JPH07255776A - Absorbent article - Google Patents

Abstract

PURPOSE:To provide an absorbent article provided with extremely high absorbency and high comfortability by suppressing the quantity of return liquid or the leakage of liquid to the extent not being achieved in conventional absorbent articles, even when wearing the article for a long time or even on severe exercise conditions. CONSTITUTION:Concerning an absorbent article 10 provided with a liquid permeable surface material 1, liquid holding absorbent 2 and liquid non-permeable leakage-proof material 3, the absorbent 2 has at least a highly absorbent polymer 2b and cellulose fiber 2a. Concerning the highly absorbent polymer 2b, the centrifugal holding capacity of physiological saline solution after equilibrium absorbent swelling is more than 30g/g, and when the highly absorbent polymers of 0.05g are put into a cylinder whose cross-sectional area is 0.785cm<2>, swelled by the physiological saline solution up to equilibrium swelling and the physiological saline solution is permeated, its permeation rate is higher than 10ml/min. On the other hand, the cellulose fibers 2a are obtd. by cross-linking inside cellulose molecules or between cellulose molecules with a cross-linking agent.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to absorbent articles represented by sanitary napkins, disposable diapers, and incontinence pads. More specifically, the invention relates to absorbent properties of body fluids, particularly reabsorption rate and leakage prevention. TECHNICAL FIELD The present invention relates to a highly absorbent absorbent article that has improved property and can be used very comfortably by a user.

[0002]

2. Description of the Related Art Conventionally, many proposals have been made regarding absorbent articles such as sanitary napkins having improved absorption of body fluids, and many improvements have been made. Most of these improvements have been in the improvement of absorption rate, prevention of liquid return from the absorber to the surface, prevention of leakage and reduction of stickiness to the body.

For example, regarding the material of the absorbent body in the sanitary napkin, instead of hydrophilic absorbent paper or pulp that absorbs and retains the liquid in the physical fine space, the body fluid is subjected to a physicochemical action, that is, ion permeation. It has been proposed to absorb and retain body fluids using a superabsorbent polymer that utilizes pressure, and it has been reported that this proposal can improve absorption capacity and prevent fluid return after absorption. . According to this proposal, the absorbency of the sanitary napkin is improved, and at present, an absorbent body using a combination of pulp and a superabsorbent polymer is used for most sanitary napkins.

However, even with a sanitary napkin using the above-mentioned superabsorbent polymer, it is clear from the fact that the first dissatisfaction with the sanitary napkin is leakage. I'm not satisfied.

That is, the liquid is absorbed and absorbed by the ionic osmotic pressure.
With the type of superabsorbent polymer that is retained, there is a limit to the rate of absorption of body fluid, and since the body fluid cannot be absorbed unless the superabsorbent polymer wets the body fluid, the water absorption rate when using the superabsorbent polymer It is necessary to use a fast-moving pulp in combination, but when the flexible flap absorbent layer is formed as an absorber, the pulp is a diffusion for efficiently utilizing the entire absorber in order to absorb blood in spots. There is a problem of poor sex.

[0006] Further, the above pulp exhibits a certain degree of compression and bending recovery properties when dried, but its strength is extremely reduced when wet, and shows almost no compression and bending recovery properties. Therefore, when stress is applied to the wet pulp. The problem that the pulp undergoes compressive deformation (hereinafter referred to as "breakage"), its absorption space is significantly reduced, and the body fluid once absorbed easily returns to the body side due to twisting, leading to stickiness and leakage. There is.

Further, the decrease in the pulp fiber space due to this twist leads to an increase in the transfer resistance of body fluid to the polymer,
Not only does the absorption efficiency of the polymer decrease, but also the fiber space of the pulp when the body fluid is excreted again and the synergistic effect of the absorption space decreasing with the swelling of the polymer again cause the absorption of the absorbent body as a whole. The rate of reabsorption after exposure is significantly reduced, often leading to leaks.

Further, conventionally, when the amount of the superabsorbent polymer used in the absorber is increased in order to improve the absorption performance, the absorption performance is improved along with the increase in the amount of the polymer up to a certain region, but conversely, if the amount is excessively increased. The voids between the polymer particles after absorbing the body fluid are extremely reduced, and the reabsorption rate is deteriorated, so that the absorption performance is deteriorated.

That is, conventionally, due to the gel blocking of the polymer, the amount of the polymer used is limited, and the absorption performance such as the liquid return and leakage performance is perfect when worn for a long time and under the condition that the excretion amount is very large. At present, it is not possible to obtain an absorbent article satisfying the above requirements.

Therefore, in order to improve the poor diffusibility of the pulp and the reduction amount of the absorption space due to the twist, the technique of compressing / densifying the pulp to improve the diffusivity and the liquid return property has been put into practical use. JP-A-49-143589, US Pat. No. 3,017,304, JP-B-54-36793,
As disclosed in Japanese Examined Patent Publication No. 1-33176, these techniques do not solve the essential problem that the strength is extremely reduced when the pulp gets wet, and conversely, the distance between the fibers of the pulp. If it is too dense, the transfer resistance of blood to the polymer becomes very large, and as a result, the absorption efficiency of the polymer used in combination deteriorates.

Further, for the purpose of preventing the warp of the pulp when wet, a technique of suppressing the decrease in elastic modulus during wet and reducing twisting / sagging by cross-linking the cellulose of the pulp with a suitable crosslinking agent is known. , Have been reported many times so far. For example, Japanese Patent Application Laid-Open No. 63-264971 reports a crosslinked pulp having a bulky structure (twisted structure), but an absorbent body using such a crosslinked pulp is certainly not only dry but also liquid. Even after absorption, a bulky structure can be maintained, and an absorber having a high spot absorptivity and a high absorption rate can be obtained.

However, if an absorbent body using such a crosslinked pulp is erroneously used, on the contrary, the entire absorbent body will be
It has been found that the ability to retain body fluid is reduced, fluid return is increased, and leakage tends to occur. That is, cross-linking the pulp improves the elastic modulus when wet,
The amount of absorption that the fibers themselves absorb body fluids due to crosslinking will also be suppressed, and as a result, the body fluid retention amount of the pulp alone will decrease. In the absorbent body used, the amount of body fluid absorbed and retained by the entire absorbent body is reduced, liquid return is increased, and leak prevention performance is deteriorated.

For the purpose of preventing gel blocking of the polymer and improving the absorption efficiency of the polymer, an example of using an absorbent obtained by mixing a hydrophilic fiber such as pulp and the polymer is disclosed in JP-A-59-204956. Further, examples in which a uniform layer of polymer and pulp is used only on the lower surface of the absorber are disclosed in JP-A-59-135149 and JP-A-63-109859.
No. Further, for the purpose of more effectively preventing gel blocking of the polymer after absorbing body fluid, the concentration of the polymer is gradually decreased from the lower surface of the absorbent body to the upper surface thereof, that is, the absorbent body is provided with a concentration gradient of the polymer. Techniques for constructing the above are disclosed in JP-A-62-32950, JP-A-62-45703, and the like. The above-mentioned series of techniques show a technique for constructing a pulp and a polymer, and although they are somewhat effective in suppressing gel blocking of the polymer and increasing absorption efficiency, the pulp gets wet and twists. At present, the essential problem that the fiber space is reduced and the resorption rate is deteriorated cannot be improved yet.

Further, in US Pat. No. 5,061,259, it is considered that fine powder of a polymer is a cause of gel blocking, and a polymer having a median particle diameter of 400 μm to 700 μm and having a particle size distribution regulated to be hydrophilic with a polymer. Absorbers in which fibers are mixed have been proposed. In the above proposal, it is illustrated in the text that crosslinked pulp may be used as the hydrophilic fiber, but the effect of using the crosslinked pulp is not particularly described, and the hydrophilic fiber is not particularly limited. However, the problem that the space between the fibers decreases when the hydrophilic fiber gets wet and the resorption rate decreases is not solved by the above proposal either. Further, although the polymer is also somewhat suppressed by removing the fine powder, gel blocking is suppressed, but since the essence of gel blocking of the polymer cannot be improved only by the particle size distribution, the problems of the above polymer are also solved. Not.

Therefore, the object of the present invention is to achieve extremely high absorbency by suppressing the amount of liquid return and liquid leakage even during long-time wearing or under vigorous exercise conditions, which cannot be achieved by conventional absorbent articles. And to provide an absorbent article with high comfort. Specifically, even if it absorbs body fluid once, the fibers that make up the absorber do not cause kinking / sagging, the resorption rate is excellent, and the superabsorbent polymer does not cause absorption inhibition, and its absorption performance is maximized. It is possible to immobilize most of the body fluid with a superabsorbent polymer even when worn for a long period of time or under the condition of excretion in large quantities, and absorbs less liquid returning to the surface of the absorbent article and less leakage. To provide goods.

[0016]

As a result of intensive studies to solve the above problems, the present inventors have found that they have a high centrifugal retention capacity and high absorption with a high fluid flow rate (high permeation rate). It was found that an absorbent article including an absorbent body having a functional polymer and a specific cellulose fiber can achieve the above object, and completed the present invention.

That is, the present invention provides an absorbent article having a liquid-permeable surface material, a liquid-retaining absorber and a liquid-impermeable leak preventer, wherein the absorber is at least a superabsorbent polymer and cellulose. A) the superabsorbent polymer has a centrifugal storage capacity of 30 g / g or more after equilibrium absorption and swelling of physiological saline, and 0.05 g of the superabsorbent polymer has a cross-sectional area of 0. It is placed in a cylinder of 785 cm ² (circle diameter 10 mmφ), equilibrated and swollen with physiological saline, and then the permeation rate when physiological saline is permeated is 10 ml / min or more. B) The cellulose fiber is a cellulose molecule. It is intended to provide an absorbent article, which is a crosslinked cellulose fiber obtained by crosslinking the inside or between the molecules with a crosslinking agent.

As described above, the absorbent article of the present invention has a high centrifugal retention capacity, which represents the ability of the superabsorbent polymer to substantially (bodily fluid) absorb, and has a high fluidity of the fluid after absorbing the fluid. It is characterized in that the absorbent body is constituted by combining a highly absorbent polymer which is high in gel blocking resistance and a crosslinked cellulosic fiber which is less likely to be twisted / stained when absorbing body fluid.

[0019]

The absorbent article of the present invention comprises a superabsorbent polymer having a high centrifugal retention capacity and an excellent permeation rate after liquid absorption (high body fluid flowability), as well as when it absorbs body fluid, that is, when it gets wet. / Since the absorbent body is constructed by combining both cross-linked cellulose fibers with less fatigue, the absorption rate, especially the reabsorption rate, is superior due to the synergistic effect of each other than when used alone, and the ability to immobilize body fluids. Is high,
Excellent liquid return and liquid leakage prevention.

Specifically, the excreted body fluid is first absorbed in the fiber space (absorption space) formed by each crosslinked cellulose fiber. This cross-linked cellulose fiber has little twisting / staining even when wet, and can stabilize the absorption space for temporarily absorbing body fluid. Then, the superabsorbent polymer has a higher centrifugal retention capacity and a higher fluid flow rate, and thus, without gel blocking,
The body fluid absorbed in the absorption space can be smoothly guided to and held in the superabsorbent polymer. Both the absorption space for temporarily absorbing body fluid and the superabsorbent polymer for retaining body fluid,
Both have excellent fluidity when re-wetting, so even after repeated excretion, absorption performance is not deteriorated.
It can guide and immobilize body fluids into superabsorbent polymers very stably / effectively. As a result, the absorbent article of the present invention has a small amount of liquid returning to the surface and is comfortable with little stickiness / leakage even when the amount of excreted body fluid is small, and of course, even when worn for a long period of time with high excretion. It has wearability.

[0021]

EXAMPLES The present invention will be described in detail below with reference to the drawings, and the present invention will be specifically described with reference to Examples and Comparative Examples.

In the following examples, a sanitary napkin will be described as an example, but the present invention can be similarly applied to other absorbent articles such as disposable diapers and incontinence pads. , Within the range not departing from the requirements of the present invention,
It can be freely configured within the scope of the prior art, such as constituent materials and constituent methods.

First, the present invention will be described with reference to FIGS. Here, FIG. 1 is a schematic view showing a cross section in the width direction of a sanitary napkin as a first embodiment of the absorbent article of the present invention. 2, FIG. 3, FIG. 4 and FIG. 6 are schematic diagrams showing cross sections in the width direction of sanitary napkins as other examples (second to fifth examples) of the absorbent article of the present invention (FIG. 1). 5 is an enlarged view of the composite absorbent paper shown in FIG. 4, and FIG. 7 is an enlarged view of the composite absorbent paper shown in FIG.

The sanitary napkin 10 of this embodiment shown in FIG.
Has a liquid-permeable surface material 1, a liquid-retaining absorber 2, and a liquid-impermeable leak preventer 3. The absorbent body 2 is composed of the super absorbent polymer 2b and the cellulose fiber 2a.
And a) the superabsorbent polymer 2b has a centrifugal retention capacity of 30 g / g after equilibrium absorption and swelling of physiological saline.
That is all, and 0.05 g of the above superabsorbent polymer 2b was put into a cylinder having a cross-sectional area of 0.785 cm ² (circle diameter 10 mmφ),
The permeation rate is 10 ml / min or more when equilibrium swelling with physiological saline and then permeating physiological saline, b)
The cellulosic fibers are crosslinked cellulosic fibers obtained by crosslinking intramolecular or intermolecular cellulose with a suitable crosslinking agent.

More specifically, the sanitary napkin 10 described above.
Is formed substantially vertically long, and when the sanitary napkin 10 is worn, the surface material 1 is located on the surface side in contact with the skin, and the leak preventer 3 is located on the back surface side in contact with the underwear. The absorber 2 is interposed between the surface material 1 and the leak preventer 3. In addition, the absorber 2
As shown in FIG. 1, the back surface, all side surfaces, and the peripheral portions of the front surface are covered with the leak preventer 3, and the entire surfaces thereof are covered with the surface member 1. And
The center of the surface of the absorbent body 2 is directly covered with the surface material 1 and is configured to allow body fluid to directly permeate into the absorbent body 2. Further, on the back surface side of the surface material 1, three adhesive parts 4 are formed in a stripe shape in the longitudinal direction, and the adhesive parts 4 are protected by a release paper 5. In addition, in FIG. 1, 6 is a joining part.

Next, the characteristic part of the sanitary napkin 10 of this embodiment will be described. The absorbent body 2 is composed of the superabsorbent polymer 2b and the cellulose fibers 2a dispersed and mixed with each other, and the absorbent paper covering the entire surfaces thereof. 2c, and the uppermost layer of the absorber 2 is formed by using the absorbent paper 2c. The superabsorbent polymer 2b has a centrifugal storage capacity of 3 after being immersed in physiological saline and equilibrated and swollen.
0 g / g or more, preferably 30 g / g to 60 g / g, and 0.05 g of the superabsorbent polymer 2b is charged into a cylinder (circle diameter 10 mmφ) having a cross-sectional area of 0.785 cm ² and polymerized with physiological saline. Swells to reach the equilibrium swell absorption and the permeation rate after precipitation of the swollen polymer is 10 ml.
/ Min or more, preferably 15 ml / min or more. still,
Regarding the method for measuring the centrifugal retention capacity and the permeation rate,
It will be described later.

The centrifugal storage capacity of the superabsorbent polymer is 3
If it is less than 0 g / g, the ability to absorb and retain the liquid becomes poor. On the contrary, when the centrifugal storage capacity exceeds 60 g / g, the ability to retain the absorbed body fluid is excellent,
A polymer having such an absorption amount is inferior in gel strength after swelling, and the permeation rate of the polymer after swelling is lowered.
It is preferably 60 g / g or less. Further, when the permeation rate is less than 10 ml / min, the liquid flowability of the polymer after swelling is poor, the re-absorption rate after repeated excretion is deteriorated, and the absorption capacity of the superabsorbent polymer is efficiently increased. Cannot be expressed.

The composition and manufacturing method of the superabsorbent polymer 2b are not particularly limited as long as the centrifugal retention capacity and the absorption physical properties of the permeation rate are satisfied. Polymerizes acrylic acid or acrylic acid alkali metal salts (sodium salt, potassium salt), etc. that absorbs and holds a large amount of liquid by osmotic pressure and does not leak the absorbed liquid even under pressure. Further, a superabsorbent polymer composed of water-insoluble hydrophilic crosslinked polymer particles is preferably used. Among them, especially from the absorption space of the absorbent body that temporarily stores the body fluid, has a function of quickly absorbing the liquid, and after absorbing the body fluid and swelling, the surface of the superabsorbent polymer is kept in a dry state, Those having an absorption function that does not hinder the movement of the liquid excreted later are preferable.

Further, the above-mentioned absorption function is a function which is difficult to be exhibited when the above-mentioned super-absorbent polymer has a uniform cross-linking structure, so that the above-mentioned super-absorbent polymer preferably has a cross-linking density gradient.

As a method for imparting a crosslinking density gradient to the above-mentioned superabsorbent polymer, for example, when polyacrylate is used as the superabsorbent polymer, a crosslinking agent capable of reacting with a functional group of polyacrylate is used. (Hereinafter, referred to as “polymer cross-linking agent”), a method of further reacting with a polyacrylic acid salt to cross-link the surfaces, and the like. Particularly, by adjusting the amount of the polymer cross-linking agent used, the cross-linking density gradient can be increased. Can be adjusted.

The above-mentioned polymer crosslinking agent is preferably a water-soluble compound having two or more functional groups capable of reacting with a carboxy group, and examples thereof include ethylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether and glycerin triglycidyl ether. Examples thereof include haloepoxy compounds such as polyglycidyl ether, epichlorohydrin and α-methylchlorohydrin, polyols such as glutaraldehyde and glyoxal, and polyamines such as ethylenediamine. The amount of the polymer crosslinking agent used is 0.1 to 1 part by weight with respect to 100 parts by weight of the polymer such as the polyacrylate in order to optimize the crosslinking density gradient. preferable.

Further, the above superabsorbent polymer has a non-spherical particle shape and has an irregularity P of 1.2 or more,
Further, it is preferably 1.2 to 3.

When the particle morphology of the superabsorbent polymer is non-spherical, it is possible to prevent rearrangement of particles when the superabsorbent polymer absorbs body fluid and swells, and to prevent a decrease in voids due to adhesion. . Further, when the degree of irregularity P is less than 1.2, the irregularity value of the surface irregularities in the swollen superabsorbent polymer particles is insufficient, so that spaces are formed between the swollen superabsorbent polymer particles. Since it cannot be maintained and the liquid flowability between the particles may be deteriorated, it is preferable to have the above-mentioned irregularity.

The above irregularity P expresses the roughness of the superabsorbent polymer particles, and can be obtained by the following [Equation 1].

[0035]

[Equation 1]

Further, the actual area S and the perimeter l of the projected particles when calculating the irregularity P are high-absorbent polymer particles, which are projected particles by a product name "IV Image Processor EXCEL" manufactured by Nippon Avionics Co., Ltd. It can be measured by observing.

As described above, the superabsorbent polymer used in the present invention preferably has the above-mentioned absorbent physical properties by controlling the crosslinking density gradient, for example, by adjusting the amount of the polymer crosslinking agent used. However, not only such chemical structure control but also physical structure control (shape and irregularity) such as the particle morphology of the superabsorbent polymer as described above Can be further improved. That is, after the superabsorbent polymer absorbs body fluid and reaches swelling equilibrium, the physical structure of the swollen superabsorbent polymer also greatly contributes to the fluidity of the liquid, and in particular the spherical superabsorbent polymer. If a large amount of is used, the polymer particles tend to be closest packed to each other, the voids between the particles are extremely reduced, and the fluidity of the liquid deteriorates. In order to assemble with a gap between them, it is preferable to design the particle morphology of the superabsorbent polymer so as to have the above-mentioned irregularity P.

In order to prepare the superabsorbent polymer having the above-mentioned irregularity P, it can be obtained by pulverizing the superabsorbent polymer obtained by bulk polymerization, but it is obtained at the time of producing the superabsorbent polymer. It can also be obtained by a method in which the polymer particles are further brought into contact with each other by the above-mentioned polymer crosslinking agent. As the superabsorbent polymer, an amorphous superabsorbent polymer composed of an aggregated product having the polymer particles obtained by the above method as temporary particles can be more preferably used.

Further, the amount of the superabsorbent polymer used is
Preferably 20 to 80% by weight with respect to the entire absorber,
It is more preferably 30 to 60% by weight and the spray basis weight is preferably 20 to 500 g / m ² , more preferably 30.
Although the amount is up to 300 g / m ² , it is preferable to use them properly according to the type and purpose of the absorbent article to be used.
For example, in the field of sanitary napkins that absorb menstrual blood, in the case of a type with a small absorption amount such as a panty liner, the amount of the superabsorbent polymer used may be small, and conversely, for a long time, at night, etc. In the case of a type having a large absorption amount, it is preferable to use a large amount and ratio of the polymer. Further, since the absorbent article of the present invention is particularly suitable as an absorbent article having high absorbability even when worn for a long time when the amount of excrement is large, the effect of the absorbent article of the present invention is most remarkable. In order to express
The most preferable range is 0 to 300 g / m ² .

The amount of superabsorbent polymer used per absorbent article can also be varied depending on the type and size of the absorbent article.

For example, in sanitary napkins, the amount of superabsorbent polymer used is preferably 0.3 to 5 g, and 1 to 3 g.
Is more preferable. Also, for paper diapers for children, etc.
30g is preferable and 10-25g is more preferable.

When the amount of superabsorbent polymer used is less than 0.3 g for sanitary napkins, less than 5 g for disposable diapers, and the basis weight of spraying is less than 20 g / m ² , the ability to immobilize liquids. Is insufficient, which is not preferable. In addition, if the amount used exceeds 5 g for sanitary napkins, 30 g for disposable diapers, the basis weight for spraying exceeds 500 g / m ^2, and if the weight ratio of the polymer exceeds 80% by weight, high absorption is achieved. It is not preferable because the hydrophilic polymer cannot be completely fixed in the absorbent body.

The superabsorbent polymer 2b shown in FIG.
, The cross-linked cellulose fibers 2a can be used by being dispersed and mixed with each other, or, as described later, the super-absorbent polymer can be sandwiched between absorbent papers. The aspect provided in the absorbent body is not particularly limited, but in the present invention, in addition to the design of the superabsorbent polymer, the absorbent body is composed of paper or pulp fiber for temporarily storing body fluid. The design of the absorption space to be used is an important point. That is,
In an absorbent body mainly composed of a flap pulp sheet made of a normal softwood pulp like a conventional absorbent article, even if the above-mentioned superabsorbent polymer is used, before the pulp absorbs its absorbent function to the maximum, / Due to fatigue, the absorption rate deteriorates, leading to leakage.

The absorbent article of the present invention is a cross-linked cellulose that is cross-linked with a cross-linking agent inside or between the cellulose molecules so that the absorption space for temporarily storing body fluid is stable and does not become twisted or settled even when wet. By using the fiber 2a, the superabsorbent polymer 2b having a high retention amount satisfying the above-mentioned absorbent properties and having excellent permeability after swelling, and the crosslinked cellulose fiber 2a are combined to be used individually. In that case, an excellent effect that cannot be achieved can be obtained. The crosslinked cellulose fiber 2a will be described below.

As shown in FIG. 1, the crosslinked cellulose fiber 2a may be directly mixed with the superabsorbent polymer to form an absorbent body, but it will be described later with reference to FIGS. 2, 3, 4, and 6. As in the second to fifth examples shown in (1) to (4), an absorbent paper containing the crosslinked cellulose fibers 2a may be produced, and the absorbent paper may be used to form an absorbent body.

Examples of the cross-linking agent include N-methylol compounds such as dimethylol ethylene urea and dimethylol dihydroxyethylene urea; citric acid tricarballylic acid;
Examples thereof include polycarboxylic acids such as butanetetracarboxylic acid; polyols such as dimethylhydroxyethylene urea; and polyglycidyl ether-based crosslinking agents.

The amount of the cross-linking agent used is 0.2 to 100 parts by weight of the cellulose fiber to be cross-linked.
It is preferably 20 parts by weight. If the amount is less than 0.2 parts by weight, the cross-linking density is low, so that the elastic modulus of wetting is low, causing kinked, and if it exceeds 20 parts by weight, the cellulose fibers become too rigid and the fibers become brittle when stressed. Therefore, the amount used is preferably within the above range.

As the cellulose fiber used for the above-mentioned crosslinking, any of natural cellulose fiber such as pulp and cotton and regenerated cellulose fiber such as rayon and cupra may be used, and one kind of them may be used. Although it may be used or several kinds thereof may be mixed and used, in particular, pulp fibers such as softwood pulp are preferably used since they are inexpensive.

As described above, the reason why the cross-linking inside or between the cellulose molecules is a requirement is that the obtained cross-linked cellulose fibers are free from twisting / sagging when they are wet and the cross-linked cellulose fibers themselves absorb body fluid. Since they do not swell, even if the crosslinked cellulose fibers get wet due to the mutual effect, the distance between the fibers can be kept stable, and the body fluid can be smoothly transferred to the superabsorbent polymer.

The crosslinked cellulosic fiber is preferably such that there is no twisting / sagging when wet, that is, the residual strain when compressed when wet is small, and more specifically, the compressive residual strain when wet is preferable. It is preferably less than 40%, more preferably 0 to 35%. If the compressive residual strain when wet is 40% or more,
It is not preferable because the amount of twisting / sagging when wet becomes large, the absorption space changes, the distance between the fibers becomes small, and the transfer resistance to the polymer increases.

In order to make the compression residual strain stably less than 40% and to make the transfer resistance of the absorbed body fluid to the superabsorbent polymer lower and effective, it is necessary to crosslink the cellulose fibers. In addition, it is preferable to adjust the cross-sectional thickness of the crosslinked cellulose fiber. The reason is that the thicker the cross section of the crosslinked cellulose fiber is,
It is possible to more easily stabilize the compression residual rate when wet, keep the distance between fibers from becoming small, and to lower the migration resistance of the body fluid to the polymer to facilitate the design. Since the thickness of the crosslinked cellulose fiber is caused by the thickness of the cellulose fiber, the thickness of the cellulose fiber may be selected to adjust the thickness of the crosslinked cellulose fiber.

In addition, most of the conventional wood pulp fibers have a fiber roughness of less than 0.3 mg / m, and even if they are cross-linked, the effect due to the cross-linking is difficult to be exhibited, which is insufficient. As a result of research, the above effects can be further improved by crosslinking pulp fibers having a fiber roughness of 0.3 mg / m or more.

Examples of the pulp having a fiber roughness of 0.3 mg / m or more include kraft pulp NBKP (trade name; "ALBACEL", manufactured by Federal Paper Board Co.) and (trade name: "INDORAYON", PT). Inti Indorayon Utama
Manufactured) and the like.

The above-mentioned fiber has a cross-section thickness of a fiber roughness meter (FS-
200, manufactured by KAJAANI ELECTRONICS LTD.) And the like, and in this case, it is represented by the fiber roughness. In the present invention, the cross-sectional thickness of the cellulose fiber used for the cross-linking is preferably such that the fiber roughness is 0.3 to 2 mg / m, and 0.33 to 1 mg.
/ M is more preferable. Fiber roughness is 0.3 mg / m
Cellulose fibers of less than 1 are thin and liable, and thus the effect of cross-linking is difficult to be exhibited, which is not preferable. On the contrary, a cellulose fiber having a fiber roughness of 2 g / m or more is not preferable because the rigidity becomes too high.

Further, the closer the cross-sectional shape of the above-mentioned cellulose fiber is to a perfect circle, the smaller the resistance against migration of body fluid to the superabsorbent polymer, so it is preferable to adjust the above-mentioned cross-sectional shape as well.
Specifically, the roundness of the cross section of the cellulose fiber,
It is preferably 0.5 or more. The cross section of wood pulp fibers such as hardwood pulp and softwood pulp that are commonly used has a flat cross-sectional shape due to delignification treatment, and since the roundness of most of the cross sections is less than 0.5, The above-mentioned cellulose fiber having a roundness of 0.5 or more,
It is preferably obtained by swelling the fiber cross section by mercerization treatment. That is, as the crosslinked cellulose fiber used in the present invention, a mercerized crosslinked pulp obtained by further crosslinking a mercerized pulp having a circularity of 0.5 or more obtained by mercerizing ordinary pulp fibers is most preferable. Used.

In the mercerized crosslinked pulp, for example, the pulp having the fiber roughness of 0.3 mg / m 2 or more may be mercerized to increase the roundness of the cross section and then crosslinked.
The mercerized pulp may be obtained and crosslinked before use. As the above mercerized pulp, (trade name; "FILTRANIE
R ", manufactured by ITT Rayonier Inc.) (Product name:" POROSANIE "
R ”, manufactured by ITT Rayonier Inc.) and the like.

Further, in the sanitary napkin 10 of the present embodiment shown in FIG. 1, the permeation absorbent paper 2c forming the uppermost layer of the absorbent body 2 is an absorption paper having a high body fluid absorption permeation rate. Preferably, the permeation rate of the permeation-absorption paper 2c is set such that the permeation time of 10 g of an 85% by weight glycerin aqueous solution is 5%.
It is preferably 0 seconds or less, more preferably 5 to 40 seconds. If the permeation time exceeds 50 seconds, the permeation speed as the uppermost layer of the absorber is slow, the absorption time as the whole absorber is delayed, and body fluid may flow and leak on the surface of the absorber, which is preferable. Absent. The method of measuring the transmission rate will be described later.

As described above, the absorbent paper having a high permeation rate is at least a) crosslinked cellulose fiber; preferably 5
0 to 98% by weight, more preferably 70 to 98% by weight and b) heat-meltable adhesive fiber; preferably 2 to 30% by weight, more preferably 2 to 20% by weight, and basis weight 20 to 60.
Absorbent paper and the like obtained by making paper at g / m ² can be preferably mentioned. As the method of mixing and papermaking, a generally known method can be adopted without any particular limitation.
If the cross-linked cellulose fiber content is less than 50% by weight, the resulting absorbent paper will have an insufficient permeation rate, and if it exceeds 98% by weight, it will be difficult to form a sheet, which is not preferable. If the amount of the heat-meltable adhesive fiber is less than 2% by weight, the strength of the absorbent paper is insufficient and it becomes difficult to form a sheet.
If it exceeds 0% by weight, the permeability of the absorbent sheet may decrease, which is not preferable.

As the above-mentioned hot-melt adhesive fibers, fibers which are melted by heating and adhere to each other are used. Specifically, for example, olefin fibers such as polyethylene, polypropylene, polyester and polyvinyl alcohol; polyethylene- Particularly preferable examples include polypropylene conjugate fiber, polyethylene-polyester conjugate fiber, low melting point polyester-polyester conjugate fiber, polyvinyl alcohol-polypropylene conjugate fiber having a hydrophilic fiber surface, polyvinyl alcohol-polyester conjugate fiber, and the like.

In addition to the cross-linked cellulose fiber and the heat-melting adhesive fiber, other components can be mixed in the permeation absorbent paper 2c. The other components include softwood pulp, hardwood pulp, straw pulp and the like. Other pulps, aldehyde starches and sponge as a strong auxiliary agent can be mentioned.

Further, as shown in FIG. 1, the crosslinked cellulose fibers do not necessarily have to be used by mixing with the superabsorbent polymer, and the cellulose fibers may be used as in the second to fifth examples described later. The above absorbent body may be provided with a wet type absorbent paper having

Most of the conventional absorbent papers are absorbent papers obtained by wet-making ordinary natural pulps containing no crosslinked cellulose fibers. However, absorbent papers made from natural pulps such as softwood pulps are dehydrated during papermaking. / Wet pressure / drying process, when water is dehydrated / dried, interfacial tension of water and very strong tightening force due to hydrogen bond act between pulp fibers. Since the pulp fibers are tightened by the tightening force, the conventional absorbent paper is
The absorption / permeation of body fluid becomes very slow, and furthermore, the absorption space is extremely reduced. That is, even if a conventional absorbent paper and the above-mentioned super absorbent polymer are combined to form an absorbent body, since the above-mentioned absorption space for temporarily storing body fluid is small and the distance between fibers becomes dense, the permeability of body fluid is high. However, the absorption performance of the above superabsorbent polymer could not be fully utilized. Therefore, in the present invention, by blending the above-mentioned crosslinked cellulose fibers, the hydrogen bond between fibers during wet papermaking is suppressed, the absorption space is enlarged, and the flow of body fluid that absorbs / permeates / diffuses body fluid is achieved. By obtaining a controlled absorbent paper and constructing an absorbent body by combining this with the above-mentioned superabsorbent polymer, it is possible to obtain an absorbent article that is extremely stable and easy and has excellent absorption performance even if it is thinner than the conventional one. provide.

Next, a second embodiment of the present invention shown in FIG. 2 will be described. It should be noted that the same points as those of the above-described first embodiment will not be described in detail, but the detailed description of the above-described examples will be appropriately applied. Also, in the figure, the first
The same parts as those in Example 1 are assigned the same reference numerals.

The sanitary napkin 10 of this embodiment shown in FIG.
The absorbent body 2 has the super absorbent polymer 2b and the diffusion absorbent paper 2d coated with the super absorbent polymer 2b.
And a transparent absorbent paper 2c forming the uppermost layer of the absorbent body 2 so as to cover the front surface (skin contact surface side), the side surface and the back surface of the diffusion absorbent paper 2d.

The diffusion absorbing paper 2d is the transparent absorbing paper 2d.
It is provided in order to quickly diffuse the bodily fluid permeated from c to the entire superabsorbent polymer 2b and smoothly deliver the bodily fluid to the superabsorbent polymer 2b. Specifically, an absorbent paper having the following composition and the following physical properties is preferably used. At least a) the above crosslinked cellulose fiber; preferably 20 to 8
0% by weight, more preferably 30 to 70% by weight, b) the heat-meltable adhesive fiber; 0 to 30% by weight, more preferably 0.
20 to 20% by weight and c) hydrophilic fine fibers; 80 to 20% by weight, more preferably 70 to 30% by weight, are mixed and made into a paper with a basis weight of 20 to 60 g / m ² , and used for physiological saline. An absorption paper having a creme absorption height after 1 minute of 50 mm or more, a creme absorption height after 10 minutes of 100 mm or more, and a permeation time of 100 g of 85% by weight glycerin aqueous solution of 100 seconds or less. As the method of mixing and papermaking, a generally known method can be adopted without any particular limitation.
The method for measuring the creme absorption height will be described later.

The cross-linked cellulose fiber and the heat-melting adhesive fiber are the same as the cross-linking cellulose fiber and the heat-melting adhesive fiber described in the above example. If the cross-linked cellulose fiber content is less than 20% by weight and the hydrophilic fine fiber content is more than 80% by weight, the absorbent paper becomes too tight at the time of papermaking, the permeation rate becomes insufficient, and the space where liquid can be substantially diffused decreases. On the contrary, when the crosslinked cellulose fiber exceeds 80% by weight or when the hydrophilic fine fiber is less than 20% by weight, the diffusion distance becomes insufficient, which is not preferable. On the other hand, if the above-mentioned heat-soluble adhesive fiber exceeds 30% by weight, the hydrophilicity of the absorbent paper as a whole is lowered, and both the diffusivity / permeability may be lowered, which is not preferable.

As the hydrophilic fine fibers, fibers having a hydrophilic surface and a large surface area, preferably having a fiber roughness of less than 0.2 mg / m and a circularity of a cross section of 0.5. Preferred are hydrophilic fibers having a surface area of less than 1.0 m ² / g or more.

The hydrophilic fiber is not particularly limited as long as it has the above-mentioned physical properties, and examples thereof include cellulose fiber typified by pulp fiber, cotton and rayon, and hydrophilic synthetic fiber such as acrylonitrile and polyvinyl alcohol. However, only one of these may be used, or several types may be mixed and used. Among them, pulp fiber can be used preferably because it is available at a very low cost and the fiber surface area can be controlled by beating conditions. For example,
"Craft pulp NBKP" (trade name; "SKEENA PRIM
"E", made by Skeena Cellulose Co.) and "LBKP" (trade name; "PRINCE ALBERT ASPEN HA
RDWOOD ", manufactured by Waiwauser Paper Co., Ltd.] and straw pulp.

Next, a third embodiment of the present invention shown in FIG. 3 will be described. It should be noted that the same points as those of the above-described first embodiment will not be described in detail, but the detailed description of the above-described examples will be appropriately applied. Also, in the figure, the first
The same parts as those in Example 1 are assigned the same reference numerals.

The sanitary napkin 10 of this embodiment shown in FIG.
The absorbent body 2 sandwiches the superabsorbent polymer 2b with the diffusion absorbent paper 2d, sprinkles the superabsorbent polymer 2b in multiple layers, and coats the entire surface with the transmissive absorbent paper 2c to form one body. Has been formed.

As described in the second and third embodiments, the method of combining the highly absorbent and highly permeable diffusion absorbing paper 2d and the highly absorbent polymer 2b is not particularly limited and various selections are made. It is possible.

Next, a fourth embodiment of the present invention shown in FIGS. 4 and 5 will be described. It should be noted that the same points as those of the above-described first embodiment will not be described in detail, but the detailed description of the above-described examples will be appropriately applied. Further, in the figure, the same parts as those in the first embodiment are designated by the same reference numerals.

The sanitary napkin 10 of this embodiment shown in FIG.
The absorbent body 2 is formed by coating the super absorbent polymer 2b with the composite absorbent paper 2f. The above composite absorbent paper 2f
As shown in FIG. 5, is formed by compositely integrating a first layer made of the transparent absorption paper 2c and a second layer made of the diffusion absorption paper 2d.
At the time of wrapping, the diffusion absorption paper 2d is brought into contact with the super absorbent polymer 2b.

There is no particular limitation on the method of combining the transparent absorbing paper 2c and the diffusion absorbing paper 2d in a combined manner as long as they can be integrated. Examples include integration by embossing and integration by pressure-sensitive adhesives and adhesives represented by hot melt, etc., but the integration of both in the papermaking process is because the fibers that make up the absorbent paper are denser. It is the most preferable method because it entangles with the body and the body fluid is smoothly transmitted. As a method of integrating them in the papermaking process, a transparent absorption paper and a diffusion absorption paper are each made with their respective paper machines, they are laminated and then dried (multi-layer papermaking), and many papermaking nozzles are used to blow the papermaking wire at the time of papermaking. Examples include a method of arranging in rows and making a transparent absorption paper and a diffusion absorption paper in a plurality of rows at a time with each composition to make paper.

By combining the transparent absorbent paper and the diffuse absorbent paper together as in the present embodiment, body fluid does not flow between the two and is smoothly guided to the superabsorbent polymer, and more securely fixed. It That is, when the absorbent papers are separated from each other, bodily fluids stagnate between the absorbent papers and are difficult to be transferred to the polymer. However, as shown in FIG. 4, the transparent absorbent paper and the diffusion absorbent paper are combined and integrated. By combining the combined absorbent paper and super absorbent polymer, the body fluid absorbed and permeated on the surface of the permeation absorbent paper is smoothly absorbed inside the absorbent body without stagnation between the absorbent papers and diffused and absorbed. It is diffused throughout the absorber with paper and completely immobilized with superabsorbent polymer.

If such a composite absorbent paper is used,
The absorbent body can be composed of only one sheet of absorbent paper and the superabsorbent polymer, and a highly absorbent and ultrathin absorbent body can be obtained very easily.

Next, a fifth embodiment of the present invention shown in FIGS. 6 and 7 will be described. It should be noted that the same points as those of the above-described first embodiment will not be described in detail, but the detailed description of the above-described examples will be appropriately applied. Further, in the figure, the same parts as those in the first embodiment are designated by the same reference numerals.

The sanitary napkin 10 of this embodiment shown in FIG.
The absorbent body 2 is formed by wrapping the super absorbent polymer 2b with the composite absorbent paper 2g. 2g of the above composite absorbent paper
As shown in FIG. 7, it is formed by compositely integrating a first layer made of the transparent absorption paper 2c, a second layer made of the diffusion absorption paper 2d, and a third layer made of polymer dispersed paper 2e. Therefore, when the superabsorbent polymer 2b is included, the diffusion absorbent paper 2d is used as the superabsorbent polymer 2b.
It is designed to come into contact with b.

The polymer-dispersed paper 2e is for preventing the super-absorbent polymers from aggregating with each other even when many super-absorbent polymers are wrapped and integrated between the composite absorbent papers. It is possible to effectively suppress gel blocking of the superabsorbent polymer and further improve the liquid flowability between the particles of the superabsorbent polymer. The raw material composition of the polymer-dispersed paper 2e is preferably composed mainly of the above-mentioned crosslinked cellulose fibers that do not get wet when wet, and has a composition that fluffs at a low density in order to bury the superabsorbent polymer. Specifically, a) crosslinked cellulosic fibers; preferably 70 to 100% by weight, more preferably 80 to 100% by weight, and b) heat adhesive fibers; preferably 0 to 30% by weight, more preferably 0 to 20%. A weight percent composition is preferred.
The polymer-dispersed paper 2e is preferably an absorbent paper prepared by mixing with the above composition and making a paper having a basis weight of preferably 10 to 50 g / m ² , and more preferably 10 to 30 g / m ² .

In the present invention, it is particularly preferable to use the absorbent body 2 having the structure shown in FIG. 6 because it is an absorbent article which exhibits high absorption performance even when excreting more.

As described above, the absorbent article of the present invention comprises an absorbent body obtained by combining the above-mentioned highly absorbent polymer having high retention and high permeability with the above crosslinked cellulose fiber capable of stabilizing the absorbent space even when wet. Since it is composed, it is possible to make the excellent high absorption performance, especially the excellent reabsorption rate / retention capacity during repeated excretion, which cannot be achieved when used alone, thinner than that of the conventional absorbent article. However, it is highly excretable, has high excretion, and is highly comfortable with no liquid return, stickiness, or leakage even when worn for a long time. In addition, an absorbent paper mainly composed of the above-mentioned crosslinked cellulose fiber and having a controlled absorption / permeation / diffusion performance of body fluid (the above-mentioned permeation / absorption paper, the above-mentioned diffusion / absorption paper,
By combining the above composite absorbent paper) and the above superabsorbent polymer, it is possible to construct an extremely highly absorbent absorber very simply.

Next, the absorbent article of the present invention will be specifically described based on Examples and Comparative Examples. First, the superabsorbent polymer, cellulose fiber, and absorbent sheet used in Examples and Comparative Examples were prepared in the following manner, and their functions were measured. Unless stated otherwise, "%" in the text
"% By weight" is shown.

(1) Preparation of superabsorbent polymer Superabsorbent polymer (A) 230 ml of cyclohexane and sorbitan were placed in a 500 ml four-neck round bottom flask equipped with a stirrer, reflux condenser, dropping funnel and nitrogen gas inlet tube. Monostearate [trade name;
"Leodoll SPS-12", manufactured by Kao Corporation] 1.4 g
Was charged and stirred to obtain a uniform solution. Separately, in an Erlenmeyer flask, 30 g of acrylic acid monomer and 39 g of water
Neutralized with an aqueous solution of caustic soda in which 13.4 g of caustic soda was dissolved to a monomer concentration of 45% (water content 55%),
To this, 0.1 g of potassium persulfate was added and dissolved to obtain a monomer aqueous solution. Then, the obtained monomer aqueous solution was dropped into the above-described four-necked round bottom flask charged with cyclohexane and sorbitan monostearate under a nitrogen atmosphere and then heated to 70 to 75 ° C. to start polymerization. It was Next, the amount of water in the polymer suspended in cyclohexane was controlled to 35% by azeotropic dehydration (cyclohexane was refluxed). Then, an aqueous solution prepared by dissolving 0.03 g of ethylene glycol diglycidyl ether in 1 ml of water was added at 73 ° C., and the mixture was kept at the same temperature for 2 hours, then cyclohexane was removed, and the product was heated at 80 to 100 ° C.
And dried under reduced pressure to obtain a superabsorbent polymer (A).

Super Absorbent Polymer (B) 40 g of the above super absorbent polymer (A) was again put into a 500 ml four-necked round bottom flask together with 230 ml of cyclohexane and water was added to control the water content to 35%. The temperature was raised to 75 ° C. After reaching a constant temperature (75 ° C.), 2500 ppm of ethylene glycol diglycidyl ether was added to the superabsorbent polymer (A).
Then, after maintaining at 75 ° C for 3 hours, cyclohexane was removed, and the product was dried under reduced pressure at 80 to 100 ° C to obtain a superabsorbent polymer (B).

Superabsorbent Polymer (C) Commercially available superabsorbent polymer [trade name; "Aqualic CA
-W4 ", manufactured by Nippon Shokubai Co., Ltd.) was used as the superabsorbent polymer (C).

Superabsorbent Polymer (D) The solution in a four-necked round bottom flask charged with cyclohexane and sorbitan monostearate was heated to 70 to 75 ° C., and the above monomer aqueous solution was added thereto under a nitrogen atmosphere to 1. 5
After the drop-wise polymerization over a period of time, the superabsorbent polymer (D) was produced in the same manner as in the production of the above-described superabsorbent polymer (A), except that the polymerization was terminated at a temperature of 70 to 75 ° C. for 0.5 hours. Got

Super Absorbent Polymer (E) Except that 1.94 g of ethyl cellulose [trade name; "N-200", manufactured by Half Leas Far East Co., Ltd.] was used as the dispersion medium instead of "Reodol SPS-12". A superabsorbent polymer (E) was obtained in the same manner as in the production of the superabsorbent polymer (D).

The irregularities of the above superabsorbent polymers (A) to (E), the amount of absorption and retention after centrifugation in physiological saline, and the permeation rate were measured. The results are shown in [Table 1].
Incidentally, the above-mentioned irregularity is the above-mentioned method, and the retained absorption amount and the permeation rate after centrifugation with respect to physiological saline are:
It was measured by the following method.

[0089]

[Table 1]

<Measurement of Retained and Absorbed Amount after Centrifuging> 1 g of the superabsorbent polymer was placed in a beaker containing 500 ml of physiological saline and left as it was for 30 minutes. The sufficiently absorbed and swollen superabsorbent polymer was made into a bag shape with paper and non-woven fabric so that the polymer would not fall off, and completely fixed to the polymer with a centrifugal separator (Domestic Centrifuge Co., Ltd.) H-130C type. 2000 rpm to determine the amount of normal saline
It was rotated at a rotation speed of / min (centrifugal acceleration of 895 G) for 10 minutes, then weighed, and the retained absorption amount (centrifuged retention amount) after centrifugation was determined by the formula shown in [Formula 2] below.

[0091]

[Equation 2]

<Measurement of Transmission Speed> Device 20 shown in FIG.
[Burelet consisting of a glass cylindrical tube with an inner diameter of 10 mm and a length of about 250 mm (cylindrical part)]
0.05 g was filled, the polymer was equilibrated and swelled with an excess of physiological saline, and a liquid level was adjusted to 200 mm and a cock was attached, and it was confirmed that the swollen polymer P was sufficiently settled as shown in the drawing. The time required for the physiological saline to pass through the two lines L and M shown in the figure (liquid volume 5 ml) was determined, and the liquid passage speed was determined by the formula shown in [Equation 3] below.

[0093]

[Equation 3]

(2) Cellulose fiber Cellulose fiber (A) The fiber roughness is 0.36 mg / m and the roundness of the fiber cross section is 0.
80 mercerized pulp (trade name; "Porosenia-
J ", manufactured by ITT RAYONIER INC.) As a cross-linking agent, dimethylol dihydroxyethylene urea [trade name;
"Sumitex Resin NS-19" manufactured by Sumitomo Chemical Co., Ltd.]
5%, metal salt catalyst [trade name; "Sumitex Accelerator
X-110 "manufactured by Sumitomo Chemical Co., Ltd.] was dispersed in 1000 g of a crosslinking agent aqueous solution containing 3% to impregnate the crosslinking agent.
Then, the cross-linking agent aqueous solution was released from the mercerized pipe until the amount of the cross-linking agent aqueous solution with respect to the mercerized pulp reached 200%, and then 1 ° C. in an electric dryer at 135 ° C.
Heat for 0 minutes to cross-link the cellulose in the pulp,
A mercerized crosslinked pulp was obtained, which was used as a cellulose fiber (A).

Cellulose Fiber (B) The fiber roughness is 0.35 mg / m and the roundness of the fiber cross section is 0.
28 softwood kraft pulp (trade name; "INDORAYO
N ", manufactured by PT Inti Indorayon Utama) as a cross-linking agent, dimethylol dihydroxyethylene urea [trade name;
"Sumitex Resin NS-19", Sumitomo Chemical Co., Ltd.] 5 wt%, metal salt catalyst [trade name; "Sumitex Accelerator X
-110 "manufactured by Sumitomo Chemical Co., Ltd.] was dispersed in an aqueous solution of a crosslinking agent containing 5 wt% to impregnate the crosslinking agent. Then
After the cross-linking agent aqueous solution was released from the kraft pulp until the cross-linking agent aqueous solution to the conifer kraft pulp was 200%, it was heated in an electric dryer at 135 ° C. for 10 minutes to cross-link the cellulose in the pulp fiber, A crosslinked pulp fiber was obtained, which was used as a cellulose fiber (B).

Cellulose fiber (C) The fiber roughness is 0.78 mg / m, and the roundness of the fiber cross section is 0.6.
8 and 8 mm in length rayon [trade name; "Corona SB rayon", manufactured by Daiwabo Rayon Co., Ltd.), except that a cross-linking reaction was performed in the same manner as the above-mentioned cellulose fiber (A) to obtain a cross-linked pulp fiber. , Cellulosic fiber (C)
And

Cellulose fiber (D) The fiber roughness was 0.18 mg / m and the roundness of the fiber cross section was 0.
32 Softwood kraft pulp NBKP (trade name; SK
EENA PRIME, Skeena Cellulose CO.) Was used as the cellulose fiber (D).

Cellulose fiber (E) The fiber roughness was 0.24 mg / m and the roundness of the fiber cross section was 0.
34 Softwood kraft pulp NBKP (trade name; HA
RMAC-R, MacMillan Bloedel, ltd.) Was used as the cellulose fiber (E).

Cellulose fiber (F) The fiber roughness is 0.18 mg / m and the roundness of the fiber cross section is 0.
32 Softwood kraft pulp NBKP (trade name; SK
EENA PRIME, Skeena Cellulose CO.)
A cross-linking reaction was performed in the same manner as the cellulose fiber (A) to obtain a cross-linked pulp fiber, which was used as a cellulose fiber (F).

The fiber roughness of the above-mentioned cellulose fibers (A) to (F), the circularity of the fiber cross section, the compressive residual strain when wet, and the area swelling ratio of the fiber cross section when wet were measured by the following methods. did. The results are shown in [Table 2].

[0101]

[Table 2]

<Measurement of Fiber Roughness> In order to obtain the average fiber thickness of fibers having a non-uniform fiber cross section such as pulp, a fiber roughness meter FS-200 (KAJAANI ELECTRONICS LT
(Manufactured by D.). First, in order to obtain the true weight of the sample, the sample is dried in a vacuum dryer at 100 ° C. for 1 hour to evaporate the water content in the fiber. Accurately weigh about 1g of fiber with an accuracy of ± 0.1mg,
Let the sample weight be M. Then, in order to avoid damaging the fibers of the sample, 1 the fibers with a mixer attached to the fiber roughness meter.
Completely disintegrate in 50 ml of water, dilute it with water to 5000 ml, accurately measure 50 ml from the obtained diluted solution, use this as the solution for measuring fiber roughness, and follow the procedure of the above fiber roughness meter. The fiber roughness was determined.

<Measurement of Roundness of Fiber Cross Section> The roundness of the fiber cross section is measured by first slicing the fiber cross section vertically so that the area does not change, and taking a cross-sectional photograph by an electron microscope. The photograph was analyzed by an image analyzer (trade name "Avio EXCEL" manufactured by Nippon Avionics Co., Ltd.), and the roundness of the fiber cross section was determined using the formula shown in [Formula 4] below. still,
The roundness was an average value obtained by measuring 100 points on an arbitrary fiber cross section.

[0104]

[Equation 4]

<Compression Residual Strain after Wetting> A sample of cellulose fibers was formed into a sheet having a basis weight of 500 g / m ² and a size of 50 mm × 50 mm, and was subjected to a load of 5.0 ± 5 ± 5 mm / cm ^2.
Adjusted to be the thickness l ₀ of 0.1 mm. Then, assuming that the body fluid has been excreted, the saline solution 1
2.5g (about 10 times the sheet weight) is applied almost evenly,
Moisten the entire sheet. Then, using a Tensilon compression tester, a compression area of 10 cm ² (a disk with a radius of 1.78 cm), a compression speed of 10 mm / min, and a maximum load of 200 g / cm
Compress up to ² (ie 2000 g total) and depressurize at a constant rate. At this time, the physiological saline solution overflowing from the pulp by compression was absorbed and removed by a tissue or the like. This operation was repeated 10 times in total, and the thickness l ₁ under a load of 5 g / cm ² after the compression measurement was obtained, and the compressive deformation strain was obtained using the formula shown in [Formula 5] below.

[0106]

[Equation 5]

(3) Preparation of Absorbent Sheet Absorbent Sheet (A) 95 parts by Weight of Cellulose Fiber (A) as Cross-Linked Cellulose Fiber and Polyvinyl Alcohol [Trade Name: Fibribond, Sansho (Ltd.) )] 5 parts by weight are dispersed and mixed in water, respectively, paper-made, and then dried to make a sheet having a basis weight of 40 g / m ² , which is the absorbent sheet (A).
And

Absorbent Sheet (B) 90 parts by weight of cellulose fiber (B) as cross-linked cellulose fiber and polyethylene terephthalate (hereinafter PET) having a thickness of 1.1 denier and a length of 5 mm as heat-melting adhesive fiber.
(Trade name; "TMOTNSB", Teijin Ltd.) 10 parts by weight are each dispersed and mixed in water, paper-made, and dried to obtain an absorbent paper having a basis weight of 40 g / m ^2. (B).

Absorbent Sheet (C) Cellulose Fiber (A) 70 Layers as Crosslinked Cellulose Fiber
Part and, as hydrophilic fine fibers, fiber roughness 0.18 mg / m
Kraft pulp NB with a fiber roundness of 0.32
KP (Product name: "SKEENA PRIME", Skeena Cellulose
(Manufactured by Co.) and 70 parts by weight are dispersed and mixed in water.
40 g / m2 basis weight obtained by drying after printing on paper ²Absorb the absorbent paper
The sheet was designated as a sheet (C).

Absorbent Sheet (D) Cellulose fiber (C) is used as crosslinked cellulose fiber 30
Parts by weight, and fiber roughness as hydrophilic fine fibers 0.16 mg /
Kraft pulp NBK with m of m and fiber roundness of 0.31
P (Product name: "TYEE KRAFT", Weyerhaeuser Canada, L
40 parts by weight of mercerized pulp (trade name;
30 parts by weight of "Porosenia-J" (manufactured by ITT RAYONIER INC.) Was mixed, paper was made, and then dried to obtain a basis weight of 40 g /
An absorbent sheet (D) was obtained from the m ² absorbent paper.

Absorbent sheet (E) Kraft pulp NBKP (trade name; "SKEENA PRIME",
100 parts by weight of Skeena Cellulose Co.) was dispersed in water, and then papermaking and drying were performed to obtain an absorbent sheet (E) having a basis weight of 40 g / m ² . In this absorbent sheet (E),
Cross-linked cellulose fiber is not included.

Absorbent sheet (F) 0.7 denier, 38 mm long rayon table (manufactured by Daiwabo Rayon Co., Ltd.) was entangled with fibers by a water jet to obtain a nonwoven fabric having a basis weight of 40 g / m ^2. Was used as the absorbent sheet (F). The absorbent sheet (F) does not contain crosslinked cellulose fibers.

Absorbent Sheet (G) A dry pulp sheet having a basis weight of 40 g / m ² [trade name; “Kinocloth”, Honshu Paper Co., Ltd.] was used as the absorbent sheet (G). The absorbent sheet (G) does not contain crosslinked cellulose fibers.

Absorbent Sheet (H) Cellulose fiber (A) is used as the crosslinked cellulose fiber 95
Part by weight and 5 parts by weight of polyvinyl alcohol (trade name; "Fibribond", Sansho Co., Ltd.) as a heat-melting adhesive fiber are dispersed and mixed in water to obtain a transparent absorbent paper 2c having a basis weight of 40 g / m ^2. Kraft produced by another papermaking machine with 70 parts by weight of cellulose fibers (A) as crosslinked cellulose fibers, hydrophilic fine fibers having a fiber roughness of 0.16 mg / m and a roundness of fiber section of 0.31. Pulp NBKP (trade name; "TY
EE KRAFT ”, 30 parts by weight of Weyerh Aeuser Canada, Ltd.) were dispersed and mixed in water to prepare a diffusion absorbing paper 2d having a basis weight of 40 g / m ² . Next, the transmission / absorption paper 2c and the diffusion / absorption paper 2d are put together to form the first layer of the transmission / absorption paper 2c having the structure shown in FIG.
The composite absorbent paper (formed by forming the second layer by d) was wet-processed and dried to obtain a composite absorbent paper having a total basis weight of 80 g / m ² , which was used as the absorbent sheet (H).

Absorbent Sheet (I) The transparent absorbent paper 2c and the diffusion absorbent paper 2d were obtained with the same composition and basis weight as the absorbent sheet (H). Separately, in a third paper machine, 98 parts by weight of cellulose fibers (A) as crosslinked cellulose fibers and 2 parts by weight of polyvinyl alcohol (trade name; Fibribond, Sansho Co., Ltd.) were put into water. Dispersion and mixing were performed to prepare a polymer dispersion paper 2e having a basis weight of 20 g / m ² . Next, the transmission / absorption paper 2c, the diffusion / absorption paper 2d, and the polymer-dispersed paper 2e are combined to form a first layer of the configuration shown in FIG. To form the second layer, and the polymer-dispersed paper 2e to form the third layer). The composite absorbent paper is wet-processed and dried to obtain a composite absorbent paper having a total basis weight of 100 g / m ^2. Was used as the absorbent sheet (I).

The creme absorption height (after 1 minute and after 10 minutes) of the absorbent sheets (A) to (G) with respect to physiological saline and the permeation time of an aqueous 85% by weight glycerin solution were measured by the following methods. . The results are shown in [Table 3].
Since the absorbent sheets (H) and (I) are composite absorbent papers, the basis weights are also greatly different, and the absorbent sheets (A) to (G) are different.
Since it cannot be evaluated in the same manner as above, the physical properties of the absorbent sheet were not measured.

[0117]

[Table 3]

<Crem absorption height (after 1 minute and 10 minutes)
> The Krem absorption height was measured using the apparatus shown in FIG.
First, the absorbent sheet was cut into a length of 300 mm and a width of 20 mm to prepare a measurement piece 30 shown in FIG. Next, as shown in FIG. 9, the measurement piece 30 was hung so that the support 31 had no slack, and the upper and lower ends were fixed. Also, 300 × 1
The physiological saline 33 was used as a measuring solution to a height of 40 mm in a rectangular parallelepiped container 32 of 00 × 50 mm (length × width × depth), and the measuring piece 30 was immersed in the physiological saline 33. Then, 1 minute after the measurement piece 30 was dipped, the height of the measurement liquid absorbed by the measurement piece 30 from the liquid surface and the height of the measurement piece 30 absorbed from the liquid surface after 10 minutes were measured. Performs the same respective 10 points of measurement were the absorption height h ₁₀ of the average absorption height after 1 minute of each taking a value h _1, and after 10 minutes saline 33.

<Measurement of transit time> The measurement of the transit time was performed using the measuring device shown in FIG. First, the absorbent sheet is cut into a length of 50 mm and a width of 50 mm to produce a measuring piece 40, and then the measuring piece 40 is clamped and fixed from both upper and lower sides by glass tubes 41, 41 having an inner diameter of 35 mm as shown in FIG. did. At this time, in order to prevent the liquid from seeping out from the side during the measurement, it was fixed from both sides with clips through the silicone rubber 42. Glycerin 85% aqueous solution 43 10
10 g was placed in a ml beaker 44 and gently poured into the glass tube 41. After injecting the glycerin 85% aqueous solution 43,
With respect to the open area of the glass tube 41, the time until 50% or more of the surface of the measurement piece appeared was determined and used as the passage time of the liquid.

Measurement liquid (85% glycerin aqueous solution)
Was adjusted as follows. After mixing 15 g of ion-exchanged water with 85 g of glycerin [Wako Pure Chemical Industries, Ltd.], 0.01 g of Food Blue No. 1 [Tokyo Chemical Industry Co., Ltd.] was added to give a blue color.

(4) Preparation of liquid-permeable surface material

[Liquid-permeable Surface Material A] Mixture of Alkyl Phosphate and Sorbitan Fatty Acid Ester A polyethylene / polypropylene composite fiber (manufactured by Chisso Corporation) coated with 0.34% by weight of a surfactant was prepared. Quantity 25
25 μm of low-density polyethylene (manufactured by Mitsui Petrochemical Co., Ltd.) 51 was laminated on a dry heat-bonded nonwoven fabric 52 of g / m ² ,
The surface material A shown in FIG. 11 was obtained. The surface material A is the wall portion 53.
Has a size of 0.1 to ² mm ² and a density of 52 holes / cm ² , and has a hydrophobic surface made of low density polyethylene 51 and a hydrophilic surface made of nonwoven fabric 52. ing.

(Example 1) As the cellulose fiber 2a,
Basis weight 150 g / m ² , density 0.15 g / cm ³ , thickness 1
mm, a length of 175 mm and a width of 73 mm are used, and 0.5 g of the superabsorbent polymer (A) is used as the superabsorbent polymer 2b so that the basis weight is 39 g / m ^2. After being spread on the cellulose fibers (A) and dispersed and mixed with each other, this is coated with a permeation absorbing paper 2c which is obtained by cutting the absorbent sheet (A) into a length of 175 mm and a width of 160 mm. The absorber 2 having the structure shown was prepared. The absorbent body 2 thus obtained was treated with a poly-ami waterproof paper (length 20
5 mm, width 95 mm) is wound up using the leak preventive material 3, and further the liquid permeable surface material A (length 205 mm, width 172 mm)
In this way, the absorbent body 2 with the leak preventive material 3 wound up was wrapped and fixed using a hot melt adhesive as the fixing agent 6. Further, three hot-melt adhesives having a basis weight of 30 g / m ² , a width of 10 mm, and a length of 115 mm were coated on the back surface side of the liquid-permeable surface material A as a pressure-sensitive adhesive portion 4, and the physiology of the constitution shown in FIG. A napkin for use (invention product 1) was obtained.

Example 2 As the cellulose fiber 2a,
Basis weight 150 g / m ² , density 0.15 g / cm ² , thickness 1
mm, length 175 mm, width 73 mm adjusted, using cellulose fiber (B), as superabsorbent polymer 2b, 0.5 g of superabsorbent polymer (B), the above cellulose so as to have a basis weight of 39 g / m ^2. After spraying on the fiber (B),
As the absorbent sheet 2c, the absorbent sheet (B) has a length of 1
The absorbent body 2 shown in FIG. 1 was prepared by wrapping it in a piece cut into 75 mm and 160 mm in width. Other than this, the sanitary napkin (Product 2 of the present invention) having the structure shown in FIG. 1 was prepared in the same manner as in Example 1.

Example 3 As an absorbent sheet 2d for enclosing a superabsorbent polymer,
The absorbent sheet (C) having a length of 175 mm and a width of 190 mm was used, and a hot-melt adhesive was sprinkled on the absorbent sheet (C) in a spiral shape at a rate of about 10 g / m ² to obtain a super absorbent polymer 2b. Super absorbent polymer (A) 0.5g
Is spread over the absorbent sheet (C) in an area having a length of 175 mm and a width of 73 mm almost uniformly (basis weight: about 39 g / m ² ), and the absorbent sheet (C) is rolled up from both ends to obtain high absorbency. 73mm width wrapped to prevent polymer (A) from falling off
Integrated into. This was wrapped with an absorbent sheet (c) having a length of 175 mm and a width of 130 mm, which was wrapped as an absorbent sheet 2c to prepare an absorbent body 2 having the configuration shown in FIG. Other than the above, a sanitary napkin (invention product 3) having the structure shown in FIG. 2 was prepared in the same manner as in Example 1.

Example 4 The absorbent sheet (D) was used in place of the absorbent sheet (C) used in Example 3, and the superabsorbent polymer (C) was used in place of the superabsorbent polymer (A). Example 3 except that
The absorbent body 2 shown in FIG. 2 was prepared in the same manner as described above, and the sanitary napkin (invention product 4) having the structure shown in FIG. 2 was prepared.

Example 5 As the composite absorbent paper 2f, a composite paper absorbent sheet (H) cut into a length of 175 mm and a width of 150 mm was used, and hot melt was spirally applied thereto in an amount of about 10 g / After spraying m ^2, 0.5 g of superabsorbent polymer (A) as superabsorbent polymer 2b, length 175 mm, width 7
With an area of 3 mm, spread it on the absorbent sheet (H) almost uniformly (basis weight: about 39 g / m ² ), and then wind up both ends of the absorbent sheet (H) and wrap it to a width of 73 mm. Then, the absorbent body 2 having the structure shown in FIG. 5 was obtained. Other than this, the sanitary napkin (invention product 5) having the structure shown in FIG. 5 was prepared in the same manner as in Example 1.

Comparative Example 1 Cellulose fiber (D) was used instead of cellulose fiber (A).
In the same manner as in Example 1 except that the superabsorbent polymer (D) was used instead of the superabsorbent polymer (A), and the absorbent sheet (E) was used instead of the absorbent sheet (A). A sanitary napkin (Comparative Product 1) having the structure shown in FIG. 1 was prepared.

Comparative Example 2 Cellulose fiber (F) instead of cellulose fiber (A)
In the same manner as in Example 1 except that the superabsorbent polymer (E) was used instead of the superabsorbent polymer (A), and the absorbent sheet (F) was used instead of the absorbent sheet (A). A sanitary napkin (Comparative Product 2) having the structure shown in FIG. 1 was prepared.

Comparative Example 3 Cellulose fiber (D) instead of cellulose fiber (A)
In the same manner as in Example 1 except that the superabsorbent polymer (C) was used instead of the superabsorbent polymer (A), and the absorbent sheet (E) was used instead of the absorbent sheet (A). A sanitary napkin (Comparative Product 3) having the structure shown in FIG. 1 was prepared.

Comparative Example 4 Absorbent sheet (G) was used instead of absorbent sheet (C), superabsorbent polymer (C) was used instead of superabsorbent polymer (A), and absorbent sheet (A) was used. A sanitary napkin (Comparative Product 4) having the structure shown in FIG. 2 was prepared in the same manner as in Example 3 except that the absorbent sheet (E) was used instead of.

Performance evaluations were carried out on the sanitary napkins obtained in the examples and comparative examples. That is, Example 1
5 to 5 of the present invention and Comparative Examples 1 to 4 of Comparative Products 1 to 4 to observe the absorption performance, the absorption time, the amount of dynamic liquid return, and the leakage test were performed on each sanitary napkin by the following methods. I went about. The respective results are shown in [Table 4] below.

(1) Absorption time (5 g), Re-absorption time (1
0 g), measurement of the amount of dynamic liquid return As shown in FIG. 12, the sanitary napkins 80 obtained in Examples and Comparative Examples were placed horizontally, and an acrylic plate 82 with an injection port 81 having a diameter of 10 mm was placed thereon. A weight 83 is placed on the test sanitary napkin 80 so that a load of 5 g / cm ² is applied. Next, 5 g of defibrinated horse blood (manufactured by Japan Biotest Institute Co., Ltd.) is injected from the injection port, and the absorption time (second) until the liquid is completely absorbed is determined. After the liquid is completely absorbed, leave it as it is for 20 minutes, and defibrillate horse blood 5
g and inject the same to determine the resorption time (10 g).
Let stand for a minute. Thereafter, 1 piece of an absorbent body made of softwood pulp having a basis weight of 30 g / m ² cut into a width of 75 mm × 195 mm was used.
0 sheets, placed on the upper surface (skin contact surface side) of the sanitary napkin 80 for a test, and shown in FIG.
After putting on the shorts to which the sanitary napkin 80 is attached as shown in FIG. 14, 100 steps / min (50 m / min)
At a walking speed of 1 minute. After completion of walking, the sanitary napkin 80 and 10 absorbent bodies were taken out, and the weight of defibrinated horse blood absorbed by the absorbent body was determined as the liquid return amount (g).
The measurement was carried out at 5 points respectively, and the respective average values were obtained, which were taken as the absorption time, re-absorption time and dynamic liquid return amount.

(2) Leakage Test (Number of Leakage Occurrences) The sanitary napkin 8 for the test obtained in Examples and Comparative Examples.
0 is attached to the movable female waist model 90 as shown in FIG. 14, and after putting on the shorts, 100 steps / min (50
They were allowed to walk for 10 minutes at a walking speed of (m / min). Then, while walking, 5 g of defibrinated horse blood was injected into the sanitary napkin 80 by a tube and then walked for 20 minutes at the same speed, and then 5 g of defibrinated horse blood was further injected for 20 minutes at the same speed. At the time of walking, the number of leaks was counted from among 10 samples at each time.

[0135]

[Table 4]

Considering the absorption time and the dynamic liquid return amount in the results shown in [Table 4], both the absorption time and the reabsorption time of the product of the present invention are 10 to 28 seconds, and the dynamic liquid return amount is 0. 1 to 0.4, and good results were obtained for both of them, but the comparative product was inferior in resorption time of 47 to 92 seconds, and the liquid return amount was inferior to 0.6 to 1.2 g. However, both the absorption time and the liquid return amount cannot be satisfied. In addition, the number of leaks is 10 in the product of the present invention.
It can be seen that the number of leaks at the time of g absorption is 0 to 3 times, which is excellent with a small number of leaks, while the comparative product has a large number of leaks, 5 to 7 times, which is inferior.

That is, Example 1 which is the absorbent article of the present invention
The sanitary napkins Nos. 5 to 5 have an absorbent body composed of a combination of a superabsorbent polymer having both high liquid retention capacity and high permeation rate, and crosslinked cellulose fiber, and therefore have excellent absorption characteristics. ing. On the contrary,
As shown in Comparative Examples 3 and 4, an absorbent article containing only crosslinked cellulose fibers or only a high-retentive, high-permeability superabsorbent polymer cannot exhibit the effect, and the absorbent properties are insufficient. I understand.

Further, the absorbent article of the present invention can exhibit its effect most effectively as a high excretion type absorbent article for night use, long time use, etc., and uses a large amount of superabsorbent polymer. Even if a large amount of body fluid is excreted without gel blocking, the absorbent article has little liquid return and little leakage.

In order to verify the effects of the absorbent article of the present invention corresponding to the high excretion type absorbent article for a large amount of human, night, long time, etc., Examples 6 to 8 will be described below. And Comparative Examples 5 and 6 are shown.

Example 6 0.5 g / sheet (basis weight: about 39 g / m ² ) to 1.5 g / sheet (basis weight: about 117 g /
m ² ) except that the amount was increased to
A sanitary napkin (invention product 6) having the configuration shown in (1) was prepared.

Example 7 The superabsorbent polymer (A) was replaced with the superabsorbent polymer (B), and the spray amount was 0.5 g / sheet (basis weight of about 39 g / m ² ) to 1.5 g / sheet (basis weight). A sanitary napkin (invention product 7) having the structure shown in FIG. 2 was prepared in the same manner as in Example 3 except that the amount was increased to about 117 g / m ² ).

Example 8 As the absorbent sheet 2g, a composite paper absorbent sheet (I) cut into a length of 175 mm and a width of 150 mm was used, and a hot melt having a spiral shape of about 1 was used thereon.
After spraying at 0 g / m ² , super absorbent polymer 2
As b, 1.5 g of superabsorbent polymer (A) having a length of 17
Almost evenly spread over 5 mm and width 73 mm (basis weight about 117 g
/ M ² ), the absorbent sheet (I) was wrapped with a width of 73 mm and integrated to obtain an absorbent body 2 having a structure shown in FIG. Other than this, the sanitary napkin (Product 8 of the present invention) having the configuration shown in FIG. 6 was prepared in the same manner as in Example 1.

Comparative Example 5 As the cellulose fibers 2a, cellulose fibers (D) having a basis weight of 150 g / m ² and a thickness of 1 mm (a density of 0.15 g / c) were used.
m ³ ), length 175 mm, width 73 mm, and used. As the superabsorbent polymer 2b, 1.5 g of superabsorbent polymer (D) (grammage of 117 g / m ² ) was used. ), The absorbent sheet (E) was wrapped with a sheet cut into a length of 175 mm and a width of 160 mm to prepare an absorbent body 2 having the configuration shown in FIG. Other than this, the sanitary napkin (Comparative Product 5) having the configuration shown in FIG. 1 was prepared in the same manner as in Example 1.

Comparative Example 6 Absorbent sheet 2d wrapping polymer, having a length of 175 m
m using a 190mm wide absorbent sheet (G)
In addition, about 10g / m of hot melt in spiral shape ²so
After spraying, the super absorbent polymer 2b is used as the super absorbent polymer.
Mar (E) 1.5g in the area of length 175mm, width 73mm
Spread almost evenly (basis weight about 117 g / m²) And absorb the above
Roll up both ends of the elastic sheet (G) and wrap it in a width of 73 mm
Embodied. This is the absorbent sheet as the transparent absorbent paper 2c.
(F) cut into a length of 175 mm and a width of 130 mm
It was used for coating to prepare an absorber 2 shown in FIG. Other than this
Is a sanitary napkin as in Example 1 (Comparative Product 6).
It was created.

With respect to the sanitary napkins obtained in Examples 6 to 8 and Comparative Examples 5 to 6, the absorption performance when absorbing a large amount of body fluid, assuming long-time wearing at high excretion, will be described below. The absorption time at the time of high absorption, the amount of dynamic liquid return, and the leak test were conducted on each sanitary napkin by the methods shown. The respective results are shown in [Table 5] below.

(1) Absorption time (5 g), Re-absorption time (1
0 g), re-resorption time (15 g), and measurement of dynamic liquid return amount As shown in FIG. 12, the sanitary napkins 80 obtained in Examples and Comparative Examples were placed horizontally, and an injection port 81 having a diameter of 10 mm was attached. An acrylic plate 82 is placed, and a weight 83 is applied so that a load of 5 g / cm ² is applied to the sanitary napkin 80 for testing.
Put. Next, 5 g of defibrinated horse blood (manufactured by Japan Biotest Institute Co., Ltd.) is injected from the injection port, and the absorption time (second) until the liquid is completely absorbed is determined. After the liquid was completely absorbed, it was left as it was for 20 minutes, 5 g of defibrinated horse blood was injected again, and the re-absorption time (10 g) was calculated.
It was left for 0 minutes. Further, 5 g of defibrinated horse blood was injected, the re-absorption time (15 g) was determined, and it was left as it was for 20 minutes after it was completely absorbed in the same manner.

After that, an absorbent body made of softwood pulp having a basis weight of 30 g / m ² cut into 75 mm width × 195 mm was used as 10
Sheet, upper surface of sanitary napkin 80 for test (skin contact surface side)
After putting on the shorts with the sanitary napkin 80 attached to the movable female waist model 90 shown in FIG. 13, the walking speed of 100 steps / minute (50 m / minute) for 1 minute. I walked. After completion of walking, the sanitary napkin 80 and 10 absorbent bodies were taken out, and the weight of defibrinated horse blood absorbed by the absorbent body was determined as the liquid return amount (g). 5 each
The points were measured, and the average value of each was determined to be the absorption time, the re-absorption time, the re-resorption time, and the dynamic liquid return amount.

(2) Leakage Test (Number of Occurrences of Leakage) The sanitary napkins 8 for the tests obtained in Examples and Comparative Examples
0 is attached to the movable female waist model 90 as shown in FIG. 14, and after putting on the shorts, 100 steps / min (50
They were allowed to walk for 10 minutes at a walking speed of (m / min). After that, while injecting 5 g of defibrinated horse blood into the sanitary napkin 80 by a tube while walking, when walking for 20 minutes at the same speed, and then after injecting 5 g of defibrinated horse blood,
At the time of walking for 20 minutes, 5 g of defibrinated horse blood was injected,
At the time of walking for 20 minutes, the number of leaks was counted among 10 samples at each time.

[0149]

[Table 5]

As is clear from the results shown in [Table 5],
The absorbent article of the present invention containing a crosslinked cellulose fiber and a large amount of a highly absorbent and highly permeable superabsorbent polymer has a re-resorption time of 25 to 43 seconds up to 15 g, which is assumed to be worn for a long time and excreted a large amount. The amount of liquid returned was 0.1 to 0.3 g, and it was found that it was particularly excellent even when compared with a comparative product containing a large amount of superabsorbent polymer. Also, regarding the number of leaks, even if absorbed up to 15 g, the product of the present invention has 0 to 3
The number of leaks and the number of leaks are small and excellent, whereas the comparative sample leaks with 10 times for all the tested samples, which is inferior.

Further, as typified by the products 5 and 8 of the present invention, a composite absorbent paper containing crosslinked cellulose fibers satisfying both permeability and diffusivity of body fluid is combined with a polymer having high retention and high permeability. As a result, compared with the conventional absorbent article that is configured by combining many absorbent materials, the flow of body fluid to the superabsorbent polymer is extremely idealized without separation between the absorbent materials, and the simplest configuration is possible. It can be seen that an extremely thin absorbent article having high absorbency is obtained.

The present invention is not limited to the above embodiment,
Various modifications can be made without departing from the scope of the present invention.

[0153]

EFFECT OF THE INVENTION The absorbent article of the present invention suppresses the liquid return amount and the liquid leakage even when worn for a long time or under intense exercise conditions, which cannot be achieved by the conventional absorbent article, and is extremely high. It is absorbent and comfortable. In particular,
Even if it absorbs body fluid once, the fibers that make up the absorber do not cause kinking / sagging, the resorption rate is excellent and the superabsorbent polymer does not cause absorption inhibition, and its absorption performance is maximized, Even when worn for a long period of time or under the condition of excreting a large amount, most of the body fluid can be immobilized by the polymer, and there is little liquid return to the surface of the absorbent article and little leakage.

That is, the absorbent article of the present invention is a highly absorbent polymer having cross-linked cellulose fibers which are free from swelling / sagging even when absorbing body fluid and have little swelling when wet, and a high body fluid holding capacity and a high permeation rate. Since it has an absorbent body that has both of the above, even when repeatedly excreted, the absorption space for temporarily storing the body fluid of the crosslinked cellulose fiber is kept stable without changing, and thus the reabsorption rate is excellent, and The superabsorbent polymer that holds body fluid can also smoothly carry the body fluid to other superabsorbent polymers without gel blocking, and can reliably solidify a large amount of body fluid with the polymer, so there is little leakage even when excreting a large amount. It is an absorptive article not found in.

Furthermore, an absorbent body was constructed by combining a specific superabsorbent polymer having high absorption and high permeability with absorbent paper containing crosslinked cellulose fibers, particularly a composite absorbent paper having both permeability and diffusibility. In this case, it is possible to further improve the above-mentioned effects, and to provide an absorbent article which is highly absorbent and has an extremely simple structure and which is much thinner than conventional absorbent articles. (Effects of claims 14 and 15)

[Brief description of drawings]

FIG. 1 is a schematic view showing a cross section in a width direction of a sanitary napkin as a first embodiment of an absorbent article of the present invention.

FIG. 2 is a schematic view (corresponding to FIG. 1) showing a cross section in the width direction of a sanitary napkin as a second embodiment of the absorbent article of the present invention.

FIG. 3 is a schematic view (corresponding to FIG. 1) showing a cross section in the width direction of a sanitary napkin as a third embodiment of the absorbent article of the present invention.

FIG. 4 is a schematic diagram (corresponding to FIG. 1) showing a cross section in the width direction of a sanitary napkin as a fourth embodiment of the absorbent article of the present invention.

FIG. 5 is an enlarged view of the composite absorbent paper shown in FIG.

FIG. 6 is a schematic view (corresponding to FIG. 1) showing a cross section in the width direction of a sanitary napkin as a fifth embodiment of the absorbent article of the present invention.

FIG. 7 is an enlarged view of the composite absorbent paper shown in FIG.

FIG. 8 is a schematic view showing an apparatus for measuring the permeation rate of physiological saline.

FIG. 9 is a schematic view showing a device for measuring the creme absorption height.

FIG. 10 is a schematic diagram showing an apparatus for measuring the permeation time of an absorbent sheet.

FIG. 11 is a partially enlarged cross-sectional view of a surface material used in Examples and Comparative Examples.

FIG. 12 is a schematic diagram showing an outline of measurement of absorption time.

FIG. 13 is a schematic view showing a movable female waist model.

14 is a schematic view showing a state in which a sanitary napkin is attached to the crotch part of the movable female waist model shown in FIG.

[Explanation of symbols]

 10 Sanitary Napkins 1 Surface Material 2 Absorber 2a Cross-linked Cellulose Fiber 2b High Absorbent Polymer 2c Permeation Absorption Paper 2d Diffusion Absorption Paper 2e Polymer Dispersion Paper 2f Composite Absorption Paper 2g Composite Absorption Paper 3 Leakage proof 4 Adhesive 5 Release Paper 6 Joint

[Procedure amendment]

[Submission date] November 22, 1994

[Procedure Amendment 1]

[Document name to be amended] Statement

[Correction target item name] 0109

[Correction method] Change

[Correction content]

Absorbent Sheet (C) Cellulose Fiber (A) 70 Layers as Crosslinked Cellulose Fiber
Part and, as hydrophilic fine fibers, fiber roughness 0.18 mg / m
Kraft pulp NB with a fiber roundness of 0.32
KP (Product name: "SKEENA PRIME", Skeena Cellulose
Co.)ThirtyParts by weight and dispersed in water,
40 g / m2 basis weight obtained by drying after printing on paper ²Absorb the absorbent paper
The sheet was designated as a sheet (C).

[Procedure Amendment 2]

[Document name to be amended] Statement

[Name of item to be corrected] 0127

[Correction method] Change

[Correction content]

Example 5 As the composite absorbent paper 2f, a composite paper absorbent sheet (H) cut into a length of 175 mm and a width of 150 mm was used, and hot melt was spirally applied thereto in an amount of about 10 g / After spraying m ^2, 0.5 g of superabsorbent polymer (A) as superabsorbent polymer 2b, length 175 mm, width 7
With an area of 3 mm, spread it on the absorbent sheet (H) almost uniformly (basis weight: about 39 g / m ² ), and then wind up both ends of the absorbent sheet (H) and wrap it to a width of 73 mm. Then, the absorbent body 2 having the structure shown in FIG. 4 was obtained. Other than this, the sanitary napkin (Product 5 of the present invention) having the structure shown in FIG. 4 was prepared in the same manner as in Example 1.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁶ Identification number Internal reference number FI Technical indication location B01J 20/26 B (72) Minoru Nakanishi Minoru Nakanishi Yakushiji, Minamikochi-cho, Tochigi Prefecture 3298-75 Green Town 208 Block 1-2

Claims (15)

[Claims] 1. A liquid-permeable surface material, a liquid-retaining absorber
And absorbent articles with liquid-impermeable leak preventer
The absorbent body contains at least a superabsorbent polymer and cellulose.
A) The superabsorbent polymer has a balanced absorption expansion of physiological saline.
The centrifugal retention capacity after wetting is 30 g / g or more,
Cross-sectional area of 0.785 cm for 0.05 g of the absorbable polymer ²(Circle diameter
(10 mmφ) cylinder, equilibrated swelling with physiological saline
And then permeation of physiological saline has a permeation rate of 1
0 ml / min or more, b) The above-mentioned cellulose fiber is in the cellulose molecule or
Cross-linked cellulose fiber made by cross-linking between molecules with a cross-linking agent
There is an absorbent article characterized by the following. 2. The absorbent article according to claim 1, wherein the superabsorbent polymer has a non-spherical particle shape and an irregularity of 1.2 or more. 3. The absorbent article according to claim 1, wherein the crosslinked cellulose fibers are crosslinked pulp fibers obtained by crosslinking pulp fibers with a crosslinking agent. 4. The superabsorbent polymer is used in an amount of 20 to 80% by weight based on the total weight of the absorbent body, and a spray basis weight of 20 to 500 g / m ^2. The absorbent article according to any one of 3 to 3. 5. The absorbent article according to any one of claims 1 to 4, wherein the absorbent body comprises a wet absorbent paper having the crosslinked cellulose fiber. 6. The crosslinked cellulose fiber has a compressive residual strain when wet of less than 40%.
5. The absorbent article according to any one of 5 to 5. 7. The absorbent according to any one of claims 1 to 6, wherein the crosslinked cellulose fiber is a crosslinked pulp fiber obtained by crosslinking pulp having a fiber roughness of 0.3 mg / m or more. Goods. 8. The crosslinked cellulose fiber is a crosslinked cellulose fiber obtained by crosslinking cellulose fibers having a fiber roughness of 0.3 mg / m or more and a roundness of a fiber cross section of 0.5 or more. The absorbent article according to any one of claims 1 to 7. 9. The absorbent article according to claim 1, wherein the crosslinked cellulose fibers are mercerized crosslinked pulps obtained by mercerizing pulp fibers and then crosslinking the pulp fibers. 10. The superabsorbent polymer is used in an amount of 30 to 60% by weight based on the total weight of the absorbent body, and has a spray basis weight of 100 to 300 g / m ^2. The absorbent article according to any one of 1 to 9. 11. The sanitary napkin according to claim 1, wherein the superabsorbent polymer is used in an amount of 1 to 3 g. 12. The absorbent body, wherein the uppermost layer is a mixture of at least a) the crosslinked cellulose fibers; 50 to 98% by weight and b) hot melt adhesive fibers; 2 to 30% by weight, and a basis weight of 20. It is formed using a permeation | transmission absorption paper paper-made by 60 g / m < ² >, and the permeation | transmission time of the glycerin 85 weight% aqueous solution 10g of said permeation | transmission absorption paper is 50 seconds or less.
The absorbent article according to any one of items 1 to 11. 13. The absorbent body comprises at least a) the crosslinked cellulose fibers; 20 to 80% by weight, b) hydrophilic fine fibers; 80 to 20% by weight, and c) heat-meltable adhesive fibers; 0 to 30% by weight. %, And a diffusion absorbing paper made by making a paper having a basis weight of 20 to 60 g / m ² , and the creme absorption height of the diffusion absorbing paper after 1 minute with respect to physiological saline is 50 mm or more and after 10 minutes. 13. The absorbent article according to claim 1, which has an absorption height of 100 mm or more and further has a permeation time of an aqueous 85% by weight glycerin solution of 100 seconds or less. 14. The absorbent body comprises one composite absorbent paper in which at least two absorbent layers of a first layer and a second layer are integrally integrated, and a) the first layer is at least: 50 to 98% by weight of the crosslinked cellulose fiber and 2 to 30% by weight of the heat-meltable adhesive fiber, which is a layer formed of a permeation-absorbent paper having a basis weight of 20 to 60 g / m ² , and b) the second layer Is a mixture of at least 20 to 80% by weight of the above crosslinked cellulose fibers, 80 to 20% by weight of hydrophilic fine fibers, and 0 to 30% by weight of heat-meltable adhesive fibers, and papermaking with a basis weight of 20 to 60 g / m ² . It is a layer which consists of diffusion absorption paper, The absorbent article according to any one of claims 1 to 13 characterized by things. 15. The absorbent body comprises a single composite absorbent paper in which at least three absorbent layers of a first layer, a second layer and a third layer are integrally combined, and a) the first layer is At least 50 to 98% by weight of the crosslinked cellulose fibers and 2 to 30% by weight of the heat-meltable adhesive fibers, and a layer formed of a permeation-absorbent paper having a basis weight of 20 to 60 g / m ² , and b) the above. The second layer is a mixture of at least 20 to 80% by weight of the above crosslinked cellulose fibers, 80 to 20% by weight of hydrophilic fine fibers and 0 to 30% by weight of heat-meltable adhesive fibers, and a basis weight of 20 to 60 g / m ^2. C) The third layer is a mixture of at least 70 to 100% by weight of the above crosslinked cellulose fibers and 0 to 30% by weight of heat-meltable adhesive fibers, and has a basis weight of 10 to 10. Do not use polymer-dispersed paper made by making paper at 50 g / m ^2. The absorbent article according to any one of claims 1 to 14, wherein the absorbent article is a layer.