layer having the hardness of rubber (40 degrees or more) put on the metal shaft. Penetration holes along the longitudinal direction of the shaft 12a are formed on the high-molecular resilient layer over the circumference of the metal shaft 12a and the contact is made to the drum 1 with the contact pressure of 1-10g/mm.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、たとえば電子写真装置
に適用される現像装置およびこの現像装置を備える画像
形成装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a developing device applied to, for example, an electrophotographic apparatus and an image forming apparatus including the developing device.

【0002】[0002]

【従来の技術】近年、磁性あるいは非磁性トナーを用い
た接触現像の研究およびプリンター、ファックス、複写
機等の製品化が盛んに行なわれている。これらの接触現
像方式に用いる現像ローラは、金属材料を使用したパイ
プを感光体に接触させるタイプと、高分子弾性体ローラ
を使用するタイプに大別できる。
2. Description of the Related Art In recent years, research on contact development using magnetic or non-magnetic toner and commercialization of printers, fax machines, copying machines and the like have been actively conducted. The developing roller used in these contact developing methods can be roughly classified into a type in which a pipe made of a metal material is brought into contact with a photoconductor and a type in which a polymer elastic roller is used.

【0003】この中で、高分子弾性体を使用した現像ロ
ーラはローラ加工時に使用する可塑剤等により、現像ロ
ーラに接触している感光体を汚染し、潜像形成に必要な
所定の表面電位が得られない場合や、潜像のボケ等の発
生につながることがある。
Among them, a developing roller using a polymer elastic body contaminates a photoconductor in contact with the developing roller with a plasticizer or the like used at the time of processing the roller, and a predetermined surface potential required for latent image formation. May not be obtained, or blurring of the latent image may occur.

【0004】高分子弾性体としてゴム硬度30°(JI
S−A)近辺のポリウレタンを使用した場合にも、ロー
ラ加工時に添加する可塑剤、オイル等が感光体を汚染す
る事が知られている。さらにゴム硬度を下げると甚だし
い感光体の汚染が引き起こされる事は衆知の事実であ
る。
Rubber hardness of 30 ° (JI
It is known that even when polyurethane near S-A) is used, the plasticizer, oil and the like added during roller processing contaminate the photoconductor. It is a well-known fact that further lowering of rubber hardness causes serious contamination of the photoreceptor.

【0005】又、現像ローラにシリコンゴムを使用した
場合に於いても、低分子量のオリゴマーがゴム表面に溶
出し感光体を汚染することが知られている。高分子弾性
体を使用した接触現像用ローラは、上記の問題を排除す
るために、使用するゴムから汚染物質が溶出しないこと
が前提になる。
It is also known that even when silicone rubber is used for the developing roller, low molecular weight oligomers elute on the rubber surface and contaminate the photoreceptor. In order to eliminate the above problems, the contact developing roller using a polymer elastic body is premised on that contaminants are not eluted from the rubber used.

【0006】ポリウレタン等を使用した場合には、約4
0°以上に硬度を上げれば、比較的溶出量が減り、実用
的に耐えられる事が判明している。又、上記問題を排除
するために、現像ローラに低オリゴマータイプの硬度4
0°前後のシリコンゴムを使用する例もある。
When polyurethane or the like is used, it is about 4
It has been proved that when the hardness is increased to 0 ° or more, the amount of elution is relatively reduced, and it can be practically used. In addition, in order to eliminate the above problems, the developing roller has a hardness of low oligomer type 4
There is also an example in which a silicon rubber of about 0 ° is used.

【0007】また、高分子弾性体を接触現像用ローラに
使用する場合、表面の平滑性が求められ表面粗さRz=
10μm以下が必要であり、表面が粗いと表面粗さに対
応した模様が画像に発生する。これを実現するには、ロ
ーラ成型後表面研磨工程が必要であるが、表面研磨をす
ると通常、ローラ外径が中央部に比較し端部が大きくな
る。
Further, when the elastic polymer is used for the contact developing roller, the smoothness of the surface is required and the surface roughness Rz =
The thickness is required to be 10 μm or less, and if the surface is rough, a pattern corresponding to the surface roughness is generated in the image. To achieve this, a surface polishing step is required after the roller is molded, but when the surface is polished, the outer diameter of the roller is usually larger at the end portion than at the central portion.

【0008】ところで、画像形成装置に配設される感光
体、クリーニングブレード、現像ローラの長手方向の位
置関係は通常、前記感光体、クリーニングブレード、現
像ローラの順で長手方向の長さを小さくする必要があ
る。つまり、現像一転写工程後に感光体上の転写残りト
ナーを清掃するクリーニングブレードの幅は、トナーを
感光体に接触させて現像を行なう現像ローラよりも大き
くする必然性があり、又感光体との幅においては、略同
等かそれ以下の幅になる。
By the way, regarding the positional relationship in the longitudinal direction of the photoconductor, the cleaning blade, and the developing roller arranged in the image forming apparatus, the length of the photoconductor, the cleaning blade, and the developing roller in the longitudinal direction is made smaller in this order. There is a need. In other words, the width of the cleaning blade that cleans the transfer residual toner on the photoconductor after the development-transfer step must be larger than that of the developing roller that performs development by bringing the toner into contact with the photoconductor, and the width with the photoconductor. In, the width is almost equal or less.

【0009】従って、上記の幅関係で、端部外径が中央
部より大きい現像ローラを感光体に接触させ、現像ロー
ラ長手方向に均一な現像を行なうには外径の小さい部分
も感光体との所定のニップ幅が必要であり、このために
は所定の圧接荷重が必須となる。
Therefore, due to the above-mentioned width relation, in order to bring the developing roller whose outer diameter at the end portion is larger than the central portion into contact with the photosensitive member and to perform uniform development in the longitudinal direction of the developing roller, the portion having the smaller outer diameter also serves as the photosensitive member. A predetermined nip width is required, and a predetermined pressure contact load is essential for this.

【0010】一方、現像ローラの外径公差と共に振れ公
差も荷重アップのための重要な支配因子となり、特に感
光体軸と現像ローラ軸を固定させた軸間固定方式の場
合、感光体の円周方向に均一な画像を得るためには、感
光体の振れと現像ローラの振れの重ね合わせにおいて、
最も重なりの小さい位相の場合においても所定以上の現
像ニップが得られる軸間距離が必要である。
On the other hand, in addition to the outer diameter tolerance of the developing roller, the runout tolerance is also an important controlling factor for increasing the load. Especially, in the case of a shaft-to-axis fixing system in which the photoreceptor shaft and the developing roller shaft are fixed, the circumference of the photoreceptor is In order to obtain a uniform image in the direction, in the superimposition of the shake of the photoconductor and the shake of the developing roller,
Even in the case of the phase with the smallest overlap, the axial distance is required so that a developing nip larger than a predetermined value can be obtained.

【0011】[0011]

【発明が解決しようとする課題】しかし、外径公差、振
れ公差を吸収すべく現像ローラと感光体間の押圧力を加
えると、トナーの破壊及び凝集が発生し、当初のトナー
粒子径分布が大きく崩れ、画面上にカブリの発生および
画像のシャープさの欠如、ベタ黒画像の不均一性の発生
などの画像劣化が起こり、極めて寿命の短い装置にな
る。
However, when a pressing force between the developing roller and the photosensitive member is applied in order to absorb the outer diameter tolerance and the runout tolerance, the toner is broken and agglomerated, and the initial toner particle diameter distribution is changed. The image is greatly deteriorated, image is fogged on the screen, lack of image sharpness, nonuniformity of solid black image, and the like, and image deterioration occurs, resulting in a device having an extremely short life.

【0012】トナー層形成部材として可撓性部材を現像
ローラに接触させ、トナー薄層を弾性ローラに形成し、
静電潜像を現像する場合においても、前記現像ローラと
感光体のニップの概念と同様に、トナー層形成部材と現
像ローラのニップが重要になる。
As a toner layer forming member, a flexible member is brought into contact with a developing roller to form a thin toner layer on an elastic roller,
When developing an electrostatic latent image, the nip between the toner layer forming member and the developing roller is important, similar to the concept of the nip between the developing roller and the photoconductor.

【0013】トナー層形成部材の目的はトナー薄層を現
像ローラ上に形成すると同時に、トナー層形成部材と現
像ローラの間を通過する時に、トナーを帯電する目的が
あり、所定の摩擦帯電付与時間が必要である。従って4
0°以上の比較的ゴム硬度の高い現像ローラを使用する
とトナー層形成部材にある程度の圧力を付与する必要が
あり、また荷重をかけすぎると、前述の現像ローラと感
光体と同様にトナーの破壊および凝集を引き起こし、さ
らには現像ローラにトナーが溶着するフィルミング現象
が発生する場合もある。
The purpose of the toner layer forming member is to form a thin toner layer on the developing roller and at the same time to charge the toner when passing between the toner layer forming member and the developing roller. is necessary. Therefore 4
When a developing roller having a relatively high rubber hardness of 0 ° or more is used, it is necessary to apply a certain amount of pressure to the toner layer forming member, and if a load is applied too much, the toner will be destroyed like the developing roller and the photoconductor. In addition, aggregation may be caused, and a filming phenomenon may occur in which the toner is fused to the developing roller.

【0014】そこで、本発明は画像劣化を発生すること
なく、また、現像ローラに現像剤が溶着するフィルミン
グ現象を発生することなく、良好に画像を形成できる現
像装置およびこの現像装置を備える画像形成装置を提供
することを目的とする。
Therefore, according to the present invention, a developing device capable of forming an excellent image without causing image deterioration and a filming phenomenon in which a developer is welded to a developing roller, and an image provided with this developing device are provided. An object is to provide a forming device.

【0015】[0015]

【課題を解決するための手段】本発明は上記課題を解決
するため、潜像を担持する像担持体と、この像担持体に
接触され、現像剤を供給して前記潜像を現像する弾性の
現像剤供給部材と、この現像剤供給部材に接触され該現
像剤供給部材上に現像剤の薄層を形成する可撓性の現像
剤層形成部材とを具備し、前記現像剤供給部材は心材
と、この心材に被覆されるゴム硬度を40°以上とする
高分子弾性体とからなり、前記高分子弾性体に前記心材
の長手方向に沿う貫通孔を前記心材の周方向に亘って複
数個有し、前記像担持体に対し1〜10g/mmの接触
圧力で接触される。
In order to solve the above-mentioned problems, the present invention provides an image bearing member carrying a latent image and an elastic member which is brought into contact with the image bearing member and supplies a developer to develop the latent image. And a flexible developer layer forming member which is in contact with the developer supplying member and forms a thin layer of the developer on the developer supplying member. A core material and a polymer elastic body having a rubber hardness of 40 ° or more, which is coated on the core material, and a plurality of through holes along the longitudinal direction of the core material are provided in the polymer elastic body in the circumferential direction of the core material. One of them is provided and is brought into contact with the image carrier at a contact pressure of 1 to 10 g / mm.

【0016】また、潜像を担持する像担持体と、この像
担持体に潜像を形成する像形成手段と、前記像担持体に
接触され、現像剤を供給して前記潜像を現像する弾性の
現像剤供給部材と、この現像剤供給部材に接触され該現
像剤供給部材上に現像剤の薄層を形成する可撓性の現像
剤層形成部材とを具備し、前記現像剤供給部材は心材
と、この心材に被覆されるゴム硬度を40°以上とする
高分子弾性体とからなり、前記高分子弾性体に前記心材
の長手方向に沿う貫通孔を前記心材の周方向に亘って複
数個有し、前記像担持体に対し1〜10g/mmの接触
圧力で接触される。
Further, an image bearing member carrying a latent image, an image forming means for forming a latent image on the image bearing member, and the image bearing member are brought into contact with each other, and a developer is supplied to develop the latent image. An elastic developer supply member; and a flexible developer layer forming member that is in contact with the developer supply member and forms a thin layer of the developer on the developer supply member. Is composed of a core material and a polymer elastic body covering the core material with a rubber hardness of 40 ° or more, and a through hole along the longitudinal direction of the core material is provided in the polymer elastic body in the circumferential direction of the core material. A plurality of them are provided and are brought into contact with the image carrier at a contact pressure of 1 to 10 g / mm.

【0017】[0017]

【作用】前記現像剤供給部材を心材と、この心材に被覆
されるゴム硬度を40°以上とする高分子弾性体とによ
り構成し、前記高分子弾性体に前記心材の長手方向に沿
う貫通孔を前記心材の周方向に亘って複数個設け、この
現像剤供給部材を前記像担持体に対し1〜10g/mm
の接触圧力で接触させることにより、像担持体を汚染す
ることないとともに、印字濃度ムラ等の画像劣化がない
良好な画像を提供する。
The developer supplying member is composed of a core material and a polymer elastic body having a rubber hardness of 40 ° or more, which is covered with the core material. The polymer elastic body has a through hole extending in the longitudinal direction of the core material. Are provided along the circumferential direction of the core member, and the developer supply member is 1 to 10 g / mm with respect to the image carrier.
By contacting with the contact pressure of 1, the image carrier is not contaminated, and a good image is provided without image deterioration such as print density unevenness.

【0018】[0018]

【実施例】以下、本発明の実施例を図面を参照しながら
詳細に説明する。図2は、電子写真装置の内部構成を示
すもので、図中1は矢印a方向に回転する像担持体とし
ての負帯電性の有機感光ドラムである。この感光ドラム
1の周囲部にはその回転方向に沿って帯電チャ−ジャ
2、現像装置11、転写、剥離チャ−ジャ−3,4、ク
リ−ニングブレ−ド5が配設されている。
Embodiments of the present invention will now be described in detail with reference to the drawings. FIG. 2 shows the internal structure of the electrophotographic apparatus. In FIG. 2, reference numeral 1 denotes a negatively chargeable organic photosensitive drum as an image carrier that rotates in the direction of arrow a. Around the photosensitive drum 1, a charging charger 2, a developing device 11, transfer and peeling chargers 3 and 4, and a cleaning blade 5 are arranged along the rotation direction.

【0019】上記現像装置11は接触型一成分現像装置
で、この現像装置11は、導電性と弾性を有する現像ロ
ーラ12を備えている。前記現像ローラ12の表面には
非磁性トナーの薄層が形成され、この非磁性トナーの薄
層が感光ドラム12の表面に接触されて現像が行なわれ
る。この現像装置11は、現像剤キャリア、マグネット
ローラ、トナー濃度コントロール装置などが不要であ
り、小型化、低価格化が可能な現像装置である。
The developing device 11 is a contact type one-component developing device, and the developing device 11 includes a developing roller 12 having conductivity and elasticity. A thin layer of non-magnetic toner is formed on the surface of the developing roller 12, and the thin layer of non-magnetic toner is brought into contact with the surface of the photosensitive drum 12 for development. The developing device 11 does not require a developer carrier, a magnet roller, a toner concentration control device, and the like, and is a developing device that can be downsized and reduced in cost.

【0020】以下に上記現像装置11の現像機構につい
て説明する。上記現像装置11はトナー容器14を有
し、このトナー容器14内の非磁性トナー15は、ミキ
サー16により撹拌されつつトナー供給ローラ17に送
られ、このトナー供給ローラ17より現像ローラ12に
トナーが供給される。トナー15は現像ローラ12表面
との摩擦により帯電し、現像ローラ12の表面に静電的
に吸着して搬送される。その後、現像剤薄層形成部材
(以下、ブレードという)18によりトナー搬送量を規
制されると同時に、両者との摩擦によりトナー15の摩
擦帯電が行われる。尚、ブレード18は第1のブレード
ホルダー18a、スペーサー18b、及び第2のブレー
ドホルダー18cにより保持され、現像ローラ12に当
接されている。
The developing mechanism of the developing device 11 will be described below. The developing device 11 has a toner container 14, and the non-magnetic toner 15 in the toner container 14 is sent to a toner supply roller 17 while being agitated by a mixer 16, and the toner is supplied from the toner supply roller 17 to the developing roller 12. Supplied. The toner 15 is charged by friction with the surface of the developing roller 12, and electrostatically adsorbed on the surface of the developing roller 12 and conveyed. After that, the toner conveyance amount is regulated by the developer thin layer forming member (hereinafter referred to as a blade) 18, and at the same time, the toner 15 is triboelectrified by friction between the two. The blade 18 is held by the first blade holder 18a, the spacer 18b, and the second blade holder 18c, and is in contact with the developing roller 12.

【0021】本実施例においては、負帯電性の有機感光
体ドラム1を用いた反転現像であるため、トナー15と
して負帯電トナーを用い、ブレード18として負帯電さ
せやすい材質を使用している。又、感光ドラム表面電位
(VH ) −500vに対して、現像バイアス電位(V
D )−200vを現像バイアス電源12dから現像ロー
ラ12の金属シャフト12aに給電している。現像ロー
ラ12は感光ドラム1の回転方向(矢印a方向)と反対
方向(矢印b方向)に感光ドラム1の約1〜4倍程度の
速度で、感光体1と接触回転(摺接)している。また、
トナー粒子は現像位置でも摩擦帯電されるため、かぶり
が少なく極めてシャープな画像が得られる。現像残りト
ナーはリカバリーブレード(マイラーフィルム)19を
すり抜けトナー容器14内へ戻る。
In this embodiment, since the reversal development is carried out using the negatively chargeable organic photosensitive drum 1, a negatively charged toner is used as the toner 15 and a material that is easily negatively charged is used as the blade 18. Further, with respect to the photosensitive drum surface potential ( VH ) -500v, the developing bias potential (V
D ) -200v is supplied from the developing bias power source 12d to the metal shaft 12a of the developing roller 12. The developing roller 12 makes contact rotation (sliding contact) with the photosensitive member 1 at a speed of about 1 to 4 times that of the photosensitive drum 1 in the direction opposite to the rotation direction of the photosensitive drum 1 (direction of arrow a) (direction of arrow b). There is. Also,
Since the toner particles are triboelectrically charged even at the developing position, an extremely sharp image can be obtained with less fog. The undeveloped toner passes through the recovery blade (mylar film) 19 and returns to the toner container 14.

【0022】なお、図1において20は第1のブレード
ホルダー18aに取り付けられたバッフル板であり、上
記ブレード18の裏面に取り付けられたモルトプレン等
できたた発泡材21と当接されることにより、トナーの
シールおよびブレード18の振動を抑えることができ、
良好なトナー薄層を現像ローラ12上に形成することが
できる。また、ブレード18は第1のブレードホルダー
18aの回転軸22および加圧用の複数の圧縮スプリン
グ23により現像ローラ12に押圧される。上記複数
の、圧縮スプリング23はブレード18の薄板バネ材の
バネ定数より低いため、ブレード18の当接部が摩耗し
てもほとんど加圧力の変化がなく、良好なトナー薄層を
維持できるようになっている。
In FIG. 1, reference numeral 20 is a baffle plate attached to the first blade holder 18a, which is brought into contact with a foam material 21 made of maltoprene or the like attached to the back surface of the blade 18, The toner seal and the vibration of the blade 18 can be suppressed,
A good toner thin layer can be formed on the developing roller 12. The blade 18 is pressed against the developing roller 12 by the rotary shaft 22 of the first blade holder 18a and the plurality of compression springs 23 for pressurization. Since the plurality of compression springs 23 are lower than the spring constant of the thin leaf spring material of the blade 18, even if the abutting portion of the blade 18 is worn, there is almost no change in the pressing force, and a good toner thin layer can be maintained. Has become.

【0023】次に、本発明の現像装置11の主要構成部
材の詳細を説明する。図2は現像ローラ12を示す斜視
図で、図3はその断面図である。上記現像ローラ12に
第一に要求される特性は、「導電性と弾性を有する」と
いうことであり、これを満足する一番簡単な構成は金属
シャフトと導電性ゴムローラという組み合わせである。
そのため本発明においては、図3に示すが如く、トナー
を現像ローラ12に圧接しながら搬送するため表面平滑
性を満足し得るよう金属シャフトからなる支持体12a
の外周に弾性体層12bと表面導電層12cの二層構造
とした。
Next, details of main constituent members of the developing device 11 of the present invention will be described. 2 is a perspective view showing the developing roller 12, and FIG. 3 is a sectional view thereof. The first characteristic required of the developing roller 12 is that it has conductivity and elasticity, and the simplest configuration that satisfies this is a combination of a metal shaft and a conductive rubber roller.
Therefore, in the present invention, as shown in FIG. 3, since the toner is conveyed while being in pressure contact with the developing roller 12, the support 12a made of a metal shaft so as to satisfy the surface smoothness.
A two-layer structure of an elastic layer 12b and a surface conductive layer 12c is provided on the outer periphery of the.

【0024】上記弾性体層12bとしては、導電性のも
のとそうでないものの2通りが考えられるが、前記表面
導電層12cに剥離や傷が生じる場合を考慮して導電性
のものが望ましい。前記弾性体層12bは、ブレード1
8や感光体ドラム13と圧接されているためゴム硬度が
大きいと所定のニップを得るのに大きな荷重が必要とな
り、ひいては現像器のトルクアップにもつながる。ま
た、梱包時や長時間放置されることによるJISK63
01に示される永久歪(%)も問題となり、10%を越
えると画像に現像ローラ周期のムラが生じてしまうので
前記弾性体層12bの圧縮歪み(%)は10%以下、望
ましくは5%以下としなければならない。ゴム硬度と永
久歪(%)との関係は一般にゴム硬度が大きいほど永久
歪は小さくなるという傾向があるので材料間のバランス
が重要になる。
There are two types of elastic layers 12b, one of which is electrically conductive and the other of which is not electrically conductive. In consideration of the case where the surface conductive layer 12c is peeled or scratched, the electrically conductive layer is preferable. The elastic layer 12b is the blade 1
8 and the photoconductor drum 13 are in pressure contact with each other, a large load is required to obtain a predetermined nip when the rubber hardness is large, which leads to an increase in the torque of the developing device. In addition, JISK63 due to being packed or left for a long time
The permanent strain (%) indicated by 01 also becomes a problem, and if it exceeds 10%, unevenness of the developing roller cycle occurs in the image. Therefore, the compression strain (%) of the elastic layer 12b is 10% or less, preferably 5%. Must be: Regarding the relationship between rubber hardness and permanent set (%), generally, the larger the rubber hardness is, the smaller the permanent set tends to be. Therefore, the balance between materials becomes important.

【0025】上記表面導電層12cは、直接トナーや感
光体1に接触するため、可塑剤・可硫剤・プロセスオイ
ル等のしみ出しによりトナーや感光体1を汚染しないも
のでなければならない。また、上記導電層12cの表面
平滑性については10μmRz以下が望ましく、それ以
上では表面の凹凸模様が画像に表われやすくなる。平滑
度10μmRzを実現するためには弾性体層12bに十
分膜厚の大きい導電層12cを形成した後、後加工(研
磨)により所定の外径、表面粗さに仕上げることが考え
られるが、コストが高くなるので加工なしで実現するこ
とが望ましく、そのためには前記弾性体層12bの表面
粗さと表面導電層12cの膜厚、および塗料の粘度を最
適に選択しなければならない。すなわち、粘度が低いも
のほど、かつ弾性体層12bの表面粗さが大きいほど、
表面導電層12cの膜厚を大きくしなければならない。
また、表面導電層12cの材料自体の伸び(%)も問題
となり50%以下では、前述の如く導電層12cはゴム
の弾性変形に追従できず、とくに弾性変形の大きくなる
両端で亀裂が生じやすくなる。弾性体層12bの材料の
伸び(%)と表面導電層12cの材料自体の伸び(%)
との間にも、その差が200%以下でなければゴムの弾
性変形に追従できなくなり、前記同様に亀裂が生じた
り、現像ローラ1回転内の濃度ムラが生じやすくなる。
本実施例では、表面導電層12cを構成する材料にはト
ナーを負帯電させることから、正に摩擦帯電しやすくト
ナー搬送性にも優れている材料を選択した。
Since the surface conductive layer 12c is in direct contact with the toner and the photosensitive member 1, it must be one which does not contaminate the toner and the photosensitive member 1 due to the seeping out of the plasticizer, the vulcanizing agent, the process oil and the like. Further, the surface smoothness of the conductive layer 12c is preferably 10 μmRz or less, and when it is more than 10 μmRz, an uneven pattern on the surface is likely to appear in an image. In order to achieve a smoothness of 10 μmRz, it is conceivable to form a conductive layer 12c having a sufficiently large film thickness on the elastic layer 12b and then finish it to a predetermined outer diameter and surface roughness by post-processing (polishing). Since it is high, it is desirable to realize without processing. For that purpose, the surface roughness of the elastic layer 12b, the film thickness of the surface conductive layer 12c, and the viscosity of the coating material must be selected optimally. That is, the lower the viscosity and the higher the surface roughness of the elastic layer 12b,
The film thickness of the surface conductive layer 12c must be increased.
Further, the elongation (%) of the material itself of the surface conductive layer 12c also becomes a problem, and if it is 50% or less, the conductive layer 12c cannot follow the elastic deformation of rubber as described above, and cracks are likely to occur particularly at both ends where the elastic deformation becomes large. Become. Elongation (%) of the material of the elastic layer 12b and elongation (%) of the material of the surface conductive layer 12c itself
Also, if the difference is not more than 200%, the elastic deformation of the rubber cannot be followed, and cracks are generated or density unevenness is easily generated in one rotation of the developing roller as described above.
In the present embodiment, the material forming the surface conductive layer 12c is negatively charged with the toner. Therefore, a material that is easily frictionally charged positively and has excellent toner transportability is selected.

【0026】上記現像ローラ12に要求される電気特性
を確認するため、金属シャフトからなる支持体12aと
導電層12cとの表面間の抵抗について、現像バイアス
電源12dと金属シャフト12aとの間に任意の抵抗値
の抵抗12eを介在させて現像実験を行なった。抵抗値
107 Ω・cm以上の抵抗値において、白ベタ画像と黒ベ
タ画像との現像時では現像ローラ12の表面電位は違っ
た値を示し、白ベタ画像では白地潜像電位(VH )に、
黒ベタ画像では黒地潜像電位(VL )に近づく傾向を示
している。すなわち、大面積の画像部を有する画像で
は、画像潜像電位(VL )と現像ローラ12表面電位と
の電位差が小さくなって濃度の低い画像となり、反対に
画像部の面積が小さい細線画像等では、現像ローラ12
表面電位が白地部潜像電位(VH )に近づき画像部との
電位差が大きくなるため、細線が太りメリハリのない画
像となってしまう。このような現像ローラ12表面の電
位変動は、現像時に上記抵抗中を流れる電流によって生
じている。黒ベタ現像時には負に帯電したトナー粒子が
現像ローラ12から感光体ドラム13へ転移するため、
電流は現像ローラ12からバイアス電源12dに向かっ
て流れる。白ベタ現像時には感光体ドラム13の表面電
荷が現像ローラ12によって除電されるため、電流は現
像バイアス電源12dから現像ローラ12に向かって流
れる。すなわち、このような電流が保護抵抗12eの両
端に電位差を生じさせ、上記のように現像ローラ12表
面電位変動をもたらしている。この傾向は保護抵抗12
eが108 Ω・cm以上で顕著であり、良好な画像を得る
には金属シャフトからなる支持体12aと表面導電層1
2cとの抵抗値は108 Ω・cm以下、好ましくは107
Ω・cm以下であることを確認した。
In order to confirm the electric characteristics required for the developing roller 12, the resistance between the surfaces of the support 12a made of a metal shaft and the conductive layer 12c is arbitrarily set between the developing bias power source 12d and the metal shaft 12a. A development experiment was conducted with a resistance 12e having a resistance value of 5 μm interposed. At a resistance value of 10 7 Ω · cm or more, the surface potential of the developing roller 12 shows different values during development of a white solid image and a black solid image, and a white background latent image potential (V H ) in a white solid image. To
The solid black image shows a tendency to approach the latent image potential ( VL ) on the black background. That is, in an image having a large area image portion, the potential difference between the image latent image potential ( VL ) and the surface potential of the developing roller 12 becomes small, resulting in a low density image. Then, the developing roller 12
Since the surface potential approaches the latent image potential (V H ) on the white background and the potential difference from the image portion becomes large, the thin line becomes thick and the image is not sharp. Such potential fluctuations on the surface of the developing roller 12 are caused by the current flowing through the resistance during development. Since negatively charged toner particles are transferred from the developing roller 12 to the photosensitive drum 13 during solid black development,
The current flows from the developing roller 12 toward the bias power source 12d. At the time of solid white development, the surface charge of the photosensitive drum 13 is removed by the developing roller 12, so that the current flows from the developing bias power source 12d toward the developing roller 12. That is, such a current causes a potential difference between both ends of the protective resistance 12e, and causes the surface potential fluctuation of the developing roller 12 as described above. This tendency is the protection resistance 12
e is remarkable at 10 8 Ω · cm or more, and in order to obtain a good image, the support 12a made of a metal shaft and the surface conductive layer 1
The resistance value with 2c is 10 8 Ω · cm or less, preferably 10 7
It was confirmed to be Ω · cm or less.

【0027】以上のことから、本発明の現像ローラ12
においては、弾性体層12bに伸び250〜500%程
度、電気抵抗値106 Ω・cm以下の導電性シリコンゴム
又は導電性ウレタンゴムを使用し、導電層12cには、
電気抵抗値104-5 Ω・cm、伸び100〜400%の導
電性ポリウレタン塗料[商品名:スパレックス、日本ミ
ラトトロン(株)社製]を使用した。
From the above, the developing roller 12 of the present invention is
In the above, in the elastic layer 12b, a conductive silicone rubber or a conductive urethane rubber having an elongation of about 250 to 500% and an electric resistance value of 10 6 Ω · cm or less is used, and for the conductive layer 12c,
Electrical resistance 10 4-5 Ω · cm, extends from 100 to 400% of the conductive polyurethane paint were used: the product name spa Rex, Japan Miratotoron Co., Ltd.].

【0028】さて、本発明に使用する現像ローラ12は
図3に示す導電性ゴム層12bに電気抵抗値1x106
Ω・cm、ゴム硬度42°(JIS−A)の導電性ウレ
タンゴムを使用し、この導電性ウレタンゴムに、芯金の
長手方向に平行でかつ芯金の周方向に亘って貫通孔12
d…を設けた。具体的には、外径8mmの金属シャフト
12aに肉厚5mmのウレタンゴム層12bを配置し、
このゴム層12bに内径2mmの貫通孔12d…をシャ
フト12aの長手方向に平行に12個設けた。
[0028] Now, the developing roller 12 is an electric resistance value 1x10 6 to the conductive rubber layer 12b shown in FIG. 3 for use in the present invention
A conductive urethane rubber having an Ω · cm and a rubber hardness of 42 ° (JIS-A) is used, and a through hole 12 is formed in the conductive urethane rubber in parallel with the longitudinal direction of the cored bar and in the circumferential direction of the cored bar.
d ... is provided. Specifically, a urethane rubber layer 12b having a thickness of 5 mm is arranged on a metal shaft 12a having an outer diameter of 8 mm,
Twelve through holes 12d having an inner diameter of 2 mm are provided in the rubber layer 12b in parallel with the longitudinal direction of the shaft 12a.

【0029】上記導電性ゴム層12bの表面に、電気抵
抗値1x104-5 Ω・cm、伸び100〜400%の導電
性ポリウレタン塗料[商品名:スパレックス、日本ミラ
トトロン(株)社製]を30〜100μmにコーティン
グした表面導電層12cを設けた。
[0029] on the surface of the conductive rubber layer 12b, the electrical resistance value 1x10 4-5 Ω · cm, extends from 100 to 400% of the conductive polyurethane paint [product name: Spa Rex, Japan Miratotoron Co., Ltd.] a A surface conductive layer 12c having a thickness of 30 to 100 μm was provided.

【0030】以上の構成により、ローラとしての全体的
なゴム硬度はASKERーC硬度で略50°〜55°
(JIS−A硬度で略25°〜30°)となり、非常に
弾性に富む現像ローラ12が実現した。
With the above construction, the overall rubber hardness of the roller is approximately 50 ° to 55 ° in ASKER-C hardness.
(JIS-A hardness is about 25 ° to 30 °), and the developing roller 12 having extremely high elasticity is realized.

【0031】この現像ローラ12を現像装置11に装着
し、メイン樹脂にポリエステルを原料とした体積平均粒
径10μm、5μm以下の個数分布比率が15%、1
2.7μm以上の体積分布比率が14%の負帯電トナー
を使用し、感光体に負帯電性の有機感光体を使い印字を
行なった。
The developing roller 12 is attached to the developing device 11, and the number distribution ratio of the volume average particle diameter of 10 μm or 5 μm or less using polyester as the main resin is 15%, 1%.
Printing was carried out using a negatively charged toner having a volume distribution ratio of 14% of 2.7 μm or more and a negatively charged organic photoreceptor as the photoreceptor.

【0032】現像ローラ12と感光ドラム1の圧接力を
パラメータにして画像を出力したところ図4に示す如く
の特性図を得た。図4中の縦軸は現像ローラ12と感光
ドラム1間の加圧力であり、横軸は画像1枚中の印字濃
度ムラであり、最大濃度と最小濃度の差を表す。
When the image was output using the pressure contact force between the developing roller 12 and the photosensitive drum 1 as a parameter, a characteristic diagram as shown in FIG. 4 was obtained. The vertical axis in FIG. 4 represents the pressure applied between the developing roller 12 and the photosensitive drum 1, and the horizontal axis represents the print density unevenness in one image, which represents the difference between the maximum density and the minimum density.

【0033】現像ロ−ラ12と感光ドラム1との圧接荷
重が低い領域に於いては、印字濃度ムラが大きく、逆に
圧接加重が高い領域では印字濃度ムラは低い値を示して
いる。
In the region where the pressure contact load between the developing roller 12 and the photosensitive drum 1 is low, the print density unevenness is large, and conversely, in the region where the pressure contact load is high, the print density unevenness shows a low value.

【0034】これは圧力の低い領域では現像ローラ12
の外径精度の影響をうけ局部的に適正な現像ニップが得
られていない為である。通常、印字濃度ムラは0.2以
下に抑える必要がありこれ以上の値では視覚的にバラン
スの悪いものとなる。
This is because the developing roller 12 is used in the low pressure region.
This is because an appropriate developing nip is not locally obtained due to the influence of the outer diameter accuracy of the. Normally, it is necessary to suppress the print density unevenness to 0.2 or less, and if it is more than this value, the balance is visually unbalanced.

【0035】また、図4は横軸に1万枚プリント時点の
トナーの破壊凝集の程度を示す1つの数値として、体積
分布12.7μm以上のトナー粒子の比率を示してい
る。圧接荷重が低い領域では12.7μm以上の微粒子
トナーの増加の程度は緩慢であるが、圧接荷重が高い場
合は微粒子のトナーの増加は激しく、特に線圧10g/
mmを越えるあたりから著しい増加となっている。この
状態のトナー粒子径分布はトナーの破壊による微粒子の
増加とともに、トナーの凝集による粗大粉も増加し、画
像上にカブリの発生および画像のシャープさが著しく劣
化する。我々の検討結果では一例としてカブリの視点か
ら破壊に依る12.7μm以下の個数分布は30%以下
に抑える必要がある事が判明した。
Further, FIG. 4 shows the ratio of toner particles having a volume distribution of 12.7 μm or more as one numerical value showing the degree of toner destructive aggregation at the time of printing 10,000 sheets on the horizontal axis. In the region where the pressure contact load is low, the degree of increase of the fine particle toner of 12.7 μm or more is slow, but when the pressure contact load is high, the increase of the fine particle toner is large, and particularly the linear pressure of 10 g /
It has increased remarkably from around mm. In the toner particle size distribution in this state, as the number of fine particles increases due to the destruction of the toner and the coarse particles increase due to the aggregation of the toner, fogging on the image and the sharpness of the image are significantly deteriorated. As a result of our study, it has been found that the number distribution of 12.7 μm or less due to fracture must be suppressed to 30% or less from the viewpoint of fog as an example.

【0036】以上により、本発明の現像ローラ12と感
光ドラム1の圧接荷重は線圧で1〜10g/mmの範囲
が適正領域となる。なお、本発明においては、現像ロー
ラ12の導電性ゴム層12bにポリウレタンゴムを使用
したが、低分子オリゴマーの少ない、従って感光ドラム
12への汚染が少ない、比較的硬度の高い導電性シリコ
ンゴム等を採用し、上記の貫通孔12d…を設けてもよ
い。また、支持体として金属シャフト12aを用いた
が、バイアス電圧が給電できれば、例えば樹脂シャフト
等でもよく、バイアス電圧を弾性体層に直接給電する方
式においては、支持体を導電性にする必要はない。
From the above, the pressure contact load between the developing roller 12 and the photosensitive drum 1 of the present invention is in the range of 1 to 10 g / mm in the linear pressure. In the present invention, polyurethane rubber is used for the conductive rubber layer 12b of the developing roller 12, but the conductive silicone rubber or the like having a relatively low hardness and containing a small amount of low molecular weight oligomers, and thus the photosensitive drum 12 is less contaminated. May be adopted and the through holes 12d ... May be provided. Although the metal shaft 12a is used as the support, a resin shaft or the like may be used as long as the bias voltage can be supplied, and in the method of directly supplying the bias voltage to the elastic layer, the support need not be conductive. .

【0037】ところで、導電性ゴム層に本発明と同等の
導電性ウレタンゴムを使用し、外径8mmの金属シャフ
トに肉厚5mmのゴムを配置し現像ローラを試作した。
ゴム硬度は42°の素材を使用したがローラ成型後の硬
度は約46°(JIS硬度)となった。
By the way, a developing roller was manufactured by using a conductive urethane rubber equivalent to the present invention for the conductive rubber layer, arranging a rubber having a thickness of 5 mm on a metal shaft having an outer diameter of 8 mm.
A rubber hardness of 42 ° was used, but the hardness after roller molding was about 46 ° (JIS hardness).

【0038】このローラを接触型1成分現像装置11に
装着し実施例と同様の試験を行なったところ図5に示す
結果となり、印字濃度ムラとトナーの破壊特性上両立す
る荷重領域が存在せず、さらには印字濃度ムラが0.2
になる荷重12g/mmの状態でプリントを繰り返した
ところ約3000枚で感光体にトナーのフィルミングが
発生画像上に著しいノイズを引き起こした。
When this roller was attached to the contact type one-component developing device 11 and the same test as in the example was conducted, the result shown in FIG. 5 was obtained, and there was no load area compatible with the uneven print density and the toner destruction characteristics. In addition, print density unevenness is 0.2
When the printing was repeated under a load of 12 g / mm, the toner filming occurred on the photoconductor after about 3000 sheets, and remarkable noise was generated on the image.

【0039】図6にトナー粒径分布のストレスによる変
化を示す。実線はストレスを受ける前の分布図であり、
点線は感光体1と現像ローラのストレスによりトナーに
破壊および凝集が発生し分布が大きく変動した状態を示
す。
FIG. 6 shows changes in toner particle size distribution due to stress. The solid line is the distribution map before receiving stress,
The dotted line shows the state where the toner is destroyed and aggregated due to the stress of the photoconductor 1 and the developing roller, and the distribution is largely changed.

【0040】図7に破壊凝集により分布が崩れたトナー
が画像時にカブリに与える影響を示したものであり、分
布の崩れ度合いを示す1例のパラメータとして12.5
μm以上トナ−の体積分布比率を用いた。
FIG. 7 shows the influence of the toner whose distribution has been destroyed due to destructive aggregation on the fog during image formation. As an example of the parameter indicating the degree of distribution collapse, 12.5 is shown.
The volume distribution ratio of the toner of μm or more was used.

【0041】[0041]

【発明の効果】本発明は以上説明したように、現像剤供
給部材を心材と、この心材に被覆されるゴム硬度を40
°以上とする高分子弾性体とにより構成し、前記高分子
弾性体に前記心材の長手方向に沿う貫通孔を前記心材の
周方向に亘って複数個設け、この現像剤供給部材を前記
像担持体に対し1〜10g/mmの接触圧力で接触させ
るから、像担持体を汚染することないとともに、印字濃
度ムラなどの画像劣化のない良好な画像を提供できると
いう効果を奏する。
As described above, according to the present invention, the developer supplying member is the core material, and the hardness of the rubber coated on the core material is 40.
And a plurality of through holes extending in the longitudinal direction of the core material are provided in the polymer elastic body in the circumferential direction of the core material, and the developer supply member is provided with the image carrying member. Since the image carrier is brought into contact with the body at a contact pressure of 1 to 10 g / mm, there is an effect that a good image can be provided without contaminating the image carrier and without image deterioration such as unevenness in printing density.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例である画像形成装置の一部を
示す構成図。
FIG. 1 is a configuration diagram illustrating a part of an image forming apparatus that is an embodiment of the present invention.

【図2】図1の画像形成装置における現像装置の現像ロ
−ラを示す斜視図。
FIG. 2 is a perspective view showing a developing roller of a developing device in the image forming apparatus of FIG.

【図3】図2の現像ロ−ラを示す側断面図。FIG. 3 is a side sectional view showing the developing roller of FIG.

【図4】図1の画像形成装置における感光体と現像ロ−
ラとの接触圧と印字濃度むらおよび12.7μm以上の
トナ−体積分布比率との関係を示すグラフ図。
4 is a diagram showing a photosensitive member and a developing roller in the image forming apparatus of FIG.
FIG. 6 is a graph showing the relationship between the contact pressure with the toner, the print density unevenness, and the toner-volume distribution ratio of 12.7 μm or more.

【図5】従来の画像形成装置における感光体と現像ロ−
ラとの接触圧と印字濃度むらおよび12.7μm以上の
トナ−体積分布比率との関係を示すグラフ図。
FIG. 5 is a diagram illustrating a photosensitive member and a developing roller in a conventional image forming apparatus.
FIG. 6 is a graph showing the relationship between the contact pressure with the toner, the print density unevenness, and the toner-volume distribution ratio of 12.7 μm or more.

【図6】従来の画像形成装置におけるトナ−粒子系分布
を示すグラフ図。
FIG. 6 is a graph showing toner-particle system distribution in a conventional image forming apparatus.

【図7】従来の画像形成装置における粗大トナ−と画像
カブリの関係を示すグラフ図。
FIG. 7 is a graph showing the relationship between a coarse toner and image fog in a conventional image forming apparatus.

【符号の説明】 1…感光体(像担持体)、12…現像ロ−ラ(現像剤供
給部材)、18…ブレ−ド(現像剤層形成部材)、12
a…金属シャフト(心材)、12b…弾性体層(高分子
弾性体)、12d…貫通孔。
DESCRIPTION OF SYMBOLS 1 ... Photosensitive member (image bearing member), 12 ... Developing roller (developer supply member), 18 ... Blade (developer layer forming member), 12
a ... Metal shaft (core material), 12b ... Elastic layer (polymer elastic body), 12d ... Through hole.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 福田 善行 神奈川県川崎市幸区柳町70番地 東芝イン テリジェントテクノロジ株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Yoshiyuki Fukuda 70, Yanagimachi, Saiwai-ku, Kawasaki-shi, Kanagawa Toshiba Intelligent Technology Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 潜像を担持する像担持体と、 この像担持体に接触され、現像剤を供給して前記潜像を
現像する弾性の現像剤供給部材と、 この現像剤供給部材に接触され該現像剤供給部材上に現
像剤の薄層を形成する可撓性の現像剤層形成部材と、 を具備し、 前記現像剤供給部材は心材と、この心材に被覆されるゴ
ム硬度を40°以上とする高分子弾性体とからなり、前
記高分子弾性体に前記心材の長手方向に沿う貫通孔を前
記心材の周方向に亘って複数個有し、前記像担持体に対
し1〜10g/mmの接触圧力で接触されることを特徴
とする現像装置。
1. An image bearing member carrying a latent image, an elastic developer supplying member which is brought into contact with the image bearing member and supplies a developer to develop the latent image, and a developer supplying member. A flexible developer layer forming member for forming a thin layer of the developer on the developer supplying member, wherein the developer supplying member has a core material and a rubber hardness of 40%. And a plurality of through-holes extending in the longitudinal direction of the core material in the circumferential direction of the core material, and 1 to 10 g relative to the image carrier. A developing device which is contacted with a contact pressure of / mm.
【請求項2】 潜像を担持する像担持体と、 この像担持体に潜像を形成する像形成手段と、 前記像担持体に接触され、現像剤を供給して前記潜像を
現像する弾性の現像剤供給部材と、 この現像剤供給部材に接触され該現像剤供給部材上に現
像剤の薄層を形成する可撓性の現像剤層形成部材と、 を具備し、 前記現像剤供給部材は心材と、この心材に被覆されるゴ
ム硬度を40°以上とする高分子弾性体とからなり、前
記高分子弾性体に前記心材の長手方向に沿う貫通孔を前
記心材の周方向に亘って複数個有し、前記像担持体に対
し1〜10g/mmの接触圧力で接触されることを特徴
とする画像形成装置。
2. An image bearing member carrying a latent image, an image forming means for forming a latent image on the image bearing member, and a developer supplied to the image bearing member to develop the latent image. An elastic developer supplying member; and a flexible developer layer forming member which is in contact with the developer supplying member and forms a thin layer of the developer on the developer supplying member. The member is composed of a core material and a polymer elastic body having a rubber hardness of 40 ° or more with which the core material is covered, and a through hole along the longitudinal direction of the core material is provided in the polymer elastic body in the circumferential direction of the core material. An image forming apparatus having a plurality of the above, and being brought into contact with the image carrier at a contact pressure of 1 to 10 g / mm.
JP23603093A 1993-09-22 1993-09-22 Developing device and image forming apparatus provided with the developing device Expired - Lifetime JP2930508B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23603093A JP2930508B2 (en) 1993-09-22 1993-09-22 Developing device and image forming apparatus provided with the developing device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23603093A JP2930508B2 (en) 1993-09-22 1993-09-22 Developing device and image forming apparatus provided with the developing device

Publications (2)

Publication Number Publication Date
JPH0792792A true JPH0792792A (en) 1995-04-07
JP2930508B2 JP2930508B2 (en) 1999-08-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP23603093A Expired - Lifetime JP2930508B2 (en) 1993-09-22 1993-09-22 Developing device and image forming apparatus provided with the developing device

Country Status (1)

Country Link
JP (1) JP2930508B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007041228A (en) * 2005-08-02 2007-02-15 Konica Minolta Business Technologies Inc Elastic body roller and developing device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007041228A (en) * 2005-08-02 2007-02-15 Konica Minolta Business Technologies Inc Elastic body roller and developing device

Also Published As

Publication number Publication date
JP2930508B2 (en) 1999-08-03

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