JPH0748154A - Fiber-reinforced concrete - Google Patents
Fiber-reinforced concreteInfo
- Publication number
- JPH0748154A JPH0748154A JP19382793A JP19382793A JPH0748154A JP H0748154 A JPH0748154 A JP H0748154A JP 19382793 A JP19382793 A JP 19382793A JP 19382793 A JP19382793 A JP 19382793A JP H0748154 A JPH0748154 A JP H0748154A
- Authority
- JP
- Japan
- Prior art keywords
- carbon fiber
- fiber
- reinforced concrete
- silicone rubber
- fine particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、強度特性に優れた炭素
繊維強化コンクリ−トに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a carbon fiber reinforced concrete having excellent strength characteristics.
【０００２】[0002]
【従来の技術】炭素繊維補強コンクリ−トは耐熱、耐
火、耐水性を備え、軽量で強度に優れる等の特徴を有す
る材料として注目され、建築、土木用などへの利用、応
用が近年盛んに行われている。2. Description of the Related Art Carbon fiber reinforced concrete has attracted attention as a material having heat resistance, fire resistance, water resistance, light weight and excellent strength, and has recently been actively used and applied for construction and civil engineering. Has been done.
【０００３】炭素繊維は、従来からコンクリ−ト補強用
に用いられている石綿やガラス繊維に比べ、マトリック
スへの接着性や分散性が劣るため、これらの特性を改善
し、得られる炭素繊維強化コンクリ−トの強度を高める
ための様々な工夫が行われている。例えば、特開昭６２
−１０８７５５号公報には、炭素繊維の表面に、カチオ
ン性のスチレンブタジェン系ゴムラテックスを付着させ
ることが開示されている。Carbon fibers have inferior adhesiveness and dispersibility to a matrix as compared with asbestos and glass fibers which have been conventionally used for concrete reinforcement. Therefore, these properties are improved and the obtained carbon fiber reinforced. Various measures have been taken to increase the strength of the concrete. For example, Japanese Patent Laid-Open No. Sho 62
Japanese Patent Publication No. 108755 discloses that a cationic styrene butadiene rubber latex is attached to the surface of carbon fiber.
【０００４】[0004]
【発明が解決しようとする課題】しかしながら、炭素繊
維にゴムを付着させるためには、炭素繊維を予め酸化処
理する必要があり、未処理の炭素繊維の場合はコンクリ
−トへの接着性やコンクリ−トの中での分散性が悪かっ
た。However, in order to attach the rubber to the carbon fiber, it is necessary to oxidize the carbon fiber in advance, and in the case of untreated carbon fiber, the adhesion to the concrete and the concrete -The dispersibility in the market was poor.
【０００５】このような現状を鑑み、本発明は、これら
従来からある方法のような制約がなく、しかも炭素繊維
のマトリックスへの接着性や分散性を高め、ひいては強
度に優れた炭素繊維強化コンクリ−トを目的としてなさ
れた発明である。In view of the above situation, the present invention is not restricted by these conventional methods, and the adhesion and dispersibility of the carbon fiber to the matrix are enhanced, and by extension, the carbon fiber reinforced concrete is excellent in strength. -It is an invention made for the purpose of g.
【０００６】[0006]
【課題を解決するための手段】本発明は、ＥＳＣＡ法に
より測定されるＯ1s／Ｃ1sピーク比が０．１０未満であ
る炭素繊維にシリコンゴム微粒子が保持されている炭素
繊維を、セメント系マトリックスに分散させたことを特
徴とする繊維補強コンクリ−トにある。According to the present invention, a carbon fiber having an O 1s / C 1s peak ratio measured by ESCA of less than 0.10. A fiber reinforced concrete characterized by being dispersed in a matrix.
【０００７】以下、本発明を詳細に説明する。本発明で
用いる炭素繊維としては、公知の炭素繊維であれば特に
限定されることなく使用できるが、特に本発明において
は補強コンクリ−トの高強度化が主たる目的でありた
め、補強材料である炭素繊維としては、より高強度であ
ることが望ましい。従って、汎用的で、且つ高い強度特
性の得られやすいポリアクリロニトリル系炭素繊維が好
ましい。The present invention will be described in detail below. The carbon fiber used in the present invention is not particularly limited as long as it is a known carbon fiber, but it is a reinforcing material because the main purpose of the present invention is to increase the strength of the reinforcing concrete. It is desirable that the carbon fiber has higher strength. Therefore, a polyacrylonitrile-based carbon fiber that is versatile and easily obtains high strength characteristics is preferable.
【０００８】さらに、本発明で用い得る炭素繊維は、Ｅ
ＳＣＡ法により測定されるＯ1s／Ｃ1sピーク比が０．１
０未満のものである。ＥＳＣＡ法により測定されるＯ1s
／Ｃ1sピーク比が０．１０未満の炭素繊維は、ポリアク
リロニトリル系繊維を通常の条件で炭素化することによ
って得られる炭素繊維そのもの、または低度の表面酸化
処理物である。Further, the carbon fiber usable in the present invention is E
The O 1s / C 1s peak ratio measured by the SCA method is 0.1.
It is less than 0. O 1s measured by ESCA method
The carbon fiber having a / C 1s peak ratio of less than 0.10 is the carbon fiber itself obtained by carbonizing the polyacrylonitrile fiber under normal conditions, or a low-grade surface-oxidized product.
【０００９】炭素繊維に対するシリコンゴム微粒子の付
着量は、固形分で０．１〜５重量％の範囲が好ましい。
付着量が０．１重量％より少ないとその効果が発揮され
ず、また、５重量％を超え多過ぎると繊維同志がくっつ
き合いマトリックス中における分散が不十分となり、炭
素繊維補強コンクリ−トとした場合強度特性の向上効果
が得られなくなる。The amount of the silicon rubber fine particles attached to the carbon fibers is preferably in the range of 0.1 to 5% by weight in terms of solid content.
If the amount of adhesion is less than 0.1% by weight, the effect is not exhibited, and if it exceeds 5% by weight and too much, the fibers stick to each other and the dispersion in the matrix becomes insufficient, and the carbon fiber reinforced concrete is obtained. In that case, the effect of improving the strength characteristics cannot be obtained.
【００１０】炭素繊維にシリコンゴム微粒子を付着保持
させる手段としては、シリコンゴム微粒子をアニオン性
界面活性剤を用いて水中に分散させた分散液で処理する
方法が挙げられる。As a means for adhering and holding the silicon rubber fine particles on the carbon fiber, there may be mentioned a method of treating the silicon rubber fine particles with a dispersion liquid which is dispersed in water using an anionic surfactant.
【００１１】アニオン性界面活性剤としては通常、ドデ
シルベンゼンスルホン酸ナトリウムに代表されるスルホ
ン酸塩類や、ラウリル硫酸エステルナトリウム塩に代表
される硫酸エステル塩類、その他カルボン酸塩類、リン
酸エステル塩類などが用いらる。分散液としたときシリ
コンゴム微粒子のζ電位が−３０ｍＶ以下になる様に界
面活性剤の種類、濃度をコントロ−ルする。ζ電位が−
３０ｍＶより高い場合には繊維同志がくっつき合いセメ
ントマトリックス中における分散性が不十分となり、炭
素繊維補強コンクリ−トとした場合強度特性の向上効果
が期待できない。As the anionic surfactant, usually, sulfonates represented by sodium dodecylbenzene sulfonate, sulfate ester salts represented by sodium lauryl sulfate ester, other carboxylates, phosphate ester salts, etc. Use. The type and concentration of the surfactant are controlled so that the ζ potential of the silicon rubber fine particles becomes -30 mV or less when it is used as a dispersion liquid. ζ potential is −
When it is higher than 30 mV, the fibers stick to each other and the dispersibility in the cement matrix becomes insufficient, and when the carbon fiber reinforced concrete is used, the effect of improving the strength characteristics cannot be expected.
【００１２】シリコンゴム微粒子の付着量は、処理剤濃
度や付着方法を適宜工夫することにより調整し、付着後
は通常、乾燥して水分を除去する。これにより、シリコ
ンゴム成分が炭素繊維表面を覆い、更にシリコンゴム被
覆の上に界面活性剤が島状に散在すると考えられる。The amount of the silicone rubber fine particles adhered is adjusted by appropriately devising the concentration of the treating agent and the method of adhesion, and after the adhesion, it is usually dried to remove water. As a result, it is considered that the silicone rubber component covers the surface of the carbon fiber and further the surfactant is scattered on the silicone rubber coating in an island shape.
【００１３】本発明によるシリコンゴムをアニオン性界
面活性剤で分散した分散液を用いて表面処理した炭素繊
維による炭素繊維補強コンクリ−トは、未処理の炭素繊
維を用いたものに比べ、強度特性に優れている。The carbon fiber reinforced concrete of the carbon fiber surface-treated with the dispersion liquid in which the silicone rubber is dispersed with the anionic surfactant according to the present invention has strength characteristics higher than those of the untreated carbon fiber. Is excellent.
【００１４】この向上効果には、炭素繊維の表面に散在
する界面活性剤の静電的特性及びシリコンゴムの接着性
が関与しているものと推定される。つまり、シリコンゴ
ム微粒子の表面処理により炭素繊維同志は反発し合って
分散性が高まり、また処理剤の主成分であるシリコンゴ
ム粒子の作用でマトリックスとの接着性が高まった結
果、補強コンクリ−トの強度特性が向上したものと考え
られる。It is presumed that the electrostatic effect of the surfactant scattered on the surface of the carbon fiber and the adhesive property of the silicone rubber are involved in this improving effect. In other words, the surface treatment of the silicone rubber fine particles repels the carbon fibers to enhance the dispersibility, and the silicone rubber particles, which are the main component of the treatment agent, enhance the adhesiveness with the matrix, resulting in the reinforcement concrete. It is considered that the strength characteristics of are improved.
【００１５】又、本発明による炭素繊維補強コンクリ−
トの強度が高いことは、炭素繊維表面状態が処理剤種と
大きく関わっており、即ち、炭素繊維のＥＳＣＡ法によ
り測定されるＯ1s／Ｃ1sピーク比が０．１０以下である
場合にアニオン性シリコンゴムによる処理が強度特性向
上に有効となる。このとき、カチオン性あるいはノニオ
ン性分散液による処理では向上効果が薄い。The carbon fiber reinforced concrete according to the present invention
The fact that the carbon fiber surface state is greatly related to the kind of the treating agent means that the anion is high when the O 1s / C 1s peak ratio of the carbon fiber measured by the ESCA method is 0.10 or less. The treatment with a conductive silicone rubber is effective in improving the strength characteristics. At this time, the improvement effect is small in the treatment with the cationic or nonionic dispersion liquid.
【００１６】本発明において、処理されたよる炭素繊維
は、補強材料として用いるに当り、従来のように繊維形
態には何らの制限はなく、補強コンクリ−トの強度の製
法に応じて短繊維、長繊維、ストランド状、シート状、
不織布状、織物状など種々な形態で使用でき、ダイレク
トスプレ−法、プレミックス法、含浸法、ハンドレイア
ップ法 抄造など各種方法で施工できる利点を有する。
また、各種水硬性セメントを用いて板状、管状、柱状な
ど各種形状の成形物にすることができる。In the present invention, the treated carbon fiber is used as a reinforcing material, and there is no limitation on the fiber form as in the conventional case, and a short fiber is used depending on the manufacturing method of the strength of the reinforcing concrete. Long fiber, strand, sheet,
It can be used in various forms such as non-woven fabric and woven fabric, and has an advantage that it can be applied by various methods such as direct spray method, premix method, impregnation method, hand lay-up method and papermaking.
In addition, various hydraulic cements can be used to obtain molded products of various shapes such as plate, tube, and column.
【００１７】[0017]
【実施例】次に、実施例により本発明を更に具体的に説
明する。 実施例 繊維直径７μｍ、比重１．７９、引張強度３５０ｋｇｆ
／ｍｍ2 、弾性係数２４×１０3 ｋｇｆ／ｍｍ2 、伸度
１．５％、Ｏ1s／Ｃ1sピーク比が０．０９（表面処理し
ていない通常のもの）の炭素繊維束を、平均粒径０．２
μｍのポリジメチルシロキサンをドデシルベンゼンスリ
ホン酸ナトリウムで分散させたゴム濃度１．０％、ζ電
位−４４ｍＶの分散液に通した後、１２０℃で２分間乾
燥した。EXAMPLES Next, the present invention will be described more specifically by way of examples. Example Fiber diameter 7 μm, specific gravity 1.79, tensile strength 350 kgf
/ Mm 2 , elastic modulus 24 × 10 3 kgf / mm 2 , elongation 1.5%, O 1s / C 1s peak ratio of 0.09 (normal surface-untreated carbon fiber bundles) Particle size 0.2
After passing through a dispersion liquid having a rubber concentration of 1.0% and a zeta potential of -44 mV, which is obtained by dispersing polydimethylsiloxane of μm in sodium dodecylbenzenesulphonate, it was dried at 120 ° C. for 2 minutes.
【００１８】この炭素繊維束を３ｍｍの長さにカット
し、表１に示す配合で炭素繊維補強コンクリ−ト供試体
を作成した。練り混ぜは、繊維混入率１％として１０リ
ットルオムニミキサ−を用いた。This carbon fiber bundle was cut into a length of 3 mm, and a carbon fiber reinforced concrete specimen was prepared with the composition shown in Table 1. For kneading, a 10-liter omni mixer was used with a fiber mixture rate of 1%.
【００１９】[0019]
【表１】 [Table 1]
【００２０】成型後、第１次養生（湿気室で１日）し、
更に材令１日で離型後、第２次養生（３０℃の水中で７
日）を行った。炭素繊維補強コンクリ−トの評価は、タ
テ４ｃｍ、ヨコ１６ｃｍ、厚さ４ｃｍの供試体を用い、
スパン１０ｃｍ、クロスヘッドスピ−ド２ｍｍ／分で中
央集中載荷曲げ試験で行った。その結果は２７３Ｋｇｆ
／ｃｍ2 であった。After molding, the first curing (1 day in a humidity chamber),
After releasing the mold in one day, the second curing (7 ° C in water at 30 ° C)
Sun) went. For the evaluation of the carbon fiber reinforced concrete, a test piece having a length of 4 cm, a width of 16 cm, and a thickness of 4 cm was used.
A center concentrated load bending test was performed with a span of 10 cm and a crosshead speed of 2 mm / min. The result is 273 Kgf
Was / cm 2 .
【００２１】比較例１ 実施例と同様にしてζ電位−１９ｍＶの１．０％濃度の
ノニオン性アクリル・スチレン系分散液を用いて処理し
た炭素繊維を使って炭素繊維補強コンクリ−ト供試体を
作成し曲げ試験を行った。結果は２００Ｋｇｆ／ｃｍ2
であった。Comparative Example 1 A carbon fiber reinforced concrete specimen was prepared by using carbon fibers treated with a 1.0% concentration of nonionic acrylic styrene dispersion liquid having a ζ potential of −19 mV in the same manner as in Example. It was created and a bending test was performed. The result is 200 Kgf / cm 2.
Met.
【００２２】比較例２ 実施例１と同様にして、未処理の炭素繊維を用いて炭素
繊維補強コンクリ−ト供試体を作成し、曲げ試験を行っ
た。結果は２３７Ｋｇｆ／ｃｍ2 であった。Comparative Example 2 In the same manner as in Example 1, a carbon fiber reinforced concrete test piece was prepared using untreated carbon fiber, and a bending test was conducted. The result was 237 Kgf / cm 2 .
フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ０４Ｂ 20:10） 103:44 (72)発明者 今井 義隆 広島県大竹市御幸町20番１号 三菱レイヨ ン株式会社中央研究所内 (72)発明者 武井 吉一 東京都調布市飛田給二丁目19番１号 鹿島 建設株式会社技術研究所内 (72)発明者 末永 龍夫 東京都調布市飛田給二丁目19番１号 鹿島 建設株式会社技術研究所内 (72)発明者 里山 公治 東京都調布市飛田給二丁目19番１号 鹿島 建設株式会社技術研究所内Continuation of front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location C04B 20:10) 103: 44 (72) Inventor Yoshitaka Imai 20-1 Miyuki-cho, Otake-shi, Hiroshima Mitsubishi Rayon Central Research Institute Co., Ltd. (72) Inventor Yoshikazu Takei No. 191-1 Tobita, Chofu-shi, Tokyo Kashima Construction Co., Ltd. Technical Research Institute (72) Inventor Tatsuo Suenaga No. 19-1 Tobita, Chofu-shi, Tokyo Kashima Construction Co., Ltd. Technical Research Institute (72) Inventor Koji Satoyama 2-19-1 Tobita, Chofu City, Tokyo Kashima Construction Co., Ltd. Technical Research Institute
Claims (2)
ピーク比が０．１０未満である炭素繊維にシリコンゴム
微粒子が保持された炭素繊維が、セメント系マトリック
スに分散されていることを特徴とする繊維補強コンクリ
−ト。1. O 1s / C 1s measured by ESCA method
A fiber-reinforced concrete, wherein carbon fibers in which silicon rubber fine particles are held by carbon fibers having a peak ratio of less than 0.10 are dispersed in a cement matrix.
面活性剤で分散させた分散液で処理されたものである請
求項１の繊維補強コンクリ−ト。2. The fiber-reinforced concrete according to claim 1, wherein the carbon fiber is treated with a dispersion liquid in which silicone rubber is dispersed with an anionic surfactant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19382793A JP2757108B2 (en) | 1993-07-12 | 1993-07-12 | Fiber reinforced concrete |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19382793A JP2757108B2 (en) | 1993-07-12 | 1993-07-12 | Fiber reinforced concrete |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0748154A true JPH0748154A (en) | 1995-02-21 |
| JP2757108B2 JP2757108B2 (en) | 1998-05-25 |
Family
ID=16314410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19382793A Expired - Fee Related JP2757108B2 (en) | 1993-07-12 | 1993-07-12 | Fiber reinforced concrete |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2757108B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004076807A1 (en) * | 2003-02-25 | 2004-09-10 | Halliburton Energy Services, Inc. | Cement compositions with improved mechanical properties and methods of cementing in subterranean formations |
| JP2009514700A (en) * | 2005-11-04 | 2009-04-09 | ビービーエイ ブラックブル アクティーゼルスカブ | Reinforcement material for concrete element and method and system for producing reinforced concrete element |
-
1993
- 1993-07-12 JP JP19382793A patent/JP2757108B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004076807A1 (en) * | 2003-02-25 | 2004-09-10 | Halliburton Energy Services, Inc. | Cement compositions with improved mechanical properties and methods of cementing in subterranean formations |
| US6962201B2 (en) | 2003-02-25 | 2005-11-08 | Halliburton Energy Services, Inc. | Cement compositions with improved mechanical properties and methods of cementing in subterranean formations |
| US7351279B2 (en) | 2003-02-25 | 2008-04-01 | Halliburton Energy Services, Inc. | Cement compositions with improved mechanical properties and methods of cementing in subterranean formations |
| JP2009514700A (en) * | 2005-11-04 | 2009-04-09 | ビービーエイ ブラックブル アクティーゼルスカブ | Reinforcement material for concrete element and method and system for producing reinforced concrete element |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2757108B2 (en) | 1998-05-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |