JPH0726343B2 - Dyeing method and dye compositions for carrying out the method - Google Patents
Dyeing method and dye compositions for carrying out the methodInfo
- Publication number
- JPH0726343B2 JPH0726343B2 JP5157686A JP5157686A JPH0726343B2 JP H0726343 B2 JPH0726343 B2 JP H0726343B2 JP 5157686 A JP5157686 A JP 5157686A JP 5157686 A JP5157686 A JP 5157686A JP H0726343 B2 JPH0726343 B2 JP H0726343B2
- Authority
- JP
- Japan
- Prior art keywords
- dyeing
- dyes
- composition
- molecular weight
- following formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0041—Blends of pigments; Mixtured crystals; Solid solutions mixtures containing one azo dye
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
【発明の詳細な説明】 本発明は、拡散パラメーター「Ｄ」の差が2.4以下であ
りそして不均染パラメーター「UL」が５以下であるよう
な少なくとも２種の単色分散染料類の組成物を用いて染
色を実施することを特徴とする、ポリエステル繊維およ
びポリエステル配合繊維の高温急速染色方法に関するも
のである。DETAILED DESCRIPTION OF THE INVENTION The present invention provides a composition of at least two monochromatic disperse dyes wherein the difference in diffusion parameter “D” is 2.4 or less and the disproportionate dyeing parameter “UL” is 5 or less. The present invention relates to a high-temperature rapid dyeing method for polyester fibers and polyester-blended fibers, which is characterized by carrying out dyeing.
該方法は、例えばパッド染色−機械、糸−染色機械、ジ
ェット、ビームおよび連続範囲の如き個々の処理段階用
の公知の染色機械上でのばらばらの材料、糸、織物およ
び編物の染色用に適している。The method is suitable for dyeing loose materials, yarns, wovens and knits on known dyeing machines for individual processing steps such as pad dyeing-machines, yarn-dyeing machines, jets, beams and continuous areas. ing.
急速染色方法はそれ自体は公知でありそして例えばドイ
ツ公告3,241,727（＝英国特許2,114,165）中に記されて
いる。Rapid dyeing methods are known per se and are described, for example, in German publication 3,241,727 (= UK patent 2,114,165).
上記の染料パラメーター類も同様に事実上公知であり、
そしてそれ以上のことは以下でさらに詳細に説明しよ
う。拡散パラメーターにおける差は好ましくは2.0より
少ない。The dye parameters mentioned above are likewise known per se,
And more about that below. The difference in diffusion parameters is preferably less than 2.0.
染料組成物は好適には、一緒にしたプレスケーキ類を特
定の分散剤組成物で処理することにより得られる組成物
の形状で使用される。The dye composition is preferably used in the form of a composition obtained by treating the combined presscakes with a particular dispersant composition.
この分散剤組成物は ａ）４−６重量％の硫黄含有量および1,500gモル-1の平
均分子量を有するリグニンスルホン酸塩（型Ｉ）、 ｂ）少なくとも６重量％の硫黄含有量および6,500gモル
-1の平均分子量を有するリグニンスルホン酸塩（型I
I）、 ｃ）脂環式または芳香族スルホン酸類とホルムアルデヒ
ドとの低−塩縮合生成物（型III） からなっており、ここで分子量は分子量分布をセファク
リル（SEPHACRYL）S 300分離用ゲルを使用して屈折計で
記録しそして0.9％強度NaCl溶液中での検量線（calibra
tion）により公知のデキストラン分子量にあてはめると
いう水性ゲル透過方法により測定される。The dispersant composition is a) 4-6% by weight of sulfur content and lignin sulfonates with an average molecular weight of 1,500g mol -1 (type I), b) at least 6% by weight of the sulfur content and 6,500g Mole
Lignin sulfonate having an average molecular weight of -1 (type I
I), c) Consists of a low-salt condensation product of alicyclic or aromatic sulfonic acids and formaldehyde (type III), where the molecular weight is SEPHACRYL S 300 preparative gel with molecular weight distribution And recorded with a refractometer and a calibration curve (calibra in 0.9% strength NaCl solution).
It is measured by an aqueous gel permeation method in which a known molecular weight of dextran is applied to the gel.
適当な分散剤類ＩおよびIIは、木材の亜硫酸塩パルプ処
理により得られる商業的に入手可能な生成物質である。Suitable dispersants I and II are commercially available product materials obtained by the sulfite pulping of wood.
型IIIの適当な分散剤類は特に、芳香族スルホン酸酸類
とホルムアルデヒドとの縮合生成物類、例えば（アルキ
ル）ナフタレンスルホン酸類、ナフタレンスルホン酸お
よびベンゼンスルホン酸の混合物、スルフィン化ジフェ
ニルエーテル類、スルホン化ジフェニルチオエーテル
類、スルホン化ジフェニルスルホン類並びにシクロアル
カノンとアルカリ金属亜硫酸水素塩との混合物類のホル
ムアルデヒド縮合生成物類、のカリウム金属およびアン
モニウム塩類である。Suitable dispersants of type III are, in particular, condensation products of aromatic sulphonic acids with formaldehyde, such as (alkyl) naphthalene sulphonic acids, mixtures of naphthalene sulphonic acids and benzene sulphonic acids, sulfinated diphenyl ethers, sulphonated compounds. Potassium metal and ammonium salts of diphenyl thioethers, sulfonated diphenyl sulfones and formaldehyde condensation products of cycloalkanones and mixtures of alkali metal bisulfites.
好適には低−電解質形で使用されるそのような生成物類
は文献中に繰り返し記されている；例えば米国特許公告
2,315,951、英国特許公告715,919、ドイツ特許公告2,44
2,514、ドイツ特許公告2,542,090、ドイツ特許公告2,85
6,222を参照のこと。Such products, preferably used in the low-electrolyte form, are reiterated in the literature; see, for example, US Pat.
2,315,951, British Patent Publication 715,919, German Patent Publication 2,44
2,514, German Patent Publication 2,542,090, German Patent Publication 2,85
See 6,222.
新規な組成物中に存在している分散染料類は、それらが
冒頭に記した条件に合う限り、化学的観点からは多様で
あってよい。それらは例えば室温において微溶性である
スルホを含まない染料類、例えばキノフタロン染料類、
ニトロ染料類、メチン染料類、ナフトキノイミン染料
類、スチリル染料類、アゾスチル染料類、ナフトペリノ
ン染料類並びに特にアントラキノンおよびアゾ染料類、
例えばモノアゾおよびジスアゾ染料類、である。The disperse dyes present in the novel composition may be diverse from a chemical point of view, so long as they meet the conditions mentioned at the outset. They are, for example, sulfo-free dyes which are slightly soluble at room temperature, for example quinophthalone dyes,
Nitro dyes, methine dyes, naphthoquinoimine dyes, styryl dyes, azostil dyes, naphthoperinone dyes and especially anthraquinone and azo dyes,
For example, monoazo and disazo dyes.
組成物は、15〜50％の生の色、使用する生の染料類に関
して50〜120％の型Ｉの分散剤並びに30〜120％の混合比
が0.1〜1.1:1〜0.1に変わる型IIおよび型IIIの分散剤混
合物を含有している。The composition comprises 15-50% raw color, 50-120% of the type I dispersant with respect to the raw dyes used and 30-120% of the mixing ratio of 0.1-1.1: 1-0.1 type II. And a Type III dispersant mixture.
「生の色」とは、本発明の目的用には、例えばプレスケ
ーキから乾燥により得られるものの如き純粋な未処理の
染料を意味するものであると理解すべきである。“Green color” is to be understood as meaning, for the purposes of the present invention, a pure, untreated dye, such as that obtained by drying from presscakes.
これらの組成物類は、染料プレスケーキ類を混合し、そ
の後一般的な粉砕装置中で希望する粒子寸法に粉砕し、
そして希望するならその後噴霧乾燥することにより、得
られる。These compositions are prepared by mixing dye presscakes and then grinding in a conventional grinding machine to the desired particle size,
It is then obtained by spray drying if desired.
個別に処理された染料類に比較して、新規な方法での染
色は隣接（adjacent）繊維、セルロースおよび／または
羊毛上で驚異的に改良された熱泳動竪牢性を与える。Compared to individually treated dyes, the dyeing in the novel method gives surprisingly improved thermophoretic integrity on adjacent fibers, cellulose and / or wool.
染料実施例 実施例1a 100部の織地状ポリエステルニットウェアをジェット染
色機械中で、 0.5部の実施例3bからの染料混合物、 0.5部の実施例4bからの染料混合物、 １部の非イオン性均染助剤（50部のノニルフェノール10
エチレンオキシドおよび50部のオレイン酸６エチレンオ
キシドからなっている）、 １部の分散剤（スルオン化されたナフタレン−ホルムア
ルデヒド縮合生成物）、 ２部の60％強度酢酸、 995部の水 からなる染色液を用いて処理した。Dye Examples Example 1a 100 parts of a woven polyester knitwear in a jet dyeing machine, 0.5 part of the dye mixture from Example 3b, 0.5 part of the dye mixture from Example 4b, 1 part of a nonionic leveler. Dyeing aid (50 parts nonylphenol 10
A dyeing solution consisting of ethylene oxide and 50 parts oleic acid 6 ethylene oxide), 1 part dispersant (sulphonated naphthalene-formaldehyde condensation product), 2 parts 60% strength acetic acid, 995 parts water. Processed.
液を急速に80℃に加熱し、そして80℃から130℃に30分
間にわたり加熱した。130℃の温度を20分間保った。冷
却し、その後一般的にすすぎ、そしてアルカリ性還元清
澄化した。The liquor was heated rapidly to 80 ° C and from 80 ° C to 130 ° C for 30 minutes. The temperature of 130 ° C was maintained for 20 minutes. Cooled, then generally rinsed and alkaline reduction clarified.
得られた結果は完全に均一な明るい橙色の染色物であっ
た。この染色物は、染色をその後180℃で30秒間にわた
りヒートセットさせた時でさえ、優れた湿潤および摩擦
竪牢性を有していた。The result obtained is a completely uniform, bright orange dyeing. This dyeing had excellent wetting and abrasion stability even when the dyeing was subsequently heat set at 180 ° C. for 30 seconds.
熱泳動竪牢性をDIN54017に従う隣接混紡繊維を用いて60
℃の洗浄によるヒートセット染色物に対して試験した。Thermophoresis prudence 60 according to DIN 54017 with admixed fibers
Tested on heatset dyeings by washing at 0 ° C.
評価基準は１−５の灰色目盛りに対して測定されたナイ
ロンの色付けであった。この試験方法を用いると、上記
の染色は４−５であると評価された。The evaluation criterion was the coloring of nylon measured against a gray scale of 1-5. Using this test method, the above staining was rated 4-5.
実施例2a 100部の50％ポリエステルおよび50％木綿の混紡糸をチ
ーズ染色装置中で、 0.1部の実施例6bからの染料混合物、 0.1部の実施例5bからの染料混合物、 0.8部の実施例8bからの染料混合物、 995部の水 からなる1,000部の液を用いて処理した。Example 2a 100 parts of a 50% polyester and 50% cotton blend yarn in a cheese dyeing machine, 0.1 part of the dye mixture from Example 6b, 0.1 part of the dye mixture from Example 5b, 0.8 part of the example. The dye mixture from 8b was treated with 1,000 parts liquor consisting of 995 parts water.
他の染色浴添加物類は実施例１）中に記されている如く
であった。Other dyebath additives were as described in Example 1).
染色工程は１）中に記されている如くであった。ポリエ
ステル部分上で得られた結果は、深い完全に均一な濃青
色の染色であった。木綿繊維は完全に未着色のままであ
った。この染色物は、染色物をその後180℃で30秒間ヒ
ートセットさせた時でさえ、優れた湿潤および摩擦竪牢
性を有していた。The dyeing process was as described in 1). The result obtained on the polyester part was a deep, completely uniform deep blue dyeing. The cotton fibers remained completely unpigmented. This dyeing had excellent wetting and abrasion resistance even when the dyeing was subsequently heat set at 180 ° C. for 30 seconds.
ナイロンの色付けにより測定されるDIN54017に従う60℃
の洗浄は、４−５であると評価された。60 ° C according to DIN 54017 measured by coloring nylon
Washes were rated 4-5.
拡散パラメーター「Ｄ」の測定 厚さが15μｍで幅が4.5cmでそして長さが65cmのポリエ
チレンテレフタレートフィルム（Hostapha R15、ヘキス
トAG）を沸騰水中で空気を排除して直径が1.4cmのVAス
テンレス鋼管の上に広げた。片の端を薄いVAステンレス
鋼および弾性帯によりVAステンレス鋼管に連結した。広
げられたフィルムのついている管をHTビーカー中に200m
lのpH4.5（酢酸および酢酸Naを用いて調節された）の染
料溶液（１リットル当たり0.5gの染料）と一緒に加え、
そしてサーモスタット中で130℃において５時間半処理
した。処理時間の完了時に、フィルム付きの管を水で簡
単にすすぎ、フィルムを濾紙上に広げ、そして空気中で
乾燥した。個々の層（薄いVAステンレス鋼の棒によりマ
ークされている）の吸光を分光計で測定し、そしてセキ
ド他の工業化学雑誌68（1965）、524の方法により拡散
係数を計算するために使用した。拡散パラメーターＤは
10-10cm2/秒の単位の拡散係数である。Measurement of diffusion parameter "D" Polyethylene terephthalate film (Hostapha R15, Hoechst AG) with a thickness of 15 μm, a width of 4.5 cm and a length of 65 cm (VA) stainless steel tube with a diameter of 1.4 cm and excluding air in boiling water. Spread on top. One end of the piece was connected to a VA stainless steel tube with a thin VA stainless steel and elastic band. 200m of tube with unfolded film in HT beaker
l with a dye solution of pH 4.5 (adjusted with acetic acid and Na acetate) (0.5 g of dye per liter),
Then, it was treated at 130 ° C. for 5 hours and a half in a thermostat. At the completion of the treatment time, the tube with the film was briefly rinsed with water, the film was spread on filter paper and dried in air. The extinction of the individual layers (marked by a thin VA stainless steel bar) was measured spectrophotometrically and used to calculate the diffusion coefficient by the method of Sekid et al., Journal of Industrial Chemistry 68 (1965), 524. . The diffusion parameter D is
It is the diffusion coefficient in the unit of 10 -10 cm 2 / sec.
不均染パラメーター「UL」の測定 交叉−巻き包装を1974型S4566セプロテック（Seprote
c）研究室用染色機械中で下記の条件下で1/10の標準的
色深度を構成するような染料を供給して染色した。Measurement of non-uniform dyeing parameter "UL" Cross-wrapping type 1974 type S4566 Seprote
c) Dyes were supplied in a laboratory dyeing machine under the following conditions, supplying dyes that constituted a standard color depth of 1/10.
液比17:1、毎分２回の中から外への液循環。円錐形包
装:4゜20′中心、55×33×145mm; 750gのダクロン54紡糸糸、二重メートル評価30;最大外
径160mm;包装密度365g/リットル。1g/リットルの、50部
のノニルフェノールと10モルの酸化エチレン、50部のオ
レイン酸、並びにそれぞれ50部のスルホン化ナフタレン
／ホルムアルデヒド縮合生成物およびスルホン化ジトリ
ルエーテル／ホルムアルデヒド縮合生成物からなる、均
染剤;pH＝4.5、酢酸を用いて調節。Liquid ratio of 17: 1, liquid circulation from inside to outside twice per minute. Conical packaging: 4 ° 20 'center, 55x33x145mm; 750g Dacron 54 spun yarn, double metric rating 30; maximum outer diameter 160mm; packing density 365g / l. Level dyeing consisting of 1 g / l of 50 parts nonylphenol and 10 mol ethylene oxide, 50 parts oleic acid, and 50 parts sulfonated naphthalene / formaldehyde condensation product and sulfonated ditolyl ether / formaldehyde condensation product, respectively. Agent; pH = 4.5, adjusted with acetic acid.
温度過程;80℃から毎分２℃で130℃に加熱しそして130
℃で10分間染色した。その後、普通に還元清澄化した。
包装の外層および内層の試料を採取した。染料を試料か
らクロロベンゼンを用いて抽出した。濃度Ｃ内部および
Ｃ外部を分光計で測定した。不均染パラメーターは、 である。Temperature process; heating from 80 ℃ to 130 ℃ at 2 ℃ per minute and 130 ℃
It was stained at 0 ° C for 10 minutes. After that, reduction and clarification were performed as usual.
Samples of the outer and inner layers of the package were taken. The dye was extracted from the sample with chlorobenzene. The concentration inside C and outside C was measured with a spectrometer. The uneven dyeing parameter is Is.
処理実施例 実施例1b 259gの表Ｉ中に記されている染料Ａの水性プレスケーキ
を250gの型Ｉの分散剤と混合し、混合物を−−pH補正お
よび湿潤剤の添加後に−−ビーズミル粉砕し、そして分
散液を型II/IIIの分散剤混合物を用いて、固体含有物中
に30％の生の色を含んでおりそして噴霧乾燥されている
分散液が得られるような方法で、希釈した。Treatment Examples Example 1b 259 g of an aqueous presscake of Dye A listed in Table I was mixed with 250 g of a dispersant of type I and the mixture was--after pH correction and addition of wetting agents--bead milled. And diluting the dispersion with a type II / III dispersant mixture in such a way that a dispersion containing 30% green color in the solids content and spray dried is obtained. did.
実施例2b 実施例１中の染料Ａの代わりに、染料Ｂを同一混合比で
使用することもできた。Example 2b Instead of Dye A in Example 1, Dye B could be used in the same mixing ratio.
実施例３〜９は、実施例１に従って処理されそして非常
に良好ないし良好な木綿保有性および竪牢性並びに色調
の吸尽性により特徴づけられている組み合わせを記して
いる。これらの混合物類も同様にポリエステル／羊毛用
に適していた。Examples 3 to 9 describe the combinations treated according to Example 1 and characterized by very good to good cotton retention and upkeep and shade exhaustion. These mixtures were likewise suitable for polyester / wool.
フロントページの続き (72)発明者 エアハルト・シユフエンハウアー ドイツ連邦共和国デー‐5090レーフエルク ーゼン１・フリードリツヒ‐バイエル‐シ ユトラーセ 13 (72)発明者 ボルフガング・ヒーブラー ドイツ連邦共和国デー‐5068オーデンター ル・ミヒヤエルスヘーエ 23Continued Front Page (72) Inventor Erhard Schufuenhauer Germany Day-5090 Lef Elksen 1 Friedrich-Bayer-Sütlerse 13 (72) Inventor Wolfgang Heebler Germany Day-5068 Odental Le Mi Falsh Haye 23
Claims (8)
ありそして不均染パラメーター「UL」が５以下であるよ
うな少なくとも２種の単色分散染料類の組成物を用いて
染色を実施することを特徴とする、ポリエステル繊維お
よびポリエステル配合繊維の高温急速染色方法。1. Dyeing is carried out with a composition of at least two monochromatic disperse dyes such that the difference in the diffusion parameter "D" is less than 2.4 and the uneven dyeing parameter "UL" is less than 5. A high-temperature rapid dyeing method for polyester fibers and polyester-blended fibers, which comprises:
る、特許請求の範囲第１項記載の方法。2. The dyeing is of the formula D + E. A method according to claim 1, characterized in that a composition of the dyes of item (1) is used.
とする、特許請求の範囲第１項記載の方法。3. The dyeing is symbol A + B + D + G. The method according to claim 1, characterized in that a composition of dyes having the following formula is used.
とする、特許請求の範囲第１項記載の方法。4. The dyeing is symbol C + B + G. The method according to claim 1, characterized in that a composition of dyes having the following formula is used.
とする、特許請求の範囲第１項記載の方法。5. The dyeing is symbol F + D + E. The method according to claim 1, characterized in that a composition of dyes having the following formula is used.
とする、特許請求の範囲第１項記載の方法。6. The dyeing is K + L + H + F. The method according to claim 1, characterized in that a composition of dyes having the following formula is used.
とする、特許請求の範囲第１項記載の方法。7. The dyeing is symbol F + L + H + K + C. The method according to claim 1, characterized in that a composition of dyes having the following formula is used.
平均分子量を有するリグニンスルホン酸塩（型Ｉ）、 ｂ） 少なくとも６重量％の硫黄含有量および6,500gモ
ル-1の平均分子量を有するリグニンスルホン酸塩（型I
I）、 ｃ） 脂環式または芳香族スルホン酸類とホルムアルデ
ヒドとの低−塩縮合生成物（型III） からなる分散剤混合物を含有している組成物の形で使用
することを特徴とし、ここで分子量は分子量分布をセフ
アクリル（SEPHACRYL）S 300分離用ゲルを使用して屈折
計で記録しそして0.9％強度NaCl溶液中での検量線によ
り公知のデキストラン分子量にあてはめるという水性ゲ
ル透過方法により測定する、特許請求の範囲第１項記載
の方法。8. A dyestuff essentially comprising: a) a lignin sulfonate (type I) having a sulfur content of 4-6% by weight and an average molecular weight of 1,500 gmol -1 , b) at least 6% by weight. Lignin sulfonates (type I with a sulfur content and an average molecular weight of 6,500 gmol- 1 )
I), c) characterized in that it is used in the form of a composition containing a dispersant mixture consisting of a low-salt condensation product of cycloaliphatic or aromatic sulfonic acids and formaldehyde (type III), The molecular weight is measured by an aqueous gel permeation method in which the molecular weight distribution is recorded with a refractometer using SEPHACRYL S 300 preparative gel and fitted to a known dextran molecular weight by a calibration curve in 0.9% strength NaCl solution. A method according to claim 1.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3508904.0 | 1985-03-13 | ||
| DE19853508904 DE3508904A1 (en) | 1985-03-13 | 1985-03-13 | Dyeing process |
| DE3508907.5 | 1985-03-13 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6263259A Division JPH07207181A (en) | 1985-03-13 | 1994-10-04 | Dye composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61215784A JPS61215784A (en) | 1986-09-25 |
| JPH0726343B2 true JPH0726343B2 (en) | 1995-03-22 |
Family
ID=6265030
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5157686A Expired - Lifetime JPH0726343B2 (en) | 1985-03-13 | 1986-03-11 | Dyeing method and dye compositions for carrying out the method |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH0726343B2 (en) |
| DE (1) | DE3508904A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3704809A1 (en) * | 1987-02-16 | 1988-08-25 | Cassella Ag | MIXTURES OF MONOAZO DYES |
| JP2782489B2 (en) * | 1992-10-09 | 1998-07-30 | 鐘紡株式会社 | Cloth dyeing method |
| DE19636380A1 (en) * | 1996-09-09 | 1998-03-12 | Dystar Textilfarben Gmbh & Co | Disperse dye mixtures |
| DE19954398A1 (en) * | 1999-11-12 | 2001-05-17 | Dystar Textilfarben Gmbh & Co | Mixtures of disperse monoazo dyes |
| DE10028686A1 (en) | 2000-06-09 | 2001-12-13 | Dystar Textilfarben Gmbh & Co | New hydroxypyridone methide azo dyes, useful in e.g. dyeing and printing hydrophobic fibers, ink-jet printing and color filters |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3142609A1 (en) * | 1981-10-28 | 1983-05-05 | Basf Ag, 6700 Ludwigshafen | NAVY BLUE DISPERSION DYE MIXTURES |
| DE3246949A1 (en) * | 1981-12-28 | 1983-07-07 | Sandoz-Patent-GmbH, 7850 Lörrach | Disperse dyes |
| DE3302096A1 (en) * | 1983-01-22 | 1984-07-26 | Basf Ag, 6700 Ludwigshafen | NAVY BLUE DYE MIXTURES |
-
1985
- 1985-03-13 DE DE19853508904 patent/DE3508904A1/en active Granted
-
1986
- 1986-03-11 JP JP5157686A patent/JPH0726343B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE3508904C2 (en) | 1988-12-29 |
| JPS61215784A (en) | 1986-09-25 |
| DE3508904A1 (en) | 1986-09-18 |
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