JPH0726943A - Control method for denitration device - Google Patents

Control method for denitration device

Info

Publication number
JPH0726943A
JPH0726943A JP5153538A JP15353893A JPH0726943A JP H0726943 A JPH0726943 A JP H0726943A JP 5153538 A JP5153538 A JP 5153538A JP 15353893 A JP15353893 A JP 15353893A JP H0726943 A JPH0726943 A JP H0726943A
Authority
JP
Japan
Prior art keywords
engine
signal
amount
ammonia
controlling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP5153538A
Other languages
Japanese (ja)
Inventor
Shuya Nagayama
脩也 永山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP5153538A priority Critical patent/JPH0726943A/en
Publication of JPH0726943A publication Critical patent/JPH0726943A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Landscapes

  • Exhaust Gas After Treatment (AREA)
  • Treating Waste Gases (AREA)

Abstract

PURPOSE:To control the filling amount of ammonia in high accuracy same as the case of a NOx analyzer arrangement at a low cost, and to control response to an engine load earlier than the case of using an NOx analyzer. CONSTITUTION:In control method of a denitration device arranged in such a manner that a denitration device 22 is connected to an engine 21 provided with an output detector 24 or a gas turbine and exhaust gas discharged from the engine 21 or the gas turnine is discharged toward the atmosphere, a central processing unit 25 is connected to the output detector 24. A signal converter 26 and a control valve 27 for controlling the filling amount of ammonia which is necessary for denitration are connected to the central processing unit 25, and two and more elements in 8 elements of an atmosphere temperature, atmosphere pressure, atmosphere humidity, the scavenging temperature after an air cooler, the amount injected water or steam toward a combustion chamber, a ratio including nitrogen in fuel, a piston compressing rate, and a fuel injection timing delay amount are inputted into the central processing unit 25. It is thus possible to correct a signal which is a base for controlling the filling amount of ammonia.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は脱硝装置の制御方法に
関し、特にディーゼルエンジン又はガスエンジン又はガ
スタービン用脱硝装置のアノモニア注入制御方法に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for controlling a denitration device, and more particularly to an anomonia injection control method for a denitration device for a diesel engine, a gas engine or a gas turbine.

【0002】[0002]

【従来の技術】図3は、従来の脱硝装置システムフロー
を示す。また、図4は、従来に係るアンモニア注入制御
信号のフローを示す。図中の符番1は、ディーゼルエン
ジン(又はガスエンジン又はガスタービン)である。こ
のディーゼルエンジン1には、脱硝装置2を介して煙突
3が接続されている。これにより、ディーゼルエンジン
1から排出される排ガスは脱硝装置2を通り煙突3へ導
かれ、大気へ放出されている。前記ディーゼルエンジン
1には、エンジン出力検出器4が設けられている。この
エンジン出力検出器4には、関数発生器5,乗算器6,
信号変換器7,アンモニア注入量制御弁8が順次接続さ
れている。前記乗算器6には、エンジン出口NOx濃度
分析計9が接続されている。なお、図中の符番10はアン
モニア注入ノズル、符番11はアンモニア、符番12はNO
x補正信号である。脱硝に必要なアンモニアの注入量
は、エンジン出力検出器4の信号とNOx濃度分析計9
の出力信号から求められ、アンモニア注入量制御弁8で
その都度適切な注入量となるように制御されている。
2. Description of the Related Art FIG. 3 shows a conventional denitration system flow. Further, FIG. 4 shows a flow of a conventional ammonia injection control signal. Reference numeral 1 in the drawing is a diesel engine (or gas engine or gas turbine). A chimney 3 is connected to the diesel engine 1 via a denitration device 2. As a result, the exhaust gas discharged from the diesel engine 1 is guided to the chimney 3 through the denitration device 2 and is discharged to the atmosphere. The diesel engine 1 is provided with an engine output detector 4. The engine output detector 4 includes a function generator 5, a multiplier 6, and
The signal converter 7 and the ammonia injection amount control valve 8 are sequentially connected. An engine outlet NOx concentration analyzer 9 is connected to the multiplier 6. In the figure, reference numeral 10 is an ammonia injection nozzle, reference numeral 11 is ammonia, and reference numeral 12 is NO.
x correction signal. The injection amount of ammonia required for denitration is determined by the signal from the engine output detector 4 and the NOx concentration analyzer 9
Is calculated from the output signal of the above, and is controlled by the ammonia injection amount control valve 8 so that the injection amount becomes appropriate each time.

【0003】[0003]

【発明が解決しようとする課題】ところで、高精度の脱
硝(エンジン出口NOx濃度にできるだけ追随し、注入
アンモニア量を常に適正にすること)が強く求められる
脱硝装置においては、エンジン出口のNOx濃度そのも
のを検出してアンモニア注入量制御装置に導入しアンモ
ニア注入量を直接的に制御する方式が採用されている。
この場合、NOx濃度分析計を使用することにより次の
問題点がある。 (1) NOx濃度分析計は、200〜500万円/台と非
常に高価である。 (2) NOx濃度分析計は内蔵機器の補修及び指示値の定
期的校正並びに標準ガスの補充等のため、取扱いが非常
に煩雑である。 (3) NOx濃度分析計の出力信号の追随は、サンプルガ
ス導入ラインの導入時間及びNOx濃度分析部の応答時
間により、分析で数10秒の応答遅れが不可欠であり、
特にエンジン負荷変化の煩雑な場合の応答上問題があ
る。
By the way, in the denitrification device in which highly precise denitration (following the NOx concentration at the engine outlet as much as possible and always making the injected ammonia amount appropriate) is strongly demanded, the NOx concentration at the engine outlet itself. Is detected and introduced into the ammonia injection amount control device to directly control the ammonia injection amount.
In this case, the use of a NOx concentration analyzer has the following problems. (1) The NOx concentration analyzer is extremely expensive at 2 to 5 million yen / unit. (2) The NOx concentration analyzer is very complicated to handle because it repairs the internal equipment, periodically calibrates the indicated value, and replenishes the standard gas. (3) In order to follow the output signal of the NOx concentration analyzer, a response delay of several tens of seconds is essential in the analysis due to the introduction time of the sample gas introduction line and the response time of the NOx concentration analysis unit.
In particular, there is a problem in response when the engine load change is complicated.

【0004】この発明はこうした事情を考慮してなされ
たもので、廉価でNOx分析計を設置した場合と同等の
精度の高いアンモニア注入量制御を行なうことができる
とともに、NOx分析計を用いる場合よりエンジン負荷
応答の早い制御を可能にできる脱硝装置の制御方法を提
供することを目的とする。
The present invention has been made in consideration of such circumstances, and it is possible to perform the ammonia injection amount control with high accuracy equivalent to the case where the NOx analyzer is installed at a low price, and to compare with the case where the NOx analyzer is used. An object of the present invention is to provide a method for controlling a denitration device that enables quick control of engine load response.

【0005】[0005]

【課題を解決するための手段】この発明は、出力検出器
を備えたエンジン又はガスタービンに脱硝装置を接続し
てエンジン又はガスタービンから排出される排ガスを大
気へ放出する脱硝装置の制御方法において、前記出力検
出器に中央処理装置を接続するとともに、前記中央処理
装置に信号変換器及び脱硝に必要なアンモニアの注入量
を制御する制御弁を接続させ、大気温度,大気圧力,大
気湿度,空気冷却器後の掃気温度,燃焼室への水もしく
は蒸気噴射量,燃料中窒素含有率,ピストン圧縮比及び
燃料噴射タイミング遅延量の8要素のうち2つ以上を前
記中央処理装置へ入力して、アンモニア注入量を制御す
る基準となる信号を補正することを特徴とする脱硝装置
の制御方法である。
SUMMARY OF THE INVENTION The present invention relates to a method for controlling a denitration device, in which a denitration device is connected to an engine or a gas turbine equipped with an output detector, and exhaust gas discharged from the engine or the gas turbine is released to the atmosphere. , A central processing unit is connected to the output detector, a signal converter and a control valve for controlling the injection amount of ammonia required for denitration are connected to the central processing unit, and the atmospheric temperature, atmospheric pressure, atmospheric humidity, air Two or more of the eight elements of the scavenging temperature after the cooler, the amount of water or steam injected into the combustion chamber, the nitrogen content in the fuel, the piston compression ratio, and the fuel injection timing delay amount are input to the central processing unit, A method for controlling a denitration device is characterized in that a signal serving as a reference for controlling an ammonia injection amount is corrected.

【0006】この発明において、アンモニア注入量を制
御する基準となる信号とは、例えばエンジン出力信号か
らエンジン各出力時における制御の基準となるエンジン
出口排ガス量とエンジン出口NOx濃度を予め実測され
たデータに基づき予め組込まれた演算式により求め、か
つその2つの信号を乗算することにより算出されたエン
ジン出口のNOx総量を示す信号である
In the present invention, the signal serving as a reference for controlling the amount of injected ammonia is, for example, data obtained by previously measuring the engine outlet exhaust gas amount and the engine outlet NOx concentration which serve as the reference for control at each engine output from the engine output signal. Is a signal indicating the total amount of NOx at the engine outlet, which is obtained by an arithmetic expression previously incorporated based on the above equation and is calculated by multiplying the two signals.

【0007】[0007]

【作用】この発明において、エンジンから排出されるN
Oxの濃度は大気温度,大気圧力,大気湿度,中間空気
冷却器を有する往復動内燃エンジンにおいては空気冷却
器後の掃気湿度,及び燃料中の窒素含有率並びにエンジ
ンチューニング要素(ピストン圧縮比,燃料噴射タイミ
ング遅延量など)により大幅に変動し、その各々の要素
とエンジンから排出されるNOx濃度との相関は夫々の
エンジンの種類並びにモデルの特性として経験的に解明
されている。
In the present invention, N discharged from the engine
Ox concentration is atmospheric temperature, atmospheric pressure, atmospheric humidity, scavenging humidity after air cooler in reciprocating internal combustion engine with intermediate air cooler, nitrogen content in fuel and engine tuning factors (piston compression ratio, fuel The correlation between each element and the NOx concentration exhausted from the engine varies empirically as the type of each engine and the characteristics of the model.

【0008】従って、これらの要素の全部又は一部の特
性を予め中央処理装置に組み込み、且つ、各要素の表わ
す信号を夫々の検出器から又は直接に演算器に入力すれ
ば、エンジンから排出されるNOx濃度を正確に且つ先
行的に演算した信号を使用して、アンモニア注入量制御
を時間遅れが無く且つ高精度で適正に行うことができ
る。
Therefore, if the characteristics of all or some of these elements are incorporated in the central processing unit in advance and the signals represented by each element are input from the respective detectors or directly to the arithmetic units, they are discharged from the engine. The ammonia injection amount control can be appropriately performed with high accuracy and without time delay by using a signal that accurately and proactively calculates the NOx concentration according to the present invention.

【0009】[0009]

【実施例】以下、この発明の一実施例を図1及び図2を
参照して説明する。図中の符番21は、ディーゼルエンジ
ン(又はガスエンジン又はガスタービン)である。この
ディーゼルエンジン21には、脱硝装置22を介して煙突23
が接続されている。前記ディーゼルエンジン21には、エ
ンジン出力検出器24が設けられている。このエンジン出
力検出器24には、中央処理装置(CPU)25,信号変換
器26,アンモニア注入量制御弁27が順次接続されてい
る。なお、図中の符番28はアンモニア注入ノズル、符番
29はアンモニアである。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to FIGS. Reference numeral 21 in the drawing is a diesel engine (or gas engine or gas turbine). This diesel engine 21 has a chimney 23 through a denitration device 22.
Are connected. The diesel engine 21 is provided with an engine output detector 24. A central processing unit (CPU) 25, a signal converter 26, and an ammonia injection amount control valve 27 are sequentially connected to the engine output detector 24. Note that the reference numeral 28 in the figure is the ammonia injection nozzle, the reference numeral
29 is ammonia.

【0010】図1はNOx濃度補正信号30をCPU25に
取り組んでいるものであり、ディーゼルエンジン21へ大
気(空気)の温度,圧力等を調整し、燃料と共に噴射
し、燃焼排ガスを排出する。この排ガスにアンモニア注
入量制御弁27にて調整されたアンモニア29をアンモニア
注入ノズル28にて注入し混合した後、脱硝装置22内でN
Oxを除去した後、煙突23へ導かれ大気の放出されてい
る。前記エンジン出力検出器24より得た信号はCPU25
へ送り、別に得たNOx補正信号30,31によって補正を
加えた後、信号変換器26へ送り、これを介してアンモニ
ア注入量制御弁27を調整するものである。
In FIG. 1, the NOx concentration correction signal 30 is applied to the CPU 25. The temperature, pressure, etc. of the atmosphere (air) are adjusted to the diesel engine 21, and the diesel engine 21 is injected together with the fuel to discharge the combustion exhaust gas. Ammonia 29 adjusted by the ammonia injection amount control valve 27 is injected into the exhaust gas by the ammonia injection nozzle 28 and mixed, and then N 2 is discharged in the denitration device 22.
After removing Ox, it is guided to the chimney 23 and emitted to the atmosphere. The signal obtained from the engine output detector 24 is the CPU 25.
To the signal converter 26, and the ammonia injection amount control valve 27 is adjusted via the signal converter 26.

【0011】前記NOx補正信号30,31は変動値補正で
あって、図示しない各々のセンサーによって大気温度,
大気圧力,大気湿度,掃気温度及び水又は水蒸気噴射量
を得て、この信号を関数発生機能cへ入力する。また、
NOx補正信号31は固定値補正であって、図示しない各
々のセンサーによって燃料中窒素含有率,エンジンチュ
ーニング要素(ピストン圧縮比,燃料噴射タイミング遅
延量等)を得て、この信号を関数発生機能dへ入力する
構成となっている。
The NOx correction signals 30 and 31 are fluctuation value corrections.
Atmospheric pressure, atmospheric humidity, scavenging temperature and water or water vapor injection amount are obtained, and this signal is input to the function generating function c. Also,
The NOx correction signal 31 is a fixed value correction, and the nitrogen content in the fuel, engine tuning factors (piston compression ratio, fuel injection timing delay amount, etc.) are obtained by each sensor (not shown), and this signal is used as a function generating function d. It is configured to input to.

【0012】図2は、CPU内部でのNOx濃度,補正
の仕組みを示す。NOx補正信号30として変動値補正信
号を別に設けた各々のセンサーにより発信された信号と
してCPU25に取込み、各々の当該信号に見合った関数
により発生された補正後信号32によって制御基準信号を
補正し、更に固定値補正信号を別に設けた入力装置によ
り入力して、各々の当該信号に見合った関数により発生
された補正後信号33によって前記した制御基準信号34に
更に補正を加えた後、信号変換器26を介してアンモニア
注入量制御弁27を制御して、従来、エンジン出口(脱硝
装置入口)に設けられたNOx分析計の設置なしで高精
度のアンモニア注入制御を可能にできる。
FIG. 2 shows the NOx concentration in the CPU and the mechanism of correction. A fluctuation value correction signal as the NOx correction signal 30 is taken into the CPU 25 as a signal transmitted by each sensor provided separately, and the control reference signal is corrected by the corrected signal 32 generated by a function corresponding to each signal, Further, a fixed value correction signal is input by a separately provided input device, and the control reference signal 34 is further corrected by the corrected signal 33 generated by a function corresponding to each signal concerned, and then the signal converter. By controlling the ammonia injection amount control valve 27 via 26, highly accurate ammonia injection control can be performed without installing a NOx analyzer conventionally provided at the engine outlet (denitrification device inlet).

【0013】このように、上記実施例によれば、図示し
ない各々のセンサーによって大気温度,大気圧力,大気
湿度,掃気温度及び水又は水蒸気噴射量を得て、この信
号を関数発生機能cへ入力するとともに、図示しない各
々のセンサーによって燃料中窒素含有率,エンジンチュ
ーニング要素(ピストン圧縮比,燃料噴射タイミング遅
延量等)を得て、この信号を関数発生機能dへ入力する
構成となっているため、エンジン出口にNOx濃度分析
計を設置することなく、アンモニア注入量を高精度に制
御して脱硝装置出口のNOx濃度を常に高精度で所要値
の許容範囲内にすることができる。
As described above, according to the above-described embodiment, the atmospheric temperature, atmospheric pressure, atmospheric humidity, scavenging temperature, and water or water vapor injection amount are obtained by each sensor (not shown), and this signal is input to the function generating function c. In addition, each sensor (not shown) obtains the nitrogen content in the fuel, engine tuning factors (piston compression ratio, fuel injection timing delay amount, etc.), and inputs this signal to the function generating function d. Without installing a NOx concentration analyzer at the engine outlet, it is possible to control the ammonia injection amount with high precision and always keep the NOx concentration at the outlet of the denitration device within the allowable range of the required value with high precision.

【0014】[0014]

【発明の効果】以上詳述したようにこの発明によれば、
廉価でNOx分析計を設置した場合と同等の精度の高い
アンモニア注入量制御を行なうことができるとともに、
NOx分析計を用いる場合よりエンジン負荷応答の早い
制御を可能にできる高信頼性の脱硝装置の制御方法を提
供できる。
As described above in detail, according to the present invention,
While it is possible to control the injection amount of ammonia with the same high precision as when installing a NOx analyzer at a low price,
It is possible to provide a highly reliable denitration control method capable of controlling the engine load response faster than when using a NOx analyzer.

【図面の簡単な説明】[Brief description of drawings]

【図1】この発明の一実施例に係る脱硝装置システムフ
ローの説明図。
FIG. 1 is an explanatory diagram of a denitration device system flow according to an embodiment of the present invention.

【図2】この発明に係るアンモニア注入制御信号のフロ
ーの説明図。
FIG. 2 is an explanatory diagram of a flow of an ammonia injection control signal according to the present invention.

【図3】従来の脱硝装置システムフローの説明図。FIG. 3 is an explanatory diagram of a conventional denitration system flow.

【図4】従来に係るアンモニア注入制御信号のフローの
説明図。
FIG. 4 is an explanatory diagram of a flow of a conventional ammonia injection control signal.

【符号の説明】[Explanation of symbols]

21…エンジン、 22…脱硝装置、
23…煙突、24…エンジン出力検出器、 25…中央
処理装置、 26…信号変換器、27…アンモニア注
入量制御弁、28…アンモニア注入ノズル、29…アンモニ
ア、30,31…NOx補正信号、 32,33…補正後信
号、34…制御基準信号。
21 ... Engine, 22 ... Denitration device,
23 ... Chimney, 24 ... Engine output detector, 25 ... Central processing unit, 26 ... Signal converter, 27 ... Ammonia injection amount control valve, 28 ... Ammonia injection nozzle, 29 ... Ammonia, 30, 31 ... NOx correction signal, 32 , 33 ... post-correction signal, 34 ... control reference signal.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 B01D 53/74 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display location B01D 53/74

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 出力検出器を備えたエンジン又はガスタ
ービンに脱硝装置を接続してエンジン又はガスタービン
から排出される排ガスを大気へ放出する脱硝装置の制御
方法において、前記出力検出器に中央処理装置を接続す
るとともに、前記中央処理装置に信号変換器及び脱硝に
必要なアンモニアの注入量を制御する制御弁を接続さ
せ、大気温度,大気圧力,大気湿度,空気冷却器後の掃
気温度,燃焼室への水もしくは蒸気噴射量,燃料中窒素
含有率,ピストン圧縮比及び燃料噴射タイミング遅延量
の8要素のうち2つ以上を前記中央処理装置へ入力し
て、アンモニア注入量を制御する基準となる信号を補正
することを特徴とする脱硝装置の制御方法。
1. A method for controlling a denitration device, wherein a denitration device is connected to an engine or a gas turbine equipped with an output detector, and exhaust gas discharged from the engine or gas turbine is released to the atmosphere. In addition to connecting the device, a signal converter and a control valve for controlling the injection amount of ammonia required for denitration are connected to the central processing unit, and the atmospheric temperature, atmospheric pressure, atmospheric humidity, scavenging temperature after the air cooler, combustion Two or more of the eight elements of the amount of water or steam injected into the chamber, the nitrogen content in fuel, the piston compression ratio, and the fuel injection timing delay amount are input to the central processing unit to control the amount of ammonia injection. A method for controlling a denitration device, characterized by correcting the following signal.
【請求項2】 アンモニア注入量を制御する基準となる
信号は、エンジン出力信号からエンジン各出力時におけ
る制御の基準となるエンジン出口排ガス量とエンジン出
口NOx濃度を予め実測されたデータに基づき予め組込
まれた演算式により求め、かつその2つの信号を乗算す
ることにより算出されたエンジン出口のNOx総量を示
す信号である請求項1記載の脱硝装置の制御方法。
2. The reference signal for controlling the ammonia injection amount is pre-installed based on the data obtained by previously measuring the engine outlet exhaust gas amount and the engine outlet NOx concentration, which are the reference for control at each engine output, from the engine output signal. 2. The denitration control method according to claim 1, wherein the signal is a signal indicating the total amount of NOx at the engine outlet, which is obtained by the above-mentioned arithmetic expression and is calculated by multiplying the two signals.
JP5153538A 1993-06-24 1993-06-24 Control method for denitration device Withdrawn JPH0726943A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5153538A JPH0726943A (en) 1993-06-24 1993-06-24 Control method for denitration device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5153538A JPH0726943A (en) 1993-06-24 1993-06-24 Control method for denitration device

Publications (1)

Publication Number Publication Date
JPH0726943A true JPH0726943A (en) 1995-01-27

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Country Link
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JP2015147201A (en) * 2014-02-07 2015-08-20 三菱日立パワーシステムズ株式会社 Control device of gas turbine plant, gas turbine plant and denitration control method of gas turbine
EP2947289A1 (en) 2014-05-23 2015-11-25 Toyota Jidosha Kabushiki Kaisha Abnormality diagnosis apparatus for exhaust gas purification apparatus

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013047031A1 (en) * 2011-09-28 2013-04-04 いすゞ自動車株式会社 Urea spray scr control system
JP2013072391A (en) * 2011-09-28 2013-04-22 Isuzu Motors Ltd Urea spray selective catalytic reduction (scr) control system
CN103842629A (en) * 2011-09-28 2014-06-04 五十铃自动车株式会社 Urea spray scr control system
US9440193B2 (en) 2011-09-28 2016-09-13 Isuzu Motors Limited Urea spray selective catalytic reduction control system
JP2015147201A (en) * 2014-02-07 2015-08-20 三菱日立パワーシステムズ株式会社 Control device of gas turbine plant, gas turbine plant and denitration control method of gas turbine
EP2947289A1 (en) 2014-05-23 2015-11-25 Toyota Jidosha Kabushiki Kaisha Abnormality diagnosis apparatus for exhaust gas purification apparatus
US9404405B2 (en) 2014-05-23 2016-08-02 Toyota Jidosha Kabushiki Kaisha Abnormality diagnosis apparatus for exhaust gas purification apparatus

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