JPH07223209A - Fibrous molding and manufacture thereof - Google Patents

Fibrous molding and manufacture thereof

Info

Publication number
JPH07223209A
JPH07223209A JP3771294A JP3771294A JPH07223209A JP H07223209 A JPH07223209 A JP H07223209A JP 3771294 A JP3771294 A JP 3771294A JP 3771294 A JP3771294 A JP 3771294A JP H07223209 A JPH07223209 A JP H07223209A
Authority
JP
Japan
Prior art keywords
molding
binder
die
mold
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP3771294A
Other languages
Japanese (ja)
Inventor
Shigeru Yoshihara
茂 吉原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TOYO YUATSU KOGYO KK
Original Assignee
TOYO YUATSU KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TOYO YUATSU KOGYO KK filed Critical TOYO YUATSU KOGYO KK
Priority to JP3771294A priority Critical patent/JPH07223209A/en
Publication of JPH07223209A publication Critical patent/JPH07223209A/en
Withdrawn legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a molding with the same degree of density as a polystyrene foam using a fibrous material. CONSTITUTION:A space between the inner force 2 and the outer force 3 of a molding die l is filled with a molding material 4 consisting of a mixture of a fiber and a binder to such a range of final density of 12g/l to 50g/l. In addition, a medium of such a nature as to cure or dry a binder in a molding material is sprayed through the porous die face 2A of the inner force 2 and/or the outer force 3, so that the binder becomes cured or dried.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は例えばインシュレーショ
ンボード、包装材等に用いられる繊維成形物およびその
製造方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fiber molding used for insulation boards, packaging materials and the like, and a method for producing the same.

【0002】[0002]

【発明の背景】従来、インシュレーションボード、包装
材等にはポリスチレン発泡体が使用されている。しかし
ながら上記ポリスチレン発泡体はスクラップの処理が問
題となる。例えば上記ポリスチレン発泡体を溶融して成
形用ペレットとして再利用するにしてもポリスチレン成
形物の需要量は上記ポリスチレン発泡体のスクラップ量
に比して極て僅かである。したがってポリスチレン発泡
体スクラップは大半は焼却処理されるが、該ポリスチレ
ン発泡体スクラップは炭素を多く含有し、焼却の際に多
量の黒煙を発生し環境を汚染する。
BACKGROUND OF THE INVENTION Polystyrene foam is conventionally used for insulation boards, packaging materials and the like. However, the above polystyrene foam has a problem in scrap processing. For example, even if the polystyrene foam is melted and reused as pellets for molding, the demand amount of the polystyrene molded product is extremely small compared to the scrap amount of the polystyrene foam. Therefore, most of the polystyrene foam scrap is incinerated, but the polystyrene foam scrap contains a large amount of carbon, and when incinerated, produces a large amount of black smoke and pollutes the environment.

【0003】[0003]

【従来の技術】従来上記ポリスチレン発泡体に代わる材
料として、最近では故紙パルプの繊維をバインダーで結
着した成形物が提供されている。該故紙パルプは焼却し
ても黒煙を発生せず、また生物学的分解も可能であって
その生物学的分解物は堆肥として利用される。従来上記
故紙パルプ等の繊維の成形物は繊維スラリーからの抄造
法、繊維とバインダーとの混合物をプレス成形する乾式
法ないしは半乾式法等によって製造される。
2. Description of the Related Art Recently, as a material to replace the above polystyrene foam, a molded article obtained by binding fibers of waste paper pulp with a binder has been provided. The waste paper pulp does not generate black smoke even when incinerated, and can be biodegraded, and the biodegraded product is used as compost. Conventionally, molded articles of fibers such as the above waste paper pulp are produced by a papermaking method from a fiber slurry, a dry method or a semi-dry method of press-molding a mixture of fibers and a binder, and the like.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、上記抄
造法は製造、特に乾燥工程において手間がかかり、また
ポリスチレン発泡体に相当するような低密度のものが得
られないし、上記乾式法または半乾式法においても、バ
インダーを硬化または乾燥せしめるためにホットプレス
の際の圧縮率を高くしなければならず、これらの方法に
おいてもポリスチレン発泡体に相当するような低密度の
ものが得られない。
However, the above-mentioned papermaking method is troublesome in production, particularly in the drying step, and it is not possible to obtain a low-density one which is equivalent to polystyrene foam, and the above-mentioned dry method or semi-dry method is used. Also, in order to cure or dry the binder, the compressibility at the time of hot pressing must be increased, and even with these methods, a low density such as polystyrene foam cannot be obtained.

【0005】[0005]

【課題を解決するための手段】本発明は上記従来の課題
を解決するための手段として、繊維をバインダーで結着
して所望形状に成形した多孔質成形体(5) であって、密
度が12g/lから50g/lの範囲である繊維成形物
(5) を提供するものであり、内型(2) と外型(3) とから
なり、外型(2) および/または内型(3) の型面(2A,3A)
が多孔にされている成形型(1) を用い、該成形型(1) の
内型(2) と外型(3) との間に繊維とバインダーとの混合
物からなる成形材料(4) を密度が最終的に12g/lか
ら50g/lになるように充填すると共に該内型(2) お
よび/または該外型(3) の多孔型面(2A,3A) から該バイ
ンダーを硬化および/または乾燥せしめるような媒体を
該成形材料(4) に吹付けることによって該成形材料(4)
のバインダーを硬化および/または乾燥せしめる繊維成
形物(5) の製造方法を提供するものである。
Means for Solving the Problems As a means for solving the above-mentioned conventional problems, the present invention provides a porous molded article (5) obtained by binding fibers with a binder to form a desired shape. Fiber moldings in the range of 12 g / l to 50 g / l
(5), which is composed of an inner mold (2) and an outer mold (3), and a mold surface (2A, 3A) of the outer mold (2) and / or the inner mold (3).
Using a mold (1) having a porous structure, a molding material (4) consisting of a mixture of fibers and a binder is placed between the inner mold (2) and the outer mold (3) of the mold (1). It is packed so that the final density is 12 g / l to 50 g / l, and the binder is cured and / or cured from the porous mold surface (2A, 3A) of the inner mold (2) and / or the outer mold (3). Alternatively, the molding material (4) is sprayed onto the molding material (4) by drying it.
The present invention provides a method for producing a fiber molded product (5), which comprises curing and / or drying the above binder.

【0006】本発明において用いられる繊維としては、
例えばパルプ、木毛、木片、更に故紙をほぐした故紙パ
ルプ等の木質繊維、ポリエステル繊維、ポリプロピレン
繊維、ポリアミド繊維、アクリル繊維、アセテート繊
維、木綿等の有機繊維、ガラス繊維、セラミック繊維、
炭素繊維等の無機繊維、あるいは上記有機または無機繊
維からなるカーペット、フェルト、不織布等のスクラッ
プを解繊して得られる再生繊維等があり、上記繊維は二
種類以上混合されてもよい。上記繊維のうち好ましいも
のとしては故紙を解繊することによって得られる故紙パ
ルプがある。
The fibers used in the present invention include:
For example, pulp, wood wool, wood chips, wood fibers such as waste paper pulp obtained by loosening waste paper, polyester fibers, polypropylene fibers, polyamide fibers, acrylic fibers, acetate fibers, organic fibers such as cotton, glass fibers, ceramic fibers,
There are inorganic fibers such as carbon fibers, or recycled fibers obtained by defibrating scraps such as carpets, felts, and nonwoven fabrics made of the above organic or inorganic fibers, and the above fibers may be mixed in two or more kinds. Among the above fibers, preferred one is waste paper pulp obtained by defibrating waste paper.

【0007】上記繊維には所望なれば、ポリスチレン、
ポリエチレン、ポリプロピレン、ポリエステル、ボリア
ミド、ポリ塩化ビニル、ポリ塩化ビニリデン等のプラス
チックまたは上記プラスチック発泡体のチップ、ハード
ボード、パーチクルボード、合板等のチップを一種また
は二種以上混合してもよい。
For the above fibers, if desired, polystyrene,
Chips of plastics such as polyethylene, polypropylene, polyester, polyamide, polyvinyl chloride, polyvinylidene chloride or the above plastic foam, hard boards, particle boards, chips such as plywood may be used alone or in combination of two or more.

【0008】上記繊維を結着するために用いられるバイ
ンダーとしては、例えばフェノール樹脂、尿素樹脂、メ
ラミン樹脂、ウレタン樹脂、エポキシ樹脂、アクリル樹
脂、ポリエチレン、ポリプロピレン、デンプン、エーテ
ル化デンプン等の変性デンプン、ロジン等の合成樹脂バ
インダーあるいは天然樹脂バインダー、あるいはウレタ
ンプレポリマー、エポキシプレポリマー、フェノールプ
レポリマー、尿素プレポリマー、メラミンプレポリマ
ー、アクリルオリゴマー、多価イソシアナート、アクリ
ルモノマー等のプレポリマー、オリゴマー、モノマー等
の合成樹脂前駆体が使用される。上記バインダーは二種
以上混合されてもよい。上記バインダーは通常粉体、液
体、溶液、エマルジョン等の形態で提供されるが、上記
繊維に対する上記バインダーの添加量は通常固形分とし
て10〜50重量%程度とする。しかしながらこの添加
量は製品に要求される物性等によって適宜調節されるべ
きであって、上記範囲は本発明を限定するものではな
い。
As the binder used for binding the above fibers, for example, phenol resin, urea resin, melamine resin, urethane resin, epoxy resin, acrylic resin, polyethylene, polypropylene, starch, modified starch such as etherified starch, Synthetic resin binder such as rosin or natural resin binder, or urethane prepolymer, epoxy prepolymer, phenol prepolymer, urea prepolymer, melamine prepolymer, acrylic oligomer, polyvalent isocyanate, prepolymer such as acrylic monomer, oligomer, monomer Synthetic resin precursors such as Two or more of the above binders may be mixed. The binder is usually provided in the form of powder, liquid, solution, emulsion or the like, and the amount of the binder added to the fibers is usually about 10 to 50% by weight as solid content. However, the addition amount should be appropriately adjusted depending on the physical properties required for the product, and the above range does not limit the present invention.

【0009】[0009]

【作用】本発明においては、繊維とバインダーとの混合
物からなる成形材料(4) を成形型(1) の内型(2) と外型
(3) との間に最終的に密度が12g/lから50g/lの
範囲になるように充填する。そして内型(2) および/ま
たは外型(3) の多孔型面(2A,3A) から該バインダーを硬
化または乾燥せしめるような媒体を該成形材料(4) に吹
付けることによって該成形材料(4) 中のバインダーを硬
化および/または乾燥せしめる。したがってバインダー
を硬化および/または乾燥せしめるために圧縮率を高く
するためのプレスを適用する必要はないから、ポリスチ
レン発泡体と同程度の密度12g/lから50g/lの
範囲の成形物(5) が容易に得られる。
In the present invention, a molding material (4) made of a mixture of fibers and a binder is used to form an inner mold (2) and an outer mold of a molding die (1).
Between (3) and (3), the final density is in the range of 12 g / l to 50 g / l. Then, the molding material (4) is sprayed with a medium for curing or drying the binder from the porous surfaces (2A, 3A) of the inner mold (2) and / or the outer mold (3). 4) Cure and / or dry the binder inside. Therefore, since it is not necessary to apply a press for increasing the compression ratio in order to cure and / or dry the binder, a molded product having a density in the range of 12 g / l to 50 g / l, which is similar to that of polystyrene foam (5) Is easily obtained.

【0010】[0010]

【実施例】本発明の第1実施例を図1〜図3によって説
明する。図に示す成形型(1) は内型(2) と外型(3) とか
らなり、該内型(2) の型面(2A)は多孔とされており、該
内型(2) 内には媒体導入口(2B)が連絡している。該外型
(3) の型面(3A)は多孔とされており、該外型(3) 内には
図示しない吸引ポンプ、吸引ファン、イジェクター等の
吸引手段が接続している吸引経路(3B)が連絡しており、
更にミキシングタンク(6) の底部から差出されている成
形材料供給経路(3C)が連絡しており、該ミキシングタン
ク(6) には攪拌機(6A)が備えられており、該供給経路(3
C)の外型(3) との連絡部分付近には外型(3) 内部方向に
向って圧力空気を吹込むブローパイプ(7) が連絡してい
る。上記成形型(1) において繊維成形物(5) を成形する
には、ミキシングタンク(6) において、バインダーとし
て10重量%のエーテル化デンプンと10重量%の水を
混合した故紙パルプ混合物からなる成形材料(4) を調製
し、図1に示すように内型(2) を外型(3) 内に下降させ
て所定の間隔を保ち、該ブローパイプ(7) から圧力空気
を該内型(2) と該外型(3) との間の空間(8) に向って吹
付け、更に吸引経路(3B)によって外型(3) の多孔型面(3
A)を介して該空間(8) 内を吸引し、図2に示すように該
内型(2) と該外型(3) との間の空間(8) 内に該成形材料
(4) を充填する。この際の圧力空気の圧力および吸引圧
は最終成形物の密度が25g/lになるように調節し、
それからブローパイプ(7) からの圧力空気の吹付けを止
めるとともに該内型(2) 内には媒体導入口(2B)から12
0℃の熱風を導入し、多孔型面(2A)から該成形材料(4)
に吹付ける。該熱風は該成形材料(4) の内部を通過して
該成形材料(4) 内に含まれている水分を蒸発させ、該成
形材料(4) を乾燥硬化させそして該熱風は下型(3) の多
孔型面(3A)を介して吸引パイプ(3B)に吸引され、このよ
うにして成形物(5) が成形される。成形物(5) を成形し
た後は内型(2) を上昇させて成形型(1) を開き、外型
(3)内から成形物(5) を取出す。このようにして図3に
示すようなインシュレーションボード等に使用出来る密
度25g/lのパネル状成形物(5) が製造される。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A first embodiment of the present invention will be described with reference to FIGS. The molding die (1) shown in the figure consists of an inner die (2) and an outer die (3), and the die surface (2A) of the inner die (2) is porous, and the inner die (2) The medium introduction port (2B) is in contact with. The outer mold
The mold surface (3A) of (3) is made porous, and the suction path (3B) to which suction means such as a suction pump, a suction fan, and an ejector (not shown) are connected is connected to the inside of the outer mold (3). And
Further, the molding material supply path (3C) extended from the bottom of the mixing tank (6) is connected to the mixing tank (6), and the mixing tank (6) is equipped with an agitator (6A).
A blow pipe (7) for injecting compressed air toward the inside of the outer mold (3) is connected near the part where the outer mold (3) of C) is connected. For molding the fiber molding (5) in the molding die (1), a mixing tank (6) is composed of a waste paper pulp mixture in which 10% by weight of etherified starch and 10% by weight of water are mixed as a binder. The material (4) is prepared, and as shown in FIG. 1, the inner mold (2) is lowered into the outer mold (3) to maintain a predetermined space, and pressurized air is blown from the blow pipe (7) to the inner mold (3). It is sprayed toward the space (8) between the outer mold (2) and the outer mold (3), and the suction path (3B) is used to blow the porous mold surface (3
The inside of the space (8) is sucked through A), and the molding material is introduced into the space (8) between the inner mold (2) and the outer mold (3) as shown in FIG.
Fill (4). At this time, the pressure of the compressed air and the suction pressure are adjusted so that the density of the final molded product is 25 g / l,
Then, the blowing of the pressure air from the blow pipe (7) is stopped and the medium introduction port (2B) is inserted into the inner mold (2) from the medium introduction port (2B).
The molding material (4) was introduced from the porous mold surface (2A) by introducing hot air at 0 ° C.
Spray on. The hot air passes through the inside of the molding material (4) to evaporate the water contained in the molding material (4), dry and cure the molding material (4), and the hot air blows the lower mold (3 (3) is sucked into the suction pipe (3B) through the porous surface (3A), and thus the molded product (5) is molded. After molding the molded product (5), raise the inner mold (2) to open the mold (1),
Remove the molded product (5) from inside (3). Thus, a panel-shaped molded product (5) having a density of 25 g / l which can be used for an insulation board as shown in FIG. 3 is manufactured.

【0011】本発明の第2実施例を図4〜図6によって
説明する。図に示す成形型(11)は内型(12)と外型(13)と
からなり、該内型(12)の型面(12A) は多孔にされてお
り、該内型(12)内には吸引ポンプあるいはイジェクター
等の吸引手段に接続している吸引経路(12B) が連絡して
おり、更に該外型(13)の型面(13A) は多孔にされてお
り、該外型(13)内には媒体導入口(13B) が連絡してい
る。上記外型(13)内には図4に示すようにバインダーと
して30重量%のフェノール樹脂を混合した再生繊維混
合物からなる成形材料(14)を充填し、図5に示すように
内型(12)を下降させて該内型(12)と該外型(13)との間で
該成形材料(14)を軽くプレスする。この際のプレス圧は
最終密度が40g/lになるように調節し、該外型(13)
内には媒体導入口(13B) から180℃の熱風が導入さ
れ、多孔型面(13A) から成形材料(4) に吹付けられる。
該熱風は該成形材料(14)の内部を通過して該成形材料(1
4)内に含まれているフェノール樹脂を硬化させ内型(12)
の多孔型面(12A) を介して吸引パイプ(12B) に吸引さ
れ、このようにして成形物(15)が形成される。成形物(1
5)を成形した後は内型(12)を上昇させて成形型(11)を開
き、外型(13)内から成形物(15)を取出す。このようにし
て図6に示すような包装容器等に使用出来る密度40g
/lの箱形成形物(15)が製造される。
A second embodiment of the present invention will be described with reference to FIGS. The molding die (11) shown in the figure consists of an inner die (12) and an outer die (13), the die surface (12A) of the inner die (12) is made porous, and the inner die (12) A suction path (12B) connected to a suction means such as a suction pump or an ejector is connected to the outer mold (13A), and the mold surface (13A) of the outer mold (13) is made porous. The medium inlet (13B) communicates with the inside of 13). As shown in FIG. 4, the outer mold (13) is filled with a molding material (14) made of a recycled fiber mixture in which 30% by weight of a phenol resin is mixed as a binder, and as shown in FIG. ) Is lowered and the molding material (14) is lightly pressed between the inner mold (12) and the outer mold (13). The press pressure at this time is adjusted so that the final density is 40 g / l, and the outer mold (13)
Hot air at 180 ° C. is introduced into the inside from the medium introduction port (13B), and is blown onto the molding material (4) from the porous mold surface (13A).
The hot air passes through the inside of the molding material (14) and the molding material (1
4) Harden the phenolic resin contained in the inner mold (12)
It is sucked into the suction pipe (12B) through the porous surface (12A), and thus the molded product (15) is formed. Molded product (1
After molding 5), the inner mold (12) is raised to open the molding mold (11), and the molded product (15) is taken out from the outer mold (13). In this way, a density of 40 g that can be used for packaging containers such as those shown in FIG.
/ L box-shaped mold (15) is produced.

【0012】上記実施例以外、例えば第1実施例で成形
材料(4) に水分を添加しない場合には、内型(2) の多孔
型面(2A)から水蒸気を吹出し、該成形材料(4) に含まれ
るバインダーとしてのエーテル化デンプンを膨潤させる
ことによって故紙パルプを結着してもよい。この場合、
水蒸気吹出しに次いで熱風吹出しを行なって乾燥を成形
型(1) 内で行なってもよい。更に第2実施例では該成形
材料(14)に含まれるフェノール樹脂の硬化触媒(酸また
はアルカリ)を熱風に混合して吹出させてもよい。
When water is not added to the molding material (4) in the first embodiment other than the above-mentioned embodiments, water vapor is blown out from the porous mold surface (2A) of the inner mold (2) to form the molding material (4). The waste paper pulp may be bound by swelling the etherified starch as a binder contained in (1). in this case,
Drying may be performed in the molding die (1) by blowing hot air and then blowing hot air. Further, in the second embodiment, the phenol resin curing catalyst (acid or alkali) contained in the molding material (14) may be mixed with hot air and blown out.

【0013】[0013]

【発明の効果】したがって本発明においては繊維を成形
材料として使用して、ポリスチレン発泡体の密度と同等
な密度を有する成形物が容易に得られる。
Therefore, in the present invention, by using fibers as a molding material, a molded product having a density similar to that of polystyrene foam can be easily obtained.

【図面の簡単な説明】[Brief description of drawings]

図1〜図3は本発明の第1実施例を示すものである。 1 to 3 show a first embodiment of the present invention.

【図1】成形前説明断面図FIG. 1 is an explanatory cross-sectional view before molding

【図2】成形後説明断面図FIG. 2 is an explanatory cross-sectional view after molding

【図3】成形物斜視図 図4〜図6は本発明の第2実施例を示すものである。FIG. 3 is a perspective view of a molded product. FIGS. 4 to 6 show a second embodiment of the present invention.

【図4】成形前説明断面図FIG. 4 is an explanatory cross-sectional view before molding

【図5】成形後説明断面図FIG. 5 is an explanatory cross-sectional view after molding

【図6】成形物斜視図FIG. 6 is a perspective view of a molded product.

【符号の説明】[Explanation of symbols]

1,11 成形型 2,12 内型 3,13 外型 2A,3A,12A,13A 多孔型面 4,14 成形材料 5,15 成形物 1,11 Mold 2,12 Inner mold 3,13 Outer mold 2A, 3A, 12A, 13A Porous mold surface 4,14 Molding material 5,15 Molded product

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】繊維をバインダーで結着して所望形状に成
形した多孔質成形体であって、密度が12g/lから5
0g/lの範囲であることを特徴とす繊維成形物
1. A porous molded body obtained by binding fibers with a binder to form a desired shape, and having a density of 12 g / l to 5
Fiber molding characterized by being in the range of 0 g / l
【請求項2】該繊維は故紙パルプである請求項1に記載
の繊維成形物
2. The fiber molding according to claim 1, wherein the fiber is waste paper pulp.
【請求項3】内型と外型とからなり、外型および/また
は内型の型面が多孔にされている成形型を用い、該成形
型の内型と外型との間に繊維とバインダーとの混合物か
らなる成形材料を密度が最終的に12g/lから50g
/lになるように充填すると共に該内型および/または
該外型の多孔型面から該バインダーを硬化および/また
は乾燥せしめるような媒体を該成形材料に吹付けること
によって該成形材料のバインダーを硬化および/または
乾燥せしめることを特徴とする繊維成形物の製造方法
3. A molding die comprising an inner die and an outer die, wherein the die surface of the outer die and / or the inner die is porous, and fibers are provided between the inner die and the outer die of the die. Molding material consisting of a mixture with a binder, the final density of which is 12 g / l to 50 g
The binder of the molding material is sprayed onto the molding material with a medium such that the mixture is filled to be 1 / l and the curing and / or drying of the binder is performed from the porous mold surface of the inner mold and / or the outer mold. A method for producing a fiber molding, which comprises curing and / or drying
【請求項4】該繊維は故紙パルプである請求項3に記載
の繊維成形物の製造方法
4. The method for producing a fiber molding according to claim 3, wherein the fiber is waste paper pulp.
JP3771294A 1994-02-10 1994-02-10 Fibrous molding and manufacture thereof Withdrawn JPH07223209A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3771294A JPH07223209A (en) 1994-02-10 1994-02-10 Fibrous molding and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3771294A JPH07223209A (en) 1994-02-10 1994-02-10 Fibrous molding and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH07223209A true JPH07223209A (en) 1995-08-22

Family

ID=12505139

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3771294A Withdrawn JPH07223209A (en) 1994-02-10 1994-02-10 Fibrous molding and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH07223209A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002361613A (en) * 2001-06-11 2002-12-18 Kimura Chem Plants Co Ltd Method and apparatus for producing mold board
JP2003514691A (en) * 1999-11-23 2003-04-22 ジュセッペ ロカティ, Method and plant for producing paper sheets having a substantially rigid structure
US7670518B2 (en) 2000-11-23 2010-03-02 Hi-Tech Engineering Limited Composite products

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003514691A (en) * 1999-11-23 2003-04-22 ジュセッペ ロカティ, Method and plant for producing paper sheets having a substantially rigid structure
US7670518B2 (en) 2000-11-23 2010-03-02 Hi-Tech Engineering Limited Composite products
JP2002361613A (en) * 2001-06-11 2002-12-18 Kimura Chem Plants Co Ltd Method and apparatus for producing mold board

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