JPH07268297A - Pressure-sensitive adhesive composition for kraft pressure-sensitive adhesive tape - Google Patents

Abstract

PURPOSE:To obtain a pressure-sensitive adhesive composition for kraft pressure- sensitive adhesive tape which has pressure-sensitive adhesive characteristics including excellent pressure-sensitive adhesiveness and low-temperature resistance, a low viscosity and a high solid content and therefore a good workability in coating and costs suitably. CONSTITUTION:The composition is a solvent-based pressure-sensitive adhesive composition containing a styrene/isoprene block copolymer and a natural rubber in a weight ratio of 0.2-1.5, the content of the styrene/isoprene block copolymer in the block copolymer being 50-90wt.%, and the content of the styrene/isoprene/ styrene block copolymer in the block copolymer being 50-10wt.%.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pressure-sensitive adhesive composition for kraft pressure-sensitive adhesive tape, which is suitable for general use, packaging, correction and the like.

[0002]

2. Description of the Related Art A general kraft pressure-sensitive adhesive tape has a release agent such as a silicone-based release agent on the processed surface of so-called polyethylene-processed paper obtained by extruding and laminating an polyethylene resin as an anchor coat layer on a base paper such as kraft paper. It is prepared by rolling up a non-release-treated surface of a support which has been coated and release-treated, which is coated with a pressure-sensitive adhesive and subjected to an adhesive treatment and wound into a roll.

Conventionally, as the above-mentioned pressure-sensitive adhesive, a solvent-type pressure-sensitive adhesive comprising a natural rubber as a main component and a tackifying resin or the like, a styrene-isoprene block copolymer or a styrene-butadiene block copolymer is used. A solvent-type or hot-melt type pressure-sensitive adhesive comprising a block copolymer such as a coalesce as a main component and a tackifying resin and the like mixed therein is generally used (Japanese Patent Publication No. 60-31233).

However, in the case of the above-mentioned natural rubber solvent type pressure-sensitive adhesive, the molecular weight of the natural rubber as the main component is about 100-2.
Since it is as high as, 000,000, the resulting adhesive will generally have high viscosity and low solid content, and if the solid content is increased to obtain the required adhesive properties, the solution viscosity will increase significantly and the coating surface uniformity And the workability of coating is deteriorated.

On the other hand, in the case of the block copolymer type solvent type or hot melt type pressure-sensitive adhesive, since the block copolymer as the main component is pseudo-crosslinked with styrene, the modulus becomes higher than that of natural rubber at room temperature,
For example, in order to increase the wetting and adhesion of the adherend at low temperature, it is necessary to add a larger amount of tackifying resin, softening agent, etc. than in the case of natural rubber, and as a result, the adhesion and holding power at high temperature On the contrary, it is difficult to balance the adhesive properties such as decrease, and since the block copolymer is more expensive than natural rubber, the cost of the obtained adhesive and kraft adhesive tape is high. There are problems such as.

[0006]

SUMMARY OF THE INVENTION In order to solve the above-mentioned conventional problems, the present invention has excellent adhesive properties such as adhesiveness and cold resistance, and has a low viscosity and a high solid content for good coating workability. Another object of the present invention is to provide a pressure-sensitive adhesive composition for kraft pressure-sensitive adhesive tape, which is suitable for cost.

[0007]

The adhesive composition for kraft adhesive tape of the present invention contains a styrene-isoprene block copolymer / natural rubber in a weight ratio of 0.2 to 1.5. Of the styrene-isoprene-type block copolymer, wherein the content of the styrene-isoprene-type block copolymer in the block copolymer is 50 to 90% by weight. It is characterized in that the content is 50 to 10% by weight, whereby the above object is achieved.

The styrene-isoprene block copolymer used in the pressure-sensitive adhesive composition of the present invention is generally a thermoplastic elastomer having a molecular weight of about 100,000 to 300,000 obtained by living anionic polymerization with an alkyllithium catalyst. Having a polyisoprene component as a soft segment and a polystyrene component as a hard segment in the molecule, the polyisoprene component develops rubber-like elasticity,
Further, the polystyrene component forms physical crosslinks (domains) and serves as a bridging point to exert a plastic deformation preventing function, and is therefore widely used as a base polymer for pressure-sensitive adhesives and adhesives.

The block copolymer may be a linear (linear type) or radial (radial type) styrene-isoprene-styrene type block copolymer, depending on the arrangement of the polyisoprene component and the polystyrene component.
Alternatively, it comprises a mixture of the styrene-isoprene-styrene type block copolymer and a linear styrene-isoprene type block copolymer.

The content of the polystyrene component in the block copolymer is not particularly limited, but is 5 to 5
About 0% by weight is preferable, and about 10 to 30% by weight is more preferable. When the content of the polystyrene component is less than about 5% by weight, the resulting pressure-sensitive adhesive composition is apt to undergo plastic deformation, and sufficient adhesive properties cannot be obtained. On the contrary, when it exceeds about 50% by weight, it is obtained. The rubber-like elasticity of the pressure-sensitive adhesive composition becomes poor, and sufficient pressure-sensitive adhesive properties cannot be obtained.

The weight average molecular weight of the block copolymer is not particularly limited, but it is 50,000 to 4
About 00000 is preferable, 100,000 to 30,000
About 0 is more preferable. When the weight average molecular weight of the block copolymer is less than about 50,000, the pressure-sensitive adhesive composition obtained has insufficient adhesive properties, and conversely 40,000.
When it exceeds about 0, the viscosity of the obtained pressure-sensitive adhesive composition becomes high, and it becomes difficult to achieve low viscosity and high solidification, so that the coating workability also deteriorates.

The type of natural rubber used in the pressure-sensitive adhesive composition of the present invention is not particularly limited, and it is an ordinary pale crepe, brown crepe, or smoked sheet grade product obtained by smoking natural rubber. Etc. are preferably used.

In the pressure-sensitive adhesive composition of the present invention, it is necessary that the styrene-isoprene block copolymer / natural rubber is contained in a weight ratio of 0.2 to 1.5. . When the weight ratio is less than 0.2,
Low viscosity and high solidification of the obtained pressure-sensitive adhesive composition become difficult, and conversely, when it exceeds 1.5, the cost of the obtained pressure-sensitive adhesive composition and the kraft pressure-sensitive adhesive tape increases.

In the pressure-sensitive adhesive composition of the present invention, styrene in the styrene-isoprene block copolymer is used.
The content of the isoprene type block copolymer (hereinafter referred to as "die block") is 50 to 90% by weight, and the content of the styrene-isoprene-styrene type block copolymer (hereinafter referred to as "triblock") is included. It is necessary that the amount is 50 to 10% by weight. If the content of the die block is less than 50% by weight, the cold resistance of the obtained pressure-sensitive adhesive composition decreases, and conversely if it exceeds 90% by weight, the heat resistance of the obtained pressure-sensitive adhesive composition significantly decreases. .

The type of organic solvent used in the pressure-sensitive adhesive composition of the present invention is not particularly limited as long as it can dissolve the styrene-isoprene block copolymer and natural rubber, and normal hexane. Examples thereof include aliphatic hydrocarbons such as normal heptane, alicyclic hydrocarbons such as cyclohexane, aromatic hydrocarbons such as toluene and xylene, and one or more of these are preferably used.

The pressure-sensitive adhesive composition of the present invention contains a rosin-based resin, if necessary, within a range not impairing the object of the present invention.
For tackifier compositions such as terpene-based resins, terpene-phenolic resins, petroleum-based resins, coumarone-indene-based resins, and other tackifying resins, softeners, plasticizers, fillers, stabilizers, colorants, viscosity modifiers, etc. Various commonly used additives may be contained.

[0017]

The pressure-sensitive adhesive composition obtained by the present invention contains a styrene-isoprene block copolymer / natural rubber in a weight ratio of 0.2 to 1.5, so that it has a low viscosity and a high solid content. Differentiation is possible, coating workability is good, and cost is also appropriate.

Further, in the present invention, the content of the die block in the block copolymer is 50 to 90% by weight and the content of the triblock is 50 to 10% by weight. The product has excellent cold resistance.

[0019]

EXAMPLES In order to explain the present invention in more detail, examples will be given below. In the examples, "part" means "part by weight",
"%" Means "% by weight".

(Example 1)

( 1) Preparation of adhesive composition 80 parts of natural rubber "RSS # 1" having a Mooney viscosity of about 80,
Styrene-isoprene block copolymer (styrene content 15%, weight average molecular weight about 200,000) 20 parts, petroleum resin-based tackifying resin "ESCOLETS 1310" (manufactured by Tonex Co.) 140 parts, naphthene-based process oil "Diana" Process NS24 "(manufactured by Idemitsu Kosan Co., Ltd.) based on a pressure-sensitive adhesive composition consisting of 40 parts, calcium carbonate 40 parts and toluene 480 parts, and the content of the die block in the styrene-isoprene block copolymer is 25%.
(Comparative Example 1), 50% and 90%, three types of pressure-sensitive adhesive compositions having a viscosity at 25 ° C. of 30,000 cps and a solid content of 40% were obtained. Regarding the styrene-isoprene block copolymers, those in which the molecular weight of triblock was adjusted according to the content of each die block so that the weight average molecular weight was about 200,000 were used.

( 2) Preparation of Kraft Adhesive Tape The resulting adhesive composition was coated and dried on a non-polyethylene resin surface of kraft paper having polyethylene resin extruded and laminated on one side so that the film thickness after drying would be 30 μm. Then, three kinds of craft adhesive tapes were produced.

( 3) Evaluation Using the obtained kraft pressure-sensitive adhesive tape, a cardboard holding force test and a paper peeling test were conducted by the following methods. The results are shown in Table 1. All evaluations were performed in an atmosphere of 0 ° C.

Cardboard holding power test : 50 mm × 15
Kraft adhesive tape was attached to one side of a cardboard (single flute with K liner for the surface layer) cut to 0 mm so that the adhesive area would be 25 mm x 25 mm, and was pressure-bonded with a 1 kg roller, left for 20 minutes, and then craft adhesive tape. Was hung vertically, and the kraft pressure-sensitive adhesive tape was left standing with a load of 1 kg hanging on it, and the time (minutes) until the kraft pressure-sensitive adhesive tape peeled off and dropped was measured.

Paper peelability test : A kraft adhesive tape with an adhesive area of 25 mm × on one side of the same cardboard as above.
After being adhered so as to have a length of 25 mm and pressure-bonded with a 2 kg roller, it was immediately peeled at a 90-degree angle at a peeling speed of 100 mm / sec, and the fracture area ratio (%) of the corrugated cardboard at the bonded portion was measured.

(Example 2)

Using the same raw material as used in Example 1,
The basic composition of the adhesive composition is 40 parts of natural rubber, 60 parts of styrene-isoprene block copolymer, 120 parts of tackifying resin, 40 parts of process oil, 40 parts of calcium carbonate.
Parts and 370 parts of toluene, the content of the die block in the styrene-isoprene block copolymer was determined as in Example 1.
Similarly, as 25% (Comparative Example 2), 50% and 90%,
Viscosity at 25 ° C. 30,000 cps, solid content 44.8
% Of three types of adhesive compositions were obtained.

Using the pressure-sensitive adhesive composition thus obtained, Example 1
3 kinds of craft adhesive tapes were made in the same manner as
The results of carrying out the cardboard holding power test and the paper peeling test in the same manner as in Example 1 are as shown in Table 1.

[0029]

[Table 1]

[0030]

As described above, the pressure-sensitive adhesive composition for kraft pressure-sensitive adhesive tape according to the present invention exhibits excellent adhesive properties such as adhesiveness and cold resistance, and has a low viscosity and high solid content. Since it has coating workability and the cost is appropriate, it is suitably used for a kraft adhesive tape.

Claims (1)

[Claims] 1. A solvent-type pressure-sensitive adhesive composition containing a styrene-isoprene block copolymer / natural rubber in a weight ratio of 0.2 to 1.5, said block copolymer. The content of the styrene-isoprene type block copolymer is 50 to 90% by weight, and the content of the styrene-isoprene-styrene type block copolymer is 50 to 1
An adhesive composition for kraft adhesive tape, which is 0% by weight.