JPH07255382A - Preparation of candy - Google Patents

Preparation of candy

Info

Publication number
JPH07255382A
JPH07255382A JP6057281A JP5728194A JPH07255382A JP H07255382 A JPH07255382 A JP H07255382A JP 6057281 A JP6057281 A JP 6057281A JP 5728194 A JP5728194 A JP 5728194A JP H07255382 A JPH07255382 A JP H07255382A
Authority
JP
Japan
Prior art keywords
water
parts
sugar
candy
hemicellulose
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6057281A
Other languages
Japanese (ja)
Other versions
JP2959387B2 (en
Inventor
Taro Takahashi
太郎 高橋
Yuichi Maeda
裕一 前田
Hitoshi Furuta
均 古田
Hiroko Kurita
博子 栗田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuji Oil Co Ltd
Original Assignee
Fuji Oil Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Oil Co Ltd filed Critical Fuji Oil Co Ltd
Priority to JP6057281A priority Critical patent/JP2959387B2/en
Publication of JPH07255382A publication Critical patent/JPH07255382A/en
Application granted granted Critical
Publication of JP2959387B2 publication Critical patent/JP2959387B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Confectionery (AREA)

Abstract

PURPOSE:To prepare a jelly candy having springy palatability, a soft candy and a hard candy resistant to bleeding of oil, etc., such as caramel by using sugar and starch syrup as main raw materials and using a water-soluble hemicellulose as a quality improver. CONSTITUTION:A caramel is prepared by using sugar and starch syrup as main raw materials, a water-soluble hemicellulose (preferably originated from soybean cotyledon) as a quality improver and preferably further a protein component and an oil and fat component.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、キャンデーの製造法に
関する。
FIELD OF THE INVENTION This invention relates to a method of making candy.

【0002】[0002]

【従来の技術】キャンデーは、砂糖、水飴を主原料とし
てつくられる菓子の総称であり、砂糖と水飴を煮詰めた
糖液に練乳、油脂、香料、色素、酸味料、調味料、澱
粉、凝固剤等を加え、混合、成形、冷却等の工程を経て
製造される。これらのキャンデーは、糖液を煮詰める温
度が高く水分含量が比較的低いドロップ、タフィー等の
ハードキャンデーと糖液を煮詰める温度が低く水分含量
が比較的高いゼリー菓子、キャラメル、ヌガー等のソフ
トキャンデーとに大別される。
2. Description of the Related Art Candy is a general term for confectionery made from sugar and starch syrup as the main ingredients. Etc. are added, and the mixture is manufactured through processes such as mixing, molding, and cooling. These candies include drops with a high boiling temperature of sugar solution and relatively low water content, hard candy such as toffee and soft candy with a low boiling temperature of sugar solution and relatively high water content such as jelly confectionery, caramel, and nougat. It is roughly divided into.

【0003】[0003]

【発明が解決しようとする課題】上記の如きキャンデー
は主原料として砂糖を使用しているため組織が硬くひび
割れを起こすことががあり、またシットリとした滑らか
な組織、食感あるいは弾力性に富んだ食感を希望する近
年の消費者のニーズ動向を必ずしも満足するものではな
かった。
Since the candy as described above uses sugar as the main ingredient, its structure may be hard and may cause cracks, and it may have a tight and smooth structure, rich texture or elasticity. However, it has not always satisfied the needs of consumers in recent years who desire a texture.

【0004】[0004]

【課題を解決するための手段】本発明者らは、如上の点
に鑑み鋭意研究した結果、キャンデーの原料中に水溶性
ヘミセルロースを使用することにより、キャンデーの物
性、組織ならびに食感などの品質を改良し得るという知
見を得た。本発明は、かかる知見に基づいて完成された
ものである。
Means for Solving the Problems As a result of intensive studies in view of the above points, the present inventors have found that the use of water-soluble hemicellulose in the raw material of candy makes it possible to improve the physical properties, texture and texture of the candy. We obtained the knowledge that The present invention has been completed based on such findings.

【0005】即ち本発明は、砂糖、水飴を主原料として
キャンデーを製造するに際し、品質改良剤として水溶性
ヘミセルロースを使用することを特徴とするキャンデー
の製造法、である。
That is, the present invention is a method for producing a candy characterized by using water-soluble hemicellulose as a quality improving agent when producing a candy using sugar or starch syrup as a main raw material.

【0006】本発明におけるキャンデーとはハードキャ
ンデーおよびソフトキャンデーのいずれをも包含するも
のであって、それらのキャンデーは水溶性ヘミセルロー
スを使用すること以外は従来公知の方法に準じて製造す
ることができる。
The candy in the present invention includes both hard candy and soft candy, and those candies can be produced according to a conventionally known method except that water-soluble hemicellulose is used. .

【0007】例えば、ハードキャンデーの一種であるド
ロップは、通常、砂糖を主原料としこれに10〜20%の水
飴を加えて140 〜150 ℃、水分1〜2%になるまで煮詰
め、次いで酒石酸、クエン酸、乳酸などの有機酸あるい
は果汁、色素、香料などを添加し混合して冷却した後、
タブレットマシンにて所望の形状に打ち抜くなどして製
造される。
For example, a drop which is a kind of hard candy is usually made from sugar as a main raw material and 10 to 20% of starch syrup is added to it and boiled down to 140 to 150 ° C. and a water content of 1 to 2%, and then tartaric acid, After adding organic acids such as citric acid and lactic acid or fruit juice, pigments, flavors, etc. and mixing and cooling,
It is manufactured by punching into a desired shape on a tablet machine.

【0008】以上の如き方法に準じて製造される各種ハ
ードキャンデーの製造工程中に、本発明における水溶性
ヘミセルロースを添加使用することによって、キャンデ
ー組織をより滑らかにしひび割れを起こし難いハードキ
ャンデーを得ることができる。
By adding and using the water-soluble hemicellulose of the present invention in the manufacturing process of various hard candy produced according to the above method, a hard candy having a smoother candy structure and less likely to crack is obtained. You can

【0009】また、ソフトキャンデーの一種であるゼリ
ー(jelly)菓子は、糖液を適当な凝固剤で固めたもので
あって、凝固剤としてペクチンを使用したペクチンゼリ
ー菓子、寒天を使用した寒天ゼリー菓子、ゼラチンを使
用したゼラチンゼリー菓子がある。この他に凝固剤とし
て澱粉を使用したものもある。これらのゼリー菓子は、
互いに他の凝固剤を補足凝固剤として適宜混合使用する
ことがある。
A jelly confection, which is a kind of soft candy, is obtained by solidifying a sugar solution with an appropriate coagulant, and is a pectin jelly confection using pectin as a coagulant or an agar jelly using agar. There are sweets and gelatin jelly sweets that use gelatin. In addition to this, there is also one using starch as a coagulant. These jelly candies are
Other coagulants may be appropriately mixed and used as supplementary coagulants.

【0010】ペクチンには高メトキシルペクチンと低メ
トキシルペクチンとがあり、後者の低メトキシルペクチ
ンが凝固するにはカルシウムがあればよいが、前者の高
メトキシルペクチンが凝固するには砂糖と酸が必要であ
る。ペクチンの品質を評価するには、最適の条件下で標
準の固さに調製したときのペクチンに対する可溶性固形
分(通常は砂糖)の比で示され、例えば1gのペクチン
を標準の固さに調製するのに砂糖が150 g必要であった
とすれば、そのペクチンは150 グレードであるという。
通常、150 グレードのペクチンがゼリー菓子の製造に使
用されるようであるが、糖濃度が低いと貯蔵性が悪く、
高いと結晶を生じるようになる。
Pectin includes high methoxyl pectin and low methoxyl pectin, and calcium is sufficient for coagulation of the latter low methoxyl pectin, but sugar and acid are required for coagulation of the former high methoxyl pectin. is there. To evaluate the quality of pectin, the ratio of soluble solids (usually sugar) to pectin when prepared to a standard hardness under optimal conditions, for example 1 g of pectin prepared to a standard hardness If you needed 150 grams of sugar to do it, the pectin is said to be 150 grades.
Normally, 150-grade pectin seems to be used to make jelly confectionery, but low sugar levels lead to poor storage and
If it is high, crystals will be formed.

【0011】ペクチンゼリー菓子は、普通、ペクチン
(1〜1.5 %)を溶解させ易いように予め砂糖の一部と
混合しておき、ペクチンの約40倍量の沸騰水に徐々に加
え沸騰させた後、水飴および少量の酸を加えさらに沸騰
させる。次いで残りの砂糖を加え加熱を続けて約110 ℃
になったら加熱を止め、酸、色素および香料を加え冷却
板に流し固めることによって製造される。
Pectin jelly confectionery is usually prepared by mixing pectin (1 to 1.5%) with a part of sugar in advance so that it can be easily dissolved, and gradually adding about 40 times the boiling water of pectin to bring it to a boil. After that, starch syrup and a small amount of acid are added and further boiled. Then add the remaining sugar and continue heating to about 110 ° C.
When it becomes, the heating is stopped, an acid, a dye and a fragrance are added, and the mixture is poured into a cooling plate and solidified.

【0012】寒天は、紅藻類(テングサ)を煮沸した濾
液を凝固させ、凍結乾燥させてつくられる。通常、寒天
ゼリー菓子は寒天(1〜1.5 %)を数時間水に浸漬した
後、徐々に加熱溶解して寒天溶液を調製し、この寒天溶
液に砂糖と水飴を加えて加熱溶解後冷却した後、少量の
酸と所望の色素、香料を添加し、モールドに注入して十
数時間保持することにより製造される。
Agar is produced by coagulating a filtrate obtained by boiling red algae (agar beetle) and freeze-drying it. Usually, agar jelly confections are prepared by immersing agar (1-1.5%) in water for several hours, then slowly heating and dissolving it to prepare an agar solution, adding sugar and starch syrup to this agar solution, heating and dissolving, and then cooling. It is manufactured by adding a small amount of acid, a desired dye, and a fragrance, injecting it into a mold, and holding it for more than 10 hours.

【0013】ゼラチンは、動物の骨や皮に含まれるコラ
ーゲンからつくられ、そのゲル強度は一般にブルーム
(bloom)で示されブルームが大きい程ゲル強度は強い。
ゼラチンゼリー菓子をつくるには、一般にゼラチン(普
通170 ブルーム以上)5〜12.5%を約倍量の温水に徐々
に加えてゼラチン溶液を調製しておく。一方、砂糖およ
び水飴(砂糖/水飴=67/33〜50/50)を両者合計量の
約4分の1の水に加えて114 〜116 ℃に加熱した後70℃
まで冷却してから、先に調製したゼラチン溶液を加え、
適宜色素、香料などを添加し混合して製造される。
Gelatin is made from collagen contained in the bones and skins of animals, and its gel strength is generally represented by bloom. The larger the bloom, the stronger the gel strength.
To make gelatin jelly confectionery, generally gelatin (usually 170 bloom or more) 5-12.5% is gradually added to about twice the amount of warm water to prepare a gelatin solution. On the other hand, sugar and starch syrup (sugar / syrup = 67 / 33-50 / 50) were added to about 1/4 of the total amount of both and heated to 114-116 ° C, then 70 ° C.
After cooling to, add the gelatin solution prepared above,
It is manufactured by appropriately adding a dye, a fragrance and the like and mixing them.

【0014】以上の如くして製造される各種ゼリー菓子
の製造工程中に、本発明における水溶性ヘミセルロース
を添加使用することによって、一段と弾力性に富んだ食
感を有するゼリー菓子を得ることができ、従来のゼリー
菓子の品質を改良することができる。
By adding and using the water-soluble hemicellulose of the present invention in the production process of various jelly confectionery produced as described above, it is possible to obtain a jelly confectionery having a much more elastic texture. , Can improve the quality of conventional jelly confectionery.

【0015】また、キャラメルは主原料が砂糖、水飴、
蛋白成分(練乳、牛乳などの乳蛋白含有物、大豆蛋白)
および油脂(バター、硬化油など)であり、蛋白と糖と
の、いわゆるメイラード反応により着色し、特有の風味
(香味)とチューイング性を有している。砂糖と水飴と
の比率は1:1(固形分比)が標準で、砂糖が多いと結
晶し易くザラついた組織となりチューイング性を失う。
逆に水飴が多いと硬くなる。蛋白成分は蛋白分として4
〜5%が標準で、少ないと保形性が悪化する。油脂分は
キャラメルの粘着性を抑え組織を滑らかにする効果があ
る。油脂分は多いほど美味であるが多すぎると保存中に
油脂分が浸み出してくるので余り多く配合することはで
きず、通常は10%前後が標準であって、油脂分を均一に
分散させるために乳化剤を使用する場合がある。キャラ
メルには、以上の主原料の他に小麦粉、澱粉その他種々
の原料と香料などを配合してつくられる場合があり、上
記の各原料の標準が適宜変更される場合がある。
The main ingredients of caramel are sugar, starch syrup,
Protein component (milk protein containing milk protein, milk, soybean protein)
And fats and oils (butter, hardened oil, etc.), which are colored by the so-called Maillard reaction between protein and sugar, and have a unique flavor (flavor) and chewing property. The standard ratio of sugar to starch syrup is 1: 1 (solid content ratio), and if sugar is present in a large amount, it tends to crystallize, resulting in a rough texture and losing chewing properties.
On the contrary, the more starch syrup gets harder. The protein component is 4 as protein
-5% is the standard, and if it is too small, the shape retention property deteriorates. The oil and fat content has the effect of suppressing the stickiness of caramel and making the structure smooth. The more oil and fat, the more delicious it is, but if it is too much, the oil and fat will ooze out during storage, so it cannot be added in a too large amount.Normally, around 10% is the standard, and the oil and fat is evenly dispersed. An emulsifier may be used to do this. Caramel may be made by mixing various raw materials such as wheat flour, starch and the like and flavors in addition to the above main raw materials, and the standard of each raw material may be appropriately changed.

【0016】一般的に、キャラメルは水飴と砂糖および
蛋白成分を混合して攪拌しながら加熱し、次いで油脂分
を加え十分混合した後、約125 ℃になるまで煮詰め、香
料などを添加混合してから冷却盤に流し適度に冷却した
後、適当な大きさに分割切断し成形、包装されるという
工程を経て製造される。
In general, caramel is mixed with starch syrup, sugar and protein components and heated with stirring. Then, fat and oil components are added and mixed well, then boiled down to about 125 ° C., spices and the like are added and mixed. It is manufactured by passing it through a cooling plate into a cooling plate, cooling it appropriately, dividing and cutting it into an appropriate size, molding and packaging.

【0017】一般的には以上の如くして製造されるキャ
ラメルの製造工程中に、本発明における水溶性ヘミセル
ロースを添加使用することによって、キャラメルの保形
性が良好となり、特に保存中の油脂分の浸み出しを抑制
し得ることができる等、従来のキャラメルの品質を改良
することができる。
Generally, by adding and using the water-soluble hemicellulose of the present invention during the production process of the caramel produced as described above, the shape retention of the caramel is improved, and especially the oil and fat content during storage is improved. It is possible to improve the quality of conventional caramel, such as the ability to suppress leaching of

【0018】本発明におけるキャンデーとはハードキャ
ンデーおよびソフトキャンデーのいずれをも包含するも
のであるが、特にソフトキャンデー、なかでも糖液を凝
固剤で固めたグミ、ゼリービーンズ等のゼリー菓子、お
よび蛋白成分と油脂分を使用して製造されるキャラメル
に対して優れた効果を有する。
The candy in the present invention includes both hard candy and soft candy. Especially, soft candy, in particular, jelly confection such as gummy and jelly beans in which a sugar solution is hardened with a coagulant, and protein are used. It has an excellent effect on caramel produced using the ingredients and fats and oils.

【0019】本発明において、以上のような効果を有す
る水溶性ヘミセルロースは豆類由来、特に大豆、なかで
も子葉由来のものが好ましい。
In the present invention, the water-soluble hemicellulose having the above-mentioned effects is preferably derived from beans, particularly soybean, especially cotyledon.

【0020】水溶性ヘミセルロースは、その分子量がど
の様な値のものでも使用可能であるが、好ましくは平均
分子量が数千〜数百万、具体的には5千〜100 万である
のが好ましい。なお、この水溶性ヘミセルロースの平均
分子量は標準プルラン(昭和電工(株)販)を標準物質
として0.1 MのNaNO3 溶液中の粘度を測定する極限粘度
法で求めた値である。
The water-soluble hemicellulose can be used with any molecular weight, but it is preferable that the average molecular weight is from several thousand to several million, specifically from 5,000 to 1,000,000. . The average molecular weight of this water-soluble hemicellulose is a value obtained by the limiting viscosity method in which the viscosity of 0.1 M NaNO3 solution is measured using standard pullulan (available from Showa Denko KK) as a standard substance.

【0021】水溶性ヘミセルロースは、ヘミセルロース
を含む原料から水抽出や場合によっては酸、アルカリ条
件下で加熱溶出させるか、酵素により分解溶出させるこ
とができる。水溶性ヘミセルロース製造法の一例を示す
と以下のようである。
The water-soluble hemicellulose can be extracted with water from a raw material containing hemicellulose, and in some cases, can be heated and eluted under an acid or alkaline condition, or can be decomposed and eluted with an enzyme. An example of the water-soluble hemicellulose production method is as follows.

【0022】油糧種子、例えば大豆、パーム、ヤシ、コ
ーン、綿実などの油脂や蛋白質を除いた殻、あるいは穀
類、例えば米、小麦などの澱粉等を除いた粕等の植物を
原料とすることができる。原料が大豆であれば、豆腐や
豆乳、分離大豆蛋白を製造するときに副生するオカラを
利用することができる。
[0022] Oil seeds such as soybean, palm, palm, corn, cottonseed and other oil-and-fat-free shells, or cereals such as rice and wheat starch-free plants such as meal are used as raw materials. be able to. If the raw material is soybeans, tofu, soymilk, and okara, which is a by-product when producing isolated soybean protein, can be used.

【0023】これらの原料を酸性乃至アルカリ性の条件
下、好ましくは各々の蛋白質の等電点付近のpHで、好ま
しくは130 ℃以下80℃以上、より好ましくは130 ℃以下
100℃以上にて加熱分解し、水溶性画分を分画した後、
そのまま乾燥するか、例えば活性炭処理或いは樹脂吸着
処理或いはエタノール沈澱処理して疎水性物質あるいは
低分子物質を除去し乾燥することによって、水溶性ヘミ
セルロースを得ることができる。
These raw materials are preferably acidic or alkaline, preferably at a pH near the isoelectric point of each protein, preferably 130 ° C. or lower, 80 ° C. or higher, and more preferably 130 ° C. or lower.
After heat-decomposing at 100 ° C or higher to fractionate the water-soluble fraction,
The water-soluble hemicellulose can be obtained by drying as it is, or by treating with activated carbon, resin adsorption or ethanol precipitation to remove hydrophobic substances or low molecular weight substances and drying.

【0024】また、粘度が高過ぎると、キャンディー製
造時の作業性が悪くなる場合がある。そこで、水溶性ヘ
ミセルロースの分子量が大きく、粘度が高過ぎる時に
は、脱色・脱臭や乾燥する以前に、更に低分子化する処
理が有効な場合が多い。
If the viscosity is too high, the workability during candy production may deteriorate. Therefore, when the molecular weight of the water-soluble hemicellulose is large and the viscosity is too high, it is often effective to further lower the molecular weight before decolorizing / deodorizing or drying.

【0025】低分子化処理は、加熱分解する時に加熱条
件を強くする事によっても可能であるが、ヘミセルロー
スの分解抽出溶液をアルカリ・酸・熱・酵素等の処理に
よって行う事も出来る。
The treatment for lowering the molecular weight can be carried out by increasing the heating conditions during the heat decomposition, but the decomposition and extraction solution of hemicellulose can also be carried out by the treatment with alkali, acid, heat, enzyme or the like.

【0026】水溶性ヘミセルロース溶液の粘度は、例え
ば10%水溶液の場合 200センチポイズ以下が良く、より
好ましくは 100センチポイズ以下が良い。
The viscosity of the water-soluble hemicellulose solution is preferably 200 centipoise or less, more preferably 100 centipoise or less in the case of a 10% aqueous solution.

【0027】本発明において水溶性ヘミセルロースの使
用量は、キャンデーが副原料配合の変化も伴って数千種
類にも及ぶことにより、一該に規定することはできない
が、下限は数%から上限は数十%まで任意の割合で使用
することにより効果が得られるので、実際の生産に当た
っては予め実験的に確かめた上で実施するのが好まし
い。
In the present invention, the amount of the water-soluble hemicellulose used cannot be specified because the number of kinds of candy is thousands due to changes in the blending of auxiliary materials, but the lower limit is from a few% to the upper limit. Since the effect can be obtained by using it in an arbitrary ratio up to several tens of%, it is preferable to confirm it experimentally in advance before actual production.

【0028】以上の如く、本発明における水溶性ヘミセ
ルロースをキャンデーの品質改良剤として使用した場
合、ゼリー菓子ではより弾力性を持つ食感となり、ソフ
トキャンデーでは組織が滑らかでシットリした食感とな
り、特に油脂分を比較的多量使用したキャラメルでも油
の浸み出しが抑制され、またハードキャンデーでは組織
が滑らかになりひび割れ難くなる等の効果が得られる。
As described above, when the water-soluble hemicellulose of the present invention is used as a candy quality improving agent, the jelly confectionery has a more elastic texture, and the soft candy has a smooth texture and a tight texture. Even with caramel that uses a relatively large amount of oil and fat, the leaching of oil is suppressed, and with hard candy, the texture is smooth and cracks are less likely to occur.

【0029】[0029]

【実施例】以下、実施例により本発明の実施態様を説明
するが、これは例示であって本願発明の精神がこれらの
例示によって制限されるものではない。なお、例中、部
および%は何れも重量基準を意味する。
EXAMPLES The embodiments of the present invention will be described below with reference to examples, but these are examples and the spirit of the present invention is not limited by these examples. In the examples, parts and% mean weight basis.

【0030】○ 水溶性大豆ヘミセルロースの調製 分離大豆蛋白製造工程において得られた生オカラに2倍
量の水を加え、塩酸にてpHを4.5 に調製し、120 ℃で1.
5 時間加水分解した。冷却後遠心分離し(10000 G ×30
分)、上澄と沈澱部に分離した。こうして分離した沈澱
部を更に等重量の水で水洗し、遠心分離し、上澄を先の
上澄と一緒にしてイオン交換樹脂を用いて脱塩し、活性
炭カラム処理した後、乾燥して水溶性大豆ヘミセルロー
ス(イ)を得た。
Preparation of Water-Soluble Soybean Hemicellulose To the raw okara obtained in the isolated soybean protein manufacturing process, double the amount of water was added, and the pH was adjusted to 4.5 with hydrochloric acid, and the pH was adjusted to 120 ° C at 1.
Hydrolyzed for 5 hours. After cooling, centrifuge (10000 G × 30
Minutes) and separated into a supernatant and a precipitate. The precipitate thus separated is washed with an equal weight of water, centrifuged, and the supernatant is combined with the previous supernatant to desalinize with an ion exchange resin, treated with an activated carbon column, and then dried to dissolve in water. Soybean hemicellulose (I) was obtained.

【0031】前記加水分解の方法を 125℃で2.5 時間と
した以外は同様にして水溶性大豆ヘミセルロース(ロ)
を得た。更に、この水溶性大豆ヘミセルロース(ロ)を
0.5 %食塩水に溶解し、エタノール濃度が50%となるよ
うにして再沈澱を3回繰り返し、UF膜を用いて脱塩し
て水溶性ヘミセルロース(ハ)を得た。
Water-soluble soybean hemicellulose (II) was similarly prepared except that the hydrolysis was carried out at 125 ° C. for 2.5 hours.
Got Furthermore, this water-soluble soybean hemicellulose (b)
Water-soluble hemicellulose (c) was obtained by dissolving in 0.5% saline and repeating reprecipitation three times so that the concentration of ethanol was 50% and desalting using a UF membrane.

【0032】得られた水溶性大豆ヘミセルロース
(イ)、(ロ)、(ハ)の成分を常法により、粘度をB
M型粘度計(ローターNo1,60rpm )により、平均分子量
を極限粘度法により測定した結果を以下にまとめる。
The viscosity of the resulting water-soluble soybean hemicellulose (a), (b) and (c) was adjusted to B by a conventional method.
The results of measuring the average molecular weight by an intrinsic viscosity method with an M-type viscometer (rotor No. 1,60 rpm) are summarized below.

【0033】 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 成 分(%) (イ) (ロ) (ハ) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 水 分 5.71 7.75 5.10 粗蛋白 2.64 5.05 0.53 粗灰分 0.13 0.18 0.07 多糖類 90.80 85.92 94.00 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 粘 度 55.0cP 35.5cP 72.0cP −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 平均分子量 230,000 180,000 325,000 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−----------------------------------------------- Component (%) (a) (b) ( C) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Water 5.71 7.75 5.10 Crude protein 2.64 5.05 0.53 Crude ash 0.13 0.18 0.07 Polysaccharide 90.80 85.92 94.00 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Viscosity 55.0cP 35.5cP 72.0cP ----- −−−−−−−−−−−−−−−−−−−−−−−−−−−−− Average molecular weight 230,000 180,000 325,000 −−−−−−−−−−−−−−−−− −−−−−−−−−−−−−−−−−−−

【0034】次に、(イ)、(ロ)及び(ハ)の水溶性
大豆ヘミセルロースの糖組成を次の方法で分析した。ウ
ロン酸の測定は Blumenkrantz 法により、また中性糖は
アルジトールアセテート法によりGLCを用いて測定し
た。
Next, the sugar compositions of the water-soluble soybean hemicelluloses (a), (b) and (c) were analyzed by the following method. The uronic acid was measured by the Blumenkrantz method, and the neutral sugar was measured by GLC by the alditol acetate method.

【0035】結果は以下のとおり。 糖組成(重量%) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 糖の種類 (イ) (ロ) (ハ) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ウロン酸 20.4 16.9 23.1 ラムノース 2.4 2.7 2.1 フコース 2.7 5.2 3.9 アラビノース 19.9 19.2 19.4 キシロース 6.4 8.4 5.8 ガラクトース 47.3 45.9 45.2 グルコース 0.9 1.7 0.5 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−The results are as follows. Sugar composition (% by weight) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Sugar type (a) (b) (C) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−- uronic acid 20.4 16.9 23.1 rhamnose 2.4 2.7 2.1 fucose 2.7 5.2 3.9 arabinose 19.9 19.2 19.4 Xylose 6.4 8.4 5.8 Galactose 47.3 45.9 45.2 Glucose 0.9 1.7 0.5 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−

【0036】実施例1 砂糖50部と水溶性大豆ヘミセルロース(イ)5部を混合
し、ここに水飴(DE=42)40部、水20部を加え糖度85%に
なるまで煮詰めて糖液を調製した。一方、ゼラチン2部
を温水10.5部に溶解したゼラチン液、クエン酸1部、黄
色色素0.1 部、水溶性オレンジフレーバー0.4 部を水1
部に溶解させた酸液を調製しておき、上記の糖液に加
え、よく攪拌混合したのち脱泡してスターチモールド
(20mm×20mm×10mm)内にデポジットした。デポジット
後室温にて15時間冷却乾燥させゼリー菓子を得た。この
ゼリー菓子は、手にベトつかず、さらに、弾力性に富む
良好な食感を有している、商品価値の高いものであっ
た。
Example 1 50 parts of sugar and 5 parts of water-soluble soybean hemicellulose (a) were mixed, and 40 parts of starch syrup (DE = 42) and 20 parts of water were added thereto and boiled to a sugar content of 85% to prepare a sugar solution. Prepared. On the other hand, a gelatin solution prepared by dissolving 2 parts of gelatin in 10.5 parts of warm water, 1 part of citric acid, 0.1 part of yellow pigment, and 0.4 parts of water-soluble orange flavor to 1 part of water.
An acid solution dissolved in the solution was prepared, added to the above sugar solution, thoroughly mixed with stirring, degassed, and deposited in a starch mold (20 mm × 20 mm × 10 mm). After depositing, it was cooled and dried at room temperature for 15 hours to obtain a jelly confectionery. This jelly confectionery had a high commercial value because it was not sticky to the hands and had a good texture with rich elasticity.

【0037】実施例2 実施例1において水溶性大豆ヘミセルロース(イ)を使
用する代わりに水溶性大豆ヘミセルロース(ロ)を使用
した他は実施例1と同様にしてゼリー菓子を得た。この
ゼリー菓子も同様に手にベトつかず、良好な食感を有し
ている、商品価値の高いものであった。
Example 2 A jelly confectionery product was obtained in the same manner as in Example 1 except that the water-soluble soybean hemicellulose (b) was used instead of the water-soluble soybean hemicellulose (a). Similarly, this jelly confectionery was not sticky to the hands, had a good texture, and was of high commercial value.

【0038】実施例3 実施例1において水溶性大豆ヘミセルロース(イ)を使
用する代わりに水溶性大豆ヘミセルロース(ハ)を使用
した以外は実施例1と同様にしてゼリー菓子を得た。こ
のゼリー菓子は、実施例1および2で得たゼリー菓子と
比べ、弾力性が更に強く、チューイング性を有するゼリ
ー菓子であった。
Example 3 A jelly confectionery was obtained in the same manner as in Example 1 except that the water-soluble soybean hemicellulose (b) was used instead of the water-soluble soybean hemicellulose (a). This jelly confectionery was a jelly confectionery having higher elasticity and chewing property than the jelly confectionery obtained in Examples 1 and 2.

【0039】実施例4 砂糖50部と水飴(DE=42)40部、水10部を加え糖度85%に
なるまで煮詰めて糖液を調製した。一方、水溶性大豆ヘ
ミセルロース(イ)5部を50℃の温水16.5部に溶解し、
ここにオレンジオイル0.4 部を加えホモミキサーにて乳
化混合し乳化液を調製した。この乳化液と、ゼラチン2
部を温水4部で溶解したゼラチン液、クエン酸1部、黄
色色素0.1 部を水1部に溶解した酸液を上記の糖液に加
え、よく攪拌混合したのち脱泡してスターチモールド
(20mm×20mm×10mm)内にデポジットした。デポジット
後室温にて15時間冷却乾燥させゼリー菓子を得た。この
ゼリー菓子は、フレーバーを乳化させて添加しているた
め製造時の熱によるフレーバーの消失がなく、実施例
1、2および3で得たゼリー菓子に比べ、フレーバーの
保持性が更に良く、非常に商品価値の高いものであっ
た。
Example 4 A sugar solution was prepared by adding 50 parts of sugar, 40 parts of starch syrup (DE = 42) and 10 parts of water and boiling until the sugar content reached 85%. On the other hand, 5 parts of water-soluble soybean hemicellulose (a) was dissolved in 16.5 parts of warm water at 50 ° C,
To this, 0.4 part of orange oil was added and emulsified and mixed with a homomixer to prepare an emulsion. This emulsion and gelatin 2
A solution of gelatin dissolved in 4 parts of warm water, 1 part of citric acid, and 0.1 part of yellow dye dissolved in 1 part of water were added to the above sugar solution, mixed well with stirring, and then defoamed to obtain a starch mold (20 mm). Deposited within (20 mm x 10 mm). After depositing, it was cooled and dried at room temperature for 15 hours to obtain a jelly confectionery. Since this jelly confection does not lose the flavor due to heat during the production because the flavor is emulsified and added, the jelly confection has a better flavor retention than the jelly confections obtained in Examples 1, 2 and 3, and It had high commercial value.

【0040】実施例5 砂糖50部と水飴(DE=42)40部、水10部を加え糖度85%に
なるまで煮詰めて糖液を調製した。一方、水溶性大豆ヘ
ミセルロース(イ)5部を50℃の温水18部に溶解し、こ
こにチョコレート(油分含量35%)10部を加えホモミキ
サーにて乳化混合し乳化液を調製した。この乳化液と、
ゼラチン2部を温水4部で溶解したゼラチン液を上記の
糖液に加え、よく攪拌混合したのち脱泡してスターチモ
ールド(20mm×20mm×10mm)内にデポジットした。デポ
ジット後室温にて15時間冷却乾燥させてゼリー菓子を得
た。このゼリー菓子は、チョコレートの風味を有する弾
力性に富んだ食感の菓子であった。
Example 5 A sugar solution was prepared by adding 50 parts of sugar, 40 parts of starch syrup (DE = 42) and 10 parts of water and boiling until the sugar content reached 85%. On the other hand, 5 parts of water-soluble soybean hemicellulose (a) was dissolved in 18 parts of warm water at 50 ° C., 10 parts of chocolate (oil content 35%) was added thereto, and the mixture was emulsified and mixed with a homomixer to prepare an emulsion. With this emulsion,
A gelatin solution prepared by dissolving 2 parts of gelatin in 4 parts of warm water was added to the above sugar solution, thoroughly mixed with stirring, degassed and deposited in a starch mold (20 mm × 20 mm × 10 mm). After depositing, it was cooled and dried at room temperature for 15 hours to obtain a jelly confectionery. The jelly confectionery was a confectionery product having a chocolate flavor and a high elasticity.

【0041】実施例6 水溶性大豆ヘミセルロース(イ)25部と砂糖30部に水11
0 部を加え糖度60%になるまで煮詰めて糖液を調製し、
さらに水飴45部を加え品温が117 ℃となるまで煮詰め
た。一方、ゼラチン5部を温水15部で溶解したゼラチン
液、クエン酸1部、ステビオサイド0.13部、オレンジフ
レーバー0.4 部、黄色色素0.1 部を水1部に溶解した酸
液を調製しておき、上記糖液に加え、よく攪拌混合した
のちに70℃程度まで冷却してスターチモールドにデポジ
ットした。デポジット後、冷却乾燥させ水溶性ヘミセル
ロース入りゼリー菓子を調製した。このゼリー菓子は弾
力性に富んだ良好な食感を有していた。
Example 6 25 parts of water-soluble soybean hemicellulose (a), 30 parts of sugar and 11 parts of water
Add 0 parts and boil until the sugar content reaches 60% to prepare a sugar solution,
Furthermore, 45 parts of starch syrup was added and boiled until the product temperature reached 117 ° C. On the other hand, a gelatin solution prepared by dissolving 5 parts of gelatin in 15 parts of warm water, 1 part of citric acid, 0.13 part of stevioside, 0.4 part of orange flavor, and 0.1 part of yellow pigment in 1 part of water were prepared. The mixture was added to the solution, mixed well with stirring, cooled to about 70 ° C., and deposited on a starch mold. After depositing, the mixture was cooled and dried to prepare a water-soluble hemicellulose-containing jelly confectionery. This jelly confectionery had good elasticity and good texture.

【0042】比較例1 実施例1において水溶性大豆ヘミセルロース(イ)を使
用する代わりに砂糖を使用した他は実施例1と同様にし
てゼリー菓子を得た。このゼリー菓子は、乾燥後も表面
がベトベトしており、ゼリー菓子同士が結着し易いだけ
でなく、手に粘稠な糖液が付着する商品価値の低いもの
であった。
Comparative Example 1 A jelly confectionery was obtained in the same manner as in Example 1 except that sugar was used instead of the water-soluble soybean hemicellulose (a) in Example 1. The surface of the jelly confectionery was sticky even after drying, and not only the jelly confectionery was easily bound to each other, but also the viscous sugar solution adhered to the hands, which had low commercial value.

【0043】比較例2 実施例1において水溶性大豆ヘミセルロース(イ)を使
用する代わりにアラビアガムを使用した他は実施例1と
同様にしてゼリー菓子を得た。このゼリー菓子は、乾燥
後にゼリー菓子表面のひび割れが多く認められる商品価
値の低いものであった。
Comparative Example 2 A jelly confectionery was obtained in the same manner as in Example 1 except that gum arabic was used instead of the water-soluble soybean hemicellulose (a) in Example 1. This jelly confectionery had a low commercial value in which many cracks were observed on the surface of the jelly confectionery after drying.

【0044】比較例3 実施例1において水溶性大豆ヘミセルロース(イ)を使
用する代わりにプルランを使用した他は実施例1と同様
にしてゼリー菓子を得た。このゼリー菓子は、製造時に
糖液の粘度が上昇し、煮詰め作業が困難になった他、出
来上がったゼリー菓子は硬くなり、食感の悪いものであ
った。
Comparative Example 3 A jelly confectionery was obtained in the same manner as in Example 1 except that pullulan was used in place of the water-soluble soybean hemicellulose (a) in Example 1. In this jelly confectionery, the viscosity of the sugar solution increased during production, which made it difficult to boil down, and the finished jelly confectionery became hard and had a bad texture.

【0045】比較例4 実施例1において水溶性大豆ヘミセルロース(イ)を使
用する代わりにペクチンを使用した他は実施例1と同様
にしてゼリー菓子を得た。このゼリー菓子は、製造時に
糖液の粘度が著しく上昇し、糖度80%までしか煮詰めら
れなかった他、出来上がったゼリー菓子は硬く、アメ状
の製品となった。
Comparative Example 4 A jelly confectionery was obtained in the same manner as in Example 1 except that pectin was used instead of using the water-soluble soybean hemicellulose (a) in Example 1. The jelly confectionery had a significantly increased viscosity of the sugar solution during production, and could only be boiled down to a sugar content of 80%. The finished jelly confectionery product was a hard, candy-shaped product.

【0046】比較例5 砂糖55部に水110 部を加え糖度60%になるまで煮詰めて
糖液を調製し、さらに水飴45部を加え品温が117 ℃とな
るまで煮詰めた。一方、ゼラチン5部を温水15部で溶解
したゼラチン液、クエン酸1部、オレンジフレーバー0.
4 部、黄色色素0.1 部を水1部に溶解した酸液を調製し
ておき、上記糖液に加え、よく攪拌混合したのちに70℃
程度まで冷却してスターチモールドにデポジットした。
デポジット後、冷却乾燥させゼリー菓子を調製した。こ
のゼリー菓子は組織が硬く、弾力性を有する食感が得ら
れなかった。
Comparative Example 5 55 parts of sugar was added to 110 parts of water and boiled down to a sugar content of 60% to prepare a sugar solution, and further 45 parts of starch syrup was added thereto and boiled down to a product temperature of 117 ° C. On the other hand, a gelatin solution prepared by dissolving 5 parts of gelatin in 15 parts of warm water, 1 part of citric acid, and orange flavor.
Prepare an acid solution prepared by dissolving 4 parts and 0.1 part of yellow pigment in 1 part of water, add to the above sugar solution, mix well with stirring, and then at 70 ° C.
After cooling to a certain degree, it was deposited on a starch mold.
After depositing, it was cooled and dried to prepare a jelly confectionery. The jelly confectionery had a hard texture and no elastic texture was obtained.

【0047】実施例7 水飴32部と砂糖6部に全脂加糖練乳(糖度60%)24部、
乳化剤0.3 部とナタネ硬化油20部および水溶性大豆ヘミ
セルロース(ハ)2部とを加え品温が122 ℃となるまで
煮詰めた。ここに、品温115 ℃のフォンダント(砂糖7
5.5部、水飴5.6部、水18.9部)15.7部を添加し、よく攪
拌混合した後、70℃まで冷却し、ローラーで圧延、カッ
ターにて切断して一つの大きさが20mm×20mm×10mmのキ
ャラメルを調製した。このキャラメルは油分を多量使用
したものであって非常に美味であった。このキャラメル
を東洋濾紙(No.1)の上に置き、35℃に2日間放置したと
ころ、油分の浸み出しは全くなかったのに対し、比較の
ため水溶性大豆ヘミセルロースを添加しないで同様に調
製したキャラメルは、かなり油分の浸み出しが観察され
た。
Example 7 32 parts of starch syrup and 6 parts of sugar, 24 parts of full-fat-sweetened condensed milk (sugar content of 60%),
0.3 part of an emulsifier, 20 parts of rapeseed hydrogenated oil and 2 parts of water-soluble soybean hemicellulose (c) were added and boiled down until the product temperature reached 122 ° C. Here, the fondant (sugar 7
5.5 parts, starch syrup 5.6 parts, water 18.9 parts) 15.7 parts) were added, mixed well with stirring, cooled to 70 ° C, rolled with a roller, cut with a cutter to make one size of 20 mm × 20 mm × 10 mm. Caramel was prepared. This caramel used a large amount of oil and was very delicious. When this caramel was placed on Toyo Filter Paper (No.1) and left at 35 ° C for 2 days, no oil leached out, but for comparison, the same was done without adding water-soluble soybean hemicellulose. In the prepared caramel, leaching of oil was considerably observed.

【0048】実施例8 水溶性大豆ヘミセルロース(ハ)10部と砂糖5部に水35
部を加え糖度60%になるまで煮詰めて糖液を調製し、さ
らに水飴45部、加糖練乳35部を加え品温が122℃となる
まで煮詰めた。ここに、バター5部、乳化剤0.3 部、ス
テビオサイド0.05部を加え、よく攪拌混合したのち70℃
程度まで冷却してフォンダント(砂糖75部、水飴7部、
水18部)を10部添加し、冷却エージング後ローラーで圧
延、カッターにて切断し、キャラメルを調製した。この
キャラメルは噛み出しが軟らかく、非常に滑らかな食感
であった。
Example 8 10 parts of water-soluble soybean hemicellulose (c), 5 parts of sugar and 35 parts of water
A sugar solution was prepared by adding 1 part and boiling to a sugar content of 60%, and further adding 45 parts of starch syrup and 35 parts of condensed condensed milk and boiling until the product temperature reached 122 ° C. To this, add 5 parts butter, 0.3 parts emulsifier, 0.05 parts stevioside, mix well with stirring, and then at 70 ° C.
Cool down to a degree and fondant (75 parts sugar, 7 parts starch syrup,
10 parts of water (18 parts) was added, and after cooling aging, rolled with a roller and cut with a cutter to prepare a caramel. This caramel had a soft chew and a very smooth texture.

【0049】比較例6 砂糖15部に水35部を加え糖度60%になるまで煮詰めて糖
液を調製し、さらに水飴45部、練乳35部を加え品温が12
2 ℃となるまで煮詰めた。ここに、バター5部、乳化剤
0.3 部を加え、よく攪拌混合したのち70℃程度まで冷却
してフォンダント(砂糖75部、水飴7部、水18部)を10
部添加し、冷却エージング後ローラーで圧延、カッター
にて切断し、ソフトキャンディーを調製した。このソフ
トキャンディーは噛み出しが硬く、また一部の砂糖結晶
が粗大化し、若干ザラザラとした食感となった。
Comparative Example 6 A sugar solution was prepared by adding 35 parts of water to 15 parts of sugar and boiling until the sugar content reached 60%, and further adding 45 parts of starch syrup and 35 parts of condensed milk to a product temperature of 12
Boiled down to 2 ° C. 5 parts butter and emulsifier here
Add 0.3 parts, mix well, cool to about 70 ° C, and add 10 parts of fondant (75 parts sugar, 7 parts starch syrup, 18 parts water).
After adding a part, cooling aging, rolling with a roller and cutting with a cutter, soft candy was prepared. This soft candy was hard to bite out, and some sugar crystals were coarsened, resulting in a slightly rough texture.

【0050】実施例9 水溶性大豆ヘミセルロース(ロ)5部と砂糖60部に水15
0 部を加え糖度60%になるまで煮詰めて糖液を調製し、
さらに水飴35部を加え品温が140 ℃となるまで煮詰め
た。ここに、クエン酸1部、ステビオサイド0.03部、黄
色色素0.1 部、オレンジフレーバー0.4 部を水1部に溶
解した酸液を加え、よく攪拌混合したのち70℃程度まで
冷却し、タブレットマシンで円形に打抜き、ハードキャ
ンデーを調製した。このハードキャンデーは組織が滑ら
かで、ひび割れの認められる物は殆どなかった。
Example 9 5 parts of water-soluble soybean hemicellulose (II), 60 parts of sugar and 15 parts of water
Add 0 parts and boil until the sugar content reaches 60% to prepare a sugar solution,
Furthermore, 35 parts of starch syrup were added and boiled down until the product temperature reached 140 ° C. To this, add 1 part citric acid, 0.03 part stevioside, 0.1 part yellow pigment, 0.4 part orange flavor in 1 part water, add the acid solution, stir and mix well, cool to about 70 ° C, and round with a tablet machine. Punching, hard candy was prepared. This hard candy had a smooth texture and few cracks were found.

【0051】実施例10 水溶性大豆ヘミセルロース(ロ)20部と砂糖45部に水15
0 部を加え糖度60%になるまで煮詰めて糖液を調製し、
さらに水飴35部を加え品温が140 ℃となるまで煮詰め
た。ここに、クエン酸1部、ステビオサイド0.1 部、黄
色色素0.1 部、オレンジフレーバー0.4 部を水1部に溶
解した酸液を加え、よく攪拌混合したのち70℃程度まで
冷却し、タブレットマシンで円形に打抜きハードキャン
デーを調製した。このハードキャンデーも前例で得たも
のと同様に組織が滑らかで、ひび割れの認められる物は
全くなかった。
Example 10 20 parts of water-soluble soybean hemicellulose (II), 45 parts of sugar and 15 parts of water
Add 0 parts and boil until the sugar content reaches 60% to prepare a sugar solution,
Furthermore, 35 parts of starch syrup were added and boiled down until the product temperature reached 140 ° C. To this, add 1 part citric acid, 0.1 part stevioside, 0.1 part yellow pigment, 0.4 part orange flavor in 1 part water, add the acid solution, stir and mix well, cool to about 70 ° C, and round with a tablet machine. A punched hard candy was prepared. Similar to the hard candy obtained in the previous example, this hard candy had a smooth texture and no cracks were observed.

【0052】実施例11 水溶性大豆ヘミセルロース(ロ)35部と砂糖30部に水15
0 部を加え糖度60%になるまで煮詰めて糖液を調製し、
さらに水飴35部を加え品温が140 ℃となるまで煮詰め
た。ここに、クエン酸1部、ステビオサイド0.18部、黄
色色素0.1 部、オレンジフレーバー0.4 部を水1部に溶
解した酸液を加え、よく攪拌混合したのち70℃程度まで
冷却し、タブレットマシンで円形に打抜きハードキャン
デーを調製した。このハードキャンデーは実施例10およ
び11で得たものより更に組織のシットリ感が強く、より
滑らかな組織を有していた。
Example 11 35 parts of water-soluble soybean hemicellulose (II), 30 parts of sugar and 15 parts of water
Add 0 parts and boil until the sugar content reaches 60% to prepare a sugar solution,
Furthermore, 35 parts of starch syrup were added and boiled down until the product temperature reached 140 ° C. To this, add 1 part citric acid, 0.18 parts stevioside, 0.1 parts yellow pigment, 0.4 parts orange flavor in 1 part water, add the acid solution, stir and mix well, cool to about 70 ° C, and round with a tablet machine. A punched hard candy was prepared. This hard candy had a stronger texture and a smoother texture than those obtained in Examples 10 and 11.

【0053】実施例12 水溶性大豆ヘミセルロース(ロ)50部と砂糖15部に水15
0 部を加え糖度60%になるまで煮詰めて糖液を調製し、
さらに水飴35部を加え品温が140 ℃となるまで煮詰め
た。ここに、クエン酸1部、ステビオサイド0.25部、黄
色色素0.1 部、オレンジフレーバー0.4 部を水1部に溶
解した酸液を加え、よく攪拌混合したのち70℃程度まで
冷却し、タブレットマシンで円形に打抜きハードキャン
デーを調製した。このハードキャンデーは組織が滑らか
で、若干の弾力性が感じられた。
Example 12 50 parts of water-soluble soybean hemicellulose (II), 15 parts of sugar and 15 parts of water
Add 0 parts and boil until the sugar content reaches 60% to prepare a sugar solution,
Furthermore, 35 parts of starch syrup were added and boiled down until the product temperature reached 140 ° C. To this, add 1 part of citric acid, 0.25 part of stevioside, 0.1 part of yellow pigment, 0.4 part of orange flavor in 1 part of water. A punched hard candy was prepared. The structure of this hard candy was smooth, and some elasticity was felt.

【0054】比較例7 砂糖65部に水150 部を加え糖度60%になるまで煮詰めて
糖液を調製し、さらに水飴35部を加え品温が140 ℃とな
るまで煮詰めた。ここに、クエン酸1部、黄色色素0.1
部、オレンジフレーバー0.4 部を水1部に溶解した酸液
を加え、よく攪拌混合したのち70℃程度まで冷却し、タ
ブレットマシンで円形に打抜き、ハードキャンデーを調
製した。このハードキャンデーの組織は非常に硬く、ほ
とんどの物にひび割れが認められた。
Comparative Example 7 A sugar solution was prepared by adding 150 parts of water to 65 parts of sugar and boiling it down to a sugar content of 60%, and further adding 35 parts of starch syrup until the product temperature reached 140 ° C. Here, citric acid 1 part, yellow pigment 0.1
And 0.4 parts of orange flavor were dissolved in 1 part of water, and the mixture was stirred and mixed well, cooled to about 70 ° C., and punched in a circle with a tablet machine to prepare a hard candy. The structure of this hard candy was very hard, and most of them had cracks.

【0055】実施例6,8〜12、比較例5〜7で得られ
たキャンデーを、それぞれゼリー菓子、キャラメル、ハ
ードキャンデーに分け20名のパネラーによる試食評価を
行った結果を以下に示す。
The candy obtained in Examples 6, 8 to 12 and Comparative Examples 5 to 7 was divided into jelly confectionery, caramel and hard candy, and the results of the tasting evaluation by 20 panelists are shown below.

【0056】 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 実施例の方が良い 比較例の方が良い と答えた人 と答えた人 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ゼリー菓子 15 5 (実施例6) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− キャラメル 19 1 (実施例8) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ハードキャンデー 12 8 (実施例9) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ハードキャンデー 14 6 (実施例10) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ハードキャンデー 15 5 (実施例11) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ハードキャンデー 14 6 (実施例12) −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−-------------------------------------------- Example is better Comparative example is better Person who replied, and person who replied ------------------------------------------ Jelly confectionery 15 5 (Example 6) -------------------------------------- Caramel 19 1 (Example 8) ----- -------------------------------- Hard candy 128 (Example 9) ---------- -------------- Hard candy 14 6 (Example 10) --------------------- ------------- Hard candy 155 (Example 11) --- -------------- Hard candy 146 (Example 12) --------------- −−−−−−−−−−−−−−−−−−−−−−−−−−

【0057】[0057]

【発明の効果】以上のように、キャンデーを製造するに
際し、本発明における水溶性ヘミセルロースを用いる
と、一段と弾力性に富む食感を有したゼリー菓子、油の
浸み出しを起こし難いキャラメルなど品質の改善された
ソフトキャンデー、さらに滑らかな組織を有しひび割れ
を起こし難いハードキャンデーを得ることができる。
As described above, in the production of candy, when the water-soluble hemicellulose of the present invention is used, the quality of jelly confectionery having a more highly elastic texture, caramel which is unlikely to cause oil leaching, and the like. It is possible to obtain an improved soft candy, and a hard candy which has a smooth texture and is hard to cause cracking.

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 砂糖、水飴を主原料としてキャンデーを
製造するに際し、品質改良剤として水溶性ヘミセルロー
スを使用することを特徴とする、キャンデーの製造法。
1. A method for producing candy, which comprises using water-soluble hemicellulose as a quality improving agent when producing candy using sugar or starch syrup as a main raw material.
【請求項2】 水溶性ヘミセルロースが大豆子葉由来の
水溶性ヘミセルロースである、請求項1記載の方法。
2. The method according to claim 1, wherein the water-soluble hemicellulose is a water-soluble hemicellulose derived from soybean cotyledons.
【請求項3】 キャンデーがソフトキャンデーである、
請求項1または2記載の方法。
3. The candy is a soft candy,
The method according to claim 1 or 2.
【請求項4】 ソフトキャンデーが糖液を凝固剤で固め
たゼリー菓子である、請求項3に記載の方法。
4. The method according to claim 3, wherein the soft candy is a jelly confectionery prepared by solidifying a sugar solution with a coagulant.
【請求項5】 ソフトキャンデーが蛋白成分および油脂
分を使用したキャラメルである、請求項3に記載の方
法。
5. The method according to claim 3, wherein the soft candy is a caramel using a protein component and an oil / fat component.
JP6057281A 1994-03-28 1994-03-28 How to make candy Expired - Fee Related JP2959387B2 (en)

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ID=13051160

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10257853A (en) * 1997-03-19 1998-09-29 House Foods Corp Buffalo berry candy and its production
KR100536647B1 (en) * 1998-05-20 2006-03-22 후지 세유 가부시키가이샤 Rice cakes and rice cakes and anti-aging agents used for them
JP2016189713A (en) * 2015-03-31 2016-11-10 不二製油株式会社 Water-containing chocolate-like food
WO2024097612A1 (en) * 2022-10-31 2024-05-10 Wm. Wrigley Jr. Company Confectionary products and methods of producing confectionary products

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10257853A (en) * 1997-03-19 1998-09-29 House Foods Corp Buffalo berry candy and its production
KR100536647B1 (en) * 1998-05-20 2006-03-22 후지 세유 가부시키가이샤 Rice cakes and rice cakes and anti-aging agents used for them
JP2016189713A (en) * 2015-03-31 2016-11-10 不二製油株式会社 Water-containing chocolate-like food
WO2024097612A1 (en) * 2022-10-31 2024-05-10 Wm. Wrigley Jr. Company Confectionary products and methods of producing confectionary products

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