JPH0784587B2 - Stabilizer redispersion method - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of redispersing a stabilizing solution used for ground excavation in an excavation method for civil engineering and construction work.

[0002]

2. Description of the Related Art Stabilizers include bentonite and carboxymethyl cellulose (hereinafter abbreviated as CMC) as main components, and if necessary, a dispersant such as sodium polyacrylate, a lignin derivative, a humic acid salt, and a surfactant. It is in the form of a slurry. So-called "bentonite stabilizer", which contains a large amount of bentonite (6-10%), was the mainstream, but in recent years there are many large-scale construction projects such as LNG storage tanks and high-rise buildings. "Polymer stabilizing solution" with a large amount of compounding is popular. Compared to "Bentonite Stabilizer", "Polymer Stabilizer" has better fluidity of slurry, is more resistant to contamination of salt and cement components, and fungus-resistant grade CMC is mainly used for spoilage. There are difficult advantages.

In addition, slime is rarely generated, and it is difficult for contaminants to adhere to buried objects. For example, it has various properties superior to the "bentonite stabilizer". However, regarding the treatment method of the once deteriorated stabilizer, it remains as a difficult problem for the contractor like "bentonite stabilizer". As the excavation depth becomes deeper, silt and clay soil is mixed into the stable liquid, and effective separation in the stable liquid cannot be achieved even with the sediment separator, and the specific gravity of the stable liquid becomes extremely high It often happens that the components such as bentonite and CMC adhere to a large amount of mixed soil particles, and the performance of the original stabilizing solution quickly declines.
In addition, the degree of contamination by cement components due to the mixing of ions from groundwater and the mixing of seawater, and the increase in the amount of concrete placed is also under severe conditions, and not only the high specific gravity of the stabilizing solution, It causes a serious deterioration of performance such as loss of fluidity and increase of drainage.

The stable liquid deteriorated to such an extent that it cannot be used as described above is reused as much as possible, or is discarded if it cannot be regenerated. With respect to disposal, due to the recent increase in environmental problems, the disposal site has been limited, and the cost is increased, so that it is required to recycle as much as possible. Separation of mixed sediment,
Water dilution, addition of dispersant (sodium polyacrylate, lignin derivative salt, polymer surfactant, sodium carbonate, etc.), CM
Various methods such as re-addition of C are adopted according to the properties of the deterioration stabilizer. However, with either method, it is usually difficult to recover the original performance and reuse it in a single process,
It is performed by combining several processes. That is, only by diluting with water or treating with a dispersant, the fluidity can be recovered but the amount of drainage cannot be reduced. On the other hand, just by adding CMC again, the amount of drainage can be reduced, but the fluidity cannot be sufficiently improved.
Both processes are often used together.

As described above, the conventional reprocessing method is complicated, laborious and costly. Therefore, there is a demand for an effective reprocessing method that can be applied to a wide range in a single process. . The invention of JP-B-49-46763 shows a stabilizing solution which is a combination of CMC and sodium polyacrylate, but the present invention is further improved to limit to a specific CMC produced from regenerated cellulose. At the same time, by limiting the amount ratio of CMC, sodium polyacrylate, and sodium carbonate, it is intended to provide a reusable method of re-dispersing a stable liquid having higher performance.

[0006]

SUMMARY OF THE INVENTION In view of the actual situation of the civil engineering industry, the present inventors have prepared a deterioration stabilizing liquid as a conventional single product, or adjusting the deterioration stabilizing liquid as a single product. CMC used for reproduction,
Each of them is treated separately, not only when each is used alone as a mixture of sodium polyacrylate and sodium carbonate with certain physical properties, and by using a mixture in which they are mixed at a certain mixing ratio. It was discovered that the regenerating function for the deterioration stabilizing solution is significantly superior to the case of combining with.

The effect of CMC in the stabilizing solution is mainly to impart viscosity and reduce the amount of drainage, but in many cases, gel viscosity is relaxed or specific gravity is reduced in the properties of the deterioration stabilizing solution. Generally, the effect of lowering it is small. Although a slight dispersion effect may be exhibited by decreasing the degree of polymerization of CMC or increasing the degree of etherification to a certain degree, sodium polyacrylate, a lignin derivative salt, which is known as a so-called dispersion peptizer, Compared with humates, hexametaphosphates, tripolyphosphates, polymeric surfactants, etc., their effects are much smaller, and they cannot fulfill their purpose in terms of fluidity recovery.

On the other hand, sodium polyacrylate is CMC.
Although the effect of dispersing the deterioration stabilizing solution is greater than that of No. 1, there is almost no effect of reducing the amount of drainage. Sodium carbonate has been used for a long time in petroleum boring, etc., but recently it is often added to civil engineering foundation work for the purpose of preventing spoilage of stable liquids and preventing contamination of stable liquids by cement contamination and harmful metal ions. is there. These three substances have different characteristics, and are added at the time of preparing the stabilizing solution according to the purpose.

However, the deterioration stabilizing solution containing excavated soil and a large amount of mixed salts has complicated properties, and the expected effect is not always exhibited. Therefore, as a result of various studies on a method capable of recovering all the performances of the deterioration stabilizing solution as a single treatment agent, A: the average degree of polymerization produced from regenerated cellulose is 500 or less, preferably 300 or less and the average degree of substitution is 0.6-0.9M /
CMC of C _6, B: powdery sodium polyacrylate having an average polymerization degree of 20 to 100, C: sodium carbonate, the above-mentioned three substances A: 25 to 75 parts by weight, B: 25 to 50 parts by weight,
It was found that by adding the powder mixture mixed in the ratio of C: 5 to 25 parts by weight to the deterioration stabilizing solution in an amount of 0.05 to 1.0%, preferably 0.1 to 0.4%, an unprecedented regeneration effect can be obtained. CMC produced from ordinary pulp was also examined as A, but the average degree of polymerization was 100 to 300, the average degree of etherification was 0.65.
In the case of ~ 0.75, there was some effect, but the rot resistance and salt resistance were temporary and insufficient, and they were lower than those of regenerated cellulose.

The CMC used in the present invention is preferably regenerated cellulose, particularly rayon regenerated from viscose, but it may also be regenerated from bemberg dissolved in copper ammonia. Regenerated cellulose has a very homogeneous crystal structure, and CMC produced using it as a raw material is C produced from ordinary pulp.
Carboxymethylation reaction progresses more uniformly than MC, and the resulting aqueous solution of CMC has fluidity, film-forming property, salt resistance,
It has excellent rot resistance and cement stain resistance. This CM
When C is used as a reprocessing agent for the deterioration stabilizing solution, it is generally C
MC is effective in the usual average degree of substitution of 0.5 to 1.5 M / C ₆ , but the one having an average degree of substitution of 0.6 to 0.9 M / C ₆ shows a remarkable effect.

[0011]

The present invention will be described below with reference to examples, but the present invention is not limited thereto.

Example 1 At the excavation construction site by the stable liquid circulation method (BW method),
After excavating 5 elements, the deterioration stabilizing solution stored in the waste stabilizing solution storage tank was passed through a mud separator (mixed sediment separating machine), and was collected while circulating the inside of the tank with a pump. A predetermined amount of the additive shown in Table 1 was added to the collected deterioration stabilizing solution, and the performance of the stabilizing solution was measured. The performance was judged to be better as the apparent viscosity of the deterioration stabilizing solution measured by a B-type rotational viscometer was smaller and the drainage amount was smaller.

[0013]

[Table 1]

Example 2 At a construction site for an underground continuous wall, a waste stabilization liquid (deterioration stabilization liquid within 5 m from the contact surface between concrete and the stabilization liquid) generated during concrete pouring was sampled, and a mixture A of 0.3% was collected. The results of addition and regeneration are shown in Table 2.

Example 3 The stabilizing solution collected from the underground continuous wall construction site contained CaCl ₂ and Ca (O
H) ₂ is added and 0.2% of the mixture B is artificially deteriorated.
The results of addition and regeneration are shown in Table 3.

Description of Tables CMC: CMC manufactured from regenerated cellulose (rayon KD-4-15, manufactured by Daiwa Spinning Co., Ltd.) was used as a raw material in a solvent of isopropyl alcohol to perform mercerization and etherification at the same time. PA: Sodium polyacrylate DP: Average degree of polymerization DS: Average degree of substitution

[0017]

[0018]

Measurement method DP: Number average degree of polymerization of 0.1M NaCl solution by osmotic pressure method DS: Alkali ash method (CMC Industry Association method) Specific gravity: Measured by mud balance PH: Measured by glass electrode PH meter Apparent viscosity: BM type rotational viscometer Viscosity value 100cp or more, No2 rotor 60rpm 100cp or less, No1 rotor 60rpm Drainage: 3kg / cm ² with a pressure filtration device according to API standard
Filtration volume after 0 minutes (ml)

[0020]

As shown in the above examples, by adding CMC produced from regenerated cellulose and specific sodium polyacrylate and sodium carbonate to specify the compounding ratio,
The stabilizing solution can be reused and the present invention has been completed.

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Yasuhiko Furusawa 2-1-1, Tobita-cho, Chofu-shi, Tokyo Kashima Construction Co., Ltd. Technical Research Institute (72) Inventor Hiroyuki Asahina 2--19-1, Nakahara-cho, Kawagoe-shi, Saitama No. (72) Inventor Chifuku Inafuku, No.143 Yufutsu, Tomakomai City, Hokkaido No. 6 (56) References Japanese Patent Publication Sho 49-46763 (JP, B1)

Claims (2)

[Claims] 1. An average degree of polymerization of 50 produced from regenerated cellulose with respect to a deteriorated stabilizing solution in the stabilizing solution excavation method.
0 or less, 25 to 75 parts by weight of sodium carboxymethyl cellulose having an average degree of substitution of 0.6 to 0.9 M / C ₆ , and an average degree of polymerization of 20 to
A mixture of 25 to 50 parts by weight of 100 sodium polyacrylate and 5 to 25 parts by weight of sodium carbonate (total 100 parts by weight) is added to 0.05 to 50 parts by weight.
A method for dispersing a reusable stabilizer, which comprises adding 1.0%. 2. The stable liquid dispersion method according to claim 1, wherein the regenerated cellulose is cellulose regenerated from viscose.