JPH07243611A - Method and apparatus for burning finely ground coal - Google Patents

Method and apparatus for burning finely ground coal

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Publication number
JPH07243611A
JPH07243611A JP3212994A JP3212994A JPH07243611A JP H07243611 A JPH07243611 A JP H07243611A JP 3212994 A JP3212994 A JP 3212994A JP 3212994 A JP3212994 A JP 3212994A JP H07243611 A JPH07243611 A JP H07243611A
Authority
JP
Japan
Prior art keywords
pulverized coal
burner
oil
combustion
coal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3212994A
Other languages
Japanese (ja)
Inventor
Takanori Yano
隆則 矢野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Power Ltd
Original Assignee
Babcock Hitachi KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Babcock Hitachi KK filed Critical Babcock Hitachi KK
Priority to JP3212994A priority Critical patent/JPH07243611A/en
Publication of JPH07243611A publication Critical patent/JPH07243611A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To reduce NOx and non-burned fractions produced following the lowering of oxygen partial pressure by forming an oil flame by an oil burner in a coal flame, and burning the oil burner with excess fuel to brine the interior of the coal flame into a high temperature reducing atmosphere. CONSTITUTION:In the case where the amount of supply coal to a burner to be ignited is too little compared with the amount of supply air when a finely- grounded coal burner is ignited anew upon starting a boiler furnace, burning is achieved by an oil burner 28, and excess air existent in the vicinity of a finely-grounded coal burner flame is consumed to eliminate the state of excess air into a high temperature reducing atmosphere, whereby the amount of production of NOx is reduced and the burning is promoted for reduction of non-burned fractions. A coal fine grinder is started and the finely-grounded coal burner is ignited. Finely-grounded coal is carried and supplied with air of a necessary amount or more to the finely-grounded burner to burn an oil fuel in response to the excess air fraction. Hereby, oxygen partial pressure is lowered so that production of NOx is reduced by making use of promotion of initial burning.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は微粉炭燃焼装置に係り、
特にボイラ火炉等の起動時において、燃焼排ガス中の窒
素酸化物(NOx)の生成を低減するのに好適な低NO
x燃焼方法およびそれを実施する装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pulverized coal combustion device,
Especially when starting a boiler furnace, etc., a low NO that is suitable for reducing the production of nitrogen oxides (NOx) in the combustion exhaust gas.
TECHNICAL FIELD The present invention relates to an x combustion method and an apparatus for implementing the same.

【0002】[0002]

【従来の技術】従来のボイラ火炉等の運用において、ボ
イラ負荷の変動による運転条件の変化や燃料の性状等の
変化により、一時的あるいは継続的に燃焼排ガス中のN
Ox値が規制値を超える場合がある。このため、2段燃
焼法あるいは超低NOx燃焼バーナ等を用いて低NOx燃
焼を行っても、燃焼排ガス中のNOx値を規制値以下に
維持することは極めて困難であった。特に、ボイラ火炉
の起動時において微粉炭バーナの燃焼が空気過剰となる
ことからNOxが生成しやすく、排ガス中のNOx値が規
制値を超えるという問題がしばしば発生する。なお、従
来技術として、微粉炭バーナの微粉炭噴流に燃焼排ガス
を混合し、微粉炭燃焼領域における酸素分圧を低下させ
てNOxの発生を抑制する微粉炭焚バーナとして、例え
ば実開昭56−52111号公報が挙げられる。
2. Description of the Related Art In the operation of a conventional boiler furnace, the N in the combustion exhaust gas is temporarily or continuously changed due to changes in operating conditions and changes in fuel properties due to changes in boiler load.
The Ox value may exceed the regulation value. For this reason, it is extremely difficult to maintain the NOx value in the combustion exhaust gas below the regulation value even if low NOx combustion is performed using the two-stage combustion method or an ultra-low NOx combustion burner. In particular, when starting up the boiler furnace, NOx is easily generated because the combustion of the pulverized coal burner causes excess air, and the problem that the NOx value in the exhaust gas exceeds the regulation value often occurs. As a conventional technique, for example, as a pulverized coal burning burner that mixes combustion exhaust gas with the pulverized coal jet of the pulverized coal burner to reduce the oxygen partial pressure in the pulverized coal combustion region to suppress the generation of NOx, for example, actual development Sho-56- No. 52111 is cited.

【0003】[0003]

【発明が解決しようとする課題】上述したように、従来
の微粉炭燃焼装置においては、ボイラ火炉等の負荷の変
動による運転条件、あるいは燃料の性状等の変化によっ
て、排ガス中に含まれるNOx値が規制値を超える場合
がしばしばあり、またボイラ火炉の起動時には、微粉炭
バーナの燃焼が空気過剰となることからNOxが生成し
やすく、排ガス中のNOx値が規制値以上になるという
問題があった。
As described above, in the conventional pulverized coal combustion apparatus, the NOx value contained in the exhaust gas varies depending on the operating conditions due to the fluctuation of the load of the boiler furnace or the like, or the change of the fuel property or the like. Often exceeds the regulation value, and when starting up the boiler furnace, NOx is easily generated because the combustion of the pulverized coal burner causes excess air, and there is a problem that the NOx value in the exhaust gas exceeds the regulation value. It was

【0004】本発明の目的は、上記従来技術における問
題点を解消するものであって、微粉炭の燃焼条件や燃料
の性状等の変化があっても、またボイラ火炉の起動時に
おいても、効果的に空気過剰状態を解消しNOxの低減
と、燃焼促進による未燃分の低減を行うことのできる微
粉炭の低NOx燃焼方法およびそれを実施する装置を提
供することにある。
The object of the present invention is to solve the above problems in the prior art, and is effective even when there are changes in the combustion conditions of pulverized coal, the properties of fuel, etc., and when the boiler furnace is started. An object of the present invention is to provide a low NOx combustion method for pulverized coal, which can eliminate an excessive air state to reduce NOx and reduce unburned content by promoting combustion, and an apparatus for implementing the method.

【0005】[0005]

【課題を解決するための手段】上記本発明の目的を達成
するために、本発明の微粉炭の低NOx燃焼方法におい
ては、微粉炭バーナ(複数)に供給される燃焼用空気量
に応じた燃料量を、主燃料である石炭と補助燃料である
油とに分割して投入して同軸燃焼を行う制御手段を設け
るものである。すなわち、石炭火炎の内部に、微粉炭バ
ーナのほぼ中心部に装備した油バーナによる油火炎を形
成させ、上記油バーナを燃料過剰燃焼制御することによ
り、石炭火炎の中心部に形成される油火炎による高温還
元領域を強化してNOxの低減をはかると共に、燃焼の
促進を行い未燃分の低減をはかるものである。本発明の
低NOx燃焼方法は、微粉炭を主たる燃料とする微粉炭
バーナと、油を補助燃料とする油バーナを備え、上記微
粉炭バーナの石炭火炎の内部に上記油バーナによる油火
炎を形成させる構造の微粉炭燃焼装置を用い、上記油バ
ーナを燃料過剰燃焼制御することにより、上記石炭火炎
の内部を高温還元性雰囲気となし、酸素分圧の低下に伴
う窒素酸化物の生成の抑制と、燃焼促進による未燃分の
低減をはかる微粉炭の低NOx燃焼方法である。そし
て、上記油バーナを燃料過剰燃焼させる時期は、微粉炭
バーナの起動時、あるいは微粉炭バーナの低負荷運用時
において、微粉炭バーナに供給される微粉炭中の1次燃
焼用空気量が過剰となる時期に行うものである。本発明
の微粉炭の低NOx燃焼装置は、微粉炭機(ミル)から
1次燃焼用空気と共に搬送される微粉炭を火炉に供給し
燃焼を行う微粉炭供給管を有する微粉炭バーナと、該微
粉炭バーナのほぼ中心部に同一のエアレジスタ内に装備
された油を補助燃料とする油バーナとを配設して上記微
粉炭と油とを同軸燃焼制御する構造となし、上記微粉炭
バーナに供給される燃焼用空気量に応じた燃料量を、主
燃料である微粉炭と補助燃料である油とにそれぞれ分割
して供給制御し、石炭火炎の内部に油火炎を形成する手
段を設けたものである。そして、微粉炭バーナに供給さ
れる微粉炭流の1次燃焼用空気の過剰分に応じた油を燃
焼させる制御手段を設けるものである。このような構造
とすることにより、微粉炭燃焼領域における酸素分圧の
低下によるNOxの低減と、油バーナによる燃焼の促進
により未燃分の低減を効果的に行うことができる。
In order to achieve the above object of the present invention, in the low NOx combustion method for pulverized coal of the present invention, the amount of combustion air supplied to the pulverized coal burners (plurality) is adjusted. A control means is provided for dividing the fuel amount into coal which is the main fuel and oil which is the auxiliary fuel and charging the same to perform coaxial combustion. That is, inside the coal flame, an oil flame is formed by an oil burner equipped in almost the center of the pulverized coal burner, and the oil burner is controlled in excess of fuel to control the oil flame to form an oil flame in the center of the coal flame. In order to reduce the NOx by strengthening the high temperature reduction region by, the combustion is promoted to reduce the unburned component. The low NOx combustion method of the present invention includes a pulverized coal burner that uses pulverized coal as a main fuel and an oil burner that uses oil as an auxiliary fuel, and forms an oil flame by the oil burner inside the coal flame of the pulverized coal burner. Using a pulverized coal combustor having a structure to make the oil burner fuel overcombustion control, the inside of the coal flame is made into a high-temperature reducing atmosphere, and suppression of the generation of nitrogen oxides due to a decrease in oxygen partial pressure and A low NOx combustion method for pulverized coal that reduces unburned components by promoting combustion. When the pulverized coal burner is started or when the pulverized coal burner is operated at a low load, the amount of primary combustion air in the pulverized coal supplied to the pulverized coal burner is excessive. It will be done at the time. A low-NOx combustion apparatus for pulverized coal of the present invention includes a pulverized coal burner having a pulverized coal supply pipe for supplying pulverized coal conveyed from a pulverized coal machine (mill) together with primary combustion air to a furnace for combustion. The pulverized coal burner has a structure for coaxially controlling combustion of the pulverized coal and the oil by disposing an oil burner provided in the same air register as an auxiliary fuel in the center of the pulverized coal burner. A means for forming an oil flame inside the coal flame is provided by dividing the amount of fuel corresponding to the amount of combustion air supplied to each of the pulverized coal, which is the main fuel, and the oil, which is the auxiliary fuel, and controlling the supply. It is a thing. Then, a control means for burning the oil according to the excess amount of the primary combustion air of the pulverized coal flow supplied to the pulverized coal burner is provided. With such a structure, NOx can be reduced by reducing the oxygen partial pressure in the pulverized coal combustion region, and unburned components can be effectively reduced by promoting combustion by the oil burner.

【0006】[0006]

【実施例】以下に本発明の実施例を挙げ、図面を用いて
さらに具体的に説明する。図2は、本発明の低NOx燃
焼方法を実施するための微粉炭焚ボイラ火炉における空
気および排ガスの制御系統を示す模式図である。ここ
で、ボイラ火炉1の通常の負荷運転時における火炉の制
御方法について説明する。図において、燃焼用空気は押
し込み送風機(FDF)2から、エアヒータ5で排ガス
と熱交換して昇温され、各微粉炭バーナ(図示せず)お
よび各アフタエアポート(図示せず)に分配供給され
る。すなわち、ウィンドボックス入口ダンパ11、12
により流量を制御した後、それぞれバーナ用ウィンドボ
ックス7、8に流入し、各バーナに供給される。また、
燃料炭は微粉炭粉砕機(ミル)21、22により粉砕さ
れ、1次空気ファン(PAF)15から、エアヒータ5
を通して所定の温度に調整され、ミル1次空気入口ダン
パ19、20によって流量を制御された1次空気によっ
て気流搬送され各バーナに供給される。また、アフタエ
アポート(AAP)9、10から供給される空気により
2段燃焼が行われ、排ガス中のNOxおよび未燃分の低
減をはかっている。そして、排ガス再循環ファン(GR
F)4により、火炉出口部から供給される蒸気温度制御
用ならびに低NOx化をはかるためにホッパへの排ガス
再循環ダンパ23が設けられている。なお、火炉1から
排出される排ガスは、誘引通風機(IDF)3により誘
引され、上記燃焼用空気とバランスが保たれ煙突6から
排出される。以上の構成において、本発明の実施例で
は、ボイラ火炉の起動時等、新たに微粉炭バーナを点火
する時に、点火するバーナに対する給炭量が空気供給量
に対して過少である場合には、図1に示す油バーナ28
によって燃焼を行い、微粉炭バーナ火炎近傍の過剰な空
気を消費して、空気過剰の状態を解消して高温還元雰囲
気となし、NOxの発生量の低減をはかると共に、燃焼
を促進させて未燃分の低減をはかる低NOx燃焼方法で
ある。そして、図2に示すように、ミル21またはミル
22を起動し、微粉炭バーナを点火する時に、微粉炭は
必要以上の1次空気により微粉炭バーナに搬送し供給さ
れることがある。この場合には、過剰空気分に応じた油
燃料を燃焼させることにより上記過剰空気を消費し、こ
れにより酸素分圧が低下するのでNOxの生成が低減さ
れ、同時に初期燃焼の促進による未燃分の低減をはかる
ことができる。
Embodiments of the present invention will be described below in more detail with reference to the drawings. FIG. 2 is a schematic diagram showing an air and exhaust gas control system in a pulverized coal burning boiler furnace for carrying out the low NOx combustion method of the present invention. Here, a method of controlling the boiler furnace 1 during normal load operation will be described. In the figure, the combustion air is heated from the forced draft fan (FDF) 2 by exchanging heat with the exhaust gas in the air heater 5, and distributed and supplied to each pulverized coal burner (not shown) and each after-air port (not shown). It That is, the wind box inlet dampers 11 and 12
After the flow rate is controlled by, the gas flows into the burner wind boxes 7 and 8 and is supplied to each burner. Also,
The fuel coal is pulverized by the pulverized coal pulverizers (mills) 21 and 22, and is fed from the primary air fan (PAF) 15 to the air heater 5
Is adjusted to a predetermined temperature through the primary air whose flow rate is controlled by the primary air inlet dampers 19 and 20 of the mill, and is conveyed to the burners by air flow. Further, two-stage combustion is performed by the air supplied from the after-air ports (AAP) 9 and 10 to reduce NOx and unburned components in the exhaust gas. And the exhaust gas recirculation fan (GR
F) 4 is provided with an exhaust gas recirculation damper 23 to the hopper for controlling the temperature of steam supplied from the furnace outlet and for reducing NOx. Note that the exhaust gas discharged from the furnace 1 is attracted by the induction fan (IDF) 3, is balanced with the combustion air, and is discharged from the chimney 6. In the above configuration, in the embodiment of the present invention, when the pulverized coal burner is newly ignited, such as at the time of starting the boiler furnace, when the coal supply amount for the ignited burner is too small with respect to the air supply amount, Oil burner 28 shown in FIG.
Burns and consumes excess air in the vicinity of the pulverized coal burner flame to eliminate excess air and create a high-temperature reducing atmosphere to reduce the amount of NOx produced and promote combustion to promote unburned combustion. This is a low NOx combustion method that aims to reduce the energy consumption. Then, as shown in FIG. 2, when the mill 21 or the mill 22 is activated and the pulverized coal burner is ignited, the pulverized coal may be conveyed and supplied to the pulverized coal burner by more than necessary primary air. In this case, the excess air is consumed by burning the oil fuel according to the excess air content, and the oxygen partial pressure is reduced by this, so that the production of NOx is reduced, and at the same time, the unburned content due to the promotion of the initial combustion is reduced. Can be reduced.

【0007】[0007]

【発明の効果】本発明の微粉炭の低NOx燃焼方法によ
れば、燃焼用空気供給量に対応して、その過剰空気量に
応じて油燃料を投入し微粉炭火炎を高温還元性火炎に自
在に制御することができるので、ボイラ火炉の起動時、
あるいは負荷の変動に伴う燃焼条件の変更等によるNO
xの増加時においても効果的にNOxの発生量を低減する
ことができ、かつ燃焼促進による未燃分の低減も可能と
なる。また、本発明の方法を実施する場合に燃焼設備の
大幅な改造を必要とすることなく、制御装置の設置また
は改造のみで実施できるので極めて経済的である。
EFFECTS OF THE INVENTION According to the low NOx combustion method for pulverized coal of the present invention, the pulverized coal flame is turned into a high-temperature reducing flame by charging oil fuel in accordance with the excess air amount corresponding to the combustion air supply amount. Since it can be controlled freely, when starting the boiler furnace,
Or NO due to changes in combustion conditions due to changes in load
Even when x increases, the amount of NOx generated can be effectively reduced, and the unburned content can be reduced by promoting combustion. Further, when the method of the present invention is carried out, it is possible to carry out the operation only by installing or modifying the control device without requiring a large modification of the combustion equipment, which is extremely economical.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の実施例において例示した微粉炭バーナ
の構造を示す模式図。
FIG. 1 is a schematic diagram showing the structure of a pulverized coal burner exemplified in an example of the present invention.

【図2】本発明の実施例において例示したボイラ火炉の
燃焼用空気および排ガスの制御系統を示す模式図。
FIG. 2 is a schematic diagram showing a control system for combustion air and exhaust gas of the boiler furnace illustrated in the embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1…ボイラ火炉 2…FDF(押し込み送風機) 3…IDF(誘引通風機) 4…GRF(排ガス再循環ファン) 5…エアヒータ 6…煙突 7、8…バーナ用ウィンドボックス 9、10…アフタエアポート(AAP)用ウィンドボッ
クス 11、12、13、14…ウィンドボックス入口ダンパ 15…1次空気ファン(PAF) 16…PAF出口ダンパ 17…冷空気ダンパ 18…熱空気ダンパ 19、20…ミル1次空気入口ダンパ 21、22…ミル(石炭微粉砕機) 23…ホッパへの排ガス再循環ダンパ 24、25…油配管 26…石炭火炎 27…油火炎 28…油バーナ 29…エアレジスタ 30…火炉水壁
1 ... Boiler furnace 2 ... FDF (pushing blower) 3 ... IDF (induction draft fan) 4 ... GRF (exhaust gas recirculation fan) 5 ... Air heater 6 ... Chimney 7, 8 ... Burner wind box 9, 10 ... After air port (AAP) ) Windbox 11, 12, 13, 14 ... Windbox inlet damper 15 ... Primary air fan (PAF) 16 ... PAF outlet damper 17 ... Cold air damper 18 ... Hot air damper 19, 20 ... Mill primary air inlet damper 21, 22 ... Mill (coal pulverizer) 23 ... Exhaust gas recirculation damper to hopper 24, 25 ... Oil pipe 26 ... Coal flame 27 ... Oil flame 28 ... Oil burner 29 ... Air register 30 ... Furnace water wall

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】微粉炭を主たる燃料とする微粉炭バーナ
と、油を補助燃料とする油バーナを備え、上記微粉炭バ
ーナの石炭火炎の内部に上記油バーナによる油火炎を形
成させる構造の微粉炭燃焼装置を用い、上記油バーナを
燃料過剰燃焼制御することにより、上記石炭火炎の内部
を高温還元性雰囲気となし、酸素分圧の低下に伴う窒素
酸化物の生成の抑制と、燃焼促進による未燃分の低減を
はかることを特徴とする微粉炭の低NOx燃焼方法。
1. A fine powder having a structure in which a pulverized coal burner using pulverized coal as a main fuel and an oil burner using oil as an auxiliary fuel are provided, and an oil flame is formed by the oil burner inside the coal flame of the pulverized coal burner. By using a charcoal combustor to control the fuel burner of the oil burner in excess of fuel, a high-temperature reducing atmosphere is created inside the coal flame, and the generation of nitrogen oxides due to the decrease in oxygen partial pressure is suppressed and combustion is promoted. A low-NOx combustion method for pulverized coal, characterized by reducing unburned components.
【請求項2】請求項1において、油バーナを燃料過剰燃
焼制御する時期は、微粉炭バーナの起動時における燃焼
用空気過剰供給時であることを特徴とする微粉炭の低N
Ox燃焼方法。
2. The low N of pulverized coal according to claim 1, wherein the fuel excess combustion control of the oil burner is at the time of excessive supply of combustion air at the startup of the pulverized coal burner.
Ox combustion method.
【請求項3】請求項1において、油バーナを燃料過剰燃
焼制御する時期は、微粉炭バーナの低負荷運用時におけ
る燃焼用空気過剰供給時であることを特徴とする微粉炭
の低NOx燃焼方法。
3. A low NOx combustion method for pulverized coal according to claim 1, characterized in that the timing for controlling the fuel excess combustion of the oil burner is during the excessive supply of combustion air during the low load operation of the pulverized coal burner. .
【請求項4】微粉炭機から1次燃焼用空気と共に搬送さ
れる微粉炭を火炉に供給し燃焼を行う微粉炭供給管を有
する微粉炭バーナと、該微粉炭バーナのほぼ中心部に、
同一のエアレジスタ内に装備された油を補助燃料とする
油バーナを配設して、上記微粉炭と油とを同軸燃焼させ
る構造となし、上記微粉炭バーナに供給される燃焼用空
気量に応じた燃料量を、主燃料である微粉炭と補助燃料
である油とにそれぞれ分割して供給制御する手段を設け
たことを特徴とする微粉炭の低NOx燃焼装置。
4. A pulverized coal burner having a pulverized coal supply pipe for supplying pulverized coal conveyed from a pulverized coal machine together with air for primary combustion to a furnace for combustion, and a pulverized coal burner at a substantially central portion,
An oil burner that uses oil as an auxiliary fuel installed in the same air register is provided, and the structure is such that the pulverized coal and oil are coaxially burned, and the amount of combustion air supplied to the pulverized coal burner is set. A low NOx combustion device for pulverized coal, characterized in that means for controlling the supply of the pulverized coal as a main fuel and oil as an auxiliary fuel are separately provided.
【請求項5】請求項4において、微粉炭バーナに供給さ
れる微粉炭流の1次燃焼用空気の過剰分に応じた量の油
燃焼制御手段を設けたことを特徴とする微粉炭の低NO
x燃焼装置。
5. A low pulverized coal low-valued coal product according to claim 4, wherein an oil combustion control means is provided in an amount corresponding to an excess of primary combustion air of the pulverized coal flow supplied to the pulverized coal burner. NO
x Combustion device.
JP3212994A 1994-03-02 1994-03-02 Method and apparatus for burning finely ground coal Pending JPH07243611A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3212994A JPH07243611A (en) 1994-03-02 1994-03-02 Method and apparatus for burning finely ground coal

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3212994A JPH07243611A (en) 1994-03-02 1994-03-02 Method and apparatus for burning finely ground coal

Publications (1)

Publication Number Publication Date
JPH07243611A true JPH07243611A (en) 1995-09-19

Family

ID=12350285

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3212994A Pending JPH07243611A (en) 1994-03-02 1994-03-02 Method and apparatus for burning finely ground coal

Country Status (1)

Country Link
JP (1) JPH07243611A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012112581A (en) * 2010-11-25 2012-06-14 Ihi Corp Boiler device
KR101249871B1 (en) * 2008-03-14 2013-04-02 얀타이 롱유안 파워 테크놀러지 컴퍼니 리미티드 A method for decreasing nitrogen oxides of a pulverized coal boiler using burners of internal combustion type
WO2014013559A1 (en) * 2012-07-18 2014-01-23 株式会社 日立製作所 Coal-fired power plant

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101249871B1 (en) * 2008-03-14 2013-04-02 얀타이 롱유안 파워 테크놀러지 컴퍼니 리미티드 A method for decreasing nitrogen oxides of a pulverized coal boiler using burners of internal combustion type
JP2012112581A (en) * 2010-11-25 2012-06-14 Ihi Corp Boiler device
WO2014013559A1 (en) * 2012-07-18 2014-01-23 株式会社 日立製作所 Coal-fired power plant

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