JPH0757554B2 - Sublimation transfer type Hardcopy transfer material - Google Patents
Sublimation transfer type Hardcopy transfer materialInfo
- Publication number
- JPH0757554B2 JPH0757554B2 JP60294862A JP29486285A JPH0757554B2 JP H0757554 B2 JPH0757554 B2 JP H0757554B2 JP 60294862 A JP60294862 A JP 60294862A JP 29486285 A JP29486285 A JP 29486285A JP H0757554 B2 JPH0757554 B2 JP H0757554B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- dye receiving
- layer
- transfer
- receiving layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
- B41M5/506—Intermediate layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B41M5/5272—Polyesters; Polycarbonates
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、昇華転写方式によるハードコピー用被転写体
に関する。Description: TECHNICAL FIELD The present invention relates to a transfer material for hard copy by a sublimation transfer method.
本発明は、基材と１層又は多層の染料受容層を有する昇
華転写式ハードコピー用印画紙において、少くとも最上
層の染料受容層を構成する樹脂層の主成分としてビスフ
エノール骨格を有する樹脂を選び、且つ樹脂層の樹脂の
ガラス転移点Tgを55℃以上とすることにより、転写後の
保存安定性に優れた印画紙を得ることができるようにし
たものである。The present invention relates to a sublimation transfer type hardcopy printing paper having a substrate and one or more dye receiving layers, and a resin having a bisphenol skeleton as a main component of a resin layer constituting at least the uppermost dye receiving layer. And the glass transition point Tg of the resin of the resin layer is set to 55 ° C. or higher so that a photographic paper excellent in storage stability after transfer can be obtained.
従来の昇華転写式ハードコピー用被転写紙（印画紙）
は、紙、合成紙、プラスチツクフイルム等の基材上にポ
リエチレンテレフタレート等のポリエステル樹脂を主成
分とする染料受容層が形成されて構成されている。一般
にポリエステル樹脂は、昇華性染料の染着性が良く、通
常の保存状態では安定性も優れている。Conventional sublimation transfer type hard copy transfer paper (printing paper)
Is constructed by forming a dye receiving layer containing a polyester resin such as polyethylene terephthalate as a main component on a substrate such as paper, synthetic paper, plastic film and the like. Generally, a polyester resin has a good dyeing property for a sublimable dye, and also has excellent stability under normal storage conditions.
ポリエチレンテレフタレート等のポリエステル樹脂を主
成分とする染料受容層が形成された従来の被転写紙は、
通常の保存状態においては安全性に優れているが、高
温、多湿の状態に置かれた場合、例えば夏季に窓際や車
中に放置された場合に染料が移行して他の被転写紙を汚
染したりするため安定性に問題が生じていた。そして、
このような問題点を解決するために、従来表面保護層と
してのラミネートフイルムの形成等の特別な処理を施し
ていた。A conventional transfer paper on which a dye receiving layer containing a polyester resin such as polyethylene terephthalate as a main component is formed is
It is excellent in safety under normal storage conditions, but when it is placed in high temperature and high humidity conditions, for example, when it is left in the window or in the car in the summer, the dye migrates and contaminates other transfer paper. Therefore, there was a problem in stability. And
In order to solve such a problem, conventionally, a special treatment such as forming a laminate film as a surface protective layer has been performed.
本発明は、上述の点に鑑みて、高温多湿状態であつても
保存安定性に優れた昇華転写式ハードコピー用被転写体
を提供するものである。In view of the above points, the present invention provides a sublimation transfer type transfer material for a hard copy, which is excellent in storage stability even in a high temperature and high humidity state.
本発明は、基材（１）とこの基材（１）上に形成された
１層又は多層の染料受容層（２）を有する昇華転写式ハ
ードコピー用被転写紙（３）において、少くとも最上層
（インクリボンと接触する層）の染料受容層（2a）は、
ビスフエノール骨格を有する樹脂を主体とした樹脂層と
し、且つこの樹脂層のガラス転移点Tgを55℃以上とす
る。ビスフエノール骨格とは、次のような構造式を有す
る骨格を指す。The present invention provides a sublimation transfer type hardcopy transfer paper (3) having at least a substrate (1) and one or multiple dye receiving layers (2) formed on the substrate (1), at least The uppermost layer (layer in contact with the ink ribbon), the dye receiving layer (2a),
The resin layer is mainly composed of a resin having a bisphenol skeleton, and the glass transition point Tg of the resin layer is 55 ° C. or higher. The bisphenol skeleton refers to a skeleton having the following structural formula.
このようなビスフエノール骨格を有する樹脂の名称と構
造式の例を下記に挙げる。 Examples of the names and structural formulas of resins having such a bisphenol skeleton are given below.
ビスフエノール型エポキシ樹脂 ポリカーボネイト フエノキシ（ビスフエノールＡ型エポキシの高分子量
物） ポリアリレート ポリサルホン ビスフエノール骨格を有する樹脂は、最上層の樹脂層の
全量に対して70wt％以上含有させる。70wt％より低い場
合には、昇華性染料の吸着性、保存安定性が低下するの
で好ましくない。最上層の樹脂層中にビスフエノール骨
格を有する樹脂以外の樹脂、例えばポリエステル、エポ
キシ、ナイロン、酢酸セルロースを30wt％までの範囲で
含有させることができるが、この場合にも樹脂層として
のガラス転移点Tgは55℃以上となるようにする。Bisphenol epoxy resin Polycarbonate Phenoxy (high molecular weight bisphenol A type epoxy) Polyarylate Polysulfone The resin having a bisphenol skeleton is contained in an amount of 70 wt% or more based on the total amount of the uppermost resin layer. If it is less than 70 wt%, the adsorptivity of the sublimable dye and the storage stability are deteriorated, which is not preferable. Resins other than resins having a bisphenol skeleton, such as polyester, epoxy, nylon, and cellulose acetate, can be contained in the uppermost resin layer in the range of up to 30 wt%. The point Tg should be 55 ° C or higher.
また、必要に応じて最上層の樹脂層中に充填材（例え
ば、SiO2、TiO2、CaCO3等）、紫外線吸収剤、酸化防止
剤、螢光増白剤、界面活性剤等を含有させることができ
る。In addition, a filler (eg, SiO 2 , TiO 2 , CaCO 3, etc.), an ultraviolet absorber, an antioxidant, a fluorescent brightening agent, a surfactant, etc. may be contained in the uppermost resin layer, if necessary. be able to.
また、染料受容層（２）を多層構造、例えば２層構造と
する場合には、基材（１）上にポリエステル樹脂より成
る染料受容層（2b）そしてこの上にビスフエノール骨格
を有する樹脂を主体とし、且つガラス転移点Tgを55℃以
上とした樹脂層より成る染料受容層（2a）を形成するこ
とにより構成することができる。このように染料受容層
（２）を２層構造とした場合、上層の染料受容層（2a）
は、0.5〜5.0μの厚さに形成することができる。When the dye receiving layer (2) has a multi-layer structure, for example, a two-layer structure, a dye receiving layer (2b) made of a polyester resin is formed on the substrate (1), and a resin having a bisphenol skeleton is formed on the dye receiving layer (2b). It can be constituted by forming the dye receiving layer (2a) which is mainly composed of a resin layer having a glass transition point Tg of 55 ° C. or higher. When the dye receiving layer (2) has a two-layer structure as described above, the upper dye receiving layer (2a)
Can be formed to a thickness of 0.5 to 5.0 μ.
ビスフエノール骨格を有する樹脂は、昇華性染料の吸着
性が強く、使用温度がガラス転移点Tg以下であれば優れ
た保存安定性を示す。従つて、本発明において、最上層
の染料受容層の主成分をビスフエノール骨格を有する樹
脂とし、且つ樹脂層のガラス転移点Tgを55℃以上とした
ことにより、通常の状態よりも高温多湿の条件下におい
ても安定な保存状態が維持される。従つて、濃度を向上
させるために、例えばポリエステル樹脂を混合させても
良いが、この場合にも樹脂層全体のガラス転移点Tgは55
℃以上とする必要がある。しかし、たとえガラス転移点
Tgが55℃以上であつても、ポリエステルの割合が30wt％
を超えるとポリエステルの性質が強く現われるようにな
り、保存安定性が劣つてくるため、ビスフエノール骨格
を有する樹脂は、樹脂層の全量に対して70wt％以上含有
させる。A resin having a bisphenol skeleton has a strong adsorptivity for sublimable dyes and exhibits excellent storage stability if the temperature of use is equal to or lower than the glass transition point Tg. Therefore, in the present invention, the main component of the dye receiving layer of the uppermost layer is a resin having a bisphenol skeleton, and the glass transition point Tg of the resin layer is 55 ° C. or higher, so that the temperature and humidity are higher than in a normal state. A stable storage state is maintained even under the conditions. Therefore, in order to improve the concentration, for example, a polyester resin may be mixed, but in this case also, the glass transition point Tg of the entire resin layer is 55.
It must be above ℃. But even if the glass transition point
Even if Tg is 55 ℃ or higher, the proportion of polyester is 30wt%
If it exceeds, the properties of the polyester will be strongly exhibited and the storage stability will be poor. Therefore, the resin having a bisphenol skeleton is contained in an amount of 70 wt% or more based on the total amount of the resin layer.
実施例１ 第１図に示すように、フエノトートYP−50（東都化成、
フエノキシ樹脂、Tg100℃）を溶剤に溶解し、基材
（１）となるアート紙上に乾燥後の厚さが10μとなるよ
うに塗布して、基材（１）と染料受容層（2a）より成る
昇華転写式ハードコピー用被転写体（３）を作製した。Example 1 As shown in FIG. 1, Phenotooth YP-50 (Tohto Kasei,
(Phenoxy resin, Tg100 ℃) is dissolved in a solvent and applied on art paper to be the base material (1) so that the thickness after drying becomes 10μ. From the base material (1) and the dye receiving layer (2a) Sublimation transfer type transfer material for hard copy (3) was prepared.
実施例２ 第１図に示すように、パンライトL1225（帝人化成、ポ
リカーボネイト樹脂、Tg145℃）を溶剤に溶解し、基材
（１）となるアート紙上に乾燥後の厚さが10μとなるよ
うに塗布して、基材（１）と染料受容層（2a）より成る
本発明に係る被転写体（３）を作製した。Example 2 As shown in FIG. 1, Panlite L1225 (Teijin Kasei, polycarbonate resin, Tg 145 ° C.) was dissolved in a solvent so that the thickness after drying was 10 μm on the art paper as the base material (1). Then, the material to be transferred (3) according to the present invention comprising the substrate (1) and the dye receiving layer (2a) was prepared.
実施例３ Ｕ−100（ユニチカ、ポリアリレート樹脂、Tg190℃）を
使用して実施例１と同様に樹脂層を形成し、染料受容層
（2a）と基材（１）より成る被転写体（３）を作製し
た。Example 3 A resin layer was formed in the same manner as in Example 1 by using U-100 (Unitika, polyarylate resin, Tg 190 ° C.), and a transferred material comprising the dye receiving layer (2a) and the substrate (1) ( 3) was produced.
実施例４ エポトートYD−012（東都化成、ビスフエノールＡ型エ
ポキシ樹脂、Tg60℃）を使用して実施例１と同様に樹脂
層を形成し、染料受容層（2a）と基材（１）より成る被
転写体（３）を作製した。Example 4 A resin layer was formed in the same manner as in Example 1 using Epotote YD-012 (Tohto Kasei, bisphenol A type epoxy resin, Tg 60 ° C.), and the dye receiving layer (2a) and the substrate (1) were used. A transfer target (3) was prepared.
実施例５ エポトートYD−017（東都化成、エポキシ樹脂、Tg77
℃）を使用して実施例１と同様に樹脂層を形成し、染料
受容層（2a）と基材（１）より成る被転写体（３）を作
製した。Example 5 Epototo YD-017 (Tohto Kasei, epoxy resin, Tg77
C.) was used to form a resin layer in the same manner as in Example 1 to prepare a transferred material (3) comprising the dye receiving layer (2a) and the substrate (1).
実施例６ エポトートYD−014（東都化成、ビスフエノールＡ型エ
ポキシ樹脂、Tg65℃）９重量部とTP−219（日本合成化
学工業、ポリエステル樹脂、Tg40℃）１重量部を混合し
た樹脂（Tg62℃）を使用して実施例１と同様に樹脂層を
形成し、染料受容層（2a）と基材（１）より成る被転写
体（３）を作製した。Example 6 9 parts by weight of Epotote YD-014 (Tohto Kasei, bisphenol A type epoxy resin, Tg 65 ° C.) and 1 part by weight of TP-219 (Nippon Gosei Kagaku Kogyo Co., Ltd., polyester resin, Tg 40 ° C.) (Tg 62 ° C.) Was used to form a resin layer in the same manner as in Example 1 to prepare a transferred body (3) including the dye receiving layer (2a) and the substrate (1).
実施例７ エポトートYD−012（Tg60℃）７重量部とUE−3300（ユ
ニチカ、ポリエステル樹脂、Tg50℃）３重量部を混合し
た樹脂（Tg57℃）を使用して実施例１と同様に樹脂層を
形成し、染料受容層（2a）と基材（１）より成る被転写
体（３）を作製した。Example 7 A resin layer was prepared in the same manner as in Example 1 using a resin (Tg57 ° C.) in which 7 parts by weight of Epotote YD-012 (Tg60 ° C.) and 3 parts by weight of UE-3300 (Unitika, polyester resin, Tg50 ° C.) were mixed. Was formed to prepare a transferred body (3) comprising the dye receiving layer (2a) and the substrate (1).
実施例８ エポトートYD−014（東都化成、ビスフエノールＡ型エ
ポキシ樹脂、Tg65℃）７重量部とMH−101−２（藤倉化
成、ポリメタクリル酸メチル、Tg105℃）３重量部を混
合した樹脂（Tg75℃）を使用して実施例１と同様に樹脂
層を形成し、染料受容層（2a）と基材（１）より成る被
転写体（３）を作製した。Example 8 7 parts by weight of Epotote YD-014 (Tohto Kasei, bisphenol A type epoxy resin, Tg65 ° C.) and 3 parts by weight of MH-101-2 (Fujikura Kasei, polymethylmethacrylate, Tg105 ° C.) ( A resin layer was formed in the same manner as in Example 1 using Tg75 ° C.) to prepare a transferred material (3) including the dye receiving layer (2a) and the base material (1).
実施例９ 第２図に示すように、溶剤に溶解したバイロン＃200
（東洋紡、ポリエステル樹脂、Tg67℃）を基材（１）上
に乾燥後の厚さが10μとなるように塗布して１層目の染
料受容層（2b）を形成した後、この上にフエノトートYP
−50（Tg100℃）７重量部とUE−3300（Tg50℃）３重量
部を混合した樹脂（Tg83℃）を使用して乾燥後の厚さが
１μとなるように塗布して２層目の染料受容層（2a）を
形成し、２層の染料受容層（２）より成る被転写体
（３）を得る。Example 9 As shown in FIG. 2, Byron # 200 dissolved in a solvent
(Toyobo, polyester resin, Tg 67 ° C) is applied on the substrate (1) so that the thickness after drying becomes 10μ to form the first dye receiving layer (2b), and then the phenotooth is formed on this. YP
-50 (Tg100 ° C) 7 parts by weight and UE-3300 (Tg50 ° C) 3 parts by weight mixed resin (Tg83 ° C) is used to apply a thickness of 1μ after drying, and the second layer is applied. A dye receiving layer (2a) is formed to obtain a transferred material (3) consisting of two dye receiving layers (2).
比較例１ バイロン＃200（東洋紡、ポリエステル樹脂、Tg67℃）
を溶剤に溶解し、基材となるアート紙上に乾燥後の厚さ
が10μとなるように塗布して、基材と染料受容層より成
る、比較例に係る昇華転写式ハードコピー用被転写体を
作製した。Comparative Example 1 Byron # 200 (Toyobo, polyester resin, Tg67 ℃)
Is dissolved in a solvent and applied onto art paper as a base material so that the thickness after drying becomes 10 μm, and comprises a base material and a dye receiving layer. Was produced.
比較例２ XA5535（ユニチカ（株）、ポリエステル樹脂、Tg105
℃）を使用して比較例１と同様に樹脂層を形成し、染料
受容層と基材より成る被転写紙を作製した。Comparative Example 2 XA5535 (Unitika Ltd., polyester resin, Tg105
C.) was used to form a resin layer in the same manner as in Comparative Example 1 to prepare a transfer paper comprising a dye receiving layer and a substrate.
比較例３ エポトートYD−011（東都化成、ビスフエノールＡ型エ
ポキシ樹脂、Tg50℃）を使用して比較例１と同様に樹脂
層を形成し、染料受容層と基材より成る被転写紙を作製
した。Comparative Example 3 Using Epototo YD-011 (Tohto Kasei, bisphenol A type epoxy resin, Tg 50 ° C.), a resin layer was formed in the same manner as in Comparative Example 1 to prepare a transfer paper consisting of a dye receiving layer and a substrate. did.
比較例４ エポトートYD−012（東都化成、ビスフエノールＡ型エ
ポキシ樹脂、Tg60℃）７重量部とTP−219（日本合成化
学工業、ポリエステル樹脂、Tg40℃）３重量部を混合し
た樹脂（Tg53℃）を使用して比較例１と同様に樹脂層を
形成し、染料受容層と基材より成る被転写体を作製し
た。Comparative Example 4 7 parts by weight of Epotote YD-012 (Tohto Kasei, bisphenol A type epoxy resin, Tg 60 ° C.) and 3 parts by weight of TP-219 (Nippon Gosei Kagaku Kogyo Co., Ltd., polyester resin, Tg 40 ° C.) (Tg 53 ° C.) ) Was used to form a resin layer in the same manner as in Comparative Example 1 to prepare a transferred material comprising a dye receiving layer and a substrate.
被転写体の評価 下記組成を有するインクを調製し、厚さ10μの基材とな
るコンデンサ紙上に乾燥後の厚さが１μとなるように塗
布してインクリボンを作製した。Evaluation of Transfer Target An ink ribbon having the following composition was prepared and applied onto a condenser paper as a base material having a thickness of 10 μm to a dry thickness of 1 μm to prepare an ink ribbon.
このインクリボンを使用し、上記実施例１〜９に係る被
転写体及び比較例１〜４に係る被転写体に対して感熱ヘ
ツドで印字を行い、印字サンプルを得た。そして第３図
に示すように印字サンプル（４）の印字面にアート紙
（５）を密着させた後、65℃で相対湿度（RH）80％、55
℃で相対湿度（RH）85％、40℃で相対湿度（RH）90％の
雰囲気中にそれぞれ１週間放置してエージングを行つ
た。エージング後、アート紙上に移行した染料の濃度を
マクベス濃度計で測定した。無地のアート紙上の汚染濃
度が0.03より小さい値であれば、目視によって汚染（再
転写）が識別されず、0.03以上の値であれば目視によっ
て汚染（再転写）が識別できる。従って、アート紙上の
汚染濃度が0.03より下の印字サンプルを○、0.03以上の
印字サンプルを×として、測定結果を下記の表に示す。 Using this ink ribbon, printing was performed on the transfer-receiving members according to Examples 1 to 9 and the transfer-receiving members according to Comparative Examples 1 to 4 with a thermal head to obtain printed samples. Then, as shown in FIG. 3, after the art paper (5) was brought into close contact with the print surface of the print sample (4), relative humidity (RH) 80%, 55
Aging was performed by leaving it in an atmosphere of 85% relative humidity (RH) at 40 ° C. and 90% relative humidity (RH) at 40 ° C. for one week each. After aging, the concentration of the dye transferred onto the art paper was measured with a Macbeth densitometer. If the contamination density on the plain art paper is less than 0.03, the contamination (retransfer) cannot be visually identified, and if it is 0.03 or more, the contamination (retransfer) can be visually identified. Therefore, the measurement results are shown in the following table, with the print sample having a stain concentration of less than 0.03 on the art paper as ○ and the print sample having the stain concentration of 0.03 or more as x.
〔発明の効果〕 本発明によれば、最上層の染料受容層は、ビスフエノー
ル骨格を有する樹脂を主体とした樹脂層であり、且つこ
の樹脂層のガラス転移点Tgを55℃以上としたことによ
り、染料受容層の染料吸着性が高まるため、通常の保存
状態よりも高温多湿の状態であつても安定性に優れた高
品位の画像が保持される。従つて、従来のような特別な
表面保護膜（ラミネートフイルム等）は不要になる。 [Effect of the Invention] According to the present invention, the uppermost dye receiving layer is a resin layer mainly composed of a resin having a bisphenol skeleton, and the glass transition point Tg of the resin layer is 55 ° C. or more. As a result, the dye-adsorbing property of the dye-receiving layer is enhanced, so that a high-quality image having excellent stability can be retained even in a high temperature and high humidity state as compared with a normal storage state. Therefore, a special surface protective film (laminate film, etc.) as in the prior art is unnecessary.
第１図及び第２図は実施例の断面図、第３図は測定方法
を示す断面図である。 （１）は基材、（２）〔（2a），（2b）〕は染料受容
層、（３）は被転写体である。1 and 2 are sectional views of the embodiment, and FIG. 3 is a sectional view showing a measuring method. (1) is a base material, (2) [(2a), (2b)] is a dye receiving layer, and (3) is a transferred material.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 篠原 悟 栃木県鹿沼市さつき町18番地 ソニーケミ カル株式会社鹿沼工場内 (72)発明者 菅井 直喜 栃木県鹿沼市さつき町18番地 ソニーケミ カル株式会社鹿沼工場内 (56)参考文献 特開 昭60−25793（ＪＰ，Ａ) 特開 昭60−19138（ＪＰ，Ａ) 特開 昭59−214696（ＪＰ，Ａ) 特開 昭59−133098（ＪＰ，Ａ) 特開 昭48−24811（ＪＰ，Ａ) ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Satoru Shinohara 18 Satsuki Town, Kanuma City, Tochigi Prefecture, within the Sony Chemical Chemical Kanuma Plant (72) Inventor Naoki Sugai 18, Satsuki Town, Kanuma City, Tochigi Prefecture Sony Chemical Chemical Kanuma Plant (56) References JP-A-60-25793 (JP, A) JP-A-60-19138 (JP, A) JP-A-59-214696 (JP, A) JP-A-59-133098 (JP, A) JP-A-48-24811 (JP, A)
Claims (1)
層の染料受容層を有する昇華転写式ハードコピー用被転
写体において、 少なくとも最上層の染料受容層は、ビスフェノール骨格
を有する樹脂を樹脂層全量に対し70wt％以上含有した樹
脂層であり、且つ該樹脂層のガラス転移点Tgは55℃以上
であることを特徴とする昇華転写式ハードコピー用被転
写体。1. A sublimation transfer type hardcopy transfer material having a substrate and one or multiple dye receiving layers formed on the substrate, wherein at least the uppermost dye receiving layer has a bisphenol skeleton. A sublimation transfer type transfer material for hard copy, which is a resin layer containing 70% by weight or more of the resin contained therein with respect to the total amount of the resin layer, and has a glass transition point Tg of 55 ° C. or more.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60294862A JPH0757554B2 (en) | 1985-12-27 | 1985-12-27 | Sublimation transfer type Hardcopy transfer material |
| DE8686310185T DE3680498D1 (en) | 1985-12-27 | 1986-12-24 | PRINTED PAPER. |
| EP19860310185 EP0228301B1 (en) | 1985-12-27 | 1986-12-24 | Printing paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60294862A JPH0757554B2 (en) | 1985-12-27 | 1985-12-27 | Sublimation transfer type Hardcopy transfer material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62152897A JPS62152897A (en) | 1987-07-07 |
| JPH0757554B2 true JPH0757554B2 (en) | 1995-06-21 |
Family
ID=17813214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60294862A Expired - Lifetime JPH0757554B2 (en) | 1985-12-27 | 1985-12-27 | Sublimation transfer type Hardcopy transfer material |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0228301B1 (en) |
| JP (1) | JPH0757554B2 (en) |
| DE (1) | DE3680498D1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7117808B1 (en) * | 2022-03-17 | 2022-08-15 | 株式会社サンエーテック | Support pedestal for rebar beams |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4775657A (en) * | 1987-06-16 | 1988-10-04 | Eastman Kodak Company | Overcoat for dye image-receiving layer used in thermal dye transfer |
| JP2764273B2 (en) * | 1988-06-03 | 1998-06-11 | 株式会社リコー | Image receiving medium for sublimation thermal transfer recording |
| JP2557983B2 (en) * | 1989-07-07 | 1996-11-27 | 帝人株式会社 | Manufacturing method of recording sheet for thermal transfer |
| JPH0292592A (en) * | 1988-09-29 | 1990-04-03 | Teijin Ltd | Thermal transfer sheet for recording |
| GB8826457D0 (en) * | 1988-11-11 | 1988-12-14 | Ici Plc | Thermal transfer receiver |
| US5294484A (en) * | 1991-08-03 | 1994-03-15 | Sony Corporation | Polyvinyl aromatic carboxylic acid ester and video printing paper |
| US5244862A (en) * | 1992-07-31 | 1993-09-14 | Bailey David B | Thermal dye transfer receiving element with modified bisphenol-A epichlorohydrin polymer dye-image receiving layer |
| US20080254382A1 (en) | 2007-03-27 | 2008-10-16 | Fujifilm Corporation | Heat-sensitive transfer sheet and image-forming method |
| US8012909B2 (en) | 2007-03-27 | 2011-09-06 | Fujifilm Corporation | Heat-sensitive transfer image-forming method |
| US8129309B2 (en) | 2007-03-29 | 2012-03-06 | Fujifilm Corporation | Heat-sensitive transfer sheet for use in heat-sensitive transfer system and image-forming method using heat-sensitive transfer system |
| EP1974948A3 (en) | 2007-03-29 | 2012-02-08 | FUJIFILM Corporation | Image-forming method using heat-sensitive transfer system |
| JP4878327B2 (en) | 2007-03-30 | 2012-02-15 | 富士フイルム株式会社 | Thermal transfer image-receiving sheet and method for producing the same |
| JP2008273641A (en) | 2007-04-25 | 2008-11-13 | Fujifilm Corp | Cardboard cylinder for heat-sensitive transfer image-receiving sheet, roll shape machined article and image forming method of the sheet |
| US11977395B2 (en) | 2016-03-24 | 2024-05-07 | Teledyne Flir Defense, Inc. | Persistent aerial communication and control system |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5937237B2 (en) * | 1980-12-22 | 1984-09-08 | 富士化学紙工業株式会社 | thermal transfer recording medium |
| JPS5945184A (en) * | 1982-09-09 | 1984-03-13 | Sony Corp | Ink ribbon for heat sensitive transfer recording |
| JPS59133098A (en) * | 1983-01-19 | 1984-07-31 | Matsushita Electric Ind Co Ltd | Image-receiving body for sublimation-type heat-sensitive recording |
| JPS59199295A (en) * | 1983-04-28 | 1984-11-12 | Sony Corp | Ink composition for ink ribbon used for sublimation transfer type copying |
| JPS59214696A (en) * | 1983-05-20 | 1984-12-04 | Ricoh Co Ltd | Thermal transfer accepting sheet |
| JPS6019138A (en) * | 1983-07-13 | 1985-01-31 | Konishiroku Photo Ind Co Ltd | Image receiving element for thermal transfer |
| JPS6025793A (en) * | 1983-07-25 | 1985-02-08 | Dainippon Printing Co Ltd | Sheet for heat transfer printing |
| JPS6038192A (en) * | 1983-08-10 | 1985-02-27 | Kanzaki Paper Mfg Co Ltd | Image receiving sheet for thermal transfer recording |
| JPS62152795A (en) * | 1985-12-26 | 1987-07-07 | Sony Chem Kk | Ink ribbon for sublimation transfer type hard copying |
-
1985
- 1985-12-27 JP JP60294862A patent/JPH0757554B2/en not_active Expired - Lifetime
-
1986
- 1986-12-24 DE DE8686310185T patent/DE3680498D1/en not_active Expired - Lifetime
- 1986-12-24 EP EP19860310185 patent/EP0228301B1/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7117808B1 (en) * | 2022-03-17 | 2022-08-15 | 株式会社サンエーテック | Support pedestal for rebar beams |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3680498D1 (en) | 1991-08-29 |
| EP0228301A3 (en) | 1988-12-14 |
| JPS62152897A (en) | 1987-07-07 |
| EP0228301A2 (en) | 1987-07-08 |
| EP0228301B1 (en) | 1991-07-24 |
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