JPH0749342A - Gas exposure indication paper - Google Patents
Gas exposure indication paperInfo
- Publication number
- JPH0749342A JPH0749342A JP19588393A JP19588393A JPH0749342A JP H0749342 A JPH0749342 A JP H0749342A JP 19588393 A JP19588393 A JP 19588393A JP 19588393 A JP19588393 A JP 19588393A JP H0749342 A JPH0749342 A JP H0749342A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- gas
- ozone
- indicator
- exposure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、特定の種類のガスに暴
露されて変色するガス暴露指示紙に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a gas exposure indicator which changes color when exposed to a specific type of gas.
【0002】[0002]
【従来の技術】近年、病院内での感染(院内感染)、特
にMRSA(マーサ)による院内感染が大きな社会問題
となっている。このような院内感染を防止するためオゾ
ンを用いた消毒装置の開発が行われている。2. Description of the Related Art In recent years, nosocomial infections in hospitals (nosocomial infections), particularly nosocomial infections due to MRSA (Martha), have become a major social problem. In order to prevent such nosocomial infections, a disinfection device using ozone is being developed.
【0003】この種の装置は、オゾンを室内や容器内に
供給した後、触媒からなるオゾンキラーでオゾンを分解
するようになっている。In this type of apparatus, after supplying ozone into a room or a container, ozone is decomposed by an ozone killer composed of a catalyst.
【0004】[0004]
【発明が解決しようとする課題】ところでオゾンは強力
な殺菌消毒力を有する反面、微量でも長時間吸入すると
人体に有害な気体である。このため、オゾンを用いた消
毒装置を使用する場合には、使用後の残留オゾンの濃度
やどれだけオゾン処理されたか等を検知する必要があ
る。オゾンの濃度の検知にはオゾンモニタが使用され
る。On the other hand, ozone has a strong sterilizing and disinfecting power, but on the other hand, ozone is a harmful gas to the human body when inhaled for a long time even in a minute amount. Therefore, when using a disinfection device using ozone, it is necessary to detect the concentration of residual ozone after use, how much ozone treatment has been performed, and the like. An ozone monitor is used to detect the concentration of ozone.
【0005】しかしながら、オゾンモニタは高価で、携
帯して使用するには不便な面がある。However, the ozone monitor is expensive and inconvenient to carry and use.
【0006】そこで、本発明の目的は、上記課題を解決
し、低コストで携帯が容易なガス暴露指示紙を提供する
ことにある。SUMMARY OF THE INVENTION Therefore, an object of the present invention is to solve the above problems and provide a gas exposure indicator paper which is low in cost and easy to carry.
【0007】[0007]
【課題を解決するための手段】上記目的を達成するため
に本発明は、特定の種類のガスに暴露されて変色する細
長の指示紙を、透明フィルムで覆い、その細長の指示紙
の一端に、外気に触れる暴露部を形成したものである。In order to achieve the above object, the present invention is to cover an elongated indicator paper, which is exposed to a specific type of gas and discolors, with a transparent film, and attach it to one end of the elongated indicator paper. The exposed part is exposed to the outside air.
【0008】また、本発明は、指示紙が、特定の種類の
ガスと反応する指示薬と、その指示薬をゲル化する化合
物とを含んでいるものである。In the present invention, the indicator paper contains an indicator which reacts with a specific type of gas and a compound which gels the indicator.
【0009】[0009]
【作用】上記構成によれば、特定の種類のガスの雰囲気
内でガス暴露指示紙の暴露部を所定時間晒すことによ
り、暴露部がガスで暴露され、ガスが指示紙の一端から
内部に拡散すると共に指示紙が変色するので、この変色
域の長さを読み取ることによりガスの強度を容易に検知
することができる。ガス暴露指示紙は、指示紙と透明フ
ィルムとからなっているだけなのでコストが低くかつ携
帯が極めて容易となる。According to the above construction, by exposing the exposed portion of the gas exposure indicator paper for a predetermined time in an atmosphere of a specific type of gas, the exposed portion is exposed to the gas and the gas diffuses from one end of the indicator paper to the inside. At the same time, since the indicator paper changes color, the intensity of the gas can be easily detected by reading the length of this color change area. The gas exposure indicator paper is low in cost and extremely easy to carry because it consists only of an indicator paper and a transparent film.
【0010】また、指示紙が、特定の種類のガスと反応
する指示薬と、その指示薬をゲル化する化合物とを含ん
でいるので、ゲル化した指示薬が保湿材として機能し、
ガス状の酸化性物質に対しても指示紙を水に濡らす必要
がなくなり、正確なオゾン強度の検知を行うことができ
る。Further, since the indicator paper contains an indicator that reacts with a specific type of gas and a compound that gels the indicator, the gelled indicator functions as a moisturizer.
It is not necessary to wet the indicator paper with water even for a gaseous oxidative substance, and accurate ozone strength can be detected.
【0011】[0011]
【実施例】以下、本発明の一実施例を添付図面に基づい
て詳述する。An embodiment of the present invention will be described in detail below with reference to the accompanying drawings.
【0012】図1(a)は本発明のガス暴露指示紙の一
実施例の平面図であり、図1(b)はそのA−A線断面
図である。FIG. 1 (a) is a plan view of an embodiment of the gas exposure indicator paper of the present invention, and FIG. 1 (b) is a sectional view taken along the line AA.
【0013】図1(a)及び図1(b)において、1は
オゾンガスの通過を阻止する材料からなる長尺状の透明
フィルム(例えばセロハンテープ)である。透明フィル
ム1の上には、透明フィルム1より幅及び長さが短い長
尺状のヨウ化カリウム澱粉紙2が1枚貼付けられてい
る。ヨウ化カリウム澱粉紙2は、オゾンガスに暴露され
ると変色するようになっている。尚、指示紙としてのヨ
ウ化カリウム澱粉紙2は図では1枚であるが2枚以上で
あってもよい。In FIGS. 1 (a) and 1 (b), reference numeral 1 is a long transparent film (eg, cellophane tape) made of a material that blocks passage of ozone gas. On the transparent film 1, one piece of a long potassium iodide starch paper 2 having a width and a length shorter than that of the transparent film 1 is attached. The potassium iodide starch paper 2 is designed to change color when exposed to ozone gas. Incidentally, the potassium iodide starch paper 2 as the instruction paper is one sheet in the figure, but it may be two or more sheets.
【0014】ここで、ヨウ化カリウム澱粉紙2は、酸化
剤を含む溶液に対して青紫色に呈色する古くから知られ
ている試験紙である。例えばヨウ化カリウム3gと可溶
性澱粉5gとを溶かした1リットルの溶液に濾紙を浸
し、乾燥させて作るものである。Here, the potassium iodide starch paper 2 is a test paper that has been known for a long time and exhibits a blue-violet color with respect to a solution containing an oxidizing agent. For example, it is prepared by immersing a filter paper in 1 liter of a solution prepared by dissolving 3 g of potassium iodide and 5 g of soluble starch and drying it.
【0015】透明フィルム1及びヨウ化カリウム澱粉紙
2の上には、透明フィルム1と同一形状の透明フィルム
3が貼付けられている。この透明フィルム3は、使用時
にその一部(図の左側)3aを手で除去することができ
るようになっている。この透明フィルムの一部3aを除
去することにより、ヨウ化カリウム澱粉紙2の一端、す
なわち暴露部2aだけ外気に触れるようになっている。
すなわち、この透明フィルム3は、未使用時にはヨウ化
カリウム澱粉紙2を密封してオゾンガスに暴露されるの
を阻止し、使用時にはヨウ化カリウム澱粉紙2の暴露部
2aだけ外気に触れるようになっている。On the transparent film 1 and the potassium iodide starch paper 2, a transparent film 3 having the same shape as the transparent film 1 is attached. This transparent film 3 can be manually removed at a part (left side in the drawing) 3a during use. By removing a part 3a of the transparent film, only one end of the potassium iodide starch paper 2, that is, the exposed part 2a is exposed to the outside air.
That is, the transparent film 3 seals the potassium iodide starch paper 2 when not in use to prevent it from being exposed to ozone gas, and when used, only the exposed portion 2a of the potassium iodide starch paper 2 comes into contact with the outside air. ing.
【0016】透明フィルム3の上には暴露部2aの境界
線を基準とした目盛り4が記されており、オゾンの暴露
量を示すようになっている。尚、目盛り4は透明フィル
ム3の上に記されているが、透明フィルム1の上に記し
てあってもよい。A scale 4 based on the boundary line of the exposed portion 2a is provided on the transparent film 3 so as to indicate the exposure amount of ozone. Although the scale 4 is written on the transparent film 3, it may be printed on the transparent film 1.
【0017】次に実施例の作用を述べる。Next, the operation of the embodiment will be described.
【0018】オゾンガスの雰囲気内で、ガス暴露指示紙
の暴露部2a上の透明フィルム3の一部3aを除去し、
所定の時間晒すことにより、ヨウ化カリウム澱粉紙2の
暴露部2aがオゾンガスで暴露され、オゾンガスがこの
暴露部2aから内部に拡散すると共にヨウ化カリウム澱
粉紙2が変色する。この変色域の長さは、オゾンガスの
暴露量に対応しており(暴露量は強度の時間積分に等し
いため)、この変色域の長さ目盛り4で読み取ることに
よりオゾンガスの強度を容易に検知することができる。
ガス暴露指示紙は、ヨウ化カリウム澱粉紙2と透明フィ
ルム1、3とからなっているだけなのでコストが低く、
かつ、携帯が容易となる。In an atmosphere of ozone gas, a part 3a of the transparent film 3 on the exposed portion 2a of the gas exposure indicator paper is removed,
By exposing the potassium iodide starch paper 2 for a predetermined time, the exposed portion 2a of the potassium iodide starch paper 2 is exposed to ozone gas, and the ozone gas diffuses from the exposed portion 2a to the inside and the potassium iodide starch paper 2 is discolored. The length of this color change area corresponds to the exposure amount of ozone gas (since the exposure amount is equal to the time integral of the intensity), the intensity of ozone gas can be easily detected by reading the length scale 4 of this color change area. be able to.
The gas exposure indicator paper consists of potassium iodide starch paper 2 and transparent films 1 and 3, so the cost is low,
And it becomes easy to carry.
【0019】(具体例)図2は本実施例のガス暴露指示
紙を用いてオゾン強度を測定した結果を示す図であり、
横軸がオゾン強度を示し、縦軸が変色長さを示してい
る。(Concrete Example) FIG. 2 is a diagram showing the result of measuring ozone strength using the gas exposure indicator paper of this embodiment.
The horizontal axis represents ozone intensity and the vertical axis represents discoloration length.
【0020】オゾナイザからのオゾンガスを、密封した
コンテナ内に導入し、その中にガス暴露指示紙を入れて
目盛りを読み取った。オゾン強度は環境用オゾンモニタ
で計測した。オゾン強度は4条件(500、400、3
00、30ppm)で行った。ヨウ化カリウム澱粉紙2
の幅は約2mmとした。Ozone gas from the ozonizer was introduced into a sealed container, and a gas exposure indicator was put in the container to read the scale. Ozone intensity was measured with an environmental ozone monitor. Ozone intensity has 4 conditions (500, 400, 3
00, 30 ppm). Potassium iodide starch paper 2
Has a width of about 2 mm.
【0021】同図に示すように、暴露したオゾン強度が
異なっていてもオゾン強度と変色長さがほぼ一つの曲線
にのっているのがわかる。As shown in the figure, it can be seen that the ozone intensity and the discoloration length are on one curve even if the exposed ozone intensity is different.
【0022】この曲線より変色長さに対するオゾン強度
の関係がわかる。従って、変色長さをオゾン強度に換算
し、得られた数値を目盛り4上に記すことにより直接オ
ゾン強度を読み取ることができる。From this curve, the relationship between ozone strength and discoloration length can be seen. Therefore, the ozone strength can be directly read by converting the discoloration length into ozone strength and writing the obtained numerical value on the scale 4.
【0023】ところで、ガス暴露指示紙を用いてオゾン
ガスの強度を検知する際に直接オゾンガスに暴露する
と、ヨウ化カリウム澱粉紙が乾燥したままであるため、
明確な青紫の呈色は示さず、やや薄い茶褐色に変色す
る。このため水に濡らした方が明確な青紫色の呈色を示
す。By the way, when the strength of ozone gas is detected by using the gas exposure indicator paper, if it is directly exposed to ozone gas, the potassium iodide starch paper remains dry.
No clear bluish-purple coloration was observed, and the color changed to a slightly dark brown. For this reason, a clear blue-violet coloration is exhibited when it is wet with water.
【0024】しかしながら、水の中に酸化性物質が含ま
れていた場合、反応を起こしてしまい正確な指示を示さ
なくなる。However, when an oxidizing substance is contained in water, a reaction occurs and an accurate indication cannot be given.
【0025】そこで本発明者は、ヨウ化カリウム澱粉紙
を製作する際に、指示薬としてのヨウ化カリウムにゲル
化するような化合物(高分子吸収ポリマ)を加えて、指
示薬を保湿材として機能させることを試みた。これによ
り、ガス状の酸化性物質に対しても水に濡らすことな
く、明確なヨウ素澱粉反応を示し変色するので、正確な
オゾン強度の検知を行うことができる。Therefore, the present inventor, when producing potassium iodide starch paper, adds a compound that gels to potassium iodide as an indicator (polymer absorption polymer) so that the indicator functions as a moisturizer. Tried that. As a result, even a gaseous oxidizing substance shows a clear iodine starch reaction and changes color without getting wet with water, so that the ozone intensity can be accurately detected.
【0026】以上において本実施例によれば、特定の種
類のガスに暴露されて変色する細長の指示紙を、透明フ
ィルムで覆い、その細長の指示紙の一端に、外気に触れ
る暴露部を形成したので、低コストで携帯が容易なガス
暴露指示紙を実現することができる。また、指示紙が、
特定の種類のガスと反応する指示薬と、その指示薬をゲ
ル化する化合物とを含んでいるので、指示薬が保湿材と
して機能し、ガス状の酸化性物質に対しても指示紙を水
に濡らす必要がなくなり、正確なオゾン強度の検知を行
うことができる。As described above, according to the present embodiment, the elongated indicator paper which changes color when exposed to a specific type of gas is covered with a transparent film, and an exposed portion exposed to the outside air is formed at one end of the elongated indicator paper. Therefore, it is possible to realize a gas exposure indicator paper which is low in cost and easy to carry. In addition, the instruction paper
Since it contains an indicator that reacts with a specific type of gas and a compound that gels the indicator, the indicator functions as a moisturizer, and it is necessary to wet the indicator paper with water even for a gaseous oxidizing substance Is eliminated, and the ozone intensity can be accurately detected.
【0027】尚、本実施例では特定の種類のガスとして
オゾンガスを用い、指示紙としてヨウ化カリウム澱粉紙
を用いた場合で説明したが、これらに限定されるもので
はなく、指示紙が特定の種類のガスに暴露されて変色す
るのであれば他の種類の指示紙を用いてもよいのはいう
までもない。In this embodiment, ozone gas is used as the specific type of gas and potassium iodide starch paper is used as the indicator paper, but the present invention is not limited to these, and the indicator paper is not limited to this. It goes without saying that other types of indicator paper may be used as long as they are exposed to a type of gas and discolor.
【0028】[0028]
【発明の効果】以上要するに本発明によれば、次のよう
な優れた効果を発揮する。In summary, according to the present invention, the following excellent effects are exhibited.
【0029】(1) 低コストで携帯が容易なガス暴露指示
紙を実現することができる。(1) It is possible to realize a gas exposure indicator that is low in cost and easy to carry.
【0030】(2) 指示紙を水に濡らすことなく正確なオ
ゾン強度の検知を行うことができる。(2) Ozone intensity can be accurately detected without wetting the indicator paper with water.
【図1】(a)は本発明のガス暴露指示紙の一実施例の
平面図であり、(b)はそのA−A線断面図である。FIG. 1 (a) is a plan view of an embodiment of a gas exposure indicator paper of the present invention, and FIG. 1 (b) is a sectional view taken along the line AA.
【図2】本実施例のガス暴露指示紙を用いてオゾン強度
を測定した結果を示す図である。FIG. 2 is a diagram showing a result of measuring ozone strength using the gas exposure indicator paper of the present embodiment.
1、3 透明フィルム 2 指示紙(ヨウ化カリウム澱粉紙) 2a 暴露部 1, 3 Transparent film 2 Indicator paper (potassium iodide starch paper) 2a Exposed part
Claims (2)
細長の指示紙を、透明フィルムで覆い、その細長の指示
紙の一端に、外気に触れる暴露部を形成したことを特徴
とするガス暴露指示紙。1. A gas characterized in that an elongated indicator paper that changes color when exposed to a specific type of gas is covered with a transparent film, and an exposed portion exposed to the outside air is formed at one end of the elongated indicator paper. Exposure instruction paper.
する指示薬と、その指示薬をゲル化する化合物とを含ん
でいることを特徴とするガス暴露指示紙。2. The gas exposure indicator paper, wherein the indicator paper contains an indicator that reacts with a gas of a specific type and a compound that gels the indicator.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19588393A JP3239548B2 (en) | 1993-08-06 | 1993-08-06 | Gas exposure instruction paper |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19588393A JP3239548B2 (en) | 1993-08-06 | 1993-08-06 | Gas exposure instruction paper |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0749342A true JPH0749342A (en) | 1995-02-21 |
JP3239548B2 JP3239548B2 (en) | 2001-12-17 |
Family
ID=16348577
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP19588393A Expired - Fee Related JP3239548B2 (en) | 1993-08-06 | 1993-08-06 | Gas exposure instruction paper |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3239548B2 (en) |
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WO2004104573A1 (en) * | 2003-05-20 | 2004-12-02 | Sakura Color Products Corporation | Indicator composition |
WO2008001834A1 (en) * | 2006-06-29 | 2008-01-03 | Sakura Color Products Corporation | Laminate type oxidizing-gas indicator and method of detecting oxidizing gas |
JP2008513783A (en) * | 2004-09-22 | 2008-05-01 | ケー アンド エム エンヴァイロメンタル インコーポレイテッド ドゥーイング ビジネス アズ モルフィックス テクノロジーズ | Method and apparatus for detecting exposure to hazardous substances |
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CN106093295A (en) * | 2016-06-17 | 2016-11-09 | 深圳九星印刷包装集团有限公司 | Carbon dioxide sensitization time instruction device |
JP2018004391A (en) * | 2016-06-30 | 2018-01-11 | 共同印刷株式会社 | Time indicator |
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-
1993
- 1993-08-06 JP JP19588393A patent/JP3239548B2/en not_active Expired - Fee Related
Cited By (15)
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---|---|---|---|---|
KR100354564B1 (en) * | 1999-12-24 | 2002-10-05 | 주식회사 엔바이온 | The tape and patch type detector for investigating leakage of fuel gas |
KR100389067B1 (en) * | 2000-02-24 | 2003-06-25 | 이후근 | Acidic and alkalic gas detecting and operating method on outlet of off-gas treatment equipment |
WO2004104573A1 (en) * | 2003-05-20 | 2004-12-02 | Sakura Color Products Corporation | Indicator composition |
JP2008513783A (en) * | 2004-09-22 | 2008-05-01 | ケー アンド エム エンヴァイロメンタル インコーポレイテッド ドゥーイング ビジネス アズ モルフィックス テクノロジーズ | Method and apparatus for detecting exposure to hazardous substances |
WO2008001834A1 (en) * | 2006-06-29 | 2008-01-03 | Sakura Color Products Corporation | Laminate type oxidizing-gas indicator and method of detecting oxidizing gas |
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