JPH07237124A - Surface processing method of mold - Google Patents

Surface processing method of mold

Info

Publication number
JPH07237124A
JPH07237124A JP2689394A JP2689394A JPH07237124A JP H07237124 A JPH07237124 A JP H07237124A JP 2689394 A JP2689394 A JP 2689394A JP 2689394 A JP2689394 A JP 2689394A JP H07237124 A JPH07237124 A JP H07237124A
Authority
JP
Japan
Prior art keywords
mold
blast
wet
glass
unevenness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2689394A
Other languages
Japanese (ja)
Other versions
JP3520545B2 (en
Inventor
Manabu Nidou
学 二藤
Yuji Furui
雄二 古居
Hiroshi Wakatsuki
若月  博
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to JP02689394A priority Critical patent/JP3520545B2/en
Publication of JPH07237124A publication Critical patent/JPH07237124A/en
Application granted granted Critical
Publication of JP3520545B2 publication Critical patent/JP3520545B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Manufacture Of Electron Tubes, Discharge Lamp Vessels, Lead-In Wires, And The Like (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

PURPOSE:To provide a glass product whose glass surface has few defects by equipping a dry type blast process in which the unevenness of a mold surface is apt to become sharp peaks but a uniform oxidized film can be generated, and a wet type blast process in which the unevenness of the mold surface is dulled without damaging the uniform oxidized film. CONSTITUTION:In the case of the surface processing (blast) of a mold to be used for the glass products or the like of a TV cathode-ray tube panel and a funnel or the like in a high temperature press industry field, by firstly administering a dry type blast process using a dry type blast material whose grain diameter is #100-#1000 (JIS standard JIS R600), a uniform oxidized film is generated although the unevenness of a mold surface is apt to become sharp peaks. Next, by administering a wet type blast process using wet type glass beads whose grain diameters are #100-#220, the unevenness of the mold surface is dulled without damaging the uniform oxidized film. In this instance, blast pressure at each blast process is set preferably within the range of 0.5-5.0kg/cm<2>.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、TVブラウン管用パネ
ルおよびファンネル等のガラス製品等の、高温プレス工
業分野に用いられる金型の表面処理(ブラスト)方法に
関し、高温条件で使用しても金型寿命(金型ライフ)を
長くできるようにするための金型の表面処理方法に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a surface treatment (blasting) method for molds used in the field of high temperature press industry such as glass for TV cathode ray tube panels and funnels. The present invention relates to a surface treatment method for a die for extending the die life (die life).

【0002】[0002]

【従来の技術】ブラスト方式には乾式ブラストと湿式ブ
ラストが存在することはよく知られた事実である。従来
は工程の簡素化の目的もあって、金型のブラストは乾式
か湿式のいずれかの工程を選択して行われていた。
2. Description of the Related Art It is a well known fact that dry blasting and wet blasting exist in blasting methods. Conventionally, for the purpose of simplifying the process, the mold blasting is performed by selecting either a dry process or a wet process.

【0003】[0003]

【発明が解決しようとする課題】しかし、湿式のみの工
程では、金型の表面に充分堅固で均質な酸化膜を予備生
成することができず、このためプレス中の不均一な高温
酸化に対して耐性がなく、容易に部分的な肌荒れを起こ
し金型寿命を低下させるという欠点があった。
However, in the wet-only process, it is not possible to pre-form a sufficiently strong and homogeneous oxide film on the surface of the mold, which prevents uneven high temperature oxidation during pressing. However, there is a drawback that the surface of the mold is easily roughened and the mold life is shortened.

【0004】また、乾式のみの工程では、金型表面の粗
度のピークが鋭すぎてガラス表面に欠点を生成したり、
ブラスト後の洗浄が不十分であるとコンタミネーショ
ン、すなわち破砕、細粒化したブラスト材の金型表面へ
の固着、吸着による残存の原因となることがあった。
Further, in the dry process only, the peak of the roughness of the mold surface is too sharp, and defects are generated on the glass surface.
Insufficient cleaning after blasting may cause contamination, that is, crushing and sticking of finely pulverized blast material to the mold surface, and residual due to adsorption.

【0005】[0005]

【課題を解決するための手段】本発明は、このような従
来技術の欠点を解消すべくなされたものであり、粒径が
#10〜#220番(JIS規格JIS R6001に
よる)の湿式用グラスビーズを用いた湿式ブラスト工程
と、粒径が#100〜#1000番の乾式用ブラスト材
を用いた乾式ブラスト工程との2種類の工程を少なくと
も含んでなることを特徴とする金型の表面処理方法を提
供するものである。
The present invention has been made to solve the above-mentioned drawbacks of the prior art, and a wet type glass having a particle size of # 10 to # 220 (according to JIS standard JIS R6001). Surface treatment of a mold comprising at least two types of steps, a wet blasting step using beads and a dry blasting step using a dry blasting material having a particle size of # 100 to # 1000. It provides a method.

【0006】また本発明においては、前記湿式ブラスト
工程および乾式ブラスト工程におけるブラスト圧力が
0.5〜5.0kg/cm2 であることが好ましい。ブ
ラスト圧力が0.5kg/cm2 より小さいと金型表面
がスティップルむらになりやすいため好ましくない。ま
た、5.0kg/cm2 より大きいとブラスト材のグラ
スビーズが破砕されてしまい、グラスビーズを繰り返し
使用しているのでその粒度分布が変わってくるため、所
望のRz (平均表面粗さ)が得られなくなる。また金型
表面のメッキ層(10μm〜20μm)も剥離させてし
まうので、5.0kg/cm2 以下が好ましい。
Further, in the present invention, it is preferable that the blast pressure in the wet blast process and the dry blast process is 0.5 to 5.0 kg / cm 2 . If the blast pressure is less than 0.5 kg / cm 2 , the mold surface is likely to have uneven stipple, which is not preferable. Further, if it is larger than 5.0 kg / cm 2, the glass beads of the blast material will be crushed and the particle size distribution will change because the glass beads are repeatedly used, so the desired R z (average surface roughness) Will not be obtained. Further, the plating layer (10 μm to 20 μm) on the surface of the mold is also peeled off, so 5.0 kg / cm 2 or less is preferable.

【0007】さらに、第1段目が前記乾式ブラスト工程
で、第2段目が前記湿式ブラスト工程であることが好ま
しい。
Further, it is preferable that the first stage is the dry blast process and the second stage is the wet blast process.

【0008】[0008]

【作用】本発明において、複数ブラスト工程のうちの前
段の乾式ブラストはドライであるがゆえに金型表面が高
温になり、均一な酸化膜を生成させる。ひとたび生成さ
れた酸化膜は非常に安定で、その後の不均一な酸化作
用、すなわち不均一な酸素の酸化に対して良好な保護障
壁となる。そのため、前処理のない湿式の単一工程に比
べて金型ライフを飛躍的に延長させることができる。
In the present invention, since the dry blast in the preceding stage of the plural blasting steps is dry, the surface of the die becomes hot and a uniform oxide film is formed. The oxide film, once formed, is very stable and provides a good protective barrier against the subsequent non-uniform oxidation action, ie non-uniform oxidation of oxygen. Therefore, the life of the die can be dramatically extended as compared with a wet single process without pretreatment.

【0009】また、これだけでは鋭利な凹凸面によりガ
ラスの面欠点が出やすいので、これを克服するために後
段の湿式グラスビーズ工程を用いることにより、鈍化し
た面とさせ、欠点のないガラス製品を成型することがで
きる。
Also, since this alone tends to cause surface defects of the glass due to the sharp uneven surface, a wet glass bead process in the subsequent stage is used to overcome this, thereby making the glass product a dull surface and providing a glass product having no defects. It can be molded.

【0010】[0010]

【実施例】以下に本発明の実施例を説明する。従来の単
一工程の湿式グラスビーズ工程では、どうしても金型ラ
イフが短いという欠点があったので、これに乾式工程を
組み合わせ複数ブラスト工程にすることで金型ライフの
延長を果たすことができる。
EXAMPLES Examples of the present invention will be described below. The conventional single-step wet glass bead process has a drawback that the mold life is inevitably short. Therefore, the mold life can be extended by combining this with a dry process to form a plurality of blast processes.

【0011】複数ブラスト工程としては2段式ブラスト
工程が好ましく、2段式において好ましい順序の組み合
わせは、1段目が乾式、2段目が湿式の順である。ガラ
スをプレス成型する際には金型面の凹凸は適度に鈍化し
ていることが肝要で、鋭角なピークを持っていると容易
に面欠点となる。湿式グラスビーズは球形をしており、
金型面の凹凸を鈍化させるのに適しているため、前述の
ような順序が好ましいことになる。また、1段目に乾式
工程をもってきた場合、ひとたび形成された均一酸化膜
は次の湿式工程によってその性質を損なわれるものでは
ないことが知られており、所期の目的を達成することが
可能である。
The multiple blasting process is preferably a two-stage blasting process, and the preferred combination of the two-stage blasting process is the first stage is dry and the second stage is wet. When press-molding glass, it is important that the irregularities on the die surface are moderately blunted, and if there are sharp peaks, it easily becomes a surface defect. Wet glass beads have a spherical shape,
The order as described above is preferable because it is suitable for making unevenness on the die surface dull. In addition, it is known that when the dry process is performed in the first stage, the uniform oxide film once formed does not lose its properties in the next wet process, and it is possible to achieve the intended purpose. Is.

【0012】また、3段目に湿式をもってくることによ
り1段目で生じうるコンタミネーションを洗浄し除去す
ることができるという効果もある。
Further, there is an effect that the contamination which may occur in the first stage can be washed and removed by bringing the wet process into the third stage.

【0013】しかし、コンタミネーションに留意したう
えで粒径の小さな乾式用ブラスト材(#600〜#10
00番)を選んだ場合には、1段目に湿式、2段目に乾
式を適用しても問題は生じない。その場合には、いわゆ
る粗度を出すためのブラスト機能は1段目の湿式グラス
ビーズにより達成されるからである。
However, in consideration of contamination, a dry blast material (# 600 to # 10) having a small particle size.
If No. 00) is selected, there is no problem even if the wet method is applied to the first step and the dry method is applied to the second step. This is because, in that case, the so-called blast function for producing roughness is achieved by the first-stage wet glass beads.

【0014】次に、好ましいブラスト材とその粒径、処
理圧力について以下に記述する。乾式用ブラスト材とし
てはガーネットまたはアランダムが好ましい。その理由
は、鋭利な形状をしているため、球形に比べて金型表面
に食い込むような作用が強く、表面での反発によるエネ
ルギー伝達ロスが小さいため、容易に均一な酸化膜を形
成しうるからである。粒径は#100〜#1000番
(JIS規格JIS R6001による)、ブラスト圧
力は0.5〜5.0kg/cm2 が好ましい。
Next, the preferred blast material, its particle size and processing pressure will be described below. Garnet or alundum is preferred as the dry blast material. The reason for this is that since it has a sharp shape, it has a stronger effect of biting into the mold surface than a spherical shape, and energy transfer loss due to repulsion on the surface is small, so a uniform oxide film can be easily formed. Because. The particle size is preferably # 100 to # 1000 (according to JIS standard JIS R6001), and the blast pressure is preferably 0.5 to 5.0 kg / cm 2 .

【0015】一方、湿式用ブラスト材としては既述のと
おり、鋭利なピークを鈍化させるのに適した球形状を持
つグラスビーズが好ましい。また、粒径は#10〜#2
20番が好ましく、ブラスト圧力は0.5〜5.0kg
/cm2 が好ましい。
On the other hand, as described above, as the wet blast material, glass beads having a spherical shape suitable for blunting a sharp peak are preferable. The particle size is # 10 to # 2.
No. 20 is preferable, blast pressure is 0.5 to 5.0 kg
/ Cm 2 is preferred.

【0016】第1段目に#150番の乾式用ブラスト材
(アランダム)を用い、ブラスト圧力1.5kg/cm
2 で乾式ブラスト工程を行った。具体的には、乾式ブラ
スト装置を用い、ステンレス製の金型(TVブラウン管
ガラス成型用プランジャー:雄型)の表面に向かって前
記乾式用ブラスト材を12分間0.3mの距離から噴射
した。ブラスト材の噴射方向は金型の表面に対して略垂
直であり、金型の表面全面を走査するようにして乾式ブ
ラスト処理を行った。
The first stage uses # 150 dry blast material (alundum) and the blast pressure is 1.5 kg / cm.
The dry blasting process was performed at 2 . Specifically, using a dry blast device, the dry blast material was jetted from a distance of 0.3 m for 12 minutes toward the surface of a stainless mold (TV CRT glass molding plunger: male mold). The injection direction of the blast material was substantially perpendicular to the surface of the mold, and the dry blast treatment was performed by scanning the entire surface of the mold.

【0017】第2段目に#80番の湿式用グラスビーズ
を用い、ブラスト圧力2.5kg/cm2 で湿式ブラス
ト工程を行った。具体的には、湿式ブラスト装置(フジ
キカイ製)を用い、ステンレス製の金型の表面に向かっ
て前記湿式用グラスビーズを20分間0.6mの距離か
ら噴射した。グラスビーズの噴射方向は金型の表面に対
して略垂直であり、金型の表面全面を、1サイクル10
分で2サイクル20分走査するようにして湿式ブラスト
処理を行った。湿式ブラスト工程では、グラスビーズは
溶媒の水に30体積%の割合で混合し分散液とされ、ブ
ラスト処理時にはその溶媒とともに金型表面に向かって
噴射される。
A wet blasting process was carried out in the second stage using # 80 wet type glass beads at a blasting pressure of 2.5 kg / cm 2 . Specifically, a wet blast device (made by Fujikikai) was used to spray the wet glass beads toward the surface of a stainless steel mold for 20 minutes from a distance of 0.6 m. The injection direction of the glass beads is substantially perpendicular to the surface of the mold, and the entire surface of the mold is covered by 10 cycles per cycle.
Wet blasting was performed by scanning for 2 cycles of 20 minutes per minute. In the wet blasting process, glass beads are mixed with water as a solvent at a ratio of 30% by volume to form a dispersion liquid, which is sprayed toward the mold surface together with the solvent during the blasting process.

【0018】このとき、金型(プランジャー)はその成
型面(凸面)が上向きとされ、17rpmの回転速度で
回転している。金型を回転させつつ、垂直ガン3本によ
り上方から前記のようにブラスト材を噴射し、かつ水平
ガン1本により水平方向からもブラスト材を噴射して湿
式ブラスト処理を完了した。前記の水平方向からのブラ
スト処理は、金型の側面を重点的に処理するために行う
ものであり、垂直方向からのブラスト処理とほぼ同様の
条件で行っている。
At this time, the mold (plunger) has its molding surface (convex surface) facing upward and is rotating at a rotation speed of 17 rpm. While rotating the mold, the blasting material was sprayed from above with three vertical guns from above, and the blasting material was sprayed from one horizontal gun also from the horizontal direction to complete the wet blasting treatment. The above-mentioned blasting treatment from the horizontal direction is performed in order to intensively treat the side surface of the mold, and is performed under substantially the same conditions as the blasting treatment from the vertical direction.

【0019】前記のような処理を行うことにより、金型
ライフが従来の約3倍以上に延びた。さらに、適切な湿
式グラスビーズ径を選定し、適度な粗度にすることによ
り金型ライフは従来の10倍を超えることも可能であ
る。
By performing the above-mentioned treatment, the life of the mold is extended to about 3 times or more of the conventional one. Further, by selecting an appropriate wet glass bead diameter and making it have an appropriate roughness, the mold life can exceed 10 times that of the conventional one.

【0020】[0020]

【発明の効果】本発明は、金型表面の凹凸が鋭いピーク
になりやすいが均一な酸化膜が生成可能な乾式ブラスト
工程と、金型面の凹凸を鈍化させ均一酸化膜を損なわな
い湿式ブラスト工程とを組み合わせることにより、プレ
ス成型後のガラス表面に欠点の少ないTVブラウン管用
パネル、ファンネル等のガラス製品が製造できる。ま
た、プレス中の不均一な高温酸化に対しても耐性があ
り、金型表面のコンタミネーションも解消されるので、
金型寿命も従来に比べて飛躍的に延びるという優れた効
果を有する。
Industrial Applicability According to the present invention, the dry blasting step in which the unevenness of the mold surface is likely to have a sharp peak but a uniform oxide film can be produced, and the wet blasting in which the unevenness of the mold surface is blunted and the uniform oxide film is not damaged. By combining with the process, glass products such as TV cathode ray tube panels and funnels with few defects on the glass surface after press molding can be manufactured. In addition, it has resistance to uneven high temperature oxidation during pressing, and the contamination of the mold surface is eliminated,
It has an excellent effect that the life of the mold is dramatically extended as compared with the conventional one.

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】粒径が#10〜#220番の湿式用グラス
ビーズを用いた湿式ブラスト工程と、粒径が#100〜
#1000番の乾式用ブラスト材を用いた乾式ブラスト
工程との2種類の工程を少なくとも含んでなることを特
徴とする金型の表面処理方法。
1. A wet blasting process using wet glass beads having a particle size of # 10 to # 220, and a particle size of # 100 to # 100.
A surface treatment method for a die, comprising at least two types of steps, a dry blasting step using a # 1000 dry blasting material.
【請求項2】前記湿式ブラスト工程および乾式ブラスト
工程におけるブラスト圧力が0.5〜5.0kg/cm
2 である請求項1記載の金型の表面処理方法。
2. The blast pressure in the wet blasting step and the dry blasting step is 0.5 to 5.0 kg / cm.
2. The term claim 1 surface treatment method of a mold according.
【請求項3】第1段目が前記乾式ブラスト工程で、第2
段目が前記湿式ブラスト工程である請求項1または2記
載の金型の表面処理方法。
3. The first stage is the dry blasting process, and the second stage is
The mold surface treatment method according to claim 1, wherein the step is the wet blasting step.
JP02689394A 1994-02-24 1994-02-24 Mold surface treatment method Expired - Fee Related JP3520545B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP02689394A JP3520545B2 (en) 1994-02-24 1994-02-24 Mold surface treatment method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP02689394A JP3520545B2 (en) 1994-02-24 1994-02-24 Mold surface treatment method

Publications (2)

Publication Number Publication Date
JPH07237124A true JPH07237124A (en) 1995-09-12
JP3520545B2 JP3520545B2 (en) 2004-04-19

Family

ID=12205935

Family Applications (1)

Application Number Title Priority Date Filing Date
JP02689394A Expired - Fee Related JP3520545B2 (en) 1994-02-24 1994-02-24 Mold surface treatment method

Country Status (1)

Country Link
JP (1) JP3520545B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000063942A1 (en) * 1999-04-21 2000-10-26 Schott Glas Picture tube funnel, method for producing said picture tube funnel and device for carrying out the method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000063942A1 (en) * 1999-04-21 2000-10-26 Schott Glas Picture tube funnel, method for producing said picture tube funnel and device for carrying out the method

Also Published As

Publication number Publication date
JP3520545B2 (en) 2004-04-19

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