JPH0731830A - Carbon dioxide absorbent containing triamine compound as effective component - Google Patents
Carbon dioxide absorbent containing triamine compound as effective componentInfo
- Publication number
- JPH0731830A JPH0731830A JP5071636A JP7163693A JPH0731830A JP H0731830 A JPH0731830 A JP H0731830A JP 5071636 A JP5071636 A JP 5071636A JP 7163693 A JP7163693 A JP 7163693A JP H0731830 A JPH0731830 A JP H0731830A
- Authority
- JP
- Japan
- Prior art keywords
- carbon dioxide
- compound
- effective component
- dioxide absorbent
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明はトリアミン化合物を有効
成分とする二酸化炭素吸収剤及び新規トリアミン化合物
に関する。The present invention relates to a carbon dioxide absorbent containing a triamine compound as an active ingredient and a novel triamine compound.
【０００２】[0002]
【従来の技術】式（Ａ）：2. Description of the Related Art Formula (A):
【化３】 で表されるトリアミン化合物（化合物Ａ）を有効成分と
する二酸化炭素吸収剤が知られており、この吸収剤は二
酸化炭素を１００〜１６０℃の温度で脱離すると報告さ
れている（USP4,112,050) 。[Chemical 3] A carbon dioxide absorbent containing a triamine compound (compound A) represented by the following as an active ingredient is known, and this absorbent is reported to desorb carbon dioxide at a temperature of 100 to 160 ° C (USP 4,112,050). ).
【０００３】また、式（Ｂ）：Further, the formula (B):
【化４】 で表されるトリアミン化合物（化合物Ｂ）が高分子用の
光安定剤の原料として用いられることが知られている
（USP4,547,538) 。[Chemical 4] It is known that the triamine compound represented by (Compound B) is used as a raw material of a light stabilizer for polymers (USP4,547,538).
【０００４】[0004]
【発明が解決しようとする課題】本発明の目的は、二酸
化炭素を効率よく吸収し、かつ１００℃以下の温度にお
いても二酸化炭素を効率よく脱離する優れた性質を有す
るトリアミン化合物を有効成分とする二酸化炭素吸収剤
及び新規トリアミン化合物を提供することにある。An object of the present invention is to use a triamine compound as an active ingredient, which has excellent properties of efficiently absorbing carbon dioxide and efficiently desorbing carbon dioxide even at a temperature of 100 ° C. or lower. To provide a carbon dioxide absorbent and a novel triamine compound.
【０００５】[0005]
【課題を解決するための手段】本発明は、式（Ｉ）：The present invention provides the formula (I):
【化５】 （式中、Ｒ1 及びＲ2 は同一又は異なって水素又はアル
キルを表し、Ｒ3 はアルキルを表す）で表されるトリア
ミン化合物（化合物Ｉ）を有効成分とする二酸化炭素吸
収剤及び式（Ｉa）：[Chemical 5] (Wherein R 1 and R 2 are the same or different and each represents hydrogen or alkyl, and R 3 represents alkyl), and a carbon dioxide absorbent containing a triamine compound (compound I) as an active ingredient and a formula (I a ):
【化６】 （式中、Ｒ1a は水素又はアルキルを表し、Ｒ1aが水素
のとき、Ｒ2a 及びＲ3aは同一又は異なってアルキルを
表し、Ｒ1a がアルキルのとき、Ｒ2a 及びＲ3aは同一又
は異なって水素又はアルキルを表す）で表される新規ト
リアミン化合物を提供する。[Chemical 6] (In the formula, R 1a represents hydrogen or alkyl, when R 1a is hydrogen, R 2a and R 3a are the same or different and represent alkyl, and when R 1a is alkyl, R 2a and R 3a are the same or different. Represents a hydrogen atom or an alkyl group).
【０００６】式（Ｉ）及び（Ｉa）の定義中、アルキル
としては炭素数１〜３のアルキル、例えば、メチル、エ
チル、ｎ−プロピル、イソプロピルが挙げられる。In the definitions of formulas (I) and (I a ), alkyl includes alkyl having 1 to 3 carbon atoms, such as methyl, ethyl, n-propyl and isopropyl.
【０００７】以下に、化合物Ｉの製法を説明する。The production method of compound I will be described below.
【化７】 （式中、Ｒ1 、Ｒ2 及びＲ3 は前記と同義である）[Chemical 7] (In the formula, R 1 , R 2 and R 3 are as defined above)
【０００８】化合物III は２−アミノ−２−メチル−１
−プロパノール（以下、ＡＭＰと称する）と等モルの硫
酸とを溶媒中、５０〜１５０℃で５時間〜３日間反応さ
せた後、濾取、洗浄することにより得られる。Compound III is 2-amino-2-methyl-1
-Propanol (hereinafter referred to as AMP) and equimolar sulfuric acid are reacted in a solvent at 50 to 150 ° C for 5 hours to 3 days, and then collected by filtration and washed.
【０００９】溶媒としては、例えばシクロヘキサン等の
脂肪族炭化水素、トルエン等の芳香族炭化水素、クロロ
ベンゼン等の芳香族炭化水素のハロゲン置換体等が挙げ
られる。Examples of the solvent include aliphatic hydrocarbons such as cyclohexane, aromatic hydrocarbons such as toluene, and halogen-substituted aromatic hydrocarbons such as chlorobenzene.
【００１０】化合物Ｉは化合物IIIとその１〜１０倍モ
ルの化合物IIとを、溶媒の存在または不存在下に、５０
〜１５０℃で５時間〜３日間反応させた後、水酸化ナト
リウム等のアルカリでフリー化することにより得られ
る。The compound I is obtained by mixing the compound III with 1 to 10 times the molar amount of the compound II in the presence or absence of a solvent.
It can be obtained by reacting at ˜150 ° C. for 5 hours to 3 days and then freeing it with an alkali such as sodium hydroxide.
【００１１】溶媒としては、例えば、水、シクロヘキサ
ン等の脂肪族炭化水素、トルエン等の芳香族炭化水素、
クロロベンゼン等の芳香族炭化水素のハロゲン置換体、
イソプロピルエーテル等のエーテル等があげられる。ま
た、過剰の化合物IIを溶媒として用いることもできる。Examples of the solvent include water, aliphatic hydrocarbons such as cyclohexane, aromatic hydrocarbons such as toluene,
Halogen-substituted aromatic hydrocarbons such as chlorobenzene,
Examples thereof include ethers such as isopropyl ether. Also, an excess of compound II can be used as a solvent.
【００１２】反応後、化合物Ｉは、例えば抽出、蒸留等
の通常の精製を行うことにより、分離、精製される。After the reaction, the compound I is separated and purified by performing ordinary purification such as extraction and distillation.
【００１３】次に、化合物Ｉの代表例を表１に示す。
尚、表中、化合物１、２及び３とは後記実施例１、２及
び３で得られた化合物１、２及び３に相当する。Next, Table 1 shows typical examples of the compound I.
In the table, compounds 1, 2 and 3 correspond to compounds 1, 2 and 3 obtained in Examples 1, 2 and 3 described below.
【００１４】[0014]
【表１】 [Table 1]
【００１５】次に、化合物Ｉを有効成分とする二酸化炭
素の吸収剤について説明する。化合物Ｉを有効成分とす
る二酸化炭素吸収剤を約４０℃において、例えば、二酸
化炭素含有排ガスと接触させ、二酸化炭素を該吸収剤に
吸収させる。次いで、吸収させた二酸化炭素を９０〜１
１０℃で脱離させ、二酸化炭素を回収する。Next, a carbon dioxide absorbent containing compound I as an active ingredient will be described. A carbon dioxide absorbent containing compound I as an active ingredient is brought into contact with, for example, a carbon dioxide-containing exhaust gas at about 40 ° C. to absorb carbon dioxide into the absorbent. Then, the absorbed carbon dioxide is 90 to 1
Desorb at 10 ° C. to collect carbon dioxide.
【００１６】化合物Ｉは通常、水または水と溶剤とで希
釈して用いられる。化合物Ｉを水で希釈して用いるに
は、化合物Ｉの濃度は１０〜９０wt% 、好ましくは１５
〜５０wt% とする。さらに、アルカリ金属の重炭酸塩、
炭酸塩等の無機化合物を加えてもよい。この場合、無機
化合物の濃度は１０〜５０wt% が好ましく、化合物Ｉは
２〜２０wt% の濃度で用いられる。The compound I is usually used by diluting it with water or water and a solvent. When compound I is used by diluting with water, the concentration of compound I is 10 to 90% by weight, preferably 15
-50 wt% In addition, alkali metal bicarbonate,
Inorganic compounds such as carbonates may be added. In this case, the concentration of the inorganic compound is preferably 10 to 50% by weight, and the compound I is used in a concentration of 2 to 20% by weight.
【００１７】化合物Ｉを水と溶剤で希釈して用いるに
は、化合物Ｉの濃度は１０〜９０ｗｔ％、好ましくは１
５〜５０ｗｔ％ とする。When compound I is used by diluting it with water and a solvent, the concentration of compound I is 10 to 90% by weight, preferably 1
5 to 50 wt%.
【００１８】溶剤としては、Ｎ−アルキル化ピロリド
ン、スルホン、スルホキシド、グリコール、グルコール
エーテル等が挙げられ、水との混合比率は５〜９５wt%
とする。Examples of the solvent include N-alkylated pyrrolidone, sulfone, sulfoxide, glycol, glycol ether and the like, and the mixing ratio with water is 5 to 95 wt%.
And
【００１９】かくして、本発明の二酸化炭素吸収剤は、
発電所、工場等からの排ガス中の二酸化炭素を吸収する
ことにおいて、好適に用いられる。Thus, the carbon dioxide absorbent of the present invention is
It is preferably used in absorbing carbon dioxide in exhaust gas from power plants, factories, and the like.
【００２０】[0020]
【実施例】以下に実施例を挙げて本発明をさらに詳しく
説明する。 実施例１ ４,７−ジアザ−２−アミノ−２,７−ジメチ
ルオクタン（化合物１）の合成 滴下ロート、水分分離管及び攪拌棒を備えた５リットル
反応フラスコにＡＭＰ４４８.７ｇ（５モル）とトルエ
ン３リットルを仕込み、攪拌下、滴下ロートより濃硫酸
４９０ｇ（５モル) を約２時間で滴下した。滴下中、内
温は約６０℃まで上昇するが、滴下終了後はオイルバス
加熱を行い、還流下、生成する水を水分分離管により除
いた。反応の進行に伴い内容物は、粥状〜ゼラチン状〜
固体状と変化した。水分の留出が終わった時点（８〜１
２時間）で反応液を冷却し固形物を減圧濾取し、エタノ
ールで洗浄後乾燥して、ＡＭＰの硫酸エステル６７６ｇ
（収率８０％）を得た。EXAMPLES The present invention will be described in more detail with reference to the following examples. Example 1 Synthesis of 4,7-diaza-2-amino-2,7-dimethyloctane (Compound 1) AMP448.7 g (5 mol) was added to a 5 liter reaction flask equipped with a dropping funnel, a water separation tube and a stirring rod. Toluene (3 liters) was charged, and under stirring, 490 g (5 mol) of concentrated sulfuric acid was dropped from the dropping funnel in about 2 hours. During the dropping, the internal temperature rises to about 60 ° C., but after the dropping, heating in an oil bath was performed, and the produced water was removed through a water separation tube under reflux. As the reaction progresses, the content is porridge-gelatinous-
It changed to a solid state. When the water is distilled off (8 to 1
(2 hours), the reaction solution was cooled, the solid matter was collected by filtration under reduced pressure, washed with ethanol and dried to give 676 g of AMP sulfate ester.
(Yield 80%) was obtained.
【００２１】次いで、コンデンサー及び攪拌棒を備えた
３リットル反応フラスコにＡＭＰの硫酸エステル５０
７.４ｇ（３モル）、Ｎ,Ｎ−ジメチルエチレンジアミン
７９３.４ｇ（９モル）及び水５１０mlを加え１２時間
加熱還流した。反応液を冷却した後、水酸化ナトリウム
水溶液を用いて系内に存在するアミンの硫酸塩をフリー
化した。メタノール２リットルを加えて、析出した硫酸
ナトリウムを濾別した後、メタノールをロータリーエバ
ポレーターで留去し、減圧蒸留して２３９ｇ（収率５０
％）の化合物１を得た。Then, AMP sulfate 50 was added to a 3 liter reaction flask equipped with a condenser and a stir bar.
7.4 g (3 mol), N, N-dimethylethylenediamine 793.4 g (9 mol) and water 510 ml were added and the mixture was heated under reflux for 12 hours. After cooling the reaction solution, the amine sulfate existing in the system was made free using an aqueous sodium hydroxide solution. After adding 2 liters of methanol and separating the precipitated sodium sulfate by filtration, methanol was distilled off by a rotary evaporator and distilled under reduced pressure to yield 239 g (yield 50
%) Of compound 1.
【００２２】その物性を以下に示す。 外観：無色透明の液体 沸点：８４℃／２３mmHg 元素分析値（Ｃ8Ｈ21Ｎ3 として） 測定値 : C 60.12% H 13.44% N 26.21% 計算値 : C 60.33% H 13.29% N 26.38%1 H-NMR (δ値) : 1.09(6H, s), 1.49(3H, br), 2.22(6
H, s), 2.41(6H, t), 2.45(2H, s), 2.72(2H, t) IR (cm-1) : 3300〜3400(br), 2950, 2820, 2770, 146
0, 1370, 1280, 1140, 1040The physical properties are shown below. Appearance: colorless transparent liquid Boiling point: 84 ℃ / 23mmHg Elemental analysis value (as C 8 H 21 N 3 ) Measured value: C 60.12% H 13.44% N 26.21% Calculated value: C 60.33% H 13.29% N 26.38% 1 H -NMR (δ value): 1.09 (6H, s), 1.49 (3H, br), 2.22 (6
H, s), 2.41 (6H, t), 2.45 (2H, s), 2.72 (2H, t) IR (cm -1 ): 3300 to 3400 (br), 2950, 2820, 2770, 146
0, 1370, 1280, 1140, 1040
【００２３】実施例２ ４,７−ジアザ−２−アミノ−
２,４−ジメチルオクタン（化合物２）の合成 実施例１のＮ,Ｎ−ジメチルエチレンジアミンの代わり
にＮ,Ｎ'−ジメチルエチレンジアミンを用いる以外は実
施例１と同様にして化合物２を得た。Example 2 4,7-Diaza-2-amino-
Synthesis of 2,4-dimethyloctane (Compound 2) Compound 2 was obtained in the same manner as in Example 1 except that N, N'-dimethylethylenediamine was used instead of N, N-dimethylethylenediamine in Example 1.
【００２４】その物性を以下に示す。 外観：無色透明の液体 沸点：１１０℃／４０mmHg 元素分析値（Ｃ8Ｈ21Ｎ3 として） 測定値 : C 60.16% H 13.21% N 26.09% 計算値 : C 60.33% H 13.29% N 26.38%1 H-NMR (δ値) : 1.06(6H, s), 1.44(3H, br), 2.25(2
H, s), 2.33(3H, s), 2.45(3H, s), 2.62(4H, m) IR (cm-1) : 3300〜3400(br), 2960, 2840, 2790, 159
0, 1460, 1040The physical properties are shown below. Appearance: colorless and transparent liquid Boiling point: 110 ° C / 40mmHg Elemental analysis value (as C 8 H 21 N 3 ) Measured value: C 60.16% H 13.21% N 26.09% Calculated value: C 60.33% H 13.29% N 26.38% 1 H -NMR (δ value): 1.06 (6H, s), 1.44 (3H, br), 2.25 (2
H, s), 2.33 (3H, s), 2.45 (3H, s), 2.62 (4H, m) IR (cm -1 ): 3300 to 3400 (br), 2960, 2840, 2790, 159
0, 1460, 1040
【００２５】実施例３ ４,７−ジアザ−２−アミノ−
２,４,７−トリメチルオクタン（化合物３）の合成 実施例１において、Ｎ,Ｎ−ジメチルエチレンジアミン
の代わりにＮ,Ｎ,Ｎ'−トリメチルエチレンジアミンを
用いる以外は実施例１と同様にして化合物３を得た。Example 3 4,7-Diaza-2-amino-
Synthesis of 2,4,7-trimethyloctane (Compound 3) Compound 3 was prepared in the same manner as in Example 1 except that N, N, N'-trimethylethylenediamine was used instead of N, N-dimethylethylenediamine. Got
【００２６】その物性を以下に示す。 外観：無色透明の液体 沸点：７６℃／１２mmHg 元素分析値（Ｃ9Ｈ23Ｎ3 として） 測定値 : C 61.26% H 12.40% N 23.21% 計算値 : C 62.38% H 13.38% N 24.25%1 H-NMR (δ値) : 1.10(6H, s), 1.70(1H, br), 2.24(6
H, s), 2.25(2H, s), 2.36(3H, s), 2.40(2H, m), 2.59
(2H, m) IR (cm-1) : 3300〜3400(br), 2940, 2750, 1460, 112
0, 1035, 840The physical properties are shown below. Appearance: colorless transparent liquid Boiling point: 76 ℃ / 12mmHg Elemental analysis value (as C 9 H 23 N 3 ) Measured value: C 61.26% H 12.40% N 23.21% Calculated value: C 62.38% H 13.38% N 24.25% 1 H -NMR (δ value): 1.10 (6H, s), 1.70 (1H, br), 2.24 (6
H, s), 2.25 (2H, s), 2.36 (3H, s), 2.40 (2H, m), 2.59
(2H, m) IR (cm -1 ): 3300-3400 (br), 2940, 2750, 1460, 112
0, 1035, 840
【００２７】実施例４ 内容量１００mlのステンレス製反応器に、化合物１、
２、３、Ａ及びＢの１Ｍ水溶液５０mlを各々単独に仕込
み、大気圧下、８００rpm で攪拌しながら内温４０℃に
調整した。ベントバルブを閉じ、二酸化炭素を約２５kg
／cm2 に封入した１００mlの蓄圧器から、予め二酸化炭
素で置換した導入管を通して、１kg／cm2の圧力で二酸
化炭素を反応器内に導入して吸収させた。１０〜１５分
間で吸収を終了した。吸収温度４０℃における飽和吸収
量を蓄圧器の圧力低下から求めた。その結果を表２に示
す。Example 4 Compound 1 was placed in a stainless steel reactor having an internal volume of 100 ml.
50 ml of 1M aqueous solutions of 2, 3, A and B were separately charged, and the internal temperature was adjusted to 40 ° C. while stirring at 800 rpm under atmospheric pressure. Close the vent valve, about 25 kg of carbon dioxide
Carbon dioxide was introduced into the reactor at a pressure of 1 kg / cm 2 from a 100 ml pressure accumulator sealed in / cm 2 through an inlet tube previously replaced with carbon dioxide to absorb the carbon dioxide. Absorption was completed in 10 to 15 minutes. The saturated absorption amount at the absorption temperature of 40 ° C. was calculated from the pressure drop of the pressure accumulator. The results are shown in Table 2.
【００２８】[0028]
【表２】 [Table 2]
【００２９】次に、ベントバルブを開放し、反応器内の
残ガスを除いた後、攪拌下、９℃／分（〜８０℃）４℃
／分（８０〜９５℃）の昇温速度で反応器内温を上昇さ
せ、発生する二酸化炭素に同伴する水蒸気を冷却、凝縮
し脱水した。得られた二酸化炭素の発生量を読み取り、
８０、９０及び９５℃の温度までの脱離率 (対４０℃飽
和吸収量) を求めた。その結果を表３に示す。Next, after opening the vent valve and removing the residual gas in the reactor, it was stirred at 9 ° C / min (~ 80 ° C) at 4 ° C.
The temperature inside the reactor was raised at a heating rate of / min (80 to 95 ° C.), and the steam accompanying the generated carbon dioxide was cooled, condensed and dehydrated. Read the amount of carbon dioxide generated,
The desorption rate up to temperatures of 80, 90 and 95 ° C (vs. 40 ° C saturated absorption) was determined. The results are shown in Table 3.
【００３０】[0030]
【表３】 [Table 3]
【００３１】また、飽和吸収量からの８０、９０及び９
５℃における二酸化炭素脱離量をアミン化合物１ｇ当た
りの二酸化炭素（ＣＯ2)の処理容量として図１に示す。Also, 80, 90 and 9 from the saturated absorption amount
The amount of desorbed carbon dioxide at 5 ° C. is shown in FIG. 1 as a treatment capacity of carbon dioxide (CO 2 ) per 1 g of the amine compound.
【００３２】図１から９０及び９５℃において本発明化
合物（化合物１、２及び３）は既知化合物（化合物Ａ及
びＢ）に比べて、単位１ｇ当たりのＣＯ2 処理容量が非
常に優れていることが判る。1 to 90 and 95 ° C., the compounds of the present invention (Compounds 1, 2 and 3) have a very excellent CO 2 treatment capacity per unit of 1 g as compared with the known compounds (Compounds A and B). I understand.
【００３３】[0033]
【発明の効果】本発明化合物は二酸化炭素を効率よく吸
収し、かつ１００℃以下の温度においても二酸化炭素を
効率よく脱離するという優れた性質を有する。The compound of the present invention has excellent properties of efficiently absorbing carbon dioxide and efficiently desorbing carbon dioxide even at a temperature of 100 ° C. or lower.
【図１】 アミン化合物１ｇ当たりの二酸化炭素の処理
容量を説明するためのグラフである。FIG. 1 is a graph for explaining a treatment capacity of carbon dioxide per 1 g of an amine compound.
Claims (2)
キルを表し、Ｒ3 はアルキルを表す）で表されるトリア
ミン化合物を有効成分とする二酸化炭素吸収剤。1. Formula (I): (In the formula, R 1 and R 2 are the same or different and each represents hydrogen or alkyl, and R 3 represents alkyl.) A carbon dioxide absorbent containing a triamine compound as an active ingredient.
のとき、Ｒ2a 及びＲ3aは同一又は異なってアルキルを
表し、Ｒ1a がアルキルのとき、Ｒ2a 及びＲ3aは同一又
は異なって水素又はアルキルを表す）で表されるトリア
ミン化合物。2. Formula (I a ): (In the formula, R 1a represents hydrogen or alkyl, when R 1a is hydrogen, R 2a and R 3a are the same or different and represent alkyl, and when R 1a is alkyl, R 2a and R 3a are the same or different. Represents hydrogen or alkyl).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5071636A JPH0731830A (en) | 1993-03-30 | 1993-03-30 | Carbon dioxide absorbent containing triamine compound as effective component |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5071636A JPH0731830A (en) | 1993-03-30 | 1993-03-30 | Carbon dioxide absorbent containing triamine compound as effective component |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0731830A true JPH0731830A (en) | 1995-02-03 |
Family
ID=13466340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5071636A Withdrawn JPH0731830A (en) | 1993-03-30 | 1993-03-30 | Carbon dioxide absorbent containing triamine compound as effective component |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0731830A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006150298A (en) * | 2004-11-30 | 2006-06-15 | Mitsubishi Heavy Ind Ltd | Absorption liquid, and co2 or h2s removal apparatus and method employing it |
| EP2097156A1 (en) * | 2006-12-28 | 2009-09-09 | Cansolv Technologies Inc. | Process for the recovery of carbon dioxide from a gas stream |
| JP2011525423A (en) * | 2008-06-23 | 2011-09-22 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for removal of acid gases from absorbent and fluid streams, in particular exhaust gas |
| JP2012030223A (en) * | 2010-07-30 | 2012-02-16 | General Electric Co <Ge> | Carbon dioxide capture system and carbon dioxide capture method |
| US10888816B2 (en) | 2016-11-01 | 2021-01-12 | Shell Oil Company | Process for producing a purified gas stream |
-
1993
- 1993-03-30 JP JP5071636A patent/JPH0731830A/en not_active Withdrawn
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006150298A (en) * | 2004-11-30 | 2006-06-15 | Mitsubishi Heavy Ind Ltd | Absorption liquid, and co2 or h2s removal apparatus and method employing it |
| EP2097156A1 (en) * | 2006-12-28 | 2009-09-09 | Cansolv Technologies Inc. | Process for the recovery of carbon dioxide from a gas stream |
| EP2097156A4 (en) * | 2006-12-28 | 2011-11-09 | Cansolv Technologies Inc | Process for the recovery of carbon dioxide from a gas stream |
| JP2011525423A (en) * | 2008-06-23 | 2011-09-22 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for removal of acid gases from absorbent and fluid streams, in particular exhaust gas |
| JP2012030223A (en) * | 2010-07-30 | 2012-02-16 | General Electric Co <Ge> | Carbon dioxide capture system and carbon dioxide capture method |
| US10888816B2 (en) | 2016-11-01 | 2021-01-12 | Shell Oil Company | Process for producing a purified gas stream |
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| A300 | Withdrawal of application because of no request for examination |
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