JPH0733507A - Panel material - Google Patents

Panel material

Info

Publication number
JPH0733507A
JPH0733507A JP5199131A JP19913193A JPH0733507A JP H0733507 A JPH0733507 A JP H0733507A JP 5199131 A JP5199131 A JP 5199131A JP 19913193 A JP19913193 A JP 19913193A JP H0733507 A JPH0733507 A JP H0733507A
Authority
JP
Japan
Prior art keywords
panel material
reinforcing material
inorganic
panel
warp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5199131A
Other languages
Japanese (ja)
Inventor
Shinichiro Okada
慎一郎 岡田
Tsugio Chuma
次夫 中馬
Shoji Doi
祥司 土肥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Osaka Gas Co Ltd
Original Assignee
Osaka Gas Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Osaka Gas Co Ltd filed Critical Osaka Gas Co Ltd
Priority to JP5199131A priority Critical patent/JPH0733507A/en
Publication of JPH0733507A publication Critical patent/JPH0733507A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Producing Shaped Articles From Materials (AREA)
  • Finishing Walls (AREA)

Abstract

PURPOSE:To provide a panel material enhanced in the humidity-controlling property, heat resistance, heat-insulating property, etc., large in mechanical strength even when being thin and long, having a light weight, and excellent in applicability. CONSTITUTION:An obliquely meshed reinforcing material is embedded in an inorganic material containing porous inorganic particles such as diatomaceous earth and an inorganic hardening material such as slaked lime. The reinforcing material comprises warps 1 and wefts 2 both comprising resin-impregnated fiber bundles, wherein the plural warps 1 are crossed with the plural wefts 2 at different positions at a crossing angle theta of 90 deg.<theta <=170 deg.. The plural warps constitute the group of the warps extended at distances, respectively, in one direction. The plural wefts 2 constitute the group of the wefts extended at distances, respectively, in a direction crossing with the abovementioned direction.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は壁材や床材などの建築用
内装材などとして有用なパネル材に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a panel material useful as a building interior material such as a wall material or a floor material.

【0002】[0002]

【従来の技術】壁材に広く利用されているケイソウ土
は、調湿性、断熱性、遮音性、脱臭性および電波吸収性
に優れる。そのため、建築用内装材として、コンクリー
ト壁などにおける結露を防止すると共に断熱性などを高
めるため、ケイソウ土を含む種々のパネル材が提案され
ている。例えば、実公昭54−85号公報には、発泡ポ
リスチレンなどの断熱防水性発泡板の片面に、軽量細粒
状骨材、無機又は有機充填剤および合成樹脂エマルジョ
ンを含む吸放湿性塗膜層を形成した化粧板が提案されて
いる。
2. Description of the Related Art Diatomaceous earth, which is widely used for wall materials, is excellent in humidity control, heat insulation, sound insulation, deodorization and radio wave absorption. Therefore, various panel materials including diatomaceous earth have been proposed as an interior material for construction in order to prevent dew condensation on a concrete wall or the like and to improve heat insulating properties. For example, in Japanese Utility Model Publication No. 54-85, a moisture absorptive and desorptive coating layer containing a lightweight fine granular aggregate, an inorganic or organic filler and a synthetic resin emulsion is formed on one side of a heat insulating and waterproof foam plate such as expanded polystyrene. A decorative veneer has been proposed.

【0003】また、特公昭58−46973号公報に
は、発泡スチロールなどの断熱層と、絡み合った繊維の
空隙に多孔質微粉末からなる吸脱水剤を含浸した吸脱水
層と、前記断熱層と吸脱水層との間に介在する遮水層と
で構成された防露層を有する内装材が開示されている。
前記吸脱水層には、ケイソウ土などの多孔質微粉末と、
界面活性剤と、接着剤と、合成樹脂溶液とを混和乳化し
たペースト状塗布剤が使用され、遮水層には水性樹脂エ
マルジョンが使用されている。
In Japanese Patent Publication No. 58-46973, a heat insulating layer such as Styrofoam, a water absorbing / dehydrating layer in which voids of entangled fibers are impregnated with a water absorbing / dehydrating agent made of porous fine powder, and the heat insulating layer and the water absorbing layer are disclosed. An interior material having a dew-proof layer composed of a water-blocking layer and a dehydrating layer is disclosed.
In the water-absorbing and dehydrating layer, a porous fine powder such as diatomaceous earth,
A paste-like coating agent obtained by mixing and emulsifying a surfactant, an adhesive, and a synthetic resin solution is used, and an aqueous resin emulsion is used for the water shield layer.

【0004】さらに、実開昭60−148417号公報
には、ポリエチレンフォームなどからなる基材の面に、
ポリエステルの不織布を介して、ケイソウ土を主剤とす
る無機質の吸水層を形成した建築用壁材が開示されてい
る。
Further, in Japanese Utility Model Publication No. 60-148417, the surface of a substrate made of polyethylene foam or the like is
A building wall material is disclosed in which an inorganic water-absorbing layer containing diatomaceous earth as a main component is formed through a polyester non-woven fabric.

【0005】特開平1−208125号公報には、合成
樹脂発泡体の少なくとも一方の面に、ケイソウ土を含む
無機質層を形成した耐火・耐候性断熱材が開示されてい
る。この先行文献には、無機質層のクラックの発生を防
止し、合成樹脂発泡体との接着性を高めるため、エチレ
ン−酢酸ビニル共重合体エマルジョンを含有させるのが
好ましいことが記載されている。
Japanese Unexamined Patent Publication (Kokai) No. 1-208125 discloses a fireproof / weatherproof heat insulating material in which an inorganic layer containing diatomaceous earth is formed on at least one surface of a synthetic resin foam. This prior document describes that it is preferable to contain an ethylene-vinyl acetate copolymer emulsion in order to prevent the occurrence of cracks in the inorganic layer and enhance the adhesiveness with the synthetic resin foam.

【0006】実開平4−2806号公報には、発泡合成
樹脂製の芯材と、この芯材の両面に塗布された吸湿材と
で構成された断熱板を板材に貼り合せた建築用パネル材
が開示されている。前記吸湿材は、ケイソウ土の焼成粉
末とセルロイドファイバーとバインダーとで構成されて
いる。
Japanese Utility Model Laid-Open No. 4-2806 discloses a construction panel material in which a heat insulating plate composed of a core material made of foamed synthetic resin and a moisture absorbing material applied to both surfaces of the core material is attached to a plate material. Is disclosed. The hygroscopic material is composed of a fired powder of diatomaceous earth, celluloid fiber and a binder.

【0007】しかし、これらの内装材は、いずれも断熱
層が合成樹脂発泡体で形成されているため、耐熱性およ
び耐火性が低い。しかも、吸水層や吸湿材と断熱材との
接着強度を高めたり、吸水層や吸湿材にクラックが生成
するのを防止するためには、接着剤や合成樹脂を必要と
する。例えば、実開昭60−148417号公報に開示
されている建築用壁材では、不織布に無機質の吸水層を
含浸により形成するのが困難であるだけでなく、得られ
た壁材は層間で剥離し易い。そのため、内装材に反りが
生じ易く、寸法安定性が低下する。
However, all of these interior materials have low heat resistance and fire resistance because the heat insulating layer is made of synthetic resin foam. Moreover, in order to increase the adhesive strength between the water absorbing layer or the hygroscopic material and the heat insulating material and to prevent cracks from being generated in the water absorbing layer or the hygroscopic material, an adhesive or a synthetic resin is required. For example, in the building wall material disclosed in Japanese Utility Model Publication No. 60-148417, it is not only difficult to form a non-woven fabric by impregnating an inorganic water-absorbing layer, but also the obtained wall material peels between layers. Easy to do. Therefore, the interior material is likely to warp, and the dimensional stability is reduced.

【0008】さらには、パネル材の強度を高めるために
は芯材や枠体などを必要とし、ケイソウ土の焼成粉末な
どの無機質材だけでは、パネル材としての強度が小さ
い。特に、パネル材が薄く長尺状であると、強度が大き
く低下する。強度を高めるためには、厚みを大きくすれ
ばよいものの、軽量化が困難となり、施工性も低下す
る。このように従来のパネル材では、機械的強度と軽量
性及び施工性の双方の特性を高めることが困難である。
Further, in order to increase the strength of the panel material, a core material, a frame body, etc. are required, and the strength of the panel material is small only with an inorganic material such as a fired powder of diatomaceous earth. In particular, when the panel material is thin and long, the strength is greatly reduced. Although it is sufficient to increase the thickness in order to increase the strength, it becomes difficult to reduce the weight and the workability also decreases. As described above, it is difficult for the conventional panel material to enhance both mechanical strength, lightness and workability.

【0009】一方、施工性を高めるため、壁材としてセ
ッコウボードも知られている。このセッコウボードは、
焼きセッコウ、ガラス繊維やパルプ、パーライトなどの
骨材および水を含むスラリーを下紙上に流し込み、上紙
を積層し、成形ロールにより所定厚みのホード状に成形
し、乾燥・硬化させることにより製造されている(「化
学便覧応用編 改訂3版」(財)日本化学会編、丸善
(株)昭和55年3月15日発行、第402〜404頁
「セッコウ」の項)。
On the other hand, gypsum board is also known as a wall material in order to improve workability. This gypsum board is
Manufactured by pouring a slurry containing water such as baked gypsum, glass fiber or pulp, aggregates such as perlite, and water onto the lower paper, stacking the upper paper, molding it into a hod with a specified thickness using a molding roll, and drying and curing. ("Chemical Handbook Applied Edition, Revised 3rd Edition" (Chemical Society of Japan), edited by Maruzen Co., Ltd., March 15, 1980, pages 402-404, "Gypsum").

【0010】しかし、このような方法で得られたボード
も、軽量化及び施工性を高めるために、厚みを薄くする
と、強度が低下する。
However, the board obtained by such a method also has a reduced strength if the thickness is reduced in order to reduce the weight and improve the workability.

【0011】このようにケイソウ土などの多孔質無機粉
粒体が、調湿性、耐熱性、断熱性、耐火性、遮音性およ
び脱臭性などに優れているにも拘らず、パネル材の強度
が小さいため、軽量かつ施工性に優れたパネル材を得る
ことが困難である。
As described above, although the porous inorganic powdery material such as diatomaceous earth is excellent in humidity control, heat resistance, heat insulation, fire resistance, sound insulation and deodorization, the strength of the panel material is high. Since it is small, it is difficult to obtain a panel material that is lightweight and has excellent workability.

【0012】[0012]

【発明が解決しようとする課題】従って、本発明の目的
は、多孔性無機粉粒体の優れた特性を維持しつつ、薄い
長尺状であっても機械的強度が大きく軽量で施工性に優
れるパネル材を提供することにある。
SUMMARY OF THE INVENTION Therefore, an object of the present invention is to maintain the excellent characteristics of the porous inorganic powder and to provide a large mechanical strength, a light weight and a good workability even if it is thin and long. It is to provide an excellent panel material.

【0013】本発明の他の目的は、調湿性、耐熱性、断
熱性、耐火性、遮音性および脱臭性が高いとともに、補
強繊維の引抜け抵抗および繊維の埋設効果および利用率
が高く、少量であっても高い補強性を有し、クラックの
発生がなく寸法安定性に優れたパネル材を提供すること
にある。
Another object of the present invention is that the humidity controllability, heat resistance, heat insulation, fire resistance, sound insulation and deodorization are high, and the pull-out resistance of the reinforcing fiber and the burying effect and utilization rate of the fiber are high. Even in that case, it is to provide a panel material having a high reinforcing property, having no cracks and having excellent dimensional stability.

【0014】[0014]

【発明の構成】本発明者らは、前記目的を達成するため
鋭意検討の結果、パネル材を斜交メッシュ状の補強材で
補強すると、薄く長尺状であっても機械的強度が大きい
ことを見いだし、本発明を完成した。
As a result of intensive studies to achieve the above object, the present inventors have found that when a panel material is reinforced with a diagonal mesh reinforcing material, it has a large mechanical strength even if it is thin and long. Then, the present invention was completed.

【0015】すなわち、本発明のパネル材は、樹脂を含
浸した繊維束からなる縦糸と横糸とが互いに交差して接
合した補強材を含むパネル材であって、一方の方向に間
隔を置いて延出する縦糸群を構成する複数の縦糸と、前
記方向と交差する方向に間隔を置いて延出する横糸群を
構成する複数の横糸とが、位置を異にして、90°<θ
≦170°の交差角度θで交差している補強材が、多孔
質無機粉粒体および無機硬化性物質を含む無機質材に埋
設されている。
That is, the panel material of the present invention is a panel material including a reinforcing material in which warp yarns and weft yarns made of fiber bundles impregnated with resin intersect and are joined to each other, and are extended at intervals in one direction. The plurality of warp yarns forming the warp yarn group and the plurality of weft yarns forming the weft yarn group extending at intervals in the direction intersecting the direction are different in position and 90 ° <θ
The reinforcing material intersecting at the intersecting angle θ of ≦ 170 ° is embedded in the inorganic material containing the porous inorganic powder and the inorganic curable substance.

【0016】以下、必要に応じて、添付図面を参照しつ
つ本発明を詳細に説明する。
Hereinafter, the present invention will be described in detail with reference to the accompanying drawings as needed.

【0017】本発明のパネル材に含まれる補強材は、斜
交メッシュ状であるという特色がある。前記斜交メッシ
ュ状の補強材は、補強繊維からなる縦糸と横糸とが前記
の交差角度θで、位置を異にして互いに交差し、かつ接
合していればよい。
The reinforcing material contained in the panel material of the present invention has a feature that it has an oblique mesh shape. In the diagonal mesh reinforcing material, it is sufficient that the warp yarns and the weft yarns made of reinforcing fibers intersect each other at different positions at the above intersecting angle θ and are joined together.

【0018】図1は補強材の一例を示す概略平面図であ
る。この例において、斜交メッシュ状補強材は、一方の
方向に所定間隔で延びる縦糸1からなる1つの縦糸群
と、前記縦糸1と交差する方向に所定間隔で延びる横糸
2からなる1つの横糸群とで構成され、縦糸1と横糸2
は交差し、交差部において積層状態で接合している。
FIG. 1 is a schematic plan view showing an example of a reinforcing material. In this example, the diagonal mesh reinforcing material is one warp yarn group consisting of warp yarns 1 extending in one direction at a predetermined interval and one weft yarn group consisting of weft yarns 2 extending in a direction intersecting the warp yarn 1 at a predetermined interval. It consists of a warp thread 1 and a weft thread 2
Intersect and are joined in a laminated state at the intersection.

【0019】斜交メッシュ状補強材において、縦糸1と
横糸2との交差角度θは、パネル材に作用する主たる荷
重方向などに応じて、前記の範囲内で適当に選択できる
が、好ましくは100゜≦θ≦140゜程度である。
In the diagonal mesh reinforcing material, the intersection angle θ between the warp threads 1 and the weft threads 2 can be appropriately selected within the above range depending on the main load direction acting on the panel material, but is preferably 100. The angle is about ≦ θ ≦ 140 °.

【0020】このような斜交メッシュ状補強材を埋設し
たパネル材においては、主たる荷重方向の応力Fが作用
すると、応力Fが斜め方向に交差する縦糸1及び横糸2
により分力される。そのため、パネル材に応力Fが作用
する方向に、交差部の鋭角部を向けて斜交メッシュ状補
強材を埋設することにより、補強性を高めることがで
き、長尺状パネル材にあっては、長手方向の強度を高め
ることができる。また、荷重方向に対して縦糸1と横糸
2が斜め方向に配筋しているため、パネル材からの引抜
き抵抗が大きい。従って、曲げ荷重などの応力に対し
て、前記メッシュ状補強材による補強効率が高く、繊維
の埋設効果及び有効率を向上させることができる。しか
も、交差部において鋭角部が指向する方向の剛性が高く
なるという強度の方向性(異方性)を有するので、鋭角
部が指向する方向の曲げ撓みも小さく、作業性および施
工性が向上する。
In the panel material in which such a diagonal mesh reinforcing material is embedded, when the stress F in the main load direction acts, the warp yarn 1 and the weft yarn 2 at which the stress F diagonally intersects.
Is divided by. Therefore, by embedding the oblique mesh reinforcing material in the direction in which the stress F acts on the panel material with the acute angle portion of the intersection facing, it is possible to enhance the reinforcing property. The strength in the longitudinal direction can be increased. Further, since the warp yarns 1 and the weft yarns 2 are arranged obliquely with respect to the load direction, the pullout resistance from the panel material is large. Therefore, the reinforcing efficiency of the mesh-like reinforcing material against stress such as bending load is high, and the effect of embedding fibers and the effective rate can be improved. Moreover, since there is strength directional property (anisotropic) that the rigidity in the direction in which the acute angle portion is directed is increased at the intersection, bending bending in the direction in which the acute angle portion is directed is small, and workability and workability are improved. .

【0021】このような斜交メッシュ状の補強材は、種
々の方法、例えば、樹脂を含浸した繊維束を前記の角度
でメッシュ状に交差させて接合したり、メッシュ状に交
差させ繊維束に樹脂を含浸させて接合してもよい。ま
た、交差部において、縦糸と横糸は、互いに絡み合って
いてもよい。斜交メッシュ状の補強材は、周囲に配置し
たピンに、順次一筆書きの要領で繊維束を引っかけて、
交差角度θ1 が45゜<θ1 ≦85゜の範囲内で斜交さ
せるピンワインディング法により得ることもできる。
Such an oblique mesh reinforcing material can be obtained by various methods, for example, by crossing and joining resin-impregnated fiber bundles in a mesh shape at the angle described above, or by intersecting them in a mesh shape to form a fiber bundle. Resin may be impregnated and joined. Moreover, the warp yarn and the weft yarn may be intertwined with each other at the intersection. The diagonal mesh reinforcing material is hooked with fiber bundles on the pins arranged around it in the order of one stroke,
It can also be obtained by a pin winding method in which the crossing angle θ1 is oblique within the range of 45 ° <θ1 ≦ 85 °.

【0022】斜交メッシュ状の補強材は、樹脂を含浸し
た繊維束を、回転ドラムなどの回転体の回転軸方向に沿
って往復動させながら、所望する補強繊維の組織(構成
方法)に応じて縦糸と横糸とが直交しない範囲、例え
ば、前記回転体に対する巻き付け角度θ1 を、45゜<
θ1 ≦85゜、好ましくは50゜≦θ1 ≦70゜程度と
して、前記回転体にメッシュ状に巻回し、巻回した繊維
束をシート状に加工することにより効率よく得ることが
できる。例えば、図1に示す前記補強材は、前記樹脂含
浸繊維束を、回転体に、一方の方向に所定ピッチで巻回
して縦糸1を構成し、巻回した前記縦糸1と交差させな
がら、前記縦糸1上に所定ピッチで巻回することにより
横糸2を構成することにより製造できる。
The diagonal mesh reinforcing material is made to reciprocate a resin-impregnated fiber bundle along the direction of the rotation axis of a rotating body such as a rotating drum, while depending on the desired reinforcing fiber structure (construction method). The warp thread and the weft thread are not orthogonal to each other, for example, the winding angle θ1 with respect to the rotating body is 45 ° <
It can be efficiently obtained by setting θ 1 ≦ 85 °, preferably about 50 ° ≦ θ 1 ≦ 70 °, by winding it around the rotating body in a mesh shape, and processing the wound fiber bundle into a sheet shape. For example, in the reinforcing material shown in FIG. 1, the resin-impregnated fiber bundle is wound around a rotating body at a predetermined pitch in one direction to form a warp thread 1, and the warp thread 1 is crossed with the warp thread 1 while intersecting the warp thread 1. It can be manufactured by constructing the weft thread 2 by winding the warp thread 1 at a predetermined pitch.

【0023】好ましい方法には、一本の樹脂含浸繊維束
を、一方の方向に所定のピッチで巻回して縦糸を形成
し、形成された縦糸と交差する方向に所定のピッチで巻
回して横糸を形成した後、前記一方の方向及び交差方向
に少なくとも1回以上、位置をずらして、好ましくは略
等間隔毎に位置をずらして往復動させて巻回する方法が
含まれる。
In a preferred method, one resin-impregnated fiber bundle is wound in one direction at a predetermined pitch to form a warp, and is wound at a predetermined pitch in a direction intersecting with the formed warp and a weft. After the formation, the method includes displacing the position at least once or more in the one direction and the intersecting direction, preferably displacing the position at substantially equal intervals and reciprocatingly winding.

【0024】図2は斜交メッシュ状補強材の他の例を示
す概略平面図である。この例の斜交メッシュ状補強材に
おいては、一方の方向に所定間隔で延びる縦糸11aか
らなる第1の縦糸群と、前記縦糸11aと交差する方向
に所定間隔で延びる横糸12aからなる第1の横糸群
と、前記一方の方向に所定間隔で延びる縦糸11bから
なる第2の縦糸群と、前記第2の縦糸群の縦糸11bと
交差する方向に所定間隔で延びる横糸12bからなる第
2の横糸群とが、互いに位置を異にして順次交差し、交
差部において積層状態で接合している。
FIG. 2 is a schematic plan view showing another example of the oblique mesh reinforcing material. In the oblique mesh reinforcing material of this example, a first warp group consisting of warp threads 11a extending in one direction at a predetermined interval and a first warp thread 12a extending in a direction intersecting the warp thread 11a with a first interval. A second weft yarn consisting of a weft yarn group, a second warp yarn group consisting of warp yarns 11b extending at a predetermined interval in the one direction, and a weft yarn 12b extending at a predetermined interval in a direction intersecting with the warp yarns 11b of the second warp yarn group. The groups and the groups intersect at different positions in sequence, and are joined in a laminated state at the intersections.

【0025】なお、図2に示す組織(構成方法)の補強
材は、樹脂含浸繊維束を、一方の方向に所定ピッチで巻
回して第1の縦糸11aを構成し、巻回した前記縦糸1
1aと交差させながら、前記縦糸11a上に所定ピッチ
で巻回して第1の横糸12aを構成する。次いで、前記
樹脂含浸繊維束を、前記第1の縦糸11a間に位置する
ピッチで、しかも前記第1横糸12aと交差させなが
ら、前記一方の方向に巻回して第2の縦糸11bを構成
した後、前記第1の横糸12a間に位置するピッチで、
しかも前記第1の縦糸11aと交差させながら、前記第
1及び第2の縦糸11a,11b上に巻回して第2の横
糸12bを構成することにより製造できる。
In the reinforcing material having the structure (construction method) shown in FIG. 2, a resin-impregnated fiber bundle is wound in one direction at a predetermined pitch to form a first warp yarn 11a, and the wound warp yarn 1 is formed.
The first weft yarn 12a is formed by winding the warp yarn 11a at a predetermined pitch while intersecting with the laft yarn 1a. Then, the resin-impregnated fiber bundle is wound in the one direction while forming a second warp yarn 11b at a pitch positioned between the first warp yarns 11a and while intersecting with the first weft yarns 12a. , At a pitch located between the first weft threads 12a,
Moreover, it can be manufactured by winding the first warp yarn 11a on the first and second warp yarns 11a and 11b while intersecting the first warp yarn 11a to form the second weft yarn 12b.

【0026】図3は斜交メッシュ状補強材のさらに他の
例を示す概略平面図である。この例において、斜交メッ
シュ状補強材は、一方の方向に所定間隔で延びる縦糸2
1aからなる第1の縦糸群と、前記縦糸21aと交差す
る方向に所定間隔で延びる横糸22aからなる第1の横
糸群と、前記と同様の縦糸21bからなる第2の縦糸群
と、前記と同様の横糸22bからなる第2の横糸群と、
縦糸21cからなる第3の縦糸群と、横糸22cからな
る第3の横糸群とが、互いに位置を異にして順次交差
し、交差部において積層状態で接合している。
FIG. 3 is a schematic plan view showing still another example of the diagonal mesh reinforcing material. In this example, the diagonal mesh reinforcing material is a warp yarn 2 extending at a predetermined interval in one direction.
A first warp yarn group consisting of 1a, a first weft yarn group consisting of weft yarns 22a extending at a predetermined interval in a direction intersecting with the warp yarns 21a, a second warp yarn group consisting of warp yarns 21b similar to the above, and A second weft thread group consisting of similar weft threads 22b;
A third warp yarn group consisting of the warp yarns 21c and a third weft yarn group consisting of the weft yarns 22c sequentially intersect at different positions and are joined in a laminated state at the intersecting portions.

【0027】図3に示す補強材は、第1の縦糸21a間
に第2及び第3の縦糸21b,21cを略等間隔毎に位
置させ、第1の横糸22a間に第2及び第3の横糸22
b,22cを略等間隔毎に位置させ、しかも、第1の縦
糸21aと第3の横糸22cとの間の複数の縦糸21
b,21c及び横糸22a,22bとを交互に交差させ
ることにより製造できる。
In the reinforcing member shown in FIG. 3, the second and third warp yarns 21b and 21c are arranged at substantially equal intervals between the first warp yarns 21a, and the second and third warp yarns 22a are arranged between the first warp yarns 22a. Weft 22
b, 22c are positioned at substantially equal intervals, and moreover, the plurality of warp yarns 21 between the first warp yarn 21a and the third weft yarn 22c are arranged.
It can be manufactured by alternately intersecting b, 21c and wefts 22a, 22b.

【0028】繊維束を構成する補強繊維としては、例え
ば、ガラス繊維;アルミニウムシリケート質繊維、アル
ミナ質繊維、炭化ケイ素繊維などのセラミック繊維;ポ
リアクリロニトリル、フェノール樹脂、レーヨンなどの
高分子、石油又は石炭系ピッチなどを素材とする炭素繊
維;ポリエチレン繊維、ポリプロピレン繊維、セルロー
ス繊維、レーヨン繊維、アセテート繊維、ナイロン繊
維、ポリエステル繊維、ポリビニルアルコール系合成繊
維(ビニロン繊維)、ポリエーテルスルホン繊維、芳香
族ポリアミド繊維(アラミド繊維など)などの高分子繊
維などが挙げられる。これらの繊維は少なくとも一種使
用できる。
Examples of the reinforcing fiber constituting the fiber bundle include glass fiber; ceramic fiber such as aluminum silicate fiber, alumina fiber and silicon carbide fiber; polymer such as polyacrylonitrile, phenol resin and rayon, petroleum or coal. Carbon fiber made of pitch based material; polyethylene fiber, polypropylene fiber, cellulose fiber, rayon fiber, acetate fiber, nylon fiber, polyester fiber, polyvinyl alcohol synthetic fiber (vinylon fiber), polyether sulfone fiber, aromatic polyamide fiber Polymer fibers such as aramid fibers and the like can be mentioned. At least one of these fibers can be used.

【0029】これらの繊維の中で、補強効果および寸法
安定性を高めるためには、引張弾性率の大きな繊維、例
えば、ガラス繊維、炭素繊維、ポリプロピレン繊維、ポ
リビニルアルコール系合成繊維、アラミド繊維などが好
ましい。
Among these fibers, in order to enhance the reinforcing effect and the dimensional stability, fibers having a large tensile elastic modulus such as glass fiber, carbon fiber, polypropylene fiber, polyvinyl alcohol-based synthetic fiber and aramid fiber are used. preferable.

【0030】繊維の素線径は、例えば、5〜30μm程
度である。繊維束は、適当な数の素線、例えば、500
〜480000本程度の素線で構成できる。
The filament diameter of the fiber is, for example, about 5 to 30 μm. A fiber bundle is made up of a suitable number of strands, for example 500
It can be composed of about 480000 strands.

【0031】繊維束は、撚りをかけることなく、回転ド
ラムに巻回してもよいが、撚りをかけると、ドラムに巻
き付けたとき繊維束が偏平になるのを防止できるととも
に、パネル材を構成する無機質材との接着性を高めるこ
とができる。繊維束の撚り数は、適当に選択できるが、
1m当り、5〜30回、好ましくは10〜15回程度で
ある。
The fiber bundle may be wound around a rotary drum without twisting. However, twisting can prevent the fiber bundle from becoming flat when wound around the drum, and constitutes a panel material. The adhesiveness with the inorganic material can be enhanced. The number of twists of the fiber bundle can be appropriately selected,
It is 5 to 30 times, preferably 10 to 15 times per 1 m.

【0032】また、回転ドラムに樹脂含浸繊維束を巻回
すると、樹脂含浸繊維束の張力を調整することにより、
樹脂含浸繊維束をプレスした場合と同様に、繊維束同士
の密着力を高めることができる。さらに、全ての樹脂含
浸繊維束を交差させることができるので、材料を有効に
利用できる。
When the resin-impregnated fiber bundle is wound on the rotary drum, the tension of the resin-impregnated fiber bundle is adjusted to
As in the case of pressing the resin-impregnated fiber bundle, the adhesion between the fiber bundles can be increased. Further, since all the resin-impregnated fiber bundles can be crossed, the material can be effectively used.

【0033】前記繊維束に含浸する樹脂としては、例え
ば、エポキシ樹脂、フェノール樹脂、ビニルエステル樹
脂、ジアリルフタレート樹脂、不飽和ポリエステル樹
脂、熱硬化性アクリル樹脂、ポリウレタン樹脂、ポリイ
ミドなどの熱硬化性樹脂;ポリアセタール、ポリスルホ
ン、ポリエーテルスルホン、ポリフェニレンスルフィ
ド、ポリフェニレンオキサイド、ポリアリレート、芳香
族ポリアミドなどの熱可塑性樹脂が例示される。上記樹
脂は一種または二種以上使用される。これらの樹脂のう
ち熱硬化性樹脂、特にエポキシ樹脂、ビニルエステル樹
脂、フェノール樹脂などが好ましい。熱硬化性樹脂を使
用する場合、樹脂の種類に応じた硬化剤が使用できる。
Examples of the resin with which the fiber bundle is impregnated are thermosetting resins such as epoxy resin, phenol resin, vinyl ester resin, diallyl phthalate resin, unsaturated polyester resin, thermosetting acrylic resin, polyurethane resin, and polyimide. And thermoplastic resins such as polyacetal, polysulfone, polyether sulfone, polyphenylene sulfide, polyphenylene oxide, polyarylate, and aromatic polyamide. The above resins are used alone or in combination of two or more. Of these resins, thermosetting resins, particularly epoxy resins, vinyl ester resins, phenol resins and the like are preferable. When a thermosetting resin is used, a curing agent depending on the type of resin can be used.

【0034】樹脂の含浸量は、繊維束の一体性などを損
わない範囲で選択でき、例えば体積含有率10〜80
%、好ましくは20〜60%程度である。なお、必要に
応じて、樹脂含浸工程で繊維束に過剰に付着した樹脂を
除去してもよい。
The amount of resin impregnated can be selected within a range that does not impair the integrity of the fiber bundle. For example, the volume content is 10 to 80.
%, Preferably about 20 to 60%. If necessary, the resin excessively attached to the fiber bundle may be removed in the resin impregnation step.

【0035】また、補強繊維のメッシュ間隔は、補強性
能に応じて適宜設定でき、例えば、2mm以上、好まし
くは5〜300mm、さらに好ましくは10〜200m
m程度である。メッシュ間隔が2mm未満であるとメッ
シュ間に充填される無機質材の量が少なく補強性が十分
でない。またねメッシュ間隔が300mmを越えると、
必要な補強性が得られない場合がある。
The mesh spacing of the reinforcing fibers can be appropriately set according to the reinforcing performance and is, for example, 2 mm or more, preferably 5 to 300 mm, more preferably 10 to 200 m.
It is about m. When the mesh interval is less than 2 mm, the amount of the inorganic material filled between the meshes is small and the reinforcing property is insufficient. If the mesh spacing exceeds 300 mm,
The required reinforcement may not be obtained.

【0036】なお、縦糸と横糸のピッチは同一であって
もよく異なっていてもよい。また、縦糸と横糸の素線数
や径も同一であってもよく異なっていてもよい。補強材
の縦糸を構成する縦糸群、及び横糸を構成する横糸群の
数は、縦糸又は横糸の上に横糸又は縦糸が交差する限
り、同一であってもよく、異なっていてもよい。
The warp and weft pitches may be the same or different. Further, the numbers of filaments and the diameters of the warp yarns and the weft yarns may be the same or different. The number of warp yarn groups that form the warp yarns of the reinforcing material and the number of weft yarn groups that form the weft yarns may be the same or different as long as the weft yarns or the warp yarns intersect with each other.

【0037】なお、補強材は、パネルの無機質材との親
和性を高めるため、シランカップリング剤、チタンカッ
プリング剤などで表面処理してもよく、さらには、その
表面に砂を付着したり研磨したりすることにより凹凸部
を形成してもよい。シランカップリング剤や砂などは、
前記樹脂とともに繊維束に含浸させてもよい。
The reinforcing material may be surface-treated with a silane coupling agent, a titanium coupling agent, or the like in order to enhance the affinity with the inorganic material of the panel, and further, sand may be attached to the surface. The uneven portion may be formed by polishing or the like. For silane coupling agents and sand,
The fiber bundle may be impregnated with the resin.

【0038】パネル材に占める斜交メッシュ状補強材の
割合は、パネル材の大きさなどに応じて選択でき、通
常、0.05〜5体積%、好ましくは0.1〜3体積%
程度である。
The proportion of the oblique mesh reinforcing material in the panel material can be selected according to the size of the panel material, etc., and is usually 0.05 to 5% by volume, preferably 0.1 to 3% by volume.
It is a degree.

【0039】本発明のパネル材に含まれる前記多孔質無
機粉粒体としては、吸着性などを有する多孔質粉粒体、
例えば、活性炭、ケイソウ土、酸性白土、活性白土、活
性アルミナ、酸化チタン、ベントナイト、パーライト、
バーミキュライト、シラスバルーン、焼成カオリン、ケ
イ酸マグネシウムなどが挙げられる。これらの多孔質無
機粉粒体は一種又は二種以上使用できる。多孔質無機粉
粒体を含むパネル材は、調湿性、防露性、断熱性、耐火
性、遮音性及び脱臭性などが高い。
Examples of the porous inorganic powdery particles contained in the panel material of the present invention include porous powdery particles having an adsorbing property,
For example, activated carbon, diatomaceous earth, acid clay, activated clay, activated alumina, titanium oxide, bentonite, perlite,
Examples thereof include vermiculite, shirasu balloon, calcined kaolin, and magnesium silicate. These porous inorganic powders can be used alone or in combination of two or more. The panel material containing the porous inorganic powder has high humidity control, dew resistance, heat insulation, fire resistance, sound insulation and deodorization.

【0040】好ましい多孔質無機粉粒体には、吸放湿性
(調湿性)、耐熱性、断熱性、耐火性、遮音性および脱
臭性に優れる多孔質無機粉粒体、特にケイソウ土が含ま
れる。ケイソウ土は、水分を殆ど含まない乾燥ケイソウ
土や、例えば500℃以上、好ましくは600〜100
0℃程度の温度で焼成されたケイソウ土の焼成粉末が好
ましい。
Preferable porous inorganic powdery particles include porous inorganic powdery particles, especially diatomaceous earth, which are excellent in moisture absorption / release (humidity control), heat resistance, heat insulation, fire resistance, sound insulation and deodorization. . The diatomaceous earth is, for example, dry diatomaceous earth containing almost no water or, for example, 500 ° C. or higher, preferably 600 to 100.
A fired powder of diatomaceous earth fired at a temperature of about 0 ° C. is preferred.

【0041】無機質粉粒体の粒度は、例えば、150メ
ッシュ以下である場合が多く、比表面積は、5〜300
0m2 /g程度である場合が多い。
The particle size of the inorganic powder is often, for example, 150 mesh or less, and the specific surface area is 5 to 300.
It is often about 0 m 2 / g.

【0042】無機質粉粒体の含有量は、パネル材全体の
10〜95重量%、好ましくは30〜75重量%程度で
ある。無機質粉粒体の含有量が10重量%未満である
と、断熱性および調湿性が低下し、95重量%を越える
と機械的強度が低下し易い。
The content of the inorganic powdery particles is 10 to 95% by weight, preferably 30 to 75% by weight, based on the whole panel material. When the content of the inorganic powdery particles is less than 10% by weight, the heat insulating property and the humidity control property are deteriorated, and when the content exceeds 95% by weight, the mechanical strength is easily decreased.

【0043】無機硬化性物質には、例えば、セッコウ;
消石灰やドロマイトプラスターなどの石灰;水硬性物質
が含まれる。水硬性物質としては、例えば、セメント
(例えば、ポルトランドセメント、早強ポルトランドセ
メント、アルミナセメント、急硬高強度セメント、焼き
セッコウなどの自硬性セメント;石灰スラグセメント、
高炉セメントなどの水硬性セメント;混合セメント)な
どが挙げられる。好ましい無機硬化性物質には、例え
ば、セッコウ、消石灰やドロマイトプラスターなどが含
まれる。なお、ドロマイトプラスターは、一般に粒子径
が揃った細粒状であるため、保水性及び施工性に優れる
とともに、糊剤を用いることなく施工できるという利点
がある。
Examples of the inorganic curable substance include gypsum;
Lime such as slaked lime and dolomite plaster; it contains hydraulic substances. Examples of hydraulic materials include cement (eg, Portland cement, early-strength Portland cement, alumina cement, rapid-hardening high-strength cement, self-hardening cement such as gypsum; lime slag cement,
Hydraulic cement such as blast furnace cement; mixed cement) and the like. Preferred inorganic curable substances include, for example, gypsum, slaked lime and dolomite plaster. Since the dolomite plaster is generally in the form of fine particles having a uniform particle size, it has an advantage that it is excellent in water retention and workability and can be applied without using a sizing agent.

【0044】無機硬化性物質の含有量は、例えば、パネ
ル材全体の5〜95重量%、好ましくは20〜75重量
%、さらに好ましくは30〜60重量%程度である。無
機硬化性物質の含有量が5重量%未満であるとパネル材
の強度が低下し易く、90重量%を越えると、前記多孔
質無機粉粒体による吸放湿性が損われ、結露が生じ易
い。
The content of the inorganic curable substance is, for example, 5 to 95% by weight, preferably 20 to 75% by weight, more preferably 30 to 60% by weight, based on the whole panel material. When the content of the inorganic curable substance is less than 5% by weight, the strength of the panel material is likely to decrease, and when it exceeds 90% by weight, the moisture absorption and desorption property of the porous inorganic powder is impaired, and dew condensation is likely to occur. .

【0045】無機硬化性物質を含有させると、前記補強
材の補強効果と相まって、無機硬化性物質の硬化によ
り、パネル材の強度をさらに向上できる。
When an inorganic curable substance is contained, the strength of the panel material can be further improved by curing the inorganic curable substance in combination with the reinforcing effect of the reinforcing material.

【0046】さらに、パネル材のひび割れを分散し、ク
ラックや反りの発生を防止し、寸法安定性を高めると共
に、さらに強度を高めるため、前記パネル材は、短繊維
を含んでいてもよい。短繊維は、前記例示の補強繊維か
ら適当に選択することができ、前記斜交メッシュ状補強
材の補強繊維とはその種類が異なっていてもよい。
Furthermore, in order to disperse cracks in the panel material, prevent the occurrence of cracks and warpage, enhance dimensional stability, and further enhance strength, the panel material may contain short fibers. The short fibers can be appropriately selected from the above-mentioned reinforcing fibers, and the kind thereof may be different from that of the reinforcing fibers of the oblique mesh reinforcing material.

【0047】短繊維の長さは、例えば、0.1〜10m
m程度であり、0.5〜7.5mm程度の短繊維が繁用
される。短繊維のアスペクト比は、補強性を高めるた
め、50〜5000程度が好ましい。
The length of the short fibers is, for example, 0.1 to 10 m.
m, and short fibers of about 0.5 to 7.5 mm are often used. The aspect ratio of the short fibers is preferably about 50 to 5000 in order to enhance the reinforcing property.

【0048】短繊維の混入率は、パネル材の所望する強
度などに応じて選択でき、例えば、0.1〜5体積%、
好ましくは0.5〜5体積%程度である。
The mixing ratio of the short fibers can be selected according to the desired strength of the panel material, for example, 0.1 to 5% by volume,
It is preferably about 0.5 to 5% by volume.

【0049】前記パネル材は、砂、ケイ砂、パーライト
などの細粒骨材;着色剤、硬化剤、有機酸塩、無機酸塩
などの凝結遅延剤、塩化カルシウムなどの硬化促進剤、
ナフタレンスルホン酸ナトリウムなどの減水剤、凝固
剤、カルボキシメチルセルロース、メチルセルロース、
ポリビニルアルコールなどの増粘剤、発泡剤、合成樹脂
エマルジョンなどの防水剤、可塑剤などの種々の添加剤
を含んでいてもよい。
The panel material is a fine-grained aggregate such as sand, silica sand, perlite; a colorant, a hardening agent, a set retarder such as an organic acid salt or an inorganic acid salt, a hardening accelerator such as calcium chloride,
Water reducing agents such as sodium naphthalene sulfonate, coagulants, carboxymethyl cellulose, methyl cellulose,
It may contain various additives such as a thickener such as polyvinyl alcohol, a foaming agent, a waterproofing agent such as a synthetic resin emulsion, and a plasticizer.

【0050】本発明のパネル材は、前記斜交メッシュ状
補強材を型枠内に配し、前記成分と水との混合物からな
る無機質流動性組成物(モルタル)を型枠内に打設し、
乾燥し、硬化させることにより製造できる。
In the panel material of the present invention, the oblique mesh reinforcing material is placed in a mold, and an inorganic fluid composition (mortar) composed of a mixture of the above components and water is cast in the mold. ,
It can be produced by drying and curing.

【0051】斜交メッシュ状補強材の配設方向は、特に
制限されないが、補強材の交差部において鈍角部が指向
する方向に対する補強性よりも、鋭角部が指向する方向
に対する補強性を高めることができる。そのため、前記
斜交メッシュ状補強材は、パネル材に作用する応力Fの
方向に、交差部の鋭角部を向けて型枠内に配し、パネル
内に埋設するのが好ましい。
The arrangement direction of the oblique mesh reinforcing material is not particularly limited, but the reinforcing property in the direction in which the acute angle portion is directed is higher than the reinforcing property in the direction in which the obtuse angle portion is directed at the intersection of the reinforcing material. You can Therefore, it is preferable that the oblique mesh reinforcing material is arranged in the form with the acute angle portion of the intersection facing in the direction of the stress F acting on the panel material and embedded in the panel.

【0052】前記のような方向に補強材を配設すると、
長尺状のパネル材においては、前記のように、斜交メッ
シュ状補強材により、主荷重方向の応力が分力されるの
で、長手方向の補強性を高めることができる。また、前
記のように、パネルからの引抜き抵抗が大きいので、補
強効果をさらに高めることができる。また、補強材は、
縦糸と横糸とが斜交しているので、メッシュ筋自体の長
手方向、すなわち交差部において鋭角部が指向する方向
の剛性が高くなるという強度の方向性(異方性)を有す
るので、直交型のメッシュが強度の非方向性(等方性)
を示すのと異なり、施工性を向上させることができる。
When the reinforcing material is arranged in the above-mentioned direction,
In the long panel material, since the stress in the main load direction is divided by the oblique mesh reinforcing material as described above, the reinforcing property in the longitudinal direction can be enhanced. In addition, as described above, since the pulling-out resistance from the panel is large, the reinforcing effect can be further enhanced. Also, the reinforcing material is
Since the warp yarns and the weft yarns cross each other diagonally, there is a directionality of strength (anisotropy) that the rigidity in the longitudinal direction of the mesh muscle itself, that is, the direction in which the acute angle portion is directed at the crossing portion is high, so that it is an orthogonal type. Mesh is non-directional in strength (isotropic)
Unlike the above, the workability can be improved.

【0053】従って、厚みが薄く長尺状であっても機械
的強度が高く、軽量で施工性を高めることができる。な
お、上記のような長尺状のパネル材においては、短辺方
向よりも長手方向に荷重が作用する場合が多いので、長
手方向に対して極めて有効に強度が発現するとともに、
短辺方向に対しても十分な強度が確保できる。
Therefore, even if the thickness is thin and long, the mechanical strength is high, the weight is light and the workability can be improved. In the long panel material as described above, since the load often acts in the longitudinal direction rather than in the short side direction, the strength is extremely effectively expressed in the longitudinal direction,
Sufficient strength can be secured even in the short side direction.

【0054】斜交メッシュ状補強材の埋設位置(かぶ
り)は、パネル材の形状、厚みや大きさなどに応じて適
当に選択できる。また、斜交メッシュ状補強材のプライ
数は、複数であってもよい。硬化は、加熱下で行なって
もよいが、通常、室温などで放置することにより、例え
ば、12時間〜4日程度で硬化させることができる。
The embedding position (fog) of the oblique mesh reinforcing material can be appropriately selected according to the shape, thickness and size of the panel material. Further, the number of plies of the diagonal mesh reinforcing material may be plural. The curing may be carried out under heating, but usually, it can be cured, for example, in about 12 hours to 4 days by leaving it at room temperature.

【0055】本発明のパネル材は、平板状であってもよ
く、湾曲板状であってもよい。パネル材の厚みは、用途
に応じて選択できるが、通常、5〜200mm、好まし
くは10〜100mm程度である場合が多い。本発明の
パネル材は、壁材、床材などの建築用内装材や外装材と
して有用である。
The panel material of the present invention may have a flat plate shape or a curved plate shape. Although the thickness of the panel material can be selected according to the application, it is usually 5 to 200 mm, preferably 10 to 100 mm in many cases. INDUSTRIAL APPLICABILITY The panel material of the present invention is useful as a building interior material or exterior material such as a wall material or a floor material.

【0056】[0056]

【発明の効果】本発明のパネル材は、斜交メッシュ状補
強材、多孔質無機粉粒体および無機硬化性物質を含むの
で、調湿性、耐熱性などが高いとともに、薄く長尺状で
あっても機械的強度が大きく軽量で施工性に優れる。ま
た、補強繊維の引抜け抵抗および繊維の利用率が高く、
少量であっても高い補強性を有し、クラックの発生がな
く寸法安定性に優れる。
EFFECTS OF THE INVENTION Since the panel material of the present invention contains a diagonal mesh reinforcing material, a porous inorganic powder and an inorganic curable substance, it has high humidity control and heat resistance and is thin and long. However, it has high mechanical strength and is lightweight and excellent in workability. In addition, the pull-out resistance of the reinforcing fiber and the utilization rate of the fiber are high,
Even with a small amount, it has high reinforcing properties and does not generate cracks and has excellent dimensional stability.

【0057】多孔質無機粉粒体がケイソウ土であるパネ
ル材は、調湿性、耐熱性、断熱性、耐火性、遮音性およ
び脱臭性が高い。無機硬化性物質が、セッコウ、消石灰
又はドロマイトプラスターである場合には、軽量化でき
るとともに、耐熱性、耐火性などを高めることができ
る。
The panel material in which the porous inorganic powder is diatomaceous earth has high humidity control, heat resistance, heat insulation, fire resistance, sound insulation and deodorization. When the inorganic curable substance is gypsum, slaked lime, or dolomite plaster, the weight can be reduced and the heat resistance and fire resistance can be improved.

【0058】[0058]

【実施例】以下に、実施例に基づいて本発明をより詳細
に説明する。
EXAMPLES The present invention will be described in more detail based on the following examples.

【0059】実施例1 素線数12000(12K)のポリアクリロニトリル系
炭素繊維(引張強度300kgf/mm2 、引張弾性率
24×103 kgf/mm2 )を3本集めて36Kと
し、1m当り12回の撚りをかけた。この繊維束にビス
フェノールA型エポキシ樹脂(油化シェル社製、商品名
エピコート827)100重量部、酸無水物系硬化剤
(ペトロケミカル社製、MNA)90重量部および硬化
促進剤(油化シェル社製、EMI−24)1重量部の溶
液に含浸させながら、20m/分の糸速度で、回転ドラ
ム(600mmφ)に、綾角65゜、繊維間隔5cmと
なるように幅1mに亘って巻き取った。巻き終った後、
装置の作動を停止し、巻回した樹脂含浸繊維束の一辺を
切開き、シート状とした後、150℃で4時間樹脂を硬
化させることにより、樹脂含有量50重量%の補強材を
得た。得られた補強材を、幅300mm、長さ1200
mmの大きさに切断し、型枠(長さ120cm、幅30
cm、深さ2cm)の中央部にセットした。
Example 1 Three polyacrylonitrile-based carbon fibers having a number of strands of 12,000 (12K) (tensile strength 300 kgf / mm 2 , tensile modulus 24 × 10 3 kgf / mm 2 ) were collected to make 36K, 12 per 1 m. Twisted twice. To this fiber bundle, 100 parts by weight of a bisphenol A type epoxy resin (produced by Yuka Shell Co., Ltd., trade name Epicoat 827), 90 parts by weight of an acid anhydride-based curing agent (produced by Petrochemical Co., MNA) and a curing accelerator (oiled shell). EMI-24) manufactured by KK, while being impregnated with 1 part by weight of a solution, wound at a yarn speed of 20 m / min on a rotating drum (600 mmφ) over a width of 1 m so that a winding angle of 65 ° and a fiber interval of 5 cm. I took it. After winding
The operation of the apparatus was stopped, one side of the wound resin-impregnated fiber bundle was cut open to form a sheet, and the resin was cured at 150 ° C. for 4 hours to obtain a reinforcing material having a resin content of 50% by weight. . The obtained reinforcing material is 300 mm wide and 1200 mm long.
Cut into a size of mm, and formwork (length 120 cm, width 30
cm, depth 2 cm).

【0060】焼成ケイソウ土(粒子径10〜40μm)
60重量部と、ドロマイトプラスター(粒子径1〜10
0μm)40重量部と、水40重量部とを混練し、混練
物を、前記型枠に流し込み、乾燥し硬化させることによ
り、パネル材を得た。パネル材の曲げ強度を、スパン9
0cmの3点曲げ試験により測定したところ、180k
g/cm2 であった。また、パネル材の熱伝導率を測定
したところ、0.16kcal/mh℃であった。
Fired diatomaceous earth (particle size 10 to 40 μm)
60 parts by weight and dolomite plaster (particle size 1 to 10
(0 μm) 40 parts by weight and 40 parts by weight of water were kneaded, and the kneaded product was poured into the mold, dried and cured to obtain a panel material. Bending strength of the panel material, span 9
When measured by a 3-point bending test of 0 cm, 180 k
It was g / cm 2 . Moreover, when the thermal conductivity of the panel material was measured, it was 0.16 kcal / mh ° C.

【0061】実施例2 綾角を50゜とする以外、炭素繊維の目付け量を実施例
1と同じくして補強材を得た。得られた補強材を、実施
例1と同様に混練物中に埋設してパネルを作製したとこ
ろ、パネルの3点曲げ強度は130kgf/cm2 であ
った。
Example 2 A reinforcing material was obtained in the same manner as in Example 1 except that the winding angle was 50 °. The obtained reinforcing material was embedded in a kneaded product in the same manner as in Example 1 to produce a panel, and the three-point bending strength of the panel was 130 kgf / cm 2 .

【0062】実施例3 綾角を70゜とする以外、炭素繊維の目付け量を実施例
1と同じくして補強材を得た。得られた補強材を、実施
例1と同様に混練物中に埋設してパネルを作製したとこ
ろ、パネルの3点曲げ強度は220kgf/cm2 であ
った。
Example 3 A reinforcing material was obtained in the same manner as in Example 1 except that the winding angle was 70 °. The obtained reinforcing material was embedded in a kneaded product in the same manner as in Example 1 to produce a panel, and the three-point bending strength of the panel was 220 kgf / cm 2 .

【0063】比較例1 実施例1と同様の繊維を用い、エポキシ樹脂を含浸させ
ながら、板の周囲に打ったピンに、一筆書きの要領で縦
方向及び横方向に順次掛けて、1m2 当りの炭素繊維使
用量が実施例1と同様になるように2軸直交型のメッシ
ュを作製し、150℃で4時間樹脂を硬化させることに
より、樹脂含有量50重量%の補強材を得た。得られた
補強材を実施例1と同様に混練物中に埋設してパネルを
作製したところ、パネルの3点曲げ強度は95kgf/
cm2 であった。
Comparative Example 1 Using the same fibers as in Example 1, while impregnating the epoxy resin, the pins struck around the plate were sequentially hung in the longitudinal direction and the lateral direction in a one-stroke manner, and per 1 m 2 A biaxially orthogonal mesh was prepared so that the amount of carbon fibers used was the same as in Example 1, and the resin was cured at 150 ° C. for 4 hours to obtain a reinforcing material having a resin content of 50% by weight. The reinforcing material thus obtained was embedded in a kneaded material in the same manner as in Example 1 to produce a panel, and the three-point bending strength of the panel was 95 kgf /
It was cm 2 .

【0064】比較例2 実施例1で用いた斜交メッシュ状補強材を、ドロマイト
プラスター100重量部と、水40重量部とを混練し、
混練物中に埋設し、パネルを作製した。パネルの3点曲
げ強度は190kgf/cm2 であった。また、パネル
材の熱伝導率を測定したところ、0.9kcal/mh
℃であった。
Comparative Example 2 The oblique mesh reinforcing material used in Example 1 was kneaded with 100 parts by weight of dolomite plaster and 40 parts by weight of water,
It was embedded in the kneaded material to prepare a panel. The three-point bending strength of the panel was 190 kgf / cm 2 . Moreover, when the thermal conductivity of the panel material was measured, it was 0.9 kcal / mh.
It was ℃.

【図面の簡単な説明】[Brief description of drawings]

【図1】図1は補強材の一例を示す概略平面図である。FIG. 1 is a schematic plan view showing an example of a reinforcing material.

【図2】図2は斜交メッシュ状補強材の他の例を示す概
略平面図である。
FIG. 2 is a schematic plan view showing another example of the oblique mesh reinforcing member.

【図3】図3は斜交メッシュ状補強材のさらに他の例を
示す概略平面図である。
FIG. 3 is a schematic plan view showing still another example of the oblique mesh reinforcing material.

【符号の説明】[Explanation of symbols]

1,11a,11b,21a,21b,21c…縦糸 2,12a,12b,22a,22b,22c…横糸 1, 11a, 11b, 21a, 21b, 21c ... Warp yarn 2, 12a, 12b, 22a, 22b, 22c ... Weft yarn

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 樹脂を含浸した繊維束からなる縦糸と横
糸とが互いに交差して接合した補強材を含むパネル材で
あって、一方の方向に間隔を置いて延出する縦糸群を構
成する複数の縦糸と、前記方向と交差する方向に間隔を
置いて延出する横糸群を構成する複数の横糸とが、位置
を異にして、90°<θ≦170°の交差角度θで交差
している補強材が、多孔質無機粉粒体および無機硬化性
物質を含む無機質材に埋設されているパネル材。
1. A panel material including a reinforcing material in which warp yarns and weft yarns made of resin-impregnated fiber bundles intersect and are joined to each other, and constitute a warp yarn group extending at intervals in one direction. A plurality of warp yarns and a plurality of weft yarns forming a weft yarn group extending at intervals in a direction intersecting the direction intersect at different positions and at an intersecting angle θ of 90 ° <θ ≦ 170 °. A panel material in which the reinforcing material is embedded in an inorganic material containing a porous inorganic powder and an inorganic curable substance.
【請求項2】 複数の縦糸群と複数の横糸群とが、互い
に位置を異にして、順次積層して交差している補強材が
埋設されている請求項1記載のパネル材。
2. A panel material according to claim 1, wherein a plurality of warp yarn groups and a plurality of weft yarn groups are embedded in a reinforcing material which is sequentially laminated and intersects at different positions.
【請求項3】 1m当り5〜30回の撚りがかけられた
繊維束で構成された補強材が埋設されている請求項1記
載のパネル材。
3. The panel material according to claim 1, wherein a reinforcing material composed of a fiber bundle twisted 5 to 30 times per 1 m is embedded.
【請求項4】 多孔質無機粉粒体がケイソウ土である請
求項1記載のパネル材。
4. The panel material according to claim 1, wherein the porous inorganic powdery material is diatomaceous earth.
【請求項5】 無機硬化性物質が、セッコウ、消石灰又
はドロマイトプラスターである請求項1記載のパネル
材。
5. The panel material according to claim 1, wherein the inorganic curable substance is gypsum, slaked lime, or dolomite plaster.
JP5199131A 1993-07-15 1993-07-15 Panel material Pending JPH0733507A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5199131A JPH0733507A (en) 1993-07-15 1993-07-15 Panel material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5199131A JPH0733507A (en) 1993-07-15 1993-07-15 Panel material

Publications (1)

Publication Number Publication Date
JPH0733507A true JPH0733507A (en) 1995-02-03

Family

ID=16402662

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5199131A Pending JPH0733507A (en) 1993-07-15 1993-07-15 Panel material

Country Status (1)

Country Link
JP (1) JPH0733507A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002021214A (en) * 2000-07-10 2002-01-23 Fujita Corp Building material capable of deodorization paint and building using these material and paint and deodorizing method
JP2002029793A (en) * 2000-07-12 2002-01-29 Daiwabo Co Ltd Composite fiber for reinforcing cement
WO2006137655A1 (en) * 2005-06-21 2006-12-28 Pine Tex Co., Ltd. Advanced method of making frc reinforced by woven fabric coated with thermoset resin
WO2009022488A1 (en) * 2007-08-15 2009-02-19 Shinsuke Tsubakihara Reinforced cured object and process for producing the same

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002021214A (en) * 2000-07-10 2002-01-23 Fujita Corp Building material capable of deodorization paint and building using these material and paint and deodorizing method
JP2002029793A (en) * 2000-07-12 2002-01-29 Daiwabo Co Ltd Composite fiber for reinforcing cement
WO2006137655A1 (en) * 2005-06-21 2006-12-28 Pine Tex Co., Ltd. Advanced method of making frc reinforced by woven fabric coated with thermoset resin
WO2009022488A1 (en) * 2007-08-15 2009-02-19 Shinsuke Tsubakihara Reinforced cured object and process for producing the same

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